JP2010174347A - Method for manufacturing electric wire conductor - Google Patents

Method for manufacturing electric wire conductor Download PDF

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JP2010174347A
JP2010174347A JP2009019580A JP2009019580A JP2010174347A JP 2010174347 A JP2010174347 A JP 2010174347A JP 2009019580 A JP2009019580 A JP 2009019580A JP 2009019580 A JP2009019580 A JP 2009019580A JP 2010174347 A JP2010174347 A JP 2010174347A
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treatment
wire
electric wire
wire conductor
heat treatment
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Masatsugu Karakawa
正嗣 唐川
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Furukawa Electric Co Ltd
Furukawa Automotive Systems Inc
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Furukawa Electric Co Ltd
Furukawa Automotive Systems Inc
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Abstract

<P>PROBLEM TO BE SOLVED: To provide a method for manufacturing an electric wire conductor made of a copper alloy, which is rarely disconnected and achieves small diameter. <P>SOLUTION: The method for manufacturing the electric wire conductor made of the copper alloy is characterized by a bonding treatment and a heat treatment of joints of the electric wire conductor and comprises steps of: manufacturing a drawing stock of the copper alloy made of desired components by a continuous casting apparatus such as SCR; subjecting the drawing stock to wire drawing (drawing treatment of a drawing stock) by cold working and subsequently to annealing; and carrying out wire drawing (first wire drawing treatment) and further wire drawing (second wire drawing treatment) so as to obtain an element wire for an automotive wire. When carrying out the first and second wire drawing treatments, ends of the electric wire conductor are subjected to a bonding treatment and a heat treatment. The bonding treatment may be carried out before or after the heat treatment. The bonding treatment is a treatment for bonding the end of an electric wire conductor to an end of another electric wire conductor. Preferably, the heat treatment is carried out by heating the joint at 500-850°C for 0.5-30 minutes. <P>COPYRIGHT: (C)2010,JPO&INPIT

Description

本発明は自動車用ワイヤーハーネスに使用される自動車用電線に用いられる電線導体の製造方法に関する。   The present invention relates to a method for producing a wire conductor used in an automobile electric wire used in an automobile wire harness.

自動車のワイヤーハーネスは、例えば、エンジンルームの内部の各装置や制御機器等を電気的に接続する電線として車両関係に広く用いられている。近年、省スペース、軽量化が要求されており、これに伴いワイヤーハーネスには、電線の細径化が要求されている。   BACKGROUND ART Wire harnesses for automobiles are widely used in vehicles, for example, as electric wires that electrically connect devices and control devices inside an engine room. In recent years, space saving and weight reduction have been demanded, and accordingly, wire harnesses are required to have a thin wire diameter.

ワイヤーハーネスに用いられる自動車用電線として、従来は電線導体として純銅からなる軟銅線を用い、この電線導体を数本撚り合わせた束の外周に樹脂等の絶縁体を被覆したものが用いられていた。これに対し、電線導体として純銅にスズを添加したCu−Sn合金線を用いて強度向上及び細径化を実現させた例がある(特許文献1)。   As an electric wire for automobiles used in a wire harness, conventionally, an annealed copper wire made of pure copper is used as an electric wire conductor, and an outer periphery of a bundle obtained by twisting several electric wire conductors is covered with an insulator such as a resin. . On the other hand, there exists an example which implement | achieved the strength improvement and diameter reduction using the Cu-Sn alloy wire which added tin to pure copper as an electric wire conductor (patent document 1).

これら自動車用電線の電線導体は、一般的に荒引線から製造する。すなわち、連続鋳造装置により荒引線を製造し、所定の長さで切断し、コイル状に巻かれる。次いで、前記荒引線を伸線装置に通して伸線(冷間加工)したり、焼鈍装置に通して焼鈍を行うことを繰り返して、所望の外径の電線導体を製造する。なお、焼鈍は連続式でもバッチ式でも良い。   The wire conductors of these automobile wires are generally manufactured from rough drawn wires. That is, a rough drawn wire is manufactured by a continuous casting apparatus, cut at a predetermined length, and wound in a coil shape. Next, the rough drawn wire is drawn (cold working) through a wire drawing device or is annealed through an annealing device to produce a wire conductor having a desired outer diameter. The annealing may be continuous or batch.

伸線工程においては、伸線装置への通線(例えば、伸線ダイスや冷却槽へ手作業で線を通していくこと)に時間がかかることから、作業の効率化のため、電線導体の線同士の端部を接続している。これにより、通線作業をしなくても、継続して伸線処理をすることができる。線同士の端部を接続する方法として、市販のコールドウェルド工具を用いて接合を行うことが一般的である。すなわち、電線導体の端部を突き合わせて押し込み、加圧、変形させて接合する。これにより接合部分は元の電線導体と同等の強度が得られるので、接合した部分を伸線処理できるとともに、電線導体として使用も可能である。   In the wire drawing process, it takes time to connect the wire conductor to the wire drawing device (for example, manually drawing the wire to a wire drawing die or a cooling bath). The ends of the are connected. Thereby, even if it does not carry out a line work, a wire drawing process can be continued. As a method of connecting the ends of the wires, it is common to perform bonding using a commercially available cold weld tool. That is, the end portions of the electric wire conductors are brought into contact with each other, pressed, pressed, deformed, and joined. As a result, the joint portion can have the same strength as the original electric wire conductor, so that the joined portion can be drawn and used as an electric wire conductor.

特開平7−192535号公報JP 7-192535 A

従来の、純銅からなる電線導体の場合は、前記の接合を行った部分を伸線処理しても断線は発生しなかった。しかし特許文献1記載の銅合金線の線同士の端部をコールドウェルド工具にて接続し、接合部を伸線したところ、断線することが多いことが判明した。また、他の銅合金線でも同様であった。   In the case of a conventional electric wire conductor made of pure copper, no disconnection occurred even when the portion where the above-mentioned bonding was performed was drawn. However, when the ends of the copper alloy wires described in Patent Document 1 are connected with a cold weld tool and the joint is drawn, it has been found that the wires are often disconnected. The same applies to other copper alloy wires.

そこで本発明は、伸線工程にて断線しにくく、かつ、細径化に対応した電線導体の製造方法を提供することを目的とする。   Then, an object of this invention is to provide the manufacturing method of the electric wire conductor which is hard to be disconnected at a wire drawing process, and respond | corresponded to diameter reduction.

上記課題は、以下の手段により達成される。すなわち、本発明は、
(1)電線導体の接合部に接合処理と熱処理を行うことを特徴とする銅合金電線導体の製造方法であって、
前記電線導体に第一の伸線処理し、前記接合処理し、前記接合部を500〜850℃で0.5〜30分熱処理し、第二の伸線処理することを特徴とする電線導体の製造方法、
(2)電線導体の接合部に接合処理と熱処理を行うことを特徴とする銅合金電線導体の製造方法であって、
前記電線導体に第一の伸線処理し、前記接合部を500〜850℃で0.5〜30分熱処理し、前記接合処理し、第二の伸線処理をすることを特徴とする電線導体の製造方法、
(3)前記電線導体は、少なくとも一方が、Snを0.1〜10質量%を含む銅合金からなることを特徴とする(1)または(2)記載の電線導体の製造方法、
を、提供するものである。
The above-mentioned subject is achieved by the following means. That is, the present invention
(1) A method for producing a copper alloy wire conductor, characterized by performing a joining process and a heat treatment on a joint portion of the wire conductor,
The wire conductor is subjected to a first wire drawing treatment, the joining treatment, the joint portion is heat treated at 500 to 850 ° C. for 0.5 to 30 minutes, and a second wire drawing treatment is performed. Production method,
(2) A method for producing a copper alloy electric wire conductor, characterized in that a bonding process and a heat treatment are performed on a bonded portion of the electric wire conductor,
The wire conductor is subjected to a first wire drawing treatment, the joint is heat treated at 500 to 850 ° C. for 0.5 to 30 minutes, the joint treatment is performed, and a second wire drawing treatment is performed. Manufacturing method,
(3) The method for producing a wire conductor according to (1) or (2), wherein at least one of the wire conductors is made of a copper alloy containing 0.1 to 10% by mass of Sn.
Is provided.

本発明の電線導体の製造方法は、線同士の接合部に加熱処理を施すことにより、伸線工程で破断することが防止され、段替作業の効率化を図ることが出来る。   In the method for producing an electric wire conductor of the present invention, by performing a heat treatment on the joint portion between the wires, the wire conductor is prevented from being broken in the wire drawing step, and the efficiency of the changeover work can be improved.

本発明の電線導体は、Sn、Ni,Si,Zn,Mg,Fe、Co、P、Mn、Beなどを含んだ銅合金よりなる。例えば、Snを0.1〜10質量%を含む銅合金、あるいは、NiとCoとSiを0.1〜10質量%含む銅合金などがある。自動車用の電線導体として好ましいのは、Snを0.1〜2.0質量%を含む銅合金、あるいは、NiとCoとを合計で0.1〜3.0質量%さらにSiを0.1〜0.7質量%含む銅合金である。また、本発明の電線導体は、導体の外径が0.1〜10mmの線からなる。   The electric wire conductor of the present invention is made of a copper alloy containing Sn, Ni, Si, Zn, Mg, Fe, Co, P, Mn, Be and the like. For example, there is a copper alloy containing 0.1 to 10% by mass of Sn or a copper alloy containing 0.1 to 10% by mass of Ni, Co and Si. A preferable wire conductor for an automobile is a copper alloy containing 0.1 to 2.0% by mass of Sn, or 0.1 to 3.0% by mass in total of Ni and Co, and 0.1% of Si. It is a copper alloy containing -0.7 mass%. Moreover, the electric wire conductor of this invention consists of a wire whose outer diameter of a conductor is 0.1-10 mm.

本発明の電線導体の製造方法を説明する。SCRなどの連続鋳造装置により、所望の成分からなる銅合金の荒引線を製造する。ついで、前記荒引線を冷間加工により伸線処理(荒引線の伸線処理)し、連続式焼鈍処理を施す。ついで冷間加工により伸線処理(第一の伸線処理)し、さらに、冷間加工により伸線処理(第二の伸線処理)を施し、自動車電線用素線とする。
このとき、前記第一の伸線処理と、前記第二の伸線処理の間に、電線導体の端部に接合処理及び熱処理を施す。また、前記第二の伸線処理を施す前に、電線導体の端部に接合処理及び熱処理を施す。前記接合処理と前記熱処理は、その順序を問わない。
The manufacturing method of the electric wire conductor of this invention is demonstrated. A rough drawn wire of a copper alloy made of a desired component is produced by a continuous casting apparatus such as SCR. Next, the rough drawn wire is drawn by cold working (drawing processing of the rough drawn wire), and then subjected to a continuous annealing treatment. Next, wire drawing processing (first wire drawing treatment) is performed by cold working, and wire drawing processing (second wire drawing treatment) is further performed by cold working to obtain a wire for an automobile electric wire.
At this time, between the first wire drawing process and the second wire drawing process, an end portion of the wire conductor is subjected to a bonding process and a heat treatment. In addition, before the second wire drawing process, a bonding process and a heat treatment are performed on the end portion of the wire conductor. The order of the joining process and the heat treatment is not limited.

本発明の接合処理は、市販のコールドウェルド工具により行う。一般的には、一方の電線導体の端部と、もう一方の電線導体の端部を突き合わせて、一対のチャックにて固定する。次いで、双方の電線導体を押し付けるように、一対のチャックを一定の距離だけ近づける。これにより、双方の電線導体の端部は塑性変形し、ゴミや酸化層の無い面同士で押し付けられることで、双方の電線導体が接合面で機械的に接続して、接合処理が完了する。前記変形にともない、前記接合面において径方向にはバリと呼ばれる突起物が電線導体周囲にはみ出す。前記バリはヤスリ等で除去し、前記電線導体の外径がほぼ一定になるようにしておく。   The joining process of the present invention is performed with a commercially available cold weld tool. Generally, the end portion of one electric wire conductor and the end portion of the other electric wire conductor are brought into contact with each other and fixed with a pair of chucks. Next, the pair of chucks are brought close to each other by a certain distance so as to press both the wire conductors. Thereby, the edge part of both electric wire conductors plastically deforms, and both electric wire conductors are mechanically connected by a joining surface by pressing against surfaces without a dust and an oxide layer, and a joining process is completed. Along with the deformation, a protrusion called a burr protrudes around the wire conductor in the radial direction on the joint surface. The burr is removed with a file or the like so that the outer diameter of the wire conductor is substantially constant.

前記接合部では、電線導体の長手方向とは異なり、前記長手方向と略90度方向へ塑性変形する。このため、銅合金の結晶組織も、前記長手方向と前記接合部ではそれぞれ、略90度方向異なる方向に長い結晶組織となる。一般的に金属組織において、結晶組織の長い方向への加工は比較的耐えられるが、前記接合部では、局所的に伸線加工の方向と結晶組織の長い方向が異なるため、伸線加工において断線しやすくなると考えられる。   Unlike the longitudinal direction of the electric wire conductor, the joint is plastically deformed in a direction approximately 90 degrees from the longitudinal direction. For this reason, the crystal structure of the copper alloy also has a long crystal structure in the direction different from the direction of about 90 degrees in the longitudinal direction and the joint portion. In general, in a metal structure, processing in a long direction of a crystal structure can be relatively tolerated. However, in the joint portion, a wire drawing process is locally different from a long direction of the crystal structure, and therefore, disconnection occurs in the wire drawing process. It is thought that it becomes easy to do.

また、バリの除去作業において、手作業などでは表面傷を除去することは難しく、傷が残存したまま伸線加工され、伸線ダイスを通過する際、破断の基点となると考えられる。   Further, in the burr removing operation, it is difficult to remove the surface flaws by manual work or the like, and it is considered that the surface flaws are drawn with the flaws remaining and become the starting point of breakage when passing through the drawing dies.

ついで熱処理を行う。本発明の熱処理は、少なくとも前記接合部を加熱装置により加熱する。加熱方法は通電方式でもバーナー方式でもかまわない。前記接合部の周囲も加熱してもかまわない。周囲とは接合部の前後1m程度の長さの部分を言う。加熱条件は、500〜850℃で、0.5〜30分が好ましい。熱処理温度が600度未満であると熱処理の効果が小さく断線しやすい。また、850℃を超える熱処理は過焼鈍の状態となり、靭性が低下して断線がしやすくなる。より好ましくは600〜800℃、さらに好ましくは650〜750℃である。   Next, heat treatment is performed. In the heat treatment of the present invention, at least the joint is heated by a heating device. The heating method may be an energization method or a burner method. The periphery of the joint may be heated. The periphery refers to a length of about 1 m before and after the joint. The heating conditions are 500 to 850 ° C. and preferably 0.5 to 30 minutes. When the heat treatment temperature is less than 600 degrees, the effect of the heat treatment is small and disconnection is likely. Moreover, the heat processing exceeding 850 degreeC will be in the state of over-annealing, toughness will fall and it will become easy to break. More preferably, it is 600-800 degreeC, More preferably, it is 650-750 degreeC.

熱処理時間が0.5分未満であれば熱処理の効果が小さく断線しやすい。また、熱処理時間が30分を超えると過焼鈍の状態となり、靭性が低下して断線がしやすくなる。より好ましくは1〜20分、さらに好ましくは2〜5分である。   If the heat treatment time is less than 0.5 minutes, the effect of the heat treatment is small and the wire breaks easily. Moreover, when heat processing time exceeds 30 minutes, it will be in the state of over-annealing and toughness will fall and it will become easy to disconnect. More preferably, it is 1-20 minutes, More preferably, it is 2-5 minutes.

本発明の熱処理を前記接合部に行うことで、前記接合部の結晶組織において加工歪の除去がなされたり、また一部の組織が部分的に再結晶したりすることで、伸線加工の方向と結晶組織の方向の向きの差が緩和される。これにより、前記接合部に表面傷が存在した場合であっても、前記接合部を伸線した際に破断しにくくなる。   By performing the heat treatment of the present invention on the joint, the processing strain is removed in the crystal structure of the joint, or a part of the structure is partially recrystallized, so that the direction of wire drawing And the difference in the orientation of the crystal structure is relaxed. Thereby, even if a surface flaw exists in the joint portion, it becomes difficult to break when the joint portion is drawn.

また、本発明の熱処理を接合処理の前に行った場合でも、同様に破断しにくくなる。これは、加工歪の除去や部分的な再結晶などが発生した状態で前記接合処理をすることで、前記接合部の結晶組織の方向の向きの差が緩和されるからである。   Further, even when the heat treatment of the present invention is performed before the bonding treatment, it is difficult to break similarly. This is because the difference in the orientation of the crystal structure direction of the joint portion is alleviated by performing the joining process in a state in which processing strain is removed or partial recrystallization occurs.

なお、熱処理は、前記接合部の付近の前後1m程度以内で行う。電線導体全体で熱処理をすると、電線導体を複数本束ねて撚線加工し自動車用電線とした際に、自動車用電線として所望の特性が得られないからである。   In addition, heat processing is performed within about 1 m before and behind the said junction part. When heat treatment is performed on the entire wire conductor, when a plurality of wire conductors are bundled and twisted to form an automobile wire, desired characteristics cannot be obtained as an automobile wire.

本発明の接合処理は、Cu−Sn合金線の電線導体同士の接合を行っても、異なる成分の電線導体同士の接合であっても良い。例えば、少なくとも一方の電線導体が、Snを0.1〜10質量%を含む銅合金であれば、もう一方の電線導体が従来品である純銅からなる銅合金であっても、本発明の効果は得られる。   The joining treatment of the present invention may be the joining of the wire conductors of Cu—Sn alloy wires or the joining of the wire conductors of different components. For example, if at least one electric wire conductor is a copper alloy containing 0.1 to 10% by mass of Sn, the effect of the present invention can be achieved even if the other electric wire conductor is a copper alloy made of pure copper, which is a conventional product. Is obtained.

以下、電線導体の製造方法について、詳細に説明する。本発明のSCRなどの連続鋳造装置により、所望の成分からなる銅合金の荒引線(外径8mm)を製造した。成分は、Snを1.0質量%添加した銅合金(Cu-1.0Sn)、及び純銅(Cu)を用いた。   Hereinafter, the manufacturing method of an electric wire conductor is demonstrated in detail. A copper alloy rough wire (outer diameter 8 mm) made of a desired component was produced by a continuous casting apparatus such as the SCR of the present invention. The components used were a copper alloy (Cu-1.0Sn) added with 1.0% by mass of Sn and pure copper (Cu).

ついで、前記荒引線を冷間加工により外形2.6mmまで伸線処理(第一の伸線処理)し、非酸化雰囲気中にて焼鈍処理をほどこした。ついで、外径0.2mm程度まで伸線処理(第二の伸線処理)して、自動車電線用素線とした。このとき、前記第二の伸線処理を施す際、電線導体の端部に接合処理及び熱処理を施した。前記接合処理と前記熱処理は、接合処理の後に熱処理を行ったもの(接合→熱処理)と、熱処理の後に接合処理を行ったもの(熱処理→接合)の両方を製造した。なお、比較例として熱処理を行わない電線導体も作製した。   Subsequently, the rough drawn wire was subjected to wire drawing processing (first wire drawing treatment) to an outer shape of 2.6 mm by cold working, and annealing treatment was performed in a non-oxidizing atmosphere. Next, wire drawing (second wire drawing) was performed to an outer diameter of about 0.2 mm to obtain an automobile electric wire. At this time, when the second wire drawing process was performed, the end portion of the wire conductor was subjected to a bonding process and a heat treatment. The bonding treatment and the heat treatment were both manufactured after the bonding treatment (bonding → heat treatment) and manufactured by the bonding treatment after the heat treatment (heat treatment → bonding). In addition, the electric wire conductor which does not heat-process as a comparative example was also produced.

前記接合処理は、市販のコールドウェルド工具(住電朝日精工製:ABM−5型)により行った。条件は、StopArmの間隔を40mm、押し回数を10回とした。次いで、接合部分をヤスリにてバリ取りを行い、電線導体の接合部の表面を研磨して、荒れや傷が無いことを目視にて確認した。   The joining process was performed using a commercially available cold weld tool (manufactured by Sumiden Asahi Seiko: ABM-5 type). The conditions were that the StopArm interval was 40 mm and the number of times of pressing was 10 times. Next, the joint portion was deburred with a file, and the surface of the joint portion of the wire conductor was polished, and it was visually confirmed that there was no roughness or scratch.

熱処理は、前記接合処理の後の場合は、前記接合部およびその前後1m程度を加熱炉の内部に通して加熱し、それ以外の電線導体は熱処理をしないようにした。前記接合処理の前に熱処理する場合は、接合処理をする予定の一方の電線導体の一端から0.5m程度、及び、もう一方の電線導体の一端から0.5m程度を加熱炉の内部に通して加熱し、それ以外の電線導体は熱処理をしないようにした。加熱条件は表1に記載の条件とした。   In the case of heat treatment after the joining treatment, the joining portion and about 1 m before and after the joining portion were heated through the inside of a heating furnace, and the other wire conductors were not subjected to heat treatment. When heat treatment is performed before the joining process, about 0.5 m from one end of one wire conductor to be joined and about 0.5 m from one end of the other wire conductor are passed through the inside of the heating furnace. The other wire conductors were not heat-treated. The heating conditions were those described in Table 1.

得られた電線導体の接合部を伸線装置に通し、外径0.2mmまで伸線加工を施した。その際、前記接合部における断線の発生の有無について評価した。評価は、接合部において断線が発生しなかった場合を「良」と判定して「○」印を付し、接合部において断線が発生した場合を「不良」と判定して「×」印を付した。結果は表1に示す。   The joint portion of the obtained electric wire conductor was passed through a wire drawing device, and was subjected to wire drawing to an outer diameter of 0.2 mm. At that time, the presence or absence of occurrence of disconnection at the joint was evaluated. In the evaluation, when the disconnection does not occur in the joint portion, it is determined as “good” and marked with “◯”, and when the disconnection occurs in the joint portion, it is determined as “bad” and the mark “×” is marked. It was attached. The results are shown in Table 1.

Figure 2010174347
Figure 2010174347

表1の結果から明らかなように、本発明の電線導体の製造方法により製造した電線導体の接合部は、伸線加工時の断線は発生しなかった。しかし、前記接合部に熱処理を行わなかった比較例では断線が発生していた。また熱処理条件を適切にしないと、断線が発生した。   As is clear from the results in Table 1, no breakage occurred during wire drawing in the joint portion of the wire conductor manufactured by the method for manufacturing a wire conductor of the present invention. However, disconnection occurred in the comparative example in which the heat treatment was not performed on the joint. Also, disconnection occurred if the heat treatment conditions were not appropriate.

Claims (3)

電線導体の接合部に接合処理と熱処理を行うことを特徴とする銅合金電線導体の製造方法であって、前記電線導体に第一の伸線処理し、前記接合処理し、前記接合部を500〜850℃で0.5〜30分熱処理し、第二の伸線処理することを特徴とする電線導体の製造方法。 A method of manufacturing a copper alloy electric wire conductor, wherein a bonding process and a heat treatment are performed on a bonding portion of the electric wire conductor, wherein the electric wire conductor is subjected to a first wire drawing treatment, the bonding treatment, and the bonding portion 500 A method for producing an electric wire conductor, comprising heat-treating at ~ 850 ° C for 0.5 to 30 minutes and performing a second wire drawing treatment. 電線導体の接合部に接合処理と熱処理を行うことを特徴とする銅合金電線導体の製造方法であって、前記電線導体に第一の伸線処理し、前記接合部を500〜850℃で0.5〜30分熱処理し、前記接合処理し、第二の伸線処理をすることを特徴とする電線導体の製造方法。 A method for producing a copper alloy electric wire conductor, characterized in that the electric wire conductor is subjected to a bonding treatment and a heat treatment, wherein the electric wire conductor is subjected to a first wire drawing treatment, and the bonding portion is heated at 500 to 850 ° C. Heat treatment for 5 to 30 minutes, the joining treatment, and the second wire drawing treatment. 前記電線導体は、少なくとも一方が、Snを0.1〜10質量%を含む銅合金からなることを特徴とする請求項1または請求項2に記載の電線導体の製造方法。 At least one of the said wire conductor consists of a copper alloy containing 0.1-10 mass% of Sn, The manufacturing method of the wire conductor of Claim 1 or Claim 2 characterized by the above-mentioned.
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106448945A (en) * 2016-12-01 2017-02-22 江苏省威能达电线电缆有限公司 Preparation method of outer aluminum mold line of compound aluminum conductor with soft core

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JPS6286151A (en) * 1985-09-24 1987-04-20 Kobe Steel Ltd Manufacture of wire rod for lead for pin grid array ic
JPH05266719A (en) * 1990-12-28 1993-10-15 Sumitomo Electric Ind Ltd Wire conductor for harness
JPH05311284A (en) * 1992-05-08 1993-11-22 Railway Technical Res Inst Copper alloy trolley wire
JP2002224851A (en) * 2001-01-31 2002-08-13 Hitachi Cable Ltd Method and apparatus for hot-pressure-welding tough pitch copper wire

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6286151A (en) * 1985-09-24 1987-04-20 Kobe Steel Ltd Manufacture of wire rod for lead for pin grid array ic
JPH05266719A (en) * 1990-12-28 1993-10-15 Sumitomo Electric Ind Ltd Wire conductor for harness
JPH05311284A (en) * 1992-05-08 1993-11-22 Railway Technical Res Inst Copper alloy trolley wire
JP2002224851A (en) * 2001-01-31 2002-08-13 Hitachi Cable Ltd Method and apparatus for hot-pressure-welding tough pitch copper wire

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106448945A (en) * 2016-12-01 2017-02-22 江苏省威能达电线电缆有限公司 Preparation method of outer aluminum mold line of compound aluminum conductor with soft core

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