JP2011067132A - Method for producing tofu-like food product - Google Patents

Method for producing tofu-like food product Download PDF

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JP2011067132A
JP2011067132A JP2009220619A JP2009220619A JP2011067132A JP 2011067132 A JP2011067132 A JP 2011067132A JP 2009220619 A JP2009220619 A JP 2009220619A JP 2009220619 A JP2009220619 A JP 2009220619A JP 2011067132 A JP2011067132 A JP 2011067132A
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tofu
freezing
soymilk
coagulation
producing
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Shoji Kaneko
昌二 金子
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Nagano Prefecture
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Abstract

<P>PROBLEM TO BE SOLVED: To provide a method for producing a Tofu (bean curd)-like food product, not including performing the coagulation reaction of soybean milk with a coagulant by a thermal treatment, but including performing a freezing coagulation utilizing freezing. <P>SOLUTION: There are provided the method for producing a Tofu-like food product including adding crude seawater magnesium chloride, magnesium chloride, or calcium chloride as a Tofu coagulant to a soybean milk, in an amount of 0.01 to 0.3 (w/w%) based on the weight of the soybean milk, in such a concentration as not completely coagulating the mixture liquid, holding or heat-holding the obtained mixture liquid without coagulation, freezing the mixture liquid to once obtain the frozen product, and then thawing the frozen product to obtain the curdled product, wherein the conditions for holding or heat-holding the mixture liquid without coagulation are at a temperature range of 50 to 70°C for 5 to 20 minutes, wherein the obtained curdled product is compressed, dehydrated, and molded; and wherein the thickness of a shortest part in a packaged shape on the freezing treatment of the mixture liquid is 8 cm or less when produced in the packaged shape. <P>COPYRIGHT: (C)2011,JPO&INPIT

Description

本発明は、豆腐様食品の製造方法に関するものである。   The present invention relates to a method for producing a tofu-like food.

一般的な豆腐製造は、原料の丸大豆を水中で一夜程度浸漬し、その浸漬大豆を加水しながらグラインダー等の磨砕機で磨りつぶして磨砕物の呉とし、その呉を十分に加熱処理した後で豆乳とオカラに分離し、豆乳が70℃程度の際に塩化マグネシウムなどの豆腐用凝固剤を豆乳が凝固するに十分な量、例えば豆乳重量に対して0.3(w/w%)以上の量を添加して凝固させることで行われている。   In general tofu production, raw soy beans are soaked in water for about one night, and the soaked soybeans are hydrated and ground with a grinder such as a grinder. In soymilk and okara, when the soymilk is at about 70 ° C., a sufficient amount of the coagulant for tofu such as magnesium chloride to solidify the soymilk, for example, 0.3 (w / w%) or more based on the weight of the soymilk It is carried out by adding and solidifying.

また、豆乳を一旦よく冷却してから、塩化マグネシウムなどの豆腐用凝固剤を豆乳が凝固するに十分な量を混合してから包装容器に充填密封し、容器ごと70℃程度の加熱処理を行って凝固させる方法もあり、この方法によると包装容器と同じ形状の豆腐を製造することが可能となる。   Also, after cooling the soymilk well, mix a sufficient amount of coagulant for tofu such as magnesium chloride to solidify the soymilk, then fill and seal the packaging container, and heat the container at about 70 ° C. There is also a method of solidifying, and this method makes it possible to produce tofu having the same shape as the packaging container.

前記の方法は、いずれも70℃程度の熱を利用して豆乳中の蛋白質と凝固剤による凝固反応を行わせる方法であり、全体的に保水性のあるソフトな豆乳凝固物を得ることができる。   Each of the above methods is a method in which the heat of about 70 ° C. is used to cause the coagulation reaction between the protein in the soymilk and the coagulant, and a soft soymilk coagulated product having water retention as a whole can be obtained. .

一方、この方法とは別に、豆乳を凍結保存した後で解凍すると不溶化物の豆乳凝固物が得られることが知られており、非特許文献1並びに非特許文献2において凝固剤を用いない豆乳の凝固法として、110℃で3分間の加熱処理した6倍加水豆乳を−5℃で一旦予備冷却した後、−20℃で2週間の凍結保存後に解凍することで豆乳凍結ゲルが得られることが記載されている。   On the other hand, in addition to this method, it is known that when soymilk is frozen and then thawed, an insolubilized soymilk coagulum is obtained. In Non-Patent Document 1 and Non-Patent Document 2, soymilk without a coagulant is used. As a coagulation method, 6-fold hydrolyzed soymilk heated at 110 ° C. for 3 minutes is precooled at −5 ° C. and then frozen at -20 ° C. for 2 weeks to obtain a soymilk frozen gel. Are listed.

また、非特許文献3においては脱脂大豆から得た酸沈殿蛋白質を、大豆の5倍量の加水後にアルカリ溶解させて調製した、通常の豆乳とは性状の異なる大豆蛋白質溶液を用いて、凍結解凍後における不溶化物の生成条件や、その収量を増加させる方法について検討されている。   In Non-Patent Document 3, freeze-thawing was performed using a soy protein solution prepared by dissolving an acid-precipitated protein obtained from defatted soybeans with alkali after 5 times the amount of soybeans and then dissolving in alkali. The production conditions of the insolubilized material later and methods for increasing the yield have been studied.

すなわち、大豆蛋白質溶液の蛋白質濃度を高濃度(4%以上)にしてpH7程度とし、100℃で1分間程度の加熱処理を行って十分に冷却した後で、亜硫酸ナトリウムを1×10−5(モル/蛋白質g)や凝固剤の塩化カルシウムを2〜2.5×10−4(モル/蛋白質g)添加した後で、−20℃2時間の凍結処理を行い、−5℃で1日間凍結保管して解凍する方法などである。 That is, the protein concentration of the soy protein solution is set to a high concentration (4% or higher) to about pH 7, and after heat treatment at 100 ° C. for about 1 minute and sufficiently cooled, sodium sulfite is added to 1 × 10 −5 ( After adding 2 to 2.5 × 10 −4 (mol / protein g) of calcium chloride as a coagulant and mol / protein g), freeze treatment at −20 ° C. for 2 hours and freeze at −5 ° C. for 1 day For example, a method of storing and thawing.

下山田真:大豆タンパク質の加工特性(豆乳の凝固特性)、調理科学、40,37−40(2007)Makoto Shimoyamada: Soy protein processing characteristics (coagulation characteristics of soy milk), Cooking Science, 40, 37-40 (2007)

下山田真:大豆成分の複合相互作用による食品機能発現に関する基礎・応用研究、食科工、50,445−450(2003)Makoto Shimoyamada: Fundamental and applied research on food function expression by complex interaction of soybean components, Shokugan, 50, 445-450 (2003)

橋詰和宗ら:大豆蛋白質の低温処理による性状変化、日食工誌、21,136−145(1974)Hashizume Kazumune et al .: Changes in properties of soybean protein by low-temperature treatment, Journal of Solar Eclipse, 21, 136-145 (1974)

しかし、非特許文献1並びに非特許文献2にあるような豆腐用凝固剤を用いずに得られる豆乳凝固物は、その生成に要する凍結保管期間が2週間の長期間を要していることや、特許文献1にあるように90〜105度の温度域における2分間〜1時間の加熱処理により、凝固物が可溶化して豆乳の状態となるため、この凝固物を加熱調理する際には課題が生じる。   However, the soymilk coagulum obtained without using the tofu coagulant as described in Non-Patent Document 1 and Non-Patent Document 2 has a long freezing storage period of 2 weeks. As described in Patent Document 1, the heat treatment for 2 minutes to 1 hour in the temperature range of 90 to 105 degrees causes the coagulated product to be solubilized into a soy milk state. Challenges arise.

特許第4065909号Patent No. 4065909

そして、非特許文献3においては凍結解凍後における不溶化物の収量を増加させるために、亜硫酸ナトリウムなど豆腐用凝固剤以外の添加物を用いることや、十分に冷却した大豆蛋白質溶液に規定濃度の塩化カルシウムを添加した後で、そのまま凍結処理を行っているため、凍結直後乃至凍結保管1日程度の凍結物の解凍により得られる凝固物の形状は小さく、十分なものとはいえない。   In Non-Patent Document 3, in order to increase the yield of the insolubilized product after freeze-thawing, an additive other than a coagulant for tofu such as sodium sulfite is used, or a well-cooled soy protein solution is chlorinated at a specified concentration. Since the freezing treatment is performed as it is after adding calcium, the shape of the coagulated product obtained by thawing of the frozen material immediately after freezing to frozen storage for about 1 day is small and it cannot be said that it is sufficient.

本発明者は、上記の課題を解決することを目的とし、豆乳に豆腐用凝固剤を、豆乳を完全に凝固させない濃度で添加した後で、凝固させないように加熱処理を行い、その混合液を凍結処理して一旦凍結物とし、その凍結物を解凍することにより、短期間における凍結保管でも凝固物の大きさも大きくなり、加熱しても溶解しにくい豆乳凝固物が得られることを主な特徴とする豆腐様食品の製造方法を見出し、ここに本発明を完成するに至った。   The present inventor aims to solve the above-mentioned problems, and after adding the tofu coagulant to the soymilk at a concentration that does not completely coagulate the soymilk, heat treatment is performed so as not to coagulate the mixture. The main feature is that the frozen product is frozen once, and the frozen product is thawed to increase the size of the coagulated product even in a short period of freezing storage, and to obtain a soymilk coagulated product that is difficult to dissolve even when heated. As a result, the present invention has been completed.

すなわち、請求項1記載の本発明は、豆乳に豆腐用凝固剤の粗製海水塩化マグネシウム、若しくは塩化マグネシウム、若しくは塩化カルシウムを、豆乳重量に対して0.01〜0.3(w/w%)の範囲内で、豆乳を完全に凝固させない濃度で添加して混合液とし、凝固させずに保持若しくは加温保持した後で、その混合液を凍結処理して一旦凍結物とし、その凍結物を解凍して凝固物を得ることを特徴とする豆腐様食品の製造方法に係わるものである。   That is, in the present invention according to claim 1, the crude magnesium chloride, magnesium chloride, or calcium chloride as a coagulant for tofu is added to soy milk in an amount of 0.01 to 0.3 (w / w%) based on the weight of soy milk. Within the range of the above, soymilk is added at a concentration that does not completely coagulate to make a mixed solution, and after holding or warming without coagulating, the mixed solution is frozen to make a frozen product once. The present invention relates to a method for producing a tofu-like food characterized by thawing to obtain a solidified product.

また、請求項2記載の本発明は、請求項1記載の豆腐様食品の製造方法において混合液を凝固させずに保持若しくは加温保持する条件を、50〜70℃の温度域で5〜20分間とすることを特徴とする豆腐様食品の製造方法に係わるものである。   Further, in the present invention described in claim 2, the condition for holding or warming the mixed solution without solidifying in the method for producing a tofu-like food according to claim 1 is 5 to 20 in a temperature range of 50 to 70 ° C. The present invention relates to a method for producing a tofu-like food, characterized in that it is for minutes.

また、請求項3記載の本発明は、請求項1乃至2記載の豆腐様食品の製造方法において得られる凝固物を、圧搾、脱水処理して成型されることを特徴とする豆腐様食品の製造方法に係わるものである。   Further, the present invention described in claim 3 is a method for producing a tofu-like food, characterized in that the coagulum obtained by the method for producing a tofu-like food according to claim 1 or 2 is molded by pressing and dehydrating. It is related to the method.

また、請求項4記載の本発明は、請求項1乃至2記載の豆腐様食品の製造方法において包装形態を用いて製造する場合に、混合液の凍結処理する際の包装形状における最短部位の厚み幅を8cm以下とすることを特徴とする豆腐様食品の製造方法に係わるものである。   Further, the present invention according to claim 4 is the thickness of the shortest part in the packaging shape when the mixed solution is subjected to the freezing process when the packaging form is used in the method for producing the tofu-like food according to claims 1 to 2. The present invention relates to a method for producing a tofu-like food characterized by having a width of 8 cm or less.

本発明により、豆乳と凝固剤との凝固反応を加熱処理ではなく、凍結処理による凍結凝固を利用した豆腐様食品の製造が可能となる。   According to the present invention, it is possible to produce a tofu-like food that utilizes freezing and solidification by freezing treatment instead of heat treatment for the solidification reaction between soy milk and the solidifying agent.

凍結処理した後、解凍して得られる豆腐様食品の形状は、膜状の湯葉様な凝固物を主体とする寄せ豆腐に類似したもので、ホエー中では溶き卵様で従来の加熱凝固による豆腐とは性状が異なる特徴を持っている。そのような特徴を有する豆腐様食品は市場に普及されておらず、新規な豆腐様製品として流通を図ることが可能となる。   The shape of the tofu-like food obtained by thawing after freezing is similar to that of tofu mainly composed of membranous yuba-like coagulum. And have different characteristics. Tofu-like foods having such characteristics are not widely used in the market and can be distributed as new tofu-like products.

しかし、豆乳のみでは凍結直後乃至1日〜2日間の短期間における凍結保管で解凍した場合では、得られる凝固物の大きさは小さくて細かい不十分なものであり、口中で食感をほとんど感じられないものとなる。そのため、適度な大きさの凝固物を得るには凍結保管に数週間以上の長期間を要することになる。また、十分に冷却した豆乳に凝固剤を添加した場合でも、添加後に加熱を伴わない場合では、得られる凝固物の大きさは豆乳のみの場合とほぼ同様なものである。   However, in the case of soy milk alone, when frozen and thawed in a short period of 1 to 2 days immediately after freezing, the size of the obtained coagulum is small and fine and insufficient, and the mouth feels almost textured. It will not be possible. Therefore, it takes a long period of several weeks or more for freezing storage in order to obtain an appropriately sized coagulum. Further, even when a coagulant is added to sufficiently cooled soy milk, the size of the obtained coagulated product is almost the same as in the case of only soy milk when heating is not performed after the addition.

請求項1記載の発明は、豆乳に凝固剤の粗製海水塩化マグネシウム、若しくは塩化マグネシウム、若しくは塩化カルシウムを、豆乳重量に対して0.01〜0.3(w/w%)の範囲内で、豆乳を完全に凝固させない濃度で添加して混合液とし、凝固させずに保持若しくは加温保持処理をすることにより、解凍後に得られる凝固物は豆乳のみの場合よりも大きいものが得られることを特徴とする豆腐様食品の製造方法である。   In the invention of claim 1, crude seawater magnesium chloride, magnesium chloride, or calcium chloride as a coagulant is added to soymilk within a range of 0.01 to 0.3 (w / w%) based on the weight of soymilk. By adding soymilk at a concentration that does not completely coagulate to make a mixed solution, and holding or heating and holding without coagulation, the coagulated product obtained after thawing can be larger than that with only soymilk It is the manufacturing method of the tofu-like food characterized.

そして、請求項2記載の発明は、請求項1における豆乳の温度が50〜70℃であればそのままで5〜20分間の保持、50℃未満の温度であれば50〜70℃で5〜20分間の加熱処理を行うことであり、凍結直後乃至は1日〜2日間の短期間における凍結保管後の解凍処理でも、得られる凝固物は大きく適度な大きさのものとなり、そのソフトな食感を感じとることができることを特徴とする豆腐様食品の製造方法である。   And if the temperature of the soymilk in Claim 1 is 50-70 degreeC, the invention of Claim 2 will hold | maintain for 5-20 minutes as it is, if it is the temperature below 50 degreeC, it will be 5-20 at 50-70 degreeC. Heat treatment for a minute, and even after thawing treatment after freezing storage in a short period of 1 day to 2 days immediately after freezing, the resulting coagulum is large and of a moderate size, and its soft texture It is the manufacturing method of the tofu-like food characterized by being able to feel.

また、豆乳のみで凍結保管、解凍して得られる凝固物は、90℃以上の温度域における2分間以上の加熱処理により、凝固物が可溶化して豆乳の状態に戻ってしまうため、この凝固物を加熱調理して用いる場合には課題が生じてしまうが、本発明により得られる凝固物は、そのような加熱処理をしても豆乳のみの場合より可溶化が起こりにくく、凝固物を残存させることができる。   In addition, the coagulated product obtained by freezing storage and thawing with only soy milk is solubilized by soaking in a temperature range of 90 ° C. or higher for 2 minutes or more, so that the coagulated product returns to the state of soy milk. However, when the product is cooked and used, a problem arises, but the solidified product obtained by the present invention is less likely to be solubilized even with such a heat treatment than with soy milk alone, and the solidified product remains. Can be made.

そして、請求項1乃至2記載の発明により得られるホエー分を含む溶き卵様の豆腐様食品は非常にソフトな物性で、甘味や旨味を有し風味が良好なため、振り混ぜて軽く咀嚼しながら飲むこともでき、豆乳よりもサラリと喉越しが良いため、飲むことを可能とする新規な豆腐様食品として流通を図ることが期待される。   And the melted egg-like tofu-like food containing the whey content obtained by the inventions of claims 1 and 2 has very soft physical properties, sweetness and umami, and good flavor. It can be drunk while being smooth and has a smoother throat than soy milk, so it is expected to be distributed as a new tofu-like food that can be drunk.

また、請求項3記載の発明は、請求項1乃至2記載の豆腐様食品の製造方法において、凍結凝固により得られた湯葉様な形状を持つ凝固物を圧搾、脱水処理して成型することにより、湯葉を集めたようなモチモチ感のある弾力性に富んだ、従来の豆腐とは異なる新規な特徴を有する木綿豆腐様な豆腐様食品の製造方法である。   The invention according to claim 3 is a method for producing a tofu-like food according to claims 1 to 2, wherein a solidified product having a yuba-like shape obtained by freeze-coagulation is compressed and dehydrated and molded. This is a method for producing a tofu-like food such as cotton tofu that has new characteristics different from conventional tofu.

また、請求項4記載の発明は請求項1乃至2記載の豆腐様食品の製造方法において、包装形態を用いて製造する場合に、凍結や解凍処理を行い易くするため、混合液の凍結処理する際の包装形状における最短部位の厚み幅を8cm以下とすることを特徴とするものであり、この場合の例示として、プラスチック製の袋状容器等に包装密封して製造、流通を行うこともできるが、特にこれらに何ら限定されるものではない。   Further, the invention according to claim 4 is a method for producing a tofu-like food according to claims 1 to 2, wherein the mixture is subjected to a freezing treatment in order to facilitate freezing and thawing treatment when produced using a packaging form. In this case, the thickness width of the shortest part in the package shape is 8 cm or less. As an example in this case, the package can be sealed in a plastic bag-like container or the like, and can be manufactured and distributed. However, it is not particularly limited to these.

なお、解凍の際には、その処理時間を短縮させるために70℃以上の温湯での解凍処理を行うことが望ましいが、特にこの方法に何ら限定されるものではない。   When thawing, it is desirable to perform thawing treatment with hot water of 70 ° C. or higher in order to shorten the processing time, but it is not particularly limited to this method.

また、従来の豆腐は、凍結により滑らかな物性からスポンジ状のザラついた物性となり、食味が低減するために凍結保存には適していなかったが、本発明による豆腐様食品の製造方法では凍結状態での長期保存も可能となるため、凍結状態での流通を図ることも可能となり、また、凍結状態なので携帯性も良くなるため、例示すればクーラーバック等への保冷剤も兼ねた用途が期待でき、解凍後には豆腐様食品をそのまま、あるいは請求項3のようなホエー抜きをして従来の木綿豆腐に類似したものとしても食することが可能となる。   In addition, the conventional tofu is not suitable for cryopreservation because it has a spongy and rough physical property due to freezing due to freezing and the taste is reduced, but in the method for producing a tofu-like food according to the present invention, it is in a frozen state. It can be stored for a long time, so that it can be distributed in a frozen state, and since it is in a frozen state, it is easy to carry, so for example, it can be used as a cooling agent for a cooler bag. After thawing, it is possible to eat the tofu-like food as it is or as a food similar to conventional cotton tofu after removing whey as in claim 3.

また、請求項1〜4記載のいずれかの発明による豆腐様食品の製造方法では、従来の熱凝固による豆腐製造よりも凝固剤量を少なくして凝固物を得られるため、大豆そのものの味をより生かせた豆腐様食品が製造できることになり、広く社会に貢献するものである。   Further, in the method for producing a tofu-like food according to any one of claims 1 to 4, since the coagulant can be obtained by reducing the amount of the coagulant compared to the conventional tofu production by thermal coagulation, the taste of the soybean itself can be obtained. This makes it possible to produce more tofu-like foods that contribute to society.

次に、実施例により本発明を具体的に説明するが、本発明は以下の実施例によって何ら限定されるものではない。   EXAMPLES Next, although an Example demonstrates this invention concretely, this invention is not limited at all by the following Examples.

(実施例1)
1)豆乳の調製
丸大豆(平成20年度長野県産ナカセンナリ大豆)400gを水温15℃の水道水で16時間浸漬した。この浸漬大豆940gに加水量の全量が原料大豆の5倍量となるように水道水を1460g加水して、家庭用ミキサーで30秒間の粉砕処理を行い生呉とした。次に、生呉に加熱蒸気を直接吹き込みながら、品温95℃到達後3分間以上の加熱処理を行い、100メッシュ程度のナイロン製のこし布で手搾りにより、オカラを分離して豆乳を製造した。この豆乳のブリックス濃度は11%で、約1800gが得られた。
Example 1
1) Preparation of soy milk 400 g of whole soybeans (Nakasennari soybeans produced in Nagano Prefecture in 2008) was immersed in tap water at a water temperature of 15 ° C. for 16 hours. 1460 g of tap water was added to 940 g of this soaked soybean so that the total amount of water added was 5 times the amount of the raw soybean, and crushed for 30 seconds with a household mixer to obtain raw raw rice. Next, heating steam for 3 minutes or more after reaching the product temperature of 95 ° C. while directly blowing heated steam into the raw kure, and soy milk was produced by separating the okara by hand squeezing with a nylon cloth of about 100 mesh. . The soymilk had a Brix concentration of 11%, and about 1800 g was obtained.

製造された豆乳を氷水中による冷却で20℃以下に冷却したものを豆乳A、室温下でそのまましばらく放置して、約70℃になったものを豆乳Bとした。以下、特にこだわらな
い限り、これらの豆乳を用いて試験を行った。
The soymilk produced was cooled to 20 ° C. or lower by cooling with ice water, and left for a while at room temperature, and the soymilk B was about 70 ° C. Hereinafter, tests were conducted using these soy milks unless otherwise noted.

2)凝固物生成に及ぼす凝固剤添加と加熱処理の影響
豆乳Aを内径25cm×15cmのプラスチック製の袋に50g入れ、豆腐用凝固剤の粗製海水塩化マグネシウム(「塩田ニガリ液体」赤穂化成(株)製)を豆乳重量に対して0、0.1、0.3(w/w%)となるように添加して良く混合してから密封し、そのままで加熱処理をしないもの(未加熱)と、70℃で10分間加熱処理し氷水中で冷却したもの(加熱)とした。その後、−20℃で1日、2日、5日間の凍結保管を行った後、約70℃の湯中で解凍し、それぞれの豆乳凝固物の状態について検討した。得られた結果を表1に示す。
2) Effect of coagulant addition and heat treatment on coagulum formation 50 g of soy milk A is put into a plastic bag with an inner diameter of 25 cm × 15 cm, and crude magnesium seawater chloride (“Shioda Nigari Liquid” Ako Kasei Co., Ltd.) )) Is added to 0, 0.1, 0.3 (w / w%) with respect to the weight of soymilk, mixed well, sealed, and not heat-treated as it is (unheated) And heated at 70 ° C. for 10 minutes and cooled in ice water (heating). Then, after refrigerated storage at −20 ° C. for 1 day, 2 days, and 5 days, it was thawed in hot water at about 70 ° C., and the state of each soymilk coagulum was examined. The obtained results are shown in Table 1.

Figure 2011067132
Figure 2011067132

表1の結果より、凍結解凍処理による豆乳凝固物の生成は、豆乳のみの場合よりも凝固剤を添加したもの、そしてその添加量が多くなるほど進行することが確認された。なお、ニガリ0.3(w/w%)添加で70℃で10分間加熱処理したものは、凍結処理前ではゲル化には至っておらず、粘性の高い豆乳様の状態であった。   From the results in Table 1, it was confirmed that the production of the soymilk coagulated product by freeze-thawing treatment progressed as the amount of the coagulant added and the amount added increased more than in the case of soymilk alone. In addition, what was heat-processed at 70 degreeC for 10 minutes by bittern 0.3 (w / w%) addition did not reach gelling before freezing, but was a highly viscous soymilk-like state.

また、凝固剤添加後に加熱処理を行うことで凍結凝固による豆乳凝固物の生成が進行し、1日間の短期凍結保管でも適度で十分な凝固物が得られることが確認された。   In addition, it was confirmed that by performing heat treatment after the addition of the coagulant, soymilk coagulum was generated by freeze coagulation, and an adequate and sufficient coagulum was obtained even in short-term freezing storage for 1 day.

(実施例2)
1)凝固物生成に及ぼす凝固剤種類の影響
豆乳Aを内径25cm×15cmのプラスチック製の袋に100g入れ、凝固剤となる粗製海水塩化マグネシウム(ニガリ)、塩化マグネシウム6水和物(塩マグ)、塩化カルシウム2水和物(塩カル)、グルコノデルタラクトン(GDL)を、豆乳重量に対して0、0.3、0.5(w/w%)となるように添加して良く混合してから密封し、70℃で10分間加熱処理した。その後、氷水中で冷却し、−20℃で1日間の凍結保管を行った後、約70℃の湯中で解凍し、それぞれの凝固物の形状と味、物性について検討した。得られた結果を表2に示す。なお、一般に豆腐製造で用いられている硫酸カルシウム(すまし粉)は水溶性ではなく懸濁液となるため、冷却豆乳と混合する際には均一に混合しにくく、底部で凝固物が生成して好ましい結果を得られないため本試験では対象から除外した。
(Example 2)
1) Effect of type of coagulant on coagulated product production 100 g of soy milk A is placed in a plastic bag with an inner diameter of 25 cm × 15 cm, and crude seawater magnesium chloride (Nigari) and magnesium chloride hexahydrate (salt mug) that are used as coagulants. , Calcium chloride dihydrate (salt cal) and glucono delta lactone (GDL) are added to the weight of soy milk to 0, 0.3, 0.5 (w / w%) and mixed well. Then, it was sealed and heat-treated at 70 ° C. for 10 minutes. Then, after cooling in ice water and freezing storage at −20 ° C. for 1 day, it was thawed in hot water at about 70 ° C., and the shape, taste and physical properties of each coagulated product were examined. The obtained results are shown in Table 2. In general, calcium sulfate (sushi powder) used in tofu production is not water-soluble but becomes a suspension. When mixed with chilled soymilk, it is difficult to mix uniformly and a solidified product is formed at the bottom. In this study, it was excluded from the subject.

Figure 2011067132
Figure 2011067132

表2の結果のとおり、本試験においては凝固剤0%とニガリ0.3%を除く全てが加熱処理により全体がゲル化し凝固していた。凍結解凍処理後に得られた凝固物は、ゲル化しなかったニガリ0.3%ではソフトで滑らかな物性のある凝固物が得られたが、他の全体がゲル化したものでは、凍り豆腐様で物性はスポンジ感のあるものとなっていた。そのため、凍結凝固により豆乳凝固物を得る際には、凍結処理前に豆乳を決してゲル化させてはいけないことが確認された。   As shown in Table 2, in this test, all except the coagulant 0% and bittern 0.3% were gelled and solidified by heat treatment. The coagulated product obtained after freeze-thaw treatment had a soft and smooth physical property when the non-gelled bittern 0.3% was obtained, but the other gelled material was frozen tofu-like and had physical properties. Had a sponge feel. Therefore, when obtaining a soymilk coagulated product by freeze coagulation, it was confirmed that the soymilk should never be gelled before the freezing treatment.

また、味に関しては、粗製海水塩化マグネシウムと塩化マグネシウムでは甘味、塩化カルシウムでは旨味が感じられたのに対して、グルコノデルタラクトンでは酸味が感じられ好ましくなかった。そのため、GDLに関しては仮に添加量を下げ、解凍後にスポンジ状とならない凝固物を得たとしても、酸味の面で課題が生じるものと推測された。   In addition, regarding the taste, crude seawater magnesium chloride and magnesium chloride were unfavorable because sweet taste was felt in calcium chloride, whereas umami taste was felt in glucono delta lactone. For this reason, even if the amount of GDL added is reduced and a solidified product that does not become spongy after thawing is obtained, it is presumed that a problem arises in terms of acidity.

以上のことから、凝固剤としては粗製海水塩化マグネシウム、塩化マグネシウム、塩化カルシウムが適し、それらの豆乳への添加量は添加後の加熱処理で全体がゲル化しない濃度とする必要があり、本実施例では粗製海水塩化マグネシウムを除き、0.3%以下とすることが確認された。   Based on the above, crude seawater magnesium chloride, magnesium chloride, and calcium chloride are suitable as coagulants, and the amount added to the soymilk must be such that the whole does not gel by heat treatment after addition. In the example, it was confirmed that the content was 0.3% or less except for crude seawater magnesium chloride.

(実施例3)
1)凝固物生成に及ぼす加熱温度の影響
豆乳Aを内径25cm×15cmのプラスチック製の袋に100g入れ、塩化マグネシウム6水和物(塩マグ)を、豆乳重量に対して0、0.1、0.2、0.3(w/w%)となるように添加して良く混合してから密封し、50℃並びに70℃で10分間加熱処理した。その後、氷水中で冷却し、−20℃で1日間の凍結保管を行った後、約70℃の湯中で解凍し、それぞれの凝固物の形状について検討した。得られた結果を表3に示す。
(Example 3)
1) Effect of heating temperature on coagulum formation Soymilk A is put in 100 g in a plastic bag with an inner diameter of 25 cm × 15 cm, and magnesium chloride hexahydrate (salt mug) is added to 0, 0.1, The mixture was added to 0.2 and 0.3 (w / w%) and mixed well, sealed, and heat-treated at 50 ° C. and 70 ° C. for 10 minutes. Then, after cooling in ice water and performing freezing storage at −20 ° C. for 1 day, it was thawed in hot water at about 70 ° C., and the shape of each coagulum was examined. The obtained results are shown in Table 3.

Figure 2011067132
Figure 2011067132

表3には記載していないが、塩化マグネシウム濃度が0.2%では、50℃加熱で極一部分、70℃加熱で一部分がゲル化する場合があり、0.3%ではいずれの加熱温度でも全体的にゲル化し凝固が確認された。実施例2の結果のとおり、ゲル化したものを凍結解凍処理して得られる凝固物は、滑らかさが失われて凍り豆腐様のスポンジ感のあるものとなってしまうので好ましくなかった。そのため、本実施例の試験条件では塩化マグネシウム(6水和物)を0.2%以下とすることが望ましいことが確認された。   Although not described in Table 3, when the magnesium chloride concentration is 0.2%, a part of the gel may be gelated by heating at 50 ° C, and a part of the gel may be gelled by heating at 70 ° C. It was gelled as a whole and solidification was confirmed. As the result of Example 2, the solidified product obtained by freezing and thawing the gelled product was not preferable because it lost its smoothness and became a frozen tofu-like sponge. Therefore, it was confirmed that it is desirable to make magnesium chloride (hexahydrate) 0.2% or less under the test conditions of this example.

また、表3の結果のとおり、50℃よりも70℃加熱の方が凝固反応が起こりやすく、凝固剤が同一濃度でも加熱温度をより高温とする方がゲル化が進行することが確認された。そのため、ゲル化を遅らせるには加熱温度の低温化が望ましいが、低温すぎると凍結解凍後に得られる凝固物は形状が細かく不十分なものとなってしまうため好ましくない。また、加熱処理に要する時間も作業性やエネルギー面を考慮した場合に長時間は望ましくないため本実施例のように10分間程度が適当と推測されるが、これに限定されるものではなく、豆乳の温度やゲル化に留意して調整されるべきものである。   Further, as shown in Table 3, it was confirmed that the coagulation reaction was more likely to occur when heating at 70 ° C. than at 50 ° C., and that the gelation progressed when the heating temperature was higher even at the same concentration of the coagulant. . For this reason, it is desirable to lower the heating temperature in order to delay gelation. However, if the temperature is too low, the solidified product obtained after freezing and thawing is not preferable because the shape becomes fine and insufficient. In addition, the time required for the heat treatment is not desirable for a long time in consideration of workability and energy, so it is estimated that about 10 minutes is appropriate as in this embodiment, but is not limited thereto. It should be adjusted in consideration of the temperature and gelation of soymilk.

(実施例4)
1)凝固物生成に及ぼす塩化マグネシウム濃度の影響
豆乳Aを内径25cm×15cmのプラスチック製の袋に100g入れ、塩化マグネシウム6水和物(塩マグ)を、豆乳重量に対して0、0.02、0.05、0.1(w/w%)となるように添加して良く混合してから密封し、50℃並びに70℃で10分間加熱処理した。その後、氷水中で冷却し、−20℃で1日間の凍結保管を行った後、約70℃の湯中で解凍し、それぞれの凝固物の形状について検討した。得られた結果を表4に示す。
Example 4
1) Effect of Magnesium Chloride Concentration on Coagulation Product Soymilk A is put in 100 g in a plastic bag with an inner diameter of 25 cm × 15 cm, and magnesium chloride hexahydrate (salt mug) is 0, 0.02 based on the weight of soymilk. , 0.05 and 0.1 (w / w%) were added, mixed well, sealed, and heat-treated at 50 ° C. and 70 ° C. for 10 minutes. Then, after cooling in ice water and performing freezing storage at −20 ° C. for 1 day, it was thawed in hot water at about 70 ° C., and the shape of each coagulum was examined. Table 4 shows the obtained results.

Figure 2011067132
Figure 2011067132

表4には記載していないが、本実施例では凝固剤添加後の加熱処理後に全体がゲル化した試験区はなかった。塩化マグネシウムの添加量が0.02%の場合、50℃加熱では得られる凝固物の形状が小さく、70℃加熱ではそれよりやや大きいものが得られ、0.05%の50℃加熱とほほ同様であった。0.05%の70℃加熱並びに0.1%添加では形状の適度な凝固物が得られ、物性もソフト感のある滑らかで良好なものが得られた。これらの結果から塩化マグネシウム(6水和物)の豆乳重量に対する最適な添加量は0.05〜0.1(w/w%)とすることができるが、これに限定されるものではなく添加する豆乳の性状等に留意して調整されるべきものである。   Although not described in Table 4, in this example, there was no test section in which the whole gelled after the heat treatment after the addition of the coagulant. When the amount of magnesium chloride added is 0.02%, the shape of the solidified product obtained is small when heated at 50 ° C, and slightly larger than 70 ° C when heated at 70 ° C. there were. When heated at 70 ° C. of 0.05% and added at 0.1%, a solid coagulate having an appropriate shape was obtained, and a smooth and good physical property with a soft feeling was obtained. From these results, the optimum addition amount of magnesium chloride (hexahydrate) with respect to the weight of soy milk can be 0.05 to 0.1 (w / w%), but is not limited thereto and is added. It should be adjusted in consideration of the properties of soy milk.

(実施例5)
塩化マグネシウムを用いた際の添加後の加熱方法の検討
1)冷却豆乳による凍結処理前の加熱方法の検討(試験1)
豆乳Aを内径14cm×10cmのプラスチック製の袋に100g入れ、塩化マグネシウム6水和物(塩マグ)を、豆乳重量に対して0、0.02、0.05、0.1、0.2(w/w%)となるように添加して良く混合してから密封し、70℃で10分間加熱処理した。その後、氷水中で冷却し、−20℃で1日間の凍結保管を行った後、約70℃の湯中で解凍し、それぞれの凝固物の性状について検討した。得られた結果を表5に示す。
(Example 5)
Examination of heating method after addition when using magnesium chloride 1) Examination of heating method before freezing treatment with chilled soymilk (Test 1)
100 g of soy milk A is put in a plastic bag having an inner diameter of 14 cm × 10 cm, and magnesium chloride hexahydrate (salt mug) is added to the weight of soy milk at 0, 0.02, 0.05, 0.1, 0.2. (W / w%) was added and mixed well, sealed, and heat-treated at 70 ° C. for 10 minutes. Then, after cooling in ice water and freezing storage at −20 ° C. for 1 day, it was thawed in hot water at about 70 ° C., and the properties of each coagulated product were examined. The results obtained are shown in Table 5.

2)温豆乳による凍結処理前の加熱方法の検討(試験2)
豆乳Bを内径14cm×10cmのプラスチック製の袋に100g入れ、塩化マグネシウム6水和物(塩マグ)を、豆乳重量に対して0、0.02、0.05、0.1、0.2
(w/w%)となるように添加して良く混合してから密封し、そのままの状態(約70℃)で10分間保持した。その後、氷水中で冷却し、−20℃で1日間の凍結保管を行った後、約70℃の湯中で解凍し、それぞれの凝固物の性状について検討した。得られた結果を表5に示す。
2) Examination of heating method before freezing with warm soymilk (Test 2)
100 g of soy milk B is put in a plastic bag having an inner diameter of 14 cm × 10 cm, and magnesium chloride hexahydrate (salt mug) is added to the weight of soy milk at 0, 0.02, 0.05, 0.1, 0.2.
(W / w%) was added and mixed well, sealed, and kept in that state (about 70 ° C.) for 10 minutes. Then, after cooling in ice water and freezing storage at −20 ° C. for 1 day, it was thawed in hot water at about 70 ° C., and the properties of each coagulated product were examined. The results obtained are shown in Table 5.

Figure 2011067132
Figure 2011067132

表5の結果のとおり、冷却豆乳を用いて加熱処理する方法と温豆乳を用いて保持する方法により得られる凝固物は類似しており、どちらの方法を用いても可能であることが確認された。作業性やエネルギー面を考慮すると温豆乳を用いる方法が適しているが、ゲル化防止への対応のし易さや作業上の都合等を考慮した場合、どちらの方法で行っても良く、特に限定されるものではない。   As shown in Table 5, the coagulation obtained by the method of heat treatment using cooled soymilk and the method of holding using warm soymilk are similar, and it was confirmed that either method can be used. It was. In consideration of workability and energy, the method using warm soy milk is suitable, but considering the ease of handling for gelation prevention and work convenience, either method can be used, especially limited Is not to be done.

(実施例6)
塩化カルシウムを用いた際の添加濃度と添加後の加熱方法の検討
1)冷却豆乳による凍結処理前の加熱方法の検討(試験1)
豆乳Aを内径14cm×10cmのプラスチック製の袋に100g入れ、塩化カルシウム2水和物(塩カル)を、豆乳重量に対して0、0.01、0.02、0.05、0.1(w/w%)となるように添加して良く混合してから密封し、70℃で10分間加熱処理した。その後、氷水中で冷却し、−20℃で1日間の凍結保管を行った後、約70℃の湯中で解凍し、それぞれの凝固物の性状について検討した。得られた結果を表6に示す。
(Example 6)
Examination of the addition concentration when using calcium chloride and the heating method after addition 1) Examination of the heating method before freezing treatment with chilled soymilk (Test 1)
100 g of soy milk A is put into a plastic bag having an inner diameter of 14 cm × 10 cm, and calcium chloride dihydrate (salt cal) is added to the weight of soy milk at 0, 0.01, 0.02, 0.05, 0.1 (W / w%) was added and mixed well, sealed, and heat-treated at 70 ° C. for 10 minutes. Then, after cooling in ice water and freezing storage at −20 ° C. for 1 day, it was thawed in hot water at about 70 ° C., and the properties of each coagulated product were examined. The results obtained are shown in Table 6.

2)温豆乳による凍結処理前の加熱方法の検討(試験2)
豆乳Bを内径14cm×10cmのプラスチック製の袋に100g入れ、塩化カルシウム2水和物(塩カル)を、豆乳重量に対して0、0.01、0.02、0.05、0.1(w/w%)となるように添加して良く混合してから密封し、そのままの状態(約70℃)で10分間保持した。その後、氷水中で冷却し、−20℃で1日間の凍結保管を行った後、約70℃の湯中で解凍し、それぞれの凝固物の性状について検討した。得られた結果を表6に示す。
2) Examination of heating method before freezing with warm soymilk (Test 2)
100 g of soy milk B is put in a plastic bag having an inner diameter of 14 cm × 10 cm, and calcium chloride dihydrate (salt cal) is added to the weight of soy milk at 0, 0.01, 0.02, 0.05, 0.1 (W / w%) was added and mixed well, sealed, and kept in that state (about 70 ° C.) for 10 minutes. Then, after cooling in ice water and freezing storage at −20 ° C. for 1 day, it was thawed in hot water at about 70 ° C., and the properties of each coagulated product were examined. The results obtained are shown in Table 6.

Figure 2011067132
Figure 2011067132

表6の結果のとおり、実施例5の塩化マグネシウムと同様に、冷却豆乳を用いて加熱処理する方法と温豆乳を用いて保持する方法により得られる凝固物は類似しており、どちらの方法を用いても可能であることが確認された。   As in the results of Table 6, like the magnesium chloride of Example 5, the coagulum obtained by the method of heat treatment using cooled soymilk and the method of holding using warm soymilk are similar. It was confirmed that it was possible to use it.

なお、0.02%並びに0.05%添加では適度な形状の凝固物が得られ、物性もソフト感のある滑らかな良好なものが得られた。これらから塩化カルシウム(2水和物)の豆乳重量に対する最適な添加量は0.02〜0.05(w/w%)とすることができるが、これに限定されるものではなく、添加する豆乳の性状等に留意して調整されるべきものである。   When 0.02% and 0.05% were added, an appropriately shaped coagulated product was obtained, and a smooth and good physical property with a soft feeling was obtained. From these, the optimum addition amount of calcium chloride (dihydrate) with respect to the weight of soy milk can be 0.02 to 0.05 (w / w%), but is not limited thereto, and is added. It should be adjusted with attention to the properties of soy milk.

(実施例7)
1)凍結解凍処理凝固物の加熱処理後の影響
実施例5並びに実施例6で得られた凝固物を100mlビーカー中へ移して、沸騰水中で約20分間の加熱処理を行い、加熱後の凝固物の形状について検討した。それらの結果を表7に示す。
(Example 7)
1) Influence after heat treatment of freeze-thawed coagulated product The coagulated product obtained in Example 5 and Example 6 was transferred into a 100 ml beaker, subjected to heat treatment in boiling water for about 20 minutes, and coagulated after heating. The shape of the object was examined. The results are shown in Table 7.

Figure 2011067132
Figure 2011067132

表7の結果のとおり、凝固剤0%の時は加熱後に凝固物は全て完全に溶解し、豆乳の状態となった。塩化マグネシウムの場合の凝固物は、0.02%では大部分が溶解し、0.05%では一部が溶解し凝固物が微細化し、0.1%では溶解は起こらず適度な大きさを維持し、0.2%でも溶解は起こらなかった。   As shown in Table 7, when the coagulant was 0%, all the coagulated product was completely dissolved after heating and became soy milk. In the case of magnesium chloride, most of the coagulum dissolves at 0.02%, part of it dissolves at 0.05% and the coagulum becomes finer, and at 0.1%, the coagulation does not occur and has an appropriate size. And no dissolution occurred at 0.2%.

また、塩化カルシウムの場合の凝固物は、0.01%では大部分が溶解し、0.02%
では一部が溶解し凝固物が微細化し、0.05%では溶解は起こらず適度な大きさを維持し、0.1%でも溶解は起こらなかった。
In the case of calcium chloride, most of the coagulum dissolves at 0.01%, and 0.02%
Then, a part was dissolved and the coagulated material was refined, and at 0.05%, dissolution did not occur and an appropriate size was maintained, and even at 0.1%, dissolution did not occur.

このように凝固剤を添加することで、凝固物の加熱による溶解を抑制することが確認された。加熱後でも溶解せず適度な大きさの凝固物が維持できる豆乳重量に対する添加量は、塩化マグネシウム(6水和物)では0.1(w/w%)、塩化カルシウム(2水和物)では0.05(w/w%)であった。よって、本実施例では、この添加量付近が最適な添加量と推測されるが、豆乳の製造条件等で変動することも想定されるため、特に限定されるものではない。   Thus, it was confirmed that the addition of a coagulant suppresses dissolution of the coagulated product by heating. The amount added to the weight of soy milk that can maintain a coagulate of an appropriate size without dissolving even after heating is 0.1 (w / w%) for magnesium chloride (hexahydrate), calcium chloride (dihydrate) It was 0.05 (w / w%). Therefore, in this example, it is presumed that the vicinity of the addition amount is the optimum addition amount, but it is not particularly limited because it is assumed that the amount varies depending on the production conditions of soymilk.

(実施例8)
1)官能評価
豆乳Bを内径25cm×15cmのプラスチック製の袋に300g入れ、豆乳重量に対して塩化マグネシウム6水和物(塩マグ)を0.05、0.1(w/w%)、塩化カルシウム2水和物(塩カル)を0.02、0.05(w/w%)となるように添加して良く混合してから密封し、そのままの状態(約70℃)で10分間保持した。その後、氷水中で冷却し、−20℃で1日間の凍結保管を行った後、約70℃の湯中で解凍し、それぞれの凝固物について官能評価を行った。なお、凝固剤0%を対照とした。
(Example 8)
1) Sensory evaluation 300 g of soy milk B is put in a plastic bag having an inner diameter of 25 cm × 15 cm, 0.05, 0.1 (w / w%) of magnesium chloride hexahydrate (salt mug) with respect to the weight of soy milk, Calcium chloride dihydrate (salt cal) was added to 0.02 and 0.05 (w / w%), mixed well, sealed, and left in that state (about 70 ° C) for 10 minutes. Retained. Then, after cooling in ice water and performing freezing storage at −20 ° C. for 1 day, it was thawed in hot water at about 70 ° C., and each coagulated product was subjected to sensory evaluation. The control was 0% coagulant.

評価方法は、パネル7名による対照を基準とした各試験区のテクスチャー並びに風味について、良い、普通、劣るの3段階評価で行い、そのパネル数を記載した。得られた結果を表8に示す。   The evaluation method was a three-step evaluation of good, normal, and inferior for the texture and flavor of each test section based on a control by seven panelists, and the number of panels was described. Table 8 shows the obtained results.

Figure 2011067132
Figure 2011067132

表8の結果から、テクスチャーに関しては、塩化マグネシウム0.05%と塩化カルシウム0.02%で「良い」が5名で評価が良好で、塩化マグネシウム0.1%と塩化カルシウム0.05%で「劣る」が5名で評価が良くなかった。添加量の多い試験区で評価が悪かった理由としては、本実施例では凝固剤0%の非常にソフトな豆乳凝固物を対照としたため、多くのパネルはソフト感を重視した評価となり、添加量が多く凝固が進行した試験区では評価が悪くなったものと推測された。しかし、このことは凝固物の食感がしっかりと確認され、凝固物の生成が良好であったことを示しており、凍結凝固による豆腐製造において、凝固剤添加と添加後の加熱処理が、短期的な凍結保管における豆乳凝固物の生成促進効果を有することを官能的に示したものといえた。   From the results of Table 8, regarding the texture, “good” was good with 0.05% magnesium chloride and 0.02% calcium chloride, and the evaluation was good with five people, and with 0.1% magnesium chloride and 0.05% calcium chloride “Inferior” was poor by 5 people. The reason why the evaluation was bad in the test area with a large amount of addition was that, in this example, since the very soft soymilk coagulated material with 0% coagulant was used as a control, many panels evaluated the softness as an important factor. However, it was speculated that the evaluation deteriorated in the test section where the coagulation progressed. However, this indicates that the texture of the coagulum was firmly confirmed, and that the coagulum was well formed. In the production of tofu by freeze coagulation, the addition of the coagulant and the heat treatment after the addition were performed in a short time. It can be said that it has shown the sensory effect that it has the effect of promoting the formation of soymilk coagulum in typical freezing storage.

また、風味に関しては、いずれの試験区でも「良い」が3名で、「普通」と合わせると過半数を超える良好な評価であった。しかし、いずれの凝固剤でも添加量の多い試験区では「劣る」とするパネル数が増加しており、凝固剤の味が評価に影響しているものと推測され、凝固剤の添加量はできるだけ少量とするほうが好ましいものといえた。   In addition, regarding the flavor, “Good” was 3 people in any of the test sections, and when combined with “Normal”, the evaluation was more than a majority. However, the number of panels that are considered “inferior” is increasing in the test plots with a large amount of any coagulant added, and it is speculated that the taste of the coagulant has an effect on the evaluation. It could be said that a smaller amount was preferable.

(実施例9)
1)木綿豆腐様な豆腐様食品の作成
豆乳Aを内径14cm×10cmのプラスチック製の袋に100g入れ、塩化マグネシウム6水和物を、豆乳重量に対して0.1(w/w%)となるように添加して良く混合してから密封し、70℃で10分間加熱処理した。その後、氷水中で冷却し、−20℃で1日間の凍結保管を行った後、約70℃の湯中で解凍し、得られた凝固物を成型器でホエー抜きしながら成型し、木綿豆腐様な豆腐様食品を製造した。
Example 9
1) Preparation of tofu-like food like cotton tofu 100 g of soy milk A is put in a plastic bag with an inner diameter of 14 cm × 10 cm, and magnesium chloride hexahydrate is 0.1 (w / w%) with respect to the weight of soy milk. The mixture was added and mixed well, sealed, and heat-treated at 70 ° C. for 10 minutes. Then, after cooling in ice water and freezing storage at -20 ° C for 1 day, thawed in hot water at about 70 ° C, molded the solidified product while removing whey with a molding machine, and cotton tofu. Various tofu-like foods were produced.

凍結解凍処理して得られた凝固物はホエー抜きが行い易く成型されやすかったため、木綿豆腐様な豆腐様食品の製造が容易であった。また、木綿豆腐様な豆腐様食品は湯葉を集めたようなモチモチ感のある弾力性に富んだ物性があり、従来の豆腐とは異なる新規な特徴を有していた。   The coagulated product obtained by freezing and thawing treatment was easy to remove whey and was easy to be molded, so that it was easy to produce a tofu-like food such as cotton tofu. In addition, tofu-like foods such as cotton tofu have a lot of elasticity with the feeling of stickiness like gathering yuba, and have new characteristics different from conventional tofu.

(実施例10)
1)包装形態を用いて製造する場合の凍結解凍処理時における包装形状(厚み)の影響
豆乳Aを内径24cm×13cmのプラスチック製の袋に400g入れ、厚み幅を約7〜8cmとして、塩化マグネシウム6水和物(塩マグ)を、豆乳重量に対して0、0.05、0.1(w/w%)となるように添加して良く混合してから密封し、70℃で10分間加熱処理した。その後、氷水中で冷却し−20℃で1日間の凍結保管を行った後、約70℃の湯中で解凍し、それぞれの凝固物の性状について検討した。
(Example 10)
1) Effect of packaging shape (thickness) during freezing and thawing when manufacturing using a packaging form 400 g of soy milk A is put into a plastic bag having an inner diameter of 24 cm × 13 cm, the thickness width is about 7 to 8 cm, and magnesium chloride Add hexahydrate (salt mug) to 0, 0.05, 0.1 (w / w%) with respect to the weight of the soymilk, mix well, seal and seal at 70 ° C. for 10 minutes. Heat-treated. Then, after cooling in ice water and freezing storage at −20 ° C. for 1 day, it was thawed in hot water at about 70 ° C., and the properties of each coagulum were examined.

包装形状の厚みを増しても、実施例5と同様に何れの添加区でも凍結解凍して良好な凝固物を得ることができた。しかし、実施例1〜9では袋状の最短部位の厚み幅が約1〜3cmであったが、実施例10では約7〜8cmであったため、凍結や解凍処理に実施例1〜9の際よりも多く時間を要し、望ましくなかった。特に、凍結状態での流通を行った場合で、消費者が早急に消費を行おうとする際に、解凍処理に長時間を要するのは簡便性の面からも問題となり、消費者から敬遠されることが危惧される。そのため、凍結処理する際の混合液の包装形状としては、凍結や解凍時に熱伝達が行われやすくするために最短部位の厚み幅を8cm以下とすることが望ましい。   Even if the thickness of the package shape was increased, it was possible to freeze and thaw in any of the added sections as in Example 5 and obtain a good coagulum. However, although the thickness width of the shortest part of the bag shape was about 1 to 3 cm in Examples 1 to 9, since it was about 7 to 8 cm in Example 10, it was in the case of Examples 1 to 9 for freezing and thawing treatment. More time consuming and undesirable. In particular, in the case of distribution in a frozen state, when a consumer wants to consume quickly, it takes a long time for the thawing process, which is a problem in terms of convenience and is avoided from the consumer. It is feared that. Therefore, the packaging shape of the mixed solution at the time of the freezing treatment is desirably 8 cm or less at the shortest portion in order to facilitate heat transfer during freezing or thawing.

豆乳と凝固剤との凝固反応を加熱処理ではなく、凍結処理による凍結凝固を利用した従来の豆腐とは性状の異なる新規な特徴を有する豆腐様食品の製造が可能となる。   It is possible to produce a tofu-like food having a novel characteristic that is different from conventional tofu using freeze-coagulation by freezing treatment instead of heat treatment for the coagulation reaction between soy milk and the coagulant.

Claims (4)

豆乳に豆腐用凝固剤の粗製海水塩化マグネシウム、若しくは塩化マグネシウム、若しくは塩化カルシウムを、豆乳重量に対して0.01〜0.3(w/w%)の範囲内で、豆乳を完全に凝固させない濃度で添加して混合液とし、凝固させずに保持若しくは加温保持した後で、その混合液を凍結処理して一旦凍結物とし、その凍結物を解凍して凝固物を得ることを特徴とする豆腐様食品の製造方法。   Soy milk is not allowed to coagulate completely within the range of 0.01-0.3 (w / w%) of crude seawater magnesium chloride, magnesium chloride, or calcium chloride, a tofu coagulant, in the range of 0.01-0.3 (w / w%) based on the weight of soy milk. It is characterized in that it is added at a concentration to make a mixed solution, and after holding or warming without coagulation, the mixed solution is frozen to temporarily freeze, and the frozen product is thawed to obtain a coagulated product. Tofu-like food manufacturing method. 請求項1記載の豆腐様食品の製造方法において混合液を凝固させずに保持若しくは加温保持する条件を、50〜70℃の温度域で5〜20分間とすることを特徴とする豆腐様食品の製造方法。   The method for producing a tofu-like food according to claim 1, wherein the condition for holding or warming the mixed solution without coagulation is 5 to 20 minutes in a temperature range of 50 to 70 ° C. Manufacturing method. 請求項1乃至2記載の豆腐様食品の製造方法において得られる凝固物を、圧搾、脱水処理して成型されることを特徴とする豆腐様食品の製造方法。   A method for producing a tofu-like food, wherein the coagulated product obtained by the method for producing a tofu-like food according to claim 1 or 2 is molded by pressing and dehydrating. 請求項1乃至2記載の豆腐様食品の製造方法において包装形態を用いて製造する場合に、混合液の凍結処理する際の包装形状における最短部位の厚み幅を8cm以下とすることを特徴とする豆腐様食品の製造方法。   In the method for producing a tofu-like food according to claim 1 or 2, when manufacturing using a packaging form, the thickness width of the shortest part in the packaging shape when freezing the mixed solution is 8 cm or less. A method for producing a tofu-like food.
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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2013165704A (en) * 2012-02-15 2013-08-29 Toyama Prefecture Method of producing soymilk, and food using the same
WO2018139715A1 (en) * 2017-01-24 2018-08-02 주식회사 태진지엔에스 Method for preparing tofu by using freeze coagulation

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2013165704A (en) * 2012-02-15 2013-08-29 Toyama Prefecture Method of producing soymilk, and food using the same
WO2018139715A1 (en) * 2017-01-24 2018-08-02 주식회사 태진지엔에스 Method for preparing tofu by using freeze coagulation
KR20180087506A (en) * 2017-01-24 2018-08-02 주식회사 태진지엔에스 Preparation method of bean curd using freezing coagulation
KR101987905B1 (en) * 2017-01-24 2019-06-13 주식회사 태진지엔에스 Preparation method of bean curd using freezing coagulation
CN110198638A (en) * 2017-01-24 2019-09-03 株式会社泰进Gns Freeze the bean curd production method of solidification mode
US11324242B2 (en) 2017-01-24 2022-05-10 Taejin Gns Co., Ltd. Method for preparing tofu by using freeze coagulation

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