JP2010202532A - Eyelash cosmetic - Google Patents
Eyelash cosmetic Download PDFInfo
- Publication number
- JP2010202532A JP2010202532A JP2009047284A JP2009047284A JP2010202532A JP 2010202532 A JP2010202532 A JP 2010202532A JP 2009047284 A JP2009047284 A JP 2009047284A JP 2009047284 A JP2009047284 A JP 2009047284A JP 2010202532 A JP2010202532 A JP 2010202532A
- Authority
- JP
- Japan
- Prior art keywords
- component
- acrylic copolymer
- cycloalkyl group
- containing acrylic
- cosmetic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000002537 cosmetic Substances 0.000 title claims abstract description 58
- 210000000720 eyelash Anatomy 0.000 title abstract 4
- 229920006243 acrylic copolymer Polymers 0.000 claims abstract description 74
- 125000000753 cycloalkyl group Chemical group 0.000 claims abstract description 65
- LEEDMQGKBNGPDN-UHFFFAOYSA-N 2-methylnonadecane Chemical compound CCCCCCCCCCCCCCCCCC(C)C LEEDMQGKBNGPDN-UHFFFAOYSA-N 0.000 claims abstract description 28
- 239000000341 volatile oil Substances 0.000 claims abstract description 9
- 239000000843 powder Substances 0.000 claims description 30
- 239000000178 monomer Substances 0.000 claims description 23
- 229920001296 polysiloxane Polymers 0.000 claims description 20
- 239000000203 mixture Substances 0.000 claims description 17
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 15
- OIWOHHBRDFKZNC-UHFFFAOYSA-N cyclohexyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OC1CCCCC1 OIWOHHBRDFKZNC-UHFFFAOYSA-N 0.000 claims description 15
- 239000000470 constituent Substances 0.000 claims description 12
- 239000007788 liquid Substances 0.000 claims description 12
- 230000000379 polymerizing effect Effects 0.000 claims description 12
- 238000002156 mixing Methods 0.000 claims description 9
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 8
- 239000004793 Polystyrene Substances 0.000 claims description 8
- 125000000217 alkyl group Chemical group 0.000 claims description 8
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- 125000004432 carbon atom Chemical group C* 0.000 claims description 7
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 7
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 5
- 239000001257 hydrogen Substances 0.000 claims description 4
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- BANXPJUEBPWEOT-UHFFFAOYSA-N 2-methyl-Pentadecane Chemical compound CCCCCCCCCCCCCC(C)C BANXPJUEBPWEOT-UHFFFAOYSA-N 0.000 description 4
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- SHOKWSLXDAIZPP-UHFFFAOYSA-N [4-(4-iodooxy-2-methyl-5-propan-2-ylphenyl)-5-methyl-2-propan-2-ylphenyl] hypoiodite Chemical compound C1=C(OI)C(C(C)C)=CC(C=2C(=CC(OI)=C(C(C)C)C=2)C)=C1C SHOKWSLXDAIZPP-UHFFFAOYSA-N 0.000 description 4
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Landscapes
- Cosmetics (AREA)
Abstract
Description
本発明は、新規なシクロアルキル基含有アクリル系共重合体を配合する睫用化粧料に関するものである。 The present invention relates to a vaginal cosmetic containing a novel cycloalkyl group-containing acrylic copolymer.
従来、睫用化粧料は、睫に塗布することにより、睫を、カールしているように見せたり(カール効果)、濃く見せたり、太く見せたり(ボリューム効果)、長く見せたり(ロング効果)する化粧料である。それぞれの効果を持続させるために皮膜形成剤を配合して、化粧膜が崩れるのを防いでいる。
また、睫用化粧料は、睫に塗布しやすく、塗布後は早く化粧膜を形成することが必要であるために、揮発性溶媒が用いられている。この代表的なものとしては、水、また軽質流動イソパラフィンやイソドデカン等のパラフィン系溶剤、環状オルガノポリシロキサンや低分子量オルガノポリシロキサン等のシリコーン系溶剤がある。
皮膜形成剤は、大きく分けて、これらの溶媒に溶解して用いるものと、溶媒に分散させて用いるものがある。ここで、溶媒に分散させたものとは、水中や有機溶媒中に高分子物質の微粒子が安定に分散した懸濁液で、界面活性剤で乳化させたモノマーを重合することによって得られる液や自然界に存在する乳状の樹液を含むものである。
溶媒に溶解させて皮膜形成剤を用いれば、睫に均一につけることができ、溶媒に分散させて塗布すれば、化粧膜の形成を早くすることができる。例えば、皮膜形成剤を用いた技術としては、被膜形成性樹脂と被膜形成性のポリマーエマルションを配合する技術(例えば、特許文献1)や、トリメチルシロキシケイ酸とアクリル−シリコーン系グラフト共重合体を用いる技術(例えば、特許文献2)があげられ、種類の異なる皮膜形成剤を組み合わせて用いる技術が検討されている。
一方、ポリメチルメタクリレートに代表されるアクリル系樹脂は透明で硬い皮膜を形成し、加工性が良好なことから化粧料においても広く利用されている。しかしながらアクリル系樹脂は極性が高く、アセトンやトルエン、酢酸ブチル、クロロホルムなどの有機溶剤には溶解するが、軽質流動イソパラフィンやイソドデカンなどのパラフィン系溶剤には不溶である。そのため、極性溶媒を用いる美爪料では、溶媒に溶解して用いられていたが、その他の化粧料では水性分散物や、溶剤分散物として用いられていた。(例えば、特許文献1、3参照)
Traditionally, vaginal cosmetics are applied to wrinkles to make wrinkles look curled (curl effect), darker, thicker (volume effect), or longer (long effect). Cosmetics to do. In order to maintain each effect, a film forming agent is blended to prevent the decorative film from collapsing.
Moreover, since the cosmetics for candy are easy to apply | coat to a candy and it is necessary to form a cosmetic film quickly after application | coating, the volatile solvent is used. Typical examples include water, paraffinic solvents such as light liquid isoparaffin and isododecane, and silicone solvents such as cyclic organopolysiloxane and low molecular weight organopolysiloxane.
Film forming agents are roughly classified into those used by being dissolved in these solvents and those used by being dispersed in a solvent. Here, what is dispersed in a solvent is a suspension in which fine particles of a polymer substance are stably dispersed in water or an organic solvent, and a liquid obtained by polymerizing a monomer emulsified with a surfactant. It contains milky sap that exists in nature.
If it is dissolved in a solvent and a film forming agent is used, it can be applied uniformly to the wrinkles, and if it is dispersed in a solvent and applied, the formation of the decorative film can be accelerated. For example, as a technique using a film-forming agent, a technique of blending a film-forming resin and a film-forming polymer emulsion (for example, Patent Document 1), trimethylsiloxysilicic acid and an acrylic-silicone graft copolymer are used. A technique to be used (for example, Patent Document 2) is mentioned, and a technique in which different types of film forming agents are used in combination has been studied.
On the other hand, acrylic resins typified by polymethyl methacrylate are widely used in cosmetics because they form a transparent and hard film and have good workability. However, acrylic resins are highly polar and dissolve in organic solvents such as acetone, toluene, butyl acetate, and chloroform, but are insoluble in paraffinic solvents such as light liquid isoparaffin and isododecane. Therefore, the nail polish using a polar solvent was used by dissolving in a solvent, but it was used as an aqueous dispersion or a solvent dispersion in other cosmetics. (For example, refer to Patent Documents 1 and 3)
しかしながら、最近の睫用化粧料は、複数の効果がそれぞれしっかり得られることが望まれてきているが、カール効果を持続させることと他の効果を共存させることは困難であった。例えば、ボリューム効果やロング効果とカール効果を得たい場合は、睫にワックスや粉体、繊維等をより多く付着させ、睫が重くなり下がるのを防ぐために、強固な化粧膜にする必要がある。そうすると、瞬き等の動きにより、化粧膜に亀裂が入り剥がれ落ち、ボリューム効果やロング効果も消失し、更に化粧膜の透明感がなくなるために、睫のツヤ感が消失することがあった。加えて、硬い化粧膜となるため、使用感も良いものではなかった。また、皮膜形成剤の水性分散物や、溶剤分散物は、化粧膜に柔軟性がありながらも、適度な強度を与え、カール効果を持続させることができるが、化粧膜の均一性が得られないために、ツヤ感が低下し、発色も悪いものに感じられるため、目を際立たせる効果が十分得られない場合があった。
そこで、カール効果とその持続性に優れ、同時に他の効果も併せ持つ睫用化粧料が得られる、技術の開発が望まれていた。
However, it has been desired that recent cosmetics for acupuncture can obtain a plurality of effects, but it has been difficult to maintain the curl effect and to make other effects coexist. For example, if you want to obtain volume effect, long effect and curl effect, it is necessary to make a strong cosmetic film in order to attach more wax, powder, fiber, etc. to the wrinkles and prevent the wrinkles from becoming heavy and falling . Then, due to movement such as blinking, the decorative film is cracked and peeled off, the volume effect and the long effect are lost, and further, the transparent feeling of the decorative film is lost, so that the glossiness of the wrinkle may be lost. In addition, since it becomes a hard decorative film, the feeling of use was not good. In addition, the aqueous dispersion of the film-forming agent and the solvent dispersion can impart a proper strength and maintain the curl effect while the decorative film is flexible, but the uniformity of the decorative film is obtained. Therefore, the glossy feeling is lowered and the color development is felt to be poor, so that the effect of conspicuous eyes may not be sufficiently obtained.
Therefore, there has been a demand for the development of a technique capable of obtaining a vaginal cosmetic that is excellent in curling effect and its sustainability and at the same time has other effects.
かかる実情において、本発明者は上記課題を解決するために鋭意研究した結果、新規なシクロアルキル基含有アクリル系共重合体と揮発性油剤とを配合することにより、カール効果及びその持続性に優れ、化粧膜の均一性及びツヤ感にも優れた睫用化粧料が得られることを見出し、本発明を完成するに至った。 In such a situation, the present inventors have intensively studied to solve the above problems, and as a result, by blending a novel cycloalkyl group-containing acrylic copolymer and a volatile oil agent, the curl effect and its durability are excellent. The present inventors have found that a vaginal cosmetic excellent in the uniformity and gloss of the decorative film can be obtained, and have completed the present invention.
すなわち、本発明は、次の成分(A)及び(B);
(A)シクロアルキル基含有アクリル系共重合体
(B)揮発性油剤
を配合することを特徴とする睫用化粧料を提供するものである。
That is, the present invention includes the following components (A) and (B);
(A) A cycloalkyl group-containing acrylic copolymer (B) A volatile oil agent is blended, and a vaginal cosmetic is provided.
本発明の睫用化粧料は、カール効果及びその持続性に優れ、化粧膜の均一性及びツヤ感に優れた睫用化粧料である。 The vaginal cosmetic of the present invention is a vaginal cosmetic excellent in curling effect and its sustainability, and excellent in the uniformity and gloss of the cosmetic film.
以下、本発明を詳細に説明する。
本発明の成分(A)のシクロアルキル基含有アクリル系共重合体としては、成分(a1)シクロアルキル基含有アクリレート及び/またはメタクリレート;と、成分(a2)炭素数8〜12の直鎖若しくは分岐のアルキル基を含有するアクリレート及び/またはメタクリレート;及び/または(a3)片末端にラジカル重合性基を含有するオルガノポリシロキシサンマクロモノマー;とを含むモノマーを重合して得られるアクリル系共重合体であって、構成モノマー総量中、成分(a1)の配合量が50〜90質量%(以下、単に「%」とする)、成分(a2)及び/または(a3)の配合量が10〜50%であり、且つ、軽質流動イソパラフィンに25℃で少なくとも30%溶解する共重合体であれば特に制限されず、例えば、成分(a1)と成分(a2)と成分(a3)と必要に応じて任意成分とを、それぞれ有機溶媒の存在下で水の非存在下、重合することにより得ることができ、より具体的には、成分(a1)50〜90%に対し、成分(a2)10〜50%を重合して得られるアクリル系共重合体や、成分(a1)50〜90%に対し、成分(a3)10〜50%を重合して得られるアクリル系共重合体や、成分(a1)50〜90%に対し、成分(a2)と(a3)の合計10〜50%を重合して得られるアクリル系共重合体を、好適に例示することができる。
また本発明において、軽質流動イソパラフィンとは、主にイソパラフィンからなる炭化水素の混合物であるが、その中でも25℃で少なくとも30%溶解する溶解度の基準として用いたものは、JIS K2254に規定される石油製品蒸留試験方法による初留温度が166℃であり、蒸留終点が202℃の蒸留性状を有し、37.8℃における動粘度が1.28mm2/sのものである。
Hereinafter, the present invention will be described in detail.
The cycloalkyl group-containing acrylic copolymer of component (A) of the present invention includes component (a1) cycloalkyl group-containing acrylate and / or methacrylate; and component (a2) linear or branched having 8 to 12 carbon atoms. And / or (a3) an organopolysiloxysan macromonomer containing a radically polymerizable group at one end; and an acrylic copolymer obtained by polymerizing a monomer. In the total amount of constituent monomers, the compounding amount of the component (a1) is 50 to 90% by mass (hereinafter simply referred to as “%”), and the compounding amount of the component (a2) and / or (a3) is 10 to 50. %, And a copolymer that is soluble in light liquid isoparaffin at least 30% at 25 ° C. is not particularly limited. For example, the component (a1 And the component (a2), the component (a3), and an optional component, if necessary, can be obtained by polymerization in the presence of an organic solvent in the absence of water, and more specifically, the component ( a1) An acrylic copolymer obtained by polymerizing component (a2) 10 to 50% with respect to 50 to 90%, or component (a3) 10 to 50% with respect to component (a1) 50 to 90%. An acrylic copolymer obtained by polymerizing and an acrylic copolymer obtained by polymerizing a total of 10 to 50% of the components (a2) and (a3) with respect to 50 to 90% of the component (a1), It can illustrate suitably.
In the present invention, light liquid isoparaffin is a mixture of hydrocarbons mainly composed of isoparaffin. Among them, the one used as a standard for solubility at 25% at 25 ° C. is petroleum oil as defined in JIS K2254. The initial distillation temperature according to the product distillation test method is 166 ° C., the distillation end point is 202 ° C., and the kinematic viscosity at 37.8 ° C. is 1.28 mm 2 / s.
本発明の成分(A)シクロアルキル基含有アクリル系共重合体の構成モノマーのうち、成分(a1)のシクロアルキル基含有アクリレート及び/またはメタクリレートは、親油性の重合性モノマーで、耐水性のある透明で硬い皮膜形成能を有する骨格を成すものである。具体例としては、シクロヘキシルアクリレート、シクロヘキシルメタクリレート、ジシクロペンタニルアクリレート、ジシクロペンタニルメタクリレート、トリシクロデシルアクリレート、トリシクロデシルメタクリレート、トリシクロデカニルアクリレート、トリシクロデカニルメタクリレート等が挙げられ、これらを1種または2種以上用いることができる。とりわけシクロヘキシルメタクリレートはラジカル重合性が良好で収率が高く、硬い皮膜を形成するための好適なガラス転移点を有する共重合体を得ることができ、特に好ましい。 Among the constituent monomers of the component (A) cycloalkyl group-containing acrylic copolymer of the present invention, the cycloalkyl group-containing acrylate and / or methacrylate of the component (a1) is a lipophilic polymerizable monomer and has water resistance. It forms a skeleton having a transparent and hard film-forming ability. Specific examples include cyclohexyl acrylate, cyclohexyl methacrylate, dicyclopentanyl acrylate, dicyclopentanyl methacrylate, tricyclodecyl acrylate, tricyclodecyl methacrylate, tricyclodecanyl acrylate, tricyclodecanyl methacrylate, and the like. 1 type (s) or 2 or more types can be used. In particular, cyclohexyl methacrylate is particularly preferred because it has a good radical polymerizability, a high yield, and a copolymer having a suitable glass transition point for forming a hard film.
本発明の成分(A)のシクロアルキル基含有アクリル系共重合体の構成モノマーのうち、成分(a2)の炭素数8〜12の直鎖若しくは分岐のアルキル基を含有するアクリレート及び/またはメタクリレートは、親油性の重合性モノマーで、皮膜に柔軟性や付着性を付与し、軽質流動イソパラフィンへの溶解性を高める骨格を成すものである。具体例としては、オクチルアクリレート、オクチルメタクリレート、2−エチルヘキシルアクリレート、2−エチルヘキシルメタクリレート、イソノニルアクリレート、イソノニルメタクリレート、ラウリルアクリレート、ラウリルメタクリレート等が挙げられ、これらを1種または2種以上用いることができるが、2−エチルヘキシルメタクリレート、ラウリルメタクリレートが好ましく、中でも2−エチルヘキシルメタクリレートが溶解性を向上することができ特に好ましい。 Among the constituent monomers of the cycloalkyl group-containing acrylic copolymer of the component (A) of the present invention, the acrylate and / or methacrylate containing a linear or branched alkyl group having 8 to 12 carbon atoms of the component (a2) is It is a lipophilic polymerizable monomer that forms a skeleton that imparts flexibility and adhesion to the film and increases the solubility in light liquid isoparaffin. Specific examples include octyl acrylate, octyl methacrylate, 2-ethylhexyl acrylate, 2-ethylhexyl methacrylate, isononyl acrylate, isononyl methacrylate, lauryl acrylate, lauryl methacrylate, and the like, and one or more of these may be used. However, 2-ethylhexyl methacrylate and lauryl methacrylate are preferable, and 2-ethylhexyl methacrylate is particularly preferable because it can improve solubility.
本発明の成分(A)のシクロアルキル基含有アクリル系共重合体の構成モノマーのうち、成分(a3)の片末端にラジカル重合性基を含有するオルガノポリシロキサンマクロモノマーとしては、アクリル酸若しくはメタクリル酸に二価の炭化水素基を介してオルガノポリシロキサンを連結したエステル化合物を挙げることができ、皮膜に耐水性を付与し、軽質流動イソパラフィンへの溶解性を高める骨格を成すものである。具体的には、下記式(1)のオルガノポリシロキサンマクロモノマーを例示することができ、 Among the constituent monomers of the cycloalkyl group-containing acrylic copolymer of the component (A) of the present invention, the organopolysiloxane macromonomer containing a radical polymerizable group at one end of the component (a3) includes acrylic acid or methacrylic acid. An ester compound in which an organopolysiloxane is linked to an acid via a divalent hydrocarbon group can be mentioned, and it forms a skeleton that imparts water resistance to the film and increases the solubility in light liquid isoparaffin. Specifically, an organopolysiloxane macromonomer of the following formula (1) can be exemplified,
(式中、mは1〜10、好ましくは1〜4、nは0〜200の整数、R1は、水素またはメチル基を示し、R2〜R8は、炭素数1〜5のアルキル基を示す。)
これらは1種単独でまたは2種以上混合して用いることができる。
より具体的には一般式(2)に示されるジメチルポリシロキサンマクロモノマーを挙げることができる。
(In the formula, m is 1 to 10, preferably 1 to 4, n is an integer of 0 to 200, R 1 represents hydrogen or a methyl group, and R 2 to R 8 are alkyl groups having 1 to 5 carbon atoms. Is shown.)
These can be used individually by 1 type or in mixture of 2 or more types.
More specifically, the dimethylpolysiloxane macromonomer shown by General formula (2) can be mentioned.
(式中、nは0〜200の整数、R1は水素またはメチル基を示し、R2は炭素数1〜5のアルキル基を示す。)
ここで、R1は水素またはメチル基で、R2は炭素数1〜5のアルキル基、ジメチルポリシロキサン基の繰返し単位を示すnは0〜200であると、充分な耐水性が得られ、さらに透明で均一な皮膜が得られるため好ましい。nは、5〜150であると耐水性や均一な膜を得る点において更に好ましい。
(In the formula, n represents an integer of 0 to 200, R 1 represents hydrogen or a methyl group, and R 2 represents an alkyl group having 1 to 5 carbon atoms.)
Here, R 1 is hydrogen or a methyl group, R 2 is an alkyl group having 1 to 5 carbon atoms, and n representing a repeating unit of a dimethylpolysiloxane group is 0 to 200, sufficient water resistance is obtained, Furthermore, it is preferable because a transparent and uniform film can be obtained. n is more preferably 5 to 150 in terms of obtaining water resistance and a uniform film.
本発明の成分(A)のシクロアルキル基含有アクリル系共重合体は、上記成分(a1)と成分(a2)及び/または成分(a3)とを構成モノマーとするが、成分(a1)50〜90%に対し、成分(a2)10〜50%を重合して得られるシクロアルキル基含有アクリル系共重合体は、柔軟性がありながら比較的硬めの皮膜が形成され、成分(a1)50〜90%に対し、成分(a3)10〜50%を重合して得られるシクロアルキル基含有アクリル系共重合体は、特に耐水性の良い皮膜が形成され、成分(a1)50〜90%に対し、成分(a2)と(a3)とを合計10〜50%で重合して得られるシクロアルキル基含有アクリル系共重合体は、特に硬さと耐水性のある皮膜が形成される。 The cycloalkyl group-containing acrylic copolymer of the component (A) of the present invention comprises the component (a1), the component (a2) and / or the component (a3) as constituent monomers, but the component (a1) 50 to The cycloalkyl group-containing acrylic copolymer obtained by polymerizing 10 to 50% of component (a2) with respect to 90% forms a relatively hard film while having flexibility, and component (a1) 50 to 50%. With respect to 90%, the cycloalkyl group-containing acrylic copolymer obtained by polymerizing component (a3) 10 to 50% has a particularly good water-resistant film formed, and component (a1) 50 to 90% The cycloalkyl group-containing acrylic copolymer obtained by polymerizing components (a2) and (a3) in a total of 10 to 50% forms a particularly hard and water-resistant film.
また、本発明の成分(A)のシクロアルキル基含有アクリル系共重合体は、本発明の効果を損なわない範囲であれば、上記成分(a1)〜(a3)以外の重合性モノマーを任意成分として含有することができる。成分(a1)〜(a3)以外の重合性モノマーとしては特に限定はされないが、スチレン、置換スチレン、酢酸ビニル、アクリル酸、メタクリル酸、前記以外のアクリル酸エステル及びメタクリル酸エステル、無水マレイン酸、マレイン酸エステル、フマル酸エステル、塩化ビニル、塩化ビニリデン、エチレン、プロピレン、ブタジエン、アクリロニトリル、フッ化オレフィン、アクリルアミド、メタクリルアミド、メチルアクリルアミド、メチルメタクリルアミド、ジメチルメタクリルアミド、N−イソプロピルアクリルアミド、N−ビニルピロリドン、N−ビニルアセトアミド、t−ブチルアクリレート、t−ブチルメタクリレート、ヒドロキシエチルメタクリレート、ヒドロキシプロピルメタクリレート、ジメチルアミノエチルメタクリレート、ジメチルアミノエチルメタクリルアミド、2−アクリルアミド−2−ジメチルプロパンスルホン酸塩等を挙げることができる。 In addition, the cycloalkyl group-containing acrylic copolymer of the component (A) of the present invention is an optional component with a polymerizable monomer other than the above components (a1) to (a3) as long as the effects of the present invention are not impaired. It can contain as. The polymerizable monomer other than the components (a1) to (a3) is not particularly limited, but styrene, substituted styrene, vinyl acetate, acrylic acid, methacrylic acid, other acrylic esters and methacrylates, maleic anhydride, Maleic acid ester, fumaric acid ester, vinyl chloride, vinylidene chloride, ethylene, propylene, butadiene, acrylonitrile, fluorinated olefin, acrylamide, methacrylamide, methylacrylamide, methylmethacrylamide, dimethylmethacrylamide, N-isopropylacrylamide, N-vinyl Pyrrolidone, N-vinylacetamide, t-butyl acrylate, t-butyl methacrylate, hydroxyethyl methacrylate, hydroxypropyl methacrylate, dimethylaminoethyl methacrylate Rate, dimethylaminoethyl methacrylamide, and 2-acrylamido-2-dimethylamino-propane sulfonate and the like.
上記成分(a1)〜(a3)や、任意の重合体モノマーの配合割合としては、成分(a1)の配合量は、構成モノマー総量の50〜90%であり、50〜80%が好ましい。50%未満では、充分な硬さの皮膜を得ることができず、また、90%を超えると軽質流動イソパラフィンへの溶解性が悪くなる。上記成分(a2)の配合量は、構成モノマー総量の10〜50%であり、15〜45%が好ましい。10%未満では、軽質流動イソパラフィンへの溶解性が悪くなり、また、50%を超えると充分な硬さの皮膜を得ることができず、べたつきやタック性、膜の不均一性などの欠点が生じる。上記成分(a3)の配合量は、構成モノマー総量の10〜50%であり、15〜45%が好ましい。10%未満であると軽質流動イソパラフィンへの溶解性が悪くなり、50%を超えると充分な硬さの皮膜を得ることができず、べたつきやタック性、膜の不均一性などの欠点が生じる。また、成分(a2)と成分(a3)を併用する場合については、その配合量の合計は、10〜50%であり、15〜45%が好ましい。成分(a2)と成分(a3)の配合量の合計が50%を超えると充分な硬さの皮膜を得ることができず、べたつきやタック性、膜の不均一性などの欠点がみられ、配合量の合計が10%未満であると軽質流動イソパラフィンへの溶解性が悪くなる。上記任意成分の配合量としては、構成モノマー総量の30%以下の範囲であればよく、20%以下が好ましく、例えば0.01〜10%配合することができる。 As a blending ratio of the components (a1) to (a3) and any polymer monomer, the blending amount of the component (a1) is 50 to 90% of the total amount of the constituent monomers, and preferably 50 to 80%. If it is less than 50%, a film having sufficient hardness cannot be obtained, and if it exceeds 90%, the solubility in light liquid isoparaffin deteriorates. The compounding amount of the component (a2) is 10 to 50% of the total amount of the constituent monomers, and preferably 15 to 45%. If it is less than 10%, the solubility in light liquid isoparaffin becomes poor, and if it exceeds 50%, a film with sufficient hardness cannot be obtained, and there are drawbacks such as stickiness, tackiness, and film non-uniformity. Arise. The compounding amount of the component (a3) is 10 to 50% of the total amount of the constituent monomers, and preferably 15 to 45%. If it is less than 10%, the solubility in light liquid isoparaffin deteriorates, and if it exceeds 50%, a film with sufficient hardness cannot be obtained, resulting in defects such as stickiness, tackiness, and film non-uniformity. . Moreover, about the case where a component (a2) and a component (a3) are used together, the total of the compounding quantity is 10 to 50%, and 15 to 45% is preferable. When the total amount of component (a2) and component (a3) exceeds 50%, a film with sufficient hardness cannot be obtained, and there are defects such as stickiness, tackiness, and film non-uniformity. If the total blending amount is less than 10%, the solubility in light liquid isoparaffin is deteriorated. The amount of the optional component may be within a range of 30% or less of the total amount of the constituent monomers, preferably 20% or less, for example, 0.01 to 10%.
本発明の成分(A)のシクロアルキル基含有アクリル系共重合体の重量平均分子量は特に制限されないが、1.0×104〜2.0×105の範囲のものが好ましい。前記重量平均分子量は、溶離液としてテトラヒドロフランを用い、直鎖ポリスチレン標準品で作成した校正曲線及び屈折率検出器を使用する液体ゲル浸透クロマトグラフィー(GPC)により測定される。この重量平均分子量が1.0×104より小さいと皮膜形成性にやや劣り、2.0×105より大きいと軽質流動イソパラフィン中での溶解粘度が高く皮膜の均一性にやや劣り好ましくない。 The weight average molecular weight of the cycloalkyl group-containing acrylic copolymer of the component (A) of the present invention is not particularly limited, but is preferably in the range of 1.0 × 10 4 to 2.0 × 10 5 . The weight average molecular weight is measured by liquid gel permeation chromatography (GPC) using tetrahydrofuran as an eluent and using a calibration curve prepared with a linear polystyrene standard and a refractive index detector. The weight average molecular weight is slightly inferior to 1.0 × 10 4 smaller than film-forming, 2.0 × slightly degraded undesirably 10 5 greater and uniformity of the solution viscosity is high coating in light liquid isoparaffin in.
本発明の成分(A)のシクロアルキル基含有アクリル系共重合体は、上記成分(a1)〜(a3)や、必要に応じて他の任意の重合体モノマーを構成モノマーとして用い、有機溶媒の存在下(水の非存在下)、公知の重合方法によるランダム重合により得ることができる。特に限定はされないが、ベンゾイルパーオキサイド、ラウロイルパーキサイド等の有機過酸化物、α,α’−アゾビスイソブチロニトリル、2,2’−アゾビス(2,4−ジメチルバレロニトリル)、2,2’−アゾビス(2−メチルブチロニトリル)等のアゾ系化合物、過硫酸カリウム、過硫酸アンモニウム等の過硫酸系重合開始剤等のラジカル重合開始剤の存在下で重合を行えばよく、溶液重合法、懸濁重合法、塊状重合法、沈殿重合法等を用いることができる。これらのうち、特に溶液重合法は、得られるアクリル系共重合体の分子量を最適範囲に調整することが容易であるため好ましい。 The cycloalkyl group-containing acrylic copolymer of the component (A) of the present invention uses the above components (a1) to (a3) and other optional polymer monomers as constituent monomers as necessary, It can be obtained by random polymerization by a known polymerization method in the presence (in the absence of water). Although not particularly limited, organic peroxides such as benzoyl peroxide and lauroyl peroxide, α, α′-azobisisobutyronitrile, 2,2′-azobis (2,4-dimethylvaleronitrile), 2, Polymerization may be performed in the presence of a radical polymerization initiator such as an azo compound such as 2′-azobis (2-methylbutyronitrile), a persulfuric polymerization initiator such as potassium persulfate or ammonium persulfate, A combination method, suspension polymerization method, bulk polymerization method, precipitation polymerization method and the like can be used. Among these, the solution polymerization method is particularly preferable because it is easy to adjust the molecular weight of the obtained acrylic copolymer to the optimum range.
本発明の成分(A)のシクロアルキル基含有アクリル系共重合体の重合時に用いる有機溶媒としては、例えばベンゼン、トルエン、キシレン等の芳香族炭化水素、メチルエチルケトン、メチルイソブチルケトン等のケトン類、酢酸エチル、酢酸ブチル等のエステル類、イソプロパノール、エタノール、メタノール等のアルコール類を挙げることができ、これらの1種または2種以上を組み合わせて用いることができる。また、軽質流動イソパラフィン、イソドデカン、イソヘキサデカン等のパラフィン系溶剤中で重合することもできる。 Examples of the organic solvent used in the polymerization of the cycloalkyl group-containing acrylic copolymer of the component (A) of the present invention include aromatic hydrocarbons such as benzene, toluene and xylene, ketones such as methyl ethyl ketone and methyl isobutyl ketone, and acetic acid. Examples thereof include esters such as ethyl and butyl acetate, and alcohols such as isopropanol, ethanol and methanol, and these can be used alone or in combination. Moreover, it can also superpose | polymerize in paraffinic solvents, such as a light liquid isoparaffin, isododecane, and isohexadecane.
本発明の成分(A)のシクロアルキル基含有アクリル系共重合体の重合反応温度は、通常のラジカル重合開始剤の使用可能な温度範囲であれば特に制限はされないが、通常40〜120℃の範囲で実施される。反応温度は使用するラジカル重合開始剤、モノマーの種類、反応温度により異なるが、通常2〜24時間実施される。重合時間が短すぎると残存モノマー量が多く収率が低くなり好ましくない。 The polymerization reaction temperature of the cycloalkyl group-containing acrylic copolymer of the component (A) of the present invention is not particularly limited as long as it is a temperature range in which a normal radical polymerization initiator can be used, but is usually 40 to 120 ° C. Implemented in a range. While the reaction temperature varies depending on the radical polymerization initiator to be used, the type of monomer, and the reaction temperature, it is usually carried out for 2 to 24 hours. If the polymerization time is too short, the amount of residual monomer is large and the yield is lowered, which is not preferable.
本発明の成分(A)のシクロアルキル基含有アクリル系共重合体は、反応させたときのパラフィン系溶剤中に溶解させたまま、または必要に応じて他の炭化水素やエステル、トリグリセライド等の油剤で希釈を行うことや、他の油剤へ溶媒置換を行うこともできる。このような油溶形態のシクロアルキル基を含有するアクリル系共重合体組成物も本発明の成分(A)に包含される。また、溶液の溶媒を除去してシクロアルキル基含有アクリル系共重合体を固体として取り出すことができ、さらに得られたシクロアルキル基含有アクリル系共重合体を軽質流動イソパラフィンに溶解することによりシクロアルキル基含有アクリル系共重合体溶液として使用することもできる。上記のシクロアルキル基含有アクリル系共重合体及びその溶液は1種または2種以上混合して用いることもできる。 The cycloalkyl group-containing acrylic copolymer of the component (A) of the present invention is dissolved in a paraffin solvent when reacted, or if necessary, other hydrocarbons, esters, triglycerides and other oil agents It is also possible to dilute with or to replace the solvent with another oil. The acrylic copolymer composition containing such an oil-soluble cycloalkyl group is also included in the component (A) of the present invention. In addition, the solvent of the solution can be removed to take out the cycloalkyl group-containing acrylic copolymer as a solid, and the resulting cycloalkyl group-containing acrylic copolymer is dissolved in light liquid isoparaffin to obtain cycloalkyl. It can also be used as a group-containing acrylic copolymer solution. The cycloalkyl group-containing acrylic copolymer and the solution thereof can be used alone or in combination.
本発明の成分(A)のシクロアルキル基含有アクリル系共重合体の溶解性は、軽質流動イソパラフィン(JIS K2254に規定される石油製品蒸留試験方法による初留温度が166℃であり、蒸留終点が202℃の蒸留性状を有し、37.8℃における動粘度が1.28mm2/sのもの)を溶解度の溶媒とした場合、25℃において少なくとも30%溶解する必要がある。この溶解性を示せば、均一で透明感があり塗膜強度の高い皮膜を形成することができる。 The solubility of the cycloalkyl group-containing acrylic copolymer of the component (A) of the present invention is such that the initial distillation temperature according to the petroleum product distillation test method specified in JIS K2254 is 166 ° C. When the solvent has a distillation property of 202 ° C. and a kinematic viscosity at 37.8 ° C. of 1.28 mm 2 / s), it is necessary to dissolve at least 30% at 25 ° C. If this solubility is shown, it is possible to form a film that is uniform, transparent, and has high coating strength.
本発明の成分(A)のシクロアルキル基含有アクリル系共重合体の睫用化粧料への配合量としては、固形分として0.1〜40%、好ましくは1〜25%、より好ましくは2〜20%程度とすることができる。この範囲であれば、仕上がり時のベタツキがなく、均一で塗膜強度の高い皮膜が形成され、ツヤ感やカール力、そしてその持続性に優れたものが得られる。
本発明の成分(A)のシクロアルキル基含有アクリル系共重合体は、成分(B)の揮発性油剤に溶解して用いることが好ましく、成分(B)の中でも軽質流動イソパラフィンに溶解して用いることが更に好ましく、濃度を15〜50%とすることが好ましい。
The blending amount of the cycloalkyl group-containing acrylic copolymer of the component (A) of the present invention into the vaginal cosmetic is 0.1 to 40%, preferably 1 to 25%, more preferably 2 as the solid content. It can be about -20%. If it is this range, there will be no stickiness at the time of finishing, a film with uniform and high coating strength will be formed, and the thing which was excellent in glossiness, curl power, and the sustainability will be obtained.
The cycloalkyl group-containing acrylic copolymer of the component (A) of the present invention is preferably used by dissolving in the volatile oil of the component (B), and is used by dissolving in light liquid isoparaffin among the components (B). More preferably, the concentration is preferably 15 to 50%.
本発明の睫用化粧料に用いられる成分(B)の揮発性油剤は、成分(A)のシクロアルキル基含有アクリル系共重合体の溶媒として働き、系への配合を容易にし、仕上がり時のベタツキをおさえ、均一な皮膜が形成され、カール力、そしてその持続性を向上させることができる。 The volatile oil agent of component (B) used in the cosmetic for cosmetics of the present invention serves as a solvent for the cycloalkyl group-containing acrylic copolymer of component (A), facilitates its incorporation into the system, and is finished. By suppressing the stickiness, a uniform film is formed, and the curling force and its durability can be improved.
本発明の睫用化粧料に用いられる成分(B)の揮発性油剤としては、1気圧、25℃において揮発性であり、通常化粧料に用いられるものであれば特に制限されず、具体的には、軽質流動イソパラフィン、デカメチルシクロペンタシロキサン、オクタメチルシクロテトラシロキサン、ドデカメチルシクロヘキサシロキサン、メチルトリメチコン、ジメチルポリシロキサン、デカメチルテトラシロキサン、エチルトリシロキサン等が挙げられる。ここで軽質流動イソパラフィンは溶解度の基準として用いたものに限定されず用いることができる。
市販品として、軽質流動イソパラフィンとしてはアイソパーH(エッソ化学社製)、イソドデカン(バイエル社製)、イソヘキサデカン(ユニケマ社製)、IPソルベント1620MU、IPソルベント2028MU、IPソルベント2835(以上、出光興産社製)、デカメチルシクロペンタシロキサンとしてはTFS405(東芝シリコーン社製)、SH245、DC345(東レ・ダウコーニング社製)、KF−995(信越化学工業社製)、メチルトリメチコンとしては、シリコーン TMF−1.5(信越化学工業社製)、メチルポリシロキサンとしてはKF−96L−2CS(信越化学工業社製)、デカメチルテトラシロキサンとしてはKF−96L−1.5CS(信越化学工業社製)、エチルトリシロキサンとしてはSILSOFT ETS(モメンティブ・パフォーマンス・マテリアルズ社製)などが挙げられる。中でも、軽質流動イソパラフィンが、成分(A)のシクロアルキル基含有アクリル系共重合体の溶解性がよく、仕上がり時のベタツキをおさえ、均一な皮膜が得られる点で好ましい。これらの揮発性油剤は、必要に応じてその1種または2種以上を用いることができる。
The volatile oil of the component (B) used in the cosmetic for cosmetics of the present invention is not particularly limited as long as it is volatile at 1 atm and 25 ° C. and is usually used in cosmetics. Examples thereof include light liquid isoparaffin, decamethylcyclopentasiloxane, octamethylcyclotetrasiloxane, dodecamethylcyclohexasiloxane, methyltrimethicone, dimethylpolysiloxane, decamethyltetrasiloxane, and ethyltrisiloxane. Here, the light liquid isoparaffin can be used without being limited to those used as the standard of solubility.
As commercial products, as light liquid isoparaffin, Isopar H (manufactured by Esso Chemical Co., Ltd.), isododecane (manufactured by Bayer), isohexadecane (manufactured by Unikema), IP solvent 1620MU, IP solvent 2028MU, IP solvent 2835 (above, Idemitsu Kosan Co., Ltd.) ), As decamethylcyclopentasiloxane, TFS405 (manufactured by Toshiba Silicone), SH245, DC345 (manufactured by Dow Corning Toray), KF-995 (manufactured by Shin-Etsu Chemical Co., Ltd.), and methyltrimethicone as silicone TMF- 1.5 (manufactured by Shin-Etsu Chemical Co., Ltd.), KF-96L-2CS (manufactured by Shin-Etsu Chemical Co., Ltd.) as methylpolysiloxane, KF-96L-1.5CS (manufactured by Shin-Etsu Chemical Co., Ltd.) as decamethyltetrasiloxane, SILSO as ethyltrisiloxane FT ETS (manufactured by Momentive Performance Materials). Among these, light liquid isoparaffin is preferable in that the solubility of the cycloalkyl group-containing acrylic copolymer of component (A) is good, the stickiness at the time of finishing is suppressed, and a uniform film can be obtained. These volatile oils can be used alone or in combination of two or more as required.
成分(B)の揮発性油剤の配合量は特に限定されないが、1〜80%が好ましく、更に好ましくは1〜70%である。この範囲であれば、仕上がり時のベタツキがなく、均一で塗膜強度の高い皮膜が形成され、ツヤ感やカール力、そしてその持続性に優れたものが得られる。 Although the compounding quantity of the volatile oil agent of a component (B) is not specifically limited, 1 to 80% is preferable, More preferably, it is 1 to 70%. If it is this range, there will be no stickiness at the time of finishing, a film with uniform and high coating strength will be formed, and the thing which was excellent in glossiness, curl power, and the sustainability will be obtained.
本発明の睫用化粧料においては、更に、成分(C)として粉体を配合することができる。成分(C)を配合することにより、着色させることができ、乾燥速度を速め、より仕上がりのべとつきを抑えることで、睫に塗布し易く使用性の良好なものが得られる。また、成分(A)(B)と組み合わせることで、付着力を向上させ、発色の持続性を高めることができる。成分(C)の粉体としては、化粧料一般に使用される粉体であれば、板状、紡錘状、針状等の形状、粒子径、多孔質、無孔質等の粒子構造等により特に限定されず、無機粉体類、光輝性粉体類、有機粉体類、色素粉体類、複合粉体類等が挙げられる。具体的には、コンジョウ、群青、ベンガラ、黄酸化鉄、黒酸化鉄、酸化チタン、酸化亜鉛、チタン・酸化チタン焼結物、酸化セリウム、酸化マグネシウム、酸化ジルコニウム、酸化アンチモン、炭酸マグネシウム、炭酸カルシウム、酸化クロム、水酸化クロム、カーボンブラック、ケイ酸アルミニウム、ケイ酸マグネシウム、ケイ酸カルシウム、ケイ酸バリウム、ケイ酸アルミニウムマグネシウム、メタケイ酸アルミニウムマグネシウム、マイカ、合成マイカ、合成セリサイト、セリサイト、タルク、無水ケイ酸、白雲母、金雲母、紅雲母、黒雲母、カオリン、硫酸バリウム、ベントナイト、スメクタイト、珪ソウ土、ヒドロキシアパタイト、窒化硼素等の無機粉体類、オキシ塩化ビスマス、雲母チタン、酸化チタン被覆オキシ塩化ビスマス、酸化鉄被覆雲母、酸化鉄被覆雲母チタン、紺青被覆雲母チタン、カルミン被覆雲母チタン、有機顔料被覆雲母チタン、酸化鉄・酸化チタン被覆合成金雲母、魚燐箔、二酸化チタン被覆ガラスフレーク、ポリエチレンテレフタレート・アルミニウム・エポキシ積層末、ポリエチレンテレフタレート・ポリオレフィン積層フィルム末、ポリエチレンテレフタレート・ポリメチルメタクリレート積層フィルム末等の光輝性粉体類、ポリアミド系樹脂、ポリエチレン系樹脂、ポリアクリル系樹脂、ポリエステル系樹脂、フッ素系樹脂、セルロース系樹脂、ポリスチレン系樹脂、スチレン−アクリル共重合体樹脂等のコポリマー樹脂、ポリプロピレン系樹脂、シリコーン樹脂、ウレタン樹脂等の有機高分子樹脂粉体、N−アシルリジン等の有機粉体類、澱粉、シルク粉末、セルロース粉末等の天然有機粉体、有機タール系顔料、有機色素のレーキ顔料等の色素粉体類、アルミニウム粉、金粉、銀粉等の金属粉体、微粒子酸化チタン被覆雲母チタン、微粒子酸化亜鉛被覆雲母チタン、硫酸バリウム被覆雲母チタン等の複合粉体等が挙げられ、これらを1種または2種以上用いることができる。また、これら粉体は2種以上の複合化したものを用いても良く、フッ素系化合物、シリコーン系化合物、金属石ケン、レシチン、水素添加レシチン、コラーゲン、高級脂肪酸、高級アルコール、エステル、ワックス、ロウ、油脂、炭化水素、界面活性剤、アミノ酸系化合物、水溶性高分子等の1種または2種以上を用いて公知の方法により表面処理を施したものであっても良い。これらの粉体は、必要に応じ1種または2種以上を用いることができる。
成分(C)の粉体に無水ケイ酸を含有することにより、乾燥速度を速め、仕上がりのべたつきのなさや睫への塗布しやすさの点でより良好なものが得られる。無水ケイ酸は化粧料一般に使用されるものであり、無定形構造のもの、疎水化処理したもの、あるいは結晶構造を有するものも好適に使用できる。粒子の大きさは特に限定されないが、体積平均粒子径レーザー回折式粒度分布測定装置により測定するとき、1nm〜50μmが好ましく、3nm〜30μmが更に好ましい。この範囲であると、使用感のより良好なものが得られる。
市販品としては、サイリシア550、サイリシア770、サイロスフェア C−1504(富士シリシア化学社製)、AEROSIL200、AEROSIL300、AEROSILR972(日本アエロジール社製)ニップシールE−220(東ソー・シリカ社製)、等があげられる。これらの無水ケイ酸は、必要に応じ1種または2種以上を用いることができる。
In the vaginal cosmetic of the present invention, a powder can be further blended as the component (C). By blending the component (C), coloring can be achieved, the drying rate is increased, and the finished stickiness is further suppressed, so that a product that is easy to apply to a candy and has good usability can be obtained. Further, by combining with the components (A) and (B), the adhesion can be improved and the color development can be maintained. As the powder of component (C), as long as it is a powder generally used in cosmetics, the shape of a plate, spindle, needle, etc., particle diameter, porous, nonporous, etc. Without being limited, inorganic powders, glitter powders, organic powders, pigment powders, composite powders and the like can be mentioned. Specifically, conger, ultramarine, bengara, yellow iron oxide, black iron oxide, titanium oxide, zinc oxide, titanium / titanium oxide sintered product, cerium oxide, magnesium oxide, zirconium oxide, antimony oxide, magnesium carbonate, calcium carbonate , Chromium oxide, chromium hydroxide, carbon black, aluminum silicate, magnesium silicate, calcium silicate, barium silicate, magnesium aluminum silicate, magnesium magnesium metasilicate, mica, synthetic mica, synthetic sericite, sericite, talc Silica, silicic acid, muscovite, phlogopite, saucite, biotite, kaolin, barium sulfate, bentonite, smectite, diatomaceous earth, hydroxyapatite, boron nitride and other inorganic powders, bismuth oxychloride, titanium mica, oxidation Titanium-coated bismuth oxychloride Iron oxide coated mica, iron oxide coated mica titanium, bitumen coated mica titanium, carmine coated mica titanium, organic pigment coated mica titanium, iron oxide / titanium oxide coated synthetic phlogopite, fish phosphorus foil, titanium dioxide coated glass flake, polyethylene terephthalate Bright powders such as aluminum / epoxy laminated powder, polyethylene terephthalate / polyolefin laminated film powder, polyethylene terephthalate / polymethyl methacrylate laminated film powder, polyamide resin, polyethylene resin, polyacrylic resin, polyester resin, fluorine resin Resin, cellulose resin, polystyrene resin, copolymer resin such as styrene-acrylic copolymer resin, organic polymer resin powder such as polypropylene resin, silicone resin, urethane resin, organic powder such as N-acyl lysine Natural organic powders such as starch, silk powder and cellulose powder, organic tar pigments, pigment powders such as organic pigment lake pigments, metal powders such as aluminum powder, gold powder and silver powder, fine titanium oxide coated mica titanium, Examples thereof include composite powders such as fine particle zinc oxide-coated mica titanium and barium sulfate-coated mica titanium, and one or more of these can be used. In addition, these powders may be used in combination of two or more, such as fluorine compounds, silicone compounds, metal soaps, lecithin, hydrogenated lecithin, collagen, higher fatty acids, higher alcohols, esters, waxes, The surface treatment may be performed by a known method using one or more of wax, fats and oils, hydrocarbons, surfactants, amino acid compounds, water-soluble polymers and the like. These powders can be used alone or in combination of two or more.
By including silicic acid anhydride in the powder of component (C), the drying rate can be increased, and a better product can be obtained in terms of the non-stickiness of the finish and the ease of application to the candy. Silicic anhydride is generally used in cosmetics, and those having an amorphous structure, those having a hydrophobic treatment, or those having a crystal structure can be suitably used. The size of the particles is not particularly limited, but is preferably 1 nm to 50 μm, more preferably 3 nm to 30 μm, when measured with a volume average particle diameter laser diffraction particle size distribution analyzer. When the amount is within this range, a material having a better feeling of use can be obtained.
Examples of commercially available products include Cylisia 550, Cylicia 770, Cyrossphere C-1504 (manufactured by Fuji Silysia Chemical Co., Ltd.), AEROSIL200, AEROSIL300, AEROSILR972 (manufactured by Nippon Aerology Co., Ltd.), Nipsea E-220 (manufactured by Tosoh Silica Co., Ltd.), and the like. It is done. These silicic anhydrides can be used alone or in combination of two or more as required.
本発明の睫用化粧料への成分(C)粉体の配合量は、特に限定されないが、0.1〜60%が好ましく、更に好ましくは0.5〜45%である。この範囲であれば、着色でき、仕上がり時のベタツキがなく、均一で塗膜強度の高い皮膜が形成され、ツヤ感やカール力、そしてその持続性に優れたものが得られる。また、成分(C)粉体中に、無水ケイ酸を3〜100%、更に好ましくは、6〜40%含有することによって、仕上がりのべたつきのなさや睫への塗布しやすさを向上することができるため好ましい。 Although the compounding quantity of the component (C) powder to the cosmetics for wrinkles of this invention is not specifically limited, 0.1 to 60% is preferable, More preferably, it is 0.5 to 45%. If it is this range, it can color, there is no stickiness at the time of a finish, a uniform and high film | membrane intensity | strength film is formed, and the thing excellent in the glossiness, curl power, and the sustainability is obtained. Further, by containing 3 to 100%, more preferably 6 to 40%, of silicic acid anhydride in the component (C) powder, the non-stickiness of the finish and the ease of application to the cocoon are improved. Is preferable.
本発明の睫用化粧料は、前記成分(A)〜(C)の他に、通常化粧料に使用される成分、例えば、成分(B)以外の油性成分、繊維、皮膜形成性分散物、界面活性剤、水性成分、紫外線吸収剤、保湿剤、褪色防止剤、酸化防止剤、消泡剤、美容成分、防腐剤、香料、などを本発明の効果を損なわない範囲で適宜配合することができる。 In addition to the components (A) to (C), the vaginal cosmetics of the present invention are components that are usually used in cosmetics, for example, oily components other than the component (B), fibers, film-forming dispersions, A surfactant, an aqueous component, an ultraviolet absorber, a moisturizer, an anti-fading agent, an antioxidant, an antifoaming agent, a cosmetic component, an antiseptic, a fragrance, and the like may be appropriately added within a range not impairing the effects of the present invention. it can.
成分(B)以外の油性成分としては、動物油、植物油、合成油等の起源、及び、固形油、半固形油、液体油等の性状を問わず、炭化水素類、油脂類、ロウ類、硬化油類、エステル油類、脂肪酸類、高級アルコール類、シリコーン油類、フッ素系油類、ラノリン誘導体類、油性ゲル化剤類等が挙げられる。
具体的には、エチレン・プロピレンコポリマー、セレシン、マイクロクリスタリンワックス、流動パラフィン、スクワラン、ワセリン、ポリイソブチレン、ポリブテン等の炭化水素類、ロジン酸ペンタエリスリット等のテルペン系樹脂、トリメチルシロキシケイ酸、キャンデリラレジン(ここで、キャンデリラレジンとは、キャンデリラワックスを有機溶剤にて分別抽出して得られる樹脂分で、樹脂分が好ましくは65%以上、更に好ましくは85%以上の割合で含有されるものである。)、アクリル酸アルキルジメチコン共重合体、ポリ酢酸ビニル系樹脂、ポリビニルイソブチルエーテル、ポリイソブチレン等の油溶性の皮膜形成樹脂類、オリーブ油、ヒマシ油、ホホバ油、ミンク油、マカデミアンナッツ油等の油脂類、セチルイソオクタネート、ミリスチン酸イソプロピル、パルミチン酸イソプロピル、ミリスチン酸オクチルドデシル、トリオクタン酸グリセリル、ジイソステアリン酸ポリグリセリル、トリイソステアリン酸ジグリセリル、トリベヘン酸グリセリル、ジオクタン酸ネオペンチルグリコール、コレステロール脂肪酸エステル、N−ラウロイル−L−グルタミン酸ジ(コレステリル・ベヘニル・オクチルドデシル)等のエステル類、ステアリルアルコール、セチルアルコール、ラウリルアルコール、オレイルアルコール、イソステアリルアルコール、ベヘニルアルコール等の高級アルコール類、高重合度ジメチルポリシロキサン、メチルフェニルポリシロキサン、ポリエーテル変性ポリシロキサン、ポリオキシアルキレン・アルキルメチルポリシロキサン・メチルポリシロキサン共重合体、架橋型オルガノポリシロキサン、フッ素変性ポリシロキサン等のシリコーン類、ラノリン、酢酸ラノリン、ラノリン脂肪酸イソプロピル、ラノリンアルコール等のラノリン誘導体、デキストリン脂肪酸エステル、蔗糖脂肪酸エステル、デンプン脂肪酸エステル、イソステアリン酸アルミニウム、ステアリン酸カルシウム等の油性ゲル化剤類等が挙げられる。
Oily components other than component (B) include hydrocarbons, fats and oils, waxes, hardened, regardless of the origin of animal oils, vegetable oils, synthetic oils, and the properties of solid oils, semisolid oils, liquid oils, etc. Examples thereof include oils, ester oils, fatty acids, higher alcohols, silicone oils, fluorine-based oils, lanolin derivatives, and oily gelling agents.
Specifically, hydrocarbons such as ethylene-propylene copolymer, ceresin, microcrystalline wax, liquid paraffin, squalane, petrolatum, polyisobutylene, polybutene, terpene resins such as rosin pentaerythritol, trimethylsiloxysilicate, can Delilary Resin (Here, candelilla resin is a resin component obtained by fractional extraction of candelilla wax with an organic solvent. The resin content is preferably 65% or more, more preferably 85% or more. ), Alkyl dimethicone acrylate copolymers, polyvinyl acetate resins, polyvinyl isobutyl ether, polyisobutylene and other oil-soluble film-forming resins, olive oil, castor oil, jojoba oil, mink oil, macadamian Fats and oils such as nut oil, cetyl isoocta , Isopropyl myristate, isopropyl palmitate, octyldodecyl myristate, glyceryl trioctanoate, polyglyceryl diisostearate, diglyceryl triisostearate, glyceryl tribehenate, neopentyl glycol dioctanoate, cholesterol fatty acid ester, N-lauroyl-L- Esters such as diglutamate (cholesteryl, behenyl, octyldodecyl), stearyl alcohol, cetyl alcohol, lauryl alcohol, oleyl alcohol, isostearyl alcohol, higher alcohols such as behenyl alcohol, high degree of polymerization dimethylpolysiloxane, methylphenylpolysiloxane, Polyether-modified polysiloxane, polyoxyalkylene, alkylmethyl, polysiloxane, methyl Resiloxane copolymers, cross-linked organopolysiloxanes, silicones such as fluorine-modified polysiloxanes, lanolin, lanolin acetate, lanolin derivatives such as lanolin fatty acid isopropyl, lanolin alcohol, dextrin fatty acid ester, sucrose fatty acid ester, starch fatty acid ester, isostearin And oily gelling agents such as aluminum oxide and calcium stearate.
繊維としては、ナイロン、ポリプロピレン、ポリエステル等の合成繊維、レーヨン等の人造繊維、セルロース等の天然繊維、アセテート人絹等の半合成繊維等が挙げられ、これらは特に限定されるものではなく、必要に応じて1種または2種以上を用いることができる。
これらの繊維は、ポリエチレンテレフタレートとナイロンを層状に重ねた複合繊維のように、1種または2種以上の複合化したものを用いても良く、また、本発明の効果を妨げない範囲で、一般油剤、シリコーン油、フッ素化合物、界面活性剤等で処理したものも使用することができる。さらにロングラッシュ効果を得たい場合は上記繊維を配合して具現化することができる。
Examples of the fibers include synthetic fibers such as nylon, polypropylene, and polyester, artificial fibers such as rayon, natural fibers such as cellulose, semi-synthetic fibers such as acetate artificial silk, and the like. 1 type, or 2 or more types can be used according to.
These fibers may be used as a composite fiber in which polyethylene terephthalate and nylon are laminated in layers, or one or two or more composite fibers may be used. In the range not impeding the effects of the present invention, Those treated with an oil agent, a silicone oil, a fluorine compound, a surfactant or the like can also be used. Furthermore, when it is desired to obtain a long rush effect, the above fibers can be blended and embodied.
皮膜形成性分散物としては、皮膜形成能を持つ重合体を水性溶媒に乳化した状態であるものや、油性溶媒中に分散した状態であるもので、通常化粧料に使用されるものであれば特に制限されず、いずれのものも使用することができる。例えば、水性溶媒中に乳化した状態であるものは、アクリル酸アルキル共重合体エマルション、アクリル酸アルキル・スチレン共重合体エマルション、ポリ酢酸ビニルエマルション、ビニルピロリドン・スチレン共重合体エマルションが挙げられ、市販品としては、ヨドゾール32A707、ヨドゾールGH810F、ヨドゾールGH800F(日本エヌエスシー社製)、プレキシトールB−500(ROHM GMBH社製)、ヨドゾールGH41F(日本エヌエスシー社製)、ビニブラン1080、ビニブラン1128C、ビニブラン1080M、ビニブラン1080T、ビニブランGV−5651、ビニブラン1108S/W(日信化学工業株式会社)、ANTARA430(ISP社製)が挙げられる。また、油性溶媒中に分散した状態ものは、アクリル酸アルキル・スチレン共重合体エマルションが挙げられ、市販品としては、ニッセツU−3700A(日本カーバイド工業社製)が挙げられる。 As the film-forming dispersion, a polymer having film-forming ability is emulsified in an aqueous solvent or a polymer dispersed in an oil-based solvent, and is usually used in cosmetics. There is no particular limitation, and any of them can be used. Examples of emulsions in an aqueous solvent include alkyl acrylate copolymer emulsions, alkyl acrylate / styrene copolymer emulsions, polyvinyl acetate emulsions, and vinylpyrrolidone / styrene copolymer emulsions, which are commercially available. Products include iodosol 32A707, iodosol GH810F, iodosol GH800F (manufactured by NSC Japan), plexitol B-500 (manufactured by ROHM GMBH), iodosol GH41F (manufactured by NSC Japan), vinibran 1080, vinibran 1128C, vinibran 1080M. , Viniblanc 1080T, Vinibrand GV-5651, Vinibrand 1108S / W (Nissin Chemical Industry Co., Ltd.), ANTARA430 (produced by ISP). Moreover, the thing in the state disperse | distributed in the oil-based solvent includes an alkyl acrylate / styrene copolymer emulsion, and a commercially available product includes Nissetsu U-3700A (manufactured by Nippon Carbide Industries Co., Ltd.).
界面活性剤としては、化粧料一般に用いられている界面活性剤であればいずれのものも使用でき、非イオン性界面活性剤、アニオン性界面活性剤、カチオン性界面活性剤、両性界面活性剤等が挙げられる。非イオン界面活性剤としては、例えば、グリセリン脂肪酸エステル及びそのアルキレングリコール付加物、ポリグリセリン脂肪酸エステル及びそのアルキレングリコール付加物、プロピレングリコール脂肪酸エステル及びそのアルキレングリコール付加物、ソルビタン脂肪酸エステル及びそのアルキレングリコール付加物、ソルビトールの脂肪酸エステル及びそのアルキレングリコール付加物、ポリアルキレングリコール脂肪酸エステル、蔗糖脂肪酸エステル、ポリオキシアルキレンアルキルエーテル、グリセリンアルキルエーテル、ポリオキシエチレンアルキルフェニルエーテル、ポリオキシエチレン硬化ヒマシ油、ラノリンのアルキレングリコール付加物、ポリオキシアルキレンアルキル共変性シリコーン、ポリエーテル変性シリコーン等が挙げられる。アニオン界面活性剤としては、例えば、ステアリン酸、ラウリン酸のような脂肪酸の無機及び有機塩、アルキルベンゼン硫酸塩、アルキルスルホン酸塩、α−オレフィンスルホン酸塩、ジアルキルスルホコハク酸塩、α−スルホン化脂肪酸塩、アシルメチルタウリン塩、ポリオキシエチレンアルキルエーテル硫酸塩、ポリオキシエチレンアルキルフェニルエーテル硫酸塩、アルキル燐酸塩、ポリオキシエチレンアルキルエーテル燐酸塩、ポリオキシエチレンアルキルフェニルエーテル燐酸塩、N−アシルアミノ酸塩、ο−アルキル置換リンゴ酸塩、アルキルスルホコハク酸塩等が挙げられる。カチオン界面活性剤としては、例えば、アルキルアミン塩、ポリアミン及びアルカノールアミン脂肪酸誘導体、アルキル四級アンモニウム塩、環式四級アンモニウム塩等が挙げられる。両性界面活性剤としては、アミノ酸タイプやベタインタイプのカルボン酸型、硫酸エステル型、スルホン酸型、リン酸エステル型のものがあり、人体に対して安全とされるものが使用できる。例えば、N,N−ジメチル−N−アルキル−N−カルボキシルメチルアンモニウムベタイン、N,N−ジアルキルアミノアルキレンカルボン酸、N,N,N−トリアルキル−N−スルフォアルキレンアンモニウムベタイン、N,N−ジアルキル−N,N−ビス(ポリオキシエチレン硫酸)アンモニウムベタイン、2−アルキル−1−ヒドロキシエチル−1−カルボキシメチルイミダゾリニウムベタイン、レシチン等が挙げられる。 As the surfactant, any surfactant that is generally used in cosmetics can be used. Nonionic surfactants, anionic surfactants, cationic surfactants, amphoteric surfactants, etc. Is mentioned. Examples of the nonionic surfactant include glycerin fatty acid ester and its alkylene glycol adduct, polyglycerin fatty acid ester and its alkylene glycol adduct, propylene glycol fatty acid ester and its alkylene glycol adduct, sorbitan fatty acid ester and its alkylene glycol addition. Sorbitol fatty acid ester and its alkylene glycol adduct, polyalkylene glycol fatty acid ester, sucrose fatty acid ester, polyoxyalkylene alkyl ether, glycerin alkyl ether, polyoxyethylene alkyl phenyl ether, polyoxyethylene hydrogenated castor oil, lanolin alkylene Glycol adduct, polyoxyalkylene alkyl co-modified silicone, polyether-modified silicone And the like. Examples of the anionic surfactant include inorganic and organic salts of fatty acids such as stearic acid and lauric acid, alkylbenzene sulfate, alkyl sulfonate, α-olefin sulfonate, dialkyl sulfosuccinate, and α-sulfonated fatty acid. Salt, acylmethyl taurate, polyoxyethylene alkyl ether sulfate, polyoxyethylene alkyl phenyl ether sulfate, alkyl phosphate, polyoxyethylene alkyl ether phosphate, polyoxyethylene alkyl phenyl ether phosphate, N-acyl amino acid salt , O-alkyl substituted malates, alkylsulfosuccinates and the like. Examples of the cationic surfactant include alkylamine salts, polyamines and alkanolamine fatty acid derivatives, alkyl quaternary ammonium salts, and cyclic quaternary ammonium salts. Examples of amphoteric surfactants include amino acid type and betaine type carboxylic acid types, sulfate ester types, sulfonic acid types, and phosphate ester types, and those that are safe for the human body can be used. For example, N, N-dimethyl-N-alkyl-N-carboxylmethylammonium betaine, N, N-dialkylaminoalkylene carboxylic acid, N, N, N-trialkyl-N-sulfoalkylene ammonium betaine, N, N- Examples include dialkyl-N, N-bis (polyoxyethylene sulfate) ammonium betaine, 2-alkyl-1-hydroxyethyl-1-carboxymethylimidazolinium betaine, and lecithin.
水性成分としては、水に可溶な成分であれば何れでもよく、例えば、エチルアルコール、イソプロピルアルコール等のアルコール類、プロピレングリコール、1,3−ブチレングリコール、ジプロピレングリコール、ポリエチレングリコール等のグリコール類、グリセリン、ジグリセリン、ポリグリセリン等のグリセロール類、ソルビトール、マルチトール、ショ糖、でんぷん糖、ラクチトール等の糖類、グアーガム、コンドロイチン硫酸ナトリウム、ヒアルロン酸ナトリウム、アラビアガム、アルギン酸ナトリウム、カラギーナン、メチルセルロース、ヒドロキシエチルセルロース、カルボキシメチルセルロース、カルボキシビニルポリマー、ポリビニルアルコール、ポリビニルピロリドン、ポリアクリル酸ナトリウム等の水溶性高分子、塩化ナトリウム、塩化マグネシウム、乳酸ナトリウム等の塩類、アロエベラ、ウィッチヘーゼル、ハマメリス、キュウリ、レモン、ラベンダー、ローズ等の植物抽出液等及び水が挙げられる。 The aqueous component may be any component that is soluble in water, for example, alcohols such as ethyl alcohol and isopropyl alcohol, glycols such as propylene glycol, 1,3-butylene glycol, dipropylene glycol, and polyethylene glycol. Glycerols such as glycerin, diglycerin, polyglycerin, saccharides such as sorbitol, maltitol, sucrose, starch sugar, lactitol, guar gum, sodium chondroitin sulfate, sodium hyaluronate, gum arabic, sodium alginate, carrageenan, methylcellulose, hydroxy Water-soluble polymers such as ethyl cellulose, carboxymethyl cellulose, carboxyvinyl polymer, polyvinyl alcohol, polyvinyl pyrrolidone, sodium polyacrylate, Sodium, magnesium chloride, salts such as sodium lactate, aloe vera, witch hazel, hamamelis, cucumber, lemon, lavender, plant extracts, etc. and water rose like.
紫外線吸収剤としては、例えばベンゾフェノン系、PABA系、ケイ皮酸系、サリチル酸系、4−tert−ブチル−4’−メトキシジベンゾイルメタン、オキシベンゾン等、保湿剤としては、例えばタンパク質、ムコ多糖、コラーゲン、エラスチン、ケラチン等、酸化防止剤としては、例えばα−トコフェロール、アスコルビン酸等、美容成分としては、例えばビタミン類、消炎剤、生薬等、防腐剤としては、例えばパラオキシ安息香酸エステル、1,2−ペンタンジオール、フェノキシエタノール等が挙げられる。 Examples of ultraviolet absorbers include benzophenone-based, PABA-based, cinnamic acid-based, salicylic acid-based, 4-tert-butyl-4'-methoxydibenzoylmethane, and oxybenzone. Examples of humectants include protein, mucopolysaccharide, and collagen. , Elastin, keratin, etc., antioxidants such as α-tocopherol, ascorbic acid, etc., cosmetic ingredients such as vitamins, anti-inflammatory agents, herbal medicines, etc., preservatives such as paraoxybenzoic acid esters, 1, 2 -Pentanediol, phenoxyethanol and the like.
本発明の睫用化粧料としては、例えば、マスカラ、マスカラオーバーコート、マスカラ下地等が挙げられ、剤型としては、油性、油中水、水中油型が挙げられ、油性型が好ましい。形態としては液状、半固形状等が挙げられる。本発明における油性型とは、液状、半固形状または固形状の油剤や油溶性化合物である油性成分を連続相とする化粧料で、実質的に水を含まないものである。 Examples of the cosmetic for wrinkles of the present invention include mascara, mascara overcoat, and mascara base. Examples of dosage forms include oily, water-in-oil, and oil-in-water types, and an oily type is preferred. Examples of the form include liquid and semi-solid forms. The oily mold in the present invention is a cosmetic having a continuous phase of an oily component that is a liquid, semi-solid or solid oil agent or oil-soluble compound, and is substantially free of water.
本発明の睫用化粧料の製造方法は特に限定されるものではないが、例えば、成分(A)、(B)を含む油性成分と成分(C)の粉体を110℃程度で加熱混合したものを混練後、容器に充填することにより得ることができる。 Although the manufacturing method of the cosmetics for candy of this invention is not specifically limited, For example, the oil-based component containing a component (A) and (B) and the powder of a component (C) were heat-mixed at about 110 degreeC. It can be obtained by kneading and filling the container.
以下に、成分(A)の製造例、実施例を挙げて本発明を更に説明する。なお、これらは本発明を何ら限定するものではない。 The present invention will be further described below with reference to production examples and examples of component (A). In addition, these do not limit this invention at all.
(製造例1)
[シクロアルキル基含有アクリル系共重合体(1)]
還流冷却器、温度計、窒素導入管及び攪拌装置を取り付けた四つ口のセパラブルフラスコ(以下、単に「フラスコ」ともいう。)にシクロヘキシルメタクリレート22.5g、2−エチルヘキシルメタクリレート7.5g及びトルエン70gを添加し、窒素ガスを導入して充分に窒素雰囲気にした後、100℃まで加温し、α,α’−アゾビスイソブチロニトリル(以下、AIBNとする)0.15gを添加して3時間還流し重合させた。得られた反応物にメタノールを注入してアクリル系共重合体を沈殿析出させ、沈殿物を濾別後、真空乾燥してシクロアルキル基含有アクリル系共重合体固形分27.4gを得た。ポリスチレン換算による重量平均分子量は5.0×104であった。
(Production Example 1)
[Cycloalkyl group-containing acrylic copolymer (1)]
A four-necked separable flask (hereinafter simply referred to as “flask”) equipped with a reflux condenser, a thermometer, a nitrogen inlet tube and a stirrer was added 22.5 g of cyclohexyl methacrylate, 7.5 g of 2-ethylhexyl methacrylate and toluene. 70 g was added, and nitrogen gas was introduced to make the atmosphere sufficiently nitrogen, and then heated to 100 ° C., and 0.15 g of α, α′-azobisisobutyronitrile (hereinafter referred to as AIBN) was added. The mixture was refluxed for 3 hours for polymerization. Methanol was injected into the resulting reaction product to precipitate an acrylic copolymer, and the precipitate was filtered off and dried under vacuum to obtain 27.4 g of a solid content of cycloalkyl group-containing acrylic copolymer. The weight average molecular weight in terms of polystyrene was 5.0 × 10 4 .
(製造例2)
[シクロアルキル基含有アクリル系共重合体(2)]
上記フラスコにシクロヘキシルメタクリレート15g、2−エチルヘキシルメタクリレート15g及びトルエン70gを添加し、窒素ガスを導入して充分に窒素雰囲気にした後、100℃まで加温し、AIBN0.15gを添加して3時間還流し重合させた。得られた反応物にメタノールを注入してアクリル系共重合体を沈殿析出させ、沈殿物を濾別後、真空乾燥してシクロアルキル基含有アクリル系共重合体固形分25.5gを得た。ポリスチレン換算による重量平均分子量は3.7×104であった。
(Production Example 2)
[Cycloalkyl group-containing acrylic copolymer (2)]
Add 15 g of cyclohexyl methacrylate, 15 g of 2-ethylhexyl methacrylate, and 70 g of toluene to the flask, introduce nitrogen gas to make a nitrogen atmosphere, then heat to 100 ° C., add 0.15 g of AIBN, and reflux for 3 hours. And polymerized. Methanol was injected into the obtained reaction product to precipitate an acrylic copolymer, and the precipitate was filtered off and dried under vacuum to obtain 25.5 g of a cycloalkyl group-containing acrylic copolymer solid content. The weight average molecular weight in terms of polystyrene was 3.7 × 10 4 .
(製造例3)
[シクロアルキル基含有アクリル系共重合体(3)]
上記フラスコにシクロヘキシルメタクリレート21g、2−エチルへキシルメタクリレート9g及びトルエン70gを添加し、窒素ガスを導入して充分に窒素雰囲気にした後、100℃まで加温し、AIBN0.15gを添加して3時間還流し重合させた。得られた反応物にメタノールを注入してアクリル系共重合体を沈殿析出させ、沈殿物を濾別後、真空乾燥してシクロアルキル基含有アクリル系共重合体固形分を23.8g得た。ポリスチレン換算による重量平均分子量は4.7×104であった。
(Production Example 3)
[Cycloalkyl group-containing acrylic copolymer (3)]
21 g of cyclohexyl methacrylate, 9 g of 2-ethylhexyl methacrylate and 70 g of toluene were added to the flask, and after introducing nitrogen gas to make a nitrogen atmosphere sufficiently, the mixture was heated to 100 ° C. and 0.15 g of AIBN was added. The mixture was refluxed for a period of time for polymerization. Methanol was injected into the obtained reaction product to precipitate an acrylic copolymer, and the precipitate was filtered off and dried under vacuum to obtain 23.8 g of a cycloalkyl group-containing acrylic copolymer solid. The weight average molecular weight in terms of polystyrene was 4.7 × 10 4 .
(製造例4)
[シクロアルキル基含有アクリル系共重合体(4)]
上記フラスコにシクロヘキシルメタクリレート22.5g、下記式(3)のメタクリル変性ジメチルポリシロキサンマクロモノマー7.5g及びトルエン70gを添加し、窒素ガスを導入して充分に窒素雰囲気にした後、80℃まで加温し、AIBN0.15gを添加して5時間還流し重合させた。得られた反応物にメタノールを注入してアクリル系共重合体を沈殿析出させ、沈殿物を濾別後、真空乾燥してシクロアルキル基含有アクリル系共重合体固形分13.4gを得た。ポリスチレン換算による重量平均分子量は5.2×104であった。
(Production Example 4)
[Cycloalkyl group-containing acrylic copolymer (4)]
Add 22.5 g of cyclohexyl methacrylate, 7.5 g of methacryl-modified dimethylpolysiloxane macromonomer of the following formula (3) and 70 g of toluene to the above flask, introduce nitrogen gas into a nitrogen atmosphere, and heat up to 80 ° C. Warm, 0.15 g of AIBN was added and refluxed for 5 hours for polymerization. Methanol was injected into the obtained reaction product to precipitate an acrylic copolymer, and the precipitate was filtered and dried under vacuum to obtain 13.4 g of a solid content of cycloalkyl group-containing acrylic copolymer. The weight average molecular weight in terms of polystyrene was 5.2 × 10 4.
(製造例5)
[シクロアルキル基含有アクリル系共重合体(5)]
上記フラスコにシクロヘキシルメタクリレート22.5g、下記式(4)のメタクリル変性ジメチルポリシロキサンマクロモノマー7.5g及びトルエン70gを添加して、窒素ガスを導入して充分に窒素雰囲気にした後、100℃まで加温し、AIBN0.15gを添加して3時間還流し重合させた。得られた反応物をエバポレーションにてトルエンを留去後、真空乾燥してシクロアルキル基含有アクリル系共重合体固形分26.6gを得た。ポリスチレン換算による重量平均分子量は6.7×104であった。
(Production Example 5)
[Cycloalkyl group-containing acrylic copolymer (5)]
After adding 22.5 g of cyclohexyl methacrylate, 7.5 g of methacryl-modified dimethylpolysiloxane macromonomer of the following formula (4) and 70 g of toluene to the flask and introducing nitrogen gas to make a nitrogen atmosphere sufficiently, the temperature reaches 100 ° C. The mixture was warmed, 0.15 g of AIBN was added, and the mixture was refluxed for 3 hours for polymerization. Toluene was distilled off from the obtained reaction product by evaporation, followed by vacuum drying to obtain 26.6 g of a cycloalkyl group-containing acrylic copolymer solid content. The weight average molecular weight in terms of polystyrene was 6.7 × 10 4 .
(製造例6)
[シクロアルキル基含有アクリル系共重合体(6)]
上記フラスコにシクロヘキシルメタクリレート22.5g、下記式(5)のメタクリル変性ジメチルポリシロキサンマクロモノマー7.5g及びトルエン70gを添加し、窒素ガスを導入して充分に窒素雰囲気にした後、80℃まで加温し、AIBN0.15gを添加して5時間還流し重合させた。得られた反応物にメタノールを注入してアクリル系共重合体を沈殿析出させ、沈殿物を濾別後、真空乾燥してシクロアルキル基含有アクリル系共重合体固形分29.1gを得た。
(Production Example 6)
[Cycloalkyl group-containing acrylic copolymer (6)]
Add 22.5 g of cyclohexyl methacrylate, 7.5 g of methacryl-modified dimethylpolysiloxane macromonomer of the following formula (5) and 70 g of toluene to the above flask, introduce nitrogen gas into a nitrogen atmosphere, and heat up to 80 ° C. Warm, 0.15 g of AIBN was added and refluxed for 5 hours for polymerization. Methanol was injected into the obtained reaction product to precipitate an acrylic copolymer, and the precipitate was filtered off and dried under vacuum to obtain 29.1 g of a solid content of cycloalkyl group-containing acrylic copolymer.
(製造例7)
[シクロアルキル基含有アクリル系共重合体(7)]
上記フラスコにシクロヘキシルメタクリレート21g、2−エチルヘキシルメタクリレート4.5g、上記式(4)のメタクリル変性ジメチルポリシロキサンマクロモノマー4.5g及びトルエン70gを添加し、窒素ガスを導入して充分に窒素雰囲気にした後、80℃まで加温し、AIBN0.15gを添加して5時間還流し重合させた。得られた反応物にメタノールを注入してアクリル系共重合体を沈殿析出させ、沈殿物を濾別後、真空乾燥してシクロアルキル基含有アクリル系共重合体固形分11.0gを得た。ポリスチレン換算による重量平均分子量は6.2×104であった。
(Production Example 7)
[Cycloalkyl group-containing acrylic copolymer (7)]
To the flask, 21 g of cyclohexyl methacrylate, 4.5 g of 2-ethylhexyl methacrylate, 4.5 g of methacryl-modified dimethylpolysiloxane macromonomer of the above formula (4) and 70 g of toluene were added, and nitrogen gas was introduced to make a nitrogen atmosphere sufficiently. Thereafter, the mixture was heated to 80 ° C., 0.15 g of AIBN was added, and the mixture was refluxed for 5 hours for polymerization. Methanol was injected into the obtained reaction product to precipitate an acrylic copolymer, and the precipitate was filtered and dried under vacuum to obtain 11.0 g of a cycloalkyl group-containing acrylic copolymer solid content. The weight average molecular weight in terms of polystyrene was 6.2 × 10 4 .
(製造例8)
その他、シクロヘキシルメタクリレート50%と上記式(4)のメタクリル変性ジメチルポリシロキサンマクロモノマー50%、シクロヘキシルメタクリレート50%とラウリルメタクリレート50%、シクロヘキシルメタクリレート75%とラウリルメタクリレート25%、シクロヘキシルメタクリレート60%と2−エチルヘキシルメタクリレート40%、及び、シクロヘキシルメタクリレートとn=150、R1がCH3基、R2がC4H9基である式(2)のメタクリル変性ジメチルポリシロキサンマクロモノマーの各組合せを原料として、上記合成方法に従って合成を行ったところ、シクロアルキル基含有アクリル系共重合体を得ることができた。
(Production Example 8)
In addition, 50% cyclohexyl methacrylate and 50% methacryl-modified dimethylpolysiloxane macromonomer of the above formula (4), 50% cyclohexyl methacrylate and 50% lauryl methacrylate, 75% cyclohexyl methacrylate and 25% lauryl methacrylate, 60% cyclohexyl methacrylate and 2- Starting from 40% ethylhexyl methacrylate and each combination of cyclohexyl methacrylate and methacryl-modified dimethylpolysiloxane macromonomer of formula (2) in which n = 150, R 1 is a CH 3 group, and R 2 is a C 4 H 9 group, When the synthesis was carried out according to the above synthesis method, a cycloalkyl group-containing acrylic copolymer could be obtained.
以下に実施例を挙げて本発明を更に説明する。なお、これらは本発明を何ら限定するものではない。 The following examples further illustrate the present invention. In addition, these do not limit this invention at all.
実施例1〜5及び比較例1〜3:マスカラ(油性型液状)
表1に示す処方のマスカラを下記製法により調製し、ツヤ感、カールアップ効果、カールキープ効果、化粧膜の均一性について下記の方法により官能評価を行った。その結果も併せて表1に示す。
Examples 1-5 and Comparative Examples 1-3: Mascara (oil-based liquid)
Mascara having the formulation shown in Table 1 was prepared by the following production method, and sensory evaluation was performed by the following method for glossiness, curl-up effect, curl-keep effect, and uniformity of the decorative film. The results are also shown in Table 1.
*1:IPソルベント1620(出光興産社製)
*2:製造例1で得られたシクロアルキル基含有アクリル系共重合体(1)を軽質流動イソパラフィン(IPソルベント1620)に溶解し、40%溶液としたもの
*3:シリコンKF−9021(信越化学工業社製)(固形分50%デカメチルシクロペンタシロキサン溶液)
*4:エステルガムHP(荒川化学工業社製)
*5:ニッセツU−3700A(日本カーバイド工業社製)(固形分50%軽質流動イソパラフィン溶液)
*6:ベントン38V BC(ELEMENTIS社製)
*7:AEROSIL 300(日本アエロジル社製)
* 1: IP solvent 1620 (made by Idemitsu Kosan Co., Ltd.)
* 2: A cycloalkyl group-containing acrylic copolymer (1) obtained in Production Example 1 was dissolved in light liquid isoparaffin (IP solvent 1620) to give a 40% solution. * 3: Silicon KF-9021 (Shin-Etsu) (Made by Chemical Industry Co., Ltd.)
* 4: Esther gum HP (Arakawa Chemical Industries)
* 5: Nissetsu U-3700A (manufactured by Nippon Carbide Industries Co., Ltd.) (light liquid isoparaffin solution with a solid content of 50%)
* 6: Benton 38V BC (manufactured by ELEMENTIS)
* 7: AEROSIL 300 (Nippon Aerosil Co., Ltd.)
(製法)
実施例1〜5及び比較例1〜3
A.成分(1)〜(7)を110℃まで加熱し、均一に溶解する。
B.Aに成分(8)〜(12)を加え、均一に混合する。
C.Bを冷却後、容器に充填し製品とする。
(Manufacturing method)
Examples 1-5 and Comparative Examples 1-3
A. Ingredients (1) to (7) are heated to 110 ° C. and dissolved uniformly.
B. Add components (8) to (12) to A and mix uniformly.
C. After cooling B, it is filled into a container to obtain a product.
(評価方法)
10名の官能評価パネルにより、各試料を下記イ〜ホの評価項目について、(1)絶対評価基準を用いて7段階に評価し、各試料の評点の平均値を(2)4段階判定基準を用いて判定した。尚、表1には、判定と( )内に評点の平均値を記載した。
尚、評価項目ロは塗布直後を評価し、評価項目イ、ハ、ニ、ホについては、試料を睫に塗布し、パネルに通常の生活をしてもらい、12時間後の化粧効果について評価した。
(評価項目)
イ.ツヤ感の持続性
ロ.カールアップ効果
ハ.カールキープ効果
ニ.ボリューム効果の持続性
ホ.化粧膜の均一性の持続性
(1)絶対評価基準
(評点):(評価)
6:非常に良い
5:良い
4:やや良い
3:普通
2:やや悪い
1:悪い
0:非常に悪い
(2)4段階判定基準
(平均点) :(判定)
5点を超える :非常に良好:◎
3点を超えて5点以下:良好 :○
1点を超えて3点以下:やや不良 :△
1点以下 :不良 :×
(Evaluation methods)
Using the sensory evaluation panel of 10 persons, each sample was evaluated on the following evaluation items (i) to (e) by (1) using 7 absolute evaluation criteria, and (2) 4-step criteria for the average score of each sample. Was used to determine. In Table 1, the average value of the evaluation and the score is shown in parentheses.
The evaluation item B was evaluated immediately after application, and for the evaluation items A, C, D, and E, the sample was applied to the bag and the panel was allowed to live a normal life, and the cosmetic effect after 12 hours was evaluated. .
(Evaluation item)
I. Persistence of glossiness b. Curl-up effect c. Curl keep effect d. Persistence of volume effect e. Persistence of cosmetic film uniformity (1) Absolute evaluation criteria (score): (Evaluation)
6: Very good 5: Good 4: Somewhat good 3: Normal 2: Somewhat bad 1: Bad 0: Very bad (2) Four-step criteria (average point): (Judgment)
More than 5 points: Very good: ◎
3 points to 5 points or less: Good: ○
More than 1 point and 3 points or less: Somewhat bad: △
1 point or less: Defect: ×
表1の結果から明らかなように、本発明品である実施例1〜5のマスカラは、非常に塗布しやすく、付着性も良く、塗布直後から化粧膜は均一でツヤ感があり、カールアップ効果も得られ、これらの持続性にとても優れたものであった。特に実施例5はボリューム効果もかなりあるものであった。
一方、シクロアルキル基含有アクリル系共重合体溶液の代わりに、トリメチルシロキシケイ酸溶液を使用している比較例1では、強固な化粧膜は得られるが、柔軟性が得られないため、経時で化粧膜の均一性が低下することにより、ツヤ感やカールキープ効果、化粧膜の均一性の点で満足のいくものが得られず、さらに付着力も低いため、ボリューム効果も満足のいくものが得られなかった。
また、シクロアルキル基含有アクリル系共重合体の代わりに、ロジン酸ペンタエリスリトールを使用している比較例2では、化粧膜にベタツキがあるため、睫同士が束付きすることで、化粧膜の均一性が低下し、ツヤ感も劣る結果となった。また、付着力が高すぎるため、睫が重く下がってくるため、カールキープ効果の点でも満足のいくものが得られなかった。
さらに、シクロアルキル基含有アクリル系共重合体溶液の代わりに、アクリル−スチレン共重合樹脂の軽質流動イソパラフィン分散物を使用している比較例3では、滑らかな使用性に欠けるため、均一に付着させることが困難で、化粧膜の均一性やツヤ感の点で満足のいくものが得られなかった。さらに、化粧膜の強度も不十分なため、カールアップ効果やカールキープ効果といった化粧効果そして、その持続性の点でも満足のいくものが得られなかった。
As is apparent from the results in Table 1, the mascara of Examples 1 to 5 which are the products of the present invention are very easy to apply and have good adhesion, and the cosmetic film is uniform and glossy immediately after application, curling up. An effect was also obtained, and these were very excellent in sustainability. In particular, Example 5 had a considerable volume effect.
On the other hand, in Comparative Example 1 using a trimethylsiloxysilicic acid solution instead of a cycloalkyl group-containing acrylic copolymer solution, a strong decorative film can be obtained, but flexibility cannot be obtained. As the uniformity of the decorative film is reduced, it is not possible to obtain satisfactory results in terms of gloss, curl-keep effect, and uniformity of the decorative film, and since the adhesion is also low, the volume effect is also satisfactory. It was not obtained.
In Comparative Example 2 in which pentaerythritol rosin acid is used instead of the cycloalkyl group-containing acrylic copolymer, the decorative film has a stickiness. As a result, the properties were lowered and the glossiness was inferior. In addition, since the adhesive force is too high, the wrinkles are heavier and lower, so that a satisfactory curl keeping effect cannot be obtained.
Further, in Comparative Example 3 in which a light fluid isoparaffin dispersion of an acrylic-styrene copolymer resin is used instead of the cycloalkyl group-containing acrylic copolymer solution, since the smooth usability is insufficient, it is adhered uniformly. It was difficult to obtain a satisfactory cosmetic film in terms of uniformity and gloss. Further, since the strength of the decorative film is insufficient, a satisfactory cosmetic effect such as a curl-up effect and a curl-keep effect and its sustainability cannot be obtained.
また、実施例1のマスカラを重ね付けする(連続して10回塗布具で塗布する)と、化粧膜の均一性やカールキープ効果を損なうことなく、ボリューム効果も得ることができたが、比較例1、2、3を重ね付けすると、化粧膜のベタツキが強すぎ、睫同士が束付きし、化粧膜の均一性が得られなかったり、化粧膜の柔軟性も低いことから、使用感も悪いものとなった。 In addition, when the mascara of Example 1 was overlaid (applied continuously with the applicator 10 times), the volume effect could be obtained without impairing the uniformity of the decorative film and the curl keeping effect. When Examples 1, 2, and 3 are overlapped, the stickiness of the decorative film is too strong, the wrinkles are bundled together, the uniformity of the decorative film is not obtained, and the flexibility of the decorative film is low, so the feeling of use is also good It was bad.
実施例1で用いたシクロアルキル基含有アクリル系共重合体溶液のかわりに、製造例2〜7で得られたシクロアルキル基含有アクリル系共重合体(2)〜(7)を軽質流動イソパラフィン(IPソルベント1620)に溶解し、40%溶液としたものを用い、実施例1と同様の製造方法で得たマスカラを評価したところ、化粧膜の均一性が高くツヤ感があり、カールキープ効果も得られ、これらの持続性にも優れるものであった。表2に処方とその結果を示す。 Instead of the cycloalkyl group-containing acrylic copolymer solution used in Example 1, the cycloalkyl group-containing acrylic copolymers (2) to (7) obtained in Production Examples 2 to 7 were used as light liquid isoparaffins ( When the mascara obtained by dissolving in the IP solvent 1620) to give a 40% solution was evaluated by the same production method as in Example 1, the uniformity of the decorative film was high and the glossy feeling was obtained, and the curl keeping effect was also obtained. It was obtained and excellent in sustainability. Table 2 shows the formulation and the results.
以下の実施例12〜15についても、実施例1〜5、比較例1〜3と同様に評価した。
実施例12:マスカラ(水中油乳化型液状)
(成分) (%)
(1)ステアリン酸 3
(2)カルナウバワックス 1
(3)ミツロウ 1
(4)パラフィンワックス 1
(5)シクロアルキル基含有アクリル系共重合体溶液 *8 10
(6)軽質流動イソパラフィン *1 0.5
(7)自己乳化型モノステアリン酸グリセリン 1
(8)ショ糖脂肪酸エステル *9 2
(9)モノオレイン酸ポリオキシエチレンソルビタン(20E.O.) 1.3
(10)セスキオレイン酸ソルビタン 0.5
(11)黒酸化鉄 5
(12)無水ケイ酸 *10 0.1
(13)無水ケイ酸 *11 0.1
(14)トリエタノールアミン 1.2
(15)1,3−ブチレングリコール 8
(16)1,2−ペンタンジオール 0.1
(17)パラオキシ安息香酸メチル 0.2
(18)ポリアクリル酸アルキル共重合体エマルション *12 10
(19)ポリ酢酸ビニルエマルション *13 0.5
(20)美容剤(シャクヤクエキス) 0.03
(21)精製水 残量
*8:製造例4で得られたシクロアルキル基含有アクリル系共重合体(4)を軽質流動イソパラフィン(IPソルベント1620)に溶解し、20%溶液としたもの
*9:シュガーワックスS−10E(第一工業製薬社製)
*10:サイリシア550(富士シリシア化学社製)
*11:ニップシールE―220(日本シリカ工業社製)
*12:YODOZOL GH810F(固形分50%)(日本エヌエスシー社製)
*13:ビニブランGV−5651(固形分40%)(日信化学工業社製)
(製法)
A.成分(1)〜(10)を110℃に加熱溶解し、成分(11)を加え、均一に混合する。
B.成分(12)〜(21)を加温し、均一に混合する。
C.AにBを加え、80℃で乳化する。
D.Cを冷却し、容器に充填して製品とする。
以上のようにして得られた実施例12の水中油乳化型のマスカラは、化粧膜の均一性に優れ、ツヤ感、カール効果、ボリューム感という化粧効果及びその持続性に優れたものであった。
The following Examples 12 to 15 were also evaluated in the same manner as Examples 1 to 5 and Comparative Examples 1 to 3.
Example 12: Mascara (oil-in-water emulsified liquid)
(Ingredient) (%)
(1) Stearic acid 3
(2) Carnauba wax 1
(3) Beeswax 1
(4) Paraffin wax 1
(5) Cycloalkyl group-containing acrylic copolymer solution * 8 10
(6) Light liquid isoparaffin * 1 0.5
(7) Self-emulsifying glyceryl monostearate 1
(8) Sucrose fatty acid ester * 9 2
(9) Polyoxyethylene sorbitan monooleate (20E.O.) 1.3
(10) Sorbitan sesquioleate 0.5
(11) Black iron oxide 5
(12) Silicic anhydride * 10 0.1
(13) Silicic anhydride * 11 0.1
(14) Triethanolamine 1.2
(15) 1,3-butylene glycol 8
(16) 1,2-pentanediol 0.1
(17) Methyl paraoxybenzoate 0.2
(18) Polyalkyl acrylate copolymer emulsion * 12 10
(19) Polyvinyl acetate emulsion * 13 0.5
(20) Beauty agent (peony extract) 0.03
(21) Purified water Residual amount * 8: Dissolved cycloalkyl group-containing acrylic copolymer (4) obtained in Production Example 4 in light liquid isoparaffin (IP solvent 1620) to give a 20% solution * 9 : Sugar wax S-10E (Daiichi Kogyo Seiyaku Co., Ltd.)
* 10: Silicia 550 (Fuji Silysia Chemical)
* 11: Nip seal E-220 (manufactured by Nippon Silica Industry Co., Ltd.)
* 12: YODOZOL GH810F (solid content 50%) (made by NSC Japan)
* 13: Vinibrand GV-5651 (solid content 40%) (manufactured by Nissin Chemical Industry Co., Ltd.)
(Manufacturing method)
A. Components (1) to (10) are heated and dissolved at 110 ° C., and component (11) is added and mixed uniformly.
B. Ingredients (12)-(21) are warmed and mixed uniformly.
C. Add B to A and emulsify at 80 ° C.
D. C is cooled and filled into a container to obtain a product.
The oil-in-water emulsified mascara of Example 12 obtained as described above was excellent in the uniformity of the cosmetic film, and was excellent in the cosmetic effect of glossiness, curl effect, volume feeling and its sustainability. .
実施例13:マスカラ(油性型液状)(ロングラッシュタイプ)
(成分) (%)
(1)シクロアルキル基含有アクリル系共重合体溶液 *2 48.6
(2)キャンデリラレジン *14 3
(3)軽質流動イソパラフィン *1 残量
(4)パルミチン酸デキストリン 1.4
(5)マイクロクリスタリンワックス 2
(6)セレシン 3
(7)ミツロウ 2
(8)トリメチルシロキシケイ酸溶液 *3 1
(9)ジメチルジステアリルアンモニウムヘクトライト *6 10
(10)無水ケイ酸 *10 7
(11)無水ケイ酸 *11 3
(12)フッ素系化合物処理黒酸化鉄 *15 5
(13)フッ素系化合物処理タルク *15 5
(14)ナイロン繊維 *16 3
*14:キャンデリラ樹脂E−1(日本ナチュラルプロダクツ社製)
*15:フルオロアルキルアルコキシシラン3%処理
*16:ナイロンファイバー6.3T−2MM(中部パイル社製)
(製法)
A.成分(4)〜(8)を90℃に加熱混合し、成分(1)〜(3)を加え、110℃に加熱溶解する。
B.Aに成分(9)を加え、混合する。
C.Bに成分(10)〜(14)を加え、均一に混合する。
D.Cを冷却して、容器に充填し製品とする。
以上のようにして得られた実施例13の油性型マスカラは、化粧膜の均一性に優れ、ツヤ感、カール効果、ロングラッシュ効果、ボリューム効果という化粧効果及びその持続性に優れたものであった。
Example 13: Mascara (oil-based liquid) (long rush type)
(Ingredient) (%)
(1) Cycloalkyl group-containing acrylic copolymer solution * 2 48.6
(2) Candelilla resin * 14 3
(3) Light liquid isoparaffin * 1 Remaining amount (4) Dextrin palmitate 1.4
(5) Microcrystalline wax 2
(6) Ceresin 3
(7) Beeswax 2
(8) Trimethylsiloxysilicate solution * 3 1
(9) Dimethyl distearyl ammonium hectorite * 6 10
(10) Silicic anhydride * 10 7
(11) Silicic acid anhydride * 11 3
(12) Fluorine compound-treated black iron oxide * 15 5
(13) Fluorine compound-treated talc * 15 5
(14) Nylon fiber * 16 3
* 14: Candelilla resin E-1 (Nippon Natural Products)
* 15: Treatment with 3% fluoroalkylalkoxysilane * 16: Nylon fiber 6.3T-2MM (manufactured by Chubu Pile Co., Ltd.)
(Manufacturing method)
A. Components (4) to (8) are heated and mixed at 90 ° C., components (1) to (3) are added, and heated and dissolved at 110 ° C.
B. Add component (9) to A and mix.
C. Add components (10) to (14) to B and mix uniformly.
D. C is cooled and filled into a container to obtain a product.
The oily mascara of Example 13 obtained as described above was excellent in the uniformity of the cosmetic film, and was excellent in the cosmetic effect such as gloss, curl effect, long rush effect, volume effect and its sustainability. It was.
実施例14:マスカラ(油中水乳化型液状)
(成分) (%)
(1)デカメチルシクロペンタシロキサン 5
(2)軽質流動イソパラフィン *1 5
(3)シクロアルキル基含有アクリル系共重合体溶液 *2 12.5
(4)PEG−9ポリジメチルシロキシエチルジメチコン *17 2
(5)ジメチルジステアリルアンモニウムヘクトライト *6 5
(6)無水ケイ酸 *10 3
(7)シリコーン系化合物処理黒酸化鉄 *18 5
(8)タルク 5
(9)ポリアクリル酸アルキル共重合体エマルション *12 10
(10)ポリ酢酸ビニルエマルション *13 10
(11)1,3−ブチレングリコール 7
(12)パラオキシ安息香酸メチル 0.1
(13)精製水 残量
*17:KF−6028P(信越化学工業社製)
*18:ジメチルポリシロキサン4%処理
(製法)
A.成分(1)〜(4)を均一に混合する。
B.Aに成分(5)〜(8)を加え、混合する。
C.Bに成分(9)〜(13)を加え、常温で乳化する。
D.Cを冷却し、容器に充填して製品とする。
以上のようにして得られた実施例14の油中水乳化型のマスカラは、化粧膜の均一性に優れ、ツヤ感、カール効果、ボリューム効果という化粧効果及びその持続性に優れたものであった。
Example 14: Mascara (water-in-oil emulsified liquid)
(Ingredient) (%)
(1) Decamethylcyclopentasiloxane 5
(2) Light liquid isoparaffin * 1 5
(3) Cycloalkyl group-containing acrylic copolymer solution * 2 12.5
(4) PEG-9 polydimethylsiloxyethyl dimethicone * 172
(5) Dimethyl distearyl ammonium hectorite * 6 5
(6) Silicic acid anhydride * 10 3
(7) Silicone compound-treated black iron oxide * 18 5
(8) Talc 5
(9) Polyalkyl acrylate copolymer emulsion * 12 10
(10) Polyvinyl acetate emulsion * 13 10
(11) 1,3-butylene glycol 7
(12) Methyl paraoxybenzoate 0.1
(13) Purified water remaining amount * 17: KF-6028P (manufactured by Shin-Etsu Chemical Co., Ltd.)
* 18: Dimethylpolysiloxane 4% treatment (production method)
A. Ingredients (1) to (4) are mixed uniformly.
B. Add components (5) to (8) to A and mix.
C. Add components (9) to (13) to B and emulsify at room temperature.
D. C is cooled and filled into a container to obtain a product.
The water-in-oil emulsified mascara of Example 14 obtained as described above was excellent in the uniformity of the cosmetic film, and was excellent in the cosmetic effect such as gloss, curl effect, and volume effect and its sustainability. It was.
実施例15:マスカラ下地(油性型液状)
(成分) (%)
(1)パルミチン酸デキストリン 6
(2)軽質流動イソパラフィン *1 残量
(3)イソドデカン 5
(4)シクロアルキル基含有アクリル系共重合体溶液 *19 50
(5)雲母チタン 3
(6)ジメチルジステアリルアンモニウムヘクトライト *4 5
(7)煙霧状無水ケイ酸 *20 2
(8)マイカ 3
(9)酸化チタン被覆ガラス末 1
(10)タルク 20
*19:製造例1で得られたシクロアルキル基含有アクリル系共重合体(1)を軽質流動イソパラフィン(IPソルベント1620)に溶解し、15%溶液としたもの
*20:AEROSIL R972(日本アエロジル社製)
(製法)
A.成分(1)〜(4)を均一に110℃で混合溶解し、成分(5)〜(10)を加えて均一に混合する。
B.Aを容器に充填し、冷却して製品とする。
以上のようにして得られた実施例15の油性型のマスカラ下地は、化粧膜の均一性に優れ、市販のマスカラの重ね塗りがしやすく、カール効果、ボリューム効果という化粧効果及びその持続性に優れたものであった。
Example 15: Mascara substrate (oil-based liquid)
(Ingredient) (%)
(1) Dextrin palmitate 6
(2) Light liquid isoparaffin * 1 Remaining amount (3) Isododecane 5
(4) Cycloalkyl group-containing acrylic copolymer solution * 19 50
(5) Mica titanium 3
(6) Dimethyl distearyl ammonium hectorite * 4 5
(7) Smoke-like silicic acid * 20 2
(8) Mica 3
(9) Titanium oxide coated glass powder 1
(10) Talc 20
* 19: A cycloalkyl group-containing acrylic copolymer (1) obtained in Production Example 1 dissolved in light liquid isoparaffin (IP solvent 1620) to give a 15% solution * 20: AEROSIL R972 (Nippon Aerosil Co., Ltd.) Made)
(Manufacturing method)
A. Components (1) to (4) are uniformly mixed and dissolved at 110 ° C., and components (5) to (10) are added and mixed uniformly.
B. A is filled into a container and cooled to obtain a product.
The oily-type mascara substrate of Example 15 obtained as described above is excellent in the uniformity of the decorative film, is easy to apply overcoat of a commercially available mascara, has a cosmetic effect such as a curl effect and a volume effect, and its sustainability. It was excellent.
Claims (9)
(A)下記の成分(a1)と、成分(a2)及び/または(a3)とを含むモノマーを重合して得られるアクリル系共重合体であって、構成モノマー総量中、成分(a1)の配合量が50〜90質量%、成分(a2)及び/または(a3)の配合量が10〜50質量%であり、且つ、軽質流動イソパラフィンに25℃で少なくとも30質量%溶解することを特徴とするシクロアルキル基含有アクリル系共重合体;
(a1)シクロアルキル基を含有するアクリレート及び/またはメタクリレート;
(a2)炭素数8〜12の直鎖若しくは分岐のアルキル基を含有するアクリレート及び/またはメタクリレート;
(a3)片末端にラジカル重合性基を含有するオルガノポリシロキサンマクロモノマー
(B)揮発性油剤
を配合することを特徴とする睫用化粧料。 The following components (A) and (B);
(A) An acrylic copolymer obtained by polymerizing a monomer containing the following component (a1) and component (a2) and / or (a3), wherein the component (a1) The blending amount is 50 to 90% by mass, the blending amount of the components (a2) and / or (a3) is 10 to 50% by mass, and at least 30% by mass is dissolved in light liquid isoparaffin at 25 ° C. A cycloalkyl group-containing acrylic copolymer;
(A1) acrylate and / or methacrylate containing a cycloalkyl group;
(A2) acrylate and / or methacrylate containing a linear or branched alkyl group having 8 to 12 carbon atoms;
(A3) A vaginal cosmetic comprising an organopolysiloxane macromonomer (B) volatile oil containing a radical polymerizable group at one end.
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JP2009047284A JP5666782B2 (en) | 2009-02-27 | 2009-02-27 | Cosmetic for salmon |
KR1020117019753A KR101679212B1 (en) | 2009-02-27 | 2010-02-26 | Make-up cosmetic containing acrylic copolymer having cycloalkyl group |
PCT/JP2010/001319 WO2010098126A1 (en) | 2009-02-27 | 2010-02-26 | Make-up cosmetic containing acrylic copolymer having cycloalkyl group |
TW099105748A TWI476215B (en) | 2009-02-27 | 2010-02-26 | And a cosmetic cosmetic containing a cycloalkyl group-containing acrylic copolymer |
CN2010800092145A CN102333518B (en) | 2009-02-27 | 2010-02-26 | Make-up cosmetic containing acrylic copolymer having cycloalkyl group |
HK12106504.2A HK1165947A1 (en) | 2009-02-27 | 2012-07-04 | Make-up cosmetic containing acrylic copolymer having cycloalkyl group |
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WO2021125093A1 (en) * | 2019-12-20 | 2021-06-24 | 桂 嶋田 | Eyelash extension adhesive |
Citations (4)
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JP2002539235A (en) * | 1999-03-25 | 2002-11-19 | スリーエム イノベイティブ プロパティズ カンパニー | Non-irritating coating composition |
JP2004300092A (en) * | 2003-03-31 | 2004-10-28 | Kose Corp | Cosmetic for eyelash |
JP2008501842A (en) * | 2004-06-11 | 2008-01-24 | ロレアル | Gradient copolymer, composition containing the same, and cosmetic makeup or care method |
JP2008163313A (en) * | 2006-11-16 | 2008-07-17 | L'oreal Sa | Novel block polymer, composition containing the same, and treating method |
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JP2002539235A (en) * | 1999-03-25 | 2002-11-19 | スリーエム イノベイティブ プロパティズ カンパニー | Non-irritating coating composition |
JP2004300092A (en) * | 2003-03-31 | 2004-10-28 | Kose Corp | Cosmetic for eyelash |
JP2008501842A (en) * | 2004-06-11 | 2008-01-24 | ロレアル | Gradient copolymer, composition containing the same, and cosmetic makeup or care method |
JP2008163313A (en) * | 2006-11-16 | 2008-07-17 | L'oreal Sa | Novel block polymer, composition containing the same, and treating method |
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Publication number | Priority date | Publication date | Assignee | Title |
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WO2021125093A1 (en) * | 2019-12-20 | 2021-06-24 | 桂 嶋田 | Eyelash extension adhesive |
CN115052581A (en) * | 2019-12-20 | 2022-09-13 | 岛田桂 | Adhesive for grafting eyelashes |
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