JP2010227070A - Yolk-containing neutral-region liquid seasoning - Google Patents

Yolk-containing neutral-region liquid seasoning Download PDF

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JP2010227070A
JP2010227070A JP2009080927A JP2009080927A JP2010227070A JP 2010227070 A JP2010227070 A JP 2010227070A JP 2009080927 A JP2009080927 A JP 2009080927A JP 2009080927 A JP2009080927 A JP 2009080927A JP 2010227070 A JP2010227070 A JP 2010227070A
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mass
seasoning
egg yolk
yolk
oil
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JP4436432B1 (en
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Masaki Oike
正樹 大池
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Mizkan Group Corp
Mizkan Co Ltd
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Mizkan Co Ltd
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Abstract

<P>PROBLEM TO BE SOLVED: To provide a yolk-containing neutral-region liquid seasoning having the flavor of fresh yolk, storable for a long period of time at normal temperature, and storable for a certain fixed period of time even after unsealed. <P>SOLUTION: The yolk-containing liquid seasoning contains: yolk at ≥5 mass% and <45 mass% based on the whole of the seasoning; the total of the solid of sugar and oil at 35-90 mass% based on the whole of the seasoning; the sugar at ≥50 mass% as a solid content based on the mass of the yolk and at ≤20 mass% based on the whole of the seasoning in terms of sweetness; and the oil at 10-70 mass% based on the whole of the seasoning. The yolk-containing liquid seasoning is emulsified into oil-in-water type one and adjusted to pH 5.5-8.0. <P>COPYRIGHT: (C)2011,JPO&INPIT

Description

本発明は、常温で長期保存が可能であり、尚且つ開封後も一定期間保存が可能である、生の卵黄風味をもった中性領域の液状調味料に関する。   The present invention relates to a liquid seasoning in a neutral region having a raw egg yolk flavor that can be stored at room temperature for a long period of time and can be stored for a certain period after opening.

卵は、その優れた栄養価に加え、特徴ある風味・色・物性、または卵のもつ乳化作用などからさまざまな料理や加工食品に利用されている。例えば、茶碗蒸しやプリンなどは卵が加熱により凝固する性質を利用している。マヨネーズやドレッシングでは、水、酢、油などを卵黄で乳化させることでコクのある風味やなめらか食感・物性を作り出している。
このような、卵黄を加熱により凝固・変性させた加工食品や、酸性領域の調味料は今まで数多く提供されてきた。
Eggs are used in various dishes and processed foods because of their excellent nutritional value, distinctive flavor, color and physical properties, and the emulsifying action of eggs. For example, chawanmushi and pudding use the property that eggs solidify by heating. In mayonnaise and dressing, water, vinegar, oil, etc. are emulsified with egg yolk to create a rich flavor, smooth texture and physical properties.
Many processed foods in which egg yolk is coagulated / denatured by heating and seasonings in the acidic region have been provided.

一方で、卵のもつコクやまろやかさを味わうため、何も調理せず生のまま食したり、温泉たまごのようにわずかな加熱で食することも好まれる。
このような、中性領域で、且つコクのある液状をした卵本来の物性を味わうためには、生卵そのものや、賞味期限の短いチルド食品を利用するしかないのが現状であった。
ただ、それらを利用するにしても、サルモネラなどの食中毒菌をはじめとする衛生面の問題や、冷蔵保存が必要で日持ちがしないなどの実用面での不便さがあった。
On the other hand, in order to taste the richness and mellowness of eggs, it is also preferred to eat raw without cooking anything, or to eat with slight heating like hot spring eggs.
In order to taste the original physical properties of such a neutral and rich liquid egg, there is no choice but to use raw eggs themselves or chilled foods with a short shelf life.
However, even if they were used, there were problems of hygiene including food poisoning bacteria such as Salmonella, and practical inconvenience such as needing refrigerated storage and not lasting.

それを解決する手段として、例えば特許文献1乃至3のような提案がなされている。
特許文献1(保存性に優れた卵黄組成物およびそれを用いた食品)では、卵黄に糖アルコールおよびトレハロースを配合し、65〜90℃で加熱殺菌した卵黄組成物をカルボナーラソースに用いることが提案されている。
しかしながら、このものは、油類が含有されていないため糖類の甘みが引き立ちすぎ、生の卵黄の風味として好ましくないものであった。さらに、このものは、卵黄含有量が50%以上と多いために微生物耐性が低く、未開封状態での長期常温保存は可能であっても、開封後に一定期間保存することはできない処方であった。
As means for solving this, proposals such as Patent Documents 1 to 3 have been proposed.
In Patent Document 1 (an egg yolk composition excellent in preservability and a food using the same), it is proposed to use an egg yolk composition mixed with sugar alcohol and trehalose in egg yolk and sterilized by heating at 65 to 90 ° C. for carbonara sauce. Has been.
However, since this oil does not contain oil, the sweetness of saccharides is too conspicuous, which is not preferable as a raw egg yolk flavor. Furthermore, this product has a low yogurt content of 50% or more and thus has low microbial resistance, and even though it can be stored at room temperature for a long period of time in an unopened state, it cannot be stored for a certain period after opening. .

特許文献2(カルボナーラ用レトルトソース)では、卵黄に糖アルコールと乳化剤を配合することでレトルト処理しても食感がなめらかで褐変の少ないカルボナーラ用ソースが提案されている
しかしながら、このものは、凝固はしないものの、レトルト加熱により生の卵黄の風味・食感は損なわれてしまっている。
Patent Document 2 (Retort Sauce for Carbonara) proposes a carbonara sauce that has a smooth texture and little browning even when retort processing is performed by adding sugar alcohol and an emulsifier to egg yolk. Although it does not, the flavor and texture of raw egg yolk are damaged by retort heating.

特許文献3(卵黄含有食品用原料及びその製造方法)では、レトルト処理されても卵黄が凝集して塊状となることがなく、滑らかな食感用を有する卵黄含有食品用原料の製造方法が提案されているが、凝固させた卵黄を微細化する方法であり、卵黄の風味・食感は損なわれてしまっている。   Patent Document 3 (yolk-containing food raw material and method for producing the same) proposes a method for producing an egg yolk-containing food raw material that has a smooth texture without egg yolk flocculating and agglomerating even when retorted. However, it is a method of refining the solidified egg yolk, and the flavor and texture of the egg yolk have been impaired.

このように引用文献1〜3記載の発明は、常温で長期保存が可能な、生の卵黄風味をもった液状卵黄組成物としてはいずれも改良の余地があった。   As described above, the inventions described in the cited documents 1 to 3 have room for improvement as liquid egg yolk compositions having a raw egg yolk flavor that can be stored at room temperature for a long period of time.

特開2001−178417号公報JP 2001-178417 A 特開平10−257871号公報Japanese Patent Laid-Open No. 10-257871 特開2008−199900号公報JP 2008-199900 A

以上のように、生の卵黄風味を付与する加工食品は、提案が散見されるものの、生の卵黄風味を付与する調味料であって、開封後の保存性にも優れる調味料は未だ提案されておらず改良の余地があった。   As described above, although processed foods that give raw egg yolk flavors are often proposed, seasonings that give raw egg yolk flavors and have excellent storage stability after opening have not yet been proposed. There was room for improvement.

そこで、本発明の目的は、マヨネーズなどの酸性調味料とは異なり、中性領域で卵黄本来の風味を保持しながら、常温で長期保存が可能であり、且つ開封後も冷蔵下にて一定期間日持ちがする卵黄含有液状調味料を提供することである。
即ち、本発明は、常温で長期保存が可能であり、尚且つ開封後も一定期間保存が可能である、生の卵黄風味をもった中性領域の液状調味料を提供することを目的とするものである。
Therefore, the object of the present invention is different from acidic seasonings such as mayonnaise, and can be stored for a long time at room temperature while maintaining the original flavor of egg yolk in a neutral region, and after opening for a certain period under refrigeration. It is to provide an egg yolk-containing liquid seasoning that will last a long time.
That is, an object of the present invention is to provide a liquid seasoning in a neutral region having a raw egg yolk flavor that can be stored at room temperature for a long period of time and can be stored for a certain period after opening. Is.

そこで、本発明は上記課題を解決すべく鋭意検討を重ねた結果、比較的少量の卵黄と、糖類、油類を必須材料として用い、尚且つそれらを絶妙な割合に調整した場合に、初めて従来では達成できていなかった卵黄の風味・物性と保存性の両方を同時に満足させることができる調味料が製造し得ることを見出し、この知見に基づいて本発明を完成するに至った。 Accordingly, the present inventors have result of extensive studies to solve the above problems, a relatively small amount of egg yolk, sugar, when used oils as essential materials, Note that and to adjust their exquisite proportions, for the first time It has been found that a seasoning that can satisfy both the flavor, physical properties and storage stability of egg yolk, which could not be achieved in the past, can be produced, and the present invention has been completed based on this finding.

すなわち、本発明は、次のとおりのものである。
(1):卵黄を含有する液状調味料において、卵黄を調味料全体の5質量%以上45質量%未満、糖類の固形分量及び油類の合計で調味料全体の35質量%以上90質量%以下含有し、該糖類は固形分量として該卵黄質量の50質量%以上を含み、且つ甘味度換算で調味料全体の20質量%以下の量で含有しており、該油類は調味料全体の10質量%以上70質量%以下の量で含有している調味料であって、水中油型に乳化され、pH5.5〜8.0に調整されていることを特徴とする卵黄含有液状調味料。
(2):水分活性が0.88以下に調整されていることを特徴とする、前記(1)に記載の卵黄含有液状調味料。
(3):90℃以上の高温殺菌による卵黄変性がされていないことを特徴とする、前記(1)〜(2)のいずれか1項に記載の卵黄含有液状調味料。
(4):食塩を調味料全体の1質量%以上6質量%以下の量で含有していることを特徴とする、前記(1)〜(3)のいずれかに1項に記載の卵黄含有液状調味料。
(5):再密封可能な密封容器に充填されたことを特徴とする、前記(1)〜(4)のいずれかに1項に記載の卵黄含有液状調味料。
That is, the present invention is as follows.
(1): In a liquid seasoning containing egg yolk, the egg yolk is 5% by mass to less than 45% by mass of the whole seasoning, and the total amount of saccharide solids and oils is 35% by mass to 90% by mass of the whole seasoning. The saccharide contains 50% by mass or more of the egg yolk mass as a solid content, and is contained in an amount of 20% by mass or less of the whole seasoning in terms of sweetness, and the oil is 10% of the whole seasoning. An egg yolk-containing liquid seasoning which is contained in an amount of not less than 70% by mass and is emulsified in an oil-in-water type and adjusted to pH 5.5 to 8.0.
(2): The egg yolk-containing liquid seasoning according to (1) above, wherein the water activity is adjusted to 0.88 or less.
(3) The egg yolk-containing liquid seasoning according to any one of (1) to (2), wherein the egg yolk is not denatured by high-temperature sterilization at 90 ° C. or higher.
(4) The egg yolk content according to any one of (1) to (3) above, wherein the salt is contained in an amount of 1% by mass or more and 6% by mass or less of the whole seasoning. Liquid seasoning.
(5) The egg yolk-containing liquid seasoning according to any one of (1) to (4) above, which is filled in a resealable sealed container.

本発明によれば、中性領域で卵黄本来の風味を保持しながら、常温で長期保存が可能であり、且つ開封後も冷蔵下にて一定期間日持ちがする卵黄含有液状調味料を提供することができる。
本発明の卵黄含有液状調味料は、納豆、山芋、うどん、そば、ラーメンなどを食する際に、卵黄の代替として本調味料を用いることで、卵黄と同じような風味やコク、食感を付与することができる。
According to the present invention, there is provided an egg yolk-containing liquid seasoning that can be stored for a long period of time at room temperature while maintaining the original flavor of egg yolk in a neutral region, and that can be kept for a certain period of time under refrigeration even after opening. Can do.
The egg yolk-containing liquid seasoning of the present invention has the same flavor, richness and texture as egg yolk by using this seasoning as an alternative to egg yolk when eating natto, yam, udon, soba, ramen, etc. Can be granted.

以下、本発明について詳細に説明する。
本発明は、卵黄含有液状調味料に関し、卵黄を含有する液状調味料において、卵黄を調味料全体の5質量%以上45質量%未満、糖類の固形分量及び油類の合計で調味料全体の35質量%以上90質量%以下含有し、該糖類は固形分量として該卵黄質量の50質量%以上を含み、且つ甘味度換算で調味料全体の20質量%以下の量で含有しており、該油類は調味料全体の10質量%以上70質量%以下の量で含有している調味料であって、水中油型に乳化され、pH5.5〜8.0に調整されていることを特徴とするものである。
Hereinafter, the present invention will be described in detail.
The present invention relates to an egg yolk-containing liquid seasoning. In a liquid seasoning containing egg yolk, the egg yolk is 5% by mass or more and less than 45% by mass of the whole seasoning, and the total amount of saccharide solids and oils is 35%. The saccharide contains 50% by mass or more of the egg yolk mass as a solid content, and is contained in an amount of 20% by mass or less of the whole seasoning in terms of sweetness, Is a seasoning contained in an amount of 10% by mass or more and 70% by mass or less of the whole seasoning, characterized by being emulsified in an oil-in-water type and adjusted to pH 5.5 to 8.0. To do.

本発明において用いる卵黄としては、鶏卵をはじめ、その他の鳥類、家禽の卵の卵黄も使用することができる。全卵から卵白を分離して得られる生卵黄あるいは、乾燥卵黄を水戻しした卵黄液であってもよい。また、その過程で卵黄の他に卵白等が少量入っていてもよい。また、糖や食塩を加えて冷凍耐性を付与した冷凍原料であってもよい。   As egg yolk used in the present invention, egg yolk of chicken eggs, other birds and poultry eggs can also be used. It may be a raw egg yolk obtained by separating the egg white from the whole egg or an egg yolk liquid obtained by rehydrating the dried egg yolk. Further, in the process, a small amount of egg white may be contained in addition to egg yolk. Moreover, the frozen raw material which added sugar and salt and provided freezing tolerance may be sufficient.

本発明の調味料には、卵黄風味を与える調味料としては比較的少量の卵黄を含有する。
具体的には、調味料全体のうち卵黄を5質量%以上45質量%未満含有する。卵黄がこれより少なくなると、卵黄本来の風味の乏しい調味料となってしまう。卵黄が多すぎると、相対的に水分活性が高い調味料となり、特に開封後の保存性の悪い調味料となってしまう。卵黄は好ましくは8質量%以上30質量%以下、さらには10質量%以上20質量%以下とすることが好ましい。
The seasoning of the present invention contains a relatively small amount of egg yolk as a seasoning that gives an egg yolk flavor.
Specifically, it contains 5% by mass or more and less than 45% by mass of egg yolk in the whole seasoning. If the egg yolk is less than this, it becomes a seasoning that lacks the original flavor of the egg yolk. When there is too much egg yolk, it becomes a seasoning with a relatively high water activity, and it becomes a seasoning with especially poor storage stability after opening. The egg yolk is preferably 8% by mass to 30% by mass, more preferably 10% by mass to 20% by mass.

本発明には糖類は必須である。糖類を添加することによって、加熱殺菌時に卵黄を凝固・変性しにくくするためである。
本発明に用いる糖類としては、結果として加熱殺菌時に卵黄の凝固・変性を回避できるもので、食品として一般に使用されるものであればいずれもかまわない。
例えば、単糖では、グルコース、フラクトース、マンノース、ガラクトース、キシロース、リボース、アラビノースなどが挙げられる。二糖では、スクロース、マルトース、ラクトース、セロビオース、トレハロースなどが挙げられる。また、ソルビトール、マルチトールなどの糖アルコール類、その他澱粉の加水分解物や水素添加した還元水あめなどが挙げられる。中でも、甘味度が小さく、変色を抑制できるトレハロースや糖アルコール類を使用するのが好ましい。これらのうちの1種類または2種類以上を組み合わせてもよい。
本発明の調味料に用いる糖類の形態としては、粉末等の固形状のものであっても、液状のものであってもよい。ただし、本発明では糖類を固形分量としての数値で表すため、液状のものを用いる場合は固形分量を考慮して含有量を設計する必要がある点に留意が必要である。
Sugars are essential for the present invention. This is because the addition of sugars makes it difficult to coagulate and denature egg yolk during heat sterilization.
As a saccharide used in the present invention, any saccharide that can avoid coagulation / denaturation of egg yolk at the time of heat sterilization and is generally used as a food may be used.
For example, monosaccharides include glucose, fructose, mannose, galactose, xylose, ribose, arabinose and the like. Disaccharides include sucrose, maltose, lactose, cellobiose, trehalose and the like. Moreover, sugar alcohols such as sorbitol and maltitol, other hydrolysates of starch, and hydrogenated reduced starch candy can be mentioned. Among them, it is preferable to use trehalose and sugar alcohols that have a small sweetness and can suppress discoloration. Of these, one type or two or more types may be combined.
The form of the saccharide used in the seasoning of the present invention may be a solid form such as a powder or a liquid form. However, in the present invention, since the saccharide is represented by a numerical value as a solid content, it is necessary to pay attention to the fact that the content needs to be designed in consideration of the solid content when a liquid product is used.

本発明の調味料には、糖類を固形分量として該卵黄質量の50質量%以上(好ましくは60質量%以上の量)を含み、且つ甘味度換算で調味料全体の20質量%以下の量(好ましくは15質量%以下の量)で含有する。糖類の含有量が少なすぎると、加熱殺菌(例えば、65℃以上90℃未満)時に卵黄の凝固・変性を回避しにくくなり、生の卵黄本来の風味・食感を損ねてしまう。また、甘味度換算で糖類の量が多すぎると、甘みを強く感じてしまい、卵黄本来の風味を損なうことになってしまう。
ここで、糖類の含有量は固形分量としての数値であるため、固形(粉末等)の糖類の場合には糖類全体の質量が含有量となり、液状の糖類の場合はその固形分の質量分のみが含有量となる。つまり、例えば、糖類としてソルビトール70%の液を40質量%含ませる場合は、糖類(この場合はソルビトール)を固形分量として28質量%含むことになる。
また、甘味度とは甘さの指標であり、蔗糖の甘さを基準として各種糖類の甘さの強さを数値化したものである。蔗糖の甘味度は1であり、例えば、スクラロースの甘味度は600であり、ソルビトール(固形分100%)は0.6である。また、トレハロースの甘味度は0.45であり、フルクトースの甘味度は1.5であり、グルコースの甘味度は0.67である。従って、例えば、蔗糖を10質量%含有する場合は甘味度換算でも10質量%含有することになり、スクラロースを0.01質量%含有すると甘味度換算では6質量%含有することになり、ソルビトールを固形分量として10質量%含有すると甘味度換算では6質量%含有することになる。
なお、卵黄として、糖類を加えて冷凍耐性を付与した冷凍卵黄を用いるなど、原料に糖類が予め含まれている場合は、それらの糖類も含めて上記の含有量に調整すべきである。
The seasoning of the present invention contains 50% by mass or more (preferably an amount of 60% by mass or more) of the egg yolk mass as a solid content of saccharide, and an amount of 20% by mass or less of the whole seasoning in terms of sweetness ( Preferably, it is contained in an amount of 15% by mass or less. If the saccharide content is too small, coagulation / denaturation of egg yolk is difficult to avoid during heat sterilization (for example, 65 ° C. or more and less than 90 ° C.), and the original flavor / texture of raw egg yolk is impaired. Moreover, when there is too much amount of saccharides in sweetness conversion, sweetness will be felt strongly and the original flavor of egg yolk will be impaired.
Here, since the saccharide content is a numerical value as a solid content, in the case of solid (powder, etc.) saccharides, the mass of the entire saccharide is the content, and in the case of liquid saccharides, only the mass of the solid content. Is the content. That is, for example, when 40% by mass of a sorbitol 70% liquid is included as a saccharide, 28% by mass of the saccharide (in this case, sorbitol) is included as the solid content.
Sweetness is an index of sweetness, and is a numerical value of the sweetness of various sugars based on the sweetness of sucrose. The sweetness of sucrose is 1, for example, the sweetness of sucralose is 600, and sorbitol (solid content 100%) is 0.6. The sweetness of trehalose is 0.45, the sweetness of fructose is 1.5, and the sweetness of glucose is 0.67. Therefore, for example, when sucrose is contained at 10% by mass, it is also contained at 10% by mass in terms of sweetness, and when sucralose is contained at 0.01% by mass, it is contained at 6% by mass in terms of sweetness. If the solid content is 10% by mass, it is 6% by mass in terms of sweetness.
In addition, when saccharides are previously contained in raw materials, such as using frozen egg yolk added with saccharides to give freezing tolerance as egg yolk, the content should be adjusted to the above content including those saccharides.

本発明には油類は必須である。油類によって、糖類の甘みを抑制することができ、さらに生の卵黄らしいコク及び食感を付与することができるようになるからである。さらに、油類を卵黄、糖類などとともに乳化することで外観上も卵黄様とすることが可能となる。
本発明に用いる油類としては、食品として一般に使用されるものであればいずれもかまわない。例えば、植物油であれば、ナタネ油、大豆油、ごま油、こめ油、オリーブ油、コーン油、ベニバナ油、パーム油、綿実油などが挙げられる。動物油であれば、卵黄油、魚油、鯨油などが挙げられる。中でも卵黄の風味を阻害せず、常温または冷蔵下で液状を呈するために、ナタネ油、大豆油、卵黄油などを使用するのが好ましい。上記の油類を1種類または2種類以上を組み合わせてもよい。
Oils are essential for the present invention. It is because the sweetness of saccharides can be suppressed by oils, and also the richness and texture of raw egg yolk can be imparted. Furthermore, by emulsifying oils together with egg yolk, saccharides, etc., it becomes possible to make the egg yolk like in appearance.
Any oil may be used as the oil used in the present invention as long as it is generally used as a food. Examples of vegetable oils include rapeseed oil, soybean oil, sesame oil, rice oil, olive oil, corn oil, safflower oil, palm oil, cottonseed oil and the like. Examples of animal oils include egg yolk oil, fish oil and whale oil. Among them, it is preferable to use rapeseed oil, soybean oil, egg yolk oil or the like in order to exhibit a liquid state at normal temperature or under refrigeration without inhibiting the flavor of egg yolk. One or two or more of the above oils may be combined.

本発明の調味料は、油類を卵黄、糖類などとともに水中油型に乳化した液状調味料である。水中油型に乳化することにより水相と油相が分離を生じずに、風味、外観ともに卵黄本来のものに近い調味料とすることができる。乳化は疑乳化の状態であっても構わない。
本発明の調味料には、油類を10質量%以上70質量%以下の量で含有する。油類の量が少なすぎると、糖類の甘みを抑制できず、さらに卵黄らしいコク及び食感を付与することができなくなってしまう。また、油類の量が多すぎると十分に乳化できない恐れがあり風味、食感、外観において好ましくない。好ましくは油類を調味料全体の25質量%以上50質量%以下の量で含有するとよい。
The seasoning of the present invention is a liquid seasoning obtained by emulsifying oils in an oil-in-water type together with egg yolk, sugars and the like. By emulsifying in an oil-in-water type, the flavor and appearance can be made close to the original egg yolk without causing separation of the water phase and the oil phase. The emulsification may be in a pseudo emulsified state.
The seasoning of the present invention contains oils in an amount of 10% by mass to 70% by mass. If the amount of oil is too small, the sweetness of saccharides cannot be suppressed, and furthermore, the richness and texture of egg yolk cannot be imparted. Moreover, when there is too much quantity of oils, there exists a possibility that it cannot fully emulsify and it is unpreferable in flavor, food texture, and external appearance. Preferably, oils may be contained in an amount of 25% by mass or more and 50% by mass or less of the whole seasoning.

本発明の調味料には食塩を含有してもよい。食塩とは食用の塩類を意味し、一般的には塩化ナトリウムを用いることが好ましいが、塩化カリウムや塩化マグネシウムなど、他の食用塩類であっても、またはそれらが塩化ナトリウムに混合されたものであっても構わない。
食塩は防腐性を高める意味でも含有することは好ましいが、食塩の含有量を多くしすぎると塩辛さが際立ち過ぎてしまうため、比較的少量用いることが好ましい。よって、防腐性及び風味の両方の観点から、食塩の含有量としては、調味料全体の1質量%以上6質量%以下とすることが望ましく、さらには2質量%以上5質量%以下とすることが最も好ましい。
The seasoning of the present invention may contain salt. Salt means edible salts, and it is generally preferable to use sodium chloride, but other edible salts such as potassium chloride and magnesium chloride, or those mixed with sodium chloride. It does not matter.
Although it is preferable to contain sodium chloride also in the meaning which improves preservative property, since saltiness will become conspicuous if salt content is increased too much, it is preferable to use a relatively small amount. Therefore, from the viewpoint of both antiseptic properties and flavor, the salt content is preferably 1% by mass or more and 6% by mass or less, and more preferably 2% by mass or more and 5% by mass or less of the whole seasoning. Is most preferred.

本発明の調味料は、上記の糖類の固形分量及び油類を合計で35質量%以上90質量%以下含有することが必須である。
本発明の調味料は卵黄の風味とするためにpH5.5〜8.0の中性域に調整されていることから、マヨネーズ等の酸性調味料に比べて防腐性が劣る。そのため、糖類及び油類の合計量が上記量より少ないと水分活性が高くなりすぎやすく、結果として保存性が低下してしまう。具体的には、開封後に一定期間冷蔵保管をすることができないものとなってしまう。水分活性(Aw)としては、0.88以下に調整することが好ましく、さらには0.84以下に調整することが好ましい。先に卵黄の含有量について、調味料全体の5〜45質量%、好ましくは8〜30質量%、さらに好ましくは10〜20質量%含有させることを説明したが、卵黄が少なすぎると、卵黄本来の風味の乏しい調味料となってしまう。卵黄が多すぎると、相対的に糖類及び油類の量が少なくなって水分活性が高い調味料となり、特に開封後の保存性の悪い調味料となってしまう。
なお、本発明の調味料は、開封後であっても冷蔵で保管をした場合、使用環境にもよるが、おおよそ2週間から1ヶ月程度は問題なく消費できるものである。
It is essential that the seasoning of the present invention contains 35% by mass or more and 90% by mass or less of the total amount of saccharide solids and oils described above.
Since the seasoning of the present invention is adjusted to a neutral range of pH 5.5 to 8.0 in order to obtain an egg yolk flavor, the antiseptic property is inferior to acidic seasonings such as mayonnaise. Therefore, if the total amount of saccharides and oils is less than the above amount, the water activity tends to be too high, and as a result, the storage stability is lowered. Specifically, after opening, it cannot be refrigerated for a certain period. The water activity (Aw) is preferably adjusted to 0.88 or less, more preferably 0.84 or less. As for the content of egg yolk, it has been explained that the content of 5-45% by mass, preferably 8-30% by mass, more preferably 10-20% by mass of the whole seasoning, but if there is too little egg yolk, It becomes a seasoning with poor flavor. If there is too much egg yolk, the amount of sugars and oils will be relatively small, resulting in a seasoning with a high water activity, especially a seasoning with poor storage stability after opening.
Note that the seasoning of the present invention can be consumed without problems for about 2 weeks to 1 month, depending on the use environment, even if it is stored refrigerated even after opening.

本発明の調味料は液状調味料であるが、ここで言う「液状」とは固形状を排除した意味合いであり、水のようなさらさらした性状のものだけでなく、粘性のある性状、例えば一般にペースト状と呼ばれるものも含むものである。   Although the seasoning of the present invention is a liquid seasoning, the term `` liquid '' here means that the solid form is excluded, and not only a free-flowing property such as water but also a viscous property, for example, in general It also includes what is called a paste.

また、本発明の調味料は、pH5.5〜8.0(好ましくはpH6.0〜7.0)の中性領域に調整された調味料である。pH5.5を下回ると、酸味が感じられ、pH8.0を超えると苦味が感じられ、いずれも生の卵黄本来の風味が損なわれてしまう。例えば、マヨネーズなどは一般にはpHが3〜4程度であり、酸味が強く、生の卵黄本来の風味を付与するための調味料ではない。そのため、本発明の課題を解決するものではない。   Moreover, the seasoning of this invention is a seasoning adjusted to the neutral region of pH 5.5-8.0 (preferably pH 6.0-7.0). When the pH is lower than 5.5, acidity is felt, and when the pH is higher than 8.0, bitterness is felt, and the original flavor of raw egg yolk is impaired. For example, mayonnaise or the like generally has a pH of about 3 to 4, has a strong acidity, and is not a seasoning for imparting the original flavor of raw egg yolk. Therefore, the problem of the present invention is not solved.

本発明の調味料には、上記した卵黄、糖類、油類、食塩以外に、味付けや保存性向上、その他の目的のため、水、醤油、酢、酒、みりん、味噌、だし液、エキス類、香料、調味料、酸味料などを、pHが中性領域になる範囲で加えても良い。また、物性調整のため、キサンタンガムなどの増粘剤、でんぷんなどの糊料、レシチンなどの乳化剤を加えても良い。さらに、外観調整のため、カロテノイド色素、果実色素、野菜色素などの着色料を加えても良い。ただし、水分当りの卵黄比率は高い方が卵黄風味を強くできるため、卵黄、糖類、油類、食塩以外の材料はなるべく少量用いることが好ましい。例えば、卵黄、糖類、油類、食塩以外の材料は、調味料全体の30質量%以下、好ましくは20質量%以下とすることが好ましい。   In addition to the above-mentioned egg yolks, sugars, oils, and salt, the seasoning of the present invention includes water, soy sauce, vinegar, sake, mirin, miso, broth, extract, for other purposes. , Fragrances, seasonings, acidulants and the like may be added in a range where the pH is in the neutral range. In order to adjust physical properties, a thickener such as xanthan gum, a paste such as starch, and an emulsifier such as lecithin may be added. Furthermore, colorants such as carotenoid pigments, fruit pigments and vegetable pigments may be added for appearance adjustment. However, the higher the yolk ratio per moisture, the stronger the yolk flavor. Therefore, it is preferable to use materials other than egg yolk, saccharides, oils and salt as little as possible. For example, materials other than egg yolk, saccharides, oils, and salt are 30% by mass or less, preferably 20% by mass or less, based on the entire seasoning.

ここで、本調味料の殺菌について説明すると、調味料品温で65℃以上90℃未満、より好ましくは75℃以上80℃以下で殺菌することが好ましい。調味料品温が90℃以上になると卵黄の蛋白変性がおこり、生の卵黄の風味が損なわれてしまう。調味料品温が65℃より低くなると、殺菌効果が得られにくくなる。殺菌方法は、充填包装前の加温式タンクによる加熱や、チューブ式連続加熱、マイクロ波連続過熱などが用いられ、充填はホットパック充填などの方法で行う。充填密封後にボイル殺菌をしても良い。   Here, sterilization of the present seasoning will be described. It is preferable to sterilize at a seasoning product temperature of 65 ° C or higher and lower than 90 ° C, more preferably 75 ° C or higher and 80 ° C or lower. When the seasoning product temperature is 90 ° C. or higher, protein modification of the egg yolk occurs, and the flavor of the raw egg yolk is impaired. When the seasoning product temperature is lower than 65 ° C., the bactericidal effect is hardly obtained. As the sterilization method, heating by a heating tank before filling and packaging, tube-type continuous heating, microwave continuous overheating and the like are used, and filling is performed by a method such as hot pack filling. Boil sterilization may be performed after filling and sealing.

本発明の調味料は、再密封可能な密封容器に充填されているような、開封後も冷蔵保管するようなコンセプトの商品において好適に用いることができる。使い切りの商品であれば、本発明のように高い保存性は求められないからである。
再密封可能な密封容器とは、口部開閉機構などを採用することにより、一度開封しても再度密封でき、再密封後に容器を横倒しにしても漏れでにくい構造とした容器である。
ここで、密封という語は完全な密封のみを意味しない。再密封可能な密封容器としては、例えば、キャップ付きの、ビン、ペットボトル、パウチ、ラミネートチューブ、などを用いることができる。
The seasoning of the present invention can be suitably used in products having a concept of refrigerated storage even after opening, such as being filled in a resealable sealed container. This is because a product that is used up is not required to have high storage stability as in the present invention.
A re-sealable sealed container is a container having a structure that can be re-sealed even if it is opened once by adopting a mouth opening / closing mechanism or the like, and is not easily leaked even if the container is laid down after re-sealing.
Here, the term seal does not mean a complete seal only. As the resealable sealed container, for example, a bottle with a cap, a plastic bottle, a pouch, a laminated tube, or the like can be used.

実施例1(各種配合割合での物性評価)
(1)調味料の調製
表1〜5の<原料割合>の欄に示す原料を所定量用いて卵黄含有液状調味料を作成した。なお、表1〜5の<原料割合>の欄は全て質量%で表示している。
糖類は表中に記載したものを用い、固形の糖類(固形分量が100%)を使用した(ソルビトールは、粉末ソルビトールを使用)。また、だし液は、鰹と昆布でとっただしを用いた。
まず、卵黄と、水、糖類、食塩、だし液、キサンタンガム(少量ずつ添加)を混合し溶解した後、高速で撹拌しながら、油類を少しずつ添加することによって、水中油型に乳化した。
その後、一度開封した後に再度密封することが可能な容器としてのキャップ付きパウチに、それぞれ100mlずつ充填し、70℃、30分でボイル殺菌(ただし、調味料22〜24は90℃、30分の殺菌とした。)をして、調味料1〜24を製造した。
Example 1 (physical property evaluation at various blending ratios)
(1) Preparation of seasonings Egg yolk-containing liquid seasonings were prepared using predetermined amounts of the raw materials shown in the <Raw material ratio> column of Tables 1-5. In addition, the columns of <Raw material ratio> in Tables 1 to 5 are all expressed in mass%.
As the saccharides, those described in the table were used, and solid saccharides (solid content was 100%) were used (sodium sorbitol was powder sorbitol). In addition, the dashi solution used was a bonito and a kelp.
First, egg yolk was mixed with water, sugar, salt, soup stock, xanthan gum (added in small portions) and dissolved, and then oils were added little by little while stirring at high speed to emulsify into an oil-in-water type.
Then, 100ml each is filled into cap pouches that can be sealed again after being opened once, and boil sterilized at 70 ° C for 30 minutes (however, seasonings 22-24 are 90 ° C for 30 minutes) And seasonings 1 to 24 were produced.

なお、各調味料の水分活性及びpHは、製造後の調味料サンプルを開封し、水分活性は、Novasina 社TH500型を用いて、pHはガラス電極式pHメーターは、(株)堀場製作所、pHメーターF−13を用いて、それぞれ測定した。測定した値を表1〜5の<製造された調味料のpHと水分活性>の欄に示した。   The water activity and pH of each seasoning were determined by opening the seasoning sample after production. The water activity was measured using a Novasina TH500 model. The pH was measured by a glass electrode type pH meter. Each was measured using a meter F-13. The measured values are shown in the column of <pH and water activity of manufactured seasonings> in Tables 1 to 5.

(2)調味料の評価
上記(1)で製造した調味料サンプル1〜24について、風味、物性、保存性を以下の要領で評価し、結果は表1〜5の<製造された調味料の評価>の欄に記載した。
(2) Evaluation of seasoning About the seasoning samples 1-24 manufactured by said (1), a flavor, a physical property, and preservability were evaluated in the following ways, and a result is < It described in the column of Evaluation>.

ここで、「風味」については、製造直後のサンプルを、熟練の官能検査員にて、「卵黄の味」、「甘味」、「油脂感」について評価し、それぞれ以下の評点を付した。
<卵黄の味>
・卵黄特有の風味がし、卵黄代替調味料として十分なレベル:○
・卵黄特有の風味は薄いが、卵黄代替調味料としては許容できるレベル:△
・卵黄特有の風味が不十分であり、卵黄代替調味料としては使えないレベル:×
<甘味>
・甘味は弱いか感じられないため、卵黄代替調味料として適した甘味である:○
・若干の甘味は感じるが、卵黄代替調味料として許容できる甘味である:△
・卵黄代替調味料としては適さない甘味を感じる:×
<油脂感>
・油脂特有の風味は弱く、卵黄代替調味料の油脂感として適している:○
・若干の油脂特有の風味は感じるが、卵黄代替調味料として許容できる油脂感である:△
・卵黄代替調味料としては適さない油脂特有の風味を感じる:×
Here, with regard to “flavor”, samples immediately after production were evaluated for “egg yolk taste”, “sweetness”, and “greasy feeling” by skilled sensory inspectors, and the following scores were assigned respectively.
<Taste of egg yolk>
・ It has an egg yolk-specific flavor and is a sufficient level as an egg yolk substitute seasoning: ○
・ Although the egg yolk has a light flavor, it is acceptable as an egg yolk alternative seasoning: △
・ Insufficient egg yolk flavor and cannot be used as an egg yolk substitute seasoning: ×
<Sweetness>
・ Since the sweetness is weak or unseen, it is suitable as an egg yolk alternative seasoning: ○
・ Slight sweetness, but acceptable sweetness as an egg yolk alternative seasoning: △
・ We feel sweetness that is not suitable as egg yolk substitute seasoning: X
<Fatiness>
・ Facilities unique to fats and oils are weak and suitable as an oily feeling for egg yolk alternative seasonings: ○
・ Although a slight flavor unique to fats and oils is felt, the fat and oil feel is acceptable as an egg yolk alternative seasoning: △
・ I feel the unique flavor of fats and oils that are not suitable as an egg yolk substitute seasoning: ×

「物性」については、製造直後のサンプルを、熟練の官能検査員にて、「卵黄の変性」、「乳化程度」について評価し、それぞれ以下の評点を付した。
<卵黄の変性>
・卵黄の変性が起きておらず、卵黄特有の滑らかな食感が感じられる:○
・卵黄の変性が起きてしまっており、卵黄特有の食感が感じられずにざらつきを感じる:×
<乳化程度>
・油分が十分に乳化されており、卵黄代替調味料として外観上、食感上ともに優れている:○
・油分が十分に乳化されておらず、卵黄代替調味料として外観上または食感上において好ましくない:×
Regarding “physical properties”, samples immediately after production were evaluated for “degeneration of egg yolk” and “degree of emulsification” by a skilled sensory inspector, and the following scores were assigned respectively.
<Degeneration of egg yolk>
・ No egg yolk degeneration has occurred and a smooth texture unique to egg yolk is felt: ○
・ Degeneration of egg yolk has occurred, and the texture specific to egg yolk is not felt.
<Emulsification degree>
・ Emulsions are sufficiently emulsified, and it is excellent in appearance and texture as an egg yolk alternative seasoning: ○
-Oil is not sufficiently emulsified, and is not preferable in terms of appearance or texture as an egg yolk substitute seasoning: ×

「保存性」については、製造直後のサンプルを常温で1ヶ月保管した後に容器を開封して少量サンプルを採取し、さらにそのサンプルを再密封して冷蔵(5℃)で1ヶ月間保管した後に少量サンプルを採取した。それぞれサンプル採取後すぐに一般性菌数・真菌数を調べた。
評価は、一般性菌数・真菌数がともに10/g未満の場合を○とし、10/g以上の場合を×とした。
また、備考として、特記事項を記載した。
Regarding “preservability”, a sample immediately after production is stored at room temperature for 1 month, then the container is opened, a small sample is taken, and the sample is resealed and stored in a refrigerator (5 ° C.) for 1 month. A small sample was taken. Immediately after collecting each sample, the number of general bacteria and fungi was examined.
The rating is the case of the number of general bacteria, fungi fewer than both 10 5 / g as ○, and as × when more than 10 5 / g.
In addition, special notes are described as remarks.

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(3)考察
上記(2)の結果から以下のことがわかった。
風味(卵黄の味)の比較から、卵黄は調味料全体の5質量%未満(調味料1)では卵黄の味が弱く、5質量%以上含有している(調味料2など)ことが必要であることがわかった。好ましくは8質量%以上(調味料3など)、さらには10質量%以上(調味料4、5など)が好ましいことがわかった。
(3) Discussion The following was found from the result of (2) above.
From the comparison of flavor (egg yolk taste), the yolk is less than 5% by mass of the whole seasoning (condiment 1), and the yolk taste is weak, and it is necessary to contain 5% by mass or more (such as seasoning 2). I found out. It turned out that 8 mass% or more (seasoning 3 etc.) is preferable, and 10 mass% or more (seasoning 4, 5, etc.) is preferable.

保存性(未開封、常温保管後)の評価結果から、糖類及び油類の合計が調味料全体の35質量%に満たないと(調味料7〜10)、開封後の保存性が悪いことがわかった。一方、糖類及び油類の合計が調味料全体の35質量%以上になると(調味料6など)、保存性が良いことがわかった。   From the evaluation results of storage stability (unopened, after storage at room temperature), if the total of sugars and oils does not reach 35% by mass of the entire seasoning (seasoning 7 to 10), the storage stability after opening may be poor. all right. On the other hand, when the sum total of saccharides and oils became 35 mass% or more of the whole seasoning (seasoning 6 etc.), it turned out that preservability is good.

風味(甘味)の評価結果から、油類の量が大きく影響することがわかり、油類が調味料全体の10質量%に満たないと(調味料7、8、10)、甘味を制御することができないことがわかった。つまり、油類は調味料全体の10質量%以上含有(調味料6、9など)すれば糖類の甘味を抑制する効果があり、さらには25質量%以上含有すること(調味料5など)が好ましいことがわかった。   From the evaluation result of flavor (sweetness), it is understood that the amount of oil greatly affects, and if the oil does not reach 10% by mass of the whole seasoning (seasoning 7, 8, 10), the sweetness should be controlled. I knew that I couldn't. That is, if the oils are contained in an amount of 10% by mass or more of the whole seasoning (seasoning 6, 9, etc.), the effect of suppressing the sweetness of the saccharide is obtained. It turned out to be preferable.

また、甘味度換算で調味料全体の20質量%を超えて糖類を含有すると(調味料20)、卵黄代替調味料として好ましくないため、甘味度換算で20質量%以下(調味料19、21、24など)が好ましいことがわかった。さらには、甘味度換算で15質量%以下(調味料22など)がより好ましいことがわかった。   Moreover, since it is not preferable as an egg yolk substitute seasoning when sugar is contained exceeding 20 mass% of the whole seasoning in terms of sweetness (condiment 20), it is not more than 20 mass% in terms of sweetness (condiments 19, 21, 24) was found to be preferable. Furthermore, it turned out that 15 mass% or less (seasoning 22 etc.) is more preferable in sweetness conversion.

物性(乳化程度)及び風味(油脂感)の評価結果から、油類が70質量%を超えると(調味料12)、油脂感が強くなり風味上好ましくなく、また乳化状態が不安定となることから、70質量%以下(調味料11、13、14など)とすることが必要であり、好ましくは50質量%以下(調味料15など)がよいことがわかった。   From the evaluation results of physical properties (emulsification degree) and flavor (feeling of oils and fats), when the oil content exceeds 70% by mass (seasoning 12), the oily feeling becomes strong and unfavorable in flavor, and the emulsified state becomes unstable. Therefore, it was necessary to set it to 70% by mass or less (seasoning 11, 13, 14 or the like), and preferably 50% by mass or less (seasoning 15 or the like) was good.

物性(卵黄の変性)の評価結果から、糖類が卵黄質量の50質量%に満たないと(調味料8、13、15、17)卵黄の変性が起きてしまうため、少なくとも糖類は卵黄質量の50質量%以上(調味料9、14など)は必要であることがわかった。
ここで、調味料17を見ると、糖類は、甘味度換算では卵黄質量の60質量%であるが、糖類量として卵黄質量の40質量%であるため、卵黄変性を抑制できていないことがわかる。つまり、卵黄変性を抑制する効果は甘味度が影響しているのではなく、糖類の含有量が影響することもわかった。
From the evaluation results of the physical properties (denaturation of egg yolk), if the saccharide is less than 50% by mass of the yolk mass (seasoning 8, 13, 15, 17), the yolk denaturation occurs, so at least the saccharide is 50 of the yolk mass. It turned out that the mass% or more (condiments 9, 14, etc.) is required.
Here, when the seasoning 17 is seen, although sugar is 60 mass% of egg yolk mass in sweetness conversion, since it is 40 mass% of egg yolk mass as saccharide amount, it turns out that egg yolk degeneration cannot be suppressed. . That is, the effect of suppressing egg yolk degeneration was not affected by the sweetness level, but also by the saccharide content.

また、90℃殺菌をすると(調味料22〜24)、未開封時の保存性は満たされるが、卵黄変性が起きてしまうため好ましくないことがわかった。   In addition, when sterilized at 90 ° C. (seasoning 22 to 24), the storage stability when unopened is satisfied, but egg yolk degeneration occurs, which is not preferable.

本発明によれば、納豆、山芋、うどん、そば、ラーメンなどを食する際に、卵黄の代替品として手軽に用いることができ、且つ比較的保存性のよい(日持ちのする)今までにない調味料を提供することができる。
ここで、保存性について詳しくは、開封後であっても冷蔵で保管をした場合、使用環境にもよるが、おおよそ2週間から1ヶ月程度は問題なく消費できるものである。
According to the present invention, when eating natto, yam, udon, buckwheat, ramen, etc., it can be easily used as a substitute for egg yolk and has a relatively good storage stability (long-lasting). Seasoning can be provided.
Here, for details of the storage stability, even after opening, when stored in a refrigerator, depending on the use environment, approximately 2 weeks to 1 month can be consumed without any problem.

Claims (5)

卵黄を含有する液状調味料において、卵黄を調味料全体の5質量%以上45質量%未満、糖類の固形分量及び油類の合計で調味料全体の35質量%以上90質量%以下含有し、該糖類は固形分量として該卵黄質量の50質量%以上を含み、且つ甘味度換算で調味料全体の20質量%以下の量で含有しており、該油類は調味料全体の10質量%以上70質量%以下の量で含有している調味料であって、水中油型に乳化され、pH5.5〜8.0に調整されていることを特徴とする卵黄含有液状調味料。   In the liquid seasoning containing egg yolk, the egg yolk is contained in an amount of 5% by mass to less than 45% by mass of the whole seasoning, 35% by mass to 90% by mass of the whole seasoning in total of the solid content of sugar and oils, The saccharide contains 50% by mass or more of the egg yolk mass as a solid content, and is contained in an amount of 20% by mass or less of the whole seasoning in terms of sweetness, and the oils are 10% by mass or more and 70% by mass of the whole seasoning. An egg yolk-containing liquid seasoning which is contained in an amount of mass% or less and is emulsified in an oil-in-water type and adjusted to pH 5.5 to 8.0. 水分活性が0.88以下に調整されていることを特徴とする請求項1に記載の卵黄含有液状調味料。   The egg yolk-containing liquid seasoning according to claim 1, wherein the water activity is adjusted to 0.88 or less. 90℃以上の高温殺菌による卵黄変性がされていないことを特徴とする請求項1〜2のいずれか1項に記載の卵黄含有液状調味料。   The egg yolk-containing liquid seasoning according to any one of claims 1 to 2, wherein the egg yolk is not denatured by high-temperature sterilization at 90 ° C or higher. 食塩を調味料全体の1質量%以上6質量%以下の量で含有していることを特徴とする請求項1〜3のいずれか1項に記載の卵黄含有液状調味料。   The egg yolk-containing liquid seasoning according to any one of claims 1 to 3, wherein the salt is contained in an amount of 1% by mass or more and 6% by mass or less of the whole seasoning. 再密封可能な密封容器に充填されたことを特徴とする請求項1〜4のいずれか1項に記載の卵黄含有液状調味料。   The egg yolk-containing liquid seasoning according to any one of claims 1 to 4, which is filled in a resealable sealed container.
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JP2012090542A (en) * 2010-10-25 2012-05-17 Q P Corp Egg salad
JP2012105602A (en) * 2010-11-18 2012-06-07 House Foods Corp Method for producing yolk-containing composition, and method for producing sauce
JP2013000095A (en) * 2011-06-21 2013-01-07 Q P Corp Emulsified seasoning liquid
CN103005386A (en) * 2012-12-31 2013-04-03 徐州康来健食品有限公司 Preparation method of Chinese yam jam
JP2016077167A (en) * 2014-10-10 2016-05-16 キユーピー株式会社 Oil-in-water type emulsified sauce
JP2016185086A (en) * 2015-03-27 2016-10-27 キユーピー株式会社 Egg yolk sauce for instant food, instant food with addition of egg yolk sauce, and method for changing taste of instant food using egg yolk sauce
JP2020005625A (en) * 2018-06-29 2020-01-16 キユーピー株式会社 Emulsified foods in plastic container
WO2024048557A1 (en) * 2022-08-30 2024-03-07 池田食研株式会社 Oil-in-water-type emulsified seasoning

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JP2012090542A (en) * 2010-10-25 2012-05-17 Q P Corp Egg salad
JP2012105602A (en) * 2010-11-18 2012-06-07 House Foods Corp Method for producing yolk-containing composition, and method for producing sauce
JP2013000095A (en) * 2011-06-21 2013-01-07 Q P Corp Emulsified seasoning liquid
CN103005386A (en) * 2012-12-31 2013-04-03 徐州康来健食品有限公司 Preparation method of Chinese yam jam
JP2016077167A (en) * 2014-10-10 2016-05-16 キユーピー株式会社 Oil-in-water type emulsified sauce
JP2016185086A (en) * 2015-03-27 2016-10-27 キユーピー株式会社 Egg yolk sauce for instant food, instant food with addition of egg yolk sauce, and method for changing taste of instant food using egg yolk sauce
JP2020005625A (en) * 2018-06-29 2020-01-16 キユーピー株式会社 Emulsified foods in plastic container
WO2024048557A1 (en) * 2022-08-30 2024-03-07 池田食研株式会社 Oil-in-water-type emulsified seasoning

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