JP2010285473A - Energy-saving aqueous paint composition - Google Patents
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- JP2010285473A JP2010285473A JP2009138249A JP2009138249A JP2010285473A JP 2010285473 A JP2010285473 A JP 2010285473A JP 2009138249 A JP2009138249 A JP 2009138249A JP 2009138249 A JP2009138249 A JP 2009138249A JP 2010285473 A JP2010285473 A JP 2010285473A
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Abstract
Description
本発明は、ボイラー、船舶、車両のエンジンやラジエター部分のような付属物などに塗って完全燃焼をさせることにより燃費の向上によるエネルギーの省力化や環境の汚染を防ぐことが可能な省エネルギー水性塗料組成物に関する。 The present invention is an energy-saving water-based paint capable of saving energy and preventing environmental pollution by improving fuel efficiency by applying it to accessories such as boilers, ships, vehicle engines and radiator parts and completely burning them. Relates to the composition.
従来、ボイラー、エンジン、電子部品などに塗布することにより燃焼効率や機能の向上を図る塗料組成物が知られており、例えば、特開2003−202100号公報、特開2004−162051号公報などに提示されているが、これらの公報に提示されている従来の塗料組成物は、塗布した機器の表面における赤外線輻射効果(放射熱による冷却効果)の向上を図ることにより間接的に機能の効率を向上させるものであり、充分な効果が期待できない場合が多い。 Conventionally, coating compositions that improve combustion efficiency and function by applying to boilers, engines, electronic components, and the like are known. For example, JP 2003-202100 A, JP 2004-162051 A, etc. Although presented, the conventional coating compositions presented in these publications indirectly improve the efficiency of the function by improving the infrared radiation effect (cooling effect by radiant heat) on the surface of the applied equipment. In many cases, sufficient effects cannot be expected.
また、ボイラーなどに塗布して熱エネルギーの吸収を大きくすることにより稼働熱効率を高める塗料組成物が例えば特開2004−225027号公報に提示されているが、この種の塗料組成物はボイラーなどの内壁に塗布するものであって保守がきわめて困難であるばかりか、製造時に塗布する場合は問題ないが特に設置後においては塗布することができない。 In addition, a coating composition that enhances the operating thermal efficiency by increasing the absorption of thermal energy by applying to a boiler or the like is presented in, for example, Japanese Patent Application Laid-Open No. 2004-225027. It is applied to the inner wall and is not only difficult to maintain, but there is no problem when applied at the time of manufacture, but it cannot be applied particularly after installation.
更に、人工鉱石の粉砕物をエンジンにおけるキヤブレター、エンジン本体、ラジエター、排気管などの表面に担持させることにより温度上昇を低減するとともに人工鉱石の波動的物性により燃料や空気の分子構造を微細化させる手段が提示されている(国際公開 (WO2002/079093))。 In addition, by supporting the pulverized artificial ore on the surface of the engine carburetor, engine body, radiator, exhaust pipe, etc., the temperature rise is reduced and the molecular structure of fuel and air is refined by the wave properties of the artificial ore. Means are presented (International Publication (WO2002 / 079093)).
ところが、前記人工鉱石を製造するには真空状態で且つ2000℃以上というきわめて高温度で繰り返して生成を行う必要があることから製造が困難で且つ高価なものとなり、また、人工鉱石の粉砕物を各種機器に担持させる手段として塗料に溶剤とともに添加する手段が提示されているが塗料の種類や配合などが具体的に示されておらず現実的でない。 However, in order to produce the artificial ore, it is necessary to repeatedly produce it in a vacuum state and at an extremely high temperature of 2000 ° C. or higher, so that the production becomes difficult and expensive. Although means for adding to a paint together with a solvent has been proposed as a means to be carried on various devices, the type and composition of the paint are not specifically shown and is not realistic.
本発明は、船やボイラー及び車のエンジンなどの外面に塗布してエンジン内部の熱をコントロールすることによりガソリン等の燃料を完全燃焼させて燃費の効率や環境汚染を防止することはいうまでもなく、製造や取り扱いも容易な省エネルギー水性塗料組成物を提供するものである。 It goes without saying that the present invention prevents the fuel efficiency and environmental pollution by completely burning fuel such as gasoline by controlling the heat inside the engine by applying it to the outer surface of ships, boilers and car engines. The present invention provides an energy-saving water-based coating composition that is easy to manufacture and handle.
前記課題を解決するためになされた本発明である省エネルギー水性塗料組成物は、カチオン系エマルジョン樹脂塗料に、粒径が120μm以下の希土類元素を含む鉱物粉末または該鉱物粉体を焼成したセラミックス(好ましくは5〜40重量%の混入量)と、粒径が3〜40μmのシリコン金属微粉末(好ましくは5〜40重量%の混入量)を混入したことを特徴とするものである。 An energy-saving water-based paint composition according to the present invention made to solve the above-mentioned problems is a mineral powder containing a rare earth element having a particle size of 120 μm or less or a ceramic obtained by firing the mineral powder in a cationic emulsion resin paint (preferably Is mixed with 5 to 40% by weight of silicon metal fine powder having a particle size of 3 to 40 μm (preferably 5 to 40% by weight).
また、本発明において、前記カチオン系エマルジョン樹脂塗料が、親水性官能基を有するモノマーの重合体からなる親水性分散粒子と、この分散粒子と異なる疎水性分散粒子とを混在させた混合分散系の水性エマルジョン樹脂塗料であるとよく、さらに、カチオン系エマルジョン樹脂塗料が、親水性官能基を有するモノマーの重合体からなる親水性分散粒子と、この分散粒子と異なる疎水性分散粒子とを混在させた混合分散系の水性エマルジョン樹脂塗料を配合させることもできる。 Further, in the present invention, the cationic emulsion resin coating is a mixed dispersion system in which hydrophilic dispersion particles composed of a polymer of a monomer having a hydrophilic functional group and hydrophobic dispersion particles different from the dispersion particles are mixed. The aqueous emulsion resin paint is good, and the cationic emulsion resin paint further comprises a mixture of hydrophilic dispersed particles made of a polymer of a monomer having a hydrophilic functional group and hydrophobic dispersed particles different from the dispersed particles. A mixed-dispersed water-based emulsion resin coating can also be blended.
加えて、前記カチオン系エマルジョン樹脂塗料はpHが5.9〜6.5の範囲であるとシリコン金属の超電導性を失うことがない。また、前記カチオン系エマルジョン樹脂塗料に疎水性フッ素エマルジョン樹脂を混合することもできる。 In addition, when the pH of the cationic emulsion resin coating is in the range of 5.9 to 6.5, the superconductivity of silicon metal is not lost. In addition, a hydrophobic fluorine emulsion resin can be mixed with the cationic emulsion resin coating.
本発明によれば、ボイラー、船舶、車両のエンジンやラジエター部分のような付属物などに塗って完全燃焼をさせることにより燃費の向上によるエネルギーの省力化や環境の汚染を防ぐことができ、特に、従来の人工鉱石を用いるもののように超高温により製造するものでなく、製造の困難性もなく、エンジンなどの機器の外部に塗布することにより効果が得られるので製品への実施が容易であるばかりか、既存の機器にも簡単に実施することができ、また、実施後の保守や修繕もきわめて容易である。殊に、水性塗料としたことにより、溶剤を用いないので環境及び作業性に優れている。 According to the present invention, it is possible to prevent energy savings and environmental pollution by improving fuel consumption by applying to combustion such as boilers, ships, vehicle engines, and accessories such as radiator parts and complete combustion. It is not manufactured by ultra-high temperature like the one using conventional artificial ore, there is no manufacturing difficulty, and the effect can be obtained by applying it to the outside of equipment such as engine, so it can be easily applied to the product. In addition, it can be easily applied to existing equipment, and maintenance and repair after implementation is extremely easy. In particular, since it is a water-based paint, it is excellent in environment and workability because no solvent is used.
本発明を詳細に説明すると、本発明は、カチオン系エマルジョン樹脂塗料(例えば昭和高分子 ポリゾールAP−1350)にシリコン金属Siとマイナスイオンを発生する麦飯石(登録商標)やモナズ石の微粉末物質を併用した混合組成物を分散してなるものであり、シリコン金属の超電導の特性を生かし、イオン発生セラミックや鉱石粉末により構成された塗料は水性カチオン系の樹脂の場合、シリコン金属が水素と結合し熱拡散率が高いために振動エネルギーが強く放出される。シリコン金属の水素化物とカチオン樹脂の間で、ResineN+OH+SiHとなり金属水素化合物が生成され、水素を吸蔵すると発熱し、水素を放出すると吸熱する。 DETAILED DESCRIPTION OF THE INVENTION The present invention will be described in detail. The present invention relates to a fine powder material of barleystone (registered trademark) or monazite that generates silicon metal Si and negative ions in a cationic emulsion resin coating (for example, Showa Polymer Polysol AP-1350). In the case of paints made of ion-generating ceramics or ore powders that are based on water-based cationic resins, silicon metals are bonded to hydrogen by taking advantage of the superconducting properties of silicon metal. However, vibration energy is strongly released due to the high thermal diffusivity. ResinN + OH + SiH is formed between the hydride of silicon metal and the cation resin, and a metal hydride compound is generated. When hydrogen is occluded, heat is generated, and when hydrogen is released, heat is absorbed.
この反応は次式のように示される。
2/n・M+H2 = 2/n・MHn+Q 〔可逆反応〕
式中、MHはシリコン水素化合物、Qは反応熱で正の値が発熱を示す。
尚、イオン鉱石粉は、常時マイナスイオンOH−やO2を出す物質で、触媒の役目をしているものと考えられる。
This reaction is shown as:
2 / n · M + H2 = 2 / n · MHn + Q [reversible reaction]
In the formula, MH is a silicon hydrogen compound, Q is heat of reaction, and a positive value indicates exotherm.
The ion ore powder is always negative ions OH - in and O 2 to produce substances, believed that the role of catalyst.
このように外部からの熱によって水素の出し入れを行うことができ、例えばエンジンの外部に塗布したときにエンジン内部の熱をコントロールして完全燃焼させることができる。 In this way, hydrogen can be taken in and out by heat from the outside. For example, when applied to the outside of the engine, the heat inside the engine can be controlled to cause complete combustion.
このような省エネルギー塗料に於いて、カチオン系エマルジョン樹脂塗料が、親水性官能基を有するモノマーの重合体からなる親水性分散粒子と、この分散粒子と異なる疎水性分散粒子とを混在させた混合分散系の耐候性に優れ、有害な溶剤を用いない水性アクリルエマルジョン樹脂塗料を配合させることができる。 In such an energy-saving coating, the cationic emulsion resin coating is a mixture dispersion in which hydrophilic dispersion particles made of a polymer of a monomer having a hydrophilic functional group and hydrophobic dispersion particles different from the dispersion particles are mixed. An aqueous acrylic emulsion resin coating that is excellent in the weather resistance of the system and does not use a harmful solvent can be blended.
また、カチオン系アクリルエマルジョン樹脂塗料は親水性分散粒子と疎水性分散粒子を混在させた混合分散系であり、これを混合したpHは酸性サイド即ちpH5.9〜6.5程度の範囲にするとよい。アルカリサイドのpHにすると、シリコン金属微粉末がアルカリ中では不安定となり、 Si金属+4H2Oアルカリ性 Si(OH)4+H2↑の反応で水素ガスが発生し、シリコン金属も水酸化物になりシリコン金属の超電導性を失うからである。 Further, the cationic acrylic emulsion resin coating is a mixed dispersion system in which hydrophilic dispersion particles and hydrophobic dispersion particles are mixed, and the pH at which these are mixed should be in the acidic side, that is, in the range of about pH 5.9 to 6.5. . When the pH of the alkali side is adjusted, the silicon metal fine powder becomes unstable in the alkali, and hydrogen gas is generated by the reaction of Si metal + 4H2O alkaline Si (OH) 4 + H2 ↑, and the silicon metal also becomes a hydroxide, thereby superconducting silicon metal. Because it loses sex.
さらに、親水性分散粒子と疎水性分散粒の混在した塗料は、イオン鉱石微粉末および金属シリコン微粉との親和性がよく、これらを均一に分散できる分散液となり、ディスパージョンは、経時的に安定したものとなる。 Furthermore, paints with a mixture of hydrophilic dispersed particles and hydrophobic dispersed particles have a good affinity with ionic ore fine powder and metal silicon fine powder, and they can be dispersed uniformly, and the dispersion is stable over time. Will be.
本発明の水性カチオン系樹脂塗料は、アクリルに限らず全ての樹脂を用いても良い。即ちカチオン系アクリルウレタン、カチオン系酢酸ビニール樹脂、カチオン系アクリルシリコン、カチオン系フッ素樹脂エマルジョン、ポリアミド系やエポキシ系等、あらゆるカチオン系エマルジョンを用いることができる。また、カチオン系アクリルエマルジョンに疎水性フッ素エマルジョン樹脂をアルカリサイドにならないような範囲で混合してもよい。 The aqueous cationic resin coating material of the present invention is not limited to acrylic and may use all resins. That is, any cationic emulsions such as cationic acrylic urethane, cationic vinyl acetate resin, cationic acrylic silicon, cationic fluororesin emulsion, polyamide type, and epoxy type can be used. Moreover, you may mix a hydrophobic fluorine emulsion resin with a cationic acrylic emulsion in the range which does not become an alkali side.
また、本発明に用いられる希土類元素を含む鉱物としては、例えば麦飯石(登録商標)があは、医王石、太陽石、アルカライト等とも称され、組織的には深成岩の一種で花崗岩に類似し、主に斜長石、カリ長石、黒雲母からなり、石英、角閃石、緑泥石があり、それに次ぎ燐石灰、磁鉄鉱、ジルコン、希土類元素などの副鉱物を有するものである。岩石として正式な名称は黒雲母モンゾナイト斑岩であり、吸着作用やマイナスイオンを発生する作用のあることが知られており、その成分を有するイオン鉱石粉としては例えば、以下に示す〔A組成物〕、〔B組成物〕、〔C組成物〕等があげられる。 In addition, as a mineral containing rare earth elements used in the present invention, for example, barley stone (registered trademark) is also called Ioishi, Taiyoishi, Alkalite, etc., and it is structurally a kind of plutonic rock and is similar to granite It mainly consists of plagioclase, potash feldspar, biotite, quartz, amphibole, and chlorite, followed by secondary minerals such as phosphate lime, magnetite, zircon, and rare earth elements. The official name of the rock is biotite monzonite porphyry, which is known to have adsorption and negative ion generation. Examples of ionic ore powder having such components include the following [A composition ], [B composition], [C composition] and the like.
〔A組成物〕
SiO2=65〜70%、K2O<8%、Al2O=14〜16%、Na2O=2〜3%、C2O<2%、 MgO<3%、TiO2=0.2〜0.3%、MnO2=0.3% 多孔質粒子は、塗料の用途に応じて適宣その粒径を選択して設ければ良いため、その粒径を限定する必要性はない。しかしながら、120メッシュ(すなわち120μm以下)より好ましくは325メッシュのものを用いて添加効率が良いという結果を確認している。
[A composition]
SiO2 = 65-70%, K2O <8%, Al2O = 14-16%, Na2O = 2-3%, C2O <2%, MgO <3%, TiO2 = 0.2-0.3%, MnO2 = 0.3% Porous particles Since it is only necessary to select and provide the particle size appropriately according to the application of the paint, there is no need to limit the particle size. However, it has been confirmed that the addition efficiency is good using 120 mesh (ie, 120 μm or less), more preferably 325 mesh.
〔B組成物〕
La2O3 55%、M2O3 4.8%、MgO 14%、SiO2 22.7%、K2O 1%、CaO 1.4%、Fe2O3 1%、TiO2 0.1%
[B composition]
La 2 O 3 55%, M 2 O 3 4.8%, MgO 14%, SiO 2 22.7%, K 2 O 1%, CaO 1.4%, Fe 2 O 3 1%, TiO 2 0.1%
〔C組成物〕
前記〔A組成物〕と〔B組成物〕の混合物を1,000℃以上の温度で焼成し、セラミック化し、微粉末としたもので次の成分の組成物である。
SiO2 42%、La2O3 28%、M2O3 9%、MgO 9%、K2O 5%、Na2O 2%、Ca 2%、TiO2 1%、M2O2 1%、Fe2O3 1%
[C composition]
The mixture of the [A composition] and the [B composition] is fired at a temperature of 1,000 ° C. or more, made into a fine powder, and is a composition of the following components.
SiO 2 42%, La 2 O 3 28%, M 2 O 3 9%, MgO 9%, K 2 O 5%, Na 2 O 2%, Ca 2%, TiO 2 1%, M 2 O 2 1% , Fe 2 O 3 1%
また、本発明では、希土類元素を含む鉱物粉末だけでなく、該鉱物粉体をAl2O3、SiO2の粉末とを混合し、1,000℃で焼成してセラミック化したものも用いることができる。 In the present invention, not only a mineral powder containing a rare earth element but also a ceramic powder obtained by mixing the mineral powder with Al 2 O 3 and SiO 2 powder and firing it at 1,000 ° C. can be used. .
以下に本発明である省エネルギー水性塗料組成物の実施例を示す。 Examples of the energy-saving water-based paint composition according to the present invention are shown below.
(実施例1) 固形分 約36%省エネ塗料組成物
成 分 重量部
カチオン系アクリルエマルジョン
(昭和高分子社製 ポリゾールAP-1350)(33%固形分) 100.0
金属シリコン微粉末 25.0
前記実施の形態に示した〔C組成物〕のマイナスイオン鉱石粉セラミック 10.0
増粘剤 メチルセルローズ(3%水溶液) 0.5
分散剤 0.2
消泡剤(シリコン系) 0.1
防腐剤 0.2
清水 50.0
(Example 1) Solid content about 36% energy-saving paint composition
Component Weight parts Cationic acrylic emulsion
(Polysol AP-1350, Showa Polymer Co., Ltd.) (33% solids) 100.0
Metallic silicon fine powder 25.0
Negative ion ore powder ceramic of [C composition] shown in the above embodiment 10.0
Thickener Methylcellulose (3% aqueous solution) 0.5
Dispersant 0.2
Antifoaming agent (silicone) 0.1
Preservative 0.2
Shimizu 50.0
(実施例2) 固形分 約37%省エネ塗料組成物
成 分 重量部
カチオン系アクリルエマルジョン
(昭和高分子社製 ポリゾールAP-1350)(33%固形分) 100.0
金属シリコン微粉末 10.0
前記実施の形態に示した〔A組成物〕のマイナスイオン鉱石粉セラミック 25.0
ウレタン系会合性増粘剤 0.5
分散剤 0.2
消泡剤(シリコン系) 0.1
防腐剤 0.2
清水 50.0
(Example 2) Solid content about 37% energy-saving paint composition
Component Weight parts Cationic acrylic emulsion
(Polysol AP-1350, Showa Polymer Co., Ltd.) (33% solids) 100.0
Metallic silicon fine powder 10.0
Negative ion ore powder ceramic of [A composition] shown in the above embodiment 25.0
Urethane-based associative thickener 0.5
Dispersant 0.2
Antifoaming agent (silicone) 0.1
Preservative 0.2
Shimizu 50.0
(実施例3) 固形分 約41%省エネ塗料組成物
成 分 重量部
カチオン系フッ素樹脂エマルジョン(ダイキン工業製)(33%固形分) 100.0
金属シリコン微粉末分散液 (50%固形分) 20.0
前記実施の形態に示した〔A組成物〕のマイナスイオン鉱石粉セラミック 30.0
増粘剤 ヒドロキシメチルセルローズ4%水溶液 0.5
分散剤 0.2
消泡剤(シリコン系) 0.1
防腐剤 0.2
清水 50.0
(Example 3) Solid content about 41% energy-saving paint composition
Component Weight parts Cationic fluororesin emulsion (Daikin Industries) (33% solids) 100.0
Metallic silicon fine powder dispersion (50% solid content) 20.0
Negative ion ore powder ceramic 30.0 of [A composition] shown in the above embodiment 30.0
Thickener Hydroxymethylcellulose 4% aqueous solution 0.5
Dispersant 0.2
Antifoaming agent (silicone) 0.1
Preservative 0.2
Shimizu 50.0
(実施例4) 固形分 約36%省エネ塗料組成物
成 分 重量部
カチオン系アクリル樹脂エマルジョン(33%固形分) 100.0
シリコン金属微粉末 10.0
前記実施の形態に示した〔C組成物〕のマイナスイオン鉱石粉微粉末 25.0
増粘剤 メチルセルローズ4%水溶液 0.5
分散剤 0.2
消泡剤(シリコン系) 0.1
防腐剤 0.2
清水 50.0
(Example 4) Solid content: about 36% energy-saving paint composition
Component Weight parts Cationic acrylic resin emulsion (33% solids) 100.0
Silicon metal fine powder 10.0
Negative ion ore fine powder of [C composition] shown in the above embodiment 25.0
Thickener Methylcellulose 4% aqueous solution 0.5
Dispersant 0.2
Antifoaming agent (silicone) 0.1
Preservative 0.2
Shimizu 50.0
(実施例5) 固形分 約36%省エネ塗料組成物
成 分 重量部
カチオン系アクリル樹脂エマルジョン(33%固形分) 100.0
シリコン金属微粉末 30.0
増粘剤 メチルセルローズ4%水溶液 0.5
分散剤 0.2
消泡剤(シリコン系) 0.1
防腐剤 0.2
清水 50.0
(Example 5) Solid content about 36% energy-saving paint composition
Component Weight parts Cationic acrylic resin emulsion (33% solids) 100.0
Silicon metal fine powder 30.0
Thickener Methylcellulose 4% aqueous solution 0.5
Dispersant 0.2
Antifoaming agent (silicone) 0.1
Preservative 0.2
Shimizu 50.0
(実施例6) 固形分 約41%省エネ塗料組成物
成 分 重量部
カチオン系アクリル樹脂エマルジョン (33%固形分) 100.0
前記実施の形態に示した〔C組成物〕のマイナスイオン鉱石粉微粉末 35.0
増粘剤 ヒドロキシメチルセルローズ4%水溶液 0.5
分散剤 0.2
消泡剤(シリコン系) 0.1
防腐剤 0.2
清水 50.0
(Example 6) Solid content about 41% energy-saving paint composition
Component Weight parts Cationic acrylic resin emulsion (33% solids) 100.0
Negative ion ore fine powder of [C composition] shown in the above embodiment 35.0
Thickener Hydroxymethylcellulose 4% aqueous solution 0.5
Dispersant 0.2
Antifoaming agent (silicone) 0.1
Preservative 0.2
Shimizu 50.0
次に前記実施例1〜6に示した本発明である省エネ塗料組成物を船のボイラー噴射口に塗装した場合のガソリンの節約、エンジン排気ガスの煙の色、排気ガスのCO 、CO2の測定結果を比較例(塗装しない場合)とともに表1に示す。 Next, when the energy-saving paint composition according to the present invention shown in the first to sixth embodiments is applied to the boiler injection port, gasoline is saved, engine exhaust smoke color, exhaust gas CO 2 , CO 2 The measurement results are shown in Table 1 together with a comparative example (when not painted).
表1によれば、本発明である省エネ塗料組成物を船のボイラー噴射口に塗装した場合に、ガソリンが7%節約され、また、排気ガスの色が白くCOガスが排出されないことが確認できた。 According to Table 1, when the energy-saving paint composition according to the present invention is applied to the boiler injection port, 7% of gasoline is saved and the color of the exhaust gas is white and CO gas is not discharged. It was.
また、前記実施例1〜6に示した本発明である省エネ塗料組成物を自動車のエンジン部分とラジエター部分に塗装した場合のガソリンの節約、エンジン排気ガスの煙の色、排気ガスのCO 、CO2の測定結果を比較例(塗装しない場合)とともに表2に示す。
尚、使用した自動車は同一メーカーの同一車種を用いた。
Further, when the energy-saving paint composition according to the present invention shown in Examples 1 to 6 is applied to the engine part and the radiator part of the automobile, gasoline saving, engine exhaust gas smoke color, exhaust gas CO 2, CO 2 the second measurements together with comparative examples (without coating) shown in Table 2.
In addition, the used car used the same model of the same manufacturer.
表2から本発明が自動車のエンジン部分とラジエター部分に塗装した場合に前記表1に示した場合と同様な効果を得られることが確認された。 From Table 2, it was confirmed that the same effect as the case shown in Table 1 can be obtained when the present invention is applied to the engine part and the radiator part of the automobile.
Claims (5)
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JP2009138249A JP2010285473A (en) | 2009-06-09 | 2009-06-09 | Energy-saving aqueous paint composition |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2015056298A1 (en) * | 2013-10-15 | 2015-04-23 | 有限会社 ビオセラ | Mat coated with functional coating composition having increased combustion efficiency improvement effect for internal combustion engine |
JP2019210344A (en) * | 2018-06-01 | 2019-12-12 | 長瀬産業株式会社 | Aqueous coating for carbon dioxide coating, coating composition, and coating method |
-
2009
- 2009-06-09 JP JP2009138249A patent/JP2010285473A/en not_active Withdrawn
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2015056298A1 (en) * | 2013-10-15 | 2015-04-23 | 有限会社 ビオセラ | Mat coated with functional coating composition having increased combustion efficiency improvement effect for internal combustion engine |
JP2019210344A (en) * | 2018-06-01 | 2019-12-12 | 長瀬産業株式会社 | Aqueous coating for carbon dioxide coating, coating composition, and coating method |
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