JP2010180261A - Resin composition - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To provide a resin composition which includes a polybutylene terephthalate resin as a main component, and excels in welding property to a polyphenylene sulfide resin composition; and to provide a molded product made from the resin composition. <P>SOLUTION: The resin composition includes: 100 pts.wt. of the total of the polybutylene terephthalate resin (A) and the polyphenylene sulfide resin (B); and 5-20 pts.wt. of an epoxy group-containing olefin resin (C). The resin composition of 100 pts.wt. contains the polybutylene terephthalate resin (A), and the polyphenylene sulfide resin (B) the terminals of a majority of which are a metal carboxylate, at a weight ratio (B)/(A) of 0.2-0.4. <P>COPYRIGHT: (C)2010,JPO&INPIT

Description

  The present invention relates to a resin composition containing a polybutylene terephthalate resin, which exhibits excellent properties in bonding and welding with a polyphenylene sulfide resin composition.

  Conventionally, in joining each part made of a thermoplastic resin due to a complicated product shape, joining by an adhesive, mechanical joining by a bolt or the like has been performed. However, adhesives have problems of adhesive strength, and mechanical joining with bolts and the like has problems of cost, labor for fastening, and weight increase. On the other hand, external heat welding such as laser welding and hot plate welding, friction heat welding such as vibration welding and ultrasonic welding can be performed in a short time, and it does not use adhesives or metal parts, so it takes Since problems such as cost, weight increase and environmental pollution do not occur, assembly by these methods is increasing.

  On the other hand, joining parts made of different thermoplastic resins by thermal welding such as laser welding or vibration welding described above has different thermal characteristics such as melting point and melt viscosity, and chemical structural formulas are different. It is difficult because it is derived from the poor compatibility. For example, it is installed as an engine control unit (hereinafter abbreviated as ECU) in order to incorporate software essential for electronic control of automobiles. The internal software is made of a polybutylene terephthalate resin composition cover and a polyphenylene sulfide resin composition. It is protected from the case, and an adhesive or snap fit is used for joining. Therefore, it is desired to improve the heat-fusibility of polybutylene terephthalate resin and polyphenylene sulfide resin, which are different materials, and it is necessary to modify the polybutylene terephthalate resin which is a cover material as a solution. One of the techniques is to alloy a polybutylene terephthalate resin and a polyphenylene sulfide resin. For example, although an alloy of a polybutylene terephthalate resin and a polyphenylene sulfide resin has been reported as in Patent Document 1, the main component is changed from a polybutylene terephthalate resin to a polyphenylene sulfide resin, which is not preferable because the manufacturing cost increases. Further, as disclosed in Patent Document 1 and Patent Document 2, an alloy of a polybutylene terephthalate resin mainly composed of a polybutylene terephthalate resin and a polyphenylene sulfide resin is also mentioned. Intensity did not develop.

JP 61-204268 A JP-A-2005-23093

  The present invention eliminates the problems of the prior art and shows a specific resin composition comprising a polybutylene terephthalate resin as a main component, and a molded article comprising the same, exhibiting excellent properties of bonding and welding with a polyphenylene sulfide resin composition It is an issue to provide.

  As a result of intensive studies to solve the above-mentioned problems, the present inventors have found a composition excellent in heat-welding strength with a polyphenylene sulfide resin while containing a polybutylene terephthalate resin as a main component, thereby completing the present invention. It was.

That is, the present invention comprises (1) a polybutylene terephthalate resin (A) and a polyphenylene sulfide resin (B) having a carboxylic acid metal salt at a majority of the terminals at a weight composition ratio (B) / (A) of 0.2 to 0. And 100 parts by weight of the resin composition contained in a ratio of 0.4, when the total of the polybutylene terephthalate resin (A) and the polyphenylene sulfide resin (B) is 100 parts by weight, the epoxy group-containing olefin resin (C) A resin composition containing 5 to 20 parts by weight,
(2) The resin composition according to (1), wherein the temperature-falling crystallization temperature is between 170 to 190 ° C., and does not show a temperature-falling crystallization temperature of two or more points,
(3) The resin composition according to (1) or (2), wherein the polybutylene terephthalate resin (A) and the polyphenylene sulfide resin (B) each form a continuous phase,
(4) The resin composition according to any one of (1) to (3), which can be bonded to a molded article made of a polybutylene terephthalate resin composition or a polyphenylene sulfide resin composition.

  According to the present invention, an inexpensive resin composition can be obtained because the resin composition is excellent in bonding weldability with a polybutylene terephthalate resin composition or a polyphenylene sulfide resin composition and has polybutylene terephthalate as a main component. The preferred form of the resin composition of the present invention is that the polybutylene terephthalate resin and the polyphenylene sulfide resin form a co-continuous structure, not a sea-island structure, so that the resin does not re-orientate due to the shearing force applied at the time of molding. A co-continuous structure can be maintained even on the surface.

  The resin composition of the present invention can be widely used for parts that require joint welding, such as cases and covers of ECUs for automobiles, automotive outer plate applications such as fenders and bumpers, mechanical parts, and electrical and electronic parts.

It is a model which shows an example of the co-continuous structure where PBT resin (A) and PPS resin (B) formed the continuous phase together. It is a model figure which shows the sea-island structure in which any one of PBT resin (A) or PPS resin (B) forms the continuous phase. It is the schematic of a hot plate welding test piece.

S Hot plate welding interface 1 PBT resin 2 PPS resin

The present invention is described in detail below.

  The present invention comprises a polybutylene terephthalate resin (A) and a polyphenylene sulfide resin (B) having a carboxylic acid metal salt at a majority of the terminals, wherein the weight composition ratio (B) / (A) is 0.2 to 0.4. When the total amount of the polybutylene terephthalate resin (A) and the polyphenylene sulfide resin (B) is 100 parts by weight, the epoxy group-containing olefin resin (C) 5 to 20 A resin composition containing parts by weight.

  The polybutylene terephthalate resin (A) used in the present invention is a normal polymerization such as a polycondensation reaction mainly comprising terephthalic acid or an ester-forming derivative thereof and 1,4-butanediol or an ester-forming derivative thereof. It is a polymer obtained by the method and may contain other copolymerization components in a range that does not impair the characteristics, for example, about 20% by weight or less. Preferred examples of these (co) polymers include polybutylene terephthalate (hereinafter abbreviated as PBT resin, if necessary), polybutylene (terephthalate / isophthalate), polybutylene (terephthalate / adipate), polybutylene (terephthalate / sebacate). , Polybutylene (terephthalate / decane dicarboxylate), polybutylene (terephthalate / naphthalate), poly (butylene / ethylene) terephthalate, etc., may be used alone or in admixture of two or more.

The PBT resin and the polyphenylene sulfide resin (hereinafter abbreviated as PPS resin if necessary) preferably form a co-continuous structure. The co-continuous structure here means that PBT and PPS each form a continuous phase. For example, PBT is not present in the form of particles in the continuous phase of PBT.
The value of the melt indexer (hereinafter referred to as MI) of the PBT resin is preferably 1 to 40 g / 10 minutes, more preferably 2 to 20 g / 10 minutes. When the MI value is 1 to 40 g / 10 min, it can be melt kneaded with polyphenylene sulfide resin (hereinafter abbreviated as PPS resin) to easily form a co-continuous structure. MI is a value obtained by drying 5 g of PBT resin at 110 ° C. for 3 hours and retaining it at 250 ° C. for 5 minutes, applying 1 kg load and measuring (based on ISO-1133).

  As the PPS resin (B) used in the present invention, a polymer having a repeating unit represented by the following structural formula can be used.

From the viewpoint of heat resistance, a polymer containing 70 mol% or more, further 90 mol% or more of the repeating unit represented by the structural formula is preferable. Further, the PPS resin may be composed of repeating units having the following structure in which less than 30 mol% of the repeating units have the following structure.

  In the PPS resin used in the present invention, the majority of the terminals are carboxylic acid metal salts, preferably 60% or more, more preferably 70% or more. If the end of the carboxylic acid metal salt of the PPS resin is 60% or more, preferably, the reaction with the epoxy group-containing olefin resin (C) can be suppressed, and the PBT resin and the PPS resin may form a co-continuous structure with each other. it can.

  In the method for producing a PPS resin used in the present invention, a hot water treatment with an aqueous solution containing a Group II metal element of the periodic table is preferably used as the washing step after washing with an organic solvent. If it is the said method, the terminal of PPS resin can be easily made into carboxylic acid metal salt. Except for the terminal of the carboxylic acid metal salt, it is the carboxylic acid terminal.

  As a method of washing with an organic solvent, there is a method of immersing a PPS resin in an organic solvent, and it is preferable to stir or heat for the purpose of making the effect of the present invention more remarkable. The amount of the organic solvent used for the PPS resin is preferably 1 to 100 kg, more preferably 2 to 50 kg, and further preferably 3 to 15 kg with respect to 1 kg of the dried PPS resin.

  As the washing temperature when washing the PPS resin with an organic solvent, an arbitrary temperature of about room temperature to about 300 ° C. can be selected. However, since cleaning efficiency tends to increase as the cleaning temperature increases, it is preferable to perform cleaning at a high temperature of 100 to 300 ° C.

  When washing the PPS resin with an organic solvent, it is possible to wash under pressure (preferably 250 to 300 ° C.) at a temperature equal to or higher than the boiling point of the organic solvent in a pressure vessel. Examples of the cleaning method include a batch type and a continuous type.

  Examples of the organic solvent used for washing the PPS resin include N-methyl-2-pyrrolidone (hereinafter abbreviated as NMP), dimethylformamide, dimethylacetamide, 1,3-dimethylimidazolidinone, hexamethylphosphorusamide, piperazinones, and the like. Nitrogen-containing polar solvent, sulfoxide-sulfone solvents such as dimethyl sulfoxide, dimethyl sulfone, sulfolane, ketone solvents such as acetone, methyl ethyl ketone, diethyl ketone, acetophenone, ether solvents such as dimethyl ether, dipropyl ether, dioxane, tetrahydrofuran, Chloroform, methylene chloride, trichlorethylene, ethylene dichloride, perchlorethylene, monochloroethane, dichloroethane, tetrachloroethane, perchlorethane, chlorobenzene, etc. Halogen solvents, methanol, ethanol, propanol, butanol, pentanol, ethylene glycol, propylene glycol, phenol, cresol, polyethylene glycol, polypropylene glycol, and other alcohol / phenol solvents, and benzene, toluene, xylene, and other aromatic hydrocarbons A solvent etc. are mentioned. Among these organic solvents, use of NMP, acetone, dimethylformamide, chloroform and the like is particularly preferable. These organic solvents are used alone or in combination of two or more.

Among the metal elements of Group II of the periodic table used in the hydrothermal treatment of PPS resin, preferred metal elements include Ca, Mg, Ba, Zn, and the like, with Ca being particularly preferred. Examples of the counter anion include acetate ion, halide ion, hydroxide ion and carbonate ion. More specific and preferred compounds include Ca acetate, Mg acetate, Zn acetate, CaCl ₂ , CaBr ₂ , ZnCl ₂ , CaCO ₃ , Ca (OH) ₂ and CaO, and particularly preferably Ca acetate.

  The temperature of the aqueous solution containing the Group II metal element of the periodic table is 130 ° C. or higher, and more preferably 150 ° C. or higher. The upper limit of the washing temperature is preferably about 250 ° C. when a normal autoclave is used.

  The bath ratio of the aqueous solution containing the Group II metal element of the periodic table is preferably selected in a range of 2 to 100, more preferably in the range of 4 to 50, and 5 to 15 in terms of weight ratio with respect to the dry polymer 1. More preferably, it is in the range.

  The PPS resin (B) used in the present invention preferably has a high melt flow rate (MFR), and the MFR is preferably 1000 g / 10 min or less, particularly preferably 700 g / 10 min or less. preferable. The lower limit of MFR is preferably 30 g / 10 min or more in terms of fluidity loss. The MFR is a value obtained by drying 5 g of PPS resin powder at 130 ° C. for 3 hours and retaining the powder at 315.5 ° C. for 5 minutes, applying a 5 kg load (based on JIS-K7210).

  The resin composition of the present invention comprises a polybutylene terephthalate resin (A) and a polyphenylene sulfide resin (B) having a carboxylic acid metal salt at a majority of the terminals at a weight composition ratio (B) / (A) of 0.2 to 0. .4 content.

  The resin composition of the present invention contains 5 to 20 parts by weight of an epoxy group-containing olefin resin (C) when the total of the polybutylene terephthalate resin (A) and the polyphenylene sulfide resin (B) is 100 parts by weight.

The epoxy group-containing olefin resin (C) is composed of a polybutylene terephthalate resin (A) and a polyphenylene sulfide resin (B) having a carboxylic acid metal salt at a majority of the terminals, and a weight composition ratio (B) / (A) of 0. When the resin composition contained in a ratio of 2 to 0.4 is 100 parts by weight, it is contained in an amount of 5 to 20 parts by weight, preferably 8 to 18 parts by weight. When the content is less than 5, the reaction with the PBT resin is reduced during melt kneading, and the modification such as the thickening of the PBT resin is insufficient. Moreover, when content exceeds 20 weight part, reaction with an epoxy-group containing olefin resin (C) and PPS resin (B) will advance, PPS resin will thicken and the target performance will not be obtained. . Resin containing polybutylene terephthalate resin (A) and polyphenylene sulfide resin (B) having a carboxylic acid metal salt at a majority of the terminals at a weight composition ratio (B) / (A) of 0.2 to 0.4 When 5 to 20 parts by weight of the epoxy group-containing olefin resin (C) is contained with respect to 100 parts by weight of the composition, the polybutylene terephthalate resin and the polyphenylene sulfide resin preferably form a co-continuous structure.
Examples of the olefin of the epoxy group-containing olefin resin (C) of the present invention include ethylene, propylene, 1-butene, butadiene, and styrene. Specific examples of the epoxy group-containing unsaturated monomer include glycidyl acrylate, Such as glycidyl methacrylate, glycidyl ethacrylate, glycidyl itaconate, vinyl esters such as vinyl ethers, vinyl acetate, vinyl propionate, acrylic acid and methacrylates such as methyl, ethyl, propyl, butyl, etc. Copolymerized glycidyl ethers and glycidyl esters are exemplified, and specific examples of the epoxy group-containing olefin resin (C) include ethylene / glycidyl methacrylate copolymer, ethylene / vinyl acetate / glycidyl methacrylate copolymer, ethylene Methyl methacrylate / glycidyl methacrylate copolymer, ethylene / glycidyl acrylate copolymer, ethylene / vinyl acetate / glycidyl acrylate copolymer, and an ethylene / glycidyl ether copolymers. Of these, an ethylene / glycidyl methacrylate copolymer is most preferred. The ratio of ethylene to glycidyl methacrylate is preferably 65 to 97% by weight of ethylene and 3 to 35% by weight of glycidyl methacrylate, more preferably 80 to 95% by weight of ethylene, 5 to 20% by weight of glycidyl methacrylate, and still more preferably ethylene. 85 to 88 wt%, glycidyl methacrylate 12 wt% to 15 wt%. When the ratio of glycidyl methacrylate is in the range of 3 to 35% by weight, high welding strength between the obtained resin composition and the PPS resin can be obtained.

  Further, the epoxy group-containing olefin resin (C) is effective even with a ternary copolymer, and among them, an ethylene / methyl acrylate / glycidyl methacrylate copolymer and an ethylene / ethyl acrylate / glycidyl methacrylate copolymer are preferable. More preferably, it is an ethylene / methyl acrylate / glycidyl methacrylate copolymer.

  The epoxy group of the epoxy group-containing olefin resin (C) used in the present invention is obtained by copolymerizing with an olefin using an epoxy group-containing unsaturated monomer as described above. An epoxy group may be introduced by chemical modification.

  Furthermore, in the resin composition of the present invention, a reinforcing material, a filler, an antioxidant, a stabilizer, an ultraviolet absorber, a colorant, a release agent, a flame retardant and the like are usually used as long as the effects of the present invention are not impaired. And small amounts of other polymers can be added.

  Stabilizers include benzotriazole compounds including 2- (2′-hydroxy-5′-methylphenyl) benzotriazole, and benzophenone compounds such as 2,4-dihydroxybenzophenone, mono- or distearyl phosphate, trimethyl phosphate And phosphoric acid esters.

  These various additives may have a synergistic effect by combining two or more kinds, and may be used in combination.

  For example, the additive exemplified as the antioxidant may act as a stabilizer or an ultraviolet absorber. Some of those exemplified as stabilizers also have an antioxidant action and an ultraviolet absorption action. In other words, the classification is for convenience and does not limit the action.

Mold release agents include plant waxes such as carnauba wax and rice wax, animal waxes such as beeswax and lanolin, mineral waxes such as montan wax, petroleum waxes such as paraffin wax and polyethylene wax, castor oil and its Derivatives, fatty acids, and oil-based waxes such as derivatives thereof. Examples of higher fatty acid derivatives include higher fatty acids such as lauric acid, myristic acid, palmitic acid, stearic acid, and montanic acid, and monohydric or dihydric or higher alcohols. Esters, partial saponification of these higher fatty acid esters partially with metal oxides such as Ca (OH) ₂ , NaOH, Mg (OH) ₂ , Zn (OH) ₂ , LiOH, Al (OH) ₃ Saponification obtained from esterified esters, higher fatty acids and metal oxides or metal hydroxides Products, higher fatty acids and polyhydric alcohol esters, which are condensed with a dicarboxylic acid such as adipic acid as a binder, mono- or diamides obtained from higher fatty acids and monoamines or diamines.

  About the manufacturing method of the resin composition of this invention, it can obtain by the method by the biaxial extruder generally known. A method of melt kneading at a temperature of 200 to 320 ° C. can be mentioned. Each component may be mixed in advance and then melt kneaded. Or about 100 weight part of resin compositions of this invention, about a small amount additive component which is 1 weight part or less, for example, after kneading | mixing and pelletizing another component by said method etc., it adds before shaping | molding. You can also. In addition, it is better that the moisture adhering to each component is small, and it is desirable to dry in advance.

  The temperature decrease crystallization temperature of the resin composition of the present invention is preferably between 170 ° C. and 190 ° C., and the resin composition of the present invention preferably does not exhibit a temperature decrease crystallization temperature of two or more points. More preferably, the resin composition of the present invention has a temperature lowering crystallization temperature of 170 ° C. to 180 ° C. and does not exhibit a temperature lowering crystallization temperature of two or more points. When the temperature-falling crystallization temperature is 170 ° C. to 190 ° C. and the temperature-falling crystallization temperature is not two or more, the PBT resin (A) and the PPS resin (B) used in the present invention are crystallized simultaneously. At this time, preferably, a co-continuous structure is formed and a high welding strength with the PPS resin is exhibited.

  In the resin composition of the present invention, preferably, the polybutylene terephthalate resin (A) and the polyphenylene sulfide resin (B) each form a continuous phase. In order for the resin composition of the present invention to have high bonding weldability with the PPS resin, it is preferable that the PBT resin (A) and the PPS resin (B) together form a continuous phase as illustrated in FIG. When the continuous phase is not formed as shown in FIG. 2, that is, only one of the PBT resin (A) or the PPS resin (B) forms the continuous phase and the other is an island-dispersed sea-island. When the structure is formed, at the time of molding processing such as injection molding or extrusion molding, the morphology near the surface of the obtained molded product changes to a striped morphology from the surface of the molded product to the inside, and with the PPS resin. High bonding weldability may not be exhibited.

  The resin composition of the present invention can preferably be welded to a molded article made of a polybutylene terephthalate resin composition or a polyphenylene sulfide resin composition. Specific methods of heat fusion include hot air welding, hot plate welding, laser welding, high frequency welding, induction heating welding, spin welding, vibration welding, ultrasonic welding, DSI molding, etc., which can be used properly depending on the application. .

  The resin composition of the present invention has excellent bonding and welding properties with PPS resin, and can be widely used for parts that require bonding and welding, such as cases and covers of automobile ECUs, and automobile outer plate applications such as fenders and bumpers. .

Hereinafter, the present invention will be described in more detail with reference to examples. The compounding compositions used in Examples and Comparative Examples are shown below.
(A-a) PBT resin MI: 2.8 g / 10 min “Toraycon” 1500S manufactured by Toray Industries, Inc.
(Ab) PBT resin MI: 8.2 g / 10 min “Toraycon” 1200S manufactured by Toray Industries, Inc.
(Ac) PBT resin MI: 28 g / 10 min “Toraycon” 1100S manufactured by Toray Industries, Inc.
(B-a) PPS resin MFR: 100 g / 10 min, 80% Ca terminal, “Torelina” E2080 manufactured by Toray Industries, Inc.
(B-b) PPS resin MFR: 158 g / 10 min, 80% of the terminals are carboxylic acid Ca salt, “Torelina” E2280 manufactured by Toray Industries, Inc.
(Bc) PPS resin MFR: 63 g / 10 min, 80% of the terminals are carboxylic acid Ca salt, “Torelina” T1881 manufactured by Toray Industries, Inc.
(Bd) PPS resin MFR: 100 g / 10 min, 80% of the terminals are carboxylic acid, “Torelina” M2088 manufactured by Toray Industries, Inc.
(Be) PPS resin MFR: 126 g / 10 min, 80% of the terminals are carboxylic acid, “Torelina” L2120 manufactured by Toray Industries, Inc.
(Ca) ethylene / glycidyl methacrylate = 88/12 (% by weight) copolymer (Bond First-E, manufactured by Sumitomo Chemical Co., Ltd.)
(Cb) Butadiene / styrene = 60/40 (% by weight) epoxy group-containing copolymer (Epofriend AT501, manufactured by Daicel Chemical Industries)
(Cc) ethylene and butylene / styrene = 80/20 (% by weight) copolymer (Tuftec M1943 manufactured by Asahi Kasei Chemicals Corporation).

Production method of PPS resin (B)
[Reference Example 1]
An autoclave equipped with a stirrer was charged with 6.005 kg (25 mol) of sodium sulfide 9 hydrate, 0.787 kg (9.6 mol) of sodium acetate and 5 kg of NMP, and gradually heated to 205 ° C. through nitrogen, Distill the liter. Next, after cooling the reaction vessel to 180 ° C, 3.712 kg (25.25 mol) of 1,4-dichlorobenzene and 2.4 kg of NMP were added, sealed under nitrogen, heated to 270 ° C, heated at 270 ° C. Reacted for 2.5 hours. Next, the mixture was put into 10 kg of NMP heated to 100 ° C., stirred for about 1 hour, filtered, and further washed with hot water at 80 ° C. for 30 minutes three times. This was filtered, poured into 25 liters of an aqueous solution containing 10.4 g of calcium acetate, stirred for about 1 hour at 192 ° C. in a sealed autoclave, filtered, and the pH of the filtrate reached 7. After washing with ion-exchanged water at about 90 ° C., it was dried under reduced pressure at 80 ° C. for 24 hours to obtain PPS (B-a) having a melting point of 278 ° C., a temperature-falling crystallization temperature of 180 ° C., and an MFR of 100 g / 10 min.

[Reference Example 2]
An autoclave equipped with a stirrer was charged with 6.005 kg (25 mol) of sodium sulfide 9 hydrate, 0.787 kg (9.6 mol) of sodium acetate and 5 kg of NMP, and gradually heated to 205 ° C. through nitrogen, Distill the liter. Next, after cooling the reaction vessel to 180 ° C, 3.712 kg (25.25 mol) of 1,4-dichlorobenzene and 2.4 kg of NMP were added, sealed under nitrogen, heated to 270 ° C, heated at 270 ° C. Reacted for 2.5 hours. Next, the mixture was put into 10 kg of NMP heated to 100 ° C., stirred for about 1 hour, filtered, and further washed with hot water at 80 ° C. for 30 minutes three times. This was filtered, poured into 20 liters of warm water containing 9.8 g of acetic acid, stirred for about 1 hour at 192 ° C. in a sealed autoclave, filtered, and dried under reduced pressure at 80 ° C. for 24 hours. As a result, PPS (Bd) having a melting point of 278 ° C., a falling crystallization temperature of 232 ° C., and an MFR of 100 g / 10 min was obtained.

  The MFR was determined by drying 5 g of PPS resin powder at 130 ° C. for 3 hours and retaining the powder at 315.5 ° C. for 5 minutes, applying a 5 kg load (based on JIS-K7210).

[Examples 1 to 10] [Comparative Examples 1 to 8]
The components (A), (B) and (C) were mixed at room temperature in the proportions shown in Table 1, and melt kneaded using a twin screw extruder TEM35B (manufactured by Toshiba) having a screw diameter of 35 mmφ. The components (A), (B), and (C) were supplied from the extruder feed-in portion, and the cylinder temperature was set to 300 ° C. The strand discharged from the die was cooled in a cooling bath and then pelletized with a strand cutter. The following properties were evaluated using this pellet. In addition, the measurement and the test of the physical property in an Example and a comparative example were performed with the following method.

(1) Temperature-falling crystallization temperature About 10 mg was sampled from the pellets of the thermoplastic resin, and the temperature was raised at a heating rate of 20 ° C./min using a differential scanning calorimeter DSC-7 manufactured by PerkinElmer, Inc. at 340 ° C. After holding for 5 minutes, the temperature of the crystallization peak (exothermic peak) when the temperature was lowered at a rate of 20 ° C./minute was measured and taken as the temperature-falling crystallization temperature. Tables 1 and 2 list the number of peaks at 170 to 180 ° C.

(2) Morphology The pellets are subjected to a “JSW55D” injection molding machine (manufactured by Nikko) and continuously molded under the conditions of an injection speed of 150 mm / second, an injection pressure of 50 to 100 MPa, and a cylinder set temperature of 200 to 320 ° C. (injection time / cooling). Time = 10.0 / 20.0 seconds, screw rotation speed 150 rpm, back pressure 2 MPa, suck back 3 mm, mold temperature 80 ° C.), square plate test piece (80 mm square, thickness 1.0 mm, film gate) Molded and observed with a transmission electron microscope. Tables 1 and 2 show “co-continuous” in which the PBT resin (A) and the PPS resin (B) together form a continuous phase as shown in FIG. 1, and the PBT resin (A) or PPS as shown in FIG. One in which only one of the resins (B) forms a continuous phase is described as “Kaijima”.

(3) Hot plate welding strength The pellets are subjected to a “JSW55D” injection molding machine (manufactured by Nikko Co., Ltd.) and continuously molded (injection) under conditions of an injection speed of 150 mm / second, an injection pressure of 50 to 100 MPa, and a cylinder set temperature of 200 to 320 ° C. Time / cooling time = 10.0 / 20.0 seconds, screw rotation speed 150 rpm, back pressure 2 MPa, suck back 3 mm, mold temperature 80 ° C., square plate test piece (80 mm square, thickness 1.0 mm, film Gate) and the resulting molded product was cut to a width of 19 mm and a length of 80 mm, and then a hot plate temperature of 320 ° C., a heating time of 10 seconds, and a cooling time of 20 for a molded product made of PPS resin (the counterpart material). In 19 seconds, 19 mm × 1.0 mm surfaces were welded to each other with a hot plate to prepare a hot plate welding test piece as shown in FIG. Using the obtained hot plate welding test piece, a tensile test was performed under the conditions of a tensile speed of 1 mm / second and a distance between chucks of 80 mm, and the obtained load was divided by the cross-sectional area of the test piece of 19 mm × 1 mm. Strength.

  In addition, the molded product made of PPS resin which is the counterpart material of this test is a pelletized PPS resin “Torelina” L2120 (Be) manufactured by Toray Industries, Inc. “JSW55D” injection molding machine (manufactured by Nikko) Continuous molding under the conditions of an injection speed of 150 mm / second, an injection pressure of 50 to 100 MPa, and a cylinder set temperature of 200 to 320 ° C. (injection time / cooling time = 10.0 / 20.0 seconds, screw rotation speed 150 rpm, back pressure 2 MPa, suck back 3 mm, mold temperature 80 ° C.), a square plate test piece (80 mm square, thickness 1.0 mm, film gate) was molded, and the resulting molded product was cut to a width of 19 mm and a length of 80 mm. It is a test piece.

  These results are shown in Tables 1 and 2.

  In Comparative Example 8, the polybutylene terephthalate resin (A), which is the object of the present invention, and the polyphenylene sulfide resin (B) having a carboxylic acid metal salt at a majority of the terminals, the weight composition ratio (B) / (A) is 0. It is not a resin composition contained in a ratio of 2 to 0.4. In Comparative Example 8, since the ratio of the PPS resin component is high, the strength is expressed by welding of the PPS resins, and does not show the welding strength of the PBT resin and the PPS resin.

  From the above results, it can be seen that the resin composition of the present invention is a resin composition containing polybutylene terephthalate as a main component, and is excellent in bonding weld strength with a PPS resin.

Claims (4)

The polybutylene terephthalate resin (A) and the polyphenylene sulfide resin (B) having a carboxylic acid metal salt at a majority of the terminals are contained at a weight composition ratio (B) / (A) of 0.2 to 0.4. A resin composition comprising 5 to 20 parts by weight of an epoxy group-containing olefin resin (C) when the total of the polybutylene terephthalate resin (A) and the polyphenylene sulfide resin (B) is 100 parts by weight. object. The resin composition according to claim 1, wherein the temperature-falling crystallization temperature is between 170 and 190 ° C., and does not exhibit a temperature-falling crystallization temperature of two or more points. The resin composition according to claim 1 or 2, wherein the polybutylene terephthalate resin (A) and the polyphenylene sulfide resin (B) each form a continuous phase. The resin composition according to any one of claims 1 to 3, which can be welded to a molded article made of a polybutylene terephthalate resin composition or a polyphenylene sulfide resin composition.

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