JP2002062092A - Tear spray and tear solution for burglar repulse - Google Patents
Tear spray and tear solution for burglar repulseInfo
- Publication number
- JP2002062092A JP2002062092A JP2000250084A JP2000250084A JP2002062092A JP 2002062092 A JP2002062092 A JP 2002062092A JP 2000250084 A JP2000250084 A JP 2000250084A JP 2000250084 A JP2000250084 A JP 2000250084A JP 2002062092 A JP2002062092 A JP 2002062092A
- Authority
- JP
- Japan
- Prior art keywords
- tear
- spray
- ethanol
- solution
- extract
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Description
【0001】[0001]
【発明の属する技術分野】本発明は、非常時の痴漢撃墜
や護身のために使用する防犯用催涙スプレー及び催涙水
溶液に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a tear spray for crime prevention and an aqueous tear tear solution used for shooting down or protecting a molester in an emergency.
【0002】[0002]
【従来の技術】元来、軍用や警備用として使用されてい
たCNガス(クロロアセトフェノン)、CSガス(オー
ズクローロベンザローマローノニトリール)等が、民間
用として痴漢撃墜用又は護身用の防犯用催涙スプレーの
成分として使用されてきた。また、赤唐辛子の抽出液を
主成分とするOCガス(オレオレシン・カプシウム)も
使用されている。2. Description of the Related Art CN gas (chloroacetophenone) and CS gas (oise chlorobenzaromarononitrile), which were originally used for military and security purposes, are used for civilian crimes for killing or molesting molesters. It has been used as an ingredient in tear sprays. In addition, OC gas (oleoresin / capsium) mainly containing an extract of red pepper is also used.
【0003】[0003]
【発明が解決しようとする課題】しかるに、これら催涙
ガスはガス状で放射するため放射距離が短く、離れた場
所からは暴漢の顔面を狙いにくく、また屋外では風によ
る影響を受けやすく、風向きによってはスプレー実施者
側へ逆流することがあった。とくにCSガスは生物化学
的作用が大きく、暴漢に対し大量に吹き付けると呼吸器
障害や皮膚炎症などの後遺症の危険がある。これに対
し、赤唐辛子の抽出液を主成分とする催涙ガスは暴漢に
対し後遺症の危険はないが、この赤唐辛子の抽出液では
その抽出薬品にエタノール等水溶性の可燃物が使用され
ていて燃焼性がある為、携帯するスプレー容器そのもの
が火気厳禁で危険性を持っていた。この対策として、赤
唐辛子のエタノール抽出液のアルコール濃度を、引火点
を高めるまで水で希釈すればよいが、水で希釈するだけ
では溶解度が落ちて唐辛子抽出物が析出することを知見
した。However, since these tear gas emits in gaseous form, the radiation distance is short, it is difficult to aim at the face of a thug from a remote place, and it is easily affected by the wind outdoors. Sometimes flowed back to the sprayer. In particular, CS gas has a large biochemical effect, and when sprayed in large quantities against a thug, there is a danger of sequelae such as respiratory disorders and skin irritation. On the other hand, tear gas containing red pepper extract as a main component has no risk of sequelae against thugs, but in this red pepper extract, water-soluble combustibles such as ethanol are used as the extraction chemical. Because of the flammability, the spray container itself was dangerous because it was strictly prohibited from fire. As a countermeasure, it has been found that the alcohol concentration of the ethanol extract of red pepper may be diluted with water until the flash point is raised. However, it has been found that simply diluting with water lowers the solubility and precipitates the pepper extract.
【0004】本発明は、かかる知見に基づきなされたも
ので、唐辛子等のエタノール抽出液を成分とする催涙水
溶液において、該抽出液の引火点を上げて火災危険性を
低くし得るとともに、抽出物の析出を抑えることができ
て溶液安定化を図ることを目的とする。また本発明は、
離れた場所からでも効果的に攻撃できるように催涙水溶
液の飛距離をのばすことができ、また屋外でも風による
影響を受けにくくして逆風下でも使用可能にする防犯用
催涙スプレーを提供することを目的とする。The present invention has been made on the basis of this finding. In an aqueous tear solution containing an ethanol extract such as pepper, the flash point of the extract can be increased to reduce the risk of fire, and the extract The purpose of the present invention is to stabilize the solution by suppressing the precipitation of. The present invention also provides
To provide a tear spray for crime prevention, which can extend the flight distance of the tear water so that it can be effectively attacked even from a distant place, and is less susceptible to the wind even outdoors and can be used under headwinds Aim.
【0005】[0005]
【課題を解決するための手段】本発明の催涙水溶液は、
唐辛子やわさび等から催涙刺激物質をエタノールで抽出
したエタノール抽出液をアルコール濃度60v/v %未満
まで水で希釈するとともに界面活性剤を添加してなるこ
とに特徴を有するものである。この場合において、前記
エタノール抽出液は5〜40重量%、前記界面活性剤は
0.01〜3重量%を配合することが好ましい。The aqueous tear solution of the present invention comprises:
It is characterized in that an ethanol extract obtained by extracting a tear stimulating substance from pepper or wasabi with ethanol is diluted with water to an alcohol concentration of less than 60 v / v% and a surfactant is added. In this case, the ethanol extract is preferably 5 to 40% by weight, and the surfactant is preferably 0.01 to 3% by weight.
【0006】本発明の防犯用催涙スプレーは、上記の催
涙水溶液を充填したスプレー容器と、このスプレー容器
から催涙水溶液を棒状もしくは粗粒子状に放射するノズ
ルとを備えてあることに特徴を有するものである。A tear spray for crime prevention according to the present invention is characterized in that it comprises a spray container filled with the above-mentioned tear-water solution, and a nozzle for emitting the tear-water solution from the spray container in the form of rods or coarse particles. It is.
【0007】[0007]
【作用】上記催涙水溶液においてエタノール抽出液のア
ルコール濃度を60v/v %未満まで水で希釈すること
で、危険物関係法令上、非危険物にすることができる。
また、エタノール抽出液を水で希釈するときこれに界面
活性剤を添加することでその可溶化作用により抽出物の
溶解度を上げることができて抽出物の析出を抑えること
ができるに至った。By diluting the alcohol concentration of the ethanol extract in the aqueous tear solution with water to less than 60 v / v%, it can be made non-dangerous in accordance with laws and regulations relating to dangerous substances.
Further, when the ethanol extract is diluted with water, the solubility of the extract can be increased due to the solubilizing effect of adding a surfactant to the extract, and the precipitation of the extract can be suppressed.
【0008】上記構成の防犯用催涙スプレーによれば、
催涙水溶液の噴射方式として棒状もしくは粗粒子状に放
射することができるので、飛距離をのばすことができ、
離れた場所からでも攻撃できて身の安全を確保でき、ま
た風による影響を受けにくく、風向きによって逆流する
ことも無くなる。According to the tear spray for crime prevention of the above construction,
As it can be radiated in the form of rods or coarse particles as a method of spraying tear water, the flight distance can be extended,
It can be attacked from a distant place to ensure personal safety, is not easily affected by the wind, and does not flow backward due to the wind direction.
【0009】[0009]
【発明の実施の形態】本発明に係る催涙水溶液は、唐辛
子から辛味成分で催涙刺激物質であるカプサイシンをエ
タノールで抽出し、このエタノール抽出液をアルコール
濃度60v/v%未満、より好ましくは10〜20v/v %
まで水で希釈し、そこへ界面活性剤を添加して調合し
た。BEST MODE FOR CARRYING OUT THE INVENTION The aqueous tear solution according to the present invention extracts capsaicin, a tear-stimulating substance, as a pungent component from pepper with ethanol, and extracts the ethanol extract with an alcohol concentration of less than 60 v / v%, more preferably 10 to 10%. 20v / v%
Until diluted with water, and a surfactant was added thereto to prepare the mixture.
【0010】その際、エタノール抽出液は5〜40重量
%、より好ましく8〜20重量%、界面活性剤は0.0
1〜3重量%、より好ましく0.03〜0.1重量%を
配合する。エタノール抽出液が5重量%未満では催涙効
果が少なく、40重量%を越えると、増量による催涙効
果の上積みがなく、また引火危険性を増大することにな
る。界面活性剤が0.01重量%未満では抽出物の析出
を抑えることができない。界面活性剤が3重量%を越え
ると、経済的に不利であり、無駄である。In this case, the ethanol extract is 5 to 40% by weight, more preferably 8 to 20% by weight, and the surfactant is 0.0
1 to 3% by weight, more preferably 0.03 to 0.1% by weight is blended. If the amount of the ethanol extract is less than 5% by weight, the tearing effect is small, and if it exceeds 40% by weight, the tearing effect due to the increased amount is not added and the risk of ignition increases. If the amount of the surfactant is less than 0.01% by weight, precipitation of the extract cannot be suppressed. If the amount of the surfactant exceeds 3% by weight, it is economically disadvantageous and wasteful.
【0011】エタノール抽出液のアルコール濃度を60
v/v %未満まで水で希釈することで、危険物関係法令
上、非危険物とすることができ、さらに10〜20v/v
%まで希釈することで、より引火性を低くすることがで
きて更に安全性を高めることができる。The alcohol concentration of the ethanol extract is adjusted to 60
By diluting with water to less than v / v%, it can be made non-hazardous in accordance with dangerous goods laws and regulations, and 10 to 20 v / v
%, The flammability can be further reduced and the safety can be further improved.
【0012】界面活性剤には、ノニオン系(例えば、三
洋化成工業(株)製 ノニポールシリーズ)、カチオン
系(例えば、ライオン(株)製 アロモックスシリー
ズ)、アニオン系(例えば、花王(株)製 エマールシ
リーズ)、あるいは両性系(例えば、花王(株)製 ア
ンヒトールシリーズ)を用いる。エタノール抽出液のア
ルコール濃度を水で希釈するときこれら界面活性剤を添
加すると、その可溶化作用により抽出物の溶解度を上げ
ることができ、抽出物の析出を抑えることができた。Surfactants include nonionic surfactants (for example, Nonipol series manufactured by Sanyo Chemical Industries, Ltd.), cationic surfactants (for example, Aromox series manufactured by Lion Corporation), and anionic surfactants (for example, Kao Corporation) (Emar series manufactured by Kao Corporation) or an amphoteric system (for example, Amphitol series manufactured by Kao Corporation). When these surfactants were added when diluting the alcohol concentration of the ethanol extract with water, the solubility of the extract could be increased by its solubilizing action, and the precipitation of the extract could be suppressed.
【0013】唐辛子以外の、例えばわさび、からし、カ
レー粉、こしょう等の無毒性植物からも催涙刺激物質を
エタノールで抽出することができる。わさびはイソチオ
シアン酸アリル+イソチオシアン酸ブチル、からしはイ
ソチオシアン酸アリル、カレー粉は多成分混合、こしょ
うはアルカロイド,ピペジン,チャビシンが、それぞれ
催涙成分となる。Tear stimulants can also be extracted with ethanol from non-toxic plants other than pepper, such as wasabi, mustard, curry powder and pepper. Wasabi is allyl isothiocyanate + butyl isothiocyanate, mustard is allyl isothiocyanate, curry powder is a multi-component mixture, and pepper is alkaloid, pipedine, and chavicin.
【0014】上記の催涙水溶液は、図1に示すごときス
プレー容器1に充填するが、このスプレー容器1の上部
に取り付けられる周知の直圧式等の噴射装置2にはヘッ
ド部材3を押圧操作することにより催涙水溶液を吸い上
げて棒状(直線状)もしくは粗粒子状に放射させること
のできるノズル4を備える。ノズル4より催涙水溶液を
棒状もしくは粗粒子状に放射させることにより、催涙水
溶液の飛距離をのばすことができ、また逆風下での使用
も可能であり、とくに離れた場所や屋外での痴漢撃墜や
護身に有用である。The above-mentioned aqueous solution for tearing is filled in a spray container 1 as shown in FIG. The nozzle 4 is capable of sucking up the tear water solution and emitting it in the form of a rod (linear) or coarse particles. By irradiating the aqueous tear solution from the nozzle 4 in the form of rods or coarse particles, the flight distance of the aqueous tear solution can be extended, and it can also be used under headwinds. Useful for self-defense.
【0015】[0015]
【発明の効果】本発明の催涙水溶液によれば、エタノー
ル抽出液の火災危険性を低くし得ながら抽出物の析出を
抑えることができて溶液安定化を図ることができる。ま
た本発明の防犯用催涙スプレーによれば、催涙水溶液に
よる上記効果のほかに催涙水溶液の飛距離をのばすこと
ができ、また風による影響も受けにくくて離れた場所や
屋外での暴漢撃墜や護身用などに有効である。According to the aqueous tear water solution of the present invention, precipitation of the extract can be suppressed while the risk of fire of the ethanol extract can be reduced, and the solution can be stabilized. According to the tear spray for crime prevention of the present invention, in addition to the above-mentioned effects of the tear-water solution, the flight distance of the tear-water solution can be extended, and it is hardly affected by the wind, so that a thug can be shot down or protected in a distant place or outdoors. It is effective for use.
【図1】防犯用催涙スプレーの側面図である。FIG. 1 is a side view of a security tear spray.
1 スプレー容器 2 噴射装置 3 ヘッド部材 4 ノズル DESCRIPTION OF SYMBOLS 1 Spray container 2 Injection device 3 Head member 4 Nozzle
Claims (4)
タノールで抽出したエタノール抽出液をアルコール濃度
60v/v %未満まで水で希釈するとともに、界面活性剤
を添加してなることを特徴とする催涙水溶液。1. A tear-forming method characterized by diluting an ethanol extract obtained by extracting a tear-stimulating substance from pepper or wasabi with ethanol to water to an alcohol concentration of less than 60 v / v% and adding a surfactant. Aqueous solution.
%、前記界面活性剤が0.01〜3重量%配合されてい
る請求項1記載の催涙水溶液。2. The aqueous tear solution according to claim 1, wherein the ethanol extract is contained in an amount of 5 to 40% by weight and the surfactant is incorporated in an amount of 0.01 to 3% by weight.
スプレー容器と、このスプレー容器から前記催涙水溶液
を棒状もしくは粗粒子状に放射するノズルとを備えた防
犯用催涙スプレー。3. A tear spray for crime prevention, comprising: a spray container filled with the tear water solution according to claim 1; and a nozzle for radiating the tear water solution from the spray container into a stick or coarse particles.
スプレー容器と、このスプレー容器から前記催涙水溶液
を棒状もしくは粗粒子状に放射するノズルとを備えた防
犯用催涙スプレー。4. A tear spray for crime prevention, comprising: a spray container filled with the tear water solution according to claim 2; and a nozzle for emitting the tear water solution from the spray container in the form of rods or coarse particles.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2000250084A JP2002062092A (en) | 2000-08-21 | 2000-08-21 | Tear spray and tear solution for burglar repulse |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2000250084A JP2002062092A (en) | 2000-08-21 | 2000-08-21 | Tear spray and tear solution for burglar repulse |
Publications (1)
Publication Number | Publication Date |
---|---|
JP2002062092A true JP2002062092A (en) | 2002-02-28 |
Family
ID=18739720
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2000250084A Withdrawn JP2002062092A (en) | 2000-08-21 | 2000-08-21 | Tear spray and tear solution for burglar repulse |
Country Status (1)
Country | Link |
---|---|
JP (1) | JP2002062092A (en) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2009186161A (en) * | 2008-02-05 | 2009-08-20 | Kenichi Kobayashi | Lacrimatory skin stimulating spray sealed in spray can together with carbon dioxide, by mixing (1) industrial ethanol as solvent, (2) solution of extracting extract and pigment of red pepper by soaking powdered red pepper in industrial ethanol and (3) chloroacetophenone (cas registered number:532-27-4) |
JP2011106765A (en) * | 2009-11-19 | 2011-06-02 | Nippon Koki Co Ltd | Injecting object and method of manufacturing the same |
JP2011184014A (en) * | 2010-03-11 | 2011-09-22 | Japan Steel Works Ltd:The | Device and method of defending vessel at sea |
WO2019112112A1 (en) * | 2017-12-08 | 2019-06-13 | 주식회사 움트리 | Method for extracting wasabi extract |
-
2000
- 2000-08-21 JP JP2000250084A patent/JP2002062092A/en not_active Withdrawn
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2009186161A (en) * | 2008-02-05 | 2009-08-20 | Kenichi Kobayashi | Lacrimatory skin stimulating spray sealed in spray can together with carbon dioxide, by mixing (1) industrial ethanol as solvent, (2) solution of extracting extract and pigment of red pepper by soaking powdered red pepper in industrial ethanol and (3) chloroacetophenone (cas registered number:532-27-4) |
JP2011106765A (en) * | 2009-11-19 | 2011-06-02 | Nippon Koki Co Ltd | Injecting object and method of manufacturing the same |
JP2011184014A (en) * | 2010-03-11 | 2011-09-22 | Japan Steel Works Ltd:The | Device and method of defending vessel at sea |
WO2019112112A1 (en) * | 2017-12-08 | 2019-06-13 | 주식회사 움트리 | Method for extracting wasabi extract |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
A300 | Withdrawal of application because of no request for examination |
Free format text: JAPANESE INTERMEDIATE CODE: A300 Effective date: 20071106 |