JP2012000089A - Tea essence - Google Patents

Tea essence Download PDF

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JP2012000089A
JP2012000089A JP2010140828A JP2010140828A JP2012000089A JP 2012000089 A JP2012000089 A JP 2012000089A JP 2010140828 A JP2010140828 A JP 2010140828A JP 2010140828 A JP2010140828 A JP 2010140828A JP 2012000089 A JP2012000089 A JP 2012000089A
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tea
extract
distillate
steam distillation
tea leaves
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JP5622451B2 (en
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Koichiro Maekawa
浩一郎 前川
Takeshi Sato
剛 佐藤
Yasutaka Shoji
靖隆 庄司
Akinori Osada
晃典 長田
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Ogawa and Co Ltd
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Abstract

PROBLEM TO BE SOLVED: To provide a material for a container-packed tea drink, enabling the container-packed tea drink having more natural flavor to be produced by improving the damage of the flavor caused by an undesirable flavor component contained in a raw material tea leaf.SOLUTION: The tea essence is produced by a method including the following steps 1 to 4: (step 1): the step for separating a distillate from tea leaves by fractionating the raw material tea leaves by reduced-pressure steam distillation; (step 2): the step for separating the distillate from the tea leaf residue by fractionating the tea leaves separated at the step 1 by normal-pressure steam distillation; (step 3): the step for obtaining an extract by extracting the tea leaf residue separated at the step 2 with water; and (step 4): the step for producing the tea essence by mixing the distillate separated at the step 2 with the extract separated at the step 3.

Description

本発明は、容器詰茶飲料等の飲食品に優れた香味を付与する茶エキスおよびその製造方法に関する。   The present invention relates to a tea extract that imparts an excellent flavor to food and drink such as a packaged tea beverage and a method for producing the same.

緑茶に代表される茶飲料は、日々の生活に潤いを与え、日本人の生活にはなくてはならないものである。近年では茶の持つ抗酸化性が注目を集めており、ノンカロリーの健康的な飲み物として、茶飲料は無糖飲料の代表的なものとなってきている。さらに最近では嗜好性の多様化により、種々の茶飲料が市場に供されている。   Tea drinks, typified by green tea, provide moisture for daily life and are essential for the lives of Japanese people. In recent years, the antioxidant properties of tea have attracted attention, and as a non-calorie healthy drink, tea drinks have become representative of sugar-free drinks. More recently, various tea beverages have been put on the market due to diversification of palatability.

茶飲料は、一般に茶葉を水などの水性溶媒で抽出して茶エキスを得、この茶エキスを飲料濃度になるよう濃度調整等を行った後、アルミや鉄製の缶、ペット(PET)やガラス製のボトルなどの密封容器に封入して販売されている。しかし、水性溶媒での抽出では茶葉に含まれる香気成分が十分に回収されないことに加え、原料茶葉に含まれる好ましくない香気成分により、茶飲料の香味が損なわれる場合がある。
茶飲料は、品質として香味、特に香気(香り)が重要視される飲料であることから、容器詰茶飲料の香味の改善に関しては、多種多様な改良方法が提案されている。
For tea beverages, tea leaves are generally extracted with an aqueous solvent such as water to obtain a tea extract, and after adjusting the concentration of the tea extract to a beverage concentration, aluminum or iron cans, pets (PET) or glass It is sold in sealed containers such as made bottles. However, the extraction with an aqueous solvent does not sufficiently recover the aromatic components contained in the tea leaves, and the flavor of the tea beverage may be impaired by the undesirable aromatic components contained in the raw tea leaves.
Since tea beverages are beverages in which flavor, particularly aroma (fragrance), is important as quality, various methods for improving the flavor of packaged tea beverages have been proposed.

例えば、茶葉の香気成分を捕集して利用した香味の良い茶エキスとして、茶葉を温水で浸漬もしくは湿潤させる工程1、工程1の茶葉を水蒸気抽出し、溜出液を回収する工程2、工程2の溜出残渣を水で抽出し、抽出液を回収する工程3、工程2の溜出液と工程3の抽出液とを混合する工程4とを含む方法により得られる、殺菌工程後にも優れた香りや風味を有する茶エキスが提案されている(特許文献1)。   For example, as a savory tea extract that collects and uses aroma components of tea leaves, Step 1 where tea leaves are immersed or moistened with warm water, Step 1 is a process of recovering distillate by steam extraction of tea leaves in Step 1 2 after extraction with water and recovering the extract, and after the sterilization step, which is obtained by a method comprising the step 3 of recovering the extract and the step 4 of mixing the distillate of step 2 and the extract of step 3 A tea extract having an aroma and flavor has been proposed (Patent Document 1).

また、抹茶を温水にてスラリーとし、該スラリーを向流接触装置(SCC)にて処理し、フレーバーを回収する第1の工程と、別途茶葉を温水抽出し、固形物を除去後活性炭処理を行い、次いで濾過により活性炭を除去して茶抽出液を得る第2の工程と、第1の工程により得られたフレーバーと第2の工程で得られた茶抽出液とを混合する第3の工程とを含む方法により得られる、抹茶のまったりとした甘味を与える茶エキスなども提案されている(特許文献2)。   In addition, the matcha tea is made into a slurry with warm water, the slurry is treated with a counter-current contact device (SCC), and the flavor is recovered. And then the second step of obtaining the tea extract by removing the activated carbon by filtration, and the third step of mixing the flavor obtained in the first step and the tea extract obtained in the second step. A tea extract that gives a sweet taste of matcha tea obtained by a method comprising

一方、緑茶、烏龍茶、紅茶などの嗜好飲料にバランスのよい香味を付与することができる新規フレーバーとして、嗜好飲料用原料を水蒸気蒸留して得られるフレーバー(A)と、嗜好飲料用原料を向流接触装置(SCC)に供して得られるフレーバー(B)とを含有し、かつフレーバー(A)の1重量部あたりフレーバー(B)を0.01〜100重量部の範囲内で含有する新規フレーバーが提案されている(特許文献3)。   On the other hand, as a new flavor capable of imparting a balanced flavor to taste drinks such as green tea, oolong tea and black tea, the flavor (A) obtained by steam distillation of the taste drink ingredients and the taste drink ingredients A flavor (B) obtained by subjecting to a contact device (SCC) and a flavor (B) in a range of 0.01 to 100 parts by weight per part by weight of the flavor (A) It has been proposed (Patent Document 3).

また、香味を改善する茶飲料用添加剤として、2,3−ジエチル−5−メチルピラジン
、2−メチルピラジン又は3−エチル−2,5−ジメチルピラジンからなる飲みごたえ感
を与える茶飲料用添加剤(特許文献4)、2,5−ジメチル−4−ヒドロキシ−3(2H
)−フラノンからなる高級茶葉のまったりとした甘さを与える茶飲料用添加剤(特許文献5)、茶抽出物の活性炭処理物からなる高級茶葉のまったりとした甘さを与える茶飲料用添加剤(特許文献6)なども提案されている。
In addition, as an additive for tea beverages for improving the flavor, an additive for tea beverages that gives a feeling of drinking made of 2,3-diethyl-5-methylpyrazine, 2-methylpyrazine or 3-ethyl-2,5-dimethylpyrazine Agent (Patent Document 4) 2,5-dimethyl-4-hydroxy-3 (2H
) -Additives for tea beverages that give the sweetness of luxury tea leaves made of furanone (Patent Document 5), Additives for tea beverages that give the sweetness of luxury tea leaves made of activated charcoal-treated products of tea extracts (Patent Document 6) has also been proposed.

特許第4104018号公報Japanese Patent No. 4104018 特開2007−167005号公報JP 2007-167005 A 特開2003−33137号公報JP 2003-33137 A 特開2008−148604号公報JP 2008-148604 A 特開2007−167003号公報JP 2007-167003 A 特開2007−167004号公報JP 2007-167004 A

上記先行技術は主として抽出時に回収される香気成分の量を増加させたり、容器詰茶飲料製造時の加熱殺菌により失われる香気成分を補充するものであり、容器詰茶飲料の香味の改善に一定の効果はあるものの、原料茶葉に含まれている好ましくない香気成分に起因する香味の毀損を改善するには至っていない。
本発明の課題は、原料茶葉に含まれる好ましくない香気成分に起因する香味の毀損を改善し、より自然な香味を有する容器詰茶飲料を製造しうる、容器詰茶飲料用素材を提供することである。
The above-mentioned prior art mainly increases the amount of aroma components recovered during extraction, or supplements aroma components lost by heat sterilization during manufacture of packaged tea beverages, and is consistent in improving the flavor of packaged tea beverages Although there is an effect of the above, it has not led to an improvement in flavor damage caused by an unfavorable aroma component contained in the raw tea leaves.
An object of the present invention is to provide a container-packed tea beverage material that can improve a flavor loss caused by an unfavorable aroma component contained in a raw tea leaf and can manufacture a container-packed tea drink having a more natural flavor. It is.

本発明者らは容器詰茶飲料の香味を改善する素材を提供するため、茶エキスの製造法を検討した。
茶の香りは栽培方法、茶葉の摘採時期、加工方法等により変化するが、これは香りを構成する多数の香気成分のバランスが変化することによると考えられている。例えば、緑茶の場合、新茶では青いフレッシュな香りを表す成分を多く含むが、摘採時期が後になるほどフレッシュな香りは減少し、最後に摘採される秋冬番茶では所謂「番茶臭」と呼ばれる好ましくない香気が増加する。
本発明者らは茶エキスの製造法を種々検討したところ、秋冬番茶を減圧水蒸気蒸留することにより好ましくない香気成分が除去されること、および好ましくない香気成分を除去した秋冬番茶を常圧水蒸気蒸留すると新茶のような甘く良質なグリーン感と華やかなフローラル香を有する留出液が得られることを見出した。
The present inventors examined a method for producing a tea extract in order to provide a material for improving the flavor of a packaged tea beverage.
The scent of tea varies depending on the cultivation method, the picking time of tea leaves, the processing method, etc., and this is considered to be due to the change in the balance of a large number of aroma components constituting the scent. For example, in the case of green tea, new tea contains a lot of components representing a blue fresh fragrance, but the fresh fragrance decreases as the picking time is later, and in the last picked autumn / winter bancha, an unpleasant fragrance called the so-called `` bancha odor '' Will increase.
The inventors of the present invention have studied various methods for producing a tea extract, wherein undesired aroma components are removed by subjecting autumn / winter bancha to steam distillation under reduced pressure, and autumn / winter bancha from which undesired aroma components have been removed to atmospheric steam distillation. It was found that a distillate having a sweet and high quality green feeling and a gorgeous floral scent like a new tea can be obtained.

この知見に基づき、秋冬番茶から減圧水蒸気蒸留により回収される香気成分を除去した後、常圧水蒸気蒸留を行って留出液を回収し、この留出液と水蒸気蒸留後の茶葉を水で抽出して得られた抽出液を混合することにより、新茶を原料とした場合と同等の甘く良質なグリーン感と華やかなフローラル香を持つ、緑茶エキスを得ることができることを見出した。さらにこの方法を用いて秋冬番茶以外の茶エキスを製造したところ、同様に好ましくない香気を含む茶葉から優れた香味を有する茶エキスが得られることを見出し、本発明を完成した。   Based on this knowledge, after removing the aroma components recovered from the fall / winter bancha by vacuum steam distillation, atmospheric steam distillation is performed to recover the distillate, and the distillate and steam-distilled tea leaves are extracted with water. It was found that a green tea extract having a sweet and high quality green feeling and a gorgeous floral scent equivalent to the case of using new tea as a raw material can be obtained by mixing the obtained extract. Further, when a tea extract other than autumn / winter bancha was produced using this method, it was found that a tea extract having an excellent flavor was obtained from tea leaves containing an unfavorable aroma, and the present invention was completed.

すなわち、本発明は以下のとおりである。
〔1〕下記の工程1〜4を含む方法によって製造される茶エキス。
(工程1)原料茶葉を減圧水蒸気蒸留により分画して留出液と茶葉を分離する工程
(工程2)工程1で分離された茶葉を常圧水蒸気蒸留により分画して留出液と茶葉残渣を分離する工程
(工程3)工程2で分離された茶葉残渣を水抽出して抽出液を得る工程
(工程4)工程2で分離された留出液と工程3で分離された抽出液を混合して茶エキスを製造する工程
That is, the present invention is as follows.
[1] A tea extract produced by a method comprising the following steps 1 to 4.
(Step 1) Step of fractionating raw tea leaves by vacuum steam distillation to separate the distillate and tea leaves (Step 2) Fractionation of tea leaves separated in step 1 by atmospheric steam distillation to distillate and tea leaves Step of separating the residue (Step 3) Step of extracting the tea leaf residue separated in Step 2 with water to obtain an extract (Step 4) The distillate separated in Step 2 and the extract separated in Step 3 Process of mixing and producing tea extract

〔2〕工程1における減圧水蒸気蒸留の条件が、減圧度がゲージ圧で−90〜−30kPaG、空間速度(SV)が50〜450h-1の水蒸気蒸留であり、その留出量が原料茶葉に対して5〜100%(質量比)であることを特徴とする〔1〕の茶エキス。 [2] The conditions of the reduced-pressure steam distillation in step 1 are steam distillation with a degree of vacuum of −90 to −30 kPaG in gauge pressure and a space velocity (SV) of 50 to 450 h −1 , and the amount of distillate in the raw tea leaves The tea extract according to [1], which is 5 to 100% (mass ratio).

〔3〕工程2の水抽出物を酵素処理および/または吸着剤処理によって精製することを特徴とする〔1〕または〔2〕のいずれかに記載の茶エキス。
〔4〕アスコルビン酸またはその塩を添加することを特徴とする〔1〕〜〔3〕のいずれかに記載の茶エキス。
〔5〕〔1〕〜〔4〕のいずれかに記載の茶エキスを添加したことを特徴とする飲食品。
[3] The tea extract according to either [1] or [2], wherein the water extract of step 2 is purified by enzyme treatment and / or adsorbent treatment.
[4] The tea extract according to any one of [1] to [3], wherein ascorbic acid or a salt thereof is added.
[5] A food or drink comprising the tea extract according to any one of [1] to [4].

本発明の茶エキスは原料茶葉に含まれる好ましくない香気が少なく、新茶を想起させる優れた香味を有することから、容器詰茶飲料に優れた風味を付与することができる。また、その豊かな香気から、茶風味を付与する素材として茶飲料以外の飲食品にも幅広く使用することが可能である。   Since the tea extract of the present invention has an unfavorable aroma contained in the raw tea leaves and has an excellent flavor reminiscent of a new tea, it can impart an excellent flavor to a packaged tea beverage. In addition, because of its rich aroma, it can be widely used in foods and drinks other than tea drinks as a material imparting tea flavor.

以下に、本発明を実施の形態に即して詳細に説明する。
(1)原料茶葉
本発明の茶エキスの原料である茶葉は、ツバキ科の常緑樹であるチャ(Camellia sinensis)の芽、葉、茎に飲料用として前処理を施したものである。茶の前処理方法としては不発酵、半発酵、後発酵があるが、いずれの処理方法によるものでもよい。不発酵茶としては緑茶(煎茶、玉露、かぶせ茶、番茶、玉緑茶、抹茶、ほうじ茶、釜炒り茶、てん茶等)、半発酵茶としてはウーロン茶、包種茶等、発酵茶としては紅茶、プーアール茶が挙げられる。茶葉は種類、等級、産地、製法などは何ら限定されることはなく、いずれの茶葉でも可能である。あるいは、種類の異なる茶葉を1種または2種以上を混合して用いてもよい。
Hereinafter, the present invention will be described in detail according to embodiments.
(1) Raw Tea Leaves Tea leaves, which are the raw materials of the tea extract of the present invention, are obtained by pre-treating tea (Camellia sinensis) buds, leaves, and stems for drinks. Tea pretreatment methods include non-fermentation, semi-fermentation, and post-fermentation, and any treatment method may be used. Non-fermented tea is green tea (sencha, gyokuro, kabusecha, bancha, tamago green tea, matcha, hojicha, kettle roasted tea, tencha, etc.), semi-fermented tea such as oolong tea, bald tea, etc. Pu-erh tea can be mentioned. There are no restrictions on the type, grade, production area, and production method of tea leaves, and any tea leaves are possible. Alternatively, different types of tea leaves may be used alone or in combination of two or more.

(2)工程1
本発明の茶エキスの製造では、まず上記(1)原料茶葉を減圧下で水蒸気蒸留し、留出する香気成分を分離する。茶葉に含まれる好ましくない香気成分は、この操作により効果的に除去することができる。減圧水蒸気蒸留の減圧度は特に限定されるものではなく、通常はゲージ圧で−90〜−30kPaGの範囲で行われるが、−71〜−31kPaGの範囲がより好ましい。減圧度がゲージ圧で−90kPaGを超えた場合は香気成分の力価が弱い場合があり、減圧度がゲージ圧で−30kPaG未満の場合は、蒸れた香りが発生する可能性がある。なお、本発明でいうゲージ圧とは、「大気圧基準」を意味する。
(2) Step 1
In the production of the tea extract of the present invention, first, the above (1) raw tea leaves are subjected to steam distillation under reduced pressure to separate aroma components to be distilled. Undesirable aroma components contained in tea leaves can be effectively removed by this operation. The degree of reduced pressure of the reduced-pressure steam distillation is not particularly limited, and is usually performed in a gauge pressure range of −90 to −30 kPaG, and more preferably −71 to −31 kPaG. When the degree of vacuum exceeds -90 kPaG by gauge pressure, the titer of the fragrance component may be weak, and when the degree of vacuum is less than -30 kPaG by gauge pressure, a steamed scent may be generated. In the present invention, the gauge pressure means “atmospheric pressure standard”.

減圧水蒸気蒸留の空間速度(SV)は限定されるものではなく、通常は50〜450h-1の範囲で行われるが、100〜350h-1の範囲で行うのがより好ましく、また、留出量を測定し、分画できる構造の蒸留装置を用いることが好ましい。空間速度で50h-1未満の場合は、商業的に抽出に時間がかかりすぎることで適切ではなく、また時間がかかりすぎることで蒸れた香りが強くなり、良くない場合があり、空間速度が450h-1を超えた場合は得られた香気成分のキャラクターが弱く、また力価が不足する可能性がある。
留出量は通常、原料茶葉に対して質量比で5〜100%であるが、より好ましくは5〜15%である。留出量が原料茶葉に対して5%以下の場合は好ましくない香気成分が十分に除去されず、100%以上の場合は好ましい香気成分も留出し、最終的に得られる茶エキスの風味が損なわれることがある。
Space velocity vacuum steam distillation (SV) is not limited, but usually is carried out in the range of 50~450H -1, more preferably in a range of 100~350H -1, also, distillate volume It is preferable to use a distillation apparatus having a structure capable of measuring and fractionating. When the space velocity is less than 50 h −1 , it is not appropriate because it takes a long time to extract commercially, and when it takes too much time, the steamed aroma becomes strong and may not be good, and the space velocity is 450 h. If it exceeds -1 , the obtained fragrance character may be weak and the titer may be insufficient.
The distillate amount is usually 5 to 100% by mass ratio with respect to the raw tea leaves, more preferably 5 to 15%. When the amount of distillate is 5% or less with respect to the raw tea leaves, unfavorable aroma components are not sufficiently removed. May be.

(3)工程2
原料茶葉を減圧水蒸気蒸留処理して好ましくない香気成分を除去した茶葉を、さらに常圧水蒸気蒸留により留出液を回収する。蒸留条件は空間速度(SV)が60〜100h-1であることが好ましく、また、好ましくは留出量を測定し、分画できる構造の蒸留装置を用いることが好ましい。
留出量は一般に原料茶葉に対して質量比で50〜150%とすることが好ましい。工程1で好ましくない香気成分を除去した茶葉はあまり強い香気を有していないが、これを常圧水蒸気蒸留すると不快臭のない優れた香気を有する留出液が得られる。常圧水蒸気蒸留により香気成分量が増加する理由は明らかではないが、良質な香気成分は茶葉中に配糖体の形で存在しており、これが常圧水蒸気蒸留により加水分解されて香気成分として水蒸気と共に留出すると考えられる。
(3) Step 2
The distillate is recovered from the tea leaves from which the undesired aromatic components have been removed by subjecting the raw tea leaves to reduced-pressure steam distillation, and further subjected to atmospheric steam distillation. As the distillation conditions, the space velocity (SV) is preferably 60 to 100 h −1 , and it is preferable to use a distillation apparatus having a structure capable of measuring and distilling the distillate.
In general, the distillate amount is preferably 50 to 150% by mass ratio with respect to the raw tea leaves. The tea leaves from which undesired fragrance components have been removed in step 1 do not have a very strong fragrance, but when this is steamed at atmospheric pressure, a distillate having an excellent fragrance without an unpleasant odor can be obtained. The reason why the amount of aroma components increases due to atmospheric steam distillation is not clear, but high-quality aroma components exist in the form of glycosides in tea leaves, which are hydrolyzed by atmospheric steam distillation as aroma components. Distilled with water vapor.

(4)工程3
工程3では常圧水蒸気蒸留後の茶葉残渣をさらに水抽出して抽出液を得る。水抽出の処理は特に制限はないが、好ましくは抽出量を測定し分画できる装置を使用することが好ましく、ドリップ方式で行うことがより好ましい。
抽出温度は特に限定されないが、30〜100℃が好ましい。
また、抽出量は特に制限はないが、水蒸気蒸留前の原料茶葉に対し、通常、質量比で100〜1000%であり、200〜700%がより好ましい。
(4) Step 3
In step 3, the tea leaf residue after atmospheric steam distillation is further extracted with water to obtain an extract. The water extraction treatment is not particularly limited, but it is preferable to use an apparatus that can measure and fractionate the extraction amount, and more preferably a drip method.
Although extraction temperature is not specifically limited, 30-100 degreeC is preferable.
Moreover, although there is no restriction | limiting in particular in the extraction amount, It is 100-1000% by mass ratio with respect to the raw material tea leaves before steam distillation, and 200-700% is more preferable.

工程3で得られた抽出液はそのまま工程2の留出液と混合して茶エキスとすることもできるが(工程4)、工程4に先立ち抽出液に酵素を添加して酵素処理を行うことにより、より風味が優れた清澄性の高い茶エキスが得られる。酵素としては特に制限なく、タンナーゼ、ペクチナーゼ、セルラーゼ、ヘミセルラーゼ、プロテアーゼ等の茶飲料の製造に通常用いられる酵素が使用できるが、特にタンナーゼ、ペクチナーゼ、セルラーゼから選択される1種または2種以上の酵素を使用することが好ましい。酵素の使用量は力価などにより異なるが、原料の茶葉の質量を基準として0.01〜100unit/gの範囲を例示することができる。   The extract obtained in step 3 can be directly mixed with the distillate from step 2 to obtain a tea extract (step 4). However, prior to step 4, an enzyme is added to the extract to perform enzyme treatment. As a result, a highly clear tea extract having a better flavor can be obtained. The enzyme is not particularly limited, and enzymes usually used for the production of tea beverages such as tannase, pectinase, cellulase, hemicellulase, and protease can be used, but in particular one or more selected from tannase, pectinase, and cellulase It is preferred to use an enzyme. The amount of the enzyme used varies depending on the titer and the like, but a range of 0.01 to 100 units / g can be exemplified based on the mass of the raw tea leaves.

また、工程4に先立ち工程3で得られた抽出液をさらに吸着剤で精製処理することにより、色調に優れ、苦味や渋味がさらに低減された抽出液を得ることができる。
吸着剤は活性炭、合成吸着剤を挙げることができ、いずれも特に限定することなく用いることができる。合成吸着剤としては、その母体がスチレン系ポリマー、例えば「アンバーライト(登録商標)XAD−16」(オルガノ株式会社製)、スチレン−ジビニルベンゼン系ポリマー、例えば「ダイヤイオン(登録商標)HP−20」(三菱化学株式会社製)、アクリル系ポリマー、例えば「ダイヤイオン(登録商標)WK−10」(三菱化学株式会社製)、メタクリル系ポリマー、例えば「ダイヤイオン(登録商標)HP−2MG」(三菱化学株式会社製)、アクリル酸エステル系ポリマー、例えば「アンバーライト(登録商標)XAD−7」(オルガノ株式会社製)、アミド系ポリマー、例えば「アンバーライト(登録商標)XAD−11」(オルガノ株式会社製)、二酸化ケイ素系、例えば「サイロピュート(登録商標)202」(富士シリシア化学株式会社製)、デキストラン系、例えば「セファデックス(登録商標)G−25」(アマシャム ファルマシア バイオテク社製)、ポリビニル系、例えば「ダイヤイオン(登録商標)FP−II」(三菱化学株式会社製)などを使用できる。
Further, by further purifying the extract obtained in step 3 prior to step 4 with an adsorbent, an extract having an excellent color tone and further reduced bitterness and astringency can be obtained.
Examples of the adsorbent include activated carbon and synthetic adsorbent, and any of them can be used without any particular limitation. As the synthetic adsorbent, the matrix is a styrene polymer such as “Amberlite (registered trademark) XAD-16” (manufactured by Organo Corporation), or a styrene-divinylbenzene polymer such as “Diaion (registered trademark) HP-20”. (Mitsubishi Chemical Corporation), an acrylic polymer such as “Diaion (registered trademark) WK-10” (Mitsubishi Chemical Corporation), a methacrylic polymer such as “Diaion (registered trademark) HP-2MG” ( Mitsubishi Chemical Co., Ltd.), acrylate polymers such as “Amberlite (registered trademark) XAD-7” (manufactured by Organo Corporation), amide polymers such as “Amberlite (registered trademark) XAD-11” (organo) Co., Ltd.), silicon dioxide-based, for example, “Silo Pute (registered trademark) 202” (Fuji Siri Manufactured by A Chemical Co., Ltd.), dextran-based, such as “Sephadex (registered trademark) G-25” (manufactured by Amersham Pharmacia Biotech), polyvinyl-based, such as “Diaion (registered trademark) FP-II” (Mitsubishi Chemical Corporation) Can be used.

本発明における吸着剤の処理方法は通常行われている方法で行えば良く、例えば、カラムに充填された吸着剤に抽出液を一定流量で送液する方法や、抽出釜に仕込んだ抽出液に吸着剤を投入し、一定時間撹拌後に吸着剤を分離する方法がある。その方法に格別の制約はなく、目的により選択することができる。   The adsorbent treatment method in the present invention may be carried out by a conventional method. For example, the adsorbent filled in the column is fed at a constant flow rate, or the extract charged in the extractor is used. There is a method of introducing an adsorbent and separating the adsorbent after stirring for a certain time. There is no particular restriction on the method, and it can be selected according to the purpose.

(5)工程4
工程2で得られた留出液と工程3で得られた抽出液を混合することにより、茶エキスを得る。この茶エキスは減圧水蒸気蒸留により原料茶葉から好ましくない香気成分が除去されているので、原料として好ましくない香りのある茶葉を用いた場合であっても、優れた風味を有する。
本発明で得られる茶エキスは通常、Brixが50以下となるように調製するが、好ましくはBrixが1〜10である。Brixが50を超える場合は、茶エキスの優れた風味を安定して保存することは難しくなる傾向にあり、また粘度が高くなることによる製造効率の低下も問題となる可能性がある。一方、Brixが1未満のものは全体の風味が弱くなる傾向にあり、また経済的観点からも不適当である。
混合方法は特に限定されないが、留出液に含まれる香気成分の揮散を防止するため、できる限り閉鎖系でかつ短時間で混合を完了することが望ましい。
(5) Step 4
A tea extract is obtained by mixing the distillate obtained in step 2 and the extract obtained in step 3. Since this tea extract has an undesired aroma component removed from the raw tea leaves by steam distillation under reduced pressure, it has an excellent flavor even when unscented tea leaves are used as raw materials.
The tea extract obtained in the present invention is usually prepared so that the Brix is 50 or less, but preferably the Brix is 1-10. When the Brix exceeds 50, it is difficult to stably store the excellent flavor of the tea extract, and there is a possibility that the production efficiency is lowered due to the increase in viscosity. On the other hand, when the Brix is less than 1, the overall flavor tends to be weak, and it is inappropriate from an economic viewpoint.
The mixing method is not particularly limited, but it is desirable to complete the mixing in a closed system and in a short time as much as possible in order to prevent volatilization of the aromatic component contained in the distillate.

本発明の茶エキスには、pH調整、酸化防止の目的でアスコルビン酸またはその塩を添加することができる。一般的には加熱処理前にアスコルビン酸またはその塩を茶エキスに添加するが、工程2の抽出に用いる水に予め添加しておいてもよい。添加量は特に制限はないが、一般に茶エキスに対して質量比で0.05〜1%が好ましい。   Ascorbic acid or a salt thereof can be added to the tea extract of the present invention for pH adjustment and antioxidant purposes. Generally, ascorbic acid or a salt thereof is added to the tea extract before the heat treatment, but it may be added in advance to the water used for the extraction in step 2. The addition amount is not particularly limited, but is generally preferably 0.05 to 1% by mass ratio with respect to the tea extract.

工程4で得られた本発明の茶エキスは、工程4に続いて加熱処理を行うことが好ましい。
加熱条件としては100℃以下で行う低温処理、100℃以上で行う高温処理のいずれでもよいが、茶エキスの殺菌という観点から、100℃以上の高温処理が好ましい。
The tea extract of the present invention obtained in step 4 is preferably subjected to heat treatment subsequent to step 4.
The heating conditions may be either a low temperature treatment performed at 100 ° C. or lower and a high temperature treatment performed at 100 ° C. or higher, but a high temperature treatment of 100 ° C. or higher is preferable from the viewpoint of sterilization of tea extract.

また、本発明の茶エキスは膜濾過により除菌することも可能である。膜濾過により除菌する場合は、限外濾過(フィルター孔径0.002〜0.1μm)、精密濾過(フィルター孔径0.05〜1μm)等が用いられるが、菌の除去という目的からフィルター孔径0.45μm以下の膜を用いるのが好ましい。   The tea extract of the present invention can be sterilized by membrane filtration. In the case of sterilization by membrane filtration, ultrafiltration (filter pore size 0.002-0.1 μm), microfiltration (filter pore size 0.05-1 μm), etc. are used, but the filter pore size is 0 for the purpose of removing bacteria. It is preferable to use a film of .45 μm or less.

(6)茶エキスの適用
本発明の茶エキスは、茶葉を常法により熱水、温水または冷水で抽出して得られる茶飲料、茶の香味成分を適宜調合して得られる茶香味を有する調合飲料、茶飲料に種々の健康素材を添加した各種混合茶飲料などの茶飲料に添加することができる。
さらに、不快臭の無い優れた香味を有する茶葉を使用したエキスと同等の風味を有することから、茶飲料以外の茶風味を有する飲食品、例えば、緑茶、紅茶等の風味を付与したスナック類、栄養食品、アイスクリーム、シャーベット等の冷菓類、ゼリー、プリン、羊かん等のデザート類、クッキー、ケーキ、チョコレート、チューイングガム、饅頭等の菓子類、菓子パン、食パン等のパン類、ラムネ菓子、タブレット、錠菓類などに添加することができる。具体的には、茶エキス入りキャンディー、抹茶アイスクリーム、抹茶プリン、抹茶入り乳飲料、緑茶ゼリーや抹茶チョコレートが例示される。
(6) Application of tea extract The tea extract of the present invention is a tea beverage obtained by extracting tea leaves with hot water, hot water or cold water by a conventional method, and a tea flavor obtained by appropriately blending tea flavor components. It can be added to tea beverages such as various mixed tea beverages obtained by adding various health ingredients to beverages and tea beverages.
Furthermore, since it has the same flavor as the extract using tea leaves having an excellent flavor without an unpleasant odor, foods and drinks having a tea flavor other than tea beverages, for example, snacks imparted with flavors such as green tea and tea, Nutrition food, ice cream, confectionery such as sherbet, dessert such as jelly, pudding, sheep cane, cookie, cake, chocolate, chewing gum, buns and other confectionery, confectionery bread, bread such as bread, ramune confectionery, tablets, tablets It can be added to confectionery. Specifically, candy containing tea extract, matcha ice cream, matcha pudding, milk drink containing matcha, green tea jelly, and matcha chocolate are exemplified.

本発明の茶エキスは、茶飲料に対して茶エキスを固形分換算で、通常は0.0001〜
5質量%添加して用いる。添加濃度が0.0001質量%未満であると、新鮮なグリーン感を感じなくなる場合があり、一方、添加濃度が5質量%を超えると、グリーン感がややくどく感じられる場合がある。本発明の効果を十分に発揮するには、添加量を茶エキス固形分換算で0.0005〜1質量%にすることが最も望ましい。さらに、本発明の茶エキスを使用する場合は、飲料用の香味料組成物として製剤化して用いると好適である。
The tea extract of the present invention is a tea extract in terms of solid content, usually from 0.0001 to
Add 5% by mass. When the added concentration is less than 0.0001% by mass, a fresh green feeling may not be felt. On the other hand, when the added concentration exceeds 5% by mass, the green feeling may be slightly felt. In order to sufficiently exhibit the effects of the present invention, it is most desirable that the addition amount be 0.0005 to 1% by mass in terms of tea extract solid content. Furthermore, when using the tea extract of this invention, it is suitable to formulate and use as a flavoring composition for drinks.

一般に香味料組成物は、対象となる食品に対して0.1質量%程度を添加するように調製されることが多く、そのように調製される場合は該香味料組成物に対して本発明の茶エキスは、通常は0.1〜100質量%、好ましくは1〜50質量%含有される。
茶エキスを添加して製造される本発明の茶飲料は、加熱殺菌後にも良質で豊かな香気を有することを特徴とする。ここで、本発明の茶飲料の製造における加熱殺菌条件は、5〜30程度のF値を満たす条件が好ましい。
In general, the flavor composition is often prepared so that about 0.1% by mass is added to the target food, and in such a case, the present invention is applied to the flavor composition. The tea extract is usually contained in an amount of 0.1 to 100% by mass, preferably 1 to 50% by mass.
The tea beverage of the present invention produced by adding a tea extract is characterized by having a good quality and rich aroma even after heat sterilization. Here, the heat sterilization conditions in the production of the tea beverage of the present invention preferably satisfy the F value of about 5 to 30.

以下に本発明の実施例を説明するが、本発明はこれら実施例に限られるものではない。   Examples of the present invention will be described below, but the present invention is not limited to these examples.

〔I〕水蒸気蒸留留出液の製造とその評価
<実験例1>
秋冬番茶のてん茶を水蒸気蒸留機に2kg仕込み、これに35℃の水を1kg均一に散布した後、10分間静置し湿潤させた。湿潤完了後にゲージ圧で−54kPaGに減圧した後、SV(空間速度)325h-1で水蒸気蒸留を行い、0.2kgの留出液を留出させ、これを除去した。次いで容器系内を常圧に戻し、常圧下で水蒸気蒸留を行い、2kgの留出液を留出させ、得られた留出液を水蒸気蒸留部1とした。
[I] Production of steam distillation distillate and its evaluation <Experimental example 1>
2 kg of autumn / winter bancha tea was charged in a steam distiller, and 1 kg of water at 35 ° C. was uniformly sprayed thereon, and then allowed to stand and wet for 10 minutes. After completion of the wetting, the pressure was reduced to −54 kPaG with a gauge pressure, and then steam distillation was performed at SV (space velocity) 325 h −1 to distill 0.2 kg of distillate, which was removed. Subsequently, the inside of the container system was returned to normal pressure, steam distillation was performed under normal pressure, 2 kg of distillate was distilled, and the obtained distillate was used as the steam distillation unit 1.

<実験例2>
秋冬番茶のてん茶を水蒸気蒸留機に2kg仕込み、これに35℃の水を1kg均一に散布した後、10分間静置し湿潤させた。湿潤完了後にゲージ圧で−54kPaGに減圧した後、SV(空間速度)585h-1で水蒸気蒸留を行い、0.2kgの留出液を留出させ、これを除去した。次いで容器系内を常圧に戻し、常圧下で水蒸気蒸留を行い、2kgの留出液を留出させ、得られた留出液を水蒸気蒸留部2とした。
<Experimental example 2>
2 kg of autumn / winter bancha tea was charged in a steam distiller, and 1 kg of water at 35 ° C. was uniformly sprayed thereon, and then allowed to stand and wet for 10 minutes. After completion of wetting, the pressure was reduced to −54 kPaG with a gauge pressure, and then steam distillation was performed at SV (space velocity) 585 h −1 to distill 0.2 kg of distillate, which was removed. Subsequently, the inside of the container system was returned to normal pressure, steam distillation was performed under normal pressure, 2 kg of distillate was distilled, and the resulting distillate was used as the steam distillation unit 2.

<実験例3>
秋冬番茶のてん茶を水蒸気蒸留機に2kg仕込み、これに35℃の水を1kg均一に散布した後、10分間静置し湿潤させた。湿潤完了後にゲージ圧で−54kPaGに減圧した後、SV(空間速度)325h-1で水蒸気蒸留を行い、0.08kgの留出液を留出させ、これを除去した。次いで容器系内を常圧に戻し、常圧下で水蒸気蒸留を行い、2kgの留出液を留出させ、得られた留出液を水蒸気蒸留部3とした。
<Experimental example 3>
2 kg of autumn / winter bancha tea was charged in a steam distiller, and 1 kg of water at 35 ° C. was uniformly sprayed thereon, and then allowed to stand and wet for 10 minutes. After completion of the wetting, the gauge pressure was reduced to -54 kPaG, and then steam distillation was performed at SV (space velocity) of 325 h -1 to distill 0.08 kg of distillate, which was removed. Subsequently, the inside of the container system was returned to normal pressure, steam distillation was performed under normal pressure, 2 kg of distillate was distilled, and the obtained distillate was used as the steam distillation unit 3.

<実験例4>
秋冬番茶のてん茶を水蒸気蒸留機に2kg仕込み、これに35℃の水を1kg均一に散布した後、10分間静置し湿潤させた。湿潤完了後にゲージ圧で−54kPaGに減圧した後、SV(空間速度)325h-1で水蒸気蒸留を行い、2.4kgの留出液を留出させ、これを除去した。次いで容器系内を常圧に戻し、常圧下で水蒸気蒸留を行い、2kgの留出液を留出させ、得られた留出液を水蒸気蒸留部4とした。
<Experimental example 4>
2 kg of autumn / winter bancha tea was charged in a steam distiller, and 1 kg of water at 35 ° C. was uniformly sprayed thereon, and then allowed to stand and wet for 10 minutes. After completion of wetting, the pressure was reduced to −54 kPaG with a gauge pressure, and then steam distillation was performed at SV (space velocity) 325 h −1 to distill 2.4 kg of distillate, which was removed. Subsequently, the inside of the container system was returned to normal pressure, steam distillation was performed under normal pressure, 2 kg of distillate was distilled, and the resulting distillate was used as the steam distillation unit 4.

<実験例5>
秋冬番茶のてん茶を水蒸気蒸留機に2kg仕込み、これに35℃の水を1kg均一に散布した後、10分間静置し湿潤させた。湿潤完了後にゲージ圧で−54kPaGに減圧した後、SV(空間速度)325h-1で水蒸気蒸留を行い、2kgの留出液を留出させ、得られた留出液を水蒸気蒸留部5とした。
<Experimental example 5>
2 kg of autumn / winter bancha tea was charged in a steam distiller, and 1 kg of water at 35 ° C. was uniformly sprayed thereon, and then allowed to stand and wet for 10 minutes. After the completion of wetting, the gauge pressure was reduced to -54 kPaG, and then steam distillation was performed at SV (space velocity) 325 h -1 to distill 2 kg of distillate. The resulting distillate was used as the steam distillation section 5. .

<実験例6>
秋冬番茶のてん茶を水蒸気蒸留機に2kg仕込み、これに35℃の水を1kg均一に散布した後、10分間静置し湿潤させた。湿潤完了後に常圧下にて水蒸気蒸留を行い、2kgの留出液を留出させ、得られた留出液を水蒸気蒸留部6とした。
<Experimental example 6>
2 kg of autumn / winter bancha tea was charged in a steam distiller, and 1 kg of water at 35 ° C. was uniformly sprayed thereon, and then allowed to stand and wet for 10 minutes. After completion of wetting, steam distillation was performed under normal pressure to distill 2 kg of distillate, and the resulting distillate was used as the steam distillation section 6.

<試験例1>
実験例1〜6で得られた水蒸気蒸留部について、官能評価を行った。評価サンプルは、蒸留水に水蒸気蒸留部を添加したものを調製した。添加量は、水蒸気蒸留部を1質量%とした。評価は熟練した官能評価パネル4名で行い、風味全体の強さ、甘いグリーン感、華やかなフローラル感、番茶臭を、1(非常に弱い)〜7(非常に強い)の7段階で評価した。評価点の平均を表1に、コメントを表2に示す。
<Test Example 1>
Sensory evaluation was performed about the steam distillation part obtained in Experimental Examples 1-6. The evaluation sample was prepared by adding a steam distillation part to distilled water. The amount added was 1% by mass in the steam distillation section. The evaluation was performed by four skilled sensory evaluation panels, and the overall strength of the flavor, sweet green feeling, gorgeous floral feeling, and bancha odor were evaluated in 7 levels from 1 (very weak) to 7 (very strong). . Table 1 shows the average score and Table 2 shows the comments.

Figure 2012000089
Figure 2012000089

Figure 2012000089
Figure 2012000089

表1、2に示されるように、減圧水蒸気蒸留または常圧水蒸気蒸留のみを行った場合(水蒸気蒸留部5、6)は番茶臭を除去できなかったのに対し、減圧水蒸気蒸留で留出液を除去した後、常圧水蒸気蒸留を行った場合(水蒸気蒸留部1〜4)は番茶臭が減少した。
水蒸気蒸留部1が最も評価が高かったことから、以下の実施例では実験例1の条件を用いて茶エキスを作製した。
As shown in Tables 1 and 2, when only vacuum steam distillation or atmospheric steam distillation was performed (steam distillation sections 5 and 6), the bancha odor could not be removed, whereas distillate was distilled by vacuum steam distillation. In the case where atmospheric steam distillation was performed after removing (steam distillation section 1 to 4), the bancha odor decreased.
Since the steam distillation part 1 had the highest evaluation, the tea extract was produced using the conditions of Experimental Example 1 in the following examples.

〔II〕茶エキスの製造とその評価
<実施例1>
秋冬番茶のてん茶を水蒸気蒸留機に2kg仕込み、これに35℃の水を1kg均一に散布した後、10分間静置し湿潤させた。湿潤完了後にゲージ圧で−54kPaGに減圧した後、SV(空間速度)325h-1で水蒸気蒸留を行い、0.2kgの留出液を留出させ、これを除去した。次いで容器系内を常圧に戻し、常圧下で水蒸気蒸留を行い、2kgの留出液を留出させた。水蒸気蒸留後遅滞無く、茶葉を80℃の水で抽出し、原料茶葉に対し、10kg(Brix4.6)の抽出液を得た。この抽出液をタンナーゼおよびペクチナーゼを用いた酵素処理と濾過により清澄化させ、減圧下で濃縮を行い、濃縮液(Brix43)を0.47kg得た。濃縮液にアスコルビン酸を5g配合し溶解させ、次いで留出液を2kg配合し攪拌均一化させ、緑茶エキス(Brix8.4)を得た。
[II] Production of tea extract and its evaluation <Example 1>
2 kg of autumn / winter bancha tea was charged in a steam distiller, and 1 kg of water at 35 ° C. was uniformly sprayed thereon, and then allowed to stand and wet for 10 minutes. After completion of the wetting, the pressure was reduced to −54 kPaG with a gauge pressure, and then steam distillation was performed at SV (space velocity) 325 h −1 to distill 0.2 kg of distillate, which was removed. Subsequently, the inside of the container system was returned to normal pressure, and steam distillation was performed under normal pressure to distill 2 kg of distillate. The tea leaves were extracted with water at 80 ° C. without delay after steam distillation, and 10 kg (Brix 4.6) of an extract was obtained with respect to the raw tea leaves. This extract was clarified by enzyme treatment using tannase and pectinase and filtration, and concentrated under reduced pressure to obtain 0.47 kg of a concentrate (Brix43). 5 g of ascorbic acid was mixed and dissolved in the concentrate, and then 2 kg of the distillate was mixed and stirred and homogenized to obtain a green tea extract (Brix 8.4).

<実施例2>
秋冬番茶のてん茶を水蒸気蒸留機に2kg仕込み、これに35℃の水を1kg均一に散布した後、10分間静置し湿潤させた。湿潤完了後にゲージ圧で−54kPaGに減圧した後、SV(空間速度)325h-1で水蒸気蒸留を行い、0.2kgの留出液を留出させ、これを除去した。次いで容器系内を常圧に戻し、常圧下で水蒸気蒸留を行い、2kgの留出液を留出させた。水蒸気蒸留後遅滞無く、茶葉を80℃の水で抽出し、原料茶葉に対し、10kg(Brix4.6)の抽出液を得た。この抽出液を濾過により清澄化させ、減圧下で濃縮を行い、濃縮液(Brix43)を0.47kg得た。濃縮液にアスコルビン酸を5g配合し溶解させ、次いで留出液を2kg配合し攪拌均一化させ、緑茶エキス(Brix8.4)を得た。
<Example 2>
2 kg of autumn / winter bancha tea was charged in a steam distiller, and 1 kg of water at 35 ° C. was uniformly sprayed thereon, and then allowed to stand and wet for 10 minutes. After completion of the wetting, the pressure was reduced to −54 kPaG with a gauge pressure, and then steam distillation was performed at SV (space velocity) 325 h −1 to distill 0.2 kg of distillate, which was removed. Subsequently, the inside of the container system was returned to normal pressure, and steam distillation was performed under normal pressure to distill 2 kg of distillate. The tea leaves were extracted with water at 80 ° C. without delay after steam distillation, and 10 kg (Brix 4.6) of an extract was obtained with respect to the raw tea leaves. The extract was clarified by filtration and concentrated under reduced pressure to obtain 0.47 kg of a concentrate (Brix43). 5 g of ascorbic acid was mixed and dissolved in the concentrate, and then 2 kg of the distillate was mixed and stirred and homogenized to obtain a green tea extract (Brix 8.4).

<実施例3>
秋冬番茶のてん茶を水蒸気蒸留機に2kg仕込み、これに35℃の水を1kg均一に散布した後、10分間静置し湿潤させた。湿潤完了後にゲージ圧で−54kPaGに減圧した後、SV(空間速度)325h-1で水蒸気蒸留を行い、0.2kgの留出液を留出させ、これを除去した。次いで容器系内を常圧に戻し、常圧下で水蒸気蒸留を行い、2kgの留出液を留出させた。水蒸気蒸留後遅滞無く、茶葉を80℃の水で抽出し、原料茶葉に対し、10kg(Brix4.6)の抽出液を得た。この抽出液に活性炭(「太閤S」フタムラ化学(株))を0.46kg投入し、液温5℃で1時間攪拌処理を行った後、遠心分離と濾過により清澄化させ、減圧下で濃縮を行い、濃縮液(Brix43)を0.47kg得た。濃縮液にアスコルビン酸を5g配合し溶解させ、次いで留出液を2kg配合し攪拌均一化させ、緑茶エキス(Brix8.4)を得た。
<Example 3>
2 kg of autumn / winter bancha tea was charged in a steam distiller, and 1 kg of water at 35 ° C. was uniformly sprayed thereon, and then allowed to stand and wet for 10 minutes. After completion of the wetting, the pressure was reduced to −54 kPaG with a gauge pressure, and then steam distillation was performed at SV (space velocity) 325 h −1 to distill 0.2 kg of distillate, which was removed. Subsequently, the inside of the container system was returned to normal pressure, and steam distillation was performed under normal pressure to distill 2 kg of distillate. The tea leaves were extracted with water at 80 ° C. without delay after steam distillation, and 10 kg (Brix 4.6) of an extract was obtained with respect to the raw tea leaves. 0.46 kg of activated carbon (“Taiko S” Phthamura Chemical Co., Ltd.) is added to this extract, and after stirring for 1 hour at a liquid temperature of 5 ° C., it is clarified by centrifugation and filtration, and concentrated under reduced pressure. And 0.47 kg of concentrated liquid (Brix43) was obtained. 5 g of ascorbic acid was mixed and dissolved in the concentrate, and then 2 kg of the distillate was mixed and stirred and homogenized to obtain a green tea extract (Brix 8.4).

<実施例4>
秋冬番茶のてん茶を水蒸気蒸留機に2kg仕込み、これに35℃の水を1kg均一に散布した後、10分間静置し湿潤させた。湿潤完了後にゲージ圧で−54kPaGに減圧した後、SV(空間速度)325h-1で水蒸気蒸留を行い、0.2kgの留出液を留出させ、これを除去した。次いで容器系内を常圧に戻し、常圧下で水蒸気蒸留を行い、2kgの留出液を留出させた。水蒸気蒸留後遅滞無く、茶葉を80℃の水で抽出し、原料茶葉に対し、10kg(Brix4.6)の抽出液を得た。この抽出液を濾過により清澄化させ、減圧下で濃縮を行い、濃縮液(Brix43)を0.47kg得た。濃縮液に留出液を2kg配合し攪拌均一化させ、緑茶エキス(Brix8.4)を得た。
<Example 4>
2 kg of autumn / winter bancha tea was charged in a steam distiller, and 1 kg of water at 35 ° C. was uniformly sprayed thereon, and then allowed to stand and wet for 10 minutes. After completion of the wetting, the pressure was reduced to −54 kPaG with a gauge pressure, and then steam distillation was performed at SV (space velocity) 325 h −1 to distill 0.2 kg of distillate, which was removed. Subsequently, the inside of the container system was returned to normal pressure, and steam distillation was performed under normal pressure to distill 2 kg of distillate. The tea leaves were extracted with water at 80 ° C. without delay after steam distillation, and 10 kg (Brix 4.6) of an extract was obtained with respect to the raw tea leaves. The extract was clarified by filtration and concentrated under reduced pressure to obtain 0.47 kg of a concentrate (Brix43). 2 kg of the distillate was blended into the concentrated liquid and homogenized with stirring to obtain a green tea extract (Brix 8.4).

<比較例1>
60℃に調温した水3kgに秋冬番茶のてん茶0.1kgを加え、5分間攪拌浸漬抽出した。抽出後100メッシュで茶葉を分離し冷却を行い、2.5kg(Brix0.38)の抽出液を得た。この抽出液を濾過により清澄化させ、減圧下で濃縮を行い、濃縮液にアスコルビン酸を0.2g加えて溶解させ、緑茶エキス(Brix8.4)を得た。
<Comparative Example 1>
0.1 kg of fall / winter bancha tea was added to 3 kg of water adjusted to 60 ° C., followed by extraction by stirring and immersion for 5 minutes. After extraction, tea leaves were separated with 100 mesh and cooled to obtain 2.5 kg (Brix 0.38) of an extract. The extract was clarified by filtration, concentrated under reduced pressure, and 0.2 g of ascorbic acid was added to the concentrate and dissolved to obtain a green tea extract (Brix 8.4).

<比較例2>
秋冬番茶のてん茶を水蒸気蒸留機に2kg仕込み、これに35℃の水を1kg均一に散布した後、10分間静置し湿潤させた。湿潤完了後、常圧下で水蒸気蒸留を行い、2kgの留出液を留出させた。水蒸気蒸留後遅滞無く、茶葉を80℃の水で抽出し、原料茶葉に対し、10kg(Brix4.6)の抽出液を得た。この抽出液をタンナーゼおよびペクチナーゼを用いた酵素処理と濾過により清澄化させ、減圧下で濃縮を行い、濃縮液(Brix43)を0.47kg得た。濃縮液にアスコルビン酸を5g配合し溶解させ、次いで留出液を2kg配合し攪拌均一化させ、緑茶エキス(Brix8.4)を得た。
<Comparative example 2>
2 kg of autumn / winter bancha tea was charged in a steam distiller, and 1 kg of water at 35 ° C. was uniformly sprayed thereon, and then allowed to stand and wet for 10 minutes. After completion of wetting, steam distillation was performed under normal pressure to distill 2 kg of distillate. The tea leaves were extracted with water at 80 ° C. without delay after steam distillation, and 10 kg (Brix 4.6) of an extract was obtained with respect to the raw tea leaves. This extract was clarified by enzyme treatment using tannase and pectinase and filtration, and concentrated under reduced pressure to obtain 0.47 kg of a concentrate (Brix43). 5 g of ascorbic acid was mixed and dissolved in the concentrate, and then 2 kg of the distillate was mixed and stirred and homogenized to obtain a green tea extract (Brix 8.4).

<比較例3>
秋冬番茶のてん茶を水蒸気蒸留機に2kg仕込み、これに35℃の水を1kg均一に散布した後、10分間静置し湿潤させた。湿潤完了後にゲージ圧で−54kPaGに減圧した後、SV(空間速度)325h-1で水蒸気蒸留を行い、2kgの留出液を留出させた。水蒸気蒸留後遅滞無く、茶葉を80℃の水で抽出し、原料茶葉に対し、10kg(Brix4.6)の抽出液を得た。この抽出液をタンナーゼおよびペクチナーゼを用いた酵素処理と濾過により清澄化させ、減圧下で濃縮を行い、濃縮液(Brix43)を0.47kg得た。濃縮液にアスコルビン酸を5g配合し溶解させ、次いで留出液を2kg配合し攪拌均一化させ、緑茶エキス(Brix8.4)を得た。
<Comparative Example 3>
2 kg of autumn / winter bancha tea was charged in a steam distiller, and 1 kg of water at 35 ° C. was uniformly sprayed thereon, and then allowed to stand and wet for 10 minutes. After completion of the wetting, the pressure was reduced to −54 kPaG with a gauge pressure, and then steam distillation was performed at SV (space velocity) 325 h −1 to distill 2 kg of distillate. The tea leaves were extracted with water at 80 ° C. without delay after steam distillation, and 10 kg (Brix 4.6) of an extract was obtained with respect to the raw tea leaves. This extract was clarified by enzyme treatment using tannase and pectinase and filtration, and concentrated under reduced pressure to obtain 0.47 kg of a concentrate (Brix43). 5 g of ascorbic acid was mixed and dissolved in the concentrate, and then 2 kg of the distillate was mixed and stirred and homogenized to obtain a green tea extract (Brix 8.4).

<試験例2>
実施例1〜4と比較例1〜3で得られた緑茶エキスについて官能評価を行った。評価サンプルは、市販緑茶飲料に緑茶エキスを添加したものを調製した。添加量は0.5質量%とした。評価は熟練した官能評価パネル6名で行い、風味全体の強さ、甘いグリーン感、華やかなフローラル感、番茶臭、焦げた香り、苦渋味について、緑茶エキス無添加の市販緑茶飲料をコントロール(4点)として、1(非常に弱い)〜7(非常に強い)の7段階で評価した。評価点の平均を表3に、コメントを表4に示す。
<Test Example 2>
Sensory evaluation was performed about the green tea extract obtained in Examples 1-4 and Comparative Examples 1-3. The evaluation sample prepared what added the green tea extract to the commercially available green tea drink. The amount added was 0.5% by mass. The evaluation was performed by six skilled sensory evaluation panels, and the control of commercial green tea beverages with no added green tea extract was performed for the overall flavor strength, sweet green feeling, gorgeous floral feeling, bancha odor, burnt aroma, bitterness and taste (4 As a point), it was evaluated in 7 stages from 1 (very weak) to 7 (very strong). Table 3 shows the average score and Table 4 shows the comments.

Figure 2012000089
Figure 2012000089

Figure 2012000089
Figure 2012000089

表3、4の結果より、実施例1〜4で作製した緑茶エキスは、比較例に比べ、番茶臭と呼ばれる秋冬番茶に含まれる好ましくない風味が減少する一方、新茶を想起させるような甘いグリーン感と華やかなフローラル香が強く、全体の風味の力価も強かった。特に実施例1の緑茶エキスでこの効果が顕著に認められた。実施例2の緑茶エキスは、やや苦渋味が感じられる他は、実施例1とほぼ同様の効果が認められた。実施例3の緑茶エキスは実施例1と同等の効果を有し、実施例4の緑茶エキスでもやや蒸れた香りが感じられる他は、実施例1とほぼ同様の効果が得られた。   From the results of Tables 3 and 4, the green tea extracts prepared in Examples 1 to 4 have a sweet green color reminiscent of new tea, while reducing the unfavorable flavor contained in autumn / winter bancha called bancha odor compared to the comparative example The feeling and gorgeous floral scent were strong, and the potency of the overall flavor was also strong. In particular, this effect was remarkably observed in the green tea extract of Example 1. The green tea extract of Example 2 showed almost the same effect as Example 1 except that it had a slightly bitter taste. The green tea extract of Example 3 had the same effect as that of Example 1, and the same effect as Example 1 was obtained except that the green tea extract of Example 4 felt a slightly steamed scent.

<実施例5>
プーアール茶を水蒸気蒸留機に2kg仕込み、これに35℃の水を1kg均一に散布した後、10分間静置し湿潤させた。湿潤完了後にゲージ圧で−54kPaGに減圧した後、SV(空間速度)325h-1で水蒸気蒸留を行い、原0.2kgの留出液を留出させ、これを除去した。次いで容器系内を常圧に戻し、常圧下で水蒸気蒸留を行い、2kgの留出液を留出させた。水蒸気蒸留後遅滞無く、茶葉を80℃の水で抽出し、原料茶葉に対し、10kg(Brix7)の抽出液を得た。この抽出液をタンナーゼおよびペクチナーゼを用いた酵素処理と濾過により清澄化させ、減圧下で濃縮を行い、濃縮液(Brix40)を0.5kg得た。濃縮液にアスコルビン酸を5g配合し溶解させ、次いで留出液を2kg配合し攪拌均一化させ、プーアール茶エキス(Brix8.4)を得た。
<Example 5>
2 kg of Pu-erh tea was charged into a steam distiller, and 1 kg of 35 ° C. water was uniformly sprayed thereon, and then allowed to stand for 10 minutes to be wet. After completion of wetting, the pressure was reduced to -54 kPaG with a gauge pressure, and then steam distillation was performed at SV (space velocity) 325 h -1 to distill off 0.2 kg of the distillate, which was removed. Subsequently, the inside of the container system was returned to normal pressure, and steam distillation was performed under normal pressure to distill 2 kg of distillate. The tea leaves were extracted with water at 80 ° C. without delay after the steam distillation, and 10 kg (Brix7) of an extract was obtained from the raw tea leaves. This extract was clarified by enzyme treatment using tannase and pectinase and filtration, and concentrated under reduced pressure to obtain 0.5 kg of a concentrate (Brix40). 5 g of ascorbic acid was mixed and dissolved in the concentrated liquid, and then 2 kg of the distillate was mixed and stirred and homogenized to obtain a Pu-erh tea extract (Brix 8.4).

<比較例4>
プーアール茶を水蒸気蒸留機に2kg仕込み、これに35℃の水を1kg均一に散布した後、10分間静置し湿潤させた。湿潤完了後、常圧下で水蒸気蒸留を行い、2kgの留出液を留出させた。水蒸気蒸留後遅滞無く、茶葉を80℃の水で抽出し、原料茶葉に対し、10kg(Brix7)の抽出液を得た。この抽出液をタンナーゼおよびペクチナーゼを用いた酵素処理と濾過により清澄化させ、減圧下で濃縮を行い、濃縮液(Brix40)を0.5kg得た。濃縮液にアスコルビン酸を5g配合し溶解させ、次いで留出液を2
kg配合し攪拌均一化させ、プーアール茶エキス(Brix8.4)を得た。
<Comparative example 4>
2 kg of Pu-erh tea was charged into a steam distiller, and 1 kg of 35 ° C. water was uniformly sprayed thereon, and then allowed to stand for 10 minutes to be wet. After completion of wetting, steam distillation was performed under normal pressure to distill 2 kg of distillate. The tea leaves were extracted with water at 80 ° C. without delay after the steam distillation, and 10 kg (Brix7) of an extract was obtained from the raw tea leaves. This extract was clarified by enzyme treatment using tannase and pectinase and filtration, and concentrated under reduced pressure to obtain 0.5 kg of a concentrate (Brix40). Add 5g of ascorbic acid to the concentrate and dissolve it.
The mixture was stirred and homogenized to obtain a pu-erh tea extract (Brix 8.4).

<試験例3>
実施例5と比較例4で得られたプーアール茶エキスについて官能評価を行った。評価サンプルは、市販混合茶飲料にプーアール茶エキスを添加したものを調製した。添加量は0.2質量%とした。評価は熟練した官能評価パネル6名で行い、風味全体の強さ、熟成したコクのある香り、甘み、焦げた香り、土臭さについて、エキス無添加の市販混合茶飲料をコントロール(4点)として、1(非常に弱い)〜7(非常に強い)の7段階で評価した。評価点の平均を表5に、コメントを表6に示す。
<Test Example 3>
Sensory evaluation was performed on the pu-erh tea extract obtained in Example 5 and Comparative Example 4. The evaluation sample prepared what added the puer tea extract to the commercially available mixed tea drink. The amount added was 0.2% by mass. The evaluation was conducted by six skilled sensory evaluation panels, and a commercial mixed tea beverage with no extract was used as a control (4 points) for the strength of the overall flavor, mature aroma, sweetness, burnt aroma and earthy odor. The evaluation was made on a scale of 1 (very weak) to 7 (very strong). The average evaluation points are shown in Table 5, and the comments are shown in Table 6.

Figure 2012000089
Figure 2012000089

Figure 2012000089
Figure 2012000089

表5、6の結果より、実施例5で作製したプーアール茶エキスは、比較例4に比べ、焦げた香りと土臭い不快臭が顕著に減少する一方、プーアール茶特有の熟成した香りが強くなり、飲んだときに感じるまろやかな甘さも強かった。   From the results of Tables 5 and 6, the Pu-erh tea extract produced in Example 5 has a markedly reduced aroma and earthy unpleasant odor compared to Comparative Example 4, while an aged scent peculiar to Pu-erh tea becomes stronger. The mellow sweetness felt when drinking was also strong.

<実施例6>
紅茶を水蒸気蒸留機に2kg仕込み、これに35℃の水を1kg均一に散布した後、10分間静置し湿潤させた。湿潤完了後にゲージ圧で−54kPaGに減圧した後、SV(空間速度)325h-1で水蒸気蒸留を行い、原0.2kgの留出液を留出させ、これを除去した。次いで容器系内を常圧に戻し、常圧下で水蒸気蒸留を行い、2kgの留出液を留出させた。水蒸気蒸留後遅滞無く、茶葉を80℃の水で抽出し、原料茶葉に対し、11kg(Brix6)の抽出液を得た。この抽出液をタンナーゼおよびペクチナーゼを用いた酵素処理と濾過により清澄化させ、減圧下で濃縮を行い、濃縮液(Brix40)を0.5kg得た。濃縮液にアスコルビン酸を5g配合し溶解させ、次いで留出液を2kg配合し攪拌均一化させ、紅茶エキス(Brix8.4)を得た。
<Example 6>
2 kg of black tea was charged into a steam distiller, and 1 kg of 35 ° C. water was uniformly sprayed thereon, and then allowed to stand for 10 minutes to be moistened. After completion of wetting, the pressure was reduced to -54 kPaG with a gauge pressure, and then steam distillation was performed at SV (space velocity) 325 h -1 to distill off 0.2 kg of the distillate, which was removed. Subsequently, the inside of the container system was returned to normal pressure, and steam distillation was performed under normal pressure to distill 2 kg of distillate. The tea leaves were extracted with water at 80 ° C. without delay after the steam distillation, and 11 kg (Brix 6) of an extract was obtained with respect to the raw tea leaves. This extract was clarified by enzyme treatment using tannase and pectinase and filtration, and concentrated under reduced pressure to obtain 0.5 kg of a concentrate (Brix40). 5 g of ascorbic acid was blended and dissolved in the concentrate, and then 2 kg of the distillate was blended and stirred and homogenized to obtain a black tea extract (Brix 8.4).

<比較例5>
紅茶を水蒸気蒸留機に2kg仕込み、これに35℃の水を1kg均一に散布した後、10分間静置し湿潤させた。湿潤完了後、常圧下で水蒸気蒸留を行い、2kgの留出液を留出させた。水蒸気蒸留後遅滞無く、茶葉を80℃の水で抽出し、原料茶葉に対し、11kg(Brix6)の抽出液を得た。この抽出液をタンナーゼおよびペクチナーゼを用いた酵素処理と濾過により清澄化させ、減圧下で濃縮を行い、濃縮液(Brix40)を0.5kg得た。濃縮液にアスコルビン酸を5g配合し溶解させ、次いで留出液を2kg配合し攪拌均一化させ、紅茶エキス(Brix8.4)を得た。
<Comparative Example 5>
2 kg of black tea was charged into a steam distiller, and 1 kg of 35 ° C. water was uniformly sprayed thereon, and then allowed to stand for 10 minutes to be moistened. After completion of wetting, steam distillation was performed under normal pressure to distill 2 kg of distillate. The tea leaves were extracted with water at 80 ° C. without delay after the steam distillation, and 11 kg (Brix 6) of an extract was obtained with respect to the raw tea leaves. This extract was clarified by enzyme treatment using tannase and pectinase and filtration, and concentrated under reduced pressure to obtain 0.5 kg of a concentrate (Brix40). 5 g of ascorbic acid was blended and dissolved in the concentrate, and then 2 kg of the distillate was blended and stirred and homogenized to obtain a black tea extract (Brix 8.4).

<試験例4>
実施例6と比較例5で得られた紅茶エキスについて官能評価を行った。評価サンプルは、市販紅茶飲料に紅茶エキスを添加したものを調製した。添加量は0.2質量%とした。
評価は熟練した官能評価パネル6名で行い、風味全体の強さ、甘い香り、華やかなフローラル香、焦げた香りについて、エキス無添加の市販混合茶飲料をコントロール(4点)として、1(非常に弱い)〜7(非常に強い)の7段階で評価した。評価点の平均を表7に、コメントを表8に示す。
<Test Example 4>
Sensory evaluation was performed about the black tea extract obtained in Example 6 and Comparative Example 5. The evaluation sample prepared what added the black tea extract to the commercially available tea drink. The amount added was 0.2% by mass.
The evaluation was conducted by 6 skilled sensory evaluation panels. The strength of the whole flavor, sweet fragrance, gorgeous floral fragrance, and burnt fragrance were controlled by using a commercially available mixed tea beverage with no extract as a control (4 points). To 7 (very strong). Table 7 shows the average score and Table 8 shows the comments.

Figure 2012000089
Figure 2012000089

Figure 2012000089
Figure 2012000089

表7、8の結果より、実施例6で作製した紅茶エキスは、比較例5に比べ、焦げた香りが減少する一方、淹れたての紅茶に感じられる甘い香りと華やかなフローラル香が強くなった。   From the results of Tables 7 and 8, the black tea extract produced in Example 6 has a strong sweet aroma and a gorgeous floral aroma that is felt in freshly brewed tea, while the burnt aroma is reduced compared to Comparative Example 5. became.

本発明の茶エキスは原料茶葉に含まれる好ましくない香気が少なく、新茶を想起させる優れた香味を有することから、容器詰茶飲料に優れた風味付与することができる。また、その豊かな香気から、茶風味を付与する素材として茶飲料以外の飲食品にも幅広く使用することが可能である。   Since the tea extract of the present invention has a less unfavorable aroma contained in the raw tea leaves and has an excellent flavor reminiscent of a new tea, an excellent flavor can be imparted to a packaged tea beverage. In addition, because of its rich aroma, it can be widely used in foods and drinks other than tea drinks as a material imparting tea flavor.

Claims (5)

下記の工程1〜4を含む方法によって製造される茶エキス。
(工程1)原料茶葉を減圧水蒸気蒸留により分画して留出液と茶葉を分離する工程
(工程2)工程1で分離された茶葉を常圧水蒸気蒸留により分画して留出液と茶葉残渣を分離する工程
(工程3)工程2で分離された茶葉残渣を水抽出して抽出液を得る工程
(工程4)工程2で分離された留出液と工程3で分離された抽出液を混合して茶エキスを製造する工程
A tea extract produced by a method comprising the following steps 1 to 4.
(Step 1) Step of separating raw tea leaves by vacuum steam distillation to separate the distillate and tea leaves (Step 2) Fractionation of tea leaves separated in step 1 by atmospheric steam distillation to distillate and tea leaves Step of separating the residue (Step 3) Step of obtaining the extract by water extraction of the tea leaf residue separated in Step 2 (Step 4) The distillate separated in Step 2 and the extract separated in Step 3 Process of mixing and producing tea extract
工程1における減圧水蒸気蒸留の条件が、減圧度がゲージ圧で−90〜−30kPaG、空間速度(SV)が50〜450h-1の水蒸気蒸留であり、その留出量が原料茶葉に対して5〜100%(質量比)であることを特徴とする請求項1記載の茶エキス。 The conditions of the reduced-pressure steam distillation in step 1 are steam distillation with a degree of vacuum of -90 to -30 kPaG in gauge pressure and a space velocity (SV) of 50 to 450 h -1 , and the amount of distillation is 5 with respect to the raw tea leaves. The tea extract according to claim 1, which is ˜100% (mass ratio). 工程2の水抽出物を酵素処理および/または吸着剤処理によって精製することを特徴とする請求項1または2記載の茶エキス。   The tea extract according to claim 1 or 2, wherein the water extract of step 2 is purified by enzyme treatment and / or adsorbent treatment. アスコルビン酸またはその塩を添加することを特徴とする請求項1〜3のいずれか1項に記載の茶エキス。   Ascorbic acid or its salt is added, The tea extract of any one of Claims 1-3 characterized by the above-mentioned. 請求項1〜4のいずれか1項に記載の茶エキスを添加したことを特徴とする飲食品。   The food / beverage product which added the tea extract of any one of Claims 1-4.
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JP2015130841A (en) * 2014-01-15 2015-07-23 小川香料株式会社 Manufacturing method of tea extract
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CN113973955A (en) * 2021-10-18 2022-01-28 上海康识食品科技有限公司 Tea concentrated solution and preparation method thereof

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CN112913949A (en) * 2021-03-15 2021-06-08 小淑记生物科技有限公司 Fresh flower instant tea and preparation method thereof
CN113973955A (en) * 2021-10-18 2022-01-28 上海康识食品科技有限公司 Tea concentrated solution and preparation method thereof

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