JP2010502544A5 - - Google Patents

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JP2010502544A5
JP2010502544A5 JP2009526617A JP2009526617A JP2010502544A5 JP 2010502544 A5 JP2010502544 A5 JP 2010502544A5 JP 2009526617 A JP2009526617 A JP 2009526617A JP 2009526617 A JP2009526617 A JP 2009526617A JP 2010502544 A5 JP2010502544 A5 JP 2010502544A5
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copper
gas generant
nitrate
generant composition
extrudable
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JP2009526617A
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JP2010502544A (en
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Priority claimed from US11/511,193 external-priority patent/US20060289096A1/en
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少なくとも1つの非アジ化有機窒素含有燃料と、
塩基性硝酸銅、酸化第二銅、二硝酸ジアミン銅−硝酸アンモニウム混合物、ジアミン銅ビテトラゾール、5アミノテトラゾールと塩基性硝酸塩との反応から生じる銅−硝酸塩錯体及びこれらの組合せの中から選択される少なくとも1つの銅含有化合物であって、前記二硝酸ジアミン銅−硝酸アンモニウム混合物において硝酸アンモニウムが重量率約3から約90パーセントの範囲で前記混合物の中に存在する、銅含有化合物と、
過塩素酸アルカリ金属及び過塩素酸アンモニウムの中から選択される少なくとも1つの過塩素酸物質を含む過塩素酸添加剤であって、該過塩素酸添加剤が、前記ガス発生剤組成物を燃焼させるとき一酸化炭素、アンモニア、二酸化窒素及び一酸化窒素の中から選択される少なくとも1つの化学種の含量が前記過塩素酸添加剤を含まない同様のガス発生剤組成物と比較して低減された気体流出物を生じるために効果的な相対量で存在する、過塩素酸添加剤と、
前記ガス発生剤組成物を押出し成形可能にするために効果的な高分子結合剤と、
を含む押出し成形可能なガス発生剤組成物。
At least one non-azide organic nitrogen-containing fuel;
At least selected from basic copper nitrate, cupric oxide, diamine copper dinitrate-ammonium nitrate mixture, diamine copper bitetrazole, copper-nitrate complex resulting from the reaction of 5-aminotetrazole with basic nitrate and combinations thereof A copper-containing compound, wherein ammonium nitrate is present in the mixture in a weight percentage range of about 3 to about 90 percent in the diamine copper nitrate-ammonium nitrate mixture;
A perchloric acid additive comprising at least one perchloric acid material selected from alkali metal perchlorate and ammonium perchlorate, wherein the perchloric acid additive burns the gas generant composition The content of at least one chemical species selected from carbon monoxide, ammonia, nitrogen dioxide and nitric oxide is reduced as compared to a similar gas generant composition not containing the perchloric acid additive. A perchloric acid additive present in a relative amount effective to produce a gaseous effluent;
An effective polymeric binder to enable extrusion of the gas generant composition;
An extrudable gas generant composition comprising:
前記高分子結合剤がセルロース系材料、天然ゴム、ポリアクリレート、ポリアクリルアミド、ポリウレタン、ポリブタジエン、ポリスチレン、ポリビニルアルコール、ポリビニルアセテート、シリコン及びこれらのうち2つまたはそれ以上の組合せの中から選択されることを特徴とする、請求項1に記載の押出し成形可能なガス発生剤組成物。   The polymer binder is selected from cellulosic materials, natural rubber, polyacrylate, polyacrylamide, polyurethane, polybutadiene, polystyrene, polyvinyl alcohol, polyvinyl acetate, silicon and combinations of two or more thereof. The extrudable gas generant composition according to claim 1, wherein 前記高分子結合剤が組成重量率1から20パーセントの相対量で存在することを特徴とする、請求項1または2に記載の押出し成形可能なガス発生剤組成物。 3. Extrudable gas generant composition according to claim 1 or 2 , characterized in that the polymeric binder is present in a relative amount of 1 to 20 percent by weight composition. 前記少なくとも1つの非アジ化有機窒素含有燃料が組成重量率5から60パーセントの相対量で存在することを特徴とする、請求項1から3のいずれか1項に記載の押出し成形可能なガス発生剤組成物。 4. Extrudable gas generation according to any one of claims 1 to 3 , characterized in that the at least one non-azide organic nitrogen-containing fuel is present in a relative amount of 5 to 60 percent by weight of composition. Agent composition. 前記少なくとも1つの銅含有化合物が組成重量率10から80パーセントの相対量で存在することを特徴とする、請求項1から4のいずれか1項に記載の押出し成形可能なガス発生剤組成物。 The extrudable gas generant composition according to any one of claims 1 to 4 , characterized in that the at least one copper-containing compound is present in a relative amount of 10 to 80 percent by weight of the composition. 前記過塩素酸添加剤が組成重量率1から10パーセントの相対量で存在することを特徴とする、請求項1から5のいずれか1項に記載の押出し成形可能なガス発生剤組成物。 6. Extrudable gas generant composition according to any one of claims 1 to 5 , characterized in that the perchloric acid additive is present in a relative amount of 1 to 10 percent by weight of the composition. 組成重量率5から60パーセントの相対量で存在する少なくとも1つの非アジ化有機窒素含有燃料と、
塩基性硝酸銅、酸化第二銅、二硝酸ジアミン銅−硝酸アンモニウム混合物、ジアミン銅ビテトラゾール、5アミノテトラゾールと塩基性硝酸塩との反応から生じる銅−硝酸塩錯体及びこれらの組合せの中から選択される少なくとも1つの銅含有化合物であって、前記二硝酸ジアミン銅−硝酸アンモニウム混合物において硝酸アンモニウムが重量率約3から約90パーセントの範囲で前記混合物の中に存在し、前記少なくとも1つの銅含有化合物が組成重量率10から80パーセントの相対量で存在する、少なくとも1つの銅含有化合物と、
過塩素酸アルカリ金属及び過塩素酸アンモニウムの中から選択される少なくとも1つの過塩素酸物質を含む過塩素酸添加剤であって、該過塩素酸添加剤が組成重量率1から10パーセントの相対量で存在し、かつ前記ガス発生剤組成物を燃焼させるとき一酸化炭素、アンモニア、二酸化窒素及び一酸化窒素の中から選択される少なくとも1つの化学種の含量が前記過塩素酸添加剤を含まない同様のガス発生剤組成物と比較して低減された気体流出物を生じるために効果的である、過塩素酸添加剤と、
組成重量率1から20パーセントの相対量で存在しかつ前記ガス発生剤組成物を押出し成形可能にするために効果的な高分子結合剤であって、該高分子結合剤がセルロース系材料、天然ゴム、ポリアクリレート、ポリアクリルアミド、ポリウレタン、ポリブタジエン、ポリスチレン、ポリビニルアルコール、ポリビニルアセテート、シリコン及びこれらのうち2つまたはそれ以上の組合せの中から選択される、高分子結合剤と、
を含む請求項1に記載の押出し成形可能なガス発生剤組成物。
At least one non-azide organic nitrogen-containing fuel present in a relative amount of 5 to 60 percent by weight of composition;
At least selected from basic copper nitrate, cupric oxide, diamine copper dinitrate-ammonium nitrate mixture, diamine copper bitetrazole, copper-nitrate complex resulting from the reaction of 5-aminotetrazole with basic nitrate and combinations thereof A copper-containing compound, wherein ammonium nitrate is present in the mixture in a weight percent range of about 3 to about 90 percent in the diamine copper nitrate-ammonium nitrate mixture, and the at least one copper-containing compound is a composition weight percent. At least one copper-containing compound present in a relative amount of 10 to 80 percent;
A perchloric acid additive comprising at least one perchloric acid material selected from alkali metal perchlorates and ammonium perchlorate, wherein the perchloric acid additive has a relative composition weight percentage of 1 to 10 percent. Present in an amount, and when the gas generant composition is burned, the content of at least one chemical species selected from carbon monoxide, ammonia, nitrogen dioxide and nitric oxide includes the perchloric acid additive. A perchloric acid additive that is effective to produce a reduced gas effluent compared to a similar gas generant composition;
A polymeric binder present in a relative amount of 1 to 20 percent by weight and effective to extrude the gas generant composition, wherein the polymeric binder is a cellulosic material, natural A polymeric binder selected from among rubber, polyacrylate, polyacrylamide, polyurethane, polybutadiene, polystyrene, polyvinyl alcohol, polyvinyl acetate, silicone and combinations of two or more thereof;
An extrudable gas generant composition according to claim 1 comprising:
前記少なくとも1つの非アジ化有機窒素含有燃料が硝酸グアニジンを含むことを特徴とする、請求項1から7のいずれか1項に記載の押出し成形可能なガス発生剤組成物。 8. Extrudable gas generant composition according to any one of claims 1 to 7 , characterized in that the at least one non-azide organic nitrogen-containing fuel comprises guanidine nitrate. 前記過塩素酸添加剤が過塩素酸アンモニウム、過塩素酸カリウム、過塩素酸ナトリウム及びこれらの組合せの中から選択されることを特徴とする、請求項1から8のいずれか1項に記載の押出し成形可能なガス発生剤組成物。 9. The perchloric acid additive according to any one of claims 1 to 8 , characterized in that it is selected from ammonium perchlorate, potassium perchlorate, sodium perchlorate and combinations thereof. Extrudable gas generant composition. 前記過塩素酸添加剤が過塩素酸アンモニウムを含むことを特徴とする、請求項1から8のいずれか1項に記載の押出し成形可能なガス発生剤組成物。 The extrudable gas generant composition according to any one of claims 1 to 8, wherein the perchloric acid additive comprises ammonium perchlorate. 前記可塩素酸添加剤が少なくとも約200ミクロンの粒度を有することを特徴とする、請求項1から10のいずれか1項に記載の押出し成形可能なガス発生剤組成物。 11. An extrudable gas generant composition according to any one of the preceding claims, wherein the chloric acid additive has a particle size of at least about 200 microns. さらに、二酸化シリコン、酸化アルミニウム、酸化亜鉛及びこれらの組合せの中から選択される酸化金属燃焼速度強化及びスラグ形成添加剤を含む、請求項1から11のいずれか1項に記載の押出し成形可能なガス発生剤。 12. Extrudable according to any of claims 1 to 11, further comprising a metal oxide burn rate enhancing and slag forming additive selected from silicon dioxide, aluminum oxide, zinc oxide and combinations thereof. Gas generating agent. さらに、酸化鉄、亜クロム酸銅、紺青顔料及びこれらの組合せから選択される燃焼強化剤を含む、請求項1から12のいずれか1項に記載の押出し成形可能なガス発生剤組成物。 The extrudable gas generant composition according to any one of claims 1 to 12 , further comprising a combustion enhancer selected from iron oxide, copper chromite, bitumen pigments and combinations thereof. 前記銅含有化合物が5アミノテトラゾールと塩基性硝酸銅との反応から生じる銅−硝酸塩錯体であることを特徴とする、請求項1から13のいずれか1項に記載の押出し成形可能なガス発生剤組成物。 The extrudable gas generant according to any one of claims 1 to 13 , characterized in that the copper-containing compound is a copper-nitrate complex resulting from the reaction of 5 aminotetrazole and basic copper nitrate. Composition. 前記銅含有化合物が、塩基性硝酸銅と、5アミノテトラゾールと塩基性硝酸銅との反応から生じる銅−硝酸塩錯体との化合物であることを特徴とする、請求項1から13のいずれか1項に記載の押出し成形可能なガス発生剤組成物。 14. The copper-containing compound is a compound of basic copper nitrate, a copper-nitrate complex resulting from a reaction of 5-aminotetrazole and basic copper nitrate, 14. An extrudable gas generant composition as described in 1. above. 自動車の膨張式拘束装置のエアバッグクッションを膨張させるための膨張ガスを発生させる方法であって、A method for generating inflation gas for inflating an airbag cushion of an inflatable restraint device for an automobile,
請求項1から15のいずれか1項に記載の押出し成形可能なガス発生剤組成物を燃焼させ、エアバッグクッションを膨張させるために膨張ガスを作るステップと、Combusting the extrudable gas generant composition according to any one of claims 1 to 15 and creating an inflation gas to inflate the airbag cushion;
前記膨張ガスにより前記エアバッグクッションを膨張させるステップと、を備える膨張ガスを発生させる方法。Inflating the airbag cushion with the inflation gas, and generating a inflation gas.
JP2009526617A 2006-08-28 2007-08-16 Extrudable gas generant Pending JP2010502544A (en)

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US11/511,193 US20060289096A1 (en) 2003-07-25 2006-08-28 Extrudable gas generant
PCT/US2007/018202 WO2008027204A1 (en) 2006-08-28 2007-08-16 Extrudable gas generant

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