CN108299870A - A kind of high blackness anti-coking corrosion-resistant ceramic coating of high temperature resistant - Google Patents
A kind of high blackness anti-coking corrosion-resistant ceramic coating of high temperature resistant Download PDFInfo
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- CN108299870A CN108299870A CN201610756167.XA CN201610756167A CN108299870A CN 108299870 A CN108299870 A CN 108299870A CN 201610756167 A CN201610756167 A CN 201610756167A CN 108299870 A CN108299870 A CN 108299870A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D1/00—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
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Abstract
The invention discloses a kind of high blackness anti-coking corrosion-resistant ceramic coating of high temperature resistant,Including binder,Filler,Auxiliary agent,Water,It is characterized in that,Binder is by 7% 15% Ludox by mass percentage,5% 7% styrene-acrylic emulsions,1% 3% sodium oxide molybdenas,3% 5% monohydrate aluminas,Filler is by 2% 5% zirconium oxides by mass percentage,1% 3% iron oxide reds,1% 3% silicon nitrides,0.2% 0.5% titanium nitrides,1% 3% magnesia,3% 6% chromium oxide,1% aluminium oxide,0.5% 1% copper oxide,5% 7% kaolin,1.9% 2.5% mica powders,0.5% 0.7% sodium bentonites,1% 3% cerium oxide,1% 3% neodymia,1% 3% lanthanas,1% 3% yttrium oxides,0.2% 0.4% molybdenum oxides,1% 3% niobium oxide compositions.
Description
Technical field
The present invention relates to ceramic coating technical field, more particularly to a kind of high blackness anti-coking corrosion-resistant ceramic of high temperature resistant applies
Material.
Background technology
Ceramic coating belongs to field of functional coatings, is a kind of novel aqueous inorganic paint.It is with nano inorganic chemical combination
Object is main component, and using water as dispersate, and low-temperature heat mode is generally gone through after application and is cured, forming properties and ceramic phase
As film.Its raw material is contained abundant, convenient for exploitation and cheap, and then keeps its cost also relatively low with respect to traditional coating.Its
In some use silane coupling agent, ceramic coating prepared by alumine hydroxide colloid, have high temperature resistant, high rigidity, it is non-ignitable it is smokeless,
Extra-weather-proof, environment-protecting and non-poisonous, the rich in color, many advantages such as application is easy.It is various after various novel improvement and enhancement
Superior performance and cheap cost are also said and gradually replace traditional coating.And traditional organic coating etc., the influence to environment is quite
To be huge, not only the frequent emission greenhouse gas of finished product leads to climate warming, but also discharges noxious material in air, leads to people
Or disease and the death of animals and plants, also energy consumption is big among the process of production, is unsatisfactory for the theory of China's low-carbon, and generates each
Kind trade effluent or toxic gas.With the development of coatings industry, some organic coatings cannot meet the green ring of people
It protects, the theory of multifunction and excellent performance, and the development of ceramic coating opens progress and research to high-new paint field,
Further meet vision of the people for promotion coating property.
Invention content
It is an object of the present invention to be directed to above-mentioned problem, a kind of high blackness anti-coking corrosion-resistant ceramic of high temperature resistant is provided
Coating.
To achieve the goals above, technical scheme of the present invention is specific as follows：
A kind of high blackness anti-coking corrosion-resistant ceramic coating of high temperature resistant, including binder, filler, auxiliary agent, water, feature exist
In binder is by 7%-15% Ludox by mass percentage, 5%-7% styrene-acrylic emulsions, 1%-3% sodium oxide molybdenas, 3%-
5% monohydrate alumina, filler is by 2%-5% zirconium oxides by mass percentage, 1%-3% iron oxide reds, 1%-3% nitrogen
SiClx, 0.2%-0.5% titanium nitrides, 1%-3% magnesia, 3%-6% chromium oxide, 1% aluminium oxide, 0.5%-1% copper oxide,
5%-7% kaolin, 1.9%-2.5% mica powders, 0.5%-0.7% sodium bentonites, 1%-3% cerium oxide, 1%-3% oxygen
Change neodymium, 1%-3% lanthanas, 1%-3% yttrium oxides, 0.2%-0.4% molybdenum oxides, 1%-3% niobium oxide composition, auxiliary agent is by pressing
The 0.3%-0.4% dispersants of mass percent meter, 0.2%-0.3% wetting agents, 0.1%-0.2% antifoaming agent, 1%-3% ammonia
Water, water are specially deionized water.
Preferably, the high blackness anti-coking corrosion-resistant ceramic coating of a kind of high temperature resistant, which is characterized in that binder by
15% Ludox by mass percentage, 5% styrene-acrylic emulsion, 1% sodium oxide molybdena, 3% monohydrate alumina, filler is by pressing quality
5% zirconium oxide of percentages, 1% iron oxide red, 3% silicon nitride, 0.2% titanium nitride, 1% magnesia, 3% chromium oxide, 1%
Aluminium oxide, 0.5% copper oxide, 5% kaolin, 2% mica powder, 0.5% sodium bentonite, 1% cerium oxide, 1% neodymia,
1% lanthana, 1% yttrium oxide, 0.2% molybdenum oxide, 1% niobium oxide composition, auxiliary agent is by 0.3% dispersion by mass percentage
Agent, 0.2% wetting agent, 0.1% antifoaming agent, 1% ammonium hydroxide.
Preferably, the high blackness anti-coking corrosion-resistant ceramic coating of a kind of high temperature resistant, which is characterized in that binder by
10% Ludox by mass percentage, 7% styrene-acrylic emulsion, 2% sodium oxide molybdena, 5% monohydrate alumina, filler is by pressing quality
3% zirconium oxide of percentages, 2% iron oxide red, 2% silicon nitride, 0.5% titanium nitride, 2% magnesia, 5% chromium oxide, 1%
Copper oxide, 7% kaolin, 2.5% mica powder, 0.7% sodium bentonite, 2% cerium oxide, 2% neodymia, 2% lanthana,
2% yttrium oxide, 0.3% molybdenum oxide, 2% niobium oxide composition, auxiliary agent is by 0.4% dispersant by mass percentage, 0.3% profit
Humectant, 0.2% antifoaming agent, 2% ammonium hydroxide.
Preferably, the high blackness anti-coking corrosion-resistant ceramic coating of a kind of high temperature resistant, which is characterized in that binder by
7% Ludox by mass percentage, 6% styrene-acrylic emulsion, 3% sodium oxide molybdena, 4% monohydrate alumina, filler is by pressing quality
2% zirconium oxide of percentages, 3% iron oxide red, 1% silicon nitride, 0.3% titanium nitride, 3% magnesia, 6% chromium oxide,
0.75% copper oxide, 6% kaolin, 1.9% mica powder, 0.6% sodium bentonite, 3% cerium oxide, 3% neodymia, 3% oxygen
Change lanthanum, 3% yttrium oxide, 0.4% molybdenum oxide, 3% niobium oxide composition, auxiliary agent by 0.35% dispersant by mass percentage,
0.25% wetting agent, 0.15% antifoaming agent, 3% ammonium hydroxide.
Preferably, the high blackness anti-coking corrosion-resistant ceramic coating of a kind of high temperature resistant, which is characterized in that described fills out
Material, zirconium oxide, iron oxide red, silicon nitride, titanium nitride, magnesia, chromium oxide, copper oxide, kaolin, mica powder, sodium base are swollen
The granularity for moistening soil, cerium oxide, neodymia, lanthana, yttrium oxide and niobium oxide is 100 nanometers, the binder, oxidation
The granularity of sodium is 100 nanometers.
The invention has the advantages that coat side, to high-temp combustion flame, the present invention is high suitable for high-temperature corrosion environment
The corrosion of the lower oxygen of temperature, the corrosion of sulphur under high temperature, flame impingement under high temperature, hardness high adhesion force are good；Can long-term fire resisting barbecue,
Favorable anti-corrosion effect in fire the anti-corrosion in fire, hardness can reach height, volatilize without any harmful substance under room temperature high temperature for a long time, green
Environmental protection, pollution-free, coating room temperature self-curing, physical property, chemical property and performance are reached advanced world standards.Its
It brushes on high-temperature furnace body metal, energy effective protection high-temperature furnace body metal is anti-corrosion in thermal-flame environment, it is acidproof resistance to improve
The resistance of alkali, the effects that protecting metal not by anti-oxidant, closed protective, overcoming common anticorrosive paint, pole is not under the high temperature conditions
It adapts to, heatproof is inadequate, the defects of being also easy to produce peeling, crowfoot cracks, change colour；Coating stability is high, impact-resistant abrasion-proof, in hot environment
Under can be reacted with other bioactive molecules, keep furnace body service life longer, cause industrial production continuity and improve amount of product throughput；
Its performance it is excellent, also improve its scope of application；It can be in space flight and aviation, petroleum and petrochemical industry, metallurgical light industry, electric power, system of army
System is used widely, and chimney, high temperature steam pipeline, heat exchanger, high temperature kiln, petroleum and petrochemical industry cracking equipment, hair are suitable for
Motivation component and exhaust pipe high-temperature resistant anti-corrosive.With the development of scientific and technological level, the promotion of industrial technology, corrosion-resistant heatproof amplitude
It is promoted, purposes also can gradually extend.
Specific implementation mode
With reference to embodiment, the present invention will be further described：
Embodiment 1
A kind of high blackness anti-coking corrosion-resistant ceramic coating of high temperature resistant, which is characterized in that binder is by by mass percentage
15% Ludox of meter, 5% styrene-acrylic emulsion, 1% sodium oxide molybdena, 3% monohydrate alumina, filler is by by mass percentage
5% zirconium oxide, 1% iron oxide red, 3% silicon nitride, 0.2% titanium nitride, 1% magnesia, 3% chromium oxide, 1% aluminium oxide,
0.5% copper oxide, 5% kaolin, 2% mica powder, 0.5% sodium bentonite, 1% cerium oxide, 1% neodymia, 1% oxidation
Lanthanum, 1% yttrium oxide, 0.2% molybdenum oxide, 1% niobium oxide composition, auxiliary agent by 0.3% dispersant by mass percentage,
0.2% wetting agent, 0.1% antifoaming agent, 1% ammonium hydroxide, the filler, zirconium oxide, iron oxide red, silicon nitride, titanium nitride, oxygen
Change magnesium, chromium oxide, copper oxide, kaolin, mica powder, sodium bentonite, cerium oxide, neodymia, lanthana, yttrium oxide and oxidation
The granularity of niobium is 100 nanometers, the binder, and the granularity of sodium oxide molybdena is 100 nanometers.
Embodiment 2
A kind of high blackness anti-coking corrosion-resistant ceramic coating of high temperature resistant, which is characterized in that binder is by by mass percentage
10% Ludox of meter, 7% styrene-acrylic emulsion, 2% sodium oxide molybdena, 5% monohydrate alumina, filler is by by mass percentage
3% zirconium oxide, 2% iron oxide red, 2% silicon nitride, 0.5% titanium nitride, 2% magnesia, 5% chromium oxide, 1% copper oxide, 7%
Kaolin, 2.5% mica powder, 0.7% sodium bentonite, 2% cerium oxide, 2% neodymia, 2% lanthana, 2% yttrium oxide,
0.3% molybdenum oxide, 2% niobium oxide composition, auxiliary agent is by 0.4% dispersant by mass percentage, 0.3% wetting agent, and 0.2%
Antifoaming agent, 2% ammonium hydroxide, the filler, zirconium oxide, iron oxide red, silicon nitride, titanium nitride, magnesia, chromium oxide, oxidation
Copper, kaolin, mica powder, sodium bentonite, cerium oxide, neodymia, lanthana, yttrium oxide and niobium oxide granularity be 100
The granularity of nanometer, the binder, sodium oxide molybdena is 100 nanometers.
Embodiment 3
A kind of high blackness anti-coking corrosion-resistant ceramic coating of high temperature resistant, which is characterized in that binder is by by mass percentage
7% Ludox of meter, 6% styrene-acrylic emulsion, 3% sodium oxide molybdena, 4% monohydrate alumina, filler is by 2% by mass percentage
Zirconium oxide, 3% iron oxide red, 1% silicon nitride, 0.3% titanium nitride, 3% magnesia, 6% chromium oxide, 0.75% copper oxide, 6%
Kaolin, 1.9% mica powder, 0.6% sodium bentonite, 3% cerium oxide, 3% neodymia, 3% lanthana, 3% yttrium oxide,
0.4% molybdenum oxide, 3% niobium oxide composition, auxiliary agent is by 0.35% dispersant by mass percentage, 0.25% wetting agent,
0.15% antifoaming agent, 3% ammonium hydroxide, the filler, zirconium oxide, iron oxide red, silicon nitride, titanium nitride, magnesia, oxidation
The granularity of chromium, copper oxide, kaolin, mica powder, sodium bentonite, cerium oxide, neodymia, lanthana, yttrium oxide and niobium oxide
It it is 100 nanometers, the granularity of the binder, sodium oxide molybdena is 100 nanometers.
Claims (5)
1. a kind of high blackness anti-coking corrosion-resistant ceramic coating of high temperature resistant, including binder, filler, auxiliary agent, water, feature exist
In binder is by 7%-15% Ludox by mass percentage, 5%-7% styrene-acrylic emulsions, 1%-3% sodium oxide molybdenas, 3%-
5% monohydrate alumina, filler is by 2%-5% zirconium oxides by mass percentage, 1%-3% iron oxide reds, 1%-3% nitrogen
SiClx, 0.2%-0.5% titanium nitrides, 1%-3% magnesia, 3%-6% chromium oxide, 1% aluminium oxide, 0.5%-1% copper oxide,
5%-7% kaolin, 1.9%-2.5% mica powders, 0.5%-0.7% sodium bentonites, 1%-3% cerium oxide, 1%-3% oxygen
Change neodymium, 1%-3% lanthanas, 1%-3% yttrium oxides, 0.2%-0.4% molybdenum oxides, 1%-3% niobium oxide composition, auxiliary agent is by pressing
The 0.3%-0.4% dispersants of mass percent meter, 0.2%-0.3% wetting agents, 0.1%-0.2% antifoaming agent, 1%-3% ammonia
Water, water are specially deionized water.
2. the high blackness anti-coking corrosion-resistant ceramic coating of a kind of high temperature resistant according to claim 1, which is characterized in that bond
Agent is by 15% Ludox by mass percentage, and 5% styrene-acrylic emulsion, 1% sodium oxide molybdena, 3% monohydrate alumina, filler is by pressing
5% zirconium oxide of mass percent meter, 1% iron oxide red, 3% silicon nitride, 0.2% titanium nitride, 1% magnesia, 3% oxidation
Chromium, 1% aluminium oxide, 0.5% copper oxide, 5% kaolin, 2% mica powder, 0.5% sodium bentonite, 1% cerium oxide, 1%
Neodymia, 1% lanthana, 1% yttrium oxide, 0.2% molybdenum oxide, 1% niobium oxide composition, auxiliary agent is by by mass percentage
0.3% dispersant, 0.2% wetting agent, 0.1% antifoaming agent, 1% ammonium hydroxide.
3. the high blackness anti-coking corrosion-resistant ceramic coating of a kind of high temperature resistant according to claim 1, which is characterized in that bond
Agent is by 10% Ludox by mass percentage, and 7% styrene-acrylic emulsion, 2% sodium oxide molybdena, 5% monohydrate alumina, filler is by pressing
3% zirconium oxide of mass percent meter, 2% iron oxide red, 2% silicon nitride, 0.5% titanium nitride, 2% magnesia, 5% oxidation
Chromium, 1% copper oxide, 7% kaolin, 2.5% mica powder, 0.7% sodium bentonite, 2% cerium oxide, 2% neodymia, 2% oxygen
Change lanthanum, 2% yttrium oxide, 0.3% molybdenum oxide, 2% niobium oxide composition, auxiliary agent by 0.4% dispersant by mass percentage,
0.3% wetting agent, 0.2% antifoaming agent, 2% ammonium hydroxide.
4. the high blackness anti-coking corrosion-resistant ceramic coating of a kind of high temperature resistant according to claim 1, which is characterized in that bond
Agent is by 7% Ludox by mass percentage, and 6% styrene-acrylic emulsion, 3% sodium oxide molybdena, 4% monohydrate alumina, filler is by pressing
2% zirconium oxide of mass percent meter, 3% iron oxide red, 1% silicon nitride, 0.3% titanium nitride, 3% magnesia, 6% oxidation
Chromium, 0.75% copper oxide, 6% kaolin, 1.9% mica powder, 0.6% sodium bentonite, 3% cerium oxide, 3% neodymia, 3%
Lanthana, 3% yttrium oxide, 0.4% molybdenum oxide, 3% niobium oxide composition, auxiliary agent is by 0.35% dispersion by mass percentage
Agent, 0.25% wetting agent, 0.15% antifoaming agent, 3% ammonium hydroxide.
5. the high blackness anti-coking corrosion-resistant ceramic coating of a kind of high temperature resistant according to any one of claims 1 to 4, feature exist
In, the filler, zirconium oxide, iron oxide red, silicon nitride, titanium nitride, magnesia, chromium oxide, copper oxide, kaolin, cloud
Female powder, sodium bentonite, cerium oxide, neodymia, lanthana, yttrium oxide and niobium oxide granularity be 100 nanometers, described is viscous
Agent is tied, the granularity of sodium oxide molybdena is 100 nanometers.
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| CN201610756167.XA CN108299870A (en) | 2016-08-30 | 2016-08-30 | A kind of high blackness anti-coking corrosion-resistant ceramic coating of high temperature resistant |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2020140389A1 (en) * | 2019-01-06 | 2020-07-09 | 微山宏瑞电力科技有限公司 | Pure inorganic covering flame-retardant fireproof high-temperature-resistant coating additive and preparation method therefor |
| CN113667407A (en) * | 2021-08-19 | 2021-11-19 | 连城凯克斯科技有限公司 | Preparation method of ceramic coating on surfaces of wire winding shaft and fixed pulley |
| CN113969069A (en) * | 2020-10-23 | 2022-01-25 | 深圳优易材料科技有限公司 | High-temperature coating capable of catalytically decomposing dioxin |
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| CN113667407A (en) * | 2021-08-19 | 2021-11-19 | 连城凯克斯科技有限公司 | Preparation method of ceramic coating on surfaces of wire winding shaft and fixed pulley |
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Application publication date: 20180720 |