JP2011058022A - High-strength hot-rolled steel sheet having excellent hole expansibility and method for producing the same - Google Patents

High-strength hot-rolled steel sheet having excellent hole expansibility and method for producing the same Download PDF

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JP2011058022A
JP2011058022A JP2009205842A JP2009205842A JP2011058022A JP 2011058022 A JP2011058022 A JP 2011058022A JP 2009205842 A JP2009205842 A JP 2009205842A JP 2009205842 A JP2009205842 A JP 2009205842A JP 2011058022 A JP2011058022 A JP 2011058022A
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JP5353578B2 (en
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Yuzo Takahashi
雄三 高橋
Junji Haji
純治 土師
Masamitsu Wakao
昌光 若生
Osamu Kono
治 河野
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Nippon Steel Corp
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Abstract

<P>PROBLEM TO BE SOLVED: To provide a hot-rolled steel sheet having excellent hole expansibility while increasing its strength. <P>SOLUTION: The steel sheet has a composition containing, by mass, ≤0.005% S and 0.05 to 0.2% Ti and further the other components in prescribed ranges, wherein the microstructure is composed of a ferritic structure, a bainitic structure or their mixed structure, and the X-ray random intensity ratio of the ä211} face parallel to the rolling face is ≤2.2. Regarding inclusions therein, in the cross-section with a sheet width direction as a normal, they are composed of an aggregate of the inclusions with an equivalent circle diameter of ≥3 μm arranged with a space of ≤50 μm to the other inclusion adjacent on a straight line in the rolling direction, and the total of the inclusion group with a rolling direction length of ≥30 μm and the inclusions having a space of >50 μm to the other inclusion adjacent on a straight line in the rolling direction, having a circle equivalent diameter of 3 μm, and obtained by being stretched to a rolling direction length of ≥30 μm per mm<SP>2</SP>of the cross section is ≤0.25 mm. <P>COPYRIGHT: (C)2011,JPO&INPIT

Description

本発明は、穴広げ性に優れた高強度熱延鋼板及びその製造方法に関するものである。   The present invention relates to a high-strength hot-rolled steel sheet excellent in hole expansibility and a method for producing the same.

近年においては、自動車の軽量化、燃費改善を目的として、自動車用鋼板の高強度化の適用が進められている。一般に、鋼板の高強度化に伴い、鋼板の延性や穴広げ性といった鋼板の加工性に関する機械的性質は低減する傾向にある。このため、鋼板の高強度化を図りつつ、加工性をバランスよく発揮させることが重要となる。   In recent years, for the purpose of reducing the weight of automobiles and improving fuel efficiency, the application of high strength steel sheets for automobiles has been promoted. In general, as the strength of a steel plate increases, mechanical properties relating to the workability of the steel plate, such as the ductility and hole expansibility of the steel plate, tend to decrease. For this reason, it is important to exhibit workability in a well-balanced manner while increasing the strength of the steel sheet.

自動車の車体重量の約20%を占める構造部材や足廻り部材等の自動車部材に用いられる鋼板は、打ち抜き加工や穴あけ加工等のせん断加工によって所定形状に切断された後、伸びフランジ加工を主体としたプレス成形が施されるため、優れた穴広げ性が要求される。穴広げ性とは、鋼板に開けた打ち抜き穴を円錐ポンチにより押し広げ、打ち抜き穴端面で亀裂が発生、板厚貫通した時点の穴径拡大率(穴広げ値(λ))を求めることにより評価される、打ち抜き端面の成形性を表す指標である。   Steel sheets used for automobile members such as structural members and suspension members that account for approximately 20% of the weight of automobile bodies are cut into a predetermined shape by shearing such as punching or drilling, and then mainly stretch flange processing. Therefore, excellent hole expandability is required. The hole expandability is evaluated by expanding the punched hole in the steel plate with a conical punch, cracking occurs at the end face of the punched hole, and determining the hole diameter expansion rate (hole expansion value (λ)) when the plate penetrates the plate thickness. This is an index representing the formability of the punched end face.

この穴広げ値はばらつきが比較的大きいため、穴広げ性を改善するには、その平均値のみならず、その統計的な下限値、即ち、統計学に基づいて所定数の標本(試験値)から推定した母集団の下限値を上げて、ばらつきを抑えることが必要である。ここでいう統計的な下限値(以下、下限値λminという。)とは、具体的には、穴広げ値の母集団の分布を正規分布と見なして、その正規分布の中で99%の標本が取り得る数値範囲の下限値を、下記式(1)に基づき推定した値である。
λmin=λave−2.5×σ ・・・ (1)
λave:所定数得られた穴広げ値の平均値
σ :所定数得られた穴広げ値の標準偏差
Since the hole expansion value has a relatively large variation, not only the average value but also the statistical lower limit value, that is, a predetermined number of samples (test value) based on the statistics is used to improve the hole expansion property. It is necessary to increase the lower limit of the population estimated from the above to suppress variation. Specifically, the statistical lower limit value (hereinafter referred to as the lower limit value λ min ) refers to the distribution of the population of hole expansion values as a normal distribution, and 99% of the normal distribution is This is a value obtained by estimating the lower limit of the numerical range that can be taken by the sample based on the following equation (1).
λ min = λ ave −2.5 × σ (1)
λ ave : Average value of hole expansion values obtained by a predetermined number σ: Standard deviation of hole expansion values obtained by a predetermined number

自動車の足回り部品では、現状、多くの場合、引張強度(TS)で440〜590MPa級の熱延鋼板が用いられている。しかし、自動車燃費軽減のためには概ね10%の鋼板重量の軽量化が必要とされており、その達成のためには、引張強度で780MPa以上、穴広げ値の平均値λaveで80%以上、穴広げ値の下限値λminで60%以上、穴広げ値の標準偏差σで10%以下の鋼板が求められている。 Currently, in automobile undercarriage parts, hot rolled steel sheets having a tensile strength (TS) of 440 to 590 MPa are used in many cases. However, in order to reduce the fuel consumption of automobiles, it is necessary to reduce the weight of the steel sheet by about 10%. To achieve this, the tensile strength is 780 MPa or more and the average value λ ave of the hole expansion value is 80% or more. There is a demand for a steel sheet having a lower limit value λ min of the hole expansion value of 60% or more and a standard deviation σ of the hole expansion value of 10% or less.

しかし、これらの目標を同時に達成する材質を有する高強度熱延鋼板はこれまで得られていない。例えば、特許文献1には、フェライト、ベイナイト等の鋼組織の分率や、フェライト組織中の析出物を最適化することにより強度と穴広げ性のバランスを改善する技術が開示されており、この開示技術によって、引張強度で780MPa以上、穴広げ値の平均値λaveで60%以上の鋼板が得られている。しかし、これでは穴広げ値の平均値λaveがまだ十分とは言えず、更には、穴拡げ値の下限値λmin、標準偏差σについても述べられておらず、十分良好な下限値λmin、標準偏差σの鋼板が得られるという保障はなく、十分な強度、穴広げ性のバランスを有しているとは言い難いものであった。 However, a high-strength hot-rolled steel sheet having a material that can simultaneously achieve these goals has not been obtained. For example, Patent Document 1 discloses a technique for improving the balance between strength and hole expansibility by optimizing the fraction of a steel structure such as ferrite and bainite and precipitates in the ferrite structure. According to the disclosed technology, a steel sheet having a tensile strength of 780 MPa or more and an average value λ ave of hole expansion values of 60% or more is obtained. However, this does not mean that the average value λ ave of the hole expansion value is still sufficient, and further, the lower limit value λ min of the hole expansion value and the standard deviation σ are not described, and a sufficiently good lower limit value λ min There was no guarantee that a steel sheet with a standard deviation σ could be obtained, and it was difficult to say that it had a sufficient balance between strength and hole expansibility.

特開2004−339606号JP 2004-339606 A

そこで、本発明は、上述した問題点に鑑みて、高強度熱延鋼板の穴広げ値の平均値λave、その下限値λmin及びその標準偏差σを改善するために案出されたものであり、その目的とするところは、穴広げ値の平均値λabeが80%以上、穴広げ値の下限値λminが60%以上、穴広げ値の標準偏差σが10%以下であり、更には優れた引張強度を得ることのできる穴広げ性に優れた高強度熱延鋼板及びその製造方法を提供することにある。 Therefore, in view of the above-described problems, the present invention has been devised to improve the average value λ ave of the high-strength hot-rolled steel sheet, its lower limit value λ min and its standard deviation σ. The average value λ bee of the hole expansion value is 80% or more, the lower limit value λ min of the hole expansion value is 60% or more, and the standard deviation σ of the hole expansion value is 10% or less. An object of the present invention is to provide a high-strength hot-rolled steel sheet excellent in hole expansibility that can obtain excellent tensile strength and a method for producing the same.

本発明者らは、上述した課題を解決するために、以下の穴広げ性に優れた高強度熱延鋼板及びその製造方法を発明した。   In order to solve the above-described problems, the present inventors have invented the following high-strength hot-rolled steel sheet excellent in hole expansibility and a method for producing the same.

第1発明に係る穴広げ性に優れた高強度熱延鋼板は、質量%で、C :0.02〜0.07%、Si:0.5〜2%、Mn:0.5〜1.5%、P ≦0.03%(但し、0%超)、S ≦0.005%、Al:0.005〜0.05%、N ≦0.005%(但し、0%超)、Ti:0.05〜0.2%、Ca:0.0005〜0.01%、を含有し、残部がFe及び不可避的不純物からなる鋼板であって、そのミクロ組織がフェライト組織、ベイナイト組織又はこれらの混合組織からなり、圧延面と平行な{211}面のX線ランダム強度比が2.2以下であり、板幅方向を法線に持つ断面において、圧延方向の直線上に隣り合う他の介在物に対して50μm以下の間隔を空けて並んだ円相当径が3μm以上である介在物の集まりからなり、圧延方向長さが30μm以上の介在物群と、圧延方向の直線上に隣り合う他の介在物に対して50μm超の間隔を空け、円相当径が3μm以上であり、圧延方向長さが30μm以上に延伸されてなる介在物との断面1mm当たりの圧延方向長さの総和が0.25mm以下であることを特徴とする穴広げ性に優れた高強度熱延鋼板。 The high-strength hot-rolled steel sheet having excellent hole expansibility according to the first invention is mass%, C: 0.02 to 0.07%, Si: 0.5 to 2%, Mn: 0.5 to 1. 5%, P ≦ 0.03% (however, over 0%), S ≦ 0.005%, Al: 0.005-0.05%, N ≦ 0.005% (however, over 0%), Ti : 0.05-0.2%, Ca: 0.0005-0.01%, the balance being a steel plate made of Fe and inevitable impurities, the microstructure of which is a ferrite structure, a bainite structure, or these The X-ray random intensity ratio of the {211} plane parallel to the rolling surface is 2.2 or less, and in the cross section having the plate width direction as the normal line, other adjacent adjacent straight lines in the rolling direction The rolling method consists of a collection of inclusions with an equivalent circle diameter of 3 μm or more arranged at an interval of 50 μm or less with respect to the inclusions. An inclusion group having a direction length of 30 μm or more and an interval of more than 50 μm with respect to other inclusions adjacent on the straight line in the rolling direction, an equivalent circle diameter of 3 μm or more, and a rolling direction length of 30 μm or more A high-strength hot-rolled steel sheet excellent in hole expansibility, characterized in that the sum of the lengths in the rolling direction per 1 mm 2 cross-section with the inclusions that are drawn into a diameter of 0.25 mm or less.

第2発明に係る穴広げ性に優れた高強度熱延鋼板は、第1発明において、更に質量%で、Nb≦0.05%(但し、0%超)、を含有することを特徴とする。   The high-strength hot-rolled steel sheet excellent in hole expansibility according to the second invention is characterized in that, in the first invention, it further contains Nb ≦ 0.05% (however, more than 0%) in mass%. .

第3発明に係る穴広げ性に優れた高強度熱延鋼板は、第1又は第2発明において、更に質量%で、Cu≦1.0%(但し、0%超)、Cr≦1.0%(但し、0%超)、Ni≦1.0%(但し、0%超)、B≦0.005%(但し、0%超)のうち、何れか一種又は二種以上を含有することを特徴とする。   The high-strength hot-rolled steel sheet having excellent hole expansibility according to the third aspect of the invention is the mass%, Cu ≦ 1.0% (however, over 0%), Cr ≦ 1.0 in the first or second aspect. % (However, over 0%), Ni ≦ 1.0% (however, over 0%), B ≦ 0.005% (however, over 0%) It is characterized by.

第4発明に係る穴広げ性に優れた高強度熱延鋼板は、第1〜第3の何れか1つの発明において、更に質量%で、REM:0.0005〜0.01%を含有することを特徴とする。   The high-strength hot-rolled steel sheet having excellent hole expansibility according to the fourth aspect of the present invention contains, in any one of the first to third aspects, further mass% and REM: 0.0005 to 0.01%. It is characterized by.

第5発明に係る穴広げ性に優れた高強度熱延鋼板の製造方法は、第1〜第4の何れか1つの発明の成分を含有する溶鋼を溶製するに際し、真空脱ガス設備で脱硫用フラックス添加後に溶鋼を3.0回以上環流させ、更に当該溶鋼から得られた鋳片を1200℃以上に加熱した後、粗圧延を行い、次に行う仕上げ圧延を960℃以上の温度域で終了させ、その後、20℃/sec以上の冷却速度で400℃以上550℃以下の温度域まで冷却した後巻き取ることを特徴とする。   The method for producing a high-strength hot-rolled steel sheet excellent in hole expansibility according to the fifth aspect of the invention is to desulfurize with a vacuum degassing facility when melting molten steel containing any one of the first to fourth aspects of the invention. After the flux is added, the molten steel is circulated 3.0 times or more, and the slab obtained from the molten steel is heated to 1200 ° C. or higher, followed by rough rolling, and the subsequent finish rolling is performed at a temperature range of 960 ° C. or higher. Then, the film is cooled to a temperature range of 400 ° C. or more and 550 ° C. or less at a cooling rate of 20 ° C./sec or more, and then wound.

第6発明に係る穴広げ性に優れた高強度熱延鋼板の製造方法は、第5発明において、20℃/sec以上の冷却速度での上記冷却中に、冷却速度を15℃/sec以下とした緩冷却を行ない、その後に再度冷却速度を20℃/sec以上として上記冷却を行なうことを特徴とする。   The method for producing a high-strength hot-rolled steel sheet having excellent hole expansibility according to the sixth invention is the fifth invention, wherein the cooling rate is 15 ° C./sec or less during the cooling at a cooling rate of 20 ° C./sec or more. The above-described slow cooling is performed, and then the cooling is performed again at a cooling rate of 20 ° C./sec or more.

第1〜第6の発明によれば、成形性、特に穴広げ性が良好であるうえ、引張強度にも優れた熱延鋼板が得られるため、これを自動車用鋼板として用いた場合、大幅な自動車軽量化、燃費軽減を図ることが可能となる。   According to the first to sixth inventions, a hot-rolled steel sheet having excellent formability, particularly hole expansibility and excellent tensile strength can be obtained. It is possible to reduce the weight of the vehicle and reduce fuel consumption.

L断面について説明するための斜視図である。It is a perspective view for demonstrating a L cross section. 介在物の圧延方向長さの総和Mについて説明するための模式図である。It is a schematic diagram for demonstrating the sum total M of the rolling direction length of an inclusion. {211}面のX線ランダム強度比と介在物の圧延方向長さの総和Mと穴広げ値の平均値λaveとの関係を示す図である。It is a figure which shows the relationship between X-ray random intensity ratio of {211} surface, total M of the rolling direction length of an inclusion, and average value (lambda) ave of a hole expansion value. {211}面のX線ランダム強度比と介在物の圧延方向長さの総和Mと穴広げ値の下限値λminとの関係を示す図である。It is a figure which shows the relationship between X-ray random intensity ratio of {211} surface, the sum total M of the rolling direction length of an inclusion, and lower limit (lambda) min of a hole expansion value. 穴広げ値の標準偏差σと介在物の圧延方向長さの総和Mとの関係を示す図である。It is a figure which shows the relationship between the standard deviation (sigma) of a hole expansion value, and the sum total M of the rolling direction length of an inclusion. 仕上げ圧延終了温度と{211}面のX線ランダム強度比との関係を示す図である。It is a figure which shows the relationship between finish rolling completion | finish temperature and the X-ray random intensity ratio of a {211} surface. 二次精錬時における溶鋼の環流回数と介在物の圧延方向長さの総和Mとの関係を示す図である。It is a figure which shows the relationship between the frequency M of the molten steel at the time of secondary refining, and the sum total M of the rolling direction length of an inclusion. 溶鋼を溶製する二次精錬工程を行うにあたって二次精錬装置として用いられるRHの構成を示す模式図である。It is a schematic diagram which shows the structure of RH used as a secondary refining apparatus in performing the secondary refining process which melts molten steel. 本発明に係る熱間圧延工程における温度と時間との関係示す図である。It is a figure which shows the relationship between the temperature and time in the hot rolling process which concerns on this invention.

以下に、本発明を実施するための形態として、穴広げ性に優れた高強度熱延鋼板及びその製造方法について詳細に説明する。   Below, as a form for implementing this invention, the high intensity | strength hot-rolled steel plate excellent in hole expansibility and its manufacturing method are demonstrated in detail.

まず、本発明を完成するに至った基礎的研究結果について説明する。   First, the basic research results that led to the completion of the present invention will be described.

本発明者らは、高強度の熱延鋼板の穴広げ性の改善のため、まず、穴広げ性を劣化させる延性破壊の起点となるパーライトのような硬質相を低減した低C成分からなり、更に、フェライト組織、ベイナイト組織又はその混合組織からなる鋼板を対象として鋭意検討を行った。この結果、このような高強度で、硬質相のない組織、成分系の鋼板において、穴広げ性を改善するためには、集合組織の制御(異方性の抑制)が重要であることを見出した。また、穴広げ値のばらつきを表すその標準偏差σを低減させて下限値λminを向上させるうえでは、鋼中に含まれる延伸した介在物と、これと同等の影響を有する介在物群との抑制が重要であることを見出した。 In order to improve the hole expansibility of a high strength hot-rolled steel sheet, the present inventors first comprise a low C component with a reduced hard phase such as pearlite that becomes the starting point of ductile fracture that degrades the hole expansibility, Furthermore, earnest examination was performed for the steel plate which consists of a ferrite structure, a bainite structure, or its mixed structure. As a result, it has been found that control of texture (suppression of anisotropy) is important in order to improve hole expansibility in such high-strength, hard-structured and component steel sheets. It was. Further, in order to improve the lower limit λ min by reducing the standard deviation σ representing the variation of the hole expansion value, the elongated inclusions contained in the steel and the inclusion group having the same effect as this We found that suppression is important.

本発明者らは、表1に示す範囲の様々な鋼成分からなる複数の鋳片に、仕上げ圧延終了温度を940〜1000℃、圧延後のランアアウトテーブルでの冷却速度を30〜40℃/sec、巻き取り温度を480〜500℃の範囲とした条件下で熱間圧延を行い、2.9mm厚の熱延鋼板を得ることとした。得られた熱延鋼板からは、引張強度、穴広げ値等で表される機械的特性の他、ミクロ組織、集合組織、介在物の分布を調べることとした。   The inventors set the finish rolling end temperature to 940 to 1000 ° C. and the cooling rate at the run-out table after rolling to 30 to 40 ° C. for a plurality of slabs made of various steel components in the range shown in Table 1. / Sec, hot rolling was performed under the conditions where the coiling temperature was in the range of 480 to 500 ° C., and a hot rolled steel sheet having a thickness of 2.9 mm was obtained. From the obtained hot-rolled steel sheet, in addition to the mechanical properties represented by the tensile strength, the hole expansion value, etc., the microstructure, texture, and inclusion distribution were examined.

なお、ここでいうミクロ組織とは、フェライト組織、ベイナイト組織等のことをいい、集合組織とは、複数の結晶粒の集まりであって、各集合組織におけるそれぞれの結晶粒の結晶方位が一定の関係を満たすもののことをいう。また、介在物とは、鋼中に異相として存在し、延性破壊の起点となるような比較的粗大なもののことをいい、例えば、鋼中のMnS、CaS等の硫化物や、CaO−Al系化合物(カルシウムアルミネート)等の酸化物、TiN等の窒化物、又は製鋼段階で脱硫のために投入する脱硫フラックスの残存物等のことをいう。この残存物は、例えば、フッ化カルシウムを含有している。 The microstructure here means a ferrite structure, a bainite structure, etc., and a texture is a group of a plurality of crystal grains, and the crystal orientation of each crystal grain in each texture is constant. A thing that satisfies a relationship. The inclusion means a relatively coarse material that exists as a heterogeneous phase in steel and serves as a starting point for ductile fracture. For example, sulfides such as MnS and CaS in steel, CaO-Al 2 This refers to oxides such as O 3 -based compounds (calcium aluminate), nitrides such as TiN, or residues of desulfurization flux that is input for desulfurization in the steelmaking stage. This residue contains, for example, calcium fluoride.

Figure 2011058022
Figure 2011058022

引張強度等の引張特性は、得られた熱延鋼板の板幅方向中央部から板幅方向と平行なJIS Z 2201記載の5号試験片を加工し、得られた試験片についてJIS Z 2241記載の試験方法を行なうことによって評価した。以上の製造条件範囲で得られた熱延鋼板の引張強度は全て780MPa〜800MPaの範囲に分布していた。   Tensile properties such as tensile strength are obtained by processing No. 5 test piece described in JIS Z 2201 parallel to the plate width direction from the center in the plate width direction of the obtained hot-rolled steel sheet, and describing the obtained test piece in JIS Z 2241. The test method was evaluated. All the tensile strengths of the hot-rolled steel sheets obtained in the above manufacturing condition range were distributed in the range of 780 MPa to 800 MPa.

ミクロ組織、集合組織、介在物の分布の調査は、鋼板の板幅方向中央位置を中心として板幅方向に300mmの範囲で切り出したサンプルにて行った。   The investigation of the distribution of the microstructure, texture, and inclusions was performed on a sample cut out in the range of 300 mm in the plate width direction with the center position in the plate width direction of the steel plate as the center.

穴広げ値の平均値λave、下限値λmin及び標準偏差σは、鋼板の板幅方向中央位置を中心として板幅方向に300mmの範囲で切り出したサンプルから採取した30枚の試験片を用いて日本鉄鋼連盟規格JFS T 1001−1996記載の打ち抜き穴広げ試験を行なうことにより得られた穴広げ値から求めた。穴広げ値の平均値λaveは試験により得られた30枚の試験片の穴広げ値の算術平均とし、穴広げ値の標準偏差σは下記の式(2)に基づき求め、穴広げ値の下限値λminは上述した式(1)に基づき求めた。なお、式(2)におけるλは、各試験片の穴広げ値である。

Figure 2011058022
The average value λ ave , the lower limit value λ min, and the standard deviation σ of the hole expansion values are obtained by using 30 test pieces taken from a sample cut in a range of 300 mm in the plate width direction around the center position in the plate width direction of the steel plate. Thus, it was obtained from the hole expansion value obtained by performing the punching hole expansion test described in the Japan Iron and Steel Federation Standard JFS T 1001-1996. The average value λ ave of the hole expansion values is the arithmetic average of the hole expansion values of the 30 test pieces obtained by the test, and the standard deviation σ of the hole expansion values is obtained based on the following formula (2). The lower limit value λ min was determined based on the above-described formula (1). In addition, (lambda) i in Formula (2) is a hole expansion value of each test piece.
Figure 2011058022

打ち抜き穴広げ試験は、初期穴径10mm、打ち抜きクリアランス12.5%で打ち抜きを行い、打ち抜きによるバリが穴広げポンチの反対側となるように試験片をセットし、頂角60°の円錐穴広げポンチにより打ち抜き穴の押し広げ加工を行い、打ち抜き端面に発生した亀裂が板厚貫通した時点の穴径(内径)の拡大率として求めた。ここで、打ち抜きクリアランスとは、打ち抜く際の、ポンチ進行方向と直交する方向におけるポンチとダイとの間隔の、加工対象となる鋼板の板厚に対する割合(%)である。   In the punching hole expansion test, punching is performed with an initial hole diameter of 10 mm and a punching clearance of 12.5%, and the test piece is set so that the burr caused by punching is on the opposite side of the hole expanding punch. The punched hole was expanded by a punch, and the expansion ratio of the hole diameter (inner diameter) at the time when the crack generated on the punched end face penetrated the plate thickness was obtained. Here, the punching clearance is the ratio (%) of the distance between the punch and the die in the direction perpendicular to the punch traveling direction to the plate thickness of the steel plate to be processed.

上述の試験方法で求めた各鋼板についての穴広げ値の平均値λaveは、65〜100%の広い範囲に分布しており、穴広げ値の下限値λminは、28〜85%の範囲に分布しており、穴広げ値の標準偏差σは6〜15%の範囲に分布していた。穴広げ値の平均値λave、その下限値λmin及びその標準偏差σへの影響因子として、鋼板中の集合組織と介在物に着目し、後述のように整理した。 The average value λ ave of the hole expansion value for each steel plate obtained by the above test method is distributed in a wide range of 65 to 100%, and the lower limit value λ min of the hole expansion value is in the range of 28 to 85%. The standard deviation σ of the hole expansion value was distributed in the range of 6 to 15%. As an influence factor on the average value λ ave of the hole expansion value, the lower limit value λ min and the standard deviation σ, the texture and inclusions in the steel sheet were focused and arranged as described later.

集合組織は、以下の方法で調査を行った。板幅方向中央位置を中心として板幅方向に20mm、圧延方向に20mmの大きさで切り出した試験片の板厚方向中央部についてのX線回折強度を、適切なX線管球を用いたディフラクトメーター法により測定した。この測定したX線回折強度に基づき、ランダムな方位分布をもつ粉末試料のX線回折強度に対する測定対象である試験片のX線回折強度の強度比、即ち、X線ランダム強度比を求めた。ここでは、圧延面と平行な{211}面のX線ランダム強度比を求めた。このX線ランダム強度比が大きいほど、鋼板中にその結晶面を有する集合組織の量が多いことを意味している。   The texture was investigated by the following method. The X-ray diffraction intensity at the central portion in the plate thickness direction of a test piece cut out in a size of 20 mm in the plate width direction and 20 mm in the rolling direction with the center position in the plate width direction as the center is measured using a suitable X-ray tube. It was measured by the fractometer method. Based on the measured X-ray diffraction intensity, the intensity ratio of the X-ray diffraction intensity of the test piece to be measured with respect to the X-ray diffraction intensity of the powder sample having a random orientation distribution, that is, the X-ray random intensity ratio was obtained. Here, the X-ray random intensity ratio of the {211} plane parallel to the rolling surface was determined. The larger the X-ray random intensity ratio, the greater the amount of texture having the crystal plane in the steel sheet.

介在物の調査は以下のように行った。板幅方向中央位置を中心として板幅方向に300mmの範囲で切り出したサンプルから試験片を採取し、図1に示す板幅方向を法線に持つ断面(以下、L断面という。)を鏡面研磨し、光学顕微鏡を用いて、×400の倍率でL断面の観察を行い、L断面において圧延方向の長さが10mm、板厚方向の長さが全板厚分の大きさの視野内にある介在物のサイズ、分布の調査を行った。   The inclusions were investigated as follows. A test piece is taken from a sample cut out in a range of 300 mm in the plate width direction with the center in the plate width direction as a center, and a cross section (hereinafter referred to as L cross section) having the normal direction in the plate width direction shown in FIG. Then, using an optical microscope, the L section is observed at a magnification of × 400, and the length in the rolling direction is 10 mm and the length in the sheet thickness direction is within the field of view of the entire sheet thickness. The size and distribution of inclusions were investigated.

介在物の調査にあたっては下記のような考えに基づき調査を行った。介在物は、鋼板の変形時にボイドを鋼中に形成して延性破壊を促進するものであり、その形状が延伸形状であるほど介在物近傍の応力集中を増大させて、その結果、延性破壊を促進して穴広げ性を劣化させることが知られている。   The investigation of inclusions was conducted based on the following ideas. Inclusions form a void in the steel during deformation of the steel sheet to promote ductile fracture.The more the shape is elongated, the greater the stress concentration in the vicinity of the inclusion, resulting in ductile fracture. It is known to promote and degrade hole expansibility.

ここで、本発明者らは、大きく延伸した1個の介在物のみならず、小さく延伸した介在物や球状の介在物が、亀裂伝搬方向である圧延方向に所定の間隔で分布して構成される介在物の集まりも、1個の大きく延伸した介在物と同じように、鋼板の変形時に介在物近傍に導入される歪の相乗効果によりその近傍に大きな応力集中を生じさせることを見出した。   Here, the present inventors are configured such that not only a single elongated inclusion, but also small elongated inclusions and spherical inclusions are distributed at predetermined intervals in the rolling direction, which is the crack propagation direction. It has also been found that, like one large stretched inclusion, a large concentration of stress is produced in the vicinity of the inclusion due to the synergistic effect of strain introduced in the vicinity of the inclusion when the steel sheet is deformed.

定量的には、図2(a)に示すように、圧延方向の直線上に隣り合う他の介在物に対して50μm以下の間隔を空けて並んでいる円相当径が3.0μm以上の介在物の集まり(以下、これを介在物群という。)からなる介在物群が、その介在物群の圧延方向長さと同程度の長さに延伸した1個の介在物と同じ効果があることを見出した。なお、ここでいう円相当径とは、介在物の形状と同じ面積の円に換算した場合の直径のことを意味し、また、圧延方向の直線とは圧延方向に伸びる仮想的な直線のことを意味する。   Quantitatively, as shown in FIG. 2 (a), an inclusion having an equivalent circle diameter of 3.0 μm or more arranged at an interval of 50 μm or less with respect to other inclusions adjacent on a straight line in the rolling direction. The inclusion group consisting of a collection of objects (hereinafter referred to as inclusion group) has the same effect as one inclusion stretched to the same length as the rolling direction length of the inclusion group. I found it. The equivalent circle diameter here means the diameter when converted into a circle having the same area as the shape of the inclusion, and the straight line in the rolling direction is a virtual straight line extending in the rolling direction. Means.

そこで、上述のような介在物群のうち、圧延方向長さが30μm以上の介在物群と、圧延方向の直線上に隣り合う他の介在物に対して50μm超の間隔が空いている介在物であっても、図2(b)に示すように、その形状が、円相当径が3.0μm以上であり、圧延方向の長さが30μm以上の介在物とを、測定対象として扱うこととした。なお、測定対象として、圧延方向長さが30μm以上のものに限定したのは、圧延方向長さがこれ未満の介在物群等では延性破壊に対する影響が小さいと考えられるためである。また、円相当径が3.0μm以上のものに限定したのは、円相当径がこれ未満の介在物では延性破壊に対する影響が小さいと考えられるためである。   Therefore, among the inclusion group as described above, the inclusion group having a length in the rolling direction of 30 μm or more and an inclusion having an interval of more than 50 μm with respect to other inclusions adjacent on the straight line in the rolling direction. Even so, as shown in FIG. 2 (b), the shape has an equivalent circle diameter of 3.0 μm or more and an inclusion having a length in the rolling direction of 30 μm or more is treated as an object to be measured. did. The reason for limiting the measurement target to those having a length in the rolling direction of 30 μm or more is that inclusions having a length in the rolling direction less than this are considered to have a small effect on ductile fracture. The reason why the equivalent circle diameter is limited to 3.0 μm or more is that inclusions having an equivalent circle diameter less than this are considered to have a small effect on ductile fracture.

なお、図2(c)に示すように、円相当径が3.0μm以上であり、圧延方向の長さが30μm以上の介在物であっても、圧延方向の直線上に隣り合う他の介在物に対して50μm以下の間隔が空いている介在物については、介在物群の一部であるとして扱うこととした。以下においては、この介在物群に含まれず、円相当径が3.0μm以上であり、圧延方向の長さが30μm以上の介在物については、「延伸介在物」と記載する。   As shown in FIG. 2 (c), even if the inclusion has an equivalent circle diameter of 3.0 μm or more and a length in the rolling direction of 30 μm or more, other intervening adjacent on the straight line in the rolling direction. Inclusions having an interval of 50 μm or less with respect to the object were treated as being part of the inclusion group. Hereinafter, inclusions that are not included in the inclusion group and have an equivalent circle diameter of 3.0 μm or more and a length in the rolling direction of 30 μm or more are referred to as “stretched inclusions”.

これら介在物群、延伸介在物は、その形状が延伸した形状であるほどこれら近傍に発生する応力集中を増大させ、鋼板変形時の亀裂の発生、伝搬を促進することが考えられるので、穴広げ性の評価にあたっては、図2(a)〜図2(c)に示すような、L断面においてのこれらの圧延方向の長さL1、L2を測定することとした。   These inclusions and stretched inclusions are considered to increase the stress concentration generated in the vicinity as the shape of the stretched inclusions is extended, and promote the generation and propagation of cracks during deformation of the steel sheet. In the evaluation of the properties, the lengths L1 and L2 in the rolling direction in the L section as shown in FIGS. 2 (a) to 2 (c) were measured.

得られた各介在物群、各延伸介在物の圧延方向長さL1、L2は、下記のような理由に基づき、それらの平均値ではなくそれらの総和Mを求めることとした。   The lengths L1 and L2 in the rolling direction of the obtained inclusion groups and the drawn inclusions were determined not as an average value but as a sum M thereof based on the following reasons.

鋼板の変形時においては、介在物群、延伸介在物の個数が少ないと、これら介在物群等の周囲で生じたボイドが途切れながら亀裂が伝搬するのに対し、これら介在物群等の個数が多いと、介在物群等の周囲のボイドが途切れることなく連結して、長く連続的なボイドを形成し、延性破壊を促進するものと考えられる。このような介在物群等の個数の影響は、介在物群等の平均値では表せないので、この点から介在物の圧延方向長さの総和Mを求めることとした。   At the time of deformation of the steel sheet, if the number of inclusion groups and stretched inclusions is small, the voids generated around these inclusion groups etc. break and the crack propagates, whereas the number of these inclusion groups etc. When the number is large, surrounding voids such as inclusions are connected without interruption, and long continuous voids are formed to promote ductile fracture. Since the influence of the number of inclusions and the like cannot be expressed by the average value of the inclusions or the like, the sum M of the inclusions in the rolling direction is determined from this point.

特に、今回の試験結果で、介在物群等の平均値は、これが30μm以上である場合、穴広げ値に対して大きな相関関係が見られず、その平均値によって穴広げ性の程度を表すことが困難であることが判明した。   In particular, in this test result, when the average value of the inclusion group etc. is 30 μm or more, there is no significant correlation with the hole expansion value, and the average value represents the degree of hole expansion. Proved difficult.

また、鋼板の変形時においては、介在物群、延伸介在物の分布が多い箇所ほど歪の相乗効果により応力集中が増大してボイドが発生し易くなるものと考えられる。このため、介在物の圧延方向長さの平均値が小さい場合でも、鋼中の介在物の個数が多い場合、即ち、介在物の圧延方向長さの総和Mが大きい場合、介在物の分布による影響を受け易くなり、穴広げ値のばらつきが大きくなることになる。この点からも介在物の圧延方向長さの総和Mを求めることとした。   Further, at the time of deformation of the steel sheet, it is considered that as the inclusion group and the distribution of the drawn inclusions are more distributed, the stress concentration increases due to the synergistic effect of strain, and voids are more likely to occur. For this reason, even when the average value of the rolling direction length of inclusions is small, when the number of inclusions in the steel is large, that is, when the total sum M of the lengths of inclusions in the rolling direction is large, the distribution of inclusions It becomes easy to be affected, and the variation of the hole expansion value becomes large. Also from this point, the sum M of the lengths of inclusions in the rolling direction was determined.

以上の観点から、単位面積当たりの介在物の圧延方向長さの総和Mを求めることとしたが、具体的には、下記の式(3)に従い、1視野ごとの各介在物群、延伸介在物についてのL1(mm)及びL2(mm)を総和してL(mm)を求め、得られたLに基づき下記の式(4)に従い数値M(mm/mm)を求め、得られたMによって評価することとした。なお、下記の式(3)におけるL1、L2は、それぞれ1視野中の各介在物群及び各延伸介在物の圧延方向長さのことであり、Sは、観察した視野の面積(mm2)のことである。

Figure 2011058022
Figure 2011058022
From the above viewpoint, the sum M of the lengths of inclusions in the rolling direction per unit area was determined. Specifically, according to the following formula (3), each inclusion group for each field of view, stretched inclusions L1 (mm) and L2 (mm) of the product were summed to obtain L (mm), and based on the obtained L, a numerical value M (mm / mm 2 ) was obtained according to the following formula (4). It was decided to evaluate by M. In the following formula (3), L1 i and L2 i are the lengths in the rolling direction of each inclusion group and each stretched inclusion in one field of view, and S is the area of the observed field of view (mm 2 ).
Figure 2011058022
Figure 2011058022

以上の試験の結果得られた、穴広げ値の平均値λave、穴広げ値の下限値λminと{211}面のランダム強度比、介在物の圧延方向長さの総和Mの関係を図3、図4に示し、穴広げ値の標準偏差σと介在物の圧延方向長さの総和Mとの関係を図5に示す。尚、ここで得られた供試鋼のミクロ組織は全て、フェライト組織、又はベイナイト組織を主相とするものであった。 The relationship between the average value λ ave of the hole expansion value, the lower limit value λ min of the hole expansion value, the random strength ratio of the {211} plane, and the total length M of the inclusions in the rolling direction, obtained as a result of the above test, is shown in FIG. 3 and FIG. 4, and FIG. 5 shows the relationship between the standard deviation σ of the hole expansion value and the total sum M of the inclusions in the rolling direction. In addition, all the microstructures of the test steels obtained here had a ferrite structure or a bainite structure as the main phase.

これより、{211}面のランダム強度比が2.2以下、介在物の圧延方向長さの総和Mが0.25mm/mm以下となる場合に、穴広げ値の平均値λaveで80%以上、穴広げ値の下限値λminで60%以上、穴広げ値の標準偏差σで10%以下の穴広げ性が改善された鋼板を得られることが判明した。 As a result, when the {211} plane random strength ratio is 2.2 or less and the total length M of inclusions in the rolling direction is 0.25 mm / mm 2 or less, the average value λ ave of the hole expansion value is 80 It was found that a steel sheet with improved hole expandability of at least 60% at a lower limit value λ min of the hole expansion value of 60% or more and a standard deviation σ of the hole expansion value of 10% or less can be obtained.

{211}面のランダム強度比が小さいほど穴広げ値の平均値λave、下限値λminが改善されるメカニズムは必ずしも明らかではないが、以下のように説明される。熱延鋼板においては{211}面が多いことにより鋼材の異方性が大きくなる。特に、圧延方向、及び圧延方向に対して45°方向並びに90°方向(板幅方向)の塑性歪み比(r値)をそれぞれr、r45、r90と定義すると、この場合においてはrとr45及びr90との差が大きくなるうえ、r90が大きく低下することになる。これにより穴広げ成形時に、板幅方向に引張歪を受ける圧延方向端面において板厚減少が大きくなり、端面に高い応力が発生して亀裂が発生、伝播しやすくなるためと考えられる。 The mechanism by which the average value λ ave of the hole expansion value and the lower limit value λ min are improved as the random intensity ratio of the {211} plane is smaller is not necessarily clear, but is explained as follows. In a hot-rolled steel sheet, the anisotropy of the steel material increases due to the large number of {211} faces. In particular, if the plastic strain ratios (r values) in the rolling direction and the 45 ° direction and 90 ° direction (sheet width direction) with respect to the rolling direction are defined as r 0 , r 45 , and r 90 , respectively, The difference between 0 and r 45 and r 90 is increased, and r 90 is greatly decreased. This is thought to be due to the fact that, during hole-opening forming, the reduction in plate thickness increases at the end surface in the rolling direction that receives tensile strain in the plate width direction, and high stress is generated on the end surface, so that cracks are easily generated and propagated.

介在物の圧延方向長さの総和Mが大きい場合に穴広げ値の平均値λave、下限値λminが低下する理由については、前述の通りであり、要約すると下記の2つの理由となる。第1に、総和Mが増大するほど介在物群、延伸介在物が延伸した形状となる結果、応力集中の度合いが高まり、穴広げ成形での端面の亀裂の発生、伝播が促進される点が挙げられる。第2に、総和Mが増大するほど介在物の個数が増大して変形時にボイドが連結し易くなり、その結果、亀裂の伝搬が促進される点が挙げられる。また、総和Mが大きい場合に穴広げ値のばらつきを表す標準偏差σが増大する理由は、前述の通りであり、要約すると、総和Mが増大するほど介在物の個数が増大し、介在物の分布による影響でばらつきが大きくなる点が挙げられる。 The reason why the average value λ ave of the hole expansion value and the lower limit value λ min decrease when the total length M of the inclusions in the rolling direction is large is as described above, and can be summarized as the following two reasons. First, as the total sum M increases, the inclusion group and the elongated inclusions have a stretched shape. As a result, the degree of stress concentration is increased, and the generation and propagation of end face cracks in hole expansion molding are promoted. Can be mentioned. Secondly, as the total sum M increases, the number of inclusions increases, and voids are easily connected during deformation. As a result, the propagation of cracks is promoted. The reason why the standard deviation σ representing the variation in the hole expansion value increases when the sum M is large is as described above. In summary, the number of inclusions increases as the sum M increases. There is a point that the variation increases due to the influence of the distribution.

また、本発明者らは、図6に示すように、熱間圧延工程における仕上げ圧延終了温度が高温であるほど{211}面のX線ランダム強度比が低減し、仕上げ圧延温度が960℃以上の温度域の条件下であれば{211}面のX線ランダム強度比強度が2.2以下となることを見出した。   Further, as shown in FIG. 6, the present inventors show that the higher the finish rolling end temperature in the hot rolling process, the lower the {211} plane X-ray random intensity ratio, and the finish rolling temperature is 960 ° C. or higher. It has been found that the X-ray random intensity ratio intensity of the {211} plane is 2.2 or less under the above temperature range conditions.

この理由は以下のように考えられる。{211}面のX線ランダム強度比は、複数パスからなる仕上げ圧延のパス間又は最終パス以降において再結晶が抑制されて、鋼板中に圧延歪みが蓄積された場合に増大することが知られている。このことから、仕上げ圧延終了温度が高温である場合、仕上げ圧延中又はその終了後における再結晶を促進することになり、これによって、{211}面のX線ランダム強度比が低減されると考えられる。   The reason is considered as follows. It is known that the X-ray random intensity ratio of the {211} plane increases when recrystallization is suppressed between the final rolling passes consisting of a plurality of passes or after the final pass, and rolling strain is accumulated in the steel sheet. ing. From this, when the finish rolling finish temperature is high, recrystallization will be promoted during or after finish rolling, and this will reduce the X-ray random intensity ratio of the {211} plane. It is done.

また、本発明者らは、穴広げ性を劣化させる要因となる圧延方向の直線上に並んだ介在物を調査したところ、これらは主として、圧延により延伸したMnSや、製鋼段階で脱硫のために投入する脱硫フラックスの残存物であることを明らかにした。   In addition, the present inventors investigated inclusions arranged on a straight line in the rolling direction, which is a factor that deteriorates hole expandability, and these are mainly for MnS drawn by rolling and for desulfurization in the steelmaking stage. It was clarified that it was a residue of desulfurization flux to be introduced.

これらを抑制するための製造方法について検討した結果、以下が重要であることが判明した。   As a result of examining the manufacturing method for suppressing these, it was found that the following is important.

MnSを抑制するには、まず鋼中に含まれるS量の低減が重要である。また、Ti添加鋼ではTiSの生成によりMnS生成が抑制されることから、Ti添加もMnS抑制に大きな効果を有する。この観点から、穴広げ性を劣化させるようなMnSを抑制するためには、Ti量下限(Ti≧0.05%)、S量上限(S≦0.005%)を設ける必要があることが判明した。特に、Tiを添加せずにS量上限をこれより低減させる手段も考えられるが、Sを低減しすぎると脱硫のために多量の脱硫フラックスを用いる必要が生じ、その分脱硫フラックスの除去のため生産性を著しく劣化させるほど長時間の溶鋼環流を行う必要が生じ、経済性を損なうことになってしまう。このため、経済性を維持した上でMnSを抑制するためにはTiを下限値以上添加することが重要である。   In order to suppress MnS, it is first important to reduce the amount of S contained in the steel. In addition, since Ti-added steel suppresses MnS generation due to TiS generation, Ti addition also has a great effect on MnS suppression. From this point of view, in order to suppress MnS that deteriorates hole expandability, it is necessary to provide a Ti amount lower limit (Ti ≧ 0.05%) and an S amount upper limit (S ≦ 0.005%). found. In particular, a means for reducing the upper limit of S amount without adding Ti can be considered. However, if S is reduced too much, it is necessary to use a large amount of desulfurization flux for desulfurization. As the productivity deteriorates significantly, it becomes necessary to carry out the molten steel recirculation for a long time, and the economic efficiency is impaired. For this reason, in order to suppress MnS while maintaining economic efficiency, it is important to add Ti more than a lower limit.

また、脱硫フラックスの残存による介在物の抑制のためには、溶鋼の二次精錬の工程において、脱硫フラックスの添加後十分な環流を行い、脱硫フラックスの除去を図ることが重要であるが、詳しくは後述する。   In addition, in order to suppress inclusions due to residual desulfurization flux, it is important to perform sufficient recirculation after desulfurization flux addition in the secondary refining process of molten steel to remove the desulfurization flux. Will be described later.

以下、本発明の構成要素を詳細に説明する。   Hereinafter, the constituent elements of the present invention will be described in detail.

まず、本発明における化学成分の限定理由について説明する。なお、以下では、組成における質量%を、単に%と記載する。   First, the reasons for limiting chemical components in the present invention will be described. Hereinafter, mass% in the composition is simply referred to as%.

C :0.02〜0.07%
Cは、Nb、Ti等と結合して析出強化等によって引張強度向上に寄与する元素であるが、Cの含有量が0.02%未満であると強度向上の効果が得られない。また、Cの含有量が、0.07%超であると、鉄炭化物が生成し、穴広げ性が劣化する。このため、Cの含有量は、0.02%以上、0.07%以下とする。
C: 0.02 to 0.07%
C is an element that combines with Nb, Ti, etc. and contributes to the improvement of tensile strength by precipitation strengthening or the like, but if the C content is less than 0.02%, the effect of improving the strength cannot be obtained. On the other hand, if the C content is more than 0.07%, iron carbide is generated and the hole expandability deteriorates. For this reason, content of C shall be 0.02% or more and 0.07% or less.

Si:0.5〜2.0%
Siは、予備脱酸に必要な元素であると共に固溶強化元素として引張強度向上に寄与する元素であるが、Siの含有量が0.5%未満であると、十分な強度向上の効果が得られない。また、Siの含有量は、2.0%超であると、加工性が劣化する。このため、Siの含有量は、0.5%以上、2.0%以下とする。
Si: 0.5 to 2.0%
Si is an element necessary for preliminary deoxidation and is an element that contributes to improving tensile strength as a solid solution strengthening element. If the Si content is less than 0.5%, sufficient strength improving effect is obtained. I can't get it. Further, if the Si content exceeds 2.0%, the workability deteriorates. For this reason, content of Si shall be 0.5% or more and 2.0% or less.

Mn:0.5〜1.5%
Mnは、固溶強化元素として鋼板の引張強度向上に寄与する元素であるが、Mnの含有量が0.5%未満であると、十分な引張強度向上の効果が得られない。また、Mnの含有量は、1.5超であると、熱間圧延時のスラブ割れが生じやすくなる。このため、Mnの含有量は、0.5〜1.5%とする。
Mn: 0.5 to 1.5%
Mn is an element that contributes to improving the tensile strength of the steel sheet as a solid solution strengthening element. However, if the Mn content is less than 0.5%, a sufficient effect of improving the tensile strength cannot be obtained. Further, if the Mn content is more than 1.5, slab cracking during hot rolling tends to occur. For this reason, content of Mn shall be 0.5 to 1.5%.

P :0.03%以下(但し、0%超)
Pは、溶鋼の精錬時において不可避的に混入する不純物であり、含有量の増加に伴い靭性等の加工性や溶接性に悪影響を及ぼすとともに疲労特性を低下させる元素である。このため、Pの含有量は、低いほど望ましく、Pの含有量が0.03%超の場合、上述のような加工性等への悪影響、疲労特性の低下が著しいものとなる。このため、Pの含有量は、0.03%以下とする。
P: 0.03% or less (however, over 0%)
P is an impurity that is inevitably mixed during the refining of molten steel, and is an element that adversely affects workability such as toughness and weldability and decreases fatigue characteristics as the content increases. For this reason, the lower the P content, the more desirable. When the P content exceeds 0.03%, the above-described adverse effects on workability and the deterioration of fatigue characteristics become significant. For this reason, the content of P is set to 0.03% or less.

S :0.005%以下(但し、0%超)
Sは、溶鋼の精錬時において不可避的に混入する不純物であり、含有量が多すぎると、鋼中で延伸したMnSを形成し、これが穴広げ性を劣化させる。このため、Sの含有量は、極力低減させるべきであり、0.005%を上限とする。
S: 0.005% or less (however, over 0%)
S is an impurity that is inevitably mixed during refining of the molten steel. When the content is too large, MnS stretched in the steel is formed, and this deteriorates the hole expandability. For this reason, the content of S should be reduced as much as possible, with 0.005% being the upper limit.

Al:0.005〜0.05%
Alは、溶鋼の脱酸に必要な元素である。Alの含有量は、溶鋼を脱酸させる効果を十分に得るために0.005%以上添加する必要がある。一方、Alの含有量は、過剰に添加してもするとその効果は飽和するため、コスト増大を防ぐ観点からその上限を0.05%とする。このため、Alの含有量は、0.005%以上、0.05%以下とする。
Al: 0.005 to 0.05%
Al is an element necessary for deoxidation of molten steel. The Al content needs to be added by 0.005% or more in order to sufficiently obtain the effect of deoxidizing molten steel. On the other hand, if the Al content is excessively added, the effect is saturated, so the upper limit is made 0.05% from the viewpoint of preventing an increase in cost. For this reason, content of Al shall be 0.005% or more and 0.05% or less.

N :0.005%以下(但し、0%超)
Nは、Cよりも高温にてTi及びNbと析出物を形成し、鋼を強化するのに有効なTi及びNbを減少させるばかりでなく、穴広げ値のバラツキを増大させる大きなサイズのTi窒化物を形成する。従って、Nの含有量は、極力低減させるべきであるが、0.005%以下ならば許容できる範囲である。
N: 0.005% or less (however, over 0%)
N forms precipitates with Ti and Nb at a higher temperature than C, and not only reduces Ti and Nb effective in strengthening the steel, but also increases the size of the hole expansion value and increases the size of Ti nitride Form things. Therefore, the N content should be reduced as much as possible, but is acceptable if it is 0.005% or less.

Ti:0.05〜0.2%
Tiは、鋳片の再加熱段階でTiSとして析出することにより延伸した介在物を形成するMnSの析出を抑制する元素である。また、Tiは、圧延後の冷却、巻き取り段階でTiCとして微細に析出して析出強化による鋼板の強度上昇に寄与する元素である。以上の効果を得るために、Tiの含有量が0.05%以上とする必要がある。しかし、Tiの含有量が0.2%超であるとその効果が飽和するだけでなく合金コストの上昇を招く。従ってTiの含有量は、0.05%以上、0.2%以下とする。
Ti: 0.05 to 0.2%
Ti is an element that suppresses precipitation of MnS that forms inclusions that have been stretched by precipitation as TiS in the reheating stage of the slab. Ti is an element that finely precipitates as TiC in the cooling and winding stages after rolling and contributes to an increase in the strength of the steel sheet due to precipitation strengthening. In order to obtain the above effects, the Ti content needs to be 0.05% or more. However, if the Ti content exceeds 0.2%, not only the effect is saturated, but also the alloy cost increases. Accordingly, the Ti content is set to 0.05% or more and 0.2% or less.

Ca:0.0005〜0.01%
Caは、溶鋼の脱硫に必要な元素であり、更には、鋼中のSを球形のCaSとして固定することにより延伸した介在物を形成するMnSの生成を抑制する元素でもあるため、添加することが必須である。これらの効果を発揮させるために、Caの下限は、0.0005%とする。一方、Caが過多に鋼中に含まれると、製造コストの増加を招くので、Caの上限は0.01%とする。
Ca: 0.0005 to 0.01%
Ca is an element necessary for desulfurization of molten steel. Furthermore, Ca is also an element that suppresses the formation of MnS that forms elongated inclusions by fixing S in the steel as spherical CaS. Is essential. In order to exert these effects, the lower limit of Ca is 0.0005%. On the other hand, if Ca is excessively contained in the steel, the manufacturing cost increases, so the upper limit of Ca is 0.01%.

以上が、本発明の基本成分の限定理由であるが、本発明においては、必要に応じて、Nb、Cu、Cr、Ni、B、REMの成分のうち、何れか一種又は二種以上を含有していてもよい。Nb、Cu、Cr、Ni、Bは、析出強化若しくは固溶強もしくは組織微細化強化により熱延鋼板の強度を向上させる効果がある元素である。   The above is the reason for limiting the basic component of the present invention. In the present invention, if necessary, one or more of Nb, Cu, Cr, Ni, B, and REM components are contained. You may do it. Nb, Cu, Cr, Ni, and B are elements that have an effect of improving the strength of the hot-rolled steel sheet by precipitation strengthening, solid solution strength, or structure refinement strengthening.

Nb;0.05%以下(但し、0%超)
Nbは、微量の添加で組織が微細化し強度を増加させる効果があるので、添加することが好ましい。しかし、Nbは、その添加量が0.05%超であると、Nbには再結晶抑制効果があるため未再結晶域圧延集合組織が増大して、{211}面のX線ランダム強度比が過度に強くなってしまい、穴広げ性の劣化を招くことになる。このため、Nbは、0.05%を上限として添加することが好ましい。
Nb: 0.05% or less (however, over 0%)
Nb is preferably added because a small amount of Nb has the effect of refining the structure and increasing the strength. However, if the amount of Nb added exceeds 0.05%, Nb has an effect of suppressing recrystallization, so that the non-recrystallized zone rolling texture increases and the X-ray random intensity ratio of {211} plane Becomes excessively strong, resulting in deterioration of hole expansibility. For this reason, it is preferable to add Nb with 0.05% as an upper limit.

Cu:1.0%以下(但し、0%超)
Cuの含有量は、1.0%超であると強度向上の効果が飽和するため、上限を1.0%として添加することが好ましい。
Cu: 1.0% or less (however, over 0%)
If the Cu content is more than 1.0%, the effect of improving the strength is saturated. Therefore, it is preferable to add Cu at an upper limit of 1.0%.

Cr:1.0%以下(但し、0%超)
Crの添加量は、1.0%超であると強度向上の効果が飽和するため、1.0%を上限として添加することが好ましい。
Cr: 1.0% or less (however, over 0%)
If the addition amount of Cr exceeds 1.0%, the effect of improving the strength is saturated. Therefore, it is preferable to add Cr at an upper limit of 1.0%.

Ni:1.0%以下(但し、0%超)
Niの添加量は、1.0%超であると強度向上の効果が飽和するため、1.0%を上限として添加することが好ましい。
Ni: 1.0% or less (however, over 0%)
If the amount of Ni is more than 1.0%, the effect of improving the strength is saturated, so it is preferable to add Ni at an upper limit of 1.0%.

B :1.0%以下(但し、0%超)
Bの含有量は、0.005%超であると強度向上の効果が飽和するため、0.005%を上限として添加することが好ましい。
B: 1.0% or less (however, over 0%)
When the content of B is more than 0.005%, the effect of improving the strength is saturated, so 0.005% is preferably added as the upper limit.

REM:0.0005〜0.01%
REM(希土類元素)は、破壊の起点となったり、加工性を劣化させる原因となる非金属介在物の形態を変化させて無害化する元素である。REMの含有量は、0.0005%未満であるとその効果が発揮されず、また、0.01%超添加してもその効果が飽和して経済性が低下する。このため、REMの含有量は、0.005%以上、0.01%以下として添加することが好ましい。
REM: 0.0005 to 0.01%
REM (rare earth element) is an element that becomes harmless by changing the form of non-metallic inclusions that can be a starting point of destruction or cause deterioration of workability. If the content of REM is less than 0.0005%, the effect is not exhibited, and even if added over 0.01%, the effect is saturated and the economy is lowered. For this reason, it is preferable to add REM content as 0.005% or more and 0.01% or less.

また、本発明においては、必要に応じて、Zr、Sn、Co、Zn、W、Mgのうち、何れか一種又は二種以上を更に添加してもかまわない。   In the present invention, one or more of Zr, Sn, Co, Zn, W, and Mg may be added as necessary.

次に本発明を適用した熱延鋼板における集合組織、ミクロ組織の限定理由について説明する。   Next, the reasons for limiting the texture and microstructure in the hot rolled steel sheet to which the present invention is applied will be described.

圧延面と平行な{211}面のX線ランダム強度比 : 2.2以下
本発明において重要な特性値である。この特性値は、熱間圧延を施した熱延鋼板から得られる試料を用いてX線回折強度の測定をすることによって得られる。この{211}面のX線ランダム強度比が2.2超であると穴広げ値の平均値λaveが80%以上、その下限値λminが60%以上の鋼板を得ることができない。
X-ray random intensity ratio of {211} plane parallel to the rolling surface: 2.2 or less This is an important characteristic value in the present invention. This characteristic value is obtained by measuring the X-ray diffraction intensity using a sample obtained from a hot-rolled steel sheet subjected to hot rolling. When the X-ray random intensity ratio of the {211} plane is more than 2.2, it is not possible to obtain a steel sheet having an average value λ ave of hole expansion values of 80% or more and a lower limit value λ min of 60% or more.

介在物の圧延方向長さの総和M:0.25mm/mm以下
本発明において重要な特性値である。本発明では、穴広げ性を良好とするため、介在物の圧延方向長さの総和Mを0.25mm/mm以下とする必要がある。ここでいう介在物の圧延方向長さの総和Mの意味は、上述した通りである。本発明では、従来より穴広げ性を劣化させる効果があることを知られている延伸介在物のみならず、所定の配列をした介在物群の圧延方向長さを抑制している点に特徴がある。この介在物の圧延方向長さの総和Mが0.25mm/mm超であると、穴広げ値の平均値λaveが80%以上、その下限値λminが60%以上、その標準偏差σが10%以下の鋼板を得ることができない。
Total M in the rolling direction length of inclusions: 0.25 mm / mm 2 or less This is an important characteristic value in the present invention. In the present invention, the total length M of inclusions in the rolling direction needs to be 0.25 mm / mm 2 or less in order to improve the hole expansion property. The meaning of the total sum M of the inclusions in the rolling direction here is as described above. In the present invention, not only the stretched inclusions that are known to have an effect of deteriorating the hole expanding property than the conventional one, but also the feature is that the length in the rolling direction of inclusions having a predetermined arrangement is suppressed. is there. When the total length M in the rolling direction of the inclusions is more than 0.25 mm / mm 2 , the average value λ ave of the hole expansion value is 80% or more, the lower limit value λ min is 60% or more, and its standard deviation σ However, it is not possible to obtain a steel sheet with 10% or less.

本発明における鋼板のミクロ組織は、優れた穴広げ性(バーリング加工性)を確保するために、フェライト組織、ベイナイト組織又はこれらの混合組織である必要がある。より良好な穴広げ性を得る観点からはベイナイト単相が好ましい。これは、フェライト単相組織の場合、組成のばらつきによっては粒界に若干のセメンタイト(鉄炭化物)が生成する可能性もあり、それにより延性破壊が促進されるためと考えられる。また、鋼板のミクロ組織中には、フェライト組織、ベイナイト組織の他のものとして、不可避的に含まれるパーライト、マルテンサイト、残留オーステナイトが、面積分率で5%以下含まれることが許容される。例えば、パーライトが面積分率で5%超含まれてしまうと、穴広げ値の平均値λaveが80%以上、その下限値λminが60%以上の鋼板を得ることができなくなってしまう可能性がある。 The microstructure of the steel sheet in the present invention needs to be a ferrite structure, a bainite structure, or a mixed structure thereof in order to ensure excellent hole expandability (burring workability). From the viewpoint of obtaining better hole expansibility, a bainite single phase is preferable. This is thought to be because, in the case of a ferrite single phase structure, some cementite (iron carbide) may be generated at the grain boundary depending on the variation in composition, which promotes ductile fracture. Further, in the microstructure of the steel sheet, pearlite, martensite, and retained austenite which are inevitably included as other ferrite structure and bainite structure are allowed to be contained in an area fraction of 5% or less. For example, if pearlite is included in an area fraction exceeding 5%, a steel sheet having an average value λ ave of hole expansion values of 80% or more and a lower limit value λ min of 60% or more may not be obtained. There is sex.

次に、本発明を適用した熱延鋼板を得るための好ましい製造方法について説明する。以下、各製造条件の限定理由について、詳細に述べる。   Next, a preferable manufacturing method for obtaining a hot-rolled steel sheet to which the present invention is applied will be described. Hereinafter, the reasons for limiting each manufacturing condition will be described in detail.

本発明においては、製鋼工程において、鋼成分が上述した所定範囲内となるように調整することと、上述のような介在物の圧延方向長さの総和Mが小さくなるように溶鋼環流の制御を行うこととが必須となる。   In the present invention, in the steelmaking process, the steel components are adjusted so as to be within the predetermined range described above, and the control of the molten steel reflux is performed so that the total sum M of the lengths in the rolling direction of the inclusions as described above becomes small. To do is essential.

製鋼工程においては、高炉等によって溶銑を得た後に、これを転炉にて溶鋼としたうえで、得られた溶鋼を各種の二次精錬で溶製して上述の所定範囲の成分含有量となるよう成分調整を行うことになる。   In the steelmaking process, after obtaining hot metal with a blast furnace or the like, after making it into molten steel in a converter, the obtained molten steel is melted by various secondary refining and the above-mentioned predetermined range of component contents and The components are adjusted so that

ここで、溶鋼を溶製するに際して、脱硫フラックスを除去して介在物の圧延方向長さの総和Mを低減するために、RH(Ruhrstahl Heraeus)等の二次精練装置を用いた溶鋼脱硫時に、脱硫フラックス添加後に溶鋼を3.0回以上、二次精練装置内で環流させることが重要となる。この理由について説明する。   Here, when melting the molten steel, in order to remove the desulfurization flux and reduce the total length M of the inclusions in the rolling direction, the molten steel is desulfurized using a secondary refining apparatus such as RH (Ruhrstahl Heraeus). After adding the desulfurization flux, it is important to recirculate the molten steel 3.0 times or more in the secondary smelting apparatus. The reason for this will be described.

図7に、表1に示す成分系の鋼を溶製する際の二次精錬工程における溶鋼環流回数と介在物の圧延方向長さの総和Mとの関係を示す。この図7に示すように、環流回数が3.0回以上の場合に介在物の圧延方向長さの総和Mが0.25mm/mm以下に低減していることが分かる。 FIG. 7 shows the relationship between the number of molten steel recirculations and the total length M of inclusions in the secondary refining process when melting the component steels shown in Table 1. As shown in FIG. 7, it can be seen that when the number of recirculations is 3.0 or more, the total length M of inclusions in the rolling direction is reduced to 0.25 mm / mm 2 or less.

溶鋼の環流回数については、単位時間当たりに二次精錬装置内で循環させる溶鋼量のことを意味する溶鋼の環流速度Q(ton/min)と、脱硫フラックス添加後の溶鋼環流時間(min)と二次精錬工程において処理すべき対象の溶鋼量(ton)とから、以下の式(5)、(6)に基づき求めることができる。

Figure 2011058022
Figure 2011058022
Regarding the number of times of recirculation of the molten steel, the recirculation velocity Q (ton / min) of the molten steel, which means the amount of molten steel circulated in the secondary refining device per unit time, and the molten steel recirculation time (min) after adding the desulfurization flux It can obtain | require based on the following formula | equation (5) and (6) from the amount of molten steel (ton) of the object which should be processed in a secondary refining process.
Figure 2011058022
Figure 2011058022

ここで、上述の溶鋼の環流速度Qについては、種々の算出式があるが、例えば「大量生産規模における不純物元素の精練限界」((株)日本鉄鋼協会高温精練プロセス部会精練フォーラム 日本学術振興会製鋼第19委員会反応プロセス研究会,平成8年3月,184頁〜187頁)に開示されている下記式(7)に基づき求めればよい。なお、下記式(7)における環流ガス流量は、0℃、1atmの条件下での1分間当たりの環流ガスの流量を意味する。

Figure 2011058022
Q :環流速度(ton/min)
V :環流ガス流量(L/min)
D :浸漬管内径(m)
P0:真空槽内圧力(Pa)
P1:環流ガス吹込位置圧力(Pa)
k :定数(二次精練装置による定数) Here, there are various calculation formulas for the recirculation velocity Q of the molten steel described above. For example, “refining limit of impurity element in mass production scale” (Japan Steel Association High Temperature Smelting Process Group Scouring Forum Japan Society for the Promotion of Science) It may be obtained based on the following formula (7) disclosed in the Steelmaking 19th Committee Reaction Process Study Group, March 1996, pages 184 to 187). In addition, the reflux gas flow rate in the following formula (7) means the flow rate of the reflux gas per minute under the conditions of 0 ° C. and 1 atm.
Figure 2011058022
Q: recirculation velocity (ton / min)
V: Circulating gas flow rate (L / min)
D: Immersion tube inner diameter (m)
P0: Vacuum chamber pressure (Pa)
P1: Circulating gas injection position pressure (Pa)
k: Constant (constant by secondary scouring device)

図8は、溶鋼を溶製する二次精錬工程を行うにあたって二次精錬装置としてRHを用いた場合のそのRHの構成を示す模式図である。二次精錬装置1は、溶鋼鍋2中に脱ガス槽3内に連通された二本の浸漬管4a、4bが浸漬されて構成されている。また、この二次精錬装置1は、環流ガス吹込管5から溶鋼鍋2内の溶鋼6に供給されるAr等の環流ガスが一方の浸漬管4a内に下方から吹き込まれるよう構成されている。二次精錬装置1における溶鋼鍋2内の溶鋼6は、溶鋼鍋2から一方の浸漬管4aを介して上昇して脱ガス槽3に入り、脱ガス処理後に脱ガス槽3から他方の浸漬管4bを介して溶鋼鍋2に下降して戻るよう構成されている。溶鋼鍋2内の溶鋼6中には、環流ガス吹込管5又は別途設けた管から脱硫フラックスが吹き込まれており、溶鋼6が環流ガスによって攪拌されることによって溶鋼6の脱硫が行なわれることになる。   FIG. 8 is a schematic diagram showing the configuration of RH when RH is used as a secondary refining apparatus in performing a secondary refining process for melting molten steel. The secondary refining apparatus 1 is configured by immersing two dip tubes 4 a and 4 b communicated in a degassing tank 3 in a molten steel pan 2. Further, the secondary refining apparatus 1 is configured such that a reflux gas such as Ar supplied from the reflux gas blowing pipe 5 to the molten steel 6 in the molten steel pan 2 is blown into the one immersion pipe 4a from below. The molten steel 6 in the molten steel pan 2 in the secondary refining apparatus 1 rises from the molten steel pan 2 through one dip tube 4a and enters the degas tank 3, and after the degas treatment, the degas tank 3 and the other dip pipe It is comprised so that it may descend | fall and return to the molten steel pan 2 via 4b. The desulfurization flux is blown into the molten steel 6 in the molten steel pan 2 from the circulating gas blowing pipe 5 or a separately provided pipe, and the molten steel 6 is desulfurized by being stirred by the circulating gas. Become.

なお、ここでは二次精錬装置としてRHを用いた例を示したが、他のDH(Dortmund Horde)、LF(Ladle Furnace)等の二次精練装置を用いても構わないことは言うまでもない。   In addition, although the example which used RH as a secondary refining apparatus was shown here, it cannot be overemphasized that other secondary refining apparatuses, such as DH (Dortmund Horde) and LF (Ladle Furnace), may be used.

以上の点を除けば、製鋼工程中の他の工程について、特にその条件を限定するものではない。二次精錬後においては、二次精錬によって得られた溶鋼から、通常の連続鋳造、又はインゴット法による鋳造の他、薄スラブ鋳造などの方法で鋳造して鋳片を得るようにすればよい。得られた鋳片は、図9に示すような条件での熱間圧延工程を行う。   Except for the above points, the conditions are not particularly limited for other processes in the steelmaking process. After secondary refining, cast steel may be obtained by casting from molten steel obtained by secondary refining by a method such as thin continuous slab casting, in addition to normal continuous casting or ingot casting. The obtained slab is subjected to a hot rolling process under conditions as shown in FIG.

鋳片や鋳片を切断して得られる鋼片を加熱するスラブ加熱工程におけるスラブ加熱温度は、例えば、1180℃以上であればよいが、1200℃以上であることが望ましい。これは、1200℃未満で鋳片等を加熱した場合に、TiやNbを含む析出物がスラブ中に十分に溶解せずに粗大化し、TiやNbの析出物による析出強化能が得られず引張強度が低下してしまうためである。更には、再加熱によりMnSを溶解させてSをTiSとして析出させることにより、延伸介在物となるMnSを抑制する観点からも1200℃以上とすることが望ましい。以上の観点からスラブ加熱温度は高いほど好ましく、1250℃以上とすることが更に望ましい。   The slab heating temperature in the slab heating step for heating a slab or a steel slab obtained by cutting the slab may be, for example, 1180 ° C. or higher, but is preferably 1200 ° C. or higher. This is because when slabs are heated at less than 1200 ° C., precipitates containing Ti and Nb are not sufficiently dissolved in the slab and are coarsened, and the precipitation strengthening ability due to the precipitates of Ti and Nb cannot be obtained. This is because the tensile strength is lowered. Furthermore, it is desirable that the temperature be set to 1200 ° C. or higher from the viewpoint of suppressing MnS serving as a stretch inclusion by dissolving MnS by reheating and precipitating S as TiS. From the above viewpoint, the slab heating temperature is preferably as high as possible, and more preferably 1250 ° C. or more.

スラブ加熱工程で加熱する鋳片や鋼片の厚みについては、特に問うものではないが、介在物の圧延方向への延伸を防ぐ観点からは、薄いほうが好ましく、250mm以下とすることが好ましい。   The thickness of the slab or steel slab to be heated in the slab heating process is not particularly limited, but from the viewpoint of preventing the inclusions from being stretched in the rolling direction, the thickness is preferably 250 mm or less.

スラブ加熱工程の後に行なう粗圧延工程での圧延終了温度は特に問うものではないが、動的な再結晶を促進し結晶方位のランダム化を促進する観点から1150℃以上であることが望ましい。   Although the rolling end temperature in the rough rolling step performed after the slab heating step is not particularly limited, it is preferably 1150 ° C. or higher from the viewpoint of promoting dynamic recrystallization and promoting randomization of crystal orientation.

粗圧延後の素材厚み(粗バー厚み)は、仕上げ圧延での集合組織の配向を弱める観点からは薄い方が好ましく、35mm以下とすることが望ましい。   The raw material thickness (rough bar thickness) after rough rolling is preferably thin from the viewpoint of weakening the texture orientation in finish rolling, and is desirably 35 mm or less.

粗圧延工程の後は、粗圧延工程によって得られた粗バーに対して更に圧延を施す仕上げ圧延工程を行う。この仕上げ圧延工程における仕上げ圧延終了温度は、未再結晶状態の圧延集合組織が残存するのを避け、{211}面のX線ランダム強度比を2.2以下として穴広げ値を良好とするために、960℃以上の温度域とする必要がある。仕上げ圧延終了温度の上限は、本発明の効果を得るためには特に定める必要はないが、操業上スケール疵が発生する可能性があるため、1000℃以下とすることが好ましい。   After the rough rolling process, a finish rolling process for further rolling the rough bar obtained by the rough rolling process is performed. The finish rolling finish temperature in this finish rolling process is to avoid leaving an unrecrystallized rolled texture, and to make the X-ray random intensity ratio of the {211} plane 2.2 or less and to improve the hole expansion value. Furthermore, it is necessary to set it as a temperature range of 960 degreeC or more. The upper limit of the finish rolling end temperature is not particularly required to obtain the effect of the present invention, but is preferably set to 1000 ° C. or less because scale wrinkles may occur in operation.

なお、仕上げ圧延工程における仕上げ圧延開始温度は、圧延後において再結晶を促進させる観点からは、高温である方が好ましく、1050℃以上とすることが望ましい。   In addition, the finish rolling start temperature in the finish rolling step is preferably a high temperature from the viewpoint of promoting recrystallization after rolling, and is desirably 1050 ° C. or higher.

また、粗圧延工程と仕上げ圧延工程とを行なうに際しては、粗バーの圧延方向、板幅方向、板厚方向における温度のバラツキを小さく制御するように、各圧延機内又は圧延機間において加熱装置を設置し、熱間圧延中の温度のバラツキを低減させるように制御してもよい。   In addition, when performing the rough rolling process and the finish rolling process, a heating device is used in each rolling mill or between the rolling mills so as to control the variation in temperature in the rolling direction, plate width direction, and plate thickness direction of the rough bar. It may be installed and controlled to reduce temperature variation during hot rolling.

また、粗圧延工程と仕上げ圧延工程との間において、粗圧延により得られる複数の粗バーを互いに接合して、この接合した複数の粗バーに連続して仕上げ圧延を行うエンドレス圧延を行うようにしてもよい。   Further, between the rough rolling process and the finish rolling process, endless rolling is performed in which a plurality of rough bars obtained by rough rolling are joined together, and finish rolling is continuously performed on the joined plurality of rough bars. May be.

また、粗圧延工程と仕上げ圧延工程との間において、必要に応じて高水圧を用いたデスケーリングを行なうようにしてもよい。   Moreover, you may make it perform descaling using a high hydraulic pressure between a rough rolling process and a finish rolling process as needed.

仕上げ圧延工程の後は、仕上げ圧延によって得られた熱延鋼板をランアウトテーブルで冷却する冷却工程を行う。冷却工程における冷却速度(℃/sec)は、例えば、18℃/sec以上であればよいが、20℃/sec以上であることが望ましい。これは、冷却速度が20℃/sec未満であると、ランアウトテーブルでの冷却時に析出したTiCが粗大化することにより、微細なTiCによる析出強化の効果が十分得られず引張強度が低下してしまうためである。   After the finish rolling process, a cooling process for cooling the hot-rolled steel sheet obtained by finish rolling with a run-out table is performed. The cooling rate (° C./sec) in the cooling step may be, for example, 18 ° C./sec or more, but is preferably 20 ° C./sec or more. This is because when the cooling rate is less than 20 ° C./sec, TiC precipitated during cooling on the run-out table is coarsened, so that the effect of precipitation strengthening due to fine TiC cannot be obtained sufficiently and the tensile strength decreases. It is because it ends.

冷却工程では、TiCの析出を促進して引張強度を向上させるために、適宜、図8に示すような、20℃/sec以上の冷却速度での冷却中に、冷却速度を15℃/秒以下とした緩冷却を行ない、その後に再度冷却速度を20℃/sec以上として冷却を行なうようにしてもよい。この緩冷却を行なう温度域、時間は、概ねTiCの析出を促進するため550〜650℃の温度域、5秒以下の時間とするのが最適である。緩冷却の時間が長すぎる場合、パーライトが生成し穴広げ性を劣化させる場合があるので、この時間は必要以上に長くすることは好ましくない。なお、図9においては、冷却工程に行なう20℃/sec以上の冷却速度での冷却を強冷却とし、15℃/sec以下の冷却速度での冷却を緩冷却として示している。   In the cooling process, in order to promote the precipitation of TiC and improve the tensile strength, as shown in FIG. 8, the cooling rate is set to 15 ° C./sec or less during cooling at a cooling rate of 20 ° C./sec or more as appropriate. It is also possible to perform the slow cooling described above, and then cool again at a cooling rate of 20 ° C./sec or more. The temperature range and time for performing this slow cooling are optimally set to a temperature range of 550 to 650 ° C. and a time of 5 seconds or less in order to promote precipitation of TiC. If the slow cooling time is too long, pearlite may be generated and the hole expandability may be deteriorated. Therefore, it is not preferable to set this time longer than necessary. In FIG. 9, cooling at a cooling rate of 20 ° C./sec or more performed in the cooling process is shown as strong cooling, and cooling at a cooling rate of 15 ° C./sec or less is shown as slow cooling.

冷却工程の後は、冷却工程を経て得られた熱延鋼板を巻き取る巻き取り工程を行う。巻き取り工程においては、400℃以上550℃以下の温度域で熱延鋼板を巻き取る必要があり、冷却工程ではこのような温度域になるまで冷却する。巻き取り温度が400℃未満であると、Ti等の炭化物が粒界に析出しにくくなり、これら炭化物による析出強化能が十分に得られない。また、巻き取り温度が550℃超であると、加工性に好ましくないパーライト等の粗大炭化物を含む相が生成する恐れがある。従って、巻き取り工程における巻取り温度は、400℃以上550℃以下とする。なお、巻き取り工程の後は、巻き取り温度から室温や所定の温度域にまで徐冷することになる。   After the cooling step, a winding step for winding the hot-rolled steel sheet obtained through the cooling step is performed. In the winding process, it is necessary to wind the hot-rolled steel sheet in a temperature range of 400 ° C. or more and 550 ° C. or less, and in the cooling process, cooling is performed until such a temperature range is reached. When the coiling temperature is less than 400 ° C., carbides such as Ti are difficult to precipitate at the grain boundaries, and the precipitation strengthening ability by these carbides cannot be sufficiently obtained. Further, when the coiling temperature is higher than 550 ° C., a phase containing coarse carbides such as pearlite, which is not preferable for workability, may be generated. Therefore, the winding temperature in the winding process is set to 400 ° C. or more and 550 ° C. or less. In addition, after a winding process, it anneals from a winding temperature to room temperature and a predetermined temperature range.

なお、可動転位の導入による延性の向上や鋼板形状の矯正を図ることを目的として、全工程終了後において圧下率0.1%以上2%以下のスキンパス圧延を施すようにしてもよい。また、全工程終了後において、熱延鋼板の表面に付着しているスケールの除去を目的として、得られた熱延鋼板を酸洗するようにしてもよい。また、熱間圧延終了後又は酸洗後に、得られた熱延鋼板に対してインライン若しくはオフラインで圧下率10%以下のスキンパス、又は圧下率40%以下の冷間圧延を施してもよい。   For the purpose of improving ductility by introducing movable dislocations and correcting the shape of the steel sheet, skin pass rolling with a rolling reduction of 0.1% or more and 2% or less may be performed after the completion of all steps. Moreover, after completion | finish of all the processes, you may make it pickle the obtained hot-rolled steel plate for the purpose of the removal of the scale adhering to the surface of a hot-rolled steel plate. Further, after completion of hot rolling or after pickling, the obtained hot-rolled steel sheet may be subjected to a skin pass with a reduction rate of 10% or less or cold rolling with a reduction rate of 40% or less in-line or offline.

また、本発明を適用した熱延鋼板は、鋳造後、各圧延工程後、冷却後の何れかの場合において、溶融めっきラインにて熱処理を施す、若しくは全工程終了後の熱延鋼板に対して溶融めっき法による表面処理を施すようにして、熱延鋼板の耐食性を向上させてもよい。また、溶融めっきに加えて合金化処理を施すようにしてもよいのは勿論である。   Moreover, the hot-rolled steel sheet to which the present invention is applied is subjected to heat treatment in a hot dipping line in any case after casting, after each rolling process, and after cooling, or with respect to the hot-rolled steel sheet after completion of all the processes. You may improve the corrosion resistance of a hot-rolled steel plate by performing the surface treatment by a hot dipping method. Of course, alloying treatment may be performed in addition to hot dipping.

次に、本発明を適用した高強度熱延鋼板及びその製造方法の実施例について詳細に説明する。   Next, examples of the high-strength hot-rolled steel sheet to which the present invention is applied and the manufacturing method thereof will be described in detail.

まず、下記の表2に示す化学成分を有する鋼番A〜Pの溶鋼を転炉の溶製後、二次精錬を行なうとともに、この二次精錬中に脱硫フラックス除去のための環流を行うことによって得た上で、連続鋳造により鋼片を得て、その後に直接又は再加熱した後に、表3に示す製造条件を経て板厚2.9mmの熱延鋼板を得た。ここで、脱硫フラックスはCaO、CaF、MgOが重量比でほぼ等量混合されたものを使用した。環流は図7に示されるようなRHを二次精錬装置として用いて行った。このようにして得られた熱延鋼板の機械的性質並びにミクロ組織等を表4に示す。表2〜4における下線は、本発明の範囲外であるか、好ましい範囲外であることを意味する。また、上述の式(7)における定数kは、4とした。また、表4における「機械的性質評価」では、λaveが80%以上、λminが60%以上、σが10%以下、引張強度が780MPa以上のものに丸印を記載し、λave、λmin、σが同条件を満たすものの引張強度が780MPa未満のものを三角印で記載し、λave、λmin、σの何れかが同条件を満たさないものをばつ印で記載した。 First, after refining the molten steel of steel numbers A to P having the chemical components shown in Table 2 below in the converter, secondary refining is performed, and recirculation for removing the desulfurization flux is performed during the secondary refining. After being obtained by the above, a steel piece was obtained by continuous casting, and then directly or reheated, and then a hot rolled steel sheet having a thickness of 2.9 mm was obtained through the production conditions shown in Table 3. Here, the desulfurization flux used was one in which CaO, CaF 2 and MgO were mixed in substantially equal amounts by weight. The reflux was performed using RH as shown in FIG. 7 as a secondary refining device. Table 4 shows the mechanical properties and microstructure of the hot-rolled steel sheet thus obtained. Underlines in Tables 2 to 4 mean that they are outside the scope of the present invention or outside the preferred ranges. The constant k in the above equation (7) is 4. Further, in the “mechanical property evaluation” in Table 4, λ ave is 80% or more, λ min is 60% or more, σ is 10% or less, and a tensile strength is 780 MPa or more, and a circle is described, and λ ave , Although λ min and σ satisfy the same conditions, those having a tensile strength of less than 780 MPa are indicated by triangular marks, and those in which any of λ ave , λ min , and σ does not satisfy the same conditions are indicated by cross marks.

Figure 2011058022
Figure 2011058022

Figure 2011058022
Figure 2011058022

Figure 2011058022
Figure 2011058022

穴広げ値は、上述のように、日本鉄鋼連盟規格JFS T 1001−1996記載の穴広げ試験方法に従い評価した。ここで、穴広げ試験時には、ばらつきも評価するため、穴広げ値の平均値λaveと標準偏差σを求めた。穴広げ値の平均値λaveは、鋼板の板幅方向中央位置を中心として板幅方向に300mmの範囲で切り出したサンプルから採取した30枚の試験片による試験値の算術平均とした。穴広げ値の下限値λminは、上述の式(1)に基づき求め、穴広げ値の標準偏差σは上記の式(2)に基づき求めた。 As described above, the hole expansion value was evaluated according to the hole expansion test method described in the Japan Iron and Steel Federation Standard JFS T 1001-1996. Here, in order to evaluate variation during the hole expansion test, an average value λ ave and standard deviation σ of the hole expansion values were obtained. The average value λ ave of the hole expansion values was the arithmetic average of the test values of 30 test pieces taken from a sample cut out in a range of 300 mm in the plate width direction with the center position in the plate width direction of the steel plate as the center. The lower limit value λ min of the hole expansion value was determined based on the above equation (1), and the standard deviation σ of the hole expansion value was determined based on the above equation (2).

引張試験値は、上述のように、得られた熱延鋼板の板幅方向中央部から板幅方向と平行なJIS Z 2201記載の5号試験片を加工し、得られた試験片についてJIS Z 2241記載の試験方法を行なうことによって評価したものである。   As described above, the tensile test value is obtained by processing the No. 5 test piece described in JIS Z 2201 parallel to the plate width direction from the center portion in the plate width direction of the obtained hot-rolled steel sheet, and JIS Z for the obtained test piece. It was evaluated by performing the test method described in 2241.

集合組織は、圧延面と平行な{211}面のX線ランダム強度比を求めることにより評価した。X線ランダム強度比を求めるにあたっては、板幅方向中央位置を中心として板幅方向に20mm、圧延方向に20mmの大きさで切り出した試験片を板厚tに対して1/2t位置まで研削した後、化学研磨されたサンプルにより測定した。   The texture was evaluated by determining the X-ray random intensity ratio of the {211} plane parallel to the rolled surface. In obtaining the X-ray random intensity ratio, a test piece cut out in a size of 20 mm in the plate width direction and 20 mm in the rolling direction with the center position in the plate width direction as the center was ground to a 1/2 t position with respect to the plate thickness t. Thereafter, the measurement was performed using a chemically polished sample.

ミクロ組織は、板幅方向中央部から図1に示すようなL断面が得られるよう切り出した試料を研磨し、ナイタール試薬を用いてこれをエッチングし、板厚中央部を光学顕微鏡を用いて200〜500倍の倍率で観察し、同定した。表4の欄「ミクロ組織」には、フェライト、ベイナイト、パーライトのうち、光学顕微鏡観察により確認できたものを記載することとした。フェライト、ベイナイト、パーライトのうち、二相が確認された場合は、二相のうち面積分率が少ない相の面積分率を表4中に記載することとした。介在物の評価方法は前述と同じである。   The microstructure was obtained by polishing a sample cut out from the central portion in the plate width direction so as to obtain an L cross section as shown in FIG. 1, etching it using a Nital reagent, and using a light microscope to measure the central portion of the plate thickness with an optical microscope. Observation and identification at a magnification of ˜500 times. In the column “Microstructure” in Table 4, the ferrite, bainite, and pearlite that can be confirmed by optical microscope observation are described. When two phases were confirmed among ferrite, bainite, and pearlite, the area fraction of the phase with the smaller area fraction of the two phases was described in Table 4. The inclusion evaluation method is the same as described above.

本発明に沿うものは、鋼番1〜12、鋼番18、鋼番20及び鋼番22である。これらの熱延鋼板は、所定量の鋼成分を含有し、更に{211}面のX線ランダム強度比が2.2以下であり、かつ介在物の圧延方向長さの総和Mが0.25mm/mm以下であることを特徴とし、穴広げ値の平均値λaveが80%以上であり、また穴広げ値の下限値λminも60%以上が得られており、更にはその大半が780MPaと優れた引張強度が得られている。 In accordance with the present invention are steel numbers 1-12, steel number 18, steel number 20 and steel number 22. These hot-rolled steel sheets contain a predetermined amount of steel components, and the {211} plane X-ray random strength ratio is 2.2 or less, and the total length M of inclusions in the rolling direction is 0.25 mm. / Mm 2 or less, the average value λ ave of the hole expansion value is 80% or more, the lower limit value λ min of the hole expansion value is 60% or more, and most of them Excellent tensile strength of 780 MPa is obtained.

鋼番18、鋼番20及び鋼番22は、以下の理由によって本発明の好ましい範囲外である。鋼番18は、スラブ加熱温度が所定より低いため、引張強度が780MPaより低下してしまっている。鋼番20は、ランアウトテーブルでの冷却速度が所定より低いため、微細なTiCによる析出強化の効果が十分得られず、引張強度が780MPaより低下してしまっている。鋼番22は、巻き取り温度が所定より低いため、十分な析出強化が得られず、目的とする引張強度が得られていない。   Steel numbers 18, 20, and 22 are outside the preferred range of the present invention for the following reasons. Steel No. 18 has a tensile strength lower than 780 MPa because the slab heating temperature is lower than a predetermined value. In Steel No. 20, the cooling rate at the run-out table is lower than a predetermined value, so that the effect of precipitation strengthening by fine TiC cannot be sufficiently obtained, and the tensile strength is lowered from 780 MPa. Steel No. 22 has a coiling temperature lower than a predetermined value, so that sufficient precipitation strengthening cannot be obtained and the intended tensile strength cannot be obtained.

上記以外の鋼番は、以下の理由によって本発明の範囲外である。鋼番13〜17は、製鋼工程における環流回数が小さいため、介在物の圧延方向長さの総和Mが2.2mm/mm超となっており、目的とする穴広げ値の平均値λave、下限値λmin及び標準偏差σが得られていない。鋼番19は、仕上げ圧延終了温度が所定より低いため、{211}面のX線ランダム強度比が所定より高くなっており、目的とする穴広げ値の平均値λave、下限値λminが得られていない。鋼番21は、巻き取り温度が所定より高いため、パーライト組織が現れており、目的とする穴広げ値の平均値λave、下限値λminが得られてない。鋼番23は、S量が所定より多いため、介在物の圧延方向長さの総和Mが所定以上となっており、目的とする穴広げ値の平均値λave、下限値λmin及び標準偏差σが得られていない。鋼番24は、Nb量が所定より多いため、{211}面のX線ランダム強度比が高くなっており、目的とする穴広げ値の平均値λave、下限値λminが得られていない。鋼番25は、Ti量が所定より低いため、目的とする引張強度が得られていない。また、鋼番25は、Ti量が所定より低いため、介在物の圧延方向長さの総和Mが所定以上となっており、目的とする穴広げ値の平均値λave、下限値λmin及び標準偏差σが得られていない。 Steel numbers other than the above are outside the scope of the present invention for the following reasons. In Steel Nos. 13 to 17, the total number M of inclusions in the rolling direction is over 2.2 mm / mm 2 because the number of recirculations in the steel making process is small, and the average value λ ave of target hole expansion values The lower limit λ min and the standard deviation σ are not obtained. Steel No. 19 has a finish rolling finish temperature lower than a predetermined value, so that the X-ray random intensity ratio of the {211} plane is higher than a predetermined value. The average value λ ave of the target hole expansion value and the lower limit value λ min are Not obtained. Steel No. 21 has a pearlite structure because the coiling temperature is higher than a predetermined value, and the average value λ ave of the target hole expansion value and the lower limit value λ min are not obtained. Steel No. 23, since S amount is larger than a predetermined rolling direction length of the sum M has become a predetermined value or more, the average value lambda ave of hole expansion value of interest, the lower limit value lambda min and a standard deviation of inclusions σ is not obtained. In Steel No. 24, since the Nb amount is larger than a predetermined value, the X-ray random intensity ratio of the {211} plane is high, and the average value λ ave of the target hole expansion value and the lower limit value λ min are not obtained. . Steel No. 25 does not have the intended tensile strength because the Ti amount is lower than the predetermined value. Further, in Steel No. 25, since the Ti amount is lower than a predetermined value, the total length M of inclusions in the rolling direction is not less than a predetermined value, and the average value λ ave of the target hole expansion value, the lower limit value λ min and The standard deviation σ is not obtained.

Claims (6)

質量%で、
C :0.02〜0.07%、
Si:0.5〜2.0%、
Mn:0.5〜1.5%、
P :0.03%以下(但し、0%超)、
S :0.005%以下(但し、0%超)、
Al:0.005〜0.05%、
N :0.005%以下(但し、0%超)、
Ti:0.05〜0.2%、
Ca:0.0005〜0.01%
を含有し、残部がFe及び不可避的不純物からなる鋼板であって、
そのミクロ組織がフェライト組織、ベイナイト組織又はこれらの混合組織からなり、
圧延面と平行な{211}面のX線ランダム強度比が2.2以下であり、
板幅方向を法線に持つ断面において、圧延方向の直線上に隣り合う他の介在物に対して50μm以下の間隔を空けて並んだ円相当径が3μm以上である介在物の集まりからなり、圧延方向長さが30μm以上の介在物群と、圧延方向の直線上に隣り合う他の介在物に対して50μm超の間隔を空け、円相当径が3μm以上であり、圧延方向長さが30μm以上に延伸されてなる介在物との断面1mm当たりの圧延方向長さの総和が0.25mm以下であること
を特徴とする穴広げ性に優れた高強度熱延鋼板。
% By mass
C: 0.02 to 0.07%,
Si: 0.5 to 2.0%,
Mn: 0.5 to 1.5%
P: 0.03% or less (however, over 0%),
S: 0.005% or less (however, over 0%),
Al: 0.005 to 0.05%,
N: 0.005% or less (however, over 0%),
Ti: 0.05 to 0.2%,
Ca: 0.0005 to 0.01%
And the balance is a steel plate made of Fe and inevitable impurities,
The microstructure consists of a ferrite structure, a bainite structure or a mixed structure thereof,
The X-ray random intensity ratio of the {211} plane parallel to the rolling surface is 2.2 or less,
In a cross section having the plate width direction as a normal line, it consists of a collection of inclusions having an equivalent circle diameter of 3 μm or more arranged at an interval of 50 μm or less with respect to other inclusions adjacent on the straight line in the rolling direction, The inclusion group having a rolling direction length of 30 μm or more is spaced from the other inclusions on the straight line in the rolling direction by more than 50 μm, the equivalent circle diameter is 3 μm or more, and the rolling direction length is 30 μm. A high-strength hot-rolled steel sheet excellent in hole expansibility, characterized in that the total length in the rolling direction per 1 mm 2 cross-section with the inclusions drawn as described above is 0.25 mm or less.
更に質量%で、
Nb:0.05%以下(但し、0%超)、
を含有すること
を特徴とする請求項1に記載の穴広げ性に優れた高強度熱延鋼板。
In addition,
Nb: 0.05% or less (however, over 0%),
The high-strength hot-rolled steel sheet excellent in hole expansibility according to claim 1, comprising:
更に質量%で、
Cu:1.0%以下(但し、0%超)、
Cr:1.0%以下(但し、0%超)、
Ni:1.0%以下(但し、0%超)、
B :0.005%以下(但し、0%超)、
のうち、何れか一種又は二種以上を含有すること
を特徴とする請求項1又は2に記載の穴広げ性に優れた高強度熱延鋼板。
In addition,
Cu: 1.0% or less (however, over 0%),
Cr: 1.0% or less (however, over 0%),
Ni: 1.0% or less (however, over 0%),
B: 0.005% or less (however, over 0%),
The high-strength hot-rolled steel sheet excellent in hole expansibility according to claim 1 or 2, characterized in that any one or more of them are contained.
更に質量%で
REM:0.0005〜0.01%
を含有すること
を特徴とする請求項1〜3の何れか1項に記載の穴広げ性に優れた高強度熱延鋼板。
Further, REM in mass%: 0.0005 to 0.01%
The high-strength hot-rolled steel sheet having excellent hole expansibility according to any one of claims 1 to 3.
請求項1〜4の何れか1項に記載の成分を含有する溶鋼を溶製するに際し、二次精錬装置で脱硫用フラックス添加後に溶鋼を3.0回以上環流させた後、当該溶鋼から得られた鋳片を1200℃以上に加熱した後、粗圧延を行い、次に行う仕上げ圧延を960℃以上の温度域で終了させ、その後、20℃/sec以上の冷却速度で400℃以上550℃以下の温度域まで冷却した後巻き取ること
を特徴とする穴広げ性に優れた高強度熱延鋼板の製造方法。
When molten steel containing the component according to any one of claims 1 to 4 is melted, the molten steel is recirculated at least 3.0 times after the desulfurization flux is added in a secondary refining device, and then obtained from the molten steel. The obtained slab is heated to 1200 ° C. or higher, followed by rough rolling, and the subsequent finish rolling is finished in a temperature range of 960 ° C. or higher, and then 400 ° C. or higher and 550 ° C. at a cooling rate of 20 ° C./sec or higher. A method for producing a high-strength hot-rolled steel sheet excellent in hole expansibility, characterized by winding after cooling to the following temperature range.
20℃/sec以上の冷却速度での上記冷却中に、冷却速度を15℃/sec以下とした緩冷却を行ない、その後に再度冷却速度を20℃/sec以上として上記冷却を行なうこと
を特徴とする請求項5記載の穴広げ性に優れた高強度熱延鋼板の製造方法。
During the cooling at a cooling rate of 20 ° C./sec or more, the cooling is performed at a cooling rate of 15 ° C./sec or less, and then the cooling is performed again at a cooling rate of 20 ° C./sec or more. The manufacturing method of the high intensity | strength hot-rolled steel plate excellent in the hole expansibility of Claim 5.
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