JP2011529115A5 - - Google Patents
Download PDFInfo
- Publication number
- JP2011529115A5 JP2011529115A5 JP2011520054A JP2011520054A JP2011529115A5 JP 2011529115 A5 JP2011529115 A5 JP 2011529115A5 JP 2011520054 A JP2011520054 A JP 2011520054A JP 2011520054 A JP2011520054 A JP 2011520054A JP 2011529115 A5 JP2011529115 A5 JP 2011529115A5
- Authority
- JP
- Japan
- Prior art keywords
- composition
- oxide
- sulfide
- group
- poly
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000203 mixture Substances 0.000 claims description 45
- 229920000642 polymer Polymers 0.000 claims description 16
- 239000002105 nanoparticle Substances 0.000 claims description 13
- 239000002253 acid Substances 0.000 claims description 12
- 229920001577 copolymer Polymers 0.000 claims description 12
- 229920001940 conductive polymer Polymers 0.000 claims description 9
- JKQOBWVOAYFWKG-UHFFFAOYSA-N molybdenum trioxide Chemical compound O=[Mo](=O)=O JKQOBWVOAYFWKG-UHFFFAOYSA-N 0.000 claims description 8
- 150000004763 sulfides Chemical class 0.000 claims description 8
- 229920000767 polyaniline Polymers 0.000 claims description 6
- 229920000128 polypyrrole Polymers 0.000 claims description 6
- BFKJFAAPBSQJPD-UHFFFAOYSA-N Tetrafluoroethylene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 claims description 4
- XOLBLPGZBRYERU-UHFFFAOYSA-N Tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 claims description 4
- QPLDLSVMHZLSFG-UHFFFAOYSA-N copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 claims description 4
- 229910044991 metal oxide Inorganic materials 0.000 claims description 4
- 150000004706 metal oxides Chemical class 0.000 claims description 4
- 229920000123 polythiophene Polymers 0.000 claims description 4
- 150000003460 sulfonic acids Chemical class 0.000 claims description 4
- XLOMVQKBTHCTTD-UHFFFAOYSA-N zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 4
- GWTYBAOENKSFAY-UHFFFAOYSA-N 1,1,1,2,2-pentafluoro-2-(1,2,2-trifluoroethenoxy)ethane Chemical compound FC(F)=C(F)OC(F)(F)C(F)(F)F GWTYBAOENKSFAY-UHFFFAOYSA-N 0.000 claims description 2
- AUUAIQGEFIEHRO-UHFFFAOYSA-N 1,1,2,2-tetrafluoro-2-[1,1,1,2,3,3-hexafluoro-3-(1,2,2-trifluoroethenoxy)propan-2-yl]oxyethanesulfonic acid Chemical compound OS(=O)(=O)C(F)(F)C(F)(F)OC(F)(C(F)(F)F)C(F)(F)OC(F)=C(F)F AUUAIQGEFIEHRO-UHFFFAOYSA-N 0.000 claims description 2
- BQCIDUSAKPWEOX-UHFFFAOYSA-N 1,1-difluoroethene Chemical group FC(F)=C BQCIDUSAKPWEOX-UHFFFAOYSA-N 0.000 claims description 2
- -1 2- (2- (1,2,2-trifluorovinyloxy) -1,1,2,3,3,3-hexafluoropropoxy) -1,1,2,2-tetrafluoroethane Chemical compound 0.000 claims description 2
- FRLJSGOEGLARCA-UHFFFAOYSA-N Cadmium sulfide Chemical compound [S-2].[Cd+2] FRLJSGOEGLARCA-UHFFFAOYSA-N 0.000 claims description 2
- KOPBYBDAPCDYFK-UHFFFAOYSA-N Caesium oxide Chemical compound [O-2].[Cs+].[Cs+] KOPBYBDAPCDYFK-UHFFFAOYSA-N 0.000 claims description 2
- JHRWWRDRBPCWTF-OLQVQODUSA-N Captafol Chemical compound C1C=CC[C@H]2C(=O)N(SC(Cl)(Cl)C(Cl)Cl)C(=O)[C@H]21 JHRWWRDRBPCWTF-OLQVQODUSA-N 0.000 claims description 2
- BWFPGXWASODCHM-UHFFFAOYSA-N Copper monosulfide Chemical compound [Cu]=S BWFPGXWASODCHM-UHFFFAOYSA-N 0.000 claims description 2
- 229910020708 Co—Pd Inorganic materials 0.000 claims description 2
- 229960004643 Cupric oxide Drugs 0.000 claims description 2
- 239000005977 Ethylene Substances 0.000 claims description 2
- XCAUINMIESBTBL-UHFFFAOYSA-N Lead(II) sulfide Chemical compound [Pb]=S XCAUINMIESBTBL-UHFFFAOYSA-N 0.000 claims description 2
- CWQXQMHSOZUFJS-UHFFFAOYSA-N Molybdenum disulfide Chemical compound S=[Mo]=S CWQXQMHSOZUFJS-UHFFFAOYSA-N 0.000 claims description 2
- 229920001609 Poly(3,4-ethylenedioxythiophene) Polymers 0.000 claims description 2
- FKTOIHSPIPYAPE-UHFFFAOYSA-N Samarium(III) oxide Chemical compound [O-2].[O-2].[O-2].[Sm+3].[Sm+3] FKTOIHSPIPYAPE-UHFFFAOYSA-N 0.000 claims description 2
- XUARKZBEFFVFRG-UHFFFAOYSA-N Silver sulfide Chemical compound [S-2].[Ag+].[Ag+] XUARKZBEFFVFRG-UHFFFAOYSA-N 0.000 claims description 2
- GNTDGMZSJNCJKK-UHFFFAOYSA-N Vanadium(V) oxide Chemical compound O=[V](=O)O[V](=O)=O GNTDGMZSJNCJKK-UHFFFAOYSA-N 0.000 claims description 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N ZrO2 Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims description 2
- 229910052946 acanthite Inorganic materials 0.000 claims description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N al2o3 Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 2
- 125000005336 allyloxy group Chemical group 0.000 claims description 2
- 229910000410 antimony oxide Inorganic materials 0.000 claims description 2
- 229910052980 cadmium sulfide Inorganic materials 0.000 claims description 2
- 229910001942 caesium oxide Inorganic materials 0.000 claims description 2
- 230000002950 deficient Effects 0.000 claims description 2
- 239000006185 dispersion Substances 0.000 claims description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 2
- AMGQUBHHOARCQH-UHFFFAOYSA-N indium;oxotin Chemical compound [In].[Sn]=O AMGQUBHHOARCQH-UHFFFAOYSA-N 0.000 claims description 2
- 229910052981 lead sulfide Inorganic materials 0.000 claims description 2
- 229940056932 lead sulfide Drugs 0.000 claims description 2
- 229910052976 metal sulfide Inorganic materials 0.000 claims description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 2
- VTRUBDSFZJNXHI-UHFFFAOYSA-N oxoantimony Chemical compound [Sb]=O VTRUBDSFZJNXHI-UHFFFAOYSA-N 0.000 claims description 2
- 229910052760 oxygen Inorganic materials 0.000 claims description 2
- MYMOFIZGZYHOMD-UHFFFAOYSA-N oxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 claims description 2
- 239000001301 oxygen Substances 0.000 claims description 2
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical class [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 claims description 2
- RUDFQVOCFDJEEF-UHFFFAOYSA-N oxygen(2-);yttrium(3+) Chemical compound [O-2].[O-2].[O-2].[Y+3].[Y+3] RUDFQVOCFDJEEF-UHFFFAOYSA-N 0.000 claims description 2
- 229920002580 poly(selenophene-2,5-diyl) polymer Polymers 0.000 claims description 2
- 229910001954 samarium oxide Inorganic materials 0.000 claims description 2
- 229940075630 samarium oxide Drugs 0.000 claims description 2
- 239000004065 semiconductor Substances 0.000 claims description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 2
- 229910052814 silicon oxide Inorganic materials 0.000 claims description 2
- 229940056910 silver sulfide Drugs 0.000 claims description 2
- ZOMNDSJRWSNDFL-UHFFFAOYSA-N sulfanylidene(sulfanylideneindiganylsulfanyl)indigane Chemical compound S=[In]S[In]=S ZOMNDSJRWSNDFL-UHFFFAOYSA-N 0.000 claims description 2
- VRRFSFYSLSPWQY-UHFFFAOYSA-N sulfanylidenecobalt Chemical compound [Co]=S VRRFSFYSLSPWQY-UHFFFAOYSA-N 0.000 claims description 2
- QXKXDIKCIPXUPL-UHFFFAOYSA-N sulfanylidenemercury Chemical compound [Hg]=S QXKXDIKCIPXUPL-UHFFFAOYSA-N 0.000 claims description 2
- WWNBZGLDODTKEM-UHFFFAOYSA-N sulfanylidenenickel Chemical compound [Ni]=S WWNBZGLDODTKEM-UHFFFAOYSA-N 0.000 claims description 2
- 125000000542 sulfonic acid group Chemical group 0.000 claims description 2
- 150000005087 tellurophenes Chemical class 0.000 claims description 2
- YHBTXTFFTYXOFV-UHFFFAOYSA-N thieno[2,3-b]thiophene Chemical compound C1=CSC2=C1C=CS2 YHBTXTFFTYXOFV-UHFFFAOYSA-N 0.000 claims description 2
- PFZLGKHSYILJTH-UHFFFAOYSA-N thieno[2,3-c]thiophene Chemical compound S1C=C2SC=CC2=C1 PFZLGKHSYILJTH-UHFFFAOYSA-N 0.000 claims description 2
- NMFKEMBATXKZSP-UHFFFAOYSA-N thieno[3,2-b]thiophene Chemical compound S1C=CC2=C1C=CS2.S1C=CC2=C1C=CS2 NMFKEMBATXKZSP-UHFFFAOYSA-N 0.000 claims description 2
- 229910001929 titanium oxide Inorganic materials 0.000 claims description 2
- 125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 claims description 2
- GRUMUEUJTSXQOI-UHFFFAOYSA-N vanadium dioxide Chemical compound O=[V]=O GRUMUEUJTSXQOI-UHFFFAOYSA-N 0.000 claims description 2
- 229910001935 vanadium oxide Inorganic materials 0.000 claims description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 2
- 229910052725 zinc Inorganic materials 0.000 claims description 2
- 239000011701 zinc Substances 0.000 claims description 2
- 239000011787 zinc oxide Substances 0.000 claims description 2
- 229910001928 zirconium oxide Inorganic materials 0.000 claims description 2
- URLKBWYHVLBVBO-UHFFFAOYSA-N p-xylene Chemical group CC1=CC=C(C)C=C1 URLKBWYHVLBVBO-UHFFFAOYSA-N 0.000 description 1
Description
本明細書において明記される種々の範囲内の数値が使用される場合、記載の範囲内の最小値および最大値の両方の前に単語「約」が付けられているかのように近似値として記載されている。この方法では、記載の範囲よりもわずかに上およびわずかに下のばらつきを使用して、その範囲内の値の場合と実質的に同じ結果を得ることができる。また、これらの範囲の開示は、ある値の一部の成分を異なる値の一部の成分と混合した場合に生じうる分数値を含めて、最小平均値と最大平均値との間のすべての値を含む連続した範囲であることを意図している。さらに、より広い範囲およびより狭い範囲が開示される場合、ある範囲の最小値を別の範囲の最大値と一致させること、およびその逆のことが本発明の意図の範囲内となる。
本発明は以下の実施の態様を含むものである。
１．少なくとも１種類の高フッ素化酸ポリマーでドープした少なくとも１種類の導電性ポリマーの水性分散体と、
無機ナノ粒子と
を含む、組成物。
２．前記導電性ポリマーが、ポリチオフェン類、ポリ（セレノフェン）類、ポリ（テルロフェン）類、ポリピロール類、ポリアニリン類、多環式芳香族ポリマー類、それらのコポリマー、およびそれらの組み合わせからなる群から選択される、前記１に記載の組成物。
３．前記導電性ポリマーが、ポリアニリン、ポリチオフェン、ポリピロール、縮合多環式複素環式芳香族ポリマー、それらのコポリマー、およびそれらの組み合わせからなる群から選択される、前記２に記載の組成物。
４．前記導電性ポリマーが、非置換ポリアニリン、ポリ（３，４−エチレンジオキシチオフェン）、非置換ポリピロール、ポリ（チエノ（２，３−ｂ）チオフェン）、ポリ（チエノ（３，２−ｂ）チオフェン）、およびポリ（チエノ（３，４−ｂ）チオフェン）からなる群から選択される、前記３に記載の組成物。
５．前記高フッ素化酸ポリマーが少なくとも９５％フッ素化されている、前記１に記載の組成物。
６．前記高フッ素化酸ポリマーがスルホン酸およびスルホンイミドから選択される、前記１に記載の組成物。
７．前記高フッ素化酸ポリマーが、パーフルオロ−エーテル−スルホン酸側鎖を有するパーフルオロオレフィンである、前記１に記載の組成物。
８．前記高フッ素化酸ポリマーが、１，１−ジフルオロエチレンと２−（１，１−ジフルオロ−２−（トリフルオロメチル）アリルオキシ）−１，１，２，２−テトラフルオロエタンスルホン酸とのコポリマー、およびエチレンと２−（２−（１，２，２−トリフルオロビニルオキシ）−１，１，２，３，３，３−ヘキサフルオロプロポキシ）−１，１，２，２−テトラフルオロエタンスルホン酸とのコポリマー、からなる群から選択される、前記１に記載の組成物。
９．前記高フッ素化酸ポリマーが、テトラフルオロエチレンとパーフルオロ（３，６−ジオキサ−４−メチル−７−オクテンスルホン酸）とのコポリマー、およびテトラフルオロエチレンおよびパーフルオロ（３−オキサ−４−ペンテンスルホン酸）とのコポリマーから選択される、前記１に記載の組成物。
１０．前記無機ナノ粒子が半導体である、前記１に記載の組成物。
１１．前記無機ナノ粒子が、金属硫化物類、金属酸化物類、およびそれらの組み合わせからなる群から選択される、前記１０に記載の組成物。
１２．前記金属酸化物が、アンチモン酸亜鉛類、インジウム・スズ酸化物、酸素欠乏型三酸化モリブデン、五酸化バナジウム、およびそれらの組み合わせからなる群から選択される、前記１１に記載の組成物。
１３．前記無機ナノ粒子が絶縁性である、前記１に記載の組成物。
１４．前記ナノ粒子が、酸化ケイ素、酸化チタン類、酸化ジルコニウム、三酸化モリブデン、酸化バナジウム、酸化アルミニウム、酸化亜鉛、酸化サマリウム、酸化イットリウム、酸化セシウム、酸化第二銅、酸化第二スズ、酸化アンチモン、およびそれらの組み合わせからなる群から選択される、前記１３に記載の組成物。
１５．前記無機ナノ粒子が、硫化カドミウム、硫化銅、硫化鉛、硫化水銀、硫化インジウム、硫化銀、硫化コバルト、硫化ニッケル、硫化モリブデン、Ｎｉ／Ｃｄ硫化物類、Ｃｏ／Ｃｄ硫化物類、Ｃｄ／Ｉｎ硫化物類、Ｐｄ−Ｃｏ−Ｐｄ硫化物類、およびそれらの組み合わせからなる群から選択される、前記１に記載の組成物。
１６．ナノ粒子対導電性ポリマーの重量比が０．１〜１０．０の範囲内である、前記１に記載の組成物。
１７．前記１に記載の組成物から作製されたフィルム。
１８．ｐ−キシレンに対して５０°未満の接触角を有する、前記１７に記載のフィルム。
１９．４６０ｎｍにおいて１．４を超える屈折率を有する、前記１７に記載のフィルム。
２０．前記１に記載の組成物から作製された少なくとも１つの層を含む電子デバイス。
２１．前記層が緩衝層である、前記２０に記載のデバイス。
２２．アノード、緩衝層、電気活性層、およびカソードを含む、前記２１に記載のデバイス。
Where numbers within the various ranges specified herein are used, they are stated as approximations as if the word “about” preceded both the minimum and maximum values within the stated range. Has been. In this way, variations slightly above and slightly below the stated range can be used to achieve substantially the same results as for values within that range. The disclosure of these ranges also includes all values between the minimum and maximum average values, including fractional values that can occur when some components of one value are mixed with some components of different values. It is intended to be a continuous range containing values. Further, when a wider range and a narrower range are disclosed, it is within the spirit of the invention to match the minimum value of one range with the maximum value of another range and vice versa.
The present invention includes the following embodiments.
1. An aqueous dispersion of at least one conductive polymer doped with at least one highly fluorinated acid polymer;
With inorganic nanoparticles
A composition comprising:
2. The conductive polymer is selected from the group consisting of polythiophenes, poly (selenophene) s, poly (tellurophenes), polypyrroles, polyanilines, polycyclic aromatic polymers, copolymers thereof, and combinations thereof. The composition according to 1 above.
3. The composition of claim 2, wherein the conductive polymer is selected from the group consisting of polyaniline, polythiophene, polypyrrole, fused polycyclic heteroaromatic polymers, copolymers thereof, and combinations thereof.
4). The conductive polymer is unsubstituted polyaniline, poly (3,4-ethylenedioxythiophene), unsubstituted polypyrrole, poly (thieno (2,3-b) thiophene), poly (thieno (3,2-b) thiophene. ), And poly (thieno (3,4-b) thiophene).
5. The composition of claim 1, wherein the highly fluorinated acid polymer is at least 95% fluorinated.
6). The composition of claim 1, wherein the highly fluorinated acid polymer is selected from sulfonic acid and sulfonimide.
7). 2. The composition according to 1 above, wherein the highly fluorinated acid polymer is a perfluoroolefin having a perfluoro-ether-sulfonic acid side chain.
8). The highly fluorinated acid polymer is a copolymer of 1,1-difluoroethylene and 2- (1,1-difluoro-2- (trifluoromethyl) allyloxy) -1,1,2,2-tetrafluoroethanesulfonic acid And ethylene and 2- (2- (1,2,2-trifluorovinyloxy) -1,1,2,3,3,3-hexafluoropropoxy) -1,1,2,2-tetrafluoroethane The composition of claim 1, wherein the composition is selected from the group consisting of copolymers with sulfonic acids.
9. The highly fluorinated acid polymer is a copolymer of tetrafluoroethylene and perfluoro (3,6-dioxa-4-methyl-7-octenesulfonic acid), and tetrafluoroethylene and perfluoro (3-oxa-4-pentene). 2. A composition according to claim 1 selected from copolymers with sulfonic acids.
10. 2. The composition according to 1 above, wherein the inorganic nanoparticles are semiconductors.
11. 11. The composition according to 10 above, wherein the inorganic nanoparticles are selected from the group consisting of metal sulfides, metal oxides, and combinations thereof.
12 12. The composition according to 11 above, wherein the metal oxide is selected from the group consisting of zinc antimonates, indium tin oxide, oxygen-deficient molybdenum trioxide, vanadium pentoxide, and combinations thereof.
13. 2. The composition according to 1 above, wherein the inorganic nanoparticles are insulating.
14 The nanoparticles are silicon oxide, titanium oxides, zirconium oxide, molybdenum trioxide, vanadium oxide, aluminum oxide, zinc oxide, samarium oxide, yttrium oxide, cesium oxide, cupric oxide, stannic oxide, antimony oxide, 14. The composition of claim 13, which is selected from the group consisting of and combinations thereof.
15. The inorganic nanoparticles are cadmium sulfide, copper sulfide, lead sulfide, mercury sulfide, indium sulfide, silver sulfide, cobalt sulfide, nickel sulfide, molybdenum sulfide, Ni / Cd sulfides, Co / Cd sulfides, Cd / In The composition of claim 1, wherein the composition is selected from the group consisting of sulfides, Pd—Co—Pd sulfides, and combinations thereof.
16. 2. The composition according to 1 above, wherein the weight ratio of the nanoparticles to the conductive polymer is in the range of 0.1 to 10.0.
17. A film prepared from the composition according to 1 above.
18. 18. The film according to 17, wherein the film has a contact angle of less than 50 ° with respect to p-xylene.
19. The film of 17, wherein the film has a refractive index greater than 1.4 at 460 nm.
20. An electronic device comprising at least one layer made from the composition of claim 1.
21. 21. The device of claim 20, wherein the layer is a buffer layer.
22. The device of claim 21, comprising an anode, a buffer layer, an electroactive layer, and a cathode.
Claims (15)
無機ナノ粒子と
を含む、組成物。 An aqueous dispersion of at least one conductive polymer doped with at least one highly fluorinated acid polymer;
A composition comprising inorganic nanoparticles.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/US2008/070718 WO2009018009A1 (en) | 2007-07-27 | 2008-07-22 | Aqueous dispersions of electrically conducting polymers containing inorganic nanoparticles |
| USPCT/US2008/070718 | 2008-07-22 | ||
| PCT/US2009/035079 WO2010011368A1 (en) | 2008-07-22 | 2009-02-25 | Aqueous dispersions of electrically conducting polymers containing inorganic nanoparticles |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2011529115A JP2011529115A (en) | 2011-12-01 |
| JP2011529115A5 true JP2011529115A5 (en) | 2012-04-12 |
Family
ID=41571063
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2011520054A Pending JP2011529115A (en) | 2008-07-22 | 2009-02-25 | Aqueous dispersion of conductive polymer containing inorganic nanoparticles |
Country Status (6)
| Country | Link |
|---|---|
| EP (1) | EP2311047A4 (en) |
| JP (1) | JP2011529115A (en) |
| KR (1) | KR20110044240A (en) |
| CN (1) | CN102099871A (en) |
| TW (1) | TW201005020A (en) |
| WO (1) | WO2010011368A1 (en) |
Families Citing this family (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5882318B2 (en) * | 2010-07-26 | 2016-03-09 | メルク パテント ゲーエムベーハー | Nanocrystals in devices |
| FR2964331B1 (en) * | 2010-09-03 | 2017-12-15 | Commissariat Energie Atomique | CHEMICALLY STABILIZED MEMBRANE, PROCESS FOR PREPARING THE SAME AND USES THEREOF |
| KR101862899B1 (en) | 2011-02-04 | 2018-05-30 | 쓰리엠 이노베이티브 프로퍼티즈 컴파니 | Amorphous perfluoropolymers comprising zirconium oxide nanoparticles |
| JP5655640B2 (en) * | 2011-03-08 | 2015-01-21 | コニカミノルタ株式会社 | ORGANIC ELECTROLUMINESCENT ELEMENT AND METHOD FOR PRODUCING ORGANIC ELECTROLUMINESCENT ELEMENT |
| CN105576140B (en) * | 2013-01-16 | 2018-10-26 | 吴剑辉 | A kind of organic electroluminescence device |
| CN103865263B (en) * | 2014-01-09 | 2016-05-11 | 常州大学 | The preparation method of the compound infrared stealth material of a kind of organic and inorganic |
| EP3002797B1 (en) * | 2014-09-30 | 2020-04-29 | Novaled GmbH | A light emitting organic device and an active OLED display |
| JP6312090B2 (en) | 2015-03-11 | 2018-04-18 | 信越化学工業株式会社 | Conductive material and substrate |
| JP6294254B2 (en) | 2015-03-23 | 2018-03-14 | 信越化学工業株式会社 | Conductive material and substrate |
| JP6499535B2 (en) * | 2015-07-09 | 2019-04-10 | 信越化学工業株式会社 | Coated product and pattern forming method |
| JP6600286B2 (en) * | 2015-11-09 | 2019-10-30 | 信越化学工業株式会社 | Conductive material and substrate |
| CN105968347B (en) * | 2016-05-23 | 2018-02-06 | 华东交通大学 | The preparation method of N substitution carboxyls polyaniline/cadmium sulfide quantum dot composite material |
| TWI618093B (en) * | 2016-12-14 | 2018-03-11 | 行政院原子能委員會核能研究所 | Method for preparing organic solar cell with high thermal stability |
| KR102564836B1 (en) * | 2017-01-18 | 2023-08-09 | 닛산 가가쿠 가부시키가이샤 | ink composition |
| CN113122070A (en) * | 2019-12-31 | 2021-07-16 | Tcl集团股份有限公司 | Composition, preparation method thereof and light-emitting diode |
| CN113258009B (en) * | 2020-04-17 | 2022-08-05 | 广东聚华印刷显示技术有限公司 | Composite material and preparation method thereof, and quantum dot light-emitting diode |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6599631B2 (en) * | 2001-01-26 | 2003-07-29 | Nanogram Corporation | Polymer-inorganic particle composites |
| JP2002293888A (en) * | 2001-03-29 | 2002-10-09 | Fuji Photo Film Co Ltd | New polymer, and material for luminescent element and luminescent element, using thereof |
| TWI302563B (en) * | 2002-09-24 | 2008-11-01 | Du Pont | Electrically conducting organic polymer/nanoparticle composites and methods for use thereof |
| US7317047B2 (en) * | 2002-09-24 | 2008-01-08 | E.I. Du Pont De Nemours And Company | Electrically conducting organic polymer/nanoparticle composites and methods for use thereof |
| JP4402937B2 (en) * | 2003-11-10 | 2010-01-20 | 株式会社日立製作所 | Nanoparticle dispersion material, nanoparticle dispersion sheet, and nanoparticle dispersion laminate sheet |
| US7112369B2 (en) * | 2004-03-02 | 2006-09-26 | Bridgestone Corporation | Nano-sized polymer-metal composites |
| JP5489458B2 (en) * | 2005-06-28 | 2014-05-14 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー | High work function transparent conductor |
| WO2007002740A2 (en) * | 2005-06-28 | 2007-01-04 | E. I. Du Pont De Nemours And Company | Buffer compositions |
| CN101688052A (en) * | 2007-07-27 | 2010-03-31 | E.I.内穆尔杜邦公司 | The aqueous dispersion that comprises the conductive polymers of inorganic nanoparticles |
| US20100247923A1 (en) * | 2008-03-19 | 2010-09-30 | E.I. Du Pont De Nemours And Company | Electrically conductive polymer compositions and films made therefrom |
-
2009
- 2009-02-25 JP JP2011520054A patent/JP2011529115A/en active Pending
- 2009-02-25 CN CN200980128309.6A patent/CN102099871A/en active Pending
- 2009-02-25 WO PCT/US2009/035079 patent/WO2010011368A1/en active Application Filing
- 2009-02-25 KR KR1020117003915A patent/KR20110044240A/en not_active Application Discontinuation
- 2009-02-25 EP EP09800711.5A patent/EP2311047A4/en not_active Withdrawn
- 2009-03-10 TW TW098107745A patent/TW201005020A/en unknown
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP2011529115A5 (en) | ||
| JP2012524834A5 (en) | ||
| JP2012520381A5 (en) | ||
| JP5612814B2 (en) | Conductive polymer solution, conductive coating film and input device | |
| US7981323B2 (en) | Selenium containing electrically conductive copolymers | |
| JP2012524831A5 (en) | ||
| JP5283818B2 (en) | Conductive composition and method for producing the same | |
| JP5460007B2 (en) | Conductive polymer solution, conductive coating film and input device | |
| JP5323302B2 (en) | Method for producing conductive polymer paint and method for producing conductive coating film | |
| EP2014718B2 (en) | Conductive composition, and their production method | |
| JP2010514904A5 (en) | ||
| US20110201826A1 (en) | Conjugated polymers from substituted 3,4-propylenedioxythiophene, compositions, method of making, and use thereof | |
| JP2013515157A5 (en) | ||
| JP5460008B2 (en) | Conductive polymer solution, conductive coating film and input device | |
| US20070096066A1 (en) | Conductive composition, conductive coating material, conductive resin, capacitor, photoelectric transducer, and their production method | |
| US10005914B2 (en) | Highly conductive polymer film compositions from nanoparticle induced phase segregation of counterion templates from conducting polymers | |
| JP5444057B2 (en) | Solid electrolytic capacitor, manufacturing method thereof, and solution for solid electrolytic capacitor | |
| US9788422B2 (en) | Conductive material and substrate | |
| Sapp et al. | Work function and implications of doped poly (3, 4-ethylenedioxythiophene)-co-poly (ethylene glycol) | |
| WO2014189036A1 (en) | Electroconductive polymer liquid dispersion and electroconductive coating | |
| JP6600286B2 (en) | Conductive material and substrate | |
| JP6016780B2 (en) | Conductive polymer solution and method for producing the same, conductive polymer material, solid electrolytic capacitor using the same, and method for producing the same | |
| JP2007103558A (en) | Solid electrolyte, electrolytic capacitor, and manufacturing method thereof | |
| JP4602128B2 (en) | Capacitor and manufacturing method thereof | |
| JP2006185973A (en) | Conductive polymer solution and its manufacturing method, conductor, capacitor, and its manufacturing method |