JP2012006916A - Powder shampoo composition - Google Patents
Powder shampoo composition Download PDFInfo
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- JP2012006916A JP2012006916A JP2011115332A JP2011115332A JP2012006916A JP 2012006916 A JP2012006916 A JP 2012006916A JP 2011115332 A JP2011115332 A JP 2011115332A JP 2011115332 A JP2011115332 A JP 2011115332A JP 2012006916 A JP2012006916 A JP 2012006916A
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- lactoferrin
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- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims abstract description 20
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- CSSYQJWUGATIHM-IKGCZBKSSA-N l-phenylalanyl-l-lysyl-l-cysteinyl-l-arginyl-l-arginyl-l-tryptophyl-l-glutaminyl-l-tryptophyl-l-arginyl-l-methionyl-l-lysyl-l-lysyl-l-leucylglycyl-l-alanyl-l-prolyl-l-seryl-l-isoleucyl-l-threonyl-l-cysteinyl-l-valyl-l-arginyl-l-arginyl-l-alanyl-l-phenylal Chemical compound C([C@H](N)C(=O)N[C@@H](CCCCN)C(=O)N[C@@H](CS)C(=O)N[C@@H](CCCNC(N)=N)C(=O)N[C@@H](CCCNC(N)=N)C(=O)N[C@@H](CC=1C2=CC=CC=C2NC=1)C(=O)N[C@@H](CCC(N)=O)C(=O)N[C@@H](CC=1C2=CC=CC=C2NC=1)C(=O)N[C@@H](CCCNC(N)=N)C(=O)N[C@@H](CCSC)C(=O)N[C@@H](CCCCN)C(=O)N[C@@H](CCCCN)C(=O)N[C@@H](CC(C)C)C(=O)NCC(=O)N[C@@H](C)C(=O)N1CCC[C@H]1C(=O)N[C@@H](CO)C(=O)N[C@@H]([C@@H](C)CC)C(=O)N[C@@H]([C@@H](C)O)C(=O)N[C@@H](CS)C(=O)N[C@@H](C(C)C)C(=O)N[C@@H](CCCNC(N)=N)C(=O)N[C@@H](CCCNC(N)=N)C(=O)N[C@@H](C)C(=O)N[C@@H](CC=1C=CC=CC=1)C(O)=O)C1=CC=CC=C1 CSSYQJWUGATIHM-IKGCZBKSSA-N 0.000 claims abstract description 15
- 229940078795 lactoferrin Drugs 0.000 claims abstract description 15
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- KZSNJWFQEVHDMF-BYPYZUCNSA-N L-valine Chemical compound CC(C)[C@H](N)C(O)=O KZSNJWFQEVHDMF-BYPYZUCNSA-N 0.000 claims description 2
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- OQFSQFPPLPISGP-UHFFFAOYSA-N beta-carboxyaspartic acid Natural products OC(=O)C(N)C(C(O)=O)C(O)=O OQFSQFPPLPISGP-UHFFFAOYSA-N 0.000 claims description 2
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Abstract
Description
本発明は、界面活性剤を含有しない粉末状シャンプー組成物に関し、洗浄力、免疫調整作用、抗菌、抗ウイルス活性、保湿性などの効果バランスの良い粉末状シャンプー組成物に関するものである。 The present invention relates to a powdery shampoo composition containing no surfactant, and relates to a powdery shampoo composition having a good balance of effects such as detergency, immunomodulating action, antibacterial activity, antiviral activity, and moisture retention.
洗髪などに用いられる液体シャンプー組成物として、５〜４０重量％の界面活性剤を含有するものが知られている（特許文献１）。しかし、界面活性剤を含有するシャンプーはアレルギー体質のユーザにとってアトピー症の発症要因になることが報告されている。このため、界面活性剤を含有しない、炭酸水素ナトリウムや炭酸ナトリウムを主剤とする衣料用洗浄組成物が提案されている（特許文献２）。 As a liquid shampoo composition used for hair washing or the like, one containing 5 to 40% by weight of a surfactant is known (Patent Document 1). However, it has been reported that a shampoo containing a surfactant is a factor in the development of atopic disease for allergic users. For this reason, the washing | cleaning composition for clothes which does not contain surfactant and which has sodium hydrogencarbonate and sodium carbonate as a main ingredient is proposed (patent document 2).
しかしながら、界面活性剤を含有しない炭酸水素ナトリウムや炭酸ナトリウムを主剤とする衣料用洗浄組成物を頭髪や洗顔用シャンプーに適用しようとすると、泡立ちしないためシャンプーが洗髪中又は洗顔中に頭髪又は顔面から流れてしまい、上手く洗髪又は洗顔できないという問題がある。 However, when applying a washing composition for clothing containing sodium bicarbonate or sodium carbonate, which does not contain a surfactant, to hair or facial shampoo, the foam does not foam, so that the shampoo is removed from the hair or face during or after washing. There is a problem in that it cannot be washed or washed well.
本発明が解決しようとする課題は、洗浄力と泡立ち性が良好で、免疫調整作用、抗菌、抗ウイルス活性、保湿性、洗髪又は洗顔作業性などの効果バランスの良い粉末状シャンプー組成物を提供することである。 The problem to be solved by the present invention is to provide a powdery shampoo composition that has good detergency and foaming properties, and has a good balance of effects such as immunomodulating action, antibacterial activity, antiviral activity, moisture retention, hair washing or face washing workability. It is to be.
本発明は、炭酸水素ナトリウム及び炭酸ナトリウムを少なくとも含む主成分たるアルカリ性無機塩と、ラクトフェリンと、アミノ酸と、増粘剤と、を含有し、界面活性剤を含有しない粉末状シャンプー組成物によって、上記課題を解決する。本発明に係る粉末状シャンプー組成物は、頭髪のみならず洗顔用としての用途を含むものである。 The present invention provides a powdered shampoo composition containing an alkaline inorganic salt as a main component containing at least sodium hydrogen carbonate and sodium carbonate, lactoferrin, an amino acid, and a thickener, and containing no surfactant. Solve the problem. The powdery shampoo composition according to the present invention includes applications for facial cleansing as well as hair.
本発明によれば、ラクトフェリンを含有し界面活性剤を含有しないので、免疫調整作用、抗菌、抗ウイルス活性に優れるとともに、アミノ酸を含有するので保湿性に優れる。また、使用に際して水に溶解すると、ラクトフェリン及びアミノ酸が炭酸水素ナトリウム及び炭酸ナトリウムと反応して炭酸ガスを発生させ、この炭酸ガスが増粘剤の作用により泡化するとともに消泡を抑制する。これによりシャンプー液の泡立ち性が良好となりシャンプー液が頭髪や顔面から流れることなく留まるので、上手く洗髪又は洗顔することができる。 According to the present invention, since lactoferrin is contained and no surfactant is contained, the immunomodulating action, antibacterial activity, and antiviral activity are excellent, and since the amino acid is contained, the moisture retention is excellent. In addition, when dissolved in water during use, lactoferrin and amino acids react with sodium hydrogen carbonate and sodium carbonate to generate carbon dioxide, which is bubbled by the action of the thickener and suppresses defoaming. As a result, the foaming property of the shampoo liquid becomes good and the shampoo liquid stays without flowing from the hair or face, so that the hair can be washed or washed well.
本発明の一実施の形態に係る粉末状シャンプー組成物は、界面活性剤を含有しないシャンプー組成物であって（以下、非界面活性剤シャンプー組成物ともいう。）、炭酸水素ナトリウム及び炭酸ナトリウムを含む主成分たるアルカリ性無機塩を洗浄作用成分として含有する。また、ラクトフェリンと、アミノ酸と、キサンタンガム又はプルランを含む増粘剤とを含有する。 The powdery shampoo composition according to one embodiment of the present invention is a shampoo composition that does not contain a surfactant (hereinafter also referred to as a non-surfactant shampoo composition), and contains sodium bicarbonate and sodium carbonate. An alkaline inorganic salt as a main component is contained as a cleaning action component. It also contains lactoferrin, amino acids, and thickeners including xanthan gum or pullulan.
洗浄作用成分たるアルカリ性無機塩は、ｐＨ緩衝作用とアルカリ作用とを有するアルカリ性無機塩である。ｐＨ緩衝作用を有するものとしては、重炭酸アルカリ金属塩、ホウ酸アルカリ金属塩、リン酸アルカリ金属塩などを挙げることができ、シュウ酸アルカリ金属塩、フタル酸アルカリ金属塩などの有機酸塩も補助的に使用できる。またアルカリ作用を有するものとしては炭酸アルカリ金属塩、ケイ酸アルカリ金属塩などを挙げることができる。これらｐＨ緩衝作用とアルカリ作用とを有するアルカリ無機塩として、少なくとも重炭酸アルカリ金属塩と炭酸アルカリ金属塩とを含むことが好ましく、なかでも炭酸水素ナトリウムと炭酸ナトリウムとを少なくとも含むことがより好ましい。 The alkaline inorganic salt as a cleaning action component is an alkaline inorganic salt having a pH buffering action and an alkaline action. Examples of those having a pH buffering action include alkali metal bicarbonates, alkali metal borates, alkali metal phosphates, and organic acid salts such as alkali metal oxalates and alkali metal phthalates. Can be used supplementarily. Examples of those having an alkali action include alkali metal carbonates and alkali metal silicates. These alkali inorganic salts having a pH buffering action and an alkali action preferably contain at least an alkali metal bicarbonate and an alkali metal carbonate, and more preferably contain at least sodium bicarbonate and sodium carbonate.
なお、上記アルカリ性無機塩に加えて、亜硫酸ナトリウムやグリチルリチン酸ジカリウムをさらに含有してもよい。亜硫酸ナトリウムは温水などの溶解液中に含まれる塩素を除去する効能があり、グリチルリチン酸ジカリウムは抗炎症作用があるため、特に頭皮や顔面に接触するシャンプーに適用して好ましい。 In addition to the alkaline inorganic salt, sodium sulfite or dipotassium glycyrrhizinate may further be contained. Sodium sulfite has an effect of removing chlorine contained in a solution such as warm water, and dipotassium glycyrrhizinate has an anti-inflammatory action, and thus is preferably applied to a shampoo that contacts the scalp and face.
ラクトフェリンは、母乳や牛乳に含まれるたんぱく質の一種であり、免疫細胞を活性化させ免疫力を高める効能がある。本例の粉末状シャンプーでは、界面活性剤を含まず、且つ免疫性能に優れたラクトフェリンを添加することで、アレルギー体質のユーザにとってアトピー症などのアレルギー症状を発症しない安全なシャンプーを提供することができる。 Lactoferrin is a kind of protein contained in breast milk and milk, and has the effect of activating immune cells and enhancing immunity. The powdered shampoo of this example can provide a safe shampoo that does not develop allergic symptoms such as atopy for users of allergic constitution by adding lactoferrin that does not contain a surfactant and has excellent immune performance. it can.
アミノ酸は、頭髪の保湿性を高めるために添加され、アスパラギン酸，アラニン，イソロイシン，グリシン，グルタミン酸，シスチン，セリン，チロシン，トリプトファン，トレオニン，バリン，ヒスチジン，フェニルアラニン，プロリン，メチオニン，リシン及びロイシンなどの１種もしくは複数種のアミノ酸を用いることができる。 Amino acids are added to enhance the moisture retention of hair, such as aspartic acid, alanine, isoleucine, glycine, glutamic acid, cystine, serine, tyrosine, tryptophan, threonine, valine, histidine, phenylalanine, proline, methionine, lysine and leucine. One or more amino acids can be used.
本例の粉末状シャンプー組成物は、洗髪の使用に際し温水に溶かして液体にするが、本例の粉末状シャンプー組成物を水に溶かすと、上記ラクトフェリンとアミノ酸は、洗浄主成分である重炭酸金属塩及び炭酸金属塩と反応し炭酸ガスを生成する。そして、この炭酸ガスと後述する増粘剤とが協働して、界面活性剤を含有しなくても泡立ち性に優れたシャンプーを提供することができる。詳細については後述する。 The powdered shampoo composition of this example is dissolved in warm water for use in hair washing to form a liquid. When the powdered shampoo composition of this example is dissolved in water, the above lactoferrin and amino acid are bicarbonate, which is a main component of washing. Reacts with metal salts and metal carbonates to produce carbon dioxide. And this carbon dioxide gas and the thickener mentioned later can cooperate, and even if it does not contain surfactant, the shampoo excellent in foaming property can be provided. Details will be described later.
増粘剤は、本例の粉末状シャンプー組成物を温水に溶かして液状シャンプーとしたときの泡立ち性を高める機能を司り、キサンタンガムやプルランなどの多糖類を用いることができる。 The thickener is responsible for the function of improving foamability when the powdered shampoo composition of this example is dissolved in warm water to form a liquid shampoo, and polysaccharides such as xanthan gum and pullulan can be used.
必要に応じてクエン酸をさらに添加することもできる。クエン酸は、上述したアミノ酸やラクトフェリンと同様に重炭酸金属塩及び炭酸金属塩と反応して液体中にて炭酸ガスを生成するので、クエン酸を添加することで液状シャンプーの泡立ち性がより向上する。 If necessary, citric acid can be further added. Citric acid reacts with metal bicarbonate and metal carbonate to produce carbon dioxide gas in the liquid in the same way as amino acids and lactoferrin described above, so adding citric acid improves the foaming properties of liquid shampoo. To do.
本例の粉末状シャンプー組成物は、前記ラクトフェリンを０．１〜０．４重量％、アミノ酸を１〜７重量％、増粘剤を３〜７重量％、炭酸水素ナトリウム及び炭酸ナトリウム含む主成分たるアルカリ性無機塩を８７〜９３重量％含有する。また、必要に応じて塩素除去性能を有する亜硫酸ナトリウムを０．５〜１．５重量％、抗炎症性能を有するグリチルリチン酸ジカリウムを０．００２〜０．００８重量％、クエン酸を２〜６重量％含有してもよい。 The powdered shampoo composition of this example is a main component containing the lactoferrin 0.1-0.4 wt%, amino acids 1-7 wt%, thickener 3-7 wt%, sodium bicarbonate and sodium carbonate. It contains 87 to 93% by weight of an alkaline inorganic salt. Further, if necessary, 0.5 to 1.5% by weight of sodium sulfite having chlorine removal performance, 0.002 to 0.008% by weight of dipotassium glycyrrhizinate having anti-inflammatory performance, and 2 to 6% of citric acid % May be contained.
そして、本例の粉末状シャンプー組成物は洗髪の使用に供されるまでは粉末状とされ、使用に際し温水に溶かして液状シャンプーとされる。使用するまでは粉末状シャンプー組成物としているので、防腐剤などの添加物が不要となり、安全性や保存性が向上する。 And the powdery shampoo composition of this example is made into a powder form until it is used for the use of shampooing, and in use, is dissolved in warm water to form a liquid shampoo. Since it is a powdery shampoo composition until it is used, additives such as preservatives are not required, and safety and storage stability are improved.
洗髪の使用に際しては、１８０〜２２０ｃｃの攪拌容器を準備し、これに３８〜４２℃の温水と、温水１００重量部に対し８〜１６重量部の粉末状シャンプー組成物とを入れ、攪拌容器を封止した状態でよく振り、攪拌する。これにより、重炭酸金属塩及び炭酸金属塩と、アミノ酸及びラクトフェリン並びに必要に応じて添加されたクエン酸とが反応し炭酸ガスが発生する。発生した炭酸ガスは増粘剤の作用によって発泡し、さらに消泡が抑制されて維持されることになる。そして、泡立ちした状態の液状シャンプーを頭髪に滴下し、頭皮をマッサージするように手で洗う。 When using the shampoo, prepare a stirring vessel of 180 to 220 cc, put 38 to 42 ° C. warm water and 8 to 16 parts by weight of a powdered shampoo composition with respect to 100 parts by weight of hot water, Shake well in a sealed state and stir. Thereby, a bicarbonate metal salt and a carbonate carbonate salt react with an amino acid, lactoferrin, and citric acid added as necessary to generate carbon dioxide gas. The generated carbon dioxide gas is foamed by the action of the thickener, and the defoaming is further suppressed and maintained. Then, a liquid shampoo in a foamed state is dropped onto the hair and washed with hands to massage the scalp.
シャンプーを終えたら温水で頭皮及び頭髪をすすぐことで洗髪を終了するが、本例のシャンプー組成物は界面活性剤を含有せず、アルカリ性無機塩を主成分としているため、成分の残留を気にすることなく少量のすすぎ湯で足りる。 After finishing the shampoo, shampoo the scalp and hair with warm water to finish washing the hair, but the shampoo composition of this example does not contain a surfactant and is mainly composed of an alkaline inorganic salt. A small amount of rinsing water is sufficient without doing so.
また、本例のシャンプー組成物はラクトフェリンを含有し界面活性剤を含有しないので、免疫調整作用、抗菌、抗ウイルス活性に優れるとともに、アミノ酸を含有するので保湿性に優れる。さらに、上述したように洗髪に際しては、ラクトフェリン及びアミノ酸が炭酸水素ナトリウム及び炭酸ナトリウムと反応して炭酸ガスを発生し、この炭酸ガスが増粘剤の作用により泡化して消泡を抑制するので、シャンプー液の泡立ち性も良好となる。しかも、洗髪又は洗顔するまでは粉末状であるため防腐剤が不要となり、より安全性が向上する。 Moreover, since the shampoo composition of this example contains lactoferrin and does not contain a surfactant, it is excellent in immunomodulating action, antibacterial activity and antiviral activity, and is excellent in moisture retention because it contains an amino acid. Furthermore, as described above, when washing the hair, lactoferrin and amino acids react with sodium hydrogen carbonate and sodium carbonate to generate carbon dioxide gas, and the carbon dioxide gas is foamed by the action of the thickener to suppress defoaming. The foaming property of the shampoo liquid is also improved. Moreover, since the powder is in the form of a powder until the hair is washed or the face is washed, no preservative is required and the safety is further improved.
《洗浄性の確認》
本例の粉末状シャンプー組成物の洗浄性能を確認するために、下記表１の配合の粉末状シャンプー組成物を作製し、それぞれを４０℃の温水に溶解して液状シャンプーとした。これを用いてＪＩＳ湿式人口汚染布（人工襟垢汚れ）をターゴトメータ（攪拌式洗浄力試験機）で洗浄し、洗浄率を測定した。洗浄率（％）は、（洗浄後の白度−洗浄前の白度）／（元布白度−洗浄前の白度）×１００にて算出した。比較例５として市販の液体シャンプー（花王社製メリット（登録商標））を用いて同様の条件で洗浄率を測定した。この結果を表１に示す。
<Confirmation of cleanability>
In order to confirm the cleaning performance of the powdery shampoo composition of this example, powdery shampoo compositions having the composition shown in Table 1 below were prepared and dissolved in warm water at 40 ° C. to obtain liquid shampoos. Using this, a JIS wet artificially contaminated cloth (artificial collar stain) was washed with a targotometer (stirring detergency tester), and the washing rate was measured. The washing rate (%) was calculated by (whiteness after washing−whiteness before washing) / (original fabric whiteness−whiteness before washing) × 100. As Comparative Example 5, the washing rate was measured under the same conditions by using a commercially available liquid shampoo (Merit (registered trademark) manufactured by Kao Corporation). The results are shown in Table 1.
また、上記実施例１〜４について、液状シャンプーとした際の泡立ち性を目視評価した結果を表１に示す。「○」は泡立ち性が良好で洗髪作業性に問題がない状態、「△」は泡立ち性がやや悪く洗髪作業性に難がある状態、「×」は泡立ちが皆無又は殆んど泡立ちが観察されず洗髪作業性に問題がある状態をそれぞれ示す。 Moreover, about the said Examples 1-4, the result of having evaluated the foaming property at the time of setting it as a liquid shampoo is shown in Table 1. “○” indicates good foaming and no problem in hair washing workability, “△” indicates slightly poor foaming and difficulty in hair washing workability, and “×” indicates no or almost no foaming. Each of them shows a state in which there is a problem in hair washing workability.
《アレルギー体質のユーザへの影響》
上記実施例２の粉末状シャンプー組成物を温水に溶かし、アトピー症の男性の患者Ａの頭髪洗浄と全身洗浄に使用したところ、使用開始から２日目に、それまで真っ赤だった頭皮や背中がきれいになり始め、就寝中に頻繁に頭や背中を掻くこともなくなった。使用開始から３ヶ月を経過すると、頭皮や背中をはじめ全身のアトピー症状がなくなり、また痒みもなくなった。
《Effects of allergies on users》
When the powdered shampoo composition of Example 2 was dissolved in warm water and used for hair washing and whole body washing of male patient A with atopic disease, on the second day from the start of use, the scalp and back that had been red until then were removed. She started to clean up and did not scratch her head and back frequently during bedtime. After 3 months from the start of use, there was no atopic symptoms throughout the scalp and back, and no itching.
同じく実施例２の粉末状シャンプー組成物を温水に溶かし、アトピー症の男子の患者Ｂの頭髪洗浄と全身洗浄に使用したところ、使用開始から５ヶ月経過した時点で頭皮の赤くボツボツとした湿疹がなくなった。さらに、８ヶ月経過した時点で、頭皮の痒みや痛みがなくなり、その状態も大幅に改善した。 Similarly, when the powdered shampoo composition of Example 2 was dissolved in warm water and used for scrubbing and washing the whole body of a patient B of atopic syndrome, the scalp had a red and crumbly eczema after 5 months from the start of use. lost. Furthermore, at the time when 8 months passed, the scalp itching and pain disappeared, and the condition improved greatly.
同じく実施例２の粉末状シャンプー組成物を温水に溶かし、アトピー症の男性の患者Ｃの頭髪洗浄と全身洗浄に使用したところ、使用開始から1ヶ月も経たないうちに、頭皮をはじめ発汗し易い部分の痒みや痛みがなくなった。 Similarly, when the powdered shampoo composition of Example 2 was dissolved in warm water and used for scrubbing and washing the head of a male patient C with atopic disease, it was easy to sweat, including the scalp, within a month from the start of use. The itchiness and pain of the part disappeared.
Claims (6)
界面活性剤を含有しないことを特徴とする粉末状シャンプー組成物。 An alkaline inorganic salt as a main component containing sodium bicarbonate and sodium carbonate, lactoferrin, amino acid, and a thickener containing xanthan gum or pullulan,
A powdered shampoo composition characterized by not containing a surfactant.
前記ラクトフェリンを０．１〜０．４重量％、前記アミノ酸を１〜７重量％、前記増粘剤を３〜７重量％、前記アルカリ性無機塩を８７〜９３重量％含有することを特徴とする粉末状シャンプー組成物。 The powdered shampoo composition according to claim 1,
0.1 to 0.4% by weight of the lactoferrin, 1 to 7% by weight of the amino acid, 3 to 7% by weight of the thickener, and 87 to 93% by weight of the alkaline inorganic salt. Powdered shampoo composition.
２〜６重量％のクエン酸をさらに含有することを特徴とする粉末状シャンプー組成物。 The powdered shampoo composition according to claim 1 or 2,
A powdery shampoo composition further comprising 2 to 6% by weight of citric acid.
前記アミノ酸は、アスパラギン酸，アラニン，イソロイシン，グリシン，グルタミン酸，シスチン，セリン，チロシン，トリプトファン，トレオニン，バリン，ヒスチジン，フェニルアラニン，プロリン，メチオニン，リシン及びロイシンからなる群より選ばれる１又はそれ以上のアミノ酸であることを特徴とする粉末状シャンプー組成物。 In the powdery shampoo composition according to any one of claims 1 to 3,
The amino acid is one or more amino acids selected from the group consisting of aspartic acid, alanine, isoleucine, glycine, glutamic acid, cystine, serine, tyrosine, tryptophan, threonine, valine, histidine, phenylalanine, proline, methionine, lysine and leucine. A powdered shampoo composition characterized by
前記温水１００重量部に対し、前記粉末状シャンプー組成物を８〜１６重量部添加して攪拌することを特徴とする洗髪方法。 In the hair washing method of Claim 5,
A hair washing method, comprising adding 8 to 16 parts by weight of the powdered shampoo composition to 100 parts by weight of warm water and stirring.
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| KR20130114986A (en) * | 2012-04-10 | 2013-10-21 | 주식회사 엘지생활건강 | Dry shampoo usable without water |
| KR101426914B1 (en) | 2014-04-25 | 2014-08-05 | 주식회사 뉴앤뉴 | Composition of scalp massage set |
| CN107184418A (en) * | 2017-04-06 | 2017-09-22 | 山东省药学科学院 | A kind of hair conditioner of pullulan-containing |
| JP2017178917A (en) * | 2016-03-28 | 2017-10-05 | 株式会社ホットアルバム炭酸泉タブレット | Solid washing agents, mineral stains washing methods, and skin or hair cosmetic methods |
| KR20190032313A (en) * | 2019-03-13 | 2019-03-27 | 주식회사 엘지생활건강 | Dry Shampoo usable without water |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| KR20130114986A (en) * | 2012-04-10 | 2013-10-21 | 주식회사 엘지생활건강 | Dry shampoo usable without water |
| KR101966251B1 (en) * | 2012-04-10 | 2019-08-13 | 주식회사 엘지생활건강 | Dry Shampoo usable without water |
| KR101426914B1 (en) | 2014-04-25 | 2014-08-05 | 주식회사 뉴앤뉴 | Composition of scalp massage set |
| JP2017178917A (en) * | 2016-03-28 | 2017-10-05 | 株式会社ホットアルバム炭酸泉タブレット | Solid washing agents, mineral stains washing methods, and skin or hair cosmetic methods |
| CN107184418A (en) * | 2017-04-06 | 2017-09-22 | 山东省药学科学院 | A kind of hair conditioner of pullulan-containing |
| KR20190032313A (en) * | 2019-03-13 | 2019-03-27 | 주식회사 엘지생활건강 | Dry Shampoo usable without water |
| KR102067109B1 (en) * | 2019-03-13 | 2020-02-11 | 주식회사 엘지생활건강 | Dry Shampoo usable without water |
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