JP2011106765A - Injecting object and method of manufacturing the same - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To provide an injecting object that can be blown far, and a method of manufacturing the same. <P>SOLUTION: In the injecting object injected from an injection device, the injecting object is formed of water, an action-effective substance, and a gelling agent, or the injecting object comprises water, ethanol, the action-effective substance, and the gelling agent. The injection device includes a container for filling the injecting object, a piston for pressing the injecting object and injecting the injecting object from the container, a non-explosive blasting gas generator for generating gas pressure for pressing the piston, and a nozzle part for jetting the injecting object pressed by the piston. The gelling agent is sodium carboxymethylcellulose, xanthan gum, guar gum, pectin, carrageenan, tamarind gum, or propylene glycol. A lachrymatory component is 2-chloroacetophenone, capsaicin, a chili-pepper extracted liquid, or allyl isothiocyanate. <P>COPYRIGHT: (C)2011,JPO&INPIT

Description

  The present invention relates to a viscous liquid propellant ejected from a jetting device for self-defense to a suspicious person and a method for manufacturing the same.

Conventionally, a defense device that uses explosives as an ejection means is known as a device for jetting stimulating substances (liquid, gas) to self-defense against an intruder (for example, Patent Document 1). reference).
The defense device described in Patent Literature 1 is configured to inject liquid ejected matter from a plurality of nozzle holes.

Moreover, as this kind of liquid propellant, an aqueous tear solution for crime prevention composed of an ethanol extract such as chili and wasabi and its spraying means are known (for example, see Patent Document 2).
In addition, a tear-resistant composition for crime prevention and harmful bird and animal extermination in which 2-chloroacetophenone is dissolved in a mixed solvent containing ethanol and water as main components is known (for example, see Patent Document 3).

WO 01/90674 A1 JP 2002-62092 A JP 2009-84260 A

However, in the defense apparatus described in Patent Document 1, explosives are used as the injection means, and thus there are limitations on handling by ordinary people.
Therefore, a device that can be handled by a general person is demanded.
Further, in the defense device described in Patent Document 1, since there are a plurality of nozzle holes and the ejected matter is liquid, the ejected matter diffuses at the time of jetting, the jetting distance is short, and the jetted matter is affected by the wind. There is a risk of sticking to the user.

  On the other hand, the tear-proof aqueous solution for crime prevention sprays and conventional tear-forming compositions described in Patent Documents 2 and 3 are not viscous, and thus are easily dispersed and easily subjected to large air resistance. For this reason, there is a problem that it is easily affected by wind and cannot be sprayed far away.

  The present invention has been made to solve such a conventional problem, and an object of the present invention is to provide a projectile that can fly far away and a method for manufacturing the same.

The invention according to claim 1 is characterized in that in the ejected matter ejected from the ejecting device, the ejected matter is composed of water, an action effect substance and a gelling agent.
The invention according to claim 2 is characterized in that in the ejected matter ejected from the ejecting device, the ejected matter is composed of water, ethanol, an action effect substance, and a gelling agent.

According to a third aspect of the present invention, in the ejected matter according to the first or second aspect, the ejecting device injects the ejected matter from the container by pressing the ejected matter and a container filling the ejected matter. A non-explosive pyrotechnic gas generator that generates a gas pressure that presses the piston, and a nozzle portion that ejects the spray that is pressed by the piston.
The invention according to claim 4 is the propellant according to any one of claims 1 to 3, wherein the gelling agent is sodium carboxymethylcellulose, xanthan gum, guar gum, pectin, carrageenan, tamarind gum or propylene glycol. It is characterized by.

The invention according to claim 5 is the propellant according to any one of claims 1 to 4, wherein the action effect substance is a tear component or a colorant.
The invention according to claim 6 is the propellant according to claim 5, wherein the tearing component is 2-chloroacetophenone, capsaicin, chili extract or allyl isothiocyanate.
The invention according to claim 7 is the projectile according to claim 5, wherein the colorant is food coloring, ink, or water-based fluorescent paint.

The invention according to claim 8 is the propellant according to any one of claims 1 to 7, wherein the propellant includes 1.3 wt% to 2.3 wt% of the gelling agent and has a viscosity of 6 dPa · s. ˜40 dPa · s.
The invention according to claim 9 is the injection according to any one of claims 1 or 3 to 8, wherein the injection includes the water 85.7 wt% to 98.69 wt%, and the gelling agent. It is comprised by 1.3 wt%-2.3 wt%, and said action effect substance 0.01wt%-12.0wt%.

  The invention according to claim 10 is the injection according to any one of claims 2 to 9, wherein the injection includes the water 54.0 wt% to 61.0 wt% and the ethanol 39.0 wt% to 46.0 wt%. An ethanol aqueous solution composed of 0 wt% is composed of 84.7 wt% to 98.59 wt%, the gelling agent 1.3 wt% to 2.3 wt%, and the action effect substance 0.01 wt% to 12.0 wt%. It is characterized by.

The invention according to an eleventh aspect is the method for producing a propellant according to any one of the second to tenth aspects, wherein the ethanol is introduced into a container and stirred, and the action effect substance and the gelling agent are introduced. , Stirring, dissolving the active substance, dispersing the gelling agent, and then adding the water and stirring to dissolve the gelling agent.
The invention according to claim 12 is the method of manufacturing a projectile according to any one of claims 2 to 10, wherein the ethanol is charged into a container, stirred, the gelling agent is charged, stirred, The gelling agent is dispersed, then the water is added and stirred, the gelling agent is dissolved, and finally the water-based fluorescent paint is added and stirred.

According to the present invention, it has tearing effect and marking effect, and it is possible to eject a long distance.
According to the present invention, it is possible to easily produce a viscous jetted product in a short time.

1 is a perspective view showing a portable liquid ejecting apparatus 1 used in a first embodiment of the present invention. 1 is an exploded perspective view showing a portable liquid ejecting apparatus 1 used in the first embodiment into two ejecting apparatuses 10 and a portable launching apparatus 20 on which these two ejecting apparatuses 10 are mounted. It is sectional drawing of the injection apparatus 10 used for the portable liquid injection apparatus 1 used for 1st embodiment. It is sectional drawing which expands and shows the non-explosive pyrotechnic type gas generator 14 of the injection device 10 shown in FIG. It is explanatory drawing which shows the assembly procedure of the non-explosive pyrotechnic type gas generator 14 shown in FIG. It is a perspective view which decomposes | disassembles and shows the portable launcher 20 used for the portable liquid injection apparatus 1 used for 1st embodiment. It is a top view which removes one case 21B and shows the state which assembled | attached the injection apparatus 10 to the portable launcher 20 shown in FIG. It is a perspective view which shows the assembly | attachment state of the switch part 24 used for the portable launcher 20 shown in FIG. 6, the power supply part 23, and socket 22c, 22d. It is explanatory drawing which shows the state which connects the non-explosive pyrotechnic type gas generator 14 to the portable launcher 20 shown in FIG. It is a perspective view which removes one case 21B and shows the state before mounting | wearing the launcher 20 which can carry the two injection devices 10 in FIG. It is a perspective view which removes one case 21B and shows the state which mounted | wore the portable launcher 20 with the two injection devices 10 in FIG. It is explanatory drawing which shows the operation state of the portable liquid injection apparatus 1 shown in FIG. It is sectional drawing which shows the operating state of the injection apparatus 10 at the time of operation of the portable liquid injection apparatus 1 shown in FIG. It is explanatory drawing which shows the relationship between the piston 13 and the adapter 17 in which the pressure release mechanism in the injection device 10 shown in FIG. 1 functions. It is explanatory drawing which shows the method of finding the optimal injection conditions (nozzle diameter, injection material viscosity) of the nozzle part 16 in the injection device 10 shown in FIG. It is explanatory drawing which shows another example of the pressure release mechanism in the injection device 10 shown in FIG. It is a perspective view which shows the portable liquid injection apparatus 100 used for 2nd embodiment of this invention. It is a perspective view which shows the state which removed the safety cover 126 of the portable liquid ejecting apparatus 100 used for 2nd embodiment of this invention. It is a perspective view which decomposes | disassembles and shows the portable liquid injection apparatus 100 used for 2nd embodiment into the two injection apparatuses 110 and the portable launcher 120 which mounts these two injection apparatuses 110. FIG. It is sectional drawing of the injection apparatus 110 used for the portable liquid injection apparatus 100 used for 2nd embodiment. It is a perspective view which decomposes | disassembles and shows the portable launcher 120 used for the portable liquid injection apparatus 100 used for 2nd embodiment. It is a top view which removes one case 121B and shows the state which assembled | attached the injection apparatus 110 to the portable launching apparatus 120 shown in FIG. It is a perspective view which shows the assembly | attachment state of the switch part 124 used for the portable launcher 120 shown in FIG. 21, the power supply part 123, and wire mount socket 122a, 122b. It is explanatory drawing which shows the state before connecting the non-explosive pyrotechnic-type gas generator 114 to the portable launcher 120 shown in FIG. It is explanatory drawing which shows the state after connecting the non-explosive pyrotechnic-type gas generator 114 to the portable launcher 120 shown in FIG. It is explanatory drawing which shows the procedure which removes the injection apparatus 110 in the portable liquid injection apparatus 100 used for 2nd embodiment from the launcher 120 which can be carried. It is explanatory drawing which shows the procedure which removes and pulls out the injection apparatus 110 from the portable launcher 120 in the portable liquid injection apparatus 100 used for 2nd embodiment. It is explanatory drawing which shows the operation state of the portable liquid ejecting apparatus 100 shown in FIG. It is sectional drawing which shows another example of the injection apparatus 110 in this invention. It is sectional drawing which shows another example of the injection apparatus 110 in this invention. It is a perspective view which shows another example of the portable liquid ejecting apparatus 100 used for 2nd embodiment. It is a perspective view which shows another example of the portable liquid ejecting apparatus 100 used for 2nd embodiment. It is a perspective view which shows another example of the portable liquid ejecting apparatus 100 used for 2nd embodiment. It is a perspective view which shows another example of the portable liquid ejecting apparatus 100 used for 2nd embodiment. a: It is a figure which shows the ratio of water and ethanol of the ethanol aqueous solution in viscous tearing liquid (CN addition) (CMC1.3 wt%-2.3 wt%, CN0.1 wt%-1 wt%, liquid temperature 20 degreeC). b: The figure which shows the ratio of water and ethanol of the ethanol aqueous solution in the viscous marking liquid (food colorant addition) (CMC1.3 wt%-2.3 wt%, food color 0.01 wt%-5 wt%, liquid temperature 20 degreeC) It is. c: The ratio of water to ethanol in the ethanol aqueous solution in the viscous marking liquid (addition of ink or water-based fluorescent paint) (CMC 1.3 to 2.3 wt%, ink or water-based fluorescent paint 1 to 12 wt%, liquid temperature 20 ° C.) FIG. d: Liquid (CMC 1.3 wt% to 2.3 wt%, CN 0.1 to 1 wt%, food dye 0.01 to 5 wt%) added with a marking effect (addition of food dye) to a viscous tear solution (CN addition), It is a figure which shows the ratio of water and ethanol of the ethanol aqueous solution in (liquid temperature: 20 degreeC). e: Liquid (CMC: 1.3 wt% to 2.3 wt%, CN: 0.1 wt% to 1 wt%, ink ink) with marking effect (ink ink or water-based fluorescent paint added) added to viscous tear fluid (CN addition) And water-based fluorescent paint: 1 wt% to 12 wt%, liquid temperature: 20 ° C.) is a graph showing the ratio of water and ethanol in an ethanol aqueous solution. A target is placed ahead of the position where the ejection device (portable liquid ejection device) is fixed indoors. It is a figure which shows the test apparatus which installs a fan in the diagonally back of a target, sends a wind toward an injection apparatus, operates an injection apparatus in a counter wind, and verifies whether a sprayed material adheres to a target. The injection result by the test apparatus shown in FIG. 40 is shown. (A) shows the case of ◯: adhering in a circular shape, and (b) shows x: adhering in dots. Or the case where it does not adhere is shown. A sampling container is installed ahead of the position where the ejection device (portable liquid ejection device) is fixed indoors. It is a figure which shows the test apparatus which sprays tear liquid toward a sampling container and samples tear fluid. It is a figure which shows the relationship between viscosity (CMC ratio) and CN waveform area (strength). It is a figure which shows how the viscosity changes according to the ratio which adds a gelatinizer. It is a figure which shows the measuring apparatus which calculates | requires the characteristic of the injection material which concerns on this invention. It is a figure which shows the typical pressure profile of the pressure generation part in FIG. It is a figure which shows the measuring method using the measuring apparatus shown in FIG.

Hereinafter, the present invention will be described based on embodiments shown in the drawings.
(First embodiment)
1 to 15 show a portable liquid ejecting apparatus 1 used in the first embodiment of the present invention.
The portable liquid ejecting apparatus 1 used in the present embodiment is composed of two ejecting apparatuses 10 and a portable launching apparatus 20 on which these two ejecting apparatuses 10 are mounted.

First, the two injection devices 10 will be described.
As shown in FIG. 3, the two injection devices 10 inject the liquid injection material 12 from the container 11 by pressing the liquid injection material 12 according to the present embodiment and the liquid injection material 12. A piston 13 for generating a gas, a non-explosive pyrotechnic gas generator 14 for generating a gas pressure for pressing the piston 13, a nozzle portion 16 for ejecting a liquid propellant 12 pressed by the piston 13, a nozzle portion 16 and a container 11, and an adapter 17 that connects the nozzle portion 16 and the adapter 17.

The liquid propellant 12 according to the present embodiment includes, for example, a tearing liquid having a viscosity of about 6 to 40 dPa · s, a marking liquid, and the like. Since the liquid propellant 12 is viscous, the liquid propellant 12 is jetted in a lump, hardly diffuses, and the jetting distance becomes long.
The tear solution is made into a viscous tear solution by dissolving a tear component in ethanol, mixing water, and adding a gelling agent. Examples of the lacrimatory component include 2-chloroacetophenone, capsaicin, chili extract, and allyl isothiocyanate. Examples of the gelling agent include xanthan gum, sodium carboxymethyl cellulose, guar gum, pectin, carrageenan, propylene glycol, tamarind gum and the like.

  The marking liquid includes a case where the paint is viscous, a case where the paint is not viscous (water dilutable), a case where the paint is not viscous (ethanol dilutable), and the like. If the paint is viscous, use it as it is within the viscosity range. When the paint is not viscous (dilutable with water), the paint is diluted with water and a gelling agent is added to obtain a viscous marking liquid. When the paint is not viscous (ethanol can be diluted), the paint is diluted with ethanol, mixed with water, and a gelling agent is added to form a viscous marking liquid. Examples of the paint include ultraviolet light-emitting paint, fluorescent paint, phosphorescent paint, paint, and ink. Examples of the gelling agent include xanthan gum, sodium carboxymethylcellulose, guar gum, pectin, carrageenan, propylene glycol, and tamarind gum.

The container 11 filled with the liquid propellant 12 is made of, for example, a cylindrical body made of metal such as stainless steel or aluminum, and is provided with a female screw portion 11a into which a non-explosive pyrotechnic gas generator 14 is screwed at one end portion. A female screw portion 11b into which the adapter 17 is screwed is provided at the other end portion.
The piston 13 includes, for example, a main body 13a having a cylindrical shape made of plastic such as Teflon (registered trademark), ABS resin, nylon resin, and the like, and a pressure release groove 13c provided on the front end portion 13b side that presses the liquid spray 12. And a pressure receiving recess 13e provided on the rear end 13d side in contact with the gas outlet of the non-explosive pyrotechnic gas generator 14. The container 11 is attached to the inner wall surface 11c on the inner side of the female screw portion 11a at one end portion.

  As shown in FIGS. 3 and 4, the non-explosive pyrotechnic gas generator 14 includes a gas generator 14 a and a metal cylindrical body made of, for example, stainless steel or aluminum, and accommodates the gas generator 14 a. The holder 14o, and the leg wires 14j1 and 14j2 connected to the bridge 14g and 14g2 connected to the bridge wire 14g are fixed with epoxy resin, and the leg wires 14j1 and 14j2 connected to the cable bridge 14g are connected to the holder 14o. For example, a wedge base 14n made of a hard resin such as nylon resin or a metal such as stainless steel or aluminum, and a bottomed cylindrical body made of a metal such as stainless steel or aluminum, and covering the wedge base 14n. The cap 14k is screwed into the holder 14o by a female screw portion 14m provided on the inner periphery of the opening end.

  For example, the gas generating unit 14a is filled with a gas generating agent 14c in a gas generator tube 14b made of a metal bottomed cylindrical body made of aluminum, and an igniter cup 14d, an igniting agent 14e, and an igniting agent. The holder 14f and the plug 14g with the bridge line are sequentially loaded, and the gas generator tube body 14b is formed by caulking processing at the site 14h of the igniter holder 14f and the site 14i of the plug 14g with the bridge line.

  For example, by using a soft metal material such as aluminum, the gas generator tube 14b can easily destroy the gas generator tube 14b due to the reaction heat and reaction gas pressure of the gas generating agent 14c which is a non-explosive composition. Can be transmitted to the outside. The gas generator tube 14b may be anything as long as it is a soft metal material with good workability. For example, since the gas generator tube 14b has the same shape as an electric detonator using copper, aluminum (for example, A1-6016-0) is used. By using it, the confusingness is removed. The aluminum gas generator tube 14b is alumite-treated on the inner and outer surfaces.

  The gas generator tube 14b is filled with a gas generating agent 14c in a range of 0.3 g to 0.5 g. This gas generating agent 14c uses a low-vibration and low-noise crushing chemical gunsizer (trade name, manufactured by Nippon Koki Co., Ltd.). This is a consumption permit in exactly the same way as the crushing method using explosives. It is a non-explosive crushing composition that crushes bedrock and the like without need. This non-explosive crushing composition is disclosed, for example, in JP-A-11-029389. The gas generating agent 14c is not for the purpose of crushing the bedrock or the like, but for changing the gas pressure to the purpose of injecting the liquid propellant 12, and as a result, the gas pressure of the gas generating agent 14c is made uniform by adjusting the particle diameter of the gas generating agent 14c. It was found that the variation can be reduced. Further, it is possible to change the dose of the gas generating agent 14c in accordance with the performance of flying an object.

  The gas generating agent 14c is composed of 11.5 parts by weight of aluminum, 38.5 parts by weight of cupric oxide, a thermite agent comprising 50 parts by weight of potassium alum or ammonium alum, and a chloride previously dissolved in acetone. It is constituted by putting 1.5 parts by weight of vinyl powder in the same container, adding an appropriate amount of acetone and mixing well. When acetone is almost volatilized and solidified, it is granulated with an 8-mesh sieve and dried. After drying, 2.5 parts by weight of potassium stearate as a blunting agent and an appropriate amount of acetone are added and slowly mixed, and when acetone is vaporized and solidified, it is granulated and dried to obtain a gas generating agent. As the gas generating agent 14c, a sieved product having 24 Tyler mesh passing 42 Tyler mesh stopping is used. That is, the particle size is adjusted in the range of 0.35 mm to 0.71 mm.

  In the gas generator tube 14b, a capsule-shaped igniter cup 14d made of a synthetic resin, which serves as a partition wall, is disposed to prevent mixing of the filled gas generant 14c and igniter 14e. The igniter cup 14d may be metal or non-metal, but since the metal material is good electric, the electric ignition signal does not flow to the bridge line 14t, but is expended on the discharge energy. Since 14e may be non-ignited, it is necessary to perform an insulating process (for example, anodized process).

  The igniter cup 14d is a thin film having a thickness of 0.1 mm or less and a half-cut capsule is used, and is inserted into the igniter holder 14f. In the igniter cup 14d and the igniter holder 14f, an igniting agent 14e composed of a non-explosive composition and an electric bridge wire (for example, a platinum-iridium wire) 14t of a plug with wire bridge 14g are arranged. The igniting agent 14e was boron / cupric oxide = 10 wt% to 20 wt% / 80 to 90 wt%.

The plug 14g with bridge line is inserted after the igniter holder 14f is inserted into the igniter cup 14d and the igniter 14e is filled in the range of 0.06g to 0.13g, and then the gas generating agent 14c is filled. A gas generator tube body is formed by press-fitting into a gas generator tube body 14b made of aluminum and forming two crimped portions (14h, 14i) from the outside of the gas generator tube body 14b made of aluminum. It is fixed to 14b. The gas generator tube 14b, which is crimped to a plug 14g with a bridge, is inserted into the wedge base 14n and filled with an epoxy resin 14u. Backward gas ejection when the gas generator 14a ignites is blocked by the epoxy resin 14u filled in the wedge base 14n.
Further, the leg lines 14j1 and 14j2 are taken out from two holes 14v vacated at the bottom of the wedge base 14n to form electrical contact portions. The wedge base 14n is provided with a wedge portion 14w to which leg lines 14j1 and 14j2 are attached and coupled to a socket 22c described later.

  The holder 14o has an inner wall portion 14p having a gas jet port 14q attached to the gas generating portion 14a and expanding toward the opening side, and a male screw portion 14r provided on the outer periphery of the opening end on the gas jet port 14q side. A male screw portion 14s that is screwed with the female screw portion 14m of the cap 14k is provided on the outer periphery of the opening end on the cap 14k side. For example, iron or stainless steel can be used as the material of the holder 14o, but aluminum A5056 is preferable in terms of weight reduction and cost. Since the holder 14o engages the male screw portion 14s with the female screw portion 14m of the cap 14k, the gas generating portion 14a is fixed by the holder 14o and the cap 14k, and the gas generating portion 14a is moved backward when the gas generating portion 14a is operated. Prevents jumping out.

The nozzle portion 16 is constituted by a one-hole straight-advancing nozzle made of a metal such as stainless steel or aluminum, or a hard resin such as ABS resin or nylon resin, and the nozzle 16a has a hole diameter of φ1.5 mm to 3 mm. Is provided with a male screw portion 16b for connection to the adapter 17.
The adapter 17 is made of, for example, a cylindrical body made of metal such as stainless steel or aluminum, and is provided with a male screw portion 17a to be screwed into the female screw portion 11b of the container 11 at one end portion, and a male screw of the nozzle portion 16 at the other end portion. A female screw portion 17b into which the portion 16b is screwed is provided. Further, the adapter 17 is provided with an annular piston receiving surface 17c that protrudes from the inner wall surface toward the center, and serves as a wall surface on which the piston 13 collides. The wall surface on the nozzle portion side of the piston receiving surface 17c is sealed so that the liquid ejected matter 12 does not leak when the nozzle portion 16 is attached, for example, from an aluminum seal, an aluminum plate, a grooved synthetic resin sheet, or the like. It is set as the contact surface which interposes the seal 18 which becomes.

Next, the portable launcher 20 will be described.
The portable launching device 20 has a container shape in which the outer shape can be made portable by connecting, for example, a split case 21A, 21B made of an injection molded product such as ABS resin or polyacetal resin with a plurality of screws 21a. ing.
The case 21 </ b> A has two attachment portions 22 that attach the two injection devices 10 in an exchangeable manner by exposing the nozzle portion 16, and a power supply portion 23 that supplies electric power to each of the injection devices 10 attached to the two attachment portions 22. And a power supply unit that is provided between the power supply unit 23 and the injection device 10 and that short-circuits the power supply unit 23 and the injection device 10. Circuit board 25.

The attachment portion 22 includes socket assembly portions 22a and 22b in which sockets 22c and 22d that are coupled to the wedge base 14n of each injection device 10 are assembled, and a partition wall portion that rises oppositely so as to restrain the side portion of each injection device 10. 22e, an O-ring 22f for fixing the distal end side portion of the container 11 of each injection device 10, and an adapter 17 of each injection device 10, and an insertion hole 28 of each injection device 10 exposing the nozzle portion 16 is provided. And a recess 22g to be formed.
For example, as shown in FIG. 9, the sockets 22c and 22d are press-fitted into the recesses 22c3 and 22d3 of the sockets 22c and 22d by terminals 22c1, 22c2, 22d1 and 22d2 separated on the + and − sides. The terminals 22c1, 22c2, 22d1, and 22d2 are soldered with leg lines 22c4, 22c5, 22d4, and 22d5, respectively, so as to be electrically connected to the power supply circuit board 25.

  Here, the connection between the wedge base 14n of the injection device 10 and the socket 22c will be described. FIG. 9 shows the case where the resin portion of the socket 22c is removed and the actual appearance so that the connection portion can be easily understood. The connection between the wedge base 14n of the injection device 10 and the socket 22d is omitted, but is the same as the connection between the wedge base 14n of the injection device 10 and the socket 22c.

The plus side leg 14j1 of the wedge base 14n of the injection device 10 and the plus side terminal 22c1 of the socket 22c are connected. Similarly, the minus side leg 14j2 of the wedge base 14n and the minus side terminal 22c2 of the socket 22c are connected to each other. Is connected.
The socket assembly portion 22a is configured by a block-shaped body having a locking groove for restraining the socket 22c from both sides of the socket 22c.

In the power supply unit 23, electrodes 23c and 23d are arranged to face each other so that the two batteries 23a can be fixed in parallel.
The switch part 24 is provided between the partition wall parts 22e. The switch 24a protrudes into the window 22h so that it can be pressed.

  In this embodiment, the switch part 24 is provided with the switch circuit provided with the program which makes it possible to operate the two injection apparatuses 10 by one. When the switch 24a is pressed, the switch circuit energizes one of the injectors 10, ignites the non-explosive pyrotechnic gas generator 14, generates gas, and presses the piston 13 to cause the liquid propellant 12 to flow. After spraying from the nozzle section 16 and energization, the switch circuit program switches to the other injector 10 side, and when the switch 24a is pushed again, the other injector 10 is energized and a non-explosive pyrotechnic gas generator 14 is ignited, gas is generated, the piston 13 is pressed to inject the liquid ejected material 12 from the nozzle 16a, and after energization, it is switched to one of the injectors 10 side.

The case 21A is surrounded by a rising wall 22i, and a screw boss portion 22j for screwing a plurality of screws 21a is provided on the rising wall 22i.
The case 21B has a function as a lid that covers the upper surface side after mounting each component in the case 21A. The case 21B is surrounded by a rising wall 21f, and a plurality of screws 21a are inserted through the rising wall 21f. And a window 21c through which the switch 24a is exposed is provided on the top plate 21d.

In the portable launching device 20, a safety cover 26 that prevents an unexpected operation of the switch unit 24 is movably attached to the top plate 21d and the bottom plate 22k of the cases 21A and 21B.
The safety cover 26 has a U-shape formed by connecting the two cover portions 26a and 26b with a connecting portion 26c having a width equivalent to the thickness of the assembled cases 21A and 21B, and the two cover portions 26a, Two guides 26d that are guided along two grooves 21e and 21e (not shown in the case 21A) provided on the side surfaces of the cases 21A and 21B are provided on the inner surface of the case 26b.

Next, the operation of the portable liquid ejecting apparatus 1 used in this embodiment will be described.
First, assembly of the portable liquid ejecting apparatus 1 used in the present embodiment will be described.
As shown in FIGS. 2 and 10, the two injection devices 10 are inserted into the insertion holes 28 of the portable launching device 20 from the wedge portion 14 w, and are inserted into the socket assembly portions 22 a and 22 b of the portable launching device 20. By engaging the respective wedge portions 14w with the provided sockets 22c and 22d, the two injection devices 10 can be moved in a state where the nozzle portion 16 protrudes from the insertion hole 28 as shown in FIGS. Assembly to the portable launcher 20 is complete.

  As shown in FIG. 9, the wedge portion 14w and the sockets 22c and 22d are connected to the positive leg 14j1 of the wedge base 14n of one injector 10 and the positive terminal 22c1 of the socket 22c. Similarly, the negative leg 14j2 of the wedge base 14n and the negative terminal 22c2 of the socket 22c are connected. The plus side leg 14j1 of the wedge base 14n of the other injection device 10 is connected to the plus side terminal 22d1 of the socket 22c. Similarly, the minus side leg 14j2 of the wedge base 14n and the minus side terminal of the socket 22d are connected. 22d2 is connected.

Thus, the assembly of the portable liquid ejecting apparatus 1 is completed by attaching the two ejecting apparatuses 10 to the portable launching apparatus 20.
In the portable liquid ejecting apparatus 1, the user can operate the switch 24a at any time by inserting a finger from the windows 21c and 22h. In order to prevent erroneous operation, the safety cover 26 can be slid to close the windows 21c and 22h.

  In this state, when the user encounters a suspicious person or the like, when the user Y presses the switch 24a of the portable liquid ejecting apparatus 1 against the suspicious person X, as shown in FIG. The injection device 10 is energized, the current of the battery 23a passes through the leg wires 14j1 and 14j2, the energizer wire 14t of the non-explosive pyrotechnic gas generator 14 is energized, the bridge wire 14t generates heat, and the igniting agent 14e The gas generating agent 14c is combusted by the ignition of the igniting agent 14e, the gas generator tube 14b is broken by the generated gas, the gas pressure is released, and the gas pressure is released as shown in FIG. The gas pressure pushes the piston 13, the piston 13 pushes the liquid propellant 12, and the pushed liquid propellant 12 breaks the seal 18 and is ejected from the nozzle 16a to the outside. Here, the force for breaking the seal 18 is about 1 to 3 kgf.

As shown in FIG. 13B, when the piston 13 reaches the adapter 17, the gas pressure passes through the gap between the adapter 17 and the piston 13, and the residual pressure is released to the outside.
On the other hand, in the switch unit 24, after energization of one injection device 10, the program of the switch circuit is switched to the other injection device 10 side.

  In this state, as shown in FIG. 12B, when the user Y presses the switch 24a again, the other injector 10 is energized, and the current of the battery 23a passes through the leg lines 14j1 and 14j2. The electric bridge wire 14t of the non-explosive pyrotechnic gas generator 14 is energized, the electric wire 14t generates heat, the igniting agent 14e is ignited, and the gas generating agent 14c is combusted by the ignition of the igniting agent 14e. As a result, the gas generator tube 14b is broken and the gas pressure is released. As shown in FIG. 13A, the released gas pressure pushes the piston 13, and the piston 13 pushes the liquid propellant 12 and pushes it. The liquid ejected material 12 thus broken breaks the seal 18 and is ejected to the outside from the nozzle 16a.

On the other hand, after the switch unit 24 energizes the other injection device 10, the program of the switch circuit is switched to the one injection device 10 side.
As described above, the portable liquid ejecting apparatus 1 used in this embodiment can perform self-defense since the liquid ejected material 12 can be ejected twice with respect to the suspicious person X. .
And after using the two injection apparatuses 10, the two injection apparatuses 10 after use are extracted from the portable launching apparatus 20, and the new injection apparatus 10 is each mounted in the portable launching apparatus 20.

Thereby, the portable liquid ejecting apparatus 1 used in the present embodiment can be put into a usable state again.
The battery 23a is replaced by removing the screw 21a and removing the case 21B from the case 21A.

Next, in the portable liquid ejecting apparatus 1 used in this embodiment, the optimum conditions for the clearance between the piston 13 (outer diameter, length, groove size) and the inner diameter portion (inner diameter, inner diameter length) of the adapter 17 were examined.
Examine the relationship between the piston and adapter with which the pressure relief mechanism functions.
In FIG. 14A, an operation test was performed to check whether the pressure release mechanism functions according to the conditions of the gas flow path portions indicated by [1], [2] and [3].

表１に示す結果から、ピストン長＜アダプタ内径長が求められた。 The results are shown in Table 1, Table 2, and Table 3.
[1] Relationship between piston length and adapter inner diameter length

From the results shown in Table 1, piston length <adapter inner diameter length was obtained.

表２に示す結果から、ピストン外径＜アダプタ内径が求められた。 [2] Relationship between piston outer diameter and adapter inner diameter

From the results shown in Table 2, piston outer diameter <adapter inner diameter was obtained.

表３に示す結果から、ピストン外周からノズルへの流路が確保できる形状であれば溝形状に制限はないことが求められた。 [3] Pressure release groove shape of piston

From the results shown in Table 3, it was required that there is no limitation on the groove shape as long as the flow path from the outer periphery of the piston to the nozzle can be secured.

The evaluation in each table is indicated by ○ and ×.
○: No injection material remains in the injection device. (Pressure release mechanism worked)
X: The injection thing remains in an injection device. (If the pressure release mechanism works, there will be no remaining propellant in the injector.)

From the above, the relationship between the adapter 17 and the piston 13 in which the pressure release mechanism functions is as follows.
Piston length <Adapter inner diameter length Piston outer diameter <Adapter inner diameter The groove shape is not limited as long as the flow path from the piston outer periphery to the nozzle 16a can be secured.

Next, in the portable liquid ejecting apparatus 1 used in the present embodiment, an ejection test is performed by changing the nozzle diameter and the propellant viscosity condition, and the nozzle diameter is φ1.5 mm to 3 mm, and the ejector viscosity is 6 dPa · s to 40 dPa · s. It was confirmed that the injection situation was good.
Find the optimal spraying conditions (nozzle diameter, jetted product viscosity).

Test Method As shown in FIG. 15 (a), an injection device is fixed on one side, and a plate on which A3 paper is pasted is installed at a position 5 m from the injection device.
The state of adhesion of the ejected matter ejected from the ejecting device to the A3 sheet is confirmed.

Nozzles are difficult to diffuse during nozzle injection, and the nozzle diameter that can be injected is determined.
The nozzle diameter is changed using a one-hole straight nozzle so that the sprayed material is difficult to diffuse.

The propellant viscosity, which is difficult to diffuse during spraying and can be sprayed, is determined.
In order to perform the test by adjusting the viscosity, the gelling agent was added to the ink diluted with water in the test, and the viscosity was adjusted by the amount added.
Gelling agent: Xanthan gum Solvent: Indian ink + water

The graph shown in FIG. 15B shows the relationship between the amount of gelling agent added and the viscosity under the above conditions, and the relationship varies depending on the type of gelling agent and the type of solvent. The propellant viscosity was measured at 20 ° C.
Result Evaluation As shown in FIG. 15 (c), the ejection result was evaluated by ◯ × according to the state of adhesion of the ejected matter to the A3 paper.

表４において、
※１．ガス発生剤薬量０．３ｇ〜０．５ｇで試験
※２．噴射物量は最大６ｍｌで試験 The results are shown in Table 4.

In Table 4,
* 1. Test with a gas generant dose of 0.3 g to 0.5 g * 2. Tested with a propellant volume of up to 6 ml

From the above, the optimum injection conditions are as follows.
Nozzle diameter: straight 1-hole nozzle with a diameter of 1.5 mm to 3 mm, jetted product viscosity: 6 dPa · s to 40 dPa · s

  In the above-described embodiment, the case where the piston 13 and the adapter 17 are provided with the pressure adjusting mechanism for releasing the gas pressure from the nozzle portion 16 to the outside when the piston 13 collides is described. However, the present invention is not limited thereto. For example, as shown in FIG. 16, a plurality of pressure release grooves 17 d connected to the inner wall of the adapter 17 and the piston receiving surface 17 c may be used.

(Second embodiment)
17 to 28 show the portable liquid ejecting apparatus 100 used in the second embodiment of the present invention.
The portable liquid ejecting apparatus 100 used in the present embodiment is composed of two ejecting apparatuses 110 and a portable launching apparatus 120 on which these two ejecting apparatuses 110 are mounted.

First, the two injection devices 110 will be described.
As shown in FIGS. 19 and 20, the two injection devices 110 include a container 111 that is filled with a liquid injection 112 according to the present embodiment, and a liquid injection from the container 111 by pressing the liquid injection 112. A piston 113 that injects 112, a non-explosive pyrotechnic gas generator 114 that generates a gas pressure that presses the piston 113, a nozzle portion 116 that ejects a liquid propellant 112 pressed by the piston 113, and a nozzle portion 116 and a cup 117 interposed between the container 111 and the container 111. The two injection devices 110 have a Δ-seal 119 attached to the container 111 as a mark for mounting on the portable launching device 120.

The liquid projectile 112 according to the present embodiment is the same as the liquid projectile 12 in the first embodiment. Therefore, detailed description is omitted.
The container 111 filled with the liquid propellant 112 is made of, for example, a cylindrical body made of metal such as stainless steel or aluminum, and is provided with a female screw portion 111a into which a non-explosive pyrotechnic gas generator 114 is screwed at one end portion. A female screw portion 111b into which the nozzle portion 116 is screwed is provided at the other end portion. In addition, the container 111 is provided with an annular piston receiving surface 111d that protrudes from the inner wall surface toward the center, and serves as a wall surface on which the piston 113 collides.

The inner diameter on the piston receiving surface 111d side is slightly larger than the inner diameter on the piston 113 side to form the pressure release portion 111e. This pressure release part 111e is set as follows based on the relationship between the adapter 17 and the piston 13 in which the pressure release function described in the first embodiment functions.
The length of the piston 113 <the length of the inner diameter of the pressure release portion 111e <the outer diameter of the piston 113 <the inner diameter of the pressure release portion 111e> The wall surface on the nozzle portion 116 side of the piston receiving surface 111d is liquid when the nozzle portion 116 is attached. The abutting surface that seals the ejected material 112 so as not to leak, for example, is provided with a grooved cup 117 made of elastic synthetic resin.

  The piston 113 includes, for example, a main body 113a having a cylindrical shape made of plastic such as Teflon (registered trademark), ABS resin, nylon resin, and the like, and a pressure release groove 113c provided on the front end portion 113b side that presses the liquid ejected matter 112. And a pressure receiving recess 113e provided on the rear end portion 113d side in contact with the gas outlet of the non-explosive pyrotechnic gas generator 114. The piston 113 is attached to the inner wall surface 111 c on the inner side of the female screw portion 111 a at one end of the container 111.

  The non-explosive pyrotechnic gas generator 114 includes a gas generator 114a, a cylindrical body made of, for example, stainless steel or aluminum, a holder 114o for housing and fixing the gas generator 114a, and an electric bridge wire. A wire mount plug 114k that fixes the embolus 114g and the leg wires 114j1 and 14j2 connected to the plug embedding plug 114g with an epoxy resin and connects the leg wires 114j1 and 14j2 connected to the emery cable plug 114g. It consists of

  For example, the gas generating unit 114a is filled with a gas generating agent 114c in a gas generator tube 114b made of a metal bottomed cylindrical body made of aluminum, and an igniter cup 114d, an igniting agent 114e, and an igniting agent. The holder 114f and the bridge plug with plug 114g are sequentially loaded, and the gas generator tube body 114b is formed by caulking at the portion 114h of the igniter holder 114f and the portion 114i of the bridge plug 114g.

  For example, by using a soft metal material such as aluminum, the gas generator tube 114b can easily destroy the gas generator tube 114b due to the reaction heat and the reaction gas pressure of the gas generating agent 114c which is a non-explosive composition. Can be transmitted to the outside. The gas generator tube body 114b may be anything as long as it is a soft metal material with good workability. For example, the gas generator tube body 114b has the same shape as an electric detonator using copper, so aluminum (for example, A1-6016-0) is used. By using it, the confusingness is removed. The aluminum gas generator tube body 114b is alumite-treated on the inner and outer surfaces.

As in the first embodiment, the gas generator tube 114b is filled with a gas generating agent 114c in a range of 0.3 g to 0.5 g. This gas generating agent 114c was the same as the gas generating agent 14c of the first embodiment. Therefore, detailed description is omitted.
In the gas generator tube 114b, as in the first embodiment, a capsule-shaped igniter cup 114d made of a synthetic resin that serves as a partition wall to prevent mixing of the filled gas generant 114c and igniter 114e. Is arranged. This igniter cup 114d was the same as the igniter cup 14d of the first embodiment. Therefore, detailed description is omitted.

  As in the first embodiment, the igniter cup 114d is inserted into the igniter holder 114f using a thin capsule having a thickness of 0.1 mm or less and a half-cut capsule. In the igniter cup 114d and the igniter holder 114f, an igniting agent 114e composed of a non-explosive composition and an electric bridge wire (for example, a platinum-iridium wire) 114t including a plug-in plug 114g are arranged. As the ignition agent 114e, boron / cupric oxide = 10 wt% to 20 wt% / 80 wt% to 90 wt%.

  The plug 114g with a bridge line is inserted after the igniter holder 114f is inserted into the igniter cup 114d and the igniter 114e is filled in the range of 0.06 to 0.13g, and then the gas generating agent 114c is filled. The medicine is pressed into the gas generator tube made of aluminum and fixed to the gas generator tube 114b made of aluminum. The gas generator tube 114b, which is crimped to a plug 114g with a bridge, is inserted into the holder 114o and filled with epoxy resin. The wire mount plug 114k is connected by caulking to the leg wires 114j1 and 114j2 extending from the plug 114g with the electric bridge line. Backward gas ejection when the gas generator 114a ignites is blocked by the epoxy resin filled in the holder 114o.

24 and 25, the wire mount plug 114k includes a box-shaped plug body 114m provided with a partition wall therein, and a partition in the plug body 114m so as to extend to the opening end of the plug body 114m. In the positive side male terminal 114u and the negative side male terminal 114v attached to the wall vertically and the outer top plate of the plug body 114m, the plug body 114m is folded back from the opening end side toward the injection device 110 side in the vertical direction. A locking tongue 114w that is attached in a telescopic manner, a release claw 114x that is attached to the tip of the locking tongue 114w, and a locking projection 114y that is attached in the middle of the locking tongue 114w Have
The holder 114o has an inner wall portion 114p having a gas outlet 114q that fixes the gas generating portion 114a and expands toward the opening side, and a male screw portion 114r is provided on the outer periphery of the opening end portion on the gas outlet 114q side. ing. For example, stainless steel or aluminum can be used as the material of the holder 114o.

The nozzle portion 116 is composed of a one-hole straight nozzle made of a metal such as stainless steel or aluminum, or a hard resin such as ABS resin or nylon resin, and the nozzle hole 116a has a hole diameter of 1.5 mm to 3 mm. The male screw part 116b for connection with the container 111 is provided in the part.
The end surface of the nozzle hole 116a of the nozzle portion 116 is sealed with a circular adhesive seal made of, for example, paper or synthetic resin, in order to identify before and after the operation of the injection device 110 and prevent foreign matter from entering the nozzle portion 116. A seal 118 is affixed.

Next, the portable launcher 120 will be described.
As shown in FIG. 21, the portable launching device 120 has a portable outer shape by, for example, connecting the two cases 121A and 121B made of an injection molded product such as ABS resin or polyacetal resin with a plurality of screws 121a. The container shape is made.

  The case 121 </ b> A exposes the nozzle part 116 to attach the two injection devices 110 in a replaceable manner, and the power supply unit 123 supplies power to each of the injection devices 110 attached to the two attachment portions 122. And a power supply unit that is provided between the power supply unit 123 and the injection device 110 and that short-circuits the power supply unit 123 and the injection device 110, and the power supply unit 123 and the switch unit 124 are attached and communicated with the attachment unit 122. Circuit board 125.

The attachment portion 122 includes wire mount sockets 122a and 122b that are coupled to the wire mount plug 114k of each injection device 110, a partition wall portion 122e that rises to oppose the side portion of each injection device 110, and each injection device. 110 includes an O-ring 122f that fixes the front end side portion of the container 111, and a recess 122g that forms an insertion hole 128 of each injection device 110 that exposes the nozzle portion 116. The wire mount sockets 122a and 122b are soldered to the power circuit board 125.
As shown in FIGS. 24 and 25, the wire mount sockets 122a and 122b are vertically attached to a box-shaped socket body 122c provided with a recess for fitting the wire mount plug 114k, and a wall surface of the recess of the socket body 122c. A positive female terminal 122c1 and a negative female terminal 122c2 and a hole 122c3 provided on the ceiling of the socket main body 122c and into which a locking projection 114y attached to the plug main body 114m is fitted. As shown in FIGS. 24 and 25, the wire mount sockets 122a and 122b are attached to a support plate 122d. The support plate 122d includes leg wires (not shown) that connect the + side female terminal 122c1 and the − side female terminal 122c2 of the wire mount sockets 122a and 122b to the power supply circuit board 125.

Here, the connection between the wire mount plug 114k of the injection device 110 and the wire mount sockets 122a and 112b will be described.
FIG. 24 shows a state before connection, and FIG. 25 shows a state after connection.
The positive male terminal 114u of the wire mount plug 114k of the injection device 110 and the positive female terminal 122c1 of the wire mount sockets 122a and 122b are connected. Similarly, the negative male terminal 114v of the wire mount plug 114k and the wire mount are connected. The negative female screws 122c2 of the sockets 122a and 122b are connected. Further, the protrusion 114y of the locking tongue 114w of the wire mount plug 114k enters the hole 122c3 of the wire mount sockets 122a and 122b, so that the wire mount plug 114k and the wire mount sockets 122a and 122b are connected and fixed. .

In the power supply unit 123, electrodes 123c and 123d are arranged to face each other so that the two batteries 123a can be fixed in parallel. The switch part 124 is provided between the partition wall parts 122e. It protrudes to the side surface of the nozzle unit 116 side of the injection device 110 so that the switch 124a can be pressed.
In the present embodiment, the switch unit 124 has the same configuration as the switch unit 24 of the first embodiment, and a description thereof will be omitted.

The case 121A is surrounded by a rising wall 122i, and a screw boss part 122j for screwing a plurality of screws 121a is provided on the rising wall 122i.
The case 121B has a function as a lid that covers the upper surface side after mounting each component in the case 121A. The case 121B is surrounded by a rising wall 121f and a plurality of screws 121a are inserted through the rising wall 121f. Holes 121b are provided. An opening 121c for exposing the switch 124a is provided on one end of the top plate 121d.

  The case 121B functions as a lid that covers each component after the components are mounted in the case 121A. The case 121B is surrounded by a rising wall 121f, and a plurality of holes 121b for inserting the screws 121a into the rising wall 121f. And a window 121y for attaching a release button is provided on the top plate 121d. As shown in FIGS. 26 and 27, the release button 121g is for removing the injection device 110 from the portable launch device 120, and is an elastic synthetic resin part, and is locked by a window 121y around. A button main body 121h provided with an annular groove 121i and a release convex portion 121j provided at the center of the button main body 121h.

  By pressing the release button 121g, as shown in FIGS. 26 and 27, the convex portion 121j of the release button 121g pushes the claw portion 114x provided on the locking tongue piece 114w of the wire mount plug 114k, and the locking tongue The convex part 114y of the piece 114w comes off from the hole part 122c3 of the wire mount sockets 122a and 122b. In this state, the ejection device 110 can be detached from the portable launching device 120 by pulling out the nozzle portion 116 of the ejection device 110 from the portable launching device 120.

In the portable launching device 120, a safety cover 126 that prevents an unexpected operation of the switch unit 124 is attached to the switch unit mounting side surfaces of the cases 121A and 121B.
As shown in FIGS. 17 and 18, the safety cover 126 has a U-shape formed by connecting two cover portions 126a and 126b with a connecting portion 126c having a width equivalent to the thickness of the assembled cases 121A and 121B. In addition, the guides are provided along grooves 121x and 122x respectively provided on the outer surfaces of the rising walls 121f and 122e that form the insertion holes 128 of the cases 121A and 121B on the inner surfaces of the two cover portions 126a and 126b and the connecting portion 126c. A guide 126e provided with the claw portion 126d is provided. A switch 124a is accommodated between the guides 126e.

As shown in FIGS. 17, 18, and 19, near the two insertion holes 128 of the portable launcher 120, the container of the ejector 110 is mounted when the injector 110 is attached to the portable launcher 120. A Δ portion 129 is provided as a mark for aligning the apex position with the Δ seal 119 attached to 111.
Further, near the two insertion holes 128 of the portable launching device 120, numerals 1 and 2 indicating the order of the ejecting devices 110 to be fired are provided.
Further, the portable launching device 120 is provided with a convex part 121l and a concave part 121k that constitute an aiming device on the cover 121A. As shown in FIG. 28, this sighting device has a convex portion 121l as a target position, and the upper surface of the convex portion 121l and the upper surface of the concave portion 121k are in a straight line, thereby aiming at the top and bottom, and the center of the concave portion 121k. Since the convex part 121l comes to the left and right, it is possible to aim at the left and right.

Next, the operation of the portable liquid ejecting apparatus 100 used in this embodiment will be described.
First, assembly of the portable liquid ejecting apparatus 100 used in this embodiment will be described.
As shown in FIG. 19, two injection devices 110 are inserted into the insertion holes 128 of the portable launching device 120 from the wire mount plug 114k, and the portable launching device 120 is shown in FIGS. By connecting to the wire mount sockets 122a and 122b, the two injection devices 110 can be carried with the nozzle portion 116 protruding from the insertion hole 128 as shown in FIGS. Assembling is completed.

  As shown in FIGS. 24 and 25, the wire mount plug 114k and the wire mount sockets 122a and 122b are coupled to each other by connecting the positive male terminal 114u and the wire mount sockets 122a and 122b of the wire mount plug 114k of each injection device 110 as shown in FIGS. The positive female terminal 122c1 is connected, and similarly, the negative male terminal 114v of the wire mount plug 114k and the female terminal 122c2 on one side of the wire mount sockets 122a and 122b are connected. Further, the protrusion 114y of the wire mount plug 114k enters the hole 122c3 of the wire mount sockets 122a and 122b and is fixed.

As described above, the assembly of the portable liquid ejecting apparatus 100 is completed by attaching the two ejecting apparatuses 110 to the portable launching apparatus 120.
The portable liquid ejecting apparatus 100 allows the user to operate the switch 124a on the nozzle unit 116 side of the projecting apparatus at any time. In order to prevent erroneous operation, the safety cover 126 is attached to the switch 124a and the nozzle part 116 side.

In this state, when the user encounters a suspicious person or the like, the safety cover 126 is removed as shown in FIG.
As shown in FIG. 28, when the user Y points the portable liquid ejecting apparatus 100 toward the suspicious person X and presses the switch 124a, the one ejecting apparatus 110 is energized, and the current of the battery 123a is changed to the leg line. 114 j 1 and 114 j 2 are passed through the non-explosive pyrotechnic-type gas generator 114, and the bridge wire 114 t is heated, the bridge wire 114 t is heated, the igniting agent 114 e is ignited, and the ignition agent 114 e ignites the gas generating agent 114 c. The gas generated by combustion burns the gas generator tube 114b, releases the gas pressure, the released gas pressure pushes the piston 113, the piston 113 pushes the liquid propellant 112, and the pushed liquid The ejected matter 112 breaks the cup 117, breaks the sealing seal 118, and is ejected to the outside from the nozzle 116a.

Here, the force for breaking the cup 117 is about 1 to 3 kgf, and the force for breaking the sealing seal 118 is about 0.5 kgf.
When the piston 113 reaches the pressure release portion 111e of the container 111 during the above-described operation, the gas pressure passes through the gap between the pressure release portion 111e and the piston 113, and the residual pressure is released to the outside.
On the other hand, in the switch unit 124, after energization of one injection device 110, the program of the switch circuit is switched to the other injection device 110 side.

In this state, when the user presses the switch 124a again, the other injector 110 is energized, the current of the battery 123a passes through the leg lines 114j1 and 114j2, and the non-explosive pyrotechnic gas generator 114 is energized. The bridge line 114t is energized, the bridge line 114t generates heat, the igniting agent 114e is ignited, the gas generating agent 114c is combusted by the ignition of the igniting agent 114e, and the generated gas breaks the gas generator tube 114b. The gas pressure is released, the released gas pressure pushes the piston 113, the piston 113 pushes the liquid propellant 112, the pushed liquid propellant 112 breaks the cup 117, breaks the sealing seal 118, and the nozzle 116a From outside.
On the other hand, after the switch unit 124 energizes the other injection device 110, the program of the switch circuit is switched to the one injection device 110 side.

As described above, the portable liquid ejecting apparatus 100 used in the present embodiment can perform the ejection of the liquid ejected matter 112 twice against the suspicious person X, and thus can self-defense. .
Therefore, as shown in FIG. 28, the liquid jet is obtained by the user Y aiming up, down, left, and right by making full use of the convex part 121l and the concave part 121k constituting the sighting device provided in the portable launching device 120. 112 injections are more accurate and can be self-defending.
And after using the two injection devices 110, the two used injection devices 110 are extracted from the portable launch device 120, and the new injection devices 110 are respectively mounted on the portable launch devices 120.

As shown in FIG. 27, the ejection device 110 is removed from the portable launcher 120 by holding the release button 121g of the portable launcher 120 and holding the nozzle portion 116 of the ejection device 110. This is accomplished by pulling it out of the portable launcher 120.
As shown in FIG. 26, by pushing the release button 121g, the claw portion 114x of the wire mount plug 114k of the injection device 110 is pushed, and the convex portion 114y of the wire mount plug 114k becomes the wire mount of the portable launch device 120. The sockets 122a and 122b are removed from the holes 122c3. The injection device 110 can be extracted from the portable launch device 120 by pulling out the injection device 110 in this state.

The injection device 110 can be attached to the portable launching device 120 by attaching a Δ seal 119 attached to the container 111 of the injection device 110 and a Δ portion provided near the insertion hole 128 of the portable launching device 120. The injection device 110 is inserted into the insertion hole 128 of the portable launching device 120 while keeping the vertex position of 129 aligned.
Thereby, the portable liquid ejecting apparatus 100 used in the present embodiment can be put into a usable state again.
The battery 123a is replaced by removing the screw 121a and removing the case 121B from the case 121A.

Next, in the portable liquid ejecting apparatus 100 used in the present embodiment, the optimum conditions for the clearance between the piston 113 (outer diameter, length, groove size) and the container pressure release portion (inner diameter, inner diameter length) were examined.
In the present embodiment, the function of the adapter 17 in the first embodiment is added to the container 111, and the container 111 is a single component having a pressure release portion 111e, so the piston in which the pressure release mechanism in the first embodiment functions. 13 and the adapter 17 are the same result.
Therefore, also in this embodiment, the same result as the first embodiment could be obtained.

  In the above-described embodiment, the case where the pressure release mechanism that releases the gas pressure from the nozzle portion 116 to the outside when the piston 113 collides is configured by the piston 113 and the pressure release portion 111e provided in the container 111 has been described. The present invention is not limited to this. For example, the present invention may be configured by forming a plurality of pressure release grooves connected to the inner wall of the pressure release portion 111e of the container 111 and the piston receiving surface 111d.

Although the case where the pressure release part 111e was provided in the container 111 was demonstrated in the said embodiment, this invention is not limited to this, For example, as shown in FIG. 30, the container 111 is adapter like 1st embodiment. 17 may be provided.
Moreover, although the said embodiment demonstrated the case where the coupling | bonding of the wire mount plug 114k and wire mount socket 122a, 122b was used for the coupling | bonding of the injection apparatus 110 and the portable launching apparatus 120, this invention is based on this. Not limited to this, as shown in FIG. 29, similarly to the first embodiment, the injection device 110 may be connected to the wedge base 14n and the socket 22c.

  Moreover, although the said embodiment demonstrated the case where a sighting device was comprised with the convex part 121l and the recessed part 121k, this invention is not restricted to this, For example, it replaces with the recessed part 121k by the side of a recessed part, as shown in FIG. It is also possible to provide two convex portions 121m and to aim at the convex portion 121z coming to the center of the two convex portions 121m. Further, as shown in FIG. 32, a ring portion 121n may be provided instead of the concave portion 121k, and the convex portion 121z may come to the center of the circle of the ring portion 121n to aim. Furthermore, as shown in FIG. 33, a laser pointer 121o may be attached to aim.

In the above embodiment, the case where the safety cover 26 or 126 is made detachable has been described. However, the present invention is not limited to this, and as shown in FIG. 34, it can be opened and closed by a hinge (not shown). A connecting member 126f connected to a hinge (not shown) may be provided so that it can be opened and closed by the hinge (not shown).
Moreover, although the case where the safety cover 26 or 126 was made detachable was described in the above embodiment, the present invention is not limited to this, and the safety cover 26 or 126 may be slid sideways.

In the first embodiment, xanthan gum (gelling agent) is added to the ink diluted with water, and the liquid diameter is adjusted according to the amount of addition, and the nozzle diameter is 1.5 mm to 3 mm. The case where the jetting material is jetted under the condition of the viscosity of 6 dPa · s to 40 dPa · s has been described.
The liquid propellant of the present invention is not limited to this. In the present invention, basically, as in the first embodiment, the case of water + action effect substance (such as ink) + gelling agent, and water + ethanol It is divided into the case of + active substance + gelling agent.

Hereinafter, the injection in this invention is demonstrated in detail.
First, the composition ratio in the case where the working effect substance is an edible dye and the solvent is only water and the composition ratio in the case of ethanol mixing will be examined.
(1) The basic requirements when the action-effect substance is an edible pigment will be described.
Since the gelling agent (sodium carboxymethylcellulose (hereinafter referred to as CMC)) and the food colorant are dissolved in water, a viscous propellant can be formed without mixing ethanol. In this case, the component composition requirements may be 1.3 wt% to 2.3 wt% of CMC, 0.01 wt% to 5 wt% of food coloring matter (action effect substance), and 92.7 wt% to 98.69 wt% of water. found.

(2) The advantages of mixing ethanol will be described.
Mixing ethanol produces the following advantages.
1) Decrease in freezing point Freezing point of ethanol: -117 ° C
2) Improvement of long-term storage stability Bactericidal effect by ethanol 3) Improvement of solvent volatility Because of the high volatility of ethanol, the effect of the effect substance after adhesion tends to appear more quickly.
4) Dispersion of water-soluble solid content (CMC, food coloring) In a state where the solid content is dispersed, water is added and dissolved to dissolve quickly.

The addition ratio of ethanol varies depending on the purpose (value) in the above 1) to 3).
On the other hand, in the above 4), there is a relationship with the manufacturing method of the injection, and it is as follows.
In the method for producing a propellant according to the present invention, when a water-soluble solid content (CMC, food coloring) is added to water or an aqueous ethanol solution, the solid content becomes a lump (Production Method 1 or Production Method 2 described later). It shows that efficiency is bad. As a method for avoiding this phenomenon, the water-soluble solid content is dispersed in ethanol and then water, which is a solvent for the water-soluble solid content, is added to dissolve the water-soluble solid content in a short time. The minimum mixing ratio of ethanol required to disperse the water-soluble solid content is the minimum composition ratio of ethanol when the solvent is an ethanol aqueous solution.
The minimum composition ratio of water-soluble solids is 1.3 wt% CMC and 0.01 wt% food color, and the ratio of ethanol required to disperse it in ethanol before adding water is the same as that of water-soluble solids. It was thought that it was necessary to have the same volume, and trial manufacture shown in Table 5 was performed.

※ＣＭＣ＋食用色素＝１．３ｇ＋０．０１ｇ≒２．５ｃｃ
２．５ｃｃ×０．７９ｇ／ｃｃ≒２．０ｇ

* CMC + food color = 1.3g + 0.01g ≒ 2.5cc
2.5cc × 0.79g / cc ≒ 2.0g

In Table 5, at level 2, the dispersion in ethanol was not sufficient and the dissolution time after adding water was long.
Therefore, the component composition requirements when the solvent is water and ethanol (dispersion medium) are as shown in Table 6.

※水の下限割合及びエタノールの上限割合は、後述する「エタノール水溶液の水とエタノールの割合検証」による

* The lower limit ratio of water and the upper limit ratio of ethanol are based on “Verification of ratio of water and ethanol in ethanol aqueous solution” described later.

Next, the composition ratio in the case where the working effect substance is ink or water-based fluorescent paint when the solvent is only water and the composition ratio in the case of alcohol mixing will be discussed.
(1) Basic requirements when the effect substance is ink or water-based fluorescent paint CMC and water-based fluorescent paint are soluble in water and insoluble in ethanol. Moreover, since the ink is dissolved in water and ethanol, a viscous propellant can be formed without mixing ethanol. In this case, the component composition requirements are CMC 1.3 wt% to 2.3 wt%, ink or water-based fluorescent paint (active effect substance) 1 wt% to 12 wt%, and water 85.7 wt% to 97.7 wt% by experiment. There was found.

(2) Advantage by mixing ethanol It is completely the same as the advantage by mixing ethanol mentioned above, The ratio was verified similarly. Table 7 shows.

※ＣＭＣ＋墨汁又は水性蛍光塗料＝１．３ｇ＋１ｇ≒３．５ｃｃ
３．５ｃｃ×約０．７９ｇ／ｃｃ≒２．８ｇ

* CMC + black ink or water-based fluorescent paint = 1.3g + 1g ≒ 3.5cc
3.5cc x about 0.79g / cc ≒ 2.8g

In Table 7, at level 2, the dispersion in ethanol was not sufficient and the dissolution time after adding water was long.
Therefore, the component composition requirements when the solvent is water and ethanol (dispersion medium) are as shown in Table 8.

※水の下限割合及びエタノールの上限割合は、後述する「エタノール水溶液の水とエタノールの割合検証」による

* The lower limit ratio of water and the upper limit ratio of ethanol are based on “Verification of ratio of water and ethanol in ethanol aqueous solution” described later.

Next, verification of the marking effect will be described.
(1) Since the viscous propellant to which 2-chloroacetophenone (hereinafter referred to as CN) is added as a lacrimatory component as an action-effect substance is colorless and transparent, after the propellant is ejected, the operator It was necessary to be able to judge whether it adhered. As a countermeasure, coloring means was used. In coloring, it is necessary to set the composition ratio, and similarly, the case of only food color not adding CN as an effect substance is also set.

When adding a marking effect to a viscous propellant, the addition ratio of food dyes to be added is verified.
A white target is placed 4 m ahead of the effective range of the portable liquid jetting device shown in this use example using a red food as a food coloring, and the ratio of the red food added is changed. From this, it was evaluated whether or not it could be visually confirmed whether or not it adhered.
A wide variety of colors and patterns can be considered as targets, but here we wanted to obtain the minimum necessary ratio of food coloring, so we decided to use a completely different white from the coloring.
The composition of the projectile at that time is as shown in Table 9.

評価結果の表し方は、付着したことを視認できたものを○、付着したことを視認できなかったものを×とした。
その結果を表１０に示す。

The evaluation result was expressed as “◯” when it was visually recognized that it was adhered, and “X” when it was not visually recognized that it was adhered.
The results are shown in Table 10.

As is clear from Table 10, all the three testers were able to visually recognize even the lowest 0.01 wt% tested this time.
Therefore, the lower limit of the addition ratio of the food coloring is 0.01 wt%.
On the other hand, when the upper limit is 3 wt% or more, there is no great difference in color strength, and it is economically not preferable to increase the amount of food color that is higher than that of an aqueous ethanol solution that is reduced when the amount of food color is increased.
Therefore, the upper limit of the addition ratio of the edible dye is 5 wt%, preferably 3 wt%.
(Reference: food red 40,000 yen / kg, CMC 4,000 yen / kg, ethanol aqueous solution 1,500 yen / kg)
Therefore, the addition ratio of the food coloring is 0.01 wt% to 5 wt%.

(2) The viscous propellant to which CN is added as a working effect substance was colorless and transparent. Therefore, it was necessary to be able to determine whether the operator adhered to the target object after the propellant was injected. It was. As a countermeasure, coloring means was used. In coloring, it is necessary to set the composition ratio, and similarly, it is also set only in the case of ink or water-based fluorescent paint without adding CN as an effect substance.
When a marking effect is added to a viscous jetted product, the addition ratio of black ink or water-based fluorescent paint to be added is verified.

A white target is placed 4 m ahead of the effective range of the portable liquid ejecting apparatus shown in this use example for the jet liquid in which the ink or water-based fluorescent paint (yellow) addition ratio is changed. It was evaluated whether or not it could be visually confirmed whether or not it adhered.
The target may be a wide variety of colors and patterns, but here, since the minimum required ratio of ink or water-based fluorescent paint is desired, it was set to be completely different from the pigment.
The composition of the projectile is as shown in Table 11.

The evaluation result was expressed as “◯” when it was visually recognized that it was adhered, and “X” when it was not visually recognized that it was adhered.
The results are shown in Table 12.

All three testers were able to see even the lowest 1.0 wt% tested this time.
Therefore, the lower limit of the addition ratio of black ink or water-based fluorescent paint is 1 wt%.
On the other hand, with respect to the upper limit value, 10 wt% or more is not much different in the color intensity, and if the ink or water-based fluorescent paint is increased, the amount of ink or water-based fluorescent paint whose unit price is higher than the ethanol aqueous solution to be reduced is not increased. Economically unfavorable.
Therefore, the upper limit of the addition ratio of black ink or water-based fluorescent paint is 12 wt%, preferably 10 wt%.
(Reference: Indian ink 1,800 yen / kg, aqueous fluorescent paint: 5,600 yen / kg, CMC 4,000 yen / kg, ethanol aqueous solution 1,500 yen / kg)
Therefore, the addition ratio of ink or water-based fluorescent paint is 1 wt% to 12 wt%.

Next, the amount of CN added when a tearing effect is added to a viscous propellant is verified.
One drop of the propellant with varying CN addition amount was attached to the human mucosa (tongue), and the time until irritation was sensed, the degree of irritation, and the time until irritation subsided were measured. When irritation was felt, it was washed away with water. Since the test with the eyeball is difficult, the test was performed on the tongue, which is a mucous membrane part and from which the ejected matter can be easily removed.
Table 13 shows the composition table of the test spray. The results are shown in Table 14.

Regardless of the amount of CN added, a strong irritation was felt as soon as it adhered (less than 1 second).
After the stimulus was sensed, it was washed away with water immediately, but it took time until the stimulus subsided. The greater the amount of CN added, the longer the recovery time.
From the above results, when the CN addition ratio is 0.1 wt%, the recovery time is short, but the sensing time and the degree of stimulation are sufficient, and this is the lower limit of the addition ratio (0 wt% is ineffective) .
In addition, regarding the upper limit of the CN addition ratio, commercially available tear sprays using CN are 1 wt% to 2 wt% (reference: Japan poisoning information center, HP for members, summary information on tears), If it is the lower limit of this, it will be considered that there is little influence on a human body, and 1 wt% was made into the upper limit.
Therefore, the CN addition amount was set to 0.1 wt% to 1 wt%.

Next, it verifies about the ratio of water and ethanol of ethanol aqueous solution.
First, the ratio of water and ethanol in an ethanol aqueous solution added to various (a tear solution, marking solution) viscous propellant is verified.
Therefore, the ratio of water and ethanol that can be produced by various viscous propellants (a to e) is obtained. Depending on the ratio of water and ethanol, CMC and action-effect substances (CN, food coloring, ink, water-based fluorescent paint) do not dissolve.
a: Viscous tear solution (CN added)
b: Viscous marking liquid (food colorant added)
c: Sexual marking liquid (addition of ink or water-based fluorescent paint)
d: Liquid with marking effect (addition of food coloring added) to viscous tear solution (CN added) e: Liquid with marking effect (ink ink or aqueous fluorescent paint added) added to viscous tear solution (CN added)

Explain the test results.
The ratio of water and ethanol that can produce various viscous sprays is shown. (Water + ethanol = 100 wt%)
FIG. 35 shows a: viscous lacrimal fluid (CN added) (CMC 1.3 wt% to 2.3 wt%, CN 0.1 wt% to 1 wt%, liquid temperature 20 ° C.).
CMC is soluble in water but insoluble in ethanol. CN is insoluble in water but soluble in ethanol.
For this reason, as is clear from FIG. 35, CMC is not completely dissolved when water is less than 54 wt%, and CN is not completely dissolved when water exceeds 61 wt%.
Further, when ethanol is less than 39 wt%, CN is not completely dissolved, and when it exceeds 46 wt%, CMC is not completely dissolved.
It was found that the ratios of water and ethanol for dissolving CMC and CN were 54 wt% to 61 wt% water and 39 wt% to 46 wt% ethanol.

FIG. 36 shows b: viscous marking liquid (food colorant added) (CMC 1.3 wt% to 2.3 wt%, food color 0.01 wt% to 5 wt%, liquid temperature 20 ° C.).
CMC is soluble in water but insoluble in ethanol. Food dyes are soluble in water and ethanol.
For this reason, as apparent from FIG. 36, CMC is not completely dissolved when water is less than 54 wt% or ethanol exceeds 46 wt%. Moreover, when ethanol was less than 2 wt%, CMC was not efficiently dissolved and it took time.
It was found that the ratio of water and ethanol for dissolving CMC and food coloring was 54 wt% to 98 wt% water and 2 wt% to 46 wt% ethanol.

FIG. 37 shows c: a viscous marking liquid (addition of ink or aqueous fluorescent paint) (CMC 1.3 to 2.3 wt%, ink or water fluorescent paint 1 wt% to 12 wt%, liquid temperature 20 ° C.).
CMC and water-based fluorescent paint are soluble in water but insoluble in ethanol. Ink is soluble in both water and ethanol.
For this reason, as shown in FIG. 37, when water is less than 54 wt% or ethanol exceeds 46 wt%, CMC and the aqueous fluorescent paint are not completely dissolved. Moreover, when ethanol was less than 2.8 wt%, CMC and the water-based fluorescent paint did not dissolve efficiently, and it took time.
It was found that the ratio of water and ethanol for dissolving CMC and ink or water-based fluorescent paint was 54 wt% to 97.2 wt% of water and 2.8 wt% to 46 wt% of ethanol.

FIG. 38 shows d: a solution obtained by adding a marking effect (addition of food coloring) to a viscous tear solution (CN addition) (CMC 1.3 wt% to 2.3 wt%, CN 0.1 wt% to 1 wt%, food coloring 0. (01 wt% to 5 wt%, liquid temperature: 20 ° C.).
CMC is soluble in water but insoluble in ethanol. CN is insoluble in water but soluble in ethanol. Food dyes are soluble in water and ethanol.
For this reason, as shown in FIG. 38, CMC will not melt | dissolve if water is less than 54 wt%, and CN will not melt | dissolve if it exceeds 61 wt%.
Further, when ethanol is less than 39 wt%, CN does not dissolve, and when it exceeds 46 wt%, CMC does not dissolve.
It was found that the ratios of water and ethanol for dissolving CMC and CN and food coloring were 54 wt% to 61 wt% water and 39 wt% to 46 wt% ethanol.

FIG. 39 shows e: a liquid obtained by adding a marking effect (inkbrush or water-based fluorescent paint addition) to a viscous tear solution (CN addition) (CMC: 1.3 wt% to 2.3 wt%, CN: 0.1 wt% to 1 wt%, black ink and water-based fluorescent paint: 1 wt% to 12 wt%, liquid temperature: 20 ° C.)
CMC and water-based fluorescent paint are soluble in water but insoluble in ethanol. CN is insoluble in water but soluble in ethanol. Ink is soluble in both water and ethanol.
For this reason, as shown in FIG. 39, CMC and the fluorescent paint do not dissolve when the water is less than 54 wt%, and CN does not dissolve when the water exceeds 61 wt%.
When ethanol is less than 39 wt%, CN does not dissolve, and when it exceeds 46 wt%, CMC and water-based fluorescent paint do not dissolve.
It was found that the ratios of water and ethanol for dissolving CMC and CN, ink, and aqueous fluorescent paint were 54 wt% to 61 wt% water and 39 wt% to 46 wt% ethanol.

Next, the wind resistance performance of the viscous projectile and the non-viscous projectile is verified.
For this purpose, as shown in FIG. 40, the target is placed at the tip of the position where the ejection device (portable liquid ejection device) is fixed indoors. A fan is installed diagonally behind the target, and the wind is sent to the spraying device. In the headwind, activate the spray device and verify that the spray is attached to the target.
In this test, the injection distance was 3 m and 4 m, and the wind speed was 3 m / s at the position of the injection device.
Table 15 shows the composition of the projectile.

The injection result is evaluated by ◯ × according to the state of attachment of the injection product to the target, and is shown in FIG. 41 and Table 16.
In FIG. 41, (a) shows the case of ◯: adhering in a circular shape, and (b) is adhering with x: dots. Or the case where it does not adhere is shown.

As shown in Table 16, when a non-viscous propellant is jetted in the head wind, it is diffused by the wind and does not adhere to the target.
Moreover, most of the projectiles are caused to flow toward the injector by the wind.
The viscous propellant adheres to the target without being diffused by the wind even when jetted in the head wind.
Therefore, it can be seen that the viscous jetted material has wind resistance and a longer injection distance.

Next, the ejection distance between the viscous tear liquid and the non-viscous tear liquid is verified (the ejection distance is verified by the CN intensity (index of arrival amount)).
Therefore, as shown in FIG. 42, a sampling container is installed at the tip of a position where the ejection device (portable liquid ejection device) is fixed indoors. The tear liquid is sprayed toward the sampling container, and the tear liquid is sampled (after the tear liquid is sprayed, the sampling container is immediately covered). The gas in the sampling container is analyzed by a gas chromatograph.
In this test, the sampling distance was 1 m, 2 m, 3 m, 4 m, and the sampling container size was 8 l (250 × W170 × H180 mm).
Table 17 shows the composition of the projectile.

As a result of the analysis, the waveform area of CN which is a tearing component in the sampling container was obtained. With this waveform area as the CN strength (an indicator of the amount reached), FIG. 43 shows the change in CN strength at each spray distance of viscous tear fluid and non-tear fluid.
Up to a spray distance of 3 m, both tear fluids have the same CN strength, but at 4 m, the CN strength of non-viscous tear fluid decreased by about 80 to 90%.
On the other hand, the viscous tear solution showed almost no decrease in CN strength even at 4 m.
Therefore, it was found that the jetting distance is longer in the case of a viscous jet.

Next, the manufacturing method of the injection thing concerning the present invention is explained.
Here, a method capable of easily producing a viscous propellant in a short time will be verified.
For the verification of the manufacturing method, from the following (1) to (7) viscous propellants, (1) a simple method for manufacturing a viscous tear solution is verified in a short time. The same manufacturing method is applied to the other spray liquids (2) to (7), and it is verified whether it can be manufactured in the same manner.
(1) viscous tear solution
(2) to (4) viscous marking fluid
(5)-(7) Liquid with marking effect added to viscous tear solution
Table 18 shows the compositions of the propellants (1) to (7).

Next, a manufacturing method will be described.
The production volume of viscous tear solution (1) is 400 ml, and three production methods are verified (working environment: 20 ° C.).
<Manufacturing method 1>
Ethanol is weighed, put into a container and stirred, and CN is weighed and put into it, stirred and dissolved. Water is weighed and added to it, and further stirred and mixed. Next, CMC is weighed, charged, heated to about 50 ° C. and stirred to dissolve the CMC to produce a spray.

<Manufacturing method 2>
Ethanol is weighed, put into a container and stirred, and CN is weighed and put into it, stirred and dissolved. On the other hand, water is weighed and put into a container, heated and stirred at about 50 degrees, and CMC is weighed and put therein, and stirred and dissolved. Next, the liquid in which CN is dissolved is dropped into and mixed with the liquid in which CMC is dissolved to produce a spray.
<Manufacturing method 3>
Ethanol is weighed, put into a container, and stirred, and CN and CMC are weighed and put into it, stirred, CN is dissolved, and CMC is dispersed. The water is weighed and charged, and further stirred to dissolve the CMC to produce a spray.
Table 19 shows a comparison of manufacturing methods.

As shown in Table 19, production method 3 was simple in a short time, and the injection product could be produced most efficiently.
Subsequently, the other injection products (2) to (7) were produced by the production method 3.
(2) to (4) A method for producing a viscous marking liquid is shown.
Ethanol is weighed and put into a container and stirred, and CMC, food coloring or ink or water-based fluorescent paint is weighed and charged into the container, and stirring, food coloring or ink or water-based fluorescent paint is dissolved and CMC is dispersed. The water is weighed and charged, and further stirred to dissolve the CMC to produce a spray.
(5) to (7) A method for producing a liquid in which a marking effect is added to a viscous tear solution.
Weigh ethanol, put in container, stir, weigh CMC, CN, food dye or ink or water fluorescent paint, stir, dissolve CN, food dye or ink or water fluorescent paint, disperse CMC To do. The water is weighed and charged, and further stirred to dissolve the CMC to produce a spray.

By the production method 3, the injections (1) to (3), (5) and (6) could be produced in the same manner as the injections (1).
However, it was not possible to produce a propellant to which the water-based fluorescent paints (4) and (7) were added.
The cause is that the acrylic resin of the water-based fluorescent paint is separated by ethanol, and it is necessary to change the order of introduction.
Then, the following manufacturing method <Manufacturing method 4> was verified as a manufacturing method of the injection liquid of (4) and (7).
<Manufacturing method 4>
In the application of production method 3, for the propellant of (4), ethanol is weighed, put into a container and stirred, and CMC is weighed and put therein, and stirred and CMC is dispersed. Water is then weighed and charged, and further stirred to dissolve CMC. Finally, the aqueous fluorescent paint is weighed, charged, and stirred to produce a spray.

Similarly, for the propellant of (7), ethanol is weighed, put into a container, stirred, and CMC and CN are weighed and put therein, stirred, CN is dissolved, and CMC is dispersed. Water is then weighed and charged, and further stirred to dissolve CMC. Finally, the aqueous fluorescent paint is weighed, charged, and stirred to produce a spray.
In the case of the production method 4, since the water-based fluorescent paint is finally stirred, the production time is increased by about 10 minutes compared to the production method 3. However, when using the water-based fluorescent paint, this production method is simple in a short time. Met.

Next, the relationship between the CMC ratio and the viscosity will be described.
An object of the present invention is to inject a projectile far away.
In the case of a conventional projectile, it is conceivable that the projectile is dispersed into small particles and receives a large air resistance as a reason why it cannot be ejected far.
As a solution, in the present invention, attention has been paid to suppressing the dispersion of the projectile by increasing the viscosity of the projectile.
The projectile is a liquid. About 90% or more of the components are water or an aqueous ethanol solution, each having a viscosity of about 0 dPa · s, and the problem cannot be solved as it is.
Therefore, a gelling agent was added to increase the viscosity.

First, it was confirmed how the viscosity changes according to the ratio of adding the gelling agent.
The result is the graph shown in FIG.
As the addition ratio of the gelling agent increased, the viscosity increased exponentially.
Then, the viscosity was increased and whether or not the projectile could be ejected far (whether or not) was evaluated using the confirmation criteria in the second embodiment according to the following criteria.
The case where it adhered to the circular shape shown in FIG.15 (C) evaluated that dispersion | distribution of the injection thing was suppressed.
The addition ratio of CMC, which is a result of good adhesion, is 1.3 wt% to 2.3 wt%, and the viscosity at that time is 6 dPa · s (20 ° C.) to 40 dPa · s (20 ° C.). I understood.

Next, a method for obtaining the characteristics of the injection according to the present invention will be described.
As shown in FIG. 45, the measuring apparatus receives the pressure from the pressure generating unit 300 that outputs the pressure profile of FIG. It includes a piston 302 that pushes out a jet that does not leak, and a single-hole straight nozzle / nozzle 303 with an inner diameter of 1.5 mm to 3 mm.
FIG. 46 shows a typical pressure profile of the pressure generator.
In FIG. 46, a pressure of 14 MPa or more is required in order to fly the ejected matter in the second embodiment of the present invention by 4 m. In addition, it is possible to change the pressure by changing the dose of the gas generating agent in accordance with the performance of flying the injection.
The said pressure profile was obtained from the injection apparatus 110 of 2nd embodiment. The pressure generator 300 is a non-explosive pyrotechnic gas generator in the cartridge.

Next, a measurement method will be described based on FIG.
First, a pressure sensor is attached to the side face of the initial piston position of the cartridge. Next, connect the pressure sensor to the oscilloscope. Next, the connector of the cartridge and the DC power source are connected by an electric wire. Next, the DC power supply is turned on and a predetermined current is applied. Next, a non-explosive pyrotechnic gas generator ignites and generates gas. Next, a pressure profile is obtained from the waveform of the oscilloscope.

DESCRIPTION OF SYMBOLS 1,100 Portable liquid injection apparatus 10,110 Injection apparatus 11,111 Container 12,112 Liquid injection thing 13,113 Piston 14,114 Non-explosive pyrotechnic gas generator 14a, 114a Gas generation part 14k Cap 14o, 114o Holder 14n Wedge base 14j1, 14j2 Leg wire 16, 116 Nozzle part 16a, 116a Nozzle 17 Adapter 17c Piston receiving surface 17d Pressure release groove 18 Seal 20, 120 Portable launcher 21A, 21B, 121A, 121B Case 22, 122 Attachment Parts 22a, 22b socket assembly parts 22c, 22d sockets 23, 123 power supply parts 23a, 123a batteries 24, 124 switch parts 24a, 124a switches 25, 125 power supply circuit boards 28, 128 insertion holes 111e pressure release parts 114k wires Mount plug 121g release button 121y window 122a, 122b wire mount socket

Claims (12)

In the projectile ejected from the ejection device,
The propellant is composed of water, an action effect substance, and a gelling agent. In the projectile ejected from the ejection device,
The propellant is composed of water, ethanol, an action effect substance, and a gelling agent. In the projectile according to claim 1 or 2,
The injection device includes: a container that fills the propellant; a piston that presses the propellant to inject the propellant from the container; and a non-explosive pyrotechnic gas generator that generates a gas pressure that presses the piston And a nozzle part for ejecting the ejected matter pressed by the piston. In the projectile according to any one of claims 1 to 3,
The gelling agent is sodium carboxymethylcellulose, xanthan gum, guar gum, pectin, carrageenan, tamarind gum or propylene glycol. In the projectile according to any one of claims 1 to 4,
The action effect substance is a tearing component or a colorant. The propellant according to claim 5, wherein
The propellant component is 2-chloroacetophenone, capsaicin, chili extract or allyl isothiocyanate. The propellant according to claim 5, wherein
The colorant is a food coloring, ink, or water-based fluorescent paint. In the projectile according to any one of claims 1 to 7,
The propellant contains 1.3 wt% to 2.3 wt% of the gelling agent and has a viscosity of 6 dPa · s to 40 dPa · s. In the projectile according to claim 1 or claims 3 to 8,
The propellant is composed of 85.7 wt% to 98.69 wt% of the water, 1.3 wt% to 2.3 wt% of the gelling agent, and 0.01 wt% to 12.0 wt% of the action effect substance. A projectile characterized by In the projectile according to any one of claims 2 to 9,
The propellant includes an ethanol aqueous solution of 84.7 wt% to 98.59 wt% composed of 54.0 wt% to 61.0 wt% of the water and 39.0 wt% to 46.0 wt% of the ethanol; A propellant comprising 3 wt% to 2.3 wt% and the action effect substance 0.01 wt% to 12.0 wt%. In the manufacturing method of the injection thing in any one of Claims 2 thru / or 10,
Stirring the ethanol into the container, stirring, charging the active substance and the gelling agent, stirring, dissolving the active substance, dispersing the gelling agent, then charging the water, Stirring and dissolving the said gelling agent. The manufacturing method of the projectile characterized by the above-mentioned. In the manufacturing method of the injection thing in any one of Claims 2 thru / or 10,
Put the ethanol into a container, stir, add the gelling agent, stir, disperse the gelling agent, then add the water, stir, dissolve the gelling agent, and finally The water-based fluorescent paint is added to and stirred.

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