JP2010207848A - Long nozzle and method of manufacturing the same - Google Patents

Long nozzle and method of manufacturing the same Download PDF

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JP2010207848A
JP2010207848A JP2009056059A JP2009056059A JP2010207848A JP 2010207848 A JP2010207848 A JP 2010207848A JP 2009056059 A JP2009056059 A JP 2009056059A JP 2009056059 A JP2009056059 A JP 2009056059A JP 2010207848 A JP2010207848 A JP 2010207848A
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nozzle
refractory ring
mortar
outer periphery
ring
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JP5164893B2 (en
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Takeshi Okawa
武士 大川
Seiichi Takahashi
誠一 高橋
Shinichi Fukunaga
新一 福永
Tomotama Yamauchi
智玲 山内
Kazuhisa Katsuki
和久 香月
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Akechi Ceramics Co Ltd
Nippon Steel Corp
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Akechi Ceramics Co Ltd
Nippon Steel Corp
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Abstract

<P>PROBLEM TO BE SOLVED: To provide a long nozzle capable of preventing occurrence of cracks of the nozzle body caused by thermal expansion of a refractory ring mounted on the upper part of a bore face, and to provide a method of manufacturing the same. <P>SOLUTION: The long nozzle 1 is the one which has an outer periphery covered with a shell 12 and which is designed to pour molten metal of a ladle into a tundish. On the upper part 3 of the nozzle bore 2, a fitting part 10 is formed for fitting the refractory ring 4, wherein the refractory ring 4 has a fibrous heat insulation material 5 stretched over the outer periphery and is fitted to the fitting part 10 via mortar 11 arranged on the upper part 3 of the nozzle bore 2. As a result, the thermal expansion margin in the radial direction of the highly corrosion resistant refractory ring 4 can be absorbed by the fibrous heat insulation material 5 which is stretched over the outer periphery of the refractory ring 4. Also, the thermal expansion of the refractory ring 4 is suppressed by fixation with the mortar 11, which prevents the occurrence of cracks of the nozzle body 6. <P>COPYRIGHT: (C)2010,JPO&INPIT

Description

本発明は、取鍋内の金属溶湯をタンディッシュに注入するロングノズルおよびその製造方法に関するものである。   The present invention relates to a long nozzle for pouring molten metal in a ladle into a tundish and a method for manufacturing the same.

鋼等の連続鋳造において、取鍋底部に配設されたスライディングノズルの開度等により、下ノズルからロングノズルに流出する金属溶湯は乱れ不均一な流れとなる。特に溶鋼注入初期にこのような不均一な流れが生じるため、ロングノズルの内孔面の上部は溶鋼の不均一な接触を受け、部分的に浸食(孔明き)され、シール不良や耐火物の溶損からくるカーボンピックアップの原因となっている。   In continuous casting of steel or the like, the molten metal flowing out from the lower nozzle to the long nozzle becomes a turbulent and non-uniform flow due to the opening degree of the sliding nozzle disposed at the bottom of the ladle. In particular, since this uneven flow occurs at the beginning of molten steel injection, the upper part of the inner surface of the long nozzle is subjected to uneven contact with the molten steel and is partially eroded (perforated), resulting in poor sealing and refractory. It is a cause of carbon pickup coming from melting.

この問題を解決するために、ロングノズルの内孔面の上部に耐食性の高い耐火物リング(特開2008−194745号公報における図1のキャップ8)をモルタルを介して装着することが行われている。   In order to solve this problem, a refractory ring having high corrosion resistance (cap 8 in FIG. 1 in Japanese Patent Laid-Open No. 2008-194745) is attached to the upper part of the inner hole surface of the long nozzle through a mortar. Yes.

しかし、この耐食性の高い耐火物リングは、一般的に、外周に存在するノズル本体の材質の2倍以上の熱膨張率を有するため、耐火物リングをモルタルを用いてノズル本体に装着した場合、モルタル代だけでは耐火物リングの熱膨張代を吸収できず、外周に存在するノズル本体に亀裂を発生させてしまうことがあった。また、ノズル本体の上部付近には補強のため鉄皮を被覆するが、この鉄皮がノズル本体を高温化させ、耐火物リングの熱膨張を促進させノズル本体の亀裂を誘発させてしまうことがあった。   However, this refractory ring with high corrosion resistance generally has a thermal expansion coefficient more than twice that of the material of the nozzle body present on the outer periphery, so when the refractory ring is attached to the nozzle body using mortar, The mortar cost alone cannot absorb the thermal expansion allowance of the refractory ring, and may cause cracks in the nozzle body existing on the outer periphery. In addition, the upper part of the nozzle body is covered with an iron skin for reinforcement, but this iron skin heats up the nozzle body and promotes the thermal expansion of the refractory ring and may induce cracks in the nozzle body. there were.

特開2008−194745号公報JP 2008-194745 A

本発明は、上記問題点を解決するためになされたものであり、すなわち、本発明の課題は、内孔面の上部に装着された耐火物リングの熱膨張によるノズル本体の亀裂発生を防止することができるロングノズルおよびその製造方法を提供することにある。   The present invention has been made to solve the above-described problems. That is, the object of the present invention is to prevent the occurrence of cracks in the nozzle body due to thermal expansion of a refractory ring attached to the upper portion of the inner hole surface. It is an object of the present invention to provide a long nozzle and a method for manufacturing the same.

上記課題を解決するものは、外周が鉄皮にて被覆され取鍋内の金属溶湯をタンディシュに注入するロングノズルであって、ノズル内孔の上部には耐火物リングを嵌装するための嵌装部が形成され、前記耐火物リングは外周にファイバー性断熱材が張設されると共に、前記ノズル内孔の上部に配されたモルタルを介して前記嵌装部に嵌装されていることを特徴とするロングノズルである。   What solves the above-mentioned problem is a long nozzle whose outer periphery is covered with an iron skin and injects a molten metal in a ladle into a tundish, and a fitting for fitting a refractory ring in the upper part of the nozzle bore. The refractory ring is fitted with the fitting part through a mortar disposed at the upper part of the nozzle inner hole, and the refractory ring is stretched with a fiber heat insulating material on the outer periphery. It is a long nozzle.

前記耐火物リングの外側面は下方に向かって径が小さくなるテーパー面に形成され、前記嵌装部の内側面と前記耐火物リングの外側面との間隙には、前記ノズル内孔の上部と前記耐火物リングとを接合するためのモルタルが侵入可能に構成されていることが好ましい。   The outer surface of the refractory ring is formed into a tapered surface whose diameter decreases downward, and the gap between the inner surface of the fitting portion and the outer surface of the refractory ring is an upper portion of the nozzle inner hole. It is preferable that a mortar for joining the refractory ring is configured to be able to enter.

また、上記課題を解決するものは、外周が鉄皮にて被覆され取鍋内の金属溶湯をタンディシュに注入するロングノズルの製造方法であって、ノズル内孔の上部に嵌装される耐火物リングの外周にファイバー性断熱材を張設した後、前記耐火物リングを前記ノズル内孔の上部にモルタルを介して嵌装する工程を有したことを特徴とするロングノズルの製造方法である。   Moreover, what solves the said subject is the manufacturing method of the long nozzle which the outer periphery is coat | covered with the iron shell, and injects the molten metal in a ladle into a tundish, Comprising: The refractory material fitted by the upper part of a nozzle inner hole A long nozzle manufacturing method comprising a step of fitting a refractory ring to an upper portion of the nozzle inner hole through a mortar after a fiber heat insulating material is stretched around the outer periphery of the ring.

請求項1に記載したロングノズルによれば、内孔面の上部に装着された耐火物リングの熱膨張によるノズル本体の亀裂発生を防止することができる。
請求項2に記載したロングノズルによれば、上記請求項1の効果に加え、ファイバー性断熱材の外側面と嵌装部との間に間隙が形成され、この間隙にモルタルが侵入することでシール性をより高めることができる。
請求項3に記載したロングノズルの製造方法によれば、内孔面の上部に装着された耐火物リングの熱膨張によるノズル本体の亀裂発生を防止することができると共に、耐火物リングとノズル本体とのシール性を保つことができるため、安定して高品質の鋼を長時間鋳造可能なロングノズルを製作できる。
According to the long nozzle described in claim 1, it is possible to prevent the nozzle body from cracking due to the thermal expansion of the refractory ring mounted on the upper portion of the inner hole surface.
According to the long nozzle described in claim 2, in addition to the effect of claim 1, a gap is formed between the outer surface of the fiber heat insulating material and the fitting portion, and the mortar penetrates into the gap. The sealing performance can be further increased.
According to the method for manufacturing a long nozzle according to claim 3, it is possible to prevent cracking of the nozzle body due to thermal expansion of the refractory ring mounted on the upper portion of the inner hole surface, and to prevent the refractory ring and the nozzle body. Therefore, it is possible to manufacture a long nozzle that can stably cast high-quality steel for a long time.

本発明の一実施例のロングノズルの上部付近の縦断面図である。It is a longitudinal cross-sectional view of the upper part vicinity of the long nozzle of one Example of this invention. 本発明のロングノズルの製造方法を説明するための説明図である。It is explanatory drawing for demonstrating the manufacturing method of the long nozzle of this invention.

本発明は、耐食性の高い耐火物リングの径方向への熱膨張代を、耐火物リングの外周に張設されたファイバー性断熱材で吸収させることができると共に、モルタル11による固定で耐火物リングの熱膨張を抑制し、ノズル本体6の亀裂発生を防止することができるロングノズルを実現した。   In the present invention, the thermal expansion allowance in the radial direction of the refractory ring having high corrosion resistance can be absorbed by the fiber heat insulating material stretched on the outer periphery of the refractory ring, and the refractory ring is fixed by the mortar 11. A long nozzle that can suppress the thermal expansion of the nozzle body 6 and prevent the nozzle body 6 from cracking has been realized.

本発明のロングノズルを図1に示した一実施例を用いて説明する。
ロングノズル1は外周が鉄皮12にて被覆され取鍋内の金属溶湯をタンディシュに注入するロングノズルであって、ノズル内孔2の上部3には耐火物リング4を嵌装するための嵌装部10が形成され、耐火物リング4は外周にファイバー性断熱材5が張設されると共に、ノズル内孔2の上部3に配されたモルタル11を介して嵌装部10に嵌装されている。以下、各構成について順次詳述する。
A long nozzle according to the present invention will be described with reference to an embodiment shown in FIG.
The long nozzle 1 is a long nozzle whose outer periphery is covered with a steel shell 12 and injects the molten metal in the ladle into the tundish, and is fitted in the upper part 3 of the nozzle inner hole 2 for fitting the refractory ring 4. The refractory ring 4 is formed with a fiber heat insulating material 5 stretched on the outer periphery, and is fitted into the fitting portion 10 via a mortar 11 disposed in the upper portion 3 of the nozzle inner hole 2. ing. Hereinafter, each configuration will be described in detail.

ロングノズル1は、上部付近を取鍋の溶鋼排出口に設けられた下ノズルに気密に接続し、下部付近(図示しない)をタンディッシュ内に挿入して使用するものである。ノズル本体6内には軸方向にノズル内孔2が貫通しており、ノズル本体6の上部は耐酸化性耐火材質からなる上端開孔部7が一体成形され構成されている。上端開孔8はノズル内孔2の孔径より大きく形成されており、ノズル内孔2には、流下する金属溶湯と接触する内側に耐火物層を内張りした内孔体9が形成されている。   The long nozzle 1 is used in such a manner that the upper part is hermetically connected to the lower nozzle provided at the molten steel discharge port of the ladle and the lower part (not shown) is inserted into the tundish. A nozzle inner hole 2 passes through the nozzle body 6 in the axial direction, and an upper end opening portion 7 made of an oxidation-resistant fire-resistant material is integrally formed at the upper portion of the nozzle body 6. The upper end opening 8 is formed larger than the diameter of the nozzle inner hole 2, and the nozzle inner hole 2 is formed with an inner hole body 9 in which a refractory layer is lined inside in contact with the molten metal flowing down.

上端開孔部7には、嵌装部10が上端開孔8に連続して形成されており、この嵌装部10には着脱可能な耐火物リング(平面視円筒形)4が嵌装されている。耐火物リング4の下面はモルタル11を介して内孔体9の上端面に接合され当接している。耐火物リング4は下面がこのモルタル11に固定されることにより膨張が抑制されている。なお、図面においてはモルタル11によるシール部位を明確にするために、モルタル11を現実より厚く描いている。さらに、ロングノズル1の外周は鉄皮12にて被覆されている。   A fitting portion 10 is formed in the upper end opening portion 7 continuously to the upper end opening 8, and a removable refractory ring (planar cylindrical shape) 4 is fitted in the fitting portion 10. ing. The lower surface of the refractory ring 4 is joined and abutted to the upper end surface of the inner hole body 9 through the mortar 11. Expansion of the refractory ring 4 is suppressed by fixing the lower surface to the mortar 11. In the drawing, the mortar 11 is drawn thicker than the actual thickness in order to clarify the sealing portion by the mortar 11. Further, the outer periphery of the long nozzle 1 is covered with an iron skin 12.

耐火物リング4は、内孔体9と同一材質により形成されており、耐火物リング4の外周(外周側面または外側面)にはファイバー性断熱材5が張設されている。耐火物リング4の外側面は、下方に向かって径が小さくなるテーパー面となっており、耐火物リング4は嵌装部10内に嵌着されている。耐火物リング4の外側面を下方に向かって径が小さくなるテーパー面とすることにより、耐火物リング4が嵌装部10内に嵌着し易くなり、かつ緊密に嵌着することができる。さらに、ファイバー性断熱材5の外側面と嵌装部10との間に間隙が形成されるため、モルタル11がこの間隙に侵入してシール性をより高めることができる。   The refractory ring 4 is formed of the same material as the inner hole body 9, and a fiber heat insulating material 5 is stretched on the outer periphery (outer peripheral side surface or outer side surface) of the refractory ring 4. The outer surface of the refractory ring 4 is a tapered surface whose diameter decreases downward, and the refractory ring 4 is fitted in the fitting portion 10. By making the outer surface of the refractory ring 4 a tapered surface whose diameter decreases downward, the refractory ring 4 can be easily fitted into the fitting portion 10 and can be tightly fitted. Furthermore, since a gap is formed between the outer surface of the fibrous heat insulating material 5 and the fitting portion 10, the mortar 11 can enter the gap to further improve the sealing performance.

このように、本発明のロングノズル1は、耐火物リング4の外周にファイバー性断熱材5が巻回され張設されているため、耐火物リング4の径方向への熱膨張代を耐火物リングの外周に張設されたファイバー性断熱材5にて吸収させることができる。より具体的には、耐火物リング4が半径方向に熱膨張すると、ファイバー性断熱材5が厚み方向に収縮するため、ノズル本体6(この実施例では上端開孔部7)を内側から押圧することがなく、耐火物リングの熱膨張によるノズル本体の亀裂発生を防止することができる。   As described above, the long nozzle 1 of the present invention has the thermal expansion allowance in the radial direction of the refractory ring 4 since the fibrous heat insulating material 5 is wound around the outer periphery of the refractory ring 4 and stretched. It can be absorbed by the fiber heat insulating material 5 stretched around the outer periphery of the ring. More specifically, when the refractory ring 4 is thermally expanded in the radial direction, the fibrous heat insulating material 5 is contracted in the thickness direction, so that the nozzle body 6 (the upper end opening portion 7 in this embodiment) is pressed from the inside. No cracking of the nozzle body due to thermal expansion of the refractory ring can be prevented.

ファイバー性断熱材としては、必要な耐熱性を有する繊維材料であればどのようなものでもよいが、例えばアルミナ・シリカセラミックスシートなどが好適に使用できる。   As the fiber heat insulating material, any fiber material having necessary heat resistance may be used. For example, an alumina / silica ceramic sheet can be preferably used.

ファイバー性断熱材の収縮率としては、モルタル代1mmで耐火物リングを装着した場合、50〜90%程度であることが好ましい。50%未満であると、耐火物リングの径方向への膨張代を吸収できない可能性があり、90%を越えると、ファイバー性断熱材の取り扱い上難点が生じるからである。また、ファイバー性断熱材の厚みとしては、モルタル代1mmで耐火物リングを装着した場合、0.5〜2mm程度が好ましい。すなわち、モルタル代とファイバー性断熱材の厚みの比(モルタル代/ファイバー性断熱材の厚み)は、0.5〜2程度が好ましい。   The shrinkage rate of the fibrous heat insulating material is preferably about 50 to 90% when a refractory ring is attached with a mortar cost of 1 mm. If it is less than 50%, the expansion allowance in the radial direction of the refractory ring may not be absorbed, and if it exceeds 90%, it will be difficult to handle the fiber heat insulating material. Moreover, as a thickness of a fiber heat insulating material, when a refractory ring is mounted | worn with the mortar cost 1mm, about 0.5-2 mm is preferable. That is, the ratio of the mortar allowance to the thickness of the fiber heat insulating material (mortar allowance / fiber heat insulating material thickness) is preferably about 0.5 to 2.

つぎに、本発明のロングノズルの製造方法について図2を用いて説明する。
本発明のロングノズル1の製造方法は、ノズル内孔2の上部3に嵌装される耐火物リング4の外周にファイバー性断熱材5を張設した後、耐火物リング4をノズル内孔2の上部3にモルタル11を介して嵌装する工程を有したものであり、耐火物リング4の嵌着工程に特徴を有するものである。なお、ロングノズル1の各構成については前述した通りであり説明を省略する。
Next, the manufacturing method of the long nozzle of the present invention will be described with reference to FIG.
In the manufacturing method of the long nozzle 1 of the present invention, the fiber heat insulating material 5 is stretched around the outer periphery of the refractory ring 4 fitted to the upper portion 3 of the nozzle inner hole 2, and then the refractory ring 4 is attached to the nozzle inner hole 2. The upper part 3 of the refractory ring 4 has a process of fitting through the mortar 11 and is characterized by the process of fitting the refractory ring 4. In addition, about each structure of the long nozzle 1, it is as above-mentioned, and description is abbreviate | omitted.

具体的には、本発明のロングノズルの製造方法において、図2の(a)に示した耐火物リング4をノズル内孔2の上部3に嵌装させる場合、まず、図2の(b)に示したように耐火物リング4の外周にファイバー性断熱材5を張設する。そして、図2の(c)に示したように、ノズル内孔2の上端面にモルタル11を塗布した後、図2の(b)に示した、外周にファイバー性断熱材5を張設した耐火物リング4を、ノズル内孔2の上部3に嵌着させる(図1の状態)。耐火物リング4の外側面は下方に向かって径が小さくなるテーパー面に形成されているため、ファイバー性断熱材5の外側面と嵌装部10との間には間隙が形成され、この間隙にモルタル11が侵入することでシール性がより高くなる。なお、この実施例では、ノズル内孔2の上端面にモルタル11を塗布したが、耐火物リング4の下端面にモルタル11を塗布したものも本発明の範疇に包含される。   Specifically, in the method for manufacturing a long nozzle of the present invention, when the refractory ring 4 shown in FIG. 2A is fitted into the upper portion 3 of the nozzle inner hole 2, first, FIG. As shown in Fig. 5, a fiber heat insulating material 5 is stretched around the outer periphery of the refractory ring 4. Then, as shown in FIG. 2C, after applying the mortar 11 to the upper end surface of the nozzle inner hole 2, the fiber heat insulating material 5 was stretched around the outer periphery shown in FIG. The refractory ring 4 is fitted into the upper portion 3 of the nozzle inner hole 2 (state shown in FIG. 1). Since the outer surface of the refractory ring 4 is formed into a tapered surface whose diameter decreases downward, a gap is formed between the outer surface of the fiber heat insulating material 5 and the fitting portion 10. When the mortar 11 penetrates into the sealant, the sealing performance becomes higher. In this embodiment, the mortar 11 is applied to the upper end surface of the nozzle inner hole 2, but the mortar 11 applied to the lower end surface of the refractory ring 4 is also included in the scope of the present invention.

このように、本発明の製造方法にて製作されたロングノズルは、耐火物リングの径方向への熱膨張代を耐火物リングの外周に張設されたファイバー性断熱材で吸収させることができると共に、モルタル11による固定で耐火物リング4の熱膨張が抑制されるため、耐火物リングの熱膨張によるノズル本体の亀裂発生を防止することができる。また、モルタルにより耐火物リングの下端面とノズル内孔上端面とのシール性が保持されているため、安定して高品質の鋼を長時間鋳造できる。   Thus, the long nozzle manufactured by the manufacturing method of the present invention can absorb the thermal expansion allowance in the radial direction of the refractory ring with the fiber heat insulating material stretched around the outer periphery of the refractory ring. At the same time, since the thermal expansion of the refractory ring 4 is suppressed by fixing with the mortar 11, it is possible to prevent the nozzle body from cracking due to the thermal expansion of the refractory ring. Moreover, since the sealing performance between the lower end surface of the refractory ring and the upper end surface of the nozzle inner hole is maintained by the mortar, high quality steel can be stably cast for a long time.

1 ロングノズル
2 ノズル内孔
3 ノズル内孔の上部
4 耐火物リング
5 ファイバー性断熱材
6 ノズル本体
7 上端開孔部
8 上端開孔
9 内孔体
10 嵌装部
11 モルタル
12 鉄皮
DESCRIPTION OF SYMBOLS 1 Long nozzle 2 Nozzle inner hole 3 Upper part of nozzle inner hole 4 Refractory ring 5 Fiber heat insulating material 6 Nozzle main body 7 Upper end opening part 8 Upper end opening part 9 Inner hole body 10 Insertion part 11 Mortar 12 Iron skin

Claims (3)

外周が鉄皮にて被覆され取鍋内の金属溶湯をタンディシュに注入するロングノズルであって、ノズル内孔の上部には耐火物リングを嵌装するための嵌装部が形成され、前記耐火物リングは外周にファイバー性断熱材が張設されると共に、前記ノズル内孔の上部に配されたモルタルを介して前記嵌装部に嵌装されていることを特徴とするロングノズル。   A long nozzle whose outer periphery is covered with an iron skin and injects a molten metal in a ladle into a tundish, and a fitting portion for fitting a refractory ring is formed in the upper portion of the nozzle inner hole. A long nozzle characterized in that a fiber ring is stretched around the outer periphery of the object ring and is fitted into the fitting portion via a mortar disposed above the nozzle inner hole. 前記耐火物リングの外側面は下方に向かって径が小さくなるテーパー面に形成され、前記嵌装部の内側面と前記耐火物リングの外側面との間隙には、前記ノズル内孔の上部と前記耐火物リングとを接合するためのモルタルが侵入可能に構成されている請求項1に記載のロングノズル。   The outer surface of the refractory ring is formed into a tapered surface whose diameter decreases downward, and the gap between the inner surface of the fitting portion and the outer surface of the refractory ring is an upper portion of the nozzle inner hole. The long nozzle according to claim 1, wherein a mortar for joining the refractory ring is configured to be able to enter. 外周が鉄皮にて被覆され取鍋内の金属溶湯をタンディシュに注入するロングノズルの製造方法であって、ノズル内孔の上部に嵌装される耐火物リングの外周にファイバー性断熱材を張設した後、前記耐火物リングを前記ノズル内孔の上部にモルタルを介して嵌装する工程を有したことを特徴とするロングノズルの製造方法。   This is a long nozzle manufacturing method in which the outer periphery is covered with a steel shell and the molten metal in the ladle is poured into the tundish, and a fiber insulation is applied to the outer periphery of the refractory ring fitted in the upper part of the nozzle bore. A method of manufacturing a long nozzle, comprising: a step of fitting the refractory ring to an upper portion of the nozzle inner hole through a mortar after installation.
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Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6178541A (en) * 1984-09-27 1986-04-22 Mitsubishi Steel Mfg Co Ltd Nozzle
JPH04294847A (en) * 1991-03-25 1992-10-19 Akechi Ceramics Kk Nozzle for continuous casting
JPH07100606A (en) * 1993-10-07 1995-04-18 Kurosaki Refract Co Ltd Structure of fit part for mounting casting nozzle
JPH11104815A (en) * 1997-10-01 1999-04-20 Toshiba Ceramics Co Ltd Nozzle for casting
JP2004136367A (en) * 2002-09-27 2004-05-13 Kurosaki Harima Corp JOINT STRUCTURE FOR CONTINUOUS CASTING NOZZLE HAVING CARBON CONTAINING CaO BASED REFRACTORY LAYER
JP2008006444A (en) * 2006-06-27 2008-01-17 Tokyo Yogyo Co Ltd Structure for discharging molten metal
JP2008194745A (en) * 2007-02-15 2008-08-28 Nippon Steel Corp Long nozzle

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6178541A (en) * 1984-09-27 1986-04-22 Mitsubishi Steel Mfg Co Ltd Nozzle
JPH04294847A (en) * 1991-03-25 1992-10-19 Akechi Ceramics Kk Nozzle for continuous casting
JPH07100606A (en) * 1993-10-07 1995-04-18 Kurosaki Refract Co Ltd Structure of fit part for mounting casting nozzle
JPH11104815A (en) * 1997-10-01 1999-04-20 Toshiba Ceramics Co Ltd Nozzle for casting
JP2004136367A (en) * 2002-09-27 2004-05-13 Kurosaki Harima Corp JOINT STRUCTURE FOR CONTINUOUS CASTING NOZZLE HAVING CARBON CONTAINING CaO BASED REFRACTORY LAYER
JP2008006444A (en) * 2006-06-27 2008-01-17 Tokyo Yogyo Co Ltd Structure for discharging molten metal
JP2008194745A (en) * 2007-02-15 2008-08-28 Nippon Steel Corp Long nozzle

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