JP2010242221A - Heat-resistant steel member and method for production thereof - Google Patents

Heat-resistant steel member and method for production thereof Download PDF

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JP2010242221A
JP2010242221A JP2010117942A JP2010117942A JP2010242221A JP 2010242221 A JP2010242221 A JP 2010242221A JP 2010117942 A JP2010117942 A JP 2010117942A JP 2010117942 A JP2010117942 A JP 2010117942A JP 2010242221 A JP2010242221 A JP 2010242221A
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resistant steel
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JP5248549B2 (en
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Ryuichi Ishii
龍一 石井
Koji Yoshimura
光司 吉村
Atsushi Maeno
敦 前野
Ikuo Morimoto
生男 森本
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Toshiba Corp
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Abstract

<P>PROBLEM TO BE SOLVED: To provide a heat-resistant steel member which has a ring form, hardly causes anisotropy, shows uniform mechanical properties in various places, and further can be easily produced, and also to provide a method for production thereof. <P>SOLUTION: The heat-resistant steel member comprises, by weight, 0.06-0.18% C, 0.05-0.6% Si, 0.2-0.8% Mn, 9-11.5% Cr, 0.1-1% Ni, 0.8-1.3% Mo, 0.05-0.5% Nb, 0.07-0.3% V, 0.03-0.08% N and the balance Fe with inevitable impurities, and is formed in a ring shape by a centrifugal casting method. <P>COPYRIGHT: (C)2011,JPO&INPIT

Description

本発明は、耐熱鋼を用いて形成されるリング状の耐熱鋼部材およびその製造方法に関する。   The present invention relates to a ring-shaped heat-resistant steel member formed using heat-resistant steel and a method for producing the same.

従来、蒸気タービンにおけるダイアフラム構造のタービンノズルとして、環状体を二つ割りにしたダイアフラム外輪とダイアフラム内輪との間に、環状列に配置されたノズル板の両端を溶接することなく固定した構成を有するものがある(例えば、特許文献1参照。)。   Conventionally, a turbine nozzle having a diaphragm structure in a steam turbine has a structure in which both ends of a nozzle plate arranged in an annular row are fixed without welding between a diaphragm outer ring and a diaphragm inner ring divided into two annular bodies. (For example, refer to Patent Document 1).

また、ノズル板は、一般的に、例えば角材などから切削によって形成されている。このノズル板の製作において、ダイアフラム外輪およびダイアフラム内輪におけるノズル板の固定部の形状や、ダイアフラム外輪の内側面およびダイアフラム内輪の外側面の曲率に対応して、厳格な製作規格の下、ノズル板を製作することは、多くの製作工程および製作時間を必要としていた。   Further, the nozzle plate is generally formed by cutting, for example, square material. In the production of this nozzle plate, the nozzle plate is subjected to strict manufacturing standards in accordance with the shape of the fixed portion of the nozzle plate in the diaphragm outer ring and the diaphragm inner ring, and the curvature of the inner surface of the diaphragm outer ring and the outer surface of the diaphragm inner ring. Manufacturing required a lot of manufacturing processes and manufacturing time.

米国特許第5743711号明細書US Pat. No. 5,743,711

上記したように、従来におけるダイアフラム構造のタービンノズルを製作する場合には、ダイアフラム外輪とダイアフラム内輪との間に、ノズル板を的確に固定しなければならず、各構成部材の構造が複雑化し、さらに組み立てに際しても熟練した技術を要していた。また、ノズル板は、厳格な製作規格の下製作されるので、製作効率の向上を図ることが難しく、さらに、角材などから切削によって製作するので、経済性の向上を図ることも難しかった。また、ノズル板などを製作するための部材は、異方性を生じず、機械的性質が均質であることが望ましい。   As described above, when manufacturing a turbine nozzle having a conventional diaphragm structure, the nozzle plate must be accurately fixed between the diaphragm outer ring and the diaphragm inner ring, and the structure of each component becomes complicated. Furthermore, skilled techniques were required for assembly. In addition, since the nozzle plate is manufactured under strict manufacturing standards, it is difficult to improve the manufacturing efficiency. Further, since the nozzle plate is manufactured by cutting from a square or the like, it is difficult to improve the economy. In addition, it is desirable that a member for manufacturing a nozzle plate or the like has no mechanical anisotropy and has uniform mechanical properties.

そこで、本発明では、リング状に形成された部材を所定の個数に等分割し切削加工して、例えば、ダイアフラム外輪、ダイアフラム内輪およびノズル板を一体的に有する分割構造体を製作することが可能であり、リング状の部材として製作しても、異方性がほとんど生じず、各所において均質な機械的性質を得ることができ、さらに、容易に製造することができる耐熱鋼部材およびその製造方法を提供することを目的とする。   Therefore, in the present invention, a ring-shaped member can be equally divided into a predetermined number and cut to produce, for example, a divided structure integrally including a diaphragm outer ring, a diaphragm inner ring, and a nozzle plate. Even when manufactured as a ring-shaped member, anisotropy hardly occurs, homogeneous mechanical properties can be obtained in various places, and a heat-resistant steel member that can be easily manufactured and a method for manufacturing the same The purpose is to provide.

上記目的を達成するために、本発明の耐熱鋼部材は、重量%で、C:0.06〜0.18%、Si:0.05〜0.6%、Mn:0.2〜0.8%、Cr:9〜11.5%、Ni:0.1〜1%、Mo:0.8〜1.3%、Nb:0.05〜0.5%、V:0.07〜0.3%、N:0.03〜0.08%を含有し、残部がFeおよび不可避的不純物からなり、遠心鋳造でリング形状に成形されたことを特徴とする。   In order to achieve the above object, the heat-resistant steel member of the present invention is C: 0.06-0.18%, Si: 0.05-0.6%, Mn: 0.2-0. 8%, Cr: 9 to 11.5%, Ni: 0.1 to 1%, Mo: 0.8 to 1.3%, Nb: 0.05 to 0.5%, V: 0.07 to 0 .3%, N: 0.03 to 0.08%, the balance is made of Fe and inevitable impurities, and is formed into a ring shape by centrifugal casting.

この耐熱鋼部材によれば、異方性がほとんど生じず、各所において均質な機械的性質を得ることができるリング形状に成形された耐熱鋼部材を提供することができる。   According to this heat-resistant steel member, it is possible to provide a heat-resistant steel member molded in a ring shape that hardly generates anisotropy and can obtain uniform mechanical properties in various places.

本発明の耐熱鋼部材の製造方法は、上記した組成成分を有する耐熱鋼部材を製造する方法であって、前記耐熱鋼部材を構成する組成成分を溶解する溶解工程と、前記溶解された溶湯を、回転する所定の形状の鋳型に流し込み、リング形状の鋳物を形成する遠心鋳造工程と、前記鋳物に対して、焼入れおよび焼戻しの熱処理を行う熱処理工程とを具備することを特徴とする。   A method for producing a heat-resistant steel member according to the present invention is a method for producing a heat-resistant steel member having the above-described composition components, wherein a melting step for melting the composition components constituting the heat-resistant steel member, and the melted molten metal A centrifugal casting process for pouring into a rotating mold having a predetermined shape to form a ring-shaped casting, and a heat treatment process for performing a heat treatment for quenching and tempering the casting.

この耐熱鋼部材の製造方法によれば、異方性がほとんど生じず、各所において機械的性質が均質な耐熱鋼部材を容易に製造することができる。   According to this method for producing a heat-resistant steel member, it is possible to easily produce a heat-resistant steel member having almost no anisotropy and uniform mechanical properties in various places.

本発明の耐熱鋼部材およびその製造方法によれば、リング形状を有し、異方性がほとんど生じず、各所において均質な機械的性質を得ることができ、さらに、容易に製造することができる。   According to the heat-resistant steel member and the manufacturing method thereof of the present invention, it has a ring shape, hardly generates anisotropy, can obtain uniform mechanical properties in various places, and can be easily manufactured. .

本発明の一実施の形態のノズル板用のリング状耐熱鋼部材の平面図である。It is a top view of the ring-shaped heat-resistant steel member for nozzle plates of one embodiment of the present invention. ノズル板の平面図である。It is a top view of a nozzle plate. ノズル板の平面図である。It is a top view of a nozzle plate.

本発明者らは、上記した従来のタービンノズル製作における問題を解決する手段として、ダイアフラム外輪、ダイアフラム内輪およびノズル板を一体的に製作することを考えた。さらに、リング状に形成された部材を所定の個数に等分割し、それを切削加工して、ダイアフラム外輪、ダイアフラム内輪およびノズル板を一体的に有する分割構造体を製作することを考えた。そこで、本発明者らは、この分割構造体を製作するにあたって、優れた特性を有し、所望の形状に無理なく成形することができ、かつ良好な品質と経済性を発揮することができる耐熱鋼部材およびその製造方法について研究を行った結果、本発明に至った。   As a means for solving the problems in the conventional turbine nozzle manufacturing described above, the present inventors have considered to manufacture the diaphragm outer ring, the diaphragm inner ring, and the nozzle plate integrally. Furthermore, it was considered to divide a ring-shaped member into a predetermined number and cut it to produce a divided structure integrally including a diaphragm outer ring, a diaphragm inner ring, and a nozzle plate. Therefore, the inventors have excellent characteristics in manufacturing this divided structure, heat-resistant that can be easily formed into a desired shape, and can exhibit good quality and economy. As a result of research on the steel member and its manufacturing method, the present invention has been achieved.

以下、本発明の一実施の形態を説明する。   Hereinafter, an embodiment of the present invention will be described.

本発明の耐熱鋼部材は、以下に示す組成成分範囲の耐熱鋼で構成され、遠心鋳造でリング形状に成形されている。なお、以下の説明において組成成分を表す%は、特に明記しない限り重量%とする。   The heat-resistant steel member of the present invention is made of heat-resistant steel having a compositional component range shown below, and is formed into a ring shape by centrifugal casting. In the following description, “%” representing a composition component is “% by weight” unless otherwise specified.

(M1)C:0.15〜0.25%、Si:0.05〜0.6%、Mn:0.2〜0.8%、Cr:9〜11.5%、Ni:0.1〜1%、Mo:0.8〜1.3%、Nb:0.05〜0.5%、V:0.07〜0.3%、N:0.03〜0.08%を含有し、残部がFeおよび不可避的不純物からなる耐熱鋼。
(M2)C:0.06〜0.18%、Si:0.05〜0.6%、Mn:0.2〜0.8%、Cr:11.25〜13%、Ni:0.1〜1%を含有し、残部がFeおよび不可避的不純物からなる耐熱鋼。
(M3)C:0.06〜0.18%、Si:0.05〜0.6%、Mn:0.2〜0.8%、Cr:13〜14%、Ni:0.1〜1%、Nb:0.2〜0.5%、N:0.03〜0.08%を含有し、残部がFeおよび不可避的不純物からなる耐熱鋼。
(M4)C:0.06〜0.18%、Si:0.05〜0.6%、Mn:0.2〜0.8%、Cr:11.5〜13.5%、Ni:0.1〜1%を含有し、残部がFeおよび不可避的不純物からなる耐熱鋼。
(M5)C:0.15〜0.25%、Si:0.05〜0.6%、Mn:0.2〜0.8%、Cr:9〜12.5%、Ni:0.1〜1%、Mo:0.8〜1.3%、V:0.07〜0.3%、W:0.8〜1.3%を含有し、残部がFeおよび不可避的不純物からなる耐熱鋼。
(M6)C:0.06〜0.18%、Si:0.05〜0.6%、Mn:0.2〜0.8%、Cr:11.5〜12.5%、Ni:0.1〜1%、Nb:0.05〜0.5%、V:0.07〜0.3%、N:0.03〜0.08%を含有し、残部がFeおよび不可避的不純物からなる耐熱鋼。
(M7)C:0.06〜0.18%、Si:0.05〜0.6%、Mn:0.2〜0.8%、Cr:9〜11.5%、Ni:0.1〜1%、Mo:0.8〜1.3%、Nb:0.05〜0.5%、V:0.07〜0.3%、N:0.03〜0.08%を含有し、残部がFeおよび不可避的不純物からなる耐熱鋼。
(M8)C:0.06〜0.18%、Si:0.05〜0.6%、Mn:0.2〜0.8%、Cr:9〜11.5%、Ni:0.1〜1%、Mo:0.8〜1.3%、Nb:0.05〜0.5%、V:0.07〜0.3%、N:0.03〜0.08%、W:0.8〜1.3%を含有し、残部がFeおよび不可避的不純物からなる耐熱鋼。
(M1) C: 0.15 to 0.25%, Si: 0.05 to 0.6%, Mn: 0.2 to 0.8%, Cr: 9 to 11.5%, Ni: 0.1 -1%, Mo: 0.8-1.3%, Nb: 0.05-0.5%, V: 0.07-0.3%, N: 0.03-0.08% And heat-resisting steel with the balance being Fe and inevitable impurities.
(M2) C: 0.06-0.18%, Si: 0.05-0.6%, Mn: 0.2-0.8%, Cr: 11.25-13%, Ni: 0.1 Heat resistant steel containing ˜1%, the balance being Fe and inevitable impurities.
(M3) C: 0.06-0.18%, Si: 0.05-0.6%, Mn: 0.2-0.8%, Cr: 13-14%, Ni: 0.1-1 %, Nb: 0.2 to 0.5%, N: 0.03 to 0.08%, and the balance is Fe and unavoidable impurities.
(M4) C: 0.06 to 0.18%, Si: 0.05 to 0.6%, Mn: 0.2 to 0.8%, Cr: 11.5 to 13.5%, Ni: 0 .1% to 1% heat-resisting steel with the balance being Fe and inevitable impurities.
(M5) C: 0.15 to 0.25%, Si: 0.05 to 0.6%, Mn: 0.2 to 0.8%, Cr: 9 to 12.5%, Ni: 0.1 Containing 1 to 1%, Mo: 0.8 to 1.3%, V: 0.07 to 0.3%, W: 0.8 to 1.3%, the balance being Fe and inevitable impurities steel.
(M6) C: 0.06 to 0.18%, Si: 0.05 to 0.6%, Mn: 0.2 to 0.8%, Cr: 11.5 to 12.5%, Ni: 0 0.1 to 1%, Nb: 0.05 to 0.5%, V: 0.07 to 0.3%, N: 0.03 to 0.08%, and the balance from Fe and inevitable impurities Heat resistant steel.
(M7) C: 0.06 to 0.18%, Si: 0.05 to 0.6%, Mn: 0.2 to 0.8%, Cr: 9 to 11.5%, Ni: 0.1 -1%, Mo: 0.8-1.3%, Nb: 0.05-0.5%, V: 0.07-0.3%, N: 0.03-0.08% And heat-resisting steel with the balance being Fe and inevitable impurities.
(M8) C: 0.06 to 0.18%, Si: 0.05 to 0.6%, Mn: 0.2 to 0.8%, Cr: 9 to 11.5%, Ni: 0.1 -1%, Mo: 0.8-1.3%, Nb: 0.05-0.5%, V: 0.07-0.3%, N: 0.03-0.08%, W: A heat resistant steel containing 0.8 to 1.3%, the balance being Fe and inevitable impurities.

ここで、上記した(M1)〜(M8)の耐熱鋼における不可避的不純物において、その不可避的不純物のうち、Pを0.03%以下、Sを0.03%以下、Coを0.25%以下、Alを0.05%以下、Tiを0.05%以下、Snを0.04%以下、Cuを0.25%以下に抑制することが好ましい。   Here, in the inevitable impurities in the heat resistant steels (M1) to (M8) described above, among the inevitable impurities, P is 0.03% or less, S is 0.03% or less, and Co is 0.25%. Hereinafter, it is preferable to suppress Al to 0.05% or less, Ti to 0.05% or less, Sn to 0.04% or less, and Cu to 0.25% or less.

上記した組成成分範囲の耐熱鋼で構成され、遠心鋳造でリング形状に成形された本発明に係る耐熱鋼部材によれば、異方性がほとんど生じず、所望の機械的特性を有し、各所におけるその機械的特性をほぼ均質とすることができる。また、容易に所望の形状の成形することができ、さらに、優れた品質と経済性を発揮することができる。   According to the heat-resisting steel member according to the present invention, which is composed of the heat-resisting steel having the compositional component range described above and formed into a ring shape by centrifugal casting, has almost no anisotropy and has desired mechanical properties. Its mechanical properties in can be made almost homogeneous. Moreover, a desired shape can be easily formed, and excellent quality and economy can be exhibited.

次に、上記した本発明に係る耐熱鋼部材における各組成成分範囲の限定理由を説明する。   Next, the reason for limitation of each composition component range in the heat-resistant steel member according to the present invention will be described.

(1)C(炭素)
Cは、焼入れ性の確保とともに、析出強化に寄与する炭化物の構成元素として不可欠である。上記した(M1)および(M5)の耐熱鋼では、含有率が0.15%未満では、上記した効果が小さく、0.25%を超えると、高温環境下における炭化物の凝集および粗大化を促進して析出強化能を低下させる。そのため、(M1)および(M5)の耐熱鋼においては、Cの含有率を0.15〜0.25%とした。
(1) C (carbon)
C is indispensable as a constituent element of the carbide contributing to precipitation strengthening while ensuring hardenability. In the heat resistant steels (M1) and (M5) described above, if the content is less than 0.15%, the above effect is small, and if it exceeds 0.25%, the agglomeration and coarsening of carbides in a high temperature environment are promoted Thus, the precipitation strengthening ability is reduced. Therefore, in the heat resistant steels (M1) and (M5), the C content is set to 0.15 to 0.25%.

また、上記した(M2)〜(M4)、(M6)〜(M8)の耐熱鋼では、切削加工後に個別に溶接を行う場合があるため、焼入れ性や強度特性を若干犠牲にしても、溶接性や溶接部の硬化を抑制することが実用上好ましい。そのためにはCの含有量を低下させる必要があり、(M2)〜(M4)、(M6)〜(M8)の耐熱鋼においては、Cの含有率を0.06〜0.18%とした。   Moreover, in the heat-resistant steels (M2) to (M4) and (M6) to (M8) described above, since welding may be performed individually after cutting, welding may be performed even at the expense of hardenability and strength characteristics. It is practically preferable to suppress the property and hardening of the weld. Therefore, it is necessary to reduce the C content. In the heat-resistant steels (M2) to (M4) and (M6) to (M8), the C content is set to 0.06 to 0.18%. .

(2)Si(ケイ素)
Siは、脱酸剤として有用であり、耐水蒸気酸化性も向上させる。また、鋳造時の溶湯の流動性を向上させる作用も併せ持つ。しかし、その含有量が高い場合は、靭性の低下および経年的な脆化を促進するため、この観点からは含有量は可能な限り抑制されることが望ましい。本発明に係る耐熱鋼においては、その含有率が0.05%未満では、上記した効果が発揮できず、0.6%を超えると、上記した効果が著しく低下する。そのため、Siの含有率を0.05〜0.6%とした。また、Siのより好適な含有率は、0.05〜0.3%である。
(2) Si (silicon)
Si is useful as a deoxidizer and also improves steam oxidation resistance. Moreover, it also has the effect | action which improves the fluidity | liquidity of the molten metal at the time of casting. However, when the content is high, a decrease in toughness and aging embrittlement are promoted. From this viewpoint, the content is desirably suppressed as much as possible. In the heat-resisting steel according to the present invention, when the content is less than 0.05%, the above-described effect cannot be exhibited, and when it exceeds 0.6%, the above-described effect is remarkably reduced. Therefore, the Si content is determined to be 0.05 to 0.6%. Moreover, the more preferable content rate of Si is 0.05 to 0.3%.

(3)Mn(マンガン)
Mnは、脱硫剤として有用な元素であり、この観点からは0.2%以上の添加が必要である。一方、含有量が多くなると硫化物の生成量が増加するとともに、クリープ強度を低下させるため、Mn含有率の上限を0.8%とし、Mnの含有率を0.2〜0.8%とした。また、Mnのより好適な含有率は、0.3〜0.6%である。
(3) Mn (manganese)
Mn is an element useful as a desulfurizing agent. From this viewpoint, addition of 0.2% or more is necessary. On the other hand, when the content increases, the amount of sulfide generated increases and the creep strength is lowered. Therefore, the upper limit of the Mn content is set to 0.8%, and the Mn content is set to 0.2 to 0.8%. did. Moreover, the more suitable content rate of Mn is 0.3 to 0.6%.

(4)Cr(クロム)
Crは、耐酸化性、耐食性に有効であるとともに、析出強化に寄与する炭窒化物の構成元素としても不可欠な元素である。その含有率が9%を下回ると、これらの効果が認められなくなる。一方、14%を上回ると、他の添加元素量とのバランスによってはフェライトの生成量が増加し、高温強度や靭性を低下させる。また、上記した(M1)〜(M8)の各耐熱鋼毎に、他の添加元素量とのバランスが異なり、また所望の機械的特性も異なる。これらを考慮して、Crの含有率を9〜14%とした。また、Crのより好適な含有率は、10〜13.5%であり、この範囲で各耐熱鋼毎に制限範囲を変化させることが好ましい。
(4) Cr (chrome)
Cr is effective for oxidation resistance and corrosion resistance, and is also an indispensable element as a constituent element of carbonitride that contributes to precipitation strengthening. When the content is less than 9%, these effects are not recognized. On the other hand, if it exceeds 14%, the amount of ferrite produced increases depending on the balance with the amount of other additive elements, and the high temperature strength and toughness are lowered. Further, for each of the heat resistant steels (M1) to (M8) described above, the balance with the amount of other additive elements is different, and the desired mechanical properties are also different. Considering these, the Cr content is determined to be 9 to 14%. Moreover, the more suitable content rate of Cr is 10 to 13.5%, and it is preferable to change a restriction | limiting range for every heat resistant steel in this range.

(5)Mo(モリブデン)
Moは、固溶強化および炭窒化物の構成元素となり析出強化に寄与し、また、焼入れ性の向上にも寄与する。本発明に係る耐熱鋼においては、意図的にMoを添加する耐熱鋼については、0.8%以上の添加により上記効果が発揮されるが、1.3%を超えると、靭性が低下するとともに、特に鋳造時の成分偏析傾向が増大する。そのため、Moの含有率を0.8〜1.3%とした。また、Moのより好適な含有率は、0.9〜1.1%である。なお、上記した(M2)および(M6)の耐熱鋼については、不可避不純物として原料から混入する場合に限り0.2%以下を許容し、可能な限りその残存含有率を0%に近づけることが望ましい。
(5) Mo (molybdenum)
Mo becomes a constituent element of solid solution strengthening and carbonitride and contributes to precipitation strengthening, and also contributes to improvement of hardenability. In the heat-resisting steel according to the present invention, about the heat-resisting steel to which Mo is intentionally added, the above effect is exhibited by addition of 0.8% or more. In particular, the tendency of component segregation during casting increases. Therefore, the Mo content is determined to be 0.8 to 1.3%. Moreover, the more preferable content rate of Mo is 0.9 to 1.1%. For the heat-resistant steels (M2) and (M6) described above, 0.2% or less is allowed only when mixed from raw materials as inevitable impurities, and the residual content can be as close to 0% as possible. desirable.

(6)Ni(ニッケル)
Niは、焼入れ性および靭性の向上に寄与する。Niを添加する耐熱鋼においては、0.1%以上の添加で、上記効果を発揮するが、1%を超えると、クリープ強度が低下するため、Niの含有率を0.1〜1%とした。また、Niのより好適な含有率は、0.1〜0.6%である。
(6) Ni (nickel)
Ni contributes to the improvement of hardenability and toughness. In the heat-resistant steel to which Ni is added, the above effect is exhibited by addition of 0.1% or more. However, if it exceeds 1%, the creep strength decreases, so the Ni content is 0.1-1%. did. Moreover, the more preferable content rate of Ni is 0.1 to 0.6%.

(7)Nb(ニオブ)
Nbは、微細な炭窒化物の形成に寄与する。Nbを添加する耐熱鋼については、0.05%以上の添加で、微細析出物が十分に析出し、母相の回復を抑制するが、0.5%を超えると、未固溶のNb炭窒化物の生成量が著しく、靭性が低下する。さらに、CあるいはNの添加量とのバランスを考慮して、Nbの含有率を0.05〜0.5%とした。また、上記した(M1)および(M3)の耐熱鋼において、Nbのより好適な含有率は、0.35〜0.45%であり、(M6)〜(M8)の耐熱鋼において、Nbのより好適な含有率は、0.07〜0.1%である。
(7) Nb (Niobium)
Nb contributes to the formation of fine carbonitrides. For heat-resistant steel to which Nb is added, addition of 0.05% or more sufficiently precipitates fine precipitates and suppresses the recovery of the parent phase. The amount of nitride produced is significant and the toughness is reduced. Furthermore, considering the balance with the addition amount of C or N, the Nb content was set to 0.05 to 0.5%. In the heat resistant steels (M1) and (M3) described above, a more preferable content of Nb is 0.35 to 0.45%. In the heat resistant steels (M6) to (M8), Nb A more preferred content is 0.07 to 0.1%.

(8)V(バナジウム)
Vは、固溶強化および微細な炭窒化物の形成に寄与する。Vを添加する耐熱鋼については、0.07%以上の添加で、微細析出物が十分に析出し母相の回復を抑制するが、0.3%を超えると、靭性の低下を招く。さらに、添加される他の元素量とのバランスおよび所望の機械的特性を考慮して、Vの含有率を0.07〜0.3%とした。また、上記した(M1)、(M5)、(M7)および(M8)の耐熱鋼において、Vのより好適な含有率は、0.15〜0.25%であり、(M6)の耐熱鋼において、Vのより好適な含有率は、0.07〜0.1%である。
(8) V (Vanadium)
V contributes to solid solution strengthening and formation of fine carbonitrides. With respect to heat-resistant steel to which V is added, addition of 0.07% or more sufficiently precipitates fine precipitates and suppresses the recovery of the parent phase. However, if it exceeds 0.3%, the toughness is reduced. Furthermore, considering the balance with the amount of other elements to be added and desired mechanical properties, the V content is determined to be 0.07 to 0.3%. In the heat resistant steels (M1), (M5), (M7) and (M8) described above, the more preferable content of V is 0.15 to 0.25%, and the heat resistant steel of (M6) In V, a more preferable content of V is 0.07 to 0.1%.

(9)W(タングステン)
Wは、固溶強化および炭窒化物の構成元素となり析出強化に寄与する。Wを添加する耐熱鋼については、0.8%以上の添加により、上記効果が発揮されるが、1.3%を超えると、靭性が低下するとともに、特に鋳造時の成分偏析傾向が増大する。そのため、Wの含有率を0.8〜1.3%とした。また、Wのより好適な含有率は、0.9〜1.1%である。なお、上記した(M1)の耐熱鋼については、不可避不純物として原料から混入する場合に限り0.25%以下を許容し、可能な限りその残存含有率を0%に近づけることが望ましい。
(9) W (tungsten)
W becomes a constituent element of solid solution strengthening and carbonitride, and contributes to precipitation strengthening. With regard to heat-resistant steel to which W is added, the above effect is exhibited by addition of 0.8% or more. However, when it exceeds 1.3%, toughness is reduced and the tendency of component segregation during casting is increased. . Therefore, the W content is set to 0.8 to 1.3%. Moreover, the more preferable content rate of W is 0.9 to 1.1%. In addition, it is desirable that the heat resistant steel of (M1) described above is allowed to be 0.25% or less only when mixed from the raw material as an inevitable impurity, and its residual content is as close to 0% as possible.

(10)N(窒素)
Nは、微細な窒化物の形成に寄与する。Nを添加する耐熱鋼については、0.03%以上の添加で、微細析出物が十分に析出し母相の回復を抑制するが、0.08%を超えると、粗大な窒化物の生成量が増加するとともに、高温での析出物の凝集および粗大化が進行する。さらに、C、VあるいはNbの添加量とのバランスを考慮して、Nbの含有率を0.03〜0.08%とした。また、Nのより好適な含有率は、0.04〜0.07%である。
(10) N (nitrogen)
N contributes to the formation of fine nitrides. For heat-resisting steels to which N is added, addition of 0.03% or more sufficiently precipitates fine precipitates and suppresses the recovery of the parent phase, but if it exceeds 0.08%, the amount of coarse nitrides produced Increases, and agglomeration and coarsening of precipitates proceed at a high temperature. Further, considering the balance with the added amount of C, V or Nb, the Nb content was set to 0.03 to 0.08%. Moreover, the more suitable content rate of N is 0.04 to 0.07%.

(11)P(リン)、S(硫黄)、Co(コバルト)、Al(アルミニウム)、Ti(チタン)、Sn(スズ)およびCu(銅)
P、S、Co、Al、Ti、SnおよびCuは、本発明に係る耐熱鋼においては、不可避的不純物に分類されるものであり、これらは靭性低下や加熱による運転中の脆化を促進する。そのため、可能な限りその残存含有率を0%に近づけることが望ましい。また、個別の元素の残存含有率は、Pは0.03%以下、好ましくは0.02%以下、Sは0.03%以下、好ましくは0.015%以下、Coは0.25%以下、AlおよびTiは0.05%以下、好ましくは0.02%以下、Snは0.05%以下、好ましくは0.04%以下、Cuは0.25%以下である。
(11) P (phosphorus), S (sulfur), Co (cobalt), Al (aluminum), Ti (titanium), Sn (tin) and Cu (copper)
P, S, Co, Al, Ti, Sn, and Cu are classified as inevitable impurities in the heat-resistant steel according to the present invention, and these promote toughness reduction and embrittlement during operation due to heating. . Therefore, it is desirable to make the residual content as close to 0% as possible. Further, the residual content of individual elements is such that P is 0.03% or less, preferably 0.02% or less, S is 0.03% or less, preferably 0.015% or less, and Co is 0.25% or less. Al and Ti are 0.05% or less, preferably 0.02% or less, Sn is 0.05% or less, preferably 0.04% or less, and Cu is 0.25% or less.

(耐熱鋼の製造方法)
次に、上記した耐熱鋼部材の製造方法について説明する。
(Method for manufacturing heat-resistant steel)
Next, the manufacturing method of the above heat-resistant steel member will be described.

まず、前述した(M1)〜(M8)のいずれかの耐熱鋼を構成する組成成分を、大気中において溶解する(溶解工程)。   First, the composition components constituting any of the heat resistant steels (M1) to (M8) described above are dissolved in the atmosphere (dissolution step).

続いて、大気中において、溶解した溶湯を、遠心鋳造装置の回転するリング形状の鋳型に流し込み、リング形状の鋳物を形成する(遠心鋳造工程)。この際の冷却は、自然放冷によって行われる。   Subsequently, in the atmosphere, the molten metal is poured into a rotating ring-shaped mold of a centrifugal casting apparatus to form a ring-shaped casting (centrifugal casting process). The cooling at this time is performed by natural cooling.

続いて、リング形状の鋳物に対して、焼入れおよび焼戻しの熱処理を行う(熱処理工程)。なお、各材質に好適な機械的特性を発揮させるための焼入れおよび焼戻しの熱処理の条件は、各耐熱鋼毎に異なる。   Subsequently, the ring-shaped casting is subjected to heat treatment for quenching and tempering (heat treatment step). In addition, the conditions of the heat processing of quenching and tempering for exhibiting a mechanical characteristic suitable for each material differ for each heat-resistant steel.

ここで、リング形状とは、両端が開口された筒体、中央が開口した円板などの形状をいい、筒体や円板などにおいて、その中心軸方向に外径や内径を増加させたり、減少させた形状も含む。   Here, the ring shape means a shape such as a cylinder with both ends opened, a disk with an opening at the center, etc. In the cylinder or disk, the outer diameter or the inner diameter is increased in the central axis direction, Includes reduced shapes.

次に、本発明に係る耐熱鋼部材が、リング形状に成形されることが好適な理由を説明する。   Next, the reason why the heat-resistant steel member according to the present invention is preferably formed into a ring shape will be described.

蒸気タービンの羽根、ノズル板、弁内臓品、熱交換器などの小型部品は、通常、鍛造あるいは圧延で成形された角材、もしくは鍛造成形で比較的最終形状に近い状態に成形された部材を機械加工により切削して仕上げる。これらのうち、例えば羽根やノズル板は、タービンロータやノズルダイアフラムのような曲率を有する一定の円周上に組込まれるため、高い寸法精度が要求される。   Small parts such as steam turbine blades, nozzle plates, valve built-in parts, and heat exchangers are usually machined by squares formed by forging or rolling, or members formed by forging, which are relatively close to the final shape. Finish by cutting by machining. Among these, for example, the blades and the nozzle plate are incorporated on a certain circumference having a curvature such as a turbine rotor and a nozzle diaphragm, so that high dimensional accuracy is required.

しかしながら、角材からの削り出した部材や個々に鍛造成形された部品部材は、個体ごとの寸法上のばらつきが不可避的に発生し、また、円周上に組込む際の寸法精度が低く、組込み時に修正加工を施す場合がある。また、弁内臓品や熱交換器などの小型部品は、最終形状としてリング状や円筒形状に加工される場合が多い。そのため、切削加工による歩留りや製作工数の観点からは、部材自体をリング形状に製作することによって、部品の製作工程をより合理化することが可能である。   However, parts cut out from square bars and individually forged parts are inevitably subject to dimensional variations from one individual to another, and the dimensional accuracy when assembled on the circumference is low. There is a case where correction processing is performed. In addition, small parts such as internal valve products and heat exchangers are often processed into a ring shape or a cylindrical shape as a final shape. Therefore, from the viewpoint of the yield by cutting and the number of manufacturing steps, it is possible to further rationalize the part manufacturing process by manufacturing the member itself in a ring shape.

すなわち、リング形状として製作された部材においては、内外輪側や側面の曲率を有する部位をリング形状のまま切削して寸法を調整することが可能である。また、加工後のリングを割断して、個別部品毎に仕上げ加工をすることで、加工工数は大幅に削減し、歩留りの向上を実現することができる。さらに、個体の寸法精度を各段に向上させることが可能となる。   That is, in a member manufactured as a ring shape, it is possible to adjust the dimensions by cutting a portion having the curvature of the inner and outer rings or the side surface while maintaining the ring shape. Also, by cutting the ring after processing and finishing each individual part, the number of processing steps can be greatly reduced, and the yield can be improved. Furthermore, it becomes possible to improve the dimensional accuracy of the individual to each stage.

これらのことから、蒸気タービンの羽根、ノズル板などの部材として利用可能な本発明に係る耐熱鋼部材は、リング形状に成形されることが好適である。   For these reasons, it is preferable that the heat-resistant steel member according to the present invention, which can be used as a member of a steam turbine blade, a nozzle plate, or the like, is formed into a ring shape.

次に、本発明に係るリング状の耐熱鋼部材が、遠心鋳造により成形されることが好適な理由を説明する。   Next, the reason why the ring-shaped heat-resistant steel member according to the present invention is preferably formed by centrifugal casting will be described.

遠心鋳造工程は、原料の溶解と鋳造の主として2つの工程からなり、所望の形状の鋳型がある場合、リング形状に成形するための所要時間は数時間である。本発明の化学組成成分範囲の材料は、鍛造あるいは圧延部材としても製作可能であるが、これらを角材として成形した後に削り出した場合、あるいは個別の鍛造後に切削加工して製作した場合は、部材の製作から加工に際し、少なくとも数ヶ月の時間を要する。   The centrifugal casting process mainly includes two steps of melting the raw material and casting. When there is a mold having a desired shape, the time required for forming into a ring shape is several hours. The material of the chemical composition component range of the present invention can be manufactured as a forged or rolled member, but when it is cut out after being molded as a square member, or when it is manufactured by cutting after individual forging, the member It takes at least several months from the production to the processing.

これらのことから、本発明に係る耐熱鋼部材は、遠心鋳造法によってリング形状に成形され、その後の切削加工で仕上げられることが、製造工数の観点からも好適である。   From these facts, it is preferable from the viewpoint of manufacturing man-hours that the heat-resistant steel member according to the present invention is formed into a ring shape by a centrifugal casting method and then finished by cutting.

なお、遠心鋳造部材の品質を向上させるため、縦型遠心鋳造時の鋳型上蓋の内径側に、押し湯を付設してもよい。また、遠心鋳造部材の品質を向上させるため、遠心鋳造時の注湯を2段階に分け、内径側の熱容量を大きくし、この部位の冷却を遅滞させることで、鋳造欠陥の発生位置を内径側の切削部位に移動させることも可能である。また、上述のように、鋳型の形状変更や溶湯の注湯方法を改善するのみならず、リング状の耐熱鋼部材の断面寸法の縦横比を変更することによって、最終的な製品形状に鋳造欠陥が残存することを避けることは当然考慮されるべきである。   In order to improve the quality of the centrifugal cast member, a hot water may be provided on the inner diameter side of the mold upper lid at the time of vertical centrifugal casting. In addition, in order to improve the quality of centrifugal cast members, the pouring at the time of centrifugal casting is divided into two stages, the heat capacity on the inner diameter side is increased, and the cooling of this part is delayed so that the position of occurrence of casting defects is on the inner diameter side. It is also possible to move to the cutting site. In addition, as described above, not only improving the mold shape and the pouring method of the molten metal, but also changing the aspect ratio of the cross-sectional dimension of the ring-shaped heat-resistant steel member, the casting defect to the final product shape Of course, it should be taken into account that it is avoided.

ここで、本発明の化学組成範囲にあるリング状の耐熱鋼部材は、ダイアフラム外輪、ダイアフラム内輪およびノズル板を一体的に有する分割構造体以外にも、例えば、上記したように、蒸気タービンの羽根、ノズル板、ダイアフラム、各種リング部品、リング形状のシート、各種円筒形状部品などの構成材料として利用することができる。なお、本発明に係るリング状の耐熱鋼部材の用途は、上記したものに限られるものではなく、他の分野の耐熱鋼として用いてもよい。なお、鋳型は、製作する部材の形状に対応して適宜製作されることが好ましい。   Here, the ring-shaped heat-resisting steel member in the chemical composition range of the present invention includes, for example, a blade of a steam turbine as described above, in addition to a divided structure integrally including a diaphragm outer ring, a diaphragm inner ring, and a nozzle plate. , Nozzle plates, diaphragms, various ring parts, ring-shaped sheets, various cylindrical parts, and the like. In addition, the use of the ring-shaped heat-resisting steel member according to the present invention is not limited to the above, and may be used as heat-resisting steel in other fields. In addition, it is preferable that a casting_mold | template is suitably manufactured according to the shape of the member to manufacture.

以下に、本発明の実施例について説明する。   Examples of the present invention will be described below.

(第1の実施例)
第1の実施例では、本発明の化学組成範囲にある耐熱鋼部材が、リング形状に製作された場合の効果について、図を参照して説明する。
(First embodiment)
In the first embodiment, the effect when the heat-resistant steel member within the chemical composition range of the present invention is manufactured in a ring shape will be described with reference to the drawings.

図1に、例えばノズル板用のリング状耐熱鋼部材10の平面図を示す。図2および図3に、ノズル板の平面図を示す。   FIG. 1 shows a plan view of a ring-shaped heat-resistant steel member 10 for a nozzle plate, for example. 2 and 3 are plan views of the nozzle plate.

リング状耐熱鋼部材10は、同心の外径Dと内径d、厚さTを有し、これらのD、dおよびTは、それぞれノズル板20の外径、内径および厚さに加工代を考慮して設定された寸法である。また、αは、リング状耐熱鋼部材10を等分割する際の1つの分割片に対応する中心角度である。   The ring-shaped heat-resistant steel member 10 has a concentric outer diameter D, inner diameter d, and thickness T, and these D, d, and T take into account the machining allowance for the outer diameter, inner diameter, and thickness of the nozzle plate 20, respectively. It is the dimension set as. Moreover, (alpha) is a center angle corresponding to one division piece at the time of equally dividing the ring-shaped heat-resisting steel member 10.

リング状耐熱鋼部材10の内外周、上下面は、予め必要寸法に一体的に切削加工される。その後、リング状耐熱鋼部材10は、1つのノズル板を構成するのに必要な角度で、ラジアル線上に等分割される。そして、1つのリング状耐熱鋼部材10からノズル板を形成するためのノズル板部材20が、「360/α」個得られる。   The inner and outer peripheries and the upper and lower surfaces of the ring-shaped heat-resistant steel member 10 are integrally machined to necessary dimensions in advance. Thereafter, the ring-shaped heat-resistant steel member 10 is equally divided on a radial line at an angle necessary to form one nozzle plate. Then, “360 / α” nozzle plate members 20 for forming a nozzle plate from one ring-shaped heat-resistant steel member 10 are obtained.

ここで、ノズル板部材20は、ラジアル線で割断されるため、仕上がり形状に即した形状となる。そのため、特に円周の加工精度や寸法精度が大幅に向上し、歩留りが向上するとともに、切削加工に要する時間が大幅に短縮される。   Here, since the nozzle plate member 20 is cleaved by a radial line, it has a shape conforming to the finished shape. For this reason, particularly the processing accuracy and dimensional accuracy of the circumference are greatly improved, the yield is improved, and the time required for cutting is greatly shortened.

一方、ノズル板部材として角材を用いる場合、割断された角材に、所定の基準面を設け、その基準面に基づいて、角材を個々のノズル板部材に分割し、その分割片を切削加工する。特に、図2および図3に示すような内外輪側に嵌合部31、32、41、42を有するノズル板30、40の場合、中心角による内外輪の寸法差が存在するため、内外輪の嵌合部の寸法精度と、内輪側の歩留りが低下する。   On the other hand, when a square bar is used as the nozzle plate member, a predetermined reference plane is provided on the cut square bar, the square bar is divided into individual nozzle plate members based on the reference plane, and the divided pieces are cut. In particular, in the case of the nozzle plates 30 and 40 having the fitting portions 31, 32, 41 and 42 on the inner and outer ring side as shown in FIGS. 2 and 3, there is a difference in the dimensions of the inner and outer rings depending on the central angle. The dimensional accuracy of the fitting portion and the yield on the inner ring side are reduced.

また、リング状耐熱鋼部材10は、遠心鋳造法により製作されるので、リング状耐熱鋼部材10の製造の所要時間を大幅に短縮することができる。さらに、上述の寸法精度や歩留りを向上させ、切削加工に要する時間を大幅に短縮することができる。   Moreover, since the ring-shaped heat-resistant steel member 10 is manufactured by the centrifugal casting method, the time required for manufacturing the ring-shaped heat-resistant steel member 10 can be greatly shortened. Furthermore, the above-described dimensional accuracy and yield can be improved, and the time required for cutting can be greatly shortened.

(第2の実施例)
第2の実施例では、リング状耐熱鋼部材の製作に際し、本発明の化学組成範囲が好適な理由について説明する。
(Second embodiment)
In the second embodiment, the reason why the chemical composition range of the present invention is suitable for manufacturing a ring-shaped heat-resistant steel member will be described.

試料となるリング状耐熱鋼部材(供試耐熱鋼1〜供試耐熱鋼8、比較供試耐熱鋼1および比較供試耐熱鋼2)は、それぞれ各耐熱鋼の組成成分約800kgを大気中で溶解し、大気中で外径が1000mm、内径が400mm、厚さが120mmのリング形状に遠心鋳造した。   The ring-shaped heat-resistant steel members (sample heat-resistant steel 1 to sample heat-resistant steel 8, comparative sample heat-resistant steel 1 and comparative sample heat-resistant steel 2) to be used as samples are each composed of about 800 kg of each heat-resistant steel in the atmosphere. Dissolved and centrifugally cast into a ring shape having an outer diameter of 1000 mm, an inner diameter of 400 mm, and a thickness of 120 mm in the atmosphere.

表1に、作製されたリング状耐熱鋼部材の化学組成を示す。表1に示されたリング状耐熱鋼部材のうち供試耐熱鋼1〜供試耐熱鋼8は、本発明に係る組成範囲にある耐熱鋼部材である。一方、比較供試耐熱鋼1および比較供試耐熱鋼2は、その組成が本発明の化学組成範囲にない耐熱鋼部材であり、比較例である。なお、表1に示された数値の単位は、重量%である。   Table 1 shows the chemical composition of the produced ring-shaped heat-resistant steel member. Of the ring-shaped heat-resistant steel members shown in Table 1, the test heat-resistant steel 1 to the test heat-resistant steel 8 are heat-resistant steel members in the composition range according to the present invention. On the other hand, the comparative test heat resistant steel 1 and the comparative test heat resistant steel 2 are heat resistant steel members whose compositions are not within the chemical composition range of the present invention, and are comparative examples. In addition, the unit of the numerical value shown in Table 1 is weight%.

各リング状耐熱鋼部材には、各材質に好適な機械的特性を発揮させるための焼入れおよび焼戻しの熱処理を施した。なお、熱処理は、各耐熱鋼部材ともに所望の機械的性質を得るため、異なる条件で行われた。   Each ring-shaped heat-resistant steel member was subjected to a heat treatment such as quenching and tempering in order to exhibit mechanical characteristics suitable for each material. The heat treatment was performed under different conditions in order to obtain desired mechanical properties for each heat-resistant steel member.

Figure 2010242221
Figure 2010242221

所定の熱処理が施された各リング状耐熱鋼部材の半径方向、接線方向および厚さ方向に沿って試験片の部材を採取し、それぞれについてJIS4号2mmVノッチシャルピ衝撃試験片を作製した。そして、これらの試験片を用いて、20℃の雰囲気温度下でシャルピ衝撃試験を実施した。また、各リング状耐熱鋼部材について常温0.2%耐力を測定した。   Test piece members were taken along the radial direction, the tangential direction, and the thickness direction of each ring-shaped heat-resistant steel member subjected to a predetermined heat treatment, and JIS No. 2 mm V notch Charpy impact test pieces were prepared for each. And the Charpy impact test was implemented under 20 degreeC atmospheric temperature using these test pieces. Moreover, normal temperature 0.2% yield strength was measured about each ring-shaped heat-resistant steel member.

表2に、20℃衝撃吸収エネルギおよび常温0.2%耐力の測定結果を示す。なお、表2には、厚さ方向に沿って採取された試験片おける衝撃吸収エネルギおよび常温0.2%耐力の値を1として示し、他の方向に沿って採取された試験片おける結果は、厚さ方向に沿って採取された試験片に対する比として示されている。   Table 2 shows the measurement results of 20 ° C. impact absorption energy and normal temperature 0.2% yield strength. Table 2 shows the impact absorption energy and the normal temperature 0.2% proof stress value of the test piece taken along the thickness direction as 1, and the results of the test piece taken along the other direction are as follows. , Shown as a ratio to specimens taken along the thickness direction.

表2に示された結果から、供試耐熱鋼1〜供試耐熱鋼8の常温0.2%耐力は、いずれの方向についても、0.9〜1.1、20℃衝撃吸収エネルギは、0.8〜1.1を示し、各リング状耐熱鋼部材の半径方向、接線方向および厚さ方向について、ほぼ同等の引張性質および衝撃性質を発揮できることがわかった。一方、比較供試耐熱鋼1および比較供試耐熱鋼2では、常温0.2%耐力および20℃衝撃吸収エネルギともに、0.5を下回る値が過半を占め、材料特性の異方性が極めて大きいことがわかった。   From the results shown in Table 2, the normal temperature 0.2% proof stress of the test heat resistant steel 1 to the test heat resistant steel 8 is 0.9 to 1.1 in any direction, and the 20 ° C. impact absorption energy is 0.8 to 1.1, and it was found that substantially the same tensile properties and impact properties can be exhibited in the radial direction, tangential direction, and thickness direction of each ring-shaped heat-resistant steel member. On the other hand, in the comparative test heat resistant steel 1 and the comparative test heat resistant steel 2, both the room temperature 0.2% proof stress and the 20 ° C. shock absorption energy account for the majority of the values below 0.5, and the material property anisotropy is extremely high. I found it big.

この測定により、本発明に係る耐熱鋼部材は、リング状の部材として製作した場合に、異方性がほとんど生じず、均質な機械的性質を得ることができることが明らかになった。   From this measurement, it has been clarified that the heat-resistant steel member according to the present invention has almost no anisotropy and can obtain homogeneous mechanical properties when manufactured as a ring-shaped member.

Figure 2010242221
Figure 2010242221

10…リング状耐熱鋼部材、20…ノズル板、30,40…ノズル板、31,32,41,42…嵌合部、D…外径、d…内径、T…厚さ。   DESCRIPTION OF SYMBOLS 10 ... Ring-shaped heat resistant steel member, 20 ... Nozzle plate, 30, 40 ... Nozzle plate, 31, 32, 41, 42 ... Fitting part, D ... Outer diameter, d ... Inner diameter, T ... Thickness.

Claims (3)

重量%で、C:0.06〜0.18%、Si:0.05〜0.6%、Mn:0.2〜0.8%、Cr:9〜11.5%、Ni:0.1〜1%、Mo:0.8〜1.3%、Nb:0.05〜0.5%、V:0.07〜0.3%、N:0.03〜0.08%を含有し、残部がFeおよび不可避的不純物からなり、遠心鋳造でリング形状に成形されたことを特徴とする耐熱鋼部材。   By weight, C: 0.06 to 0.18%, Si: 0.05 to 0.6%, Mn: 0.2 to 0.8%, Cr: 9 to 11.5%, Ni: 0.0. Contains 1 to 1%, Mo: 0.8 to 1.3%, Nb: 0.05 to 0.5%, V: 0.07 to 0.3%, N: 0.03 to 0.08% A heat-resisting steel member, wherein the balance is made of Fe and inevitable impurities and is formed into a ring shape by centrifugal casting. 前記不可避的不純物が、重量%で、P:0.03%以下、S:0.03%以下、Co:0.25%以下、Al:0.05%以下、Ti:0.05%以下、Sn:0.04%以下、Cu:0.25%以下に抑制されていることを特徴とする請求項1記載の耐熱鋼部材。   The inevitable impurities are, by weight, P: 0.03% or less, S: 0.03% or less, Co: 0.25% or less, Al: 0.05% or less, Ti: 0.05% or less, The heat resistant steel member according to claim 1, wherein Sn is suppressed to 0.04% or less and Cu: 0.25% or less. 請求項1または2記載の組成成分を有する耐熱鋼部材を製造する方法であって、
前記耐熱鋼部材を構成する組成成分を溶解する溶解工程と、
前記溶解された溶湯を、回転する所定の形状の鋳型に流し込み、リング形状の鋳物を形成する遠心鋳造工程と、
前記鋳物に対して、焼入れおよび焼戻しの熱処理を行う熱処理工程と
を具備することを特徴とする耐熱鋼部材の製造方法。
A method for producing a heat-resistant steel member having the composition component according to claim 1 or 2,
A melting step for dissolving the compositional components constituting the heat-resistant steel member;
The molten molten metal is poured into a rotating mold having a predetermined shape to form a ring-shaped casting, and a centrifugal casting process.
And a heat treatment step of performing heat treatment of quenching and tempering on the casting.
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