JP2011165696A - Method of manufacturing winding coil component - Google Patents

Method of manufacturing winding coil component Download PDF

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JP2011165696A
JP2011165696A JP2010023132A JP2010023132A JP2011165696A JP 2011165696 A JP2011165696 A JP 2011165696A JP 2010023132 A JP2010023132 A JP 2010023132A JP 2010023132 A JP2010023132 A JP 2010023132A JP 2011165696 A JP2011165696 A JP 2011165696A
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resin composition
winding
resin
coil component
curing
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Nobuyuki Kinami
信之 木南
Nobuhiro Taniuchi
宣博 谷内
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Murata Manufacturing Co Ltd
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Murata Manufacturing Co Ltd
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<P>PROBLEM TO BE SOLVED: To suppress flow-out of molding resin during drying and curing steps to prevent contamination of an external electrode due to the flow of a resin ingredient reaching a surface of the external electrode, so as to surely and efficiently make a reliable winding type coil component. <P>SOLUTION: In manufacturing a winding coil component including the molding resin provided to cover winding wound around a core of a magnetic core having the core, a pair of flanges provided at both ends of the core and the external electrode provided on an outer side face of at least one of the flanges, a resin composition which contains epoxy resin with a molecular weight of 1,850 or larger, a filler and a solvent and becomes the molding resin after curing is applied to between the pair of flanges to cover the winding wound around the core. The resin composition is dried and cured, thereby obtaining the winding type coil component having the winding molded of the molding resin. Steps of drying and curing the resin composition take place in a temperature range of 100-180°C. <P>COPYRIGHT: (C)2011,JPO&INPIT

Description

本発明は、巻線コイル部品の製造方法に関し、詳しくは、巻芯部と、その両端側に配設された一対の鍔部とを有する磁性コアの、巻芯部に巻回された巻線を覆うように、一対の鍔部間に充填されたモールド樹脂(外層樹脂)を備えた巻線コイル部品の製造方法に関する。   The present invention relates to a method of manufacturing a wound coil component, and more specifically, a winding of a magnetic core having a winding core and a pair of flanges disposed on both ends thereof, wound around the winding core. It is related with the manufacturing method of the coil component provided with mold resin (outer layer resin) with which it filled between a pair of collar parts so that it might cover.

巻線コイル部品の一つに、例えば、図4に示すように、巻芯部51とその両端側に配設された一対の鍔部52a,52bを有する磁性コア53と、この磁性コア53の巻芯部51に巻回された巻線54と、巻芯部51に巻回された巻線54を覆うように、一対の鍔部52a,52b間に充填されたモールド樹脂55と、 一対の鍔部52a,52bのうちの下側の鍔部52aの、上側の鍔部52bと対向する面とは逆側の面(外側面)に配設され、巻線54の一方端部および他方端部が電気的に接続される一対の外部電極56a,56bとを備えたチップ型の巻線コイル部品がある。   For example, as shown in FIG. 4, a magnetic core 53 having a winding core portion 51 and a pair of flange portions 52 a and 52 b disposed on both ends thereof, A winding 54 wound around the core 51, a mold resin 55 filled between the pair of flanges 52a and 52b so as to cover the winding 54 wound around the core 51, and a pair of One end and the other end of the winding 54 are disposed on the surface (outer surface) opposite to the surface facing the upper flange 52b of the lower flange 52a of the flanges 52a and 52b. There is a chip-type winding coil component including a pair of external electrodes 56a and 56b to which parts are electrically connected.

そして、このような巻線コイル部品において用いられるモールド樹脂用の樹脂組成物として、例えば、(A)エポキシ樹脂と、(B)シリカ粒子と、(C)酸無水物と、(D)硬化促進剤とを必須成分として含有し、上記(B)シリカ粒子として平均粒径10〜30μmのシリカ粒子を、エポキシ樹脂組成物中に30〜85質量%含む樹脂組成物(モールドコイル含浸用エポキシ樹脂組成物)が提案されており、また、この樹脂組成物を用いたモールドコイル装置が提案されている(特許文献1参照)。   And as a resin composition for mold resin used in such a wound coil component, for example, (A) epoxy resin, (B) silica particles, (C) acid anhydride, and (D) curing acceleration An epoxy resin composition containing 30 to 85% by mass of silica particles having an average particle size of 10 to 30 μm as the silica particles (B) as an essential component (epoxy resin composition for mold coil impregnation) And a molded coil device using this resin composition has been proposed (see Patent Document 1).

この特許文献1の樹脂組成物は、コイルへの含浸性に優れており、その硬化物は、機械強度および通電状態における絶縁破壊電圧が高く、絶縁信頼性に優れており、この樹脂組成物をモールド用樹脂として用いることにより、機械強度および絶縁信頼性に優れたモールドコイル装置を安価に製造することができるとされている。   The resin composition of this Patent Document 1 is excellent in impregnation into a coil, and the cured product has high mechanical strength and high dielectric breakdown voltage in an energized state, and is excellent in insulation reliability. By using it as a resin for molding, it is said that a molded coil device excellent in mechanical strength and insulation reliability can be manufactured at low cost.

しかしながら、この樹脂組成物を用いた場合において、巻線の露出を回避すべく、相当量の樹脂組成物を塗布することが必要になった場合、加熱して樹脂組成物を乾燥・硬化させる工程で、樹脂成分が流れ出し、鍔部の外側面にまで回り込んで外部電極の表面を汚染し、接続信頼性(実装信頼性)を低下させるという問題点がある。
また、シリカ粒子などのフィラーを高い割合で充填する場合、樹脂組成物の流動性を向上させるために溶剤を含ませることがある。このような場合、特に上記の外部電極の汚染の問題が生じやすい。
However, when this resin composition is used, when it is necessary to apply a considerable amount of the resin composition in order to avoid the exposure of the winding, the step of heating and drying and curing the resin composition Thus, there is a problem that the resin component flows out and goes around to the outer surface of the flange, contaminates the surface of the external electrode, and lowers the connection reliability (mounting reliability).
Moreover, when filling with fillers, such as a silica particle, in a high ratio, in order to improve the fluidity | liquidity of a resin composition, a solvent may be included. In such a case, the problem of contamination of the external electrode is likely to occur.

特開2008−195782号公報JP 2008-195782 A

本発明は、上記課題を解決するものであり、製造工程において用いられるモールド用の樹脂が乾燥・硬化の工程で流れ出すことを抑制して、樹脂成分が外部電極の表面にまで回り込むことによる外部電極の汚染を防止し、信頼性の高い巻線型コイル部品を確実に、しかも効率よく製造することが可能な巻線型コイル部品の製造方法を提供することを目的とする。   This invention solves the said subject, suppresses the resin for the mold used in a manufacturing process flowing out at the process of drying and hardening, and an external electrode by which a resin component wraps around to the surface of an external electrode It is an object of the present invention to provide a method for manufacturing a wire-wound coil component that can reliably and efficiently manufacture a highly reliable wire-wound coil component.

上記課題を解決するため、本発明の巻線コイル部品の製造方法は、
巻芯部とその両端側に配設された一対の鍔部とを有する磁性コアと、
前記磁性コアの前記巻芯部に巻回された巻線と、
前記一対の鍔部のうちの一方の鍔部の、他方の鍔部と対向する面とは逆側の面に配設され、前記巻線の一方端部および他方端部が電気的に接続される一対の外部電極と、
前記巻芯部に巻回された巻線を覆うように、前記一対の鍔部間に充填されたモールド樹脂と
を備えた巻線コイル部品の製造方法であって、
分子量が1850以上のエポキシ樹脂と、フィラーと、溶剤とを含有する、硬化後に前記モールド樹脂となる樹脂組成物を、前記巻芯部に巻回された巻線を覆うように前記一対の鍔部間に付与する工程と、
前記一対の鍔部間に付与された前記樹脂組成物を乾燥・硬化させる工程と
を備えていることを特徴としている。
In order to solve the above problems, a method for manufacturing a wound coil component according to the present invention includes:
A magnetic core having a winding core and a pair of flanges disposed on both ends thereof;
A winding wound around the core portion of the magnetic core;
One of the pair of flanges is disposed on a surface opposite to the surface facing the other flange, and one end and the other end of the winding are electrically connected. A pair of external electrodes,
A method for manufacturing a wound coil component comprising: a mold resin filled between the pair of flanges so as to cover the winding wound around the winding core part,
The pair of eaves parts covering a winding wound around the core part with a resin composition containing an epoxy resin having a molecular weight of 1850 or more, a filler, and a solvent, which becomes the mold resin after curing. A process of applying between,
And a step of drying and curing the resin composition applied between the pair of collars.

また、本発明の巻線型コイル部品の製造方法においては、前記樹脂組成物を乾燥・硬化させる工程が、100℃以上180℃以下の温度範囲で実施されることが望ましい。   Moreover, in the manufacturing method of the winding type coil components of this invention, it is desirable that the process of drying and hardening the said resin composition is implemented in the temperature range of 100 degreeC or more and 180 degrees C or less.

また、前記樹脂組成物を乾燥・硬化させる工程が、所定の温度で乾燥を行う乾燥工程と、前記乾燥工程よりも高い温度で実施される硬化工程とを備えていることが望ましい。   Moreover, it is desirable that the step of drying and curing the resin composition includes a drying step of drying at a predetermined temperature and a curing step performed at a temperature higher than the drying step.

本発明の巻線コイル部品の製造方法においては、分子量が1850以上のエポキシ樹脂と、フィラーと、溶剤とを含有する、硬化後にモールド樹脂となる樹脂組成物を、巻芯部に巻回された巻線を覆うようにモールド樹脂一対の鍔部間に付与し、乾燥・硬化させるようにしているので、樹脂を流れ出しにくくして、外部電極の表面が汚染されることを防止することが可能になり、信頼性の高い巻線型コイル部品を確実に、しかも効率よく製造することができるようになる。   In the method for manufacturing a wound coil component of the present invention, a resin composition that contains an epoxy resin having a molecular weight of 1850 or more, a filler, and a solvent and becomes a mold resin after curing is wound around a core part. Since it is applied between the pair of flanges of the mold resin so as to cover the windings and dried and cured, it is possible to prevent the resin from flowing out and prevent the surface of the external electrode from being contaminated. Thus, a highly reliable wire-wound coil component can be manufactured reliably and efficiently.

すなわち、分子量が1850以上のエポキシ樹脂は、軟化点が高いため、加熱して、乾燥・硬化させる際の流動性が小さく、毛細管現象による回り込みが生じにくい。したがって、このようなエポキシ樹脂をベース樹脂として用いることにより、樹脂成分の回り込みを抑制、防止して、外部電極の表面が樹脂により汚染されることを確実に防止することが可能になり、生産効率を高く保ちつつ、外部電極の表面の汚染がなく、実装信頼性に優れた巻線型コイル部品を確実に製造することができる。   That is, since an epoxy resin having a molecular weight of 1850 or higher has a high softening point, the fluidity when heated, dried and cured is small, and wraparound due to capillary action is unlikely to occur. Therefore, by using such an epoxy resin as a base resin, it is possible to suppress and prevent the resin component from wrapping around, and to reliably prevent the surface of the external electrode from being contaminated by the resin. While maintaining high, there is no contamination of the surface of the external electrode, and a wire-wound coil component having excellent mounting reliability can be reliably manufactured.

なお、本発明において用いられる樹脂組成物を構成するエポキシ樹脂の種類に特別の制約はないが、好適なエポキシ樹脂の例として、ビスフェノールA型エポキシ樹脂が挙げられる。   In addition, although there is no special restriction | limiting in the kind of epoxy resin which comprises the resin composition used in this invention, Bisphenol A type epoxy resin is mentioned as an example of a suitable epoxy resin.

また、本発明において用いられる樹脂組成物を構成するフィラーの種類についても特別の制約はなく、充填性、流動性などを制御したり、絶縁性を向上させたりすることを目的として、種々のものを用いることができる。代表的なフィラーとしては、フェライト粒子などの磁性体粒子や、シリカ粒子などの絶縁体セラミック粒子などが例示される。また、樹脂組成物中のフィラーの配合割合についても特別の制約はなく、用途などに応じて種々の割合とすることが可能である。   In addition, there are no particular restrictions on the type of filler constituting the resin composition used in the present invention, and various types are used for the purpose of controlling fillability, fluidity, etc., or improving insulation. Can be used. Typical fillers include magnetic particles such as ferrite particles and insulator ceramic particles such as silica particles. Moreover, there is no special restriction | limiting also about the compounding ratio of the filler in a resin composition, It is possible to set it as a various ratio according to a use etc.

また、樹脂組成物に含まれる溶剤の種類についても特別の制約はなく、例えば、ジプロピレングリコールメチルエーテルアセテートをはじめとする種々の溶剤を、種々の割合で用いることができる。   Moreover, there is no special restriction | limiting also about the kind of solvent contained in a resin composition, For example, various solvents including a dipropylene glycol methyl ether acetate can be used in various ratios.

さらに、本発明においては、樹脂組成物を付与する(塗布する)方法についても特別の制約はなく、例えば、外部電極が形成された面を粘着テープなどの支持体に密着させて巻線型コイル部品素子を保持し、その状態でディスペンサから樹脂組成物を供給して巻線を覆うように塗布するディスペンサ塗布工法、少なくとも外部電極が形成されている面が浸漬しないような態様で樹脂組成物に浸漬することにより樹脂組成物を巻線を覆うように塗布するディッピング塗布工法などの種々の方法を用いることができる。   Further, in the present invention, there is no special restriction on the method of applying (applying) the resin composition. For example, the surface of the external electrode is closely attached to a support such as an adhesive tape, and the coiled coil component. Dispensing in the resin composition in such a manner that at least the surface on which the external electrode is formed is not dipped, holding the element and supplying the resin composition from the dispenser in that state and applying it so as to cover the winding By doing so, various methods such as a dipping coating method of coating the resin composition so as to cover the windings can be used.

また、樹脂組成物を乾燥・硬化させる工程を、100℃以上180℃以下の温度範囲で実施することにより、さらに確実に、樹脂組成物を乾燥・硬化させる際の樹脂の流動を抑制して、樹脂成分の外部電極への回り込みを防止することが可能になり、本発明をより実効あらしめることができる。   Further, by carrying out the step of drying and curing the resin composition in a temperature range of 100 ° C. or higher and 180 ° C. or lower, the flow of the resin when drying and curing the resin composition is more reliably suppressed, It becomes possible to prevent the resin component from wrapping around the external electrode, and the present invention can be made more effective.

また、樹脂組成物を乾燥・硬化させるにあたって、硬化工程での熱処理温度よりも低い所定の温度で乾燥工程を実施した後、さらに温度を上昇させて、乾燥工程よりも高い温度で硬化工程を実施することにより、樹脂組成物の流動を抑制しつつ、確実に硬化させることが可能になり、本発明をさらに実効あらしめることができる。   Also, when drying and curing the resin composition, after performing the drying process at a predetermined temperature lower than the heat treatment temperature in the curing process, the temperature is further increased and the curing process is performed at a temperature higher than the drying process. By doing so, it becomes possible to cure the resin composition while suppressing the flow of the resin composition, and the present invention can be further effectively realized.

なお、本発明の巻線型コイル部品の製造方法においては、乾燥工程を、エポキシ樹脂の軟化温度より30℃以上高い温度とならない範囲で実施することにより、樹脂組成物の流動を十分に抑制しつつ溶剤を乾燥させることが可能になり、その後に温度をさらに上昇させて硬化工程を実施する場合にも、樹脂成分が外部電極の表面にまで回り込むことを確実に抑制、防止することが可能になる。   In addition, in the manufacturing method of the winding type coil components of this invention, while implementing a drying process in the range which does not become 30 degreeC or more higher than the softening temperature of an epoxy resin, fully suppressing the flow of a resin composition. It becomes possible to dry the solvent, and it is possible to reliably suppress and prevent the resin component from reaching the surface of the external electrode even when the curing step is performed by further raising the temperature thereafter. .

本発明の実施例において用意した、モールド樹脂を配設する前の段階の巻線コイル部品素子を示す正面断面図である。It is front sectional drawing which shows the winding coil component element of the stage before arrange | positioning mold resin prepared in the Example of this invention. 本発明の実施例において、巻芯部に巻回された巻線を覆うように、磁性コアの一対の鍔部間に樹脂組成物を塗布、充填する方法を示す図である。In the Example of this invention, it is a figure which shows the method of apply | coating and filling a resin composition between a pair of collar parts of a magnetic core so that the coil | winding wound by the winding core part may be covered. 本発明の実施例にかかる方法により製造した巻線コイル部品を示す正面断面図である。It is front sectional drawing which shows the winding coil components manufactured by the method concerning the Example of this invention. 従来の、モールド樹脂を備えた巻線コイル部品を示す正面断面図である。It is front sectional drawing which shows the conventional winding coil components provided with mold resin.

以下に本発明の実施の形態を示して、本発明の特徴とするところをさらに詳しく説明する。   Embodiments of the present invention will be described below to describe the features of the present invention in more detail.

<実施例1>
[1]樹脂組成物の作製
まず、以下の各原料を秤取し、混合することにより樹脂組成物を作製した。
なお、この樹脂組成物の粘度は23Pa・sであった。
(a)エポキシ樹脂(分子量が1850で軟化点が97℃のビスフェノールA型エポキシ樹脂)349g
(b)硬化剤(フェノール樹脂)40g
(c)溶剤(ジプロピレングリコールメチルエーテルアセテート)761g
(d)フィラー(フェライト粒子)3617g
(e)硬化促進剤(イミダゾール系硬化促進剤)3.3g
<Example 1>
[1] Production of resin composition First, the following raw materials were weighed and mixed to produce a resin composition.
The viscosity of this resin composition was 23 Pa · s.
(a) Epoxy resin (bisphenol A type epoxy resin having a molecular weight of 1850 and a softening point of 97 ° C.) 349 g
(b) Curing agent (phenol resin) 40 g
(c) Solvent (dipropylene glycol methyl ether acetate) 761 g
(d) 3617 g filler (ferrite particles)
(e) 3.3 g of accelerator (imidazole accelerator)

[2]モールド樹脂を備えた巻線コイル部品の作製
この実施例では、樹脂組成物を塗布する対象である巻線コイル部品素子として、図1に示すように、巻芯部1と、その両端側に配設された一対の鍔部2a,2bとを有する磁性コア3と、この磁性コア3の巻芯部1に巻回された、表面が絶縁被覆された巻線4と、巻線4の両端部が電気的に接続される外部電極6a,6bとを備えた巻線コイル部品素子(モールド樹脂を配設する前の巻線コイル部品)A1を用意した。
[2] Production of Winding Coil Parts with Mold Resin In this example, as shown in FIG. 1, a winding core part 1 and both ends thereof as winding coil part elements to which a resin composition is applied. A magnetic core 3 having a pair of flanges 2a and 2b disposed on the side, a winding 4 wound around the core 1 of the magnetic core 3 and having an insulating coating on the surface, and a winding 4 A winding coil component element (winding coil component before the molding resin is disposed) A1 provided with external electrodes 6a and 6b to which both ends of are electrically connected was prepared.

なお、外部電極6a,6bは、一対の鍔部2a,2bのうち、他方の鍔部2bと対向する一方の鍔部2aの、他方の鍔部2bと対向する面とは逆側の面に配設されている。そして、巻線4の一方端部が一方の外部電極6aに接続され、他方端部が他方の外部電極6bに電気的に接続されている。   In addition, external electrode 6a, 6b is on the surface on the opposite side to the surface which opposes the other collar part 2b of one collar part 2a which opposes the other collar part 2b among a pair of collar parts 2a, 2b. It is arranged. One end of the winding 4 is connected to one external electrode 6a, and the other end is electrically connected to the other external electrode 6b.

それから、図2に示すように、主面が略垂直で、長手方向が略水平になるような姿勢で所定の方向(矢印Xの方向)に搬送されるように構成された粘着テープ(保持部材)10に、巻線型コイル部品素子A1の鍔部2aの、外部電極6a,6bが形成された面を粘着保持させる。   Then, as shown in FIG. 2, an adhesive tape (holding member) configured to be conveyed in a predetermined direction (in the direction of arrow X) in such a posture that the main surface is substantially vertical and the longitudinal direction is substantially horizontal. ) 10 is adhesively held on the surface on which the external electrodes 6a and 6b are formed of the flange portion 2a of the wound coil component element A1.

そして、その状態で、巻線コイル部品素子A1の、巻芯部1に巻回された巻線4を覆うように、磁性コア3の一対の鍔部2a,2b間に、上述のようにして作製した樹脂組成物5aを、ディスペンサ塗布機11を用いて塗布、充填した。   In this state, between the pair of flange portions 2a and 2b of the magnetic core 3 so as to cover the winding 4 wound around the winding core portion 1 of the winding coil component element A1, as described above. The produced resin composition 5a was applied and filled using the dispenser applicator 11.

なお、樹脂組成物5aを塗布、充填するにあたっては、原料調合時に用いた溶剤と同じ溶剤(ジプロピレングリコールメチルエーテルアセテート)を添加することにより、粘度が3Pa・sになるまで樹脂組成物を希釈して用いた。   In addition, when applying and filling the resin composition 5a, the resin composition is diluted until the viscosity becomes 3 Pa · s by adding the same solvent (dipropylene glycol methyl ether acetate) as the solvent used for preparing the raw material. Used.

それから、鍔部2a,2b間に樹脂組成物5aが充填された巻線型コイル部品素子A1を100℃に加熱して0.5h保持することにより乾燥させ、少なくとも溶剤の大部分を揮発させて除去した後、さらに温度を上昇させて、150℃で3h保持することにより、樹脂組成物5aを硬化させた。これにより、図3に示すように、巻線型コイル部品素子A1(図1)の、巻芯部1に巻回された巻線4がモールド樹脂5によりモールドされた構造を有する巻線型コイル部品Aを得た。なお、図3において、図1と同じ符号を付した部分は同一部分を示している。   Then, the wound coil part element A1 filled with the resin composition 5a between the flanges 2a and 2b is dried by heating to 100 ° C. and holding for 0.5 h, and at least most of the solvent is volatilized and removed. Then, the temperature was further raised and the resin composition 5a was cured by holding at 150 ° C. for 3 hours. As a result, as shown in FIG. 3, the coiled coil component A having a structure in which the coil 4 wound around the core 1 of the coiled coil component element A <b> 1 (FIG. 1) is molded with the mold resin 5. Got. Note that, in FIG. 3, the same reference numerals as those in FIG. 1 denote the same parts.

そして、このようにして作製した巻線型コイル部品について、外部電極の表面を観察し、モールド樹脂の回り込みによる汚染の有無を確認するとともに、観察に供した巻線型コイル部品の個数(試料総数)と、汚染が認められた巻線型コイル部品の個数(汚染不良個数)の関係から不良率を算出した。なお、不良率は下記の式により求めた。
不良率(%)=(汚染不良が認められた試料数/試料総数)×100
Then, for the wound-type coil component produced in this way, the surface of the external electrode is observed to confirm the presence or absence of contamination due to the wraparound of the mold resin, and the number (total number of samples) of the wound-type coil components used for the observation The defect rate was calculated from the relationship between the number of wound coil components that were contaminated (number of contamination defects). In addition, the defective rate was calculated | required by the following formula.
Defective rate (%) = (number of samples with defective contamination / total number of samples) × 100

<実施例2>
上記実施例1の樹脂組成物を構成する(a)のエポキシ樹脂として、分子量が5700のビスフェノールA型エポキシ樹脂(軟化点144℃)を用い、その配合量を375gとしたこと、および、上記実施例1の樹脂組成物を構成する(b)の硬化剤として、同じフェノール樹脂を用い、その配合量を14gとしたこと以外は、実施例1場合と同様の方法で樹脂組成物を作製した。この実施例2における樹脂組成物の粘度は66Pa・sであった。
そして、この樹脂組成物を用いて実施例1の場合と同じ方法で巻線型コイル部品を作製し、同じ方法で評価を行った。
<Example 2>
As the epoxy resin (a) constituting the resin composition of Example 1, a bisphenol A type epoxy resin (softening point 144 ° C.) having a molecular weight of 5700 was used, and its blending amount was 375 g. A resin composition was prepared in the same manner as in Example 1 except that the same phenol resin was used as the curing agent (b) constituting the resin composition of Example 1 and the blending amount was 14 g. The viscosity of the resin composition in Example 2 was 66 Pa · s.
And the winding type coil components were produced by the same method as the case of Example 1 using this resin composition, and it evaluated by the same method.

<比較例1>
上記実施例1の樹脂組成物を構成する(a)のエポキシ樹脂として、分子量が1000のビスフェノールA型エポキシ樹脂(軟化点64℃)を用い、その配合量を318gとしたこと、および、上記実施例1の樹脂組成物を構成する(b)の硬化剤として、同じフェノール樹脂を用い、その配合量を70gとしたこと以外は、実施例1場合と同様の方法で樹脂組成物を作製した。この比較例1における樹脂組成物の粘度は20Pa・sであった。
そして、この樹脂組成物を用いて実施例1の場合と同じ方法で巻線型コイル部品を作製し、同じ方法で評価を行った。
<Comparative Example 1>
As the epoxy resin of (a) constituting the resin composition of Example 1, a bisphenol A type epoxy resin having a molecular weight of 1000 (softening point: 64 ° C.) was used, and its blending amount was 318 g. A resin composition was prepared in the same manner as in Example 1 except that the same phenol resin was used as the curing agent (b) constituting the resin composition of Example 1 and the blending amount was 70 g. The viscosity of the resin composition in Comparative Example 1 was 20 Pa · s.
And the winding type coil components were produced by the same method as the case of Example 1 using this resin composition, and it evaluated by the same method.

[比較例2]
上記実施例1の樹脂組成物を構成する(a)のエポキシ樹脂として、分子量が1200のビスフェノールA型エポキシ樹脂(軟化点67℃)を用い、その配合量を334gとしたこと、および、上記実施例1の樹脂組成物を構成する(b)の硬化剤として、同じフェノール樹脂を用い、その配合量を54gとしたこと以外は、実施例1場合と同様の方法で樹脂組成物を作製した。この比較例2における樹脂組成物の粘度は20Pa・sであった。
そして、この樹脂組成物を用いて実施例1の場合と同じ方法で巻線型コイル部品を作製し、同じ方法で評価を行った。
[Comparative Example 2]
As the epoxy resin (a) constituting the resin composition of Example 1 above, a bisphenol A type epoxy resin (softening point 67 ° C.) having a molecular weight of 1200 was used, and its blending amount was 334 g. A resin composition was prepared in the same manner as in Example 1 except that the same phenol resin was used as the curing agent (b) constituting the resin composition of Example 1 and the blending amount was 54 g. The viscosity of the resin composition in Comparative Example 2 was 20 Pa · s.
And the winding type coil components were produced by the same method as the case of Example 1 using this resin composition, and it evaluated by the same method.

[比較例3]
上記実施例1の樹脂組成物を構成する(a)のエポキシ樹脂として、分子量が1500のビスフェノールA型エポキシ樹脂(軟化点82℃)を用い、その配合量を341gとしたこと、および、上記実施例1の樹脂組成物を構成する(b)の硬化剤として、同じフェノール樹脂を用い、その配合量を47gとしたこと以外は、実施例1場合と同様の方法で樹脂組成物を作製した。この比較例3における樹脂組成物の粘度は22Pa・sであった。
そして、この樹脂組成物を用いて実施例1の場合と同じ方法で巻線型コイル部品を作製し、同じ方法で評価を行った。
[Comparative Example 3]
As the epoxy resin (a) constituting the resin composition of Example 1, a bisphenol A type epoxy resin having a molecular weight of 1500 (softening point 82 ° C.) was used, and its blending amount was set to 341 g. A resin composition was prepared in the same manner as in Example 1 except that the same phenol resin was used as the curing agent (b) constituting the resin composition of Example 1 and the blending amount was 47 g. The viscosity of the resin composition in Comparative Example 3 was 22 Pa · s.
And the winding type coil components were produced by the same method as the case of Example 1 using this resin composition, and it evaluated by the same method.

[評価]
上述のようにして作製した、実施例1および2の巻線型コイル部品、および比較例1〜3の巻線型コイル部品について評価結果を表1に示す。
[Evaluation]
Table 1 shows the evaluation results of the winding type coil parts of Examples 1 and 2 and the winding type coil parts of Comparative Examples 1 to 3 manufactured as described above.

Figure 2011165696
Figure 2011165696

表1に示すように、エポキシ樹脂として、分子量が1850で軟化点が97℃のエポキシ樹脂(ビスフェノールA型エポキシ樹脂)を用いた実施例1および、エポキシ樹脂として、分子量が5700で軟化点が144℃のエポキシ樹脂を用いた実施例2の巻線型コイル部品の場合、回り込んだ樹脂により外部電極の表面が汚染される不良の発生する割合(不良率)は1.5%(実施例1)、および1.4%(実施例2)と低く、信頼性の高い巻線型コイル部品を効率よく製造できることが確認された。   As shown in Table 1, Example 1 using an epoxy resin (bisphenol A type epoxy resin) having a molecular weight of 1850 and a softening point of 97 ° C. as an epoxy resin, and an epoxy resin having a molecular weight of 5700 and a softening point of 144 In the case of the wound-type coil component of Example 2 using an epoxy resin at 0 ° C., the rate of occurrence (defect rate) where the surface of the external electrode is contaminated by the wrapping resin is 1.5% (Example 1) Further, it was confirmed that a highly reliable wire-wound coil component can be efficiently manufactured with a low 1.4% (Example 2).

これに対し、エポキシ樹脂として、分子量が1000で軟化点が64℃のエポキシ樹脂(ビスフェノールA型エポキシ樹脂)を用いた比較例1、分子量が1200で軟化点が67℃のエポキシ樹脂を用いた比較例2、および、分子量が1500で軟化点が82℃のエポキシ樹脂を用いた比較例3の巻線型コイル部品の場合、回り込んだ樹脂により外部電極の表面が汚染される不良の発生する割合(不良率)は7.0%(比較例1)、5.6%(比較例2)、3.4%(比較例3)と高く、信頼性が低いことが確認された。   On the other hand, as an epoxy resin, Comparative Example 1 using an epoxy resin (bisphenol A type epoxy resin) having a molecular weight of 1000 and a softening point of 64 ° C., comparison using an epoxy resin having a molecular weight of 1200 and a softening point of 67 ° C. In the case of the wound type coil component of Example 2 and Comparative Example 3 using an epoxy resin having a molecular weight of 1500 and a softening point of 82 ° C., the ratio of occurrence of defects in which the surface of the external electrode is contaminated by the wraparound resin ( The defect rate was as high as 7.0% (Comparative Example 1), 5.6% (Comparative Example 2), and 3.4% (Comparative Example 3), confirming that the reliability was low.

なお、本発明の要件を満たす場合に、樹脂の回り込みにより外部電極の表面が汚染されることによる不良の発生率が減少するのは、樹脂組成物を構成するエポキシ樹脂として、分子量が1850以上で軟化点の高いエポキシ樹脂が用いられているため、塗布した樹脂組成物を、乾燥・硬化させるための熱処理工程において樹脂成分の流動が起こりにくくなり、外部電極の表面、すなわち、上記実施例では、粘着テープ(保持部材)10と、磁性コア3の鍔部2aの外部電極6a,6bが形成された面とで形成される空間にまで樹脂が回り込みにくくなることによる。   In addition, when the requirements of the present invention are satisfied, the incidence of defects due to contamination of the surface of the external electrode due to the wraparound of the resin is reduced because the molecular weight of the epoxy resin constituting the resin composition is 1850 or more. Since an epoxy resin having a high softening point is used, it is difficult for the resin component to flow in the heat treatment step for drying and curing the applied resin composition, and in the surface of the external electrode, that is, in the above embodiment, This is because the resin is less likely to enter the space formed by the adhesive tape (holding member) 10 and the surface on which the external electrodes 6a and 6b of the flange 2a of the magnetic core 3 are formed.

以上の結果から、本発明の巻線型コイル部品の製造方法によれば、磁性コア3の一対の鍔部2a,2b間に、巻線4を被覆するために充填される樹脂組成物5aが、その乾燥・硬化のための熱処理工程で流れ出し、外部電極6a,6bの表面にまで回り込むことを防止して、信頼性の高い巻線型コイル部品Aを効率よく製造できることが確認された。   From the above results, according to the method for manufacturing a wound-type coil component of the present invention, the resin composition 5a filled to cover the winding 4 between the pair of flanges 2a, 2b of the magnetic core 3 It was confirmed that a highly reliable coiled coil component A can be efficiently manufactured by preventing it from flowing into the surface of the external electrodes 6a and 6b through the heat treatment process for drying and curing.

なお、上記実施例では、樹脂組成物を構成するフィラーとしてフェライト粒子を用い、溶剤としてジプロピレングリコールメチルエーテルアセテートを用いているが、他の種類のフィラーや溶剤を用いることも可能である。   In the above embodiment, ferrite particles are used as the filler constituting the resin composition, and dipropylene glycol methyl ether acetate is used as the solvent. However, other types of fillers and solvents can be used.

また、上記実施例では、樹脂組成物の乾燥・硬化工程を、樹脂組成物を100℃で0.5h保持することにより実施される乾燥工程と、その後にさらに温度を上昇させて、150℃で3h保持することにより樹脂組成物を硬化させる硬化工程とを備えた、2段熱処理を行う工程としているが、各段の温度条件は、樹脂組成物を構成するエポキシ樹脂の種類や、樹脂組成物の具体的な組成などを考慮して決定することが望ましい。   Moreover, in the said Example, the drying / hardening process of a resin composition is carried out by the drying process implemented by hold | maintaining a resin composition at 100 degreeC for 0.5 h, and also raises temperature after that, at 150 degreeC. And a curing step for curing the resin composition by holding for 3 hours, a two-step heat treatment step is performed. The temperature conditions at each step are the type of epoxy resin constituting the resin composition and the resin composition. It is desirable to determine in consideration of the specific composition and the like.

また、乾燥・硬化の熱処理工程は、場合によっては、所定の一定の温度で実施する(すなわち、一段熱処理により乾燥と硬化を行わせる)ことも可能である。   Further, in some cases, the drying / curing heat treatment step may be performed at a predetermined constant temperature (that is, drying and curing are performed by one-step heat treatment).

本発明は、さらにその他の点においても上記実施例に限定されるものではなく、樹脂組成物の具体的な組成や、巻線型コイル部品を構成する磁性コアの構成、外部電極の配設態様、樹脂組成物の塗布方法などに関し、発明の範囲内において、種々の応用、変形を加えることが可能である。   The present invention is not limited to the above-described examples in other points as well. The specific composition of the resin composition, the configuration of the magnetic core constituting the wound coil component, the arrangement of the external electrodes, Various applications and modifications can be made within the scope of the invention with respect to the coating method of the resin composition.

1 巻芯部
2a,2b 鍔部
3 磁性コア
4 巻線
5 モールド樹脂
5a 樹脂組成物
6a,6b 外部電極
10 粘着テープ(保持部材)
11 ディスペンサ塗布機
A1 巻線コイル部品素子
A 巻線コイル部品
DESCRIPTION OF SYMBOLS 1 Core part 2a, 2b Eaves part 3 Magnetic core 4 Winding 5 Mold resin 5a Resin composition 6a, 6b External electrode 10 Adhesive tape (holding member)
11 Dispenser A1 Winding coil component element A Winding coil component

Claims (3)

巻芯部とその両端側に配設された一対の鍔部とを有する磁性コアと、
前記磁性コアの前記巻芯部に巻回された巻線と、
前記一対の鍔部のうちの一方の鍔部の、他方の鍔部と対向する面とは逆側の面に配設され、前記巻線の一方端部および他方端部が電気的に接続される一対の外部電極と、
前記巻芯部に巻回された巻線を覆うように、前記一対の鍔部間に充填されたモールド樹脂と
を備えた巻線コイル部品の製造方法であって、
分子量が1850以上のエポキシ樹脂と、フィラーと、溶剤とを含有する、硬化後に前記モールド樹脂となる樹脂組成物を、前記巻芯部に巻回された巻線を覆うように前記一対の鍔部間に付与する工程と、
前記一対の鍔部間に付与された前記樹脂組成物を乾燥・硬化させる工程と
を備えていることを特徴とする巻線コイル部品の製造方法。
A magnetic core having a winding core and a pair of flanges disposed on both ends thereof;
A winding wound around the core portion of the magnetic core;
One of the pair of flanges is disposed on a surface opposite to the surface facing the other flange, and one end and the other end of the winding are electrically connected. A pair of external electrodes,
A method for manufacturing a wound coil component comprising: a mold resin filled between the pair of flanges so as to cover the winding wound around the winding core part,
The pair of eaves parts covering a winding wound around the core part with a resin composition containing an epoxy resin having a molecular weight of 1850 or more, a filler, and a solvent, which becomes the mold resin after curing. A process of applying between,
A step of drying and curing the resin composition applied between the pair of collars. A method of manufacturing a wound coil component, comprising:
前記樹脂組成物を乾燥・硬化させる工程が、100℃以上180℃以下の温度範囲で実施されることを特徴とする請求項1記載の巻線コイル部品の製造方法。   The method for manufacturing a wound coil component according to claim 1, wherein the step of drying and curing the resin composition is performed in a temperature range of 100 ° C or higher and 180 ° C or lower. 前記樹脂組成物を乾燥・硬化させる工程が、所定の温度で乾燥を行う乾燥工程と、前記乾燥工程よりも高い温度で実施される硬化工程とを備えていることを特徴とする請求項1または2記載の巻線コイル部品の製造方法。   The step of drying and curing the resin composition includes a drying step of drying at a predetermined temperature and a curing step performed at a temperature higher than the drying step. 2. A method for manufacturing a wound coil component according to 2.
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US9966187B2 (en) 2014-07-28 2018-05-08 Taiyo Yuden Co., Ltd. Coil component
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JP2000286140A (en) * 1999-01-28 2000-10-13 Taiyo Yuden Co Ltd Chip-shaped electronic component and manufacture thereof
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JPH03149252A (en) * 1989-11-06 1991-06-25 Murata Mfg Co Ltd Sealing material for piezoelectric resonating component
JPH05190328A (en) * 1992-01-10 1993-07-30 Murata Mfg Co Ltd Resin armor for electronic parts
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CN102789882A (en) * 2012-08-20 2012-11-21 深圳顺络电子股份有限公司 Winding inductor of open magnetic circuit
US9966187B2 (en) 2014-07-28 2018-05-08 Taiyo Yuden Co., Ltd. Coil component
US10276296B2 (en) 2014-08-01 2019-04-30 Taiyo Yuden Co., Ltd Coil component and electronic device equipped with the same
US10741323B2 (en) 2014-08-01 2020-08-11 Taiyo Yuden Co., Ltd Coil component and electronic device equipped with the same

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