JP2010103076A - Current collecting device for fuel cell, and method for controlling the same - Google Patents

Current collecting device for fuel cell, and method for controlling the same Download PDF

Info

Publication number
JP2010103076A
JP2010103076A JP2008315772A JP2008315772A JP2010103076A JP 2010103076 A JP2010103076 A JP 2010103076A JP 2008315772 A JP2008315772 A JP 2008315772A JP 2008315772 A JP2008315772 A JP 2008315772A JP 2010103076 A JP2010103076 A JP 2010103076A
Authority
JP
Japan
Prior art keywords
fuel cell
current collector
temperature
cell stack
voltage
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP2008315772A
Other languages
Japanese (ja)
Other versions
JP5472898B2 (en
Inventor
Zenjun Boku
善 淳 朴
Seong Pil Ryu
盛 弼 柳
Duck Whan Kim
悳 煥 金
Sang-Wook Kwon
相 旭 權
Nam Woo Lee
南 遇 李
Seo Ho Choi
瑞 浩 崔
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hyundai Motor Co
Original Assignee
Hyundai Motor Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hyundai Motor Co filed Critical Hyundai Motor Co
Publication of JP2010103076A publication Critical patent/JP2010103076A/en
Application granted granted Critical
Publication of JP5472898B2 publication Critical patent/JP5472898B2/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04007—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids related to heat exchange
    • H01M8/04037—Electrical heating
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/02—Details
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/02—Details
    • H01M8/0202—Collectors; Separators, e.g. bipolar separators; Interconnectors
    • H01M8/0204—Non-porous and characterised by the material
    • H01M8/0223—Composites
    • H01M8/0228—Composites in the form of layered or coated products
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04223—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids during start-up or shut-down; Depolarisation or activation, e.g. purging; Means for short-circuiting defective fuel cells
    • H01M8/04268—Heating of fuel cells during the start-up of the fuel cells
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04298—Processes for controlling fuel cells or fuel cell systems
    • H01M8/04313—Processes for controlling fuel cells or fuel cell systems characterised by the detection or assessment of variables; characterised by the detection or assessment of failure or abnormal function
    • H01M8/0432—Temperature; Ambient temperature
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04298—Processes for controlling fuel cells or fuel cell systems
    • H01M8/04313—Processes for controlling fuel cells or fuel cell systems characterised by the detection or assessment of variables; characterised by the detection or assessment of failure or abnormal function
    • H01M8/04537—Electric variables
    • H01M8/04544—Voltage
    • H01M8/04559—Voltage of fuel cell stacks
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/24—Grouping of fuel cells, e.g. stacking of fuel cells
    • H01M8/2465—Details of groupings of fuel cells
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2250/00—Fuel cells for particular applications; Specific features of fuel cell system
    • H01M2250/20—Fuel cells in motive systems, e.g. vehicle, ship, plane
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
    • Y02T90/00—Enabling technologies or technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02T90/40—Application of hydrogen technology to transportation, e.g. using fuel cells

Abstract

<P>PROBLEM TO BE SOLVED: To improve low temperature starting properties by shortening heating time when a process raising the temperature of a fuel cell is necessary, and prevent reduction of the life of a membrane electrode assembly caused by rising of open circuit voltage of the fuel cell generating when the electrical connection between the fuel cell and a load is cut in low output of the fuel cell. <P>SOLUTION: A self discharge mode conducting self discharge by short-circuiting first current collecting plates having resistance is changed over to a normal mode outputting from a second current collecting plate having low resistance to a load. When the open air temperature is lower than low temperature starting application temperature, the fuel cell is heated by changing over to the self discharge mode, and when the temperature becomes higher than critical lower limit temperature, the mode is changed over to the normal mode. When the electrical connection between the fuel cell and the load is cut, if the voltage of a fuel cell stack is higher than critical upper limit voltage, the mode is changed over to the self discharge mode, and reduction of the life of the membrane electrode assembly caused by no-load output voltage is prevented. <P>COPYRIGHT: (C)2010,JPO&INPIT

Description

本発明は水素を燃料とする燃料電池に係り、より詳しくは、水素を燃料とする燃料電池用集電装置及びその制御方法に関する。   The present invention relates to a fuel cell using hydrogen as a fuel, and more particularly to a current collector for a fuel cell using hydrogen as a fuel and a control method thereof.

水素を燃料とする燃料電池の一般的な構成例による一部分解概略図を図５に示す。
図５によれば、燃料電池は、外側にエンドプレートを設け内側に集電板を設けた集電装置を、燃料電池（スタック）の両側に設置して構成し、集電板によって燃料電池から電気を出力し、エンドプレートを貫通する配線を通じて負荷に電気を供給する。 FIG. 5 shows a partially exploded schematic view of a general configuration example of a fuel cell using hydrogen as a fuel.
According to FIG. 5, the fuel cell is configured by installing a current collector having an end plate on the outside and a current collector plate on the inner side on both sides of the fuel cell (stack). Electricity is output, and electricity is supplied to the load through wiring that penetrates the end plate.

図６は水素を燃料とする燃料電池スタックの一般的な構成例を示す概略断面図である。図６によれば、燃料電池スタックは、単位セルを連続的に配置した集合体である。各々の単位セルの中心部に、膜・電極接合体（ＭＥＡ）１１を設置する。膜・電極接合体１１は、水素を電子と水素イオンとに分離する触媒であるアノード（燃料極）１４と、一面がアノード１４に接し水素イオンを移動させる固体高分子電解質膜１０と、固体高分子電解質膜１０の他面に塗布され水素イオンと酸素とを反応させる触媒層であるカソード（空気極）１２と、から構成される。   FIG. 6 is a schematic cross-sectional view showing a general configuration example of a fuel cell stack using hydrogen as a fuel. According to FIG. 6, the fuel cell stack is an assembly in which unit cells are continuously arranged. A membrane / electrode assembly (MEA) 11 is installed at the center of each unit cell. The membrane / electrode assembly 11 includes an anode (fuel electrode) 14 that is a catalyst that separates hydrogen into electrons and hydrogen ions, a solid polymer electrolyte membrane 10 that is in contact with the anode 14 and moves hydrogen ions, A cathode (air electrode) 12 that is a catalyst layer that is applied to the other surface of the molecular electrolyte membrane 10 to react hydrogen ions and oxygen.

膜・電極接合体（ＭＥＡ）１１のカソード１２とアノード１４との夫々の外側面に、ガス拡散層（ＧＤＬ）１６と、ガスケット１８と、分離板２０と、を内側から外側へこの順に積層し、燃料（水素）を供給すると共に反応により生成した水を排出する流路を形成して単位セル３を構成する。尚、分離板２０は隣接する単位セル３と共有される。複数の単位セル２が直列に積層された燃料電池スタック２の最外側には、各構成要素を支持、固定するためのエンドプレート３０を設置する。   A gas diffusion layer (GDL) 16, a gasket 18, and a separator plate 20 are laminated in this order from the inside to the outside on the outer surfaces of the cathode 12 and the anode 14 of the membrane / electrode assembly (MEA) 11. The unit cell 3 is configured by forming a flow path for supplying fuel (hydrogen) and discharging water generated by the reaction. The separation plate 20 is shared with the adjacent unit cell 3. An end plate 30 for supporting and fixing each component is installed on the outermost side of the fuel cell stack 2 in which a plurality of unit cells 2 are stacked in series.

燃料電池スタック２は、アノード１４で水素の酸化反応が行われて水素イオンと電子とが発生し、生成した水素イオンはアノード１４から電解質膜１０を通過してカソード１２に移動し、電子は分離板２０を通過して隣接する単位セルのカソード１２に移動する。
カソード１２では、アノード１４から固体高分子電解質膜１０を通過して移動してきた水素イオンと、隣接する単位セルのアノード１４から分離板２０を通過して移動してきた電子と、空気中の酸素と、が関与する電気化学反応によって水が生成する。 In the fuel cell stack 2, hydrogen is oxidized at the anode 14 to generate hydrogen ions and electrons. The generated hydrogen ions move from the anode 14 to the cathode 12 through the electrolyte membrane 10, and the electrons are separated. It passes through the plate 20 and moves to the cathode 12 of the adjacent unit cell.
At the cathode 12, hydrogen ions that have moved from the anode 14 through the solid polymer electrolyte membrane 10, electrons that have moved from the anode 14 of the adjacent unit cell through the separation plate 20, oxygen in the air, and , Water is generated by an electrochemical reaction involving.

これによって、燃料電池スタック２の両端のアノード１４からカソード１２への電子の流れが生成し、生成された電気エネルギーは、エンドプレート３０の集電板３４を通して電気エネルギーを要する負荷４０に供給される。
電解質膜１０に高分子膜を用いた燃料電池は、作用温度が常温（約３０℃）〜約９０℃である。一個の単位セルが発電する電圧は理論的に１．２３Ｖであるが、電池の内部抵抗等の関係で実際は無負荷運出力電圧は約０．７Ｖ、有負荷出力電圧は約０．４Ｖ程度である。単位セルの出力電圧は小さいが、燃料電池スタックは直列に接続されているため、燃料電池スタック全体として外部負荷を駆動させるのに十分な電圧を生成することができる。 As a result, an electron flow from the anode 14 to the cathode 12 at both ends of the fuel cell stack 2 is generated, and the generated electric energy is supplied to the load 40 that requires electric energy through the current collecting plate 34 of the end plate 30. .
The fuel cell using the polymer membrane as the electrolyte membrane 10 has an operating temperature of room temperature (about 30 ° C.) to about 90 ° C. The voltage generated by one unit cell is theoretically 1.23V, but in actuality, the unloaded output voltage is about 0.7V and the loaded output voltage is about 0.4V due to the internal resistance of the battery. is there. Although the output voltage of the unit cell is small, since the fuel cell stack is connected in series, the fuel cell stack as a whole can generate a voltage sufficient to drive an external load.

図８は従来の水素を燃料とする燃料電池の集電装置の一例を示す概略図である。
図８を参照すると、集電装置は燃料電池（スタック）を支持し固定するエンドプレート３０と、燃料電池スタック２の内部で発生した電気が外部に漏れることを防止する絶縁板３２と、燃料電池スタックで発生した電気を集める集電板３４と、電気を外部に送る電極３５と、を含んで構成されていた。 FIG. 8 is a schematic diagram showing an example of a current collector for a fuel cell using hydrogen as a fuel.
Referring to FIG. 8, the current collector includes an end plate 30 that supports and fixes the fuel cell (stack), an insulating plate 32 that prevents electricity generated inside the fuel cell stack 2 from leaking to the outside, and a fuel cell. A current collecting plate 34 that collects electricity generated in the stack and an electrode 35 that sends electricity to the outside are included.

従来は、集電装置の集電板は、燃料電池から負荷への電気供給効率を最大にするために電気抵抗が最小である物質を使用していた。燃料電池の温度が正常温度であるときに、集電板に電気抵抗が最小である物質を使用すると燃料電池の電気供給効率を最大にすることができる。   Conventionally, the current collector plate of the current collector uses a material having a minimum electrical resistance in order to maximize the efficiency of supplying electricity from the fuel cell to the load. When the temperature of the fuel cell is a normal temperature, the electricity supply efficiency of the fuel cell can be maximized by using a material having a minimum electrical resistance for the current collector plate.

図７は、通常の燃料電池スタックの低温始動時の分離板の温度分布を説明するグラフである。
図７に示すように、例えば低温始動時のように、燃料電池の温度を正常温度まで上昇させる場合は、燃料電池スタックの中央部（Ｂ番の単位セル３中の分離板２０の温度）から両端のエンドプレート寄り（Ａ、Ｃ番の単位セル３中の分離板２０の温度）に行くほど分離板２０の温度が低くなるため、燃料電池スタック２全体の温度を正常温度まで上昇させるのに長い時間がかかることが多かった。 FIG. 7 is a graph for explaining the temperature distribution of the separation plate when the normal fuel cell stack is started at a low temperature.
As shown in FIG. 7, when the temperature of the fuel cell is raised to a normal temperature, for example, at a low temperature start-up, from the center of the fuel cell stack (the temperature of the separation plate 20 in the B-th unit cell 3). Since the temperature of the separation plate 20 decreases toward the end plates at both ends (the temperature of the separation plate 20 in the unit cells 3 of A and C), the temperature of the entire fuel cell stack 2 is raised to a normal temperature. Often it took a long time.

また、アイドリング中及び回生制動中に燃料電池と負荷との間の接続を切断し、消耗電力を減少させることによって、燃費の向上を図る技術が開示されている（例えば特許文献１を参照）。しかしこの方法は、頻繁に開回路電圧（ＯＣＶ：Ｏｐｅｎ Ｃｉｒｃｕｉｔ Ｖｏｌｔａｇｅ）状態となるため、燃料電池の最も重要な部品である膜・電極接合体の耐久寿命を短縮するという問題を生じることがある。   In addition, a technique for improving fuel consumption by disconnecting the connection between the fuel cell and the load during idling and regenerative braking to reduce power consumption is disclosed (see, for example, Patent Document 1). However, this method frequently results in an open circuit voltage (OCV) state, which may cause a problem of shortening the durability life of the membrane / electrode assembly that is the most important part of the fuel cell.

燃料電池と負荷間の接続を切断することにより膜・電極接合体の寿命が短縮される理由は下記の通りである。
燃料電池は、燃料電池スタックの負荷がかかった状態である有負荷出力電圧と、負荷が除去された無負荷状態の出力電圧である開回路電圧間の差が、他の電池、例えば硫酸亜鉛蓄電池よりも大きい。例えば、有負荷出力電圧が０．４Ｖであり、無負荷出力電圧が０．７Ｖである単位セルを３０枚積層したスタックの場合、有負荷出力電圧が１２Ｖとなり、無負荷出力電圧は２１Ｖとなる。 The reason why the life of the membrane-electrode assembly is shortened by cutting the connection between the fuel cell and the load is as follows.
A fuel cell has a difference between a load output voltage in which the fuel cell stack is loaded and an open circuit voltage that is an output voltage in a no-load state in which the load is removed. Bigger than. For example, in the case of a stack in which 30 unit cells having a load output voltage of 0.4V and a no load output voltage of 0.7V are stacked, the load output voltage is 12V and the no load output voltage is 21V. .

燃料電池スタックで生成された電力は、出力回路の一種であるＤＣ／ＤＣコンバータを経由して適切な電圧水準に安定化されて負荷に供給されることが多い。燃料電池スタックと負荷との間の電気的接続が切断されると、燃料電池スタックは無負荷状態で駆動されるため、１２Ｖであった出力電圧が２１Ｖまで増加する。電圧の上昇により膜・電極接合体に過酸化水素が発生し、この過酸化水素により膜・電極接合体の耐久寿命が著しく短縮されるという問題が起きることがあった。   In many cases, the electric power generated in the fuel cell stack is stabilized at an appropriate voltage level via a DC / DC converter, which is a kind of output circuit, and supplied to a load. When the electrical connection between the fuel cell stack and the load is disconnected, the fuel cell stack is driven in a no-load state, so that the output voltage, which was 12 V, increases to 21 V. There has been a problem that hydrogen peroxide is generated in the membrane-electrode assembly due to the voltage increase, and the durable life of the membrane-electrode assembly is remarkably shortened by this hydrogen peroxide.

更に、ＤＣ／ＤＣコンバータの構成素子も無負荷出力時の高電圧に耐えることができるような十分な容量を持たないために損傷を受けることがあった。
米国特許第７，１９６，４９２号 Further, the constituent elements of the DC / DC converter may be damaged because they do not have a sufficient capacity to withstand the high voltage during no-load output.
U.S. Patent No. 7,196,492

本発明は、例えば低温始動時のように、燃料電池を発熱させて燃料電池の温度を正常温度まで上昇させる低温始動運転の過程が必要な場合に、燃料電池の温度を正常温度まで上昇させる低温始動運転の時間を短縮し、低温始動性を改善することを目的とする。
また本発明は、アイドリング中や回生制動中のような燃料電池の低出力時に、燃費向上のために燃料電池と負荷間の電気的結合を切断する場合に発生する燃料電池の開回路電圧の高電圧に起因する膜・電極接合体の寿命低下を防止することを目的とする。 The present invention provides a low temperature that raises the temperature of the fuel cell to the normal temperature when a low temperature start operation process is required to heat the fuel cell and raise the temperature of the fuel cell to the normal temperature, for example, at the time of cold start. The purpose is to shorten the start-up operation time and improve the low-temperature startability.
In addition, the present invention provides a high open circuit voltage of the fuel cell that is generated when the electrical coupling between the fuel cell and the load is cut to improve fuel efficiency at low output of the fuel cell during idling or regenerative braking. The object is to prevent the lifetime of the membrane / electrode assembly from being reduced due to the voltage.

かかる目的を達成するための本発明の燃料電池用集電装置は、燃料電池スタックの両端に設置されたエンドプレートと、エンドプレートの内側に積層されて設置された絶縁板と、絶縁板の内側に互いに異なる抵抗値を持ち、互いに絶縁され、積層されて設置された複数個の集電板と、集電板の各々に一体に連結されて設置されエンドプレートの外部側に延伸された電極と、によって構成されたことを特徴とする。   In order to achieve this object, a current collector for a fuel cell of the present invention includes an end plate installed at both ends of a fuel cell stack, an insulating plate stacked inside the end plate, and an inner side of the insulating plate. A plurality of current collector plates that have different resistance values, are insulated from each other, and are stacked and installed; and electrodes that are integrally connected to each of the current collector plates and are extended to the outside of the end plate; It is characterized by comprising.

更に本発明の燃料電池用集電装置は、絶縁板の内側に膜・電極接合体の耐久損傷を引き起こさない最大電圧と最小電流とに対応する抵抗を有する第１集電板が付着して設置され、第１集電板の内側に絶縁材を間に置いて、最小抵抗特性を有する第２集電板が付着して設置され、第１集電板から第１電極が前記エンドプレートの外側に延伸され、第２集電板から第２電極が前記エンドプレートの外側に延伸されることが好ましい。   Furthermore, the fuel cell current collector of the present invention is installed by attaching a first current collector plate having a resistance corresponding to the maximum voltage and the minimum current that does not cause durable damage to the membrane-electrode assembly inside the insulating plate. A second current collector plate having a minimum resistance characteristic is attached to the inside of the first current collector plate with an insulating material therebetween, and the first electrode extends from the first current collector plate to the outside of the end plate. It is preferable that the second electrode is extended from the second current collector plate to the outside of the end plate.

また本発明は、第１電極及び第２電極とには燃料電池を正常モードまたは自己放電モードに切り替える選択スイッチを連結し、選択スイッチに制御装置を連結することが好ましい。   In the present invention, it is preferable that a selection switch for switching the fuel cell to a normal mode or a self-discharge mode is connected to the first electrode and the second electrode, and a control device is connected to the selection switch.

また本発明は、外気温度を検出する段階と、外気温度が低温始動適用温度より低い場合に、制御装置の制御命令により選択スイッチを自己放電モードに転換して、燃料電池スタックの電流を放電する段階と、自己放電モードに於いて燃料電池スタックの温度が正常モード時の臨界下限温度以上になった場合に、制御装置の制御命令により選択スイッチを正常モードに転換して、燃料電池スタックを正常モードに転換する段階と、を含むことが好ましい。   The present invention also includes a step of detecting the outside air temperature, and when the outside air temperature is lower than the low temperature start application temperature, the selection switch is switched to the self-discharge mode by the control command of the control device to discharge the current of the fuel cell stack. When the temperature of the fuel cell stack exceeds the critical lower limit temperature in the normal mode in the stage and the self-discharge mode, the fuel cell stack is made normal by changing the selection switch to the normal mode according to the control command of the control device. Converting to a mode.

また本発明は、アイドリングまたは回生制動が行われることを判断する段階と、アイドリングまたは回生制動時、燃料電池スタックの電圧が正常モード時の臨界上限電圧より高い場合、制御装置の制御命令により選択スイッチを自己放電モードに転換して、燃料電池スタックの電流を放電する段階と、自己放電モードに於いて燃料電池スタックの電圧が正常モード時の臨界上限電圧以下の場合に、制御装置の制御命令により選択スイッチを正常モードに転換して、燃料電池スタックを正常モードに転換する段階と、を含むことが好ましい。   The present invention also includes a step of determining that idling or regenerative braking is performed, and a selection switch based on a control command of the control device when the voltage of the fuel cell stack is higher than the critical upper limit voltage in the normal mode during idling or regenerative braking. Is switched to the self-discharge mode to discharge the current of the fuel cell stack, and when the voltage of the fuel cell stack is lower than the critical upper limit voltage in the normal mode in the self-discharge mode, the control command of the control device Preferably, the method includes the steps of switching the selection switch to a normal mode and switching the fuel cell stack to a normal mode.

本発明に係る燃料電池用集電装置及びその制御方法は、抵抗を有する第１集電板と接続する第１電極同志を短絡して燃料電池スタックで発電された電気の放電を行わせる自己放電モードと、燃料電池スタックで発電された電気を、抵抗が少ない素材で形成された第２集電板と接続する第２電極から負荷に出力する正常モードと、を切り替える選択スイッチを制御装置に接続する。   A fuel cell current collector and a control method therefor according to the present invention are a self-discharge in which electricity generated by a fuel cell stack is discharged by short-circuiting first electrodes connected to a first current collector plate having resistance. Connected to the control device is a selection switch that switches between the mode and the normal mode in which the electricity generated by the fuel cell stack is output to the load from the second electrode connected to the second current collector plate made of a material with low resistance To do.

制御装置は、外気の温度が低温始動適用温度より低い場合は、選択スイッチを自己放電モードに切り替えて低温始動運転を行い、自己放電モードに於いて燃料電池スタックの温度が臨界下限温度より高くなった場合に選択スイッチを正常モードに切り替えるようにする。これによって低温始動時に燃料電池スタックをより早く正常温度まで上昇させることができ、低温始動時間の短縮により低温始動性を改善することができ、更に、燃料電池スタックの低温始動前後の電圧偏差を縮小して、電力の安定な供給を行うことができる。   When the temperature of the outside air is lower than the low temperature start application temperature, the control device switches the selection switch to the self discharge mode to perform the low temperature start operation, and the temperature of the fuel cell stack becomes higher than the critical lower limit temperature in the self discharge mode. If the switch is selected, the selection switch is switched to the normal mode. As a result, the fuel cell stack can be raised to the normal temperature earlier during cold start, the cold start performance can be improved by shortening the cold start time, and the voltage deviation before and after the cold start of the fuel cell stack can be reduced. Thus, stable power supply can be performed.

また本発明によると、燃費向上のために燃料電池と負荷間の電気的結合を切断する際に、燃料電池スタックの電圧が臨界上限電圧より高い場合に選択スイッチを自己放電モードに切り替え、燃料電池スタックの電流（例えば、ＯＣＶ）を大きい抵抗を有する集電板を通して消費することで、燃料電池の無負荷出力電圧によって発生する膜・電極接合体の寿命低下現象を防止することができる。   Further, according to the present invention, when disconnecting the electrical coupling between the fuel cell and the load for improving fuel efficiency, the fuel cell is switched to the self-discharge mode when the voltage of the fuel cell stack is higher than the critical upper limit voltage. By consuming the stack current (for example, OCV) through the current collector plate having a large resistance, it is possible to prevent the life-deterioration phenomenon of the membrane / electrode assembly caused by the no-load output voltage of the fuel cell.

以下、添付図面を参照し、本発明に係る燃料電池用集電装置及びその制御方法について詳細に説明する。この記載は本発明を説明するためのものであって、この記載によって本発明の技術範囲を限定するものではない。本発明は、本発明の技術的範囲から逸脱しない範囲内で、多様に変更して実施することが可能である。   Hereinafter, a fuel cell current collector and a control method thereof according to the present invention will be described in detail with reference to the accompanying drawings. This description is for explaining the present invention, and is not intended to limit the technical scope of the present invention. The present invention can be implemented with various modifications without departing from the technical scope of the present invention.

図１は、本発明による燃料電池用集電装置を示す概略図である。
図５に示すように、燃料電池（スタック）で生成された電気エネルギーは、集電装置１を通して電気を必要とする負荷に供給される。 FIG. 1 is a schematic view showing a fuel cell current collector according to the present invention.
As shown in FIG. 5, the electrical energy generated in the fuel cell (stack) is supplied to a load that requires electricity through the current collector 1.

本発明の燃料電池用集電装置は、燃料電池スタック２の単位電池を積層した方向の両端の夫々に接して設けられ、燃料電池スタック２で発電された電気を出力する一対の集電装置１であって、図１に示すように、最外側に設けられたエンドプレート３０と、エンドプレート３０の内側に積層して設けられた絶縁板３２と、絶縁板３２の内側に、各々が異なった抵抗値を有し各々が燃料電池スタック２と接続し相互に積層され相互に絶縁されて設けられた複数個の集電板３４と、を含んで構成することが好ましい。
更に、各々の集電板３４に接続して形成され、相互に絶縁されてエンドプレートと絶縁板３０とを貫通してエンドプレート３０の外側まで延伸された複数個の電極を設けることが好ましい。 The fuel cell current collector of the present invention is provided in contact with both ends in the direction in which the unit cells of the fuel cell stack 2 are stacked, and outputs a pair of current collectors 1 that output electricity generated by the fuel cell stack 2. As shown in FIG. 1, the end plate 30 provided on the outermost side, the insulating plate 32 provided on the inner side of the end plate 30, and the inner side of the insulating plate 32 were different from each other. A plurality of current collecting plates 34 each having a resistance value, each connected to the fuel cell stack 2 and stacked and insulated from each other are preferably included.
Furthermore, it is preferable to provide a plurality of electrodes that are formed to be connected to each current collector plate 34, are insulated from each other, pass through the end plate and the insulating plate 30, and extend to the outside of the end plate 30.

複数個の集電板は、燃料電池スタック２及びその構成要素の設計によって、相互に異なる抵抗を有する集電板３４の任意の個数を積層して構成することができるが、本発明に係る集電板３４は、互いに異なる抵抗値を有する集電板を積層して設けた点に特徴がある。
本発明の、好ましい燃料電池用集電装置は、絶縁板の内側に積層して形成され、燃料電池スタックの単位セルを構成する膜・電極接合体を損傷することなく使用できる最高電圧と最小電流とに対応する抵抗値を有する第１集電板、及び、第１集電板の内側に積層して形成され、最小抵抗特性を有する第２集電板から成り、複数個の電極は、第１集電板に接続された第１電極、及び、第２集電板に接続された第２電極から成ることが好ましい。 The plurality of current collector plates can be configured by stacking an arbitrary number of current collector plates 34 having different resistances depending on the design of the fuel cell stack 2 and its components. The electric plate 34 is characterized in that it is provided by stacking current collecting plates having different resistance values.
A preferred current collector for a fuel cell of the present invention is formed by laminating inside an insulating plate, and can be used without damaging the membrane / electrode assembly constituting the unit cell of the fuel cell stack. And a second current collector plate having a minimum resistance characteristic, the first current collector plate having a resistance value corresponding to the first current collector plate, and a first current collector plate. It is preferable to comprise a first electrode connected to one current collector plate and a second electrode connected to the second current collector plate.

より詳細には、一対のエンドプレート３０の夫々の内側に積層されて設けられた絶縁板３２に、膜・電極接合体の耐久損傷を引き起こさないような最大電圧（Ｖｍａｘ）と最小電流（Ｉｍｉｎ）とに対応する抵抗（Ｒ／２＝Ｖｍａｘ／Ｉｍｉｎ）を有する第１集電板５２を積層するように設け、第１集電板５２の内側に、第１集電板５２と絶縁して、抵抗が少ない素材で形成された第２集電板５４を積層するように設けることが好ましい。
ここで、膜・電極接合体の耐久損傷を引き起こさないような最大電圧と最小電流とに対応する抵抗とは、換言すれば、燃料電池スタックの単位セルを構成する膜・電極接合体が耐久損傷を引き起こす電圧の最少値の電圧より低いの起電力を燃料電池スタックに生じさせるような抵抗値とそれによって生じる（最大）電流値のことであり、燃料電池スタックを断続を繰り返しても損傷せずに運転できるような抵抗を意味する。
第１集電板５２には、一体に接続した第１電極５６をエンドプレート３０と絶縁板３２とを貫通して外部に延伸し、第２集電板５４には、一体に接続した第２電極５８を、第１集電板５２と絶縁した状態で、第１集電板５２と絶縁板３２とエンドプレート３０とを貫通して外部に延伸することが好ましい。 More specifically, a maximum voltage (V max ) and a minimum current (I) that do not cause durable damage to the membrane-electrode assembly are formed on the insulating plate 32 provided on the inner side of each of the pair of end plates 30. min ) and a first current collector plate 52 having a resistance (R / 2 = V max / I min ) corresponding to the first current collector plate 52 is provided inside the first current collector plate 52. It is preferable to provide a second current collector plate 54 that is insulated and formed of a material with low resistance so as to be laminated.
Here, the resistance corresponding to the maximum voltage and the minimum current that does not cause the durable damage of the membrane / electrode assembly is, in other words, the durability of the membrane / electrode assembly constituting the unit cell of the fuel cell stack. This is the resistance value that causes the fuel cell stack to generate an electromotive force that is lower than the minimum value of the voltage that causes the fuel cell, and the (maximum) current value that is generated thereby. Even if the fuel cell stack is repeatedly interrupted, it will not be damaged. It means the resistance that can drive.
A first electrode 56 that is integrally connected to the first current collector plate 52 extends outside through the end plate 30 and the insulating plate 32, and a second electrode that is integrally connected to the second current collector plate 54. In a state where the electrode 58 is insulated from the first current collecting plate 52, it is preferable to extend outside through the first current collecting plate 52, the insulating plate 32, and the end plate 30.

膜・電極接合体を損傷することなく使用できる最大電圧と最小電流とは、膜・電極接合体の特性値として公表されている場合が多いが、公表されていない場合には実験的に求めることができる。
例えば、燃料電池４と、可変抵抗発生手段と、電流測定手段と、電圧測定手段と、で回路を形成し、可変抵抗発生手段の抵抗値を変化させて電圧と電流を変化させ、燃料電池４が過酸化水素を発生しない状態の最大の電圧と電流とを求めればよい。 The maximum voltage and minimum current that can be used without damaging the membrane / electrode assembly are often published as characteristic values of the membrane / electrode assembly, but if they are not published, they should be determined experimentally. Can do.
For example, the fuel cell 4, the variable resistance generating means, the current measuring means, and the voltage measuring means form a circuit, and the voltage and current are changed by changing the resistance value of the variable resistance generating means. What is necessary is just to obtain | require the maximum voltage and electric current of the state which does not generate | occur | produce hydrogen peroxide.

最小抵抗特性を有する集電板とは、燃料電池スタック２で発電した電気エネルギーを最大限に負荷４０に供給できるように配備された集電板である。具体的には、素材として良導体を用いて形成した集電板を含むことが出来る。良導体とは、具体例を挙げれば、白金と金と銀と銅とアルミニウムとを含む金属、合金、炭素、電解質溶液、有機導電体を含むものであるが、これらに限られるものではない。   The current collector plate having the minimum resistance characteristic is a current collector plate arranged so that the electric energy generated by the fuel cell stack 2 can be supplied to the load 40 to the maximum extent. Specifically, a current collector plate formed using a good conductor as a material can be included. Specific examples of good conductors include metals, alloys, carbon, electrolyte solutions, and organic conductors including platinum, gold, silver, copper, and aluminum, but are not limited thereto.

図２は、本発明による燃料電池用集電装置の正常モード及び自己放電モードのための回路構成図である。
図２に示すように、本発明による燃料電池用集電装置は、第１電極５６と第２電極５８とに、第１電極５６同士を短絡して燃料電池スタック２に自己放電を行わせる自己放電モードと、燃料電池スタック２で発電された電気を第２電極５８から負荷４０に出力する正常モードと、に切り替え可能な選択スイッチ６０を接続し、選択スイッチを制御装置７０に接続することが好ましい。 FIG. 2 is a circuit configuration diagram for the normal mode and the self-discharge mode of the fuel cell current collector according to the present invention.
As shown in FIG. 2, the current collector for a fuel cell according to the present invention is configured to self-discharge the fuel cell stack 2 by short-circuiting the first electrodes 56 to the first electrode 56 and the second electrode 58. A selection switch 60 that can be switched between a discharge mode and a normal mode in which electricity generated by the fuel cell stack 2 is output from the second electrode 58 to the load 40 is connected, and the selection switch is connected to the control device 70. preferable.

即ち、自己放電モードでは、燃料電池スタック２で発電された電流は、膜・電極接合体１１の損傷を引き起こさないような最大電圧（Ｖｍａｘ）と最小電流（Ｉｍｉｎ）とに対応する抵抗（一対の第１集電板５２を含む回路全体のの合計抵抗値、Ｒ＝Ｖｍａｘ／Ｉｍｉｎ、以下同じ）を有する第１集電板５２同士が第１電極５６を介して短絡される。これによって、燃料電池スタック２で発電された電流は、膜・電極接合体１１の耐久損傷を引き起こさずに自己放電を行うことができる。 That is, in the self-discharge mode, the current generated by the fuel cell stack 2 is a resistance corresponding to a maximum voltage (V max ) and a minimum current (I min ) that do not cause damage to the membrane-electrode assembly 11. The first current collecting plates 52 having a total resistance value of the entire circuit including the pair of first current collecting plates 52, R = V max / I min (hereinafter the same) are short-circuited via the first electrode 56. As a result, the current generated by the fuel cell stack 2 can be self-discharged without causing endurance damage to the membrane-electrode assembly 11.

正常モードでは、燃料電池スタック２で発電された電流は、良導体で形成された第２集電板５４と接続された第２電極５８から負荷４０に送電される。
選択スイッチ６０に制御装置７０を接続することが好ましい。制御装置７０は、選択スイッチ６０を正常モードまたは自己放電モードに切り替えることができる。 In the normal mode, the current generated by the fuel cell stack 2 is transmitted to the load 40 from the second electrode 58 connected to the second current collector 54 formed of a good conductor.
It is preferable to connect the control device 70 to the selection switch 60. The control device 70 can switch the selection switch 60 to the normal mode or the self-discharge mode.

以下、集電装置１に対する動作及びその制御方法を説明する。
本発明に係る燃料電池の作動温度は常温〜９０°である。常温（約３０℃）より低いと発電能力が低下し、９０℃より高いと、膜・電極接合体１１が熱による損傷を受ける。このため、燃料電池を好適に運転できる臨界温度を予め設定することが多い。臨界温度は臨界上限温度と臨界下限温度を含むことができる。
特に、燃料電池の始動時には、外気温の低い場合には燃料電池は充分な性能ができないので低温始動運転を行って燃料電池の温度を、例えば前記臨界下限温度まで上げることが好ましい。低温始動運転を行うか行わないかを判断する外気温の判断基準として、低温始動適用温度を予め設定することが多い。
また、本発明に係る燃料電池は、有負荷出力電圧は、燃料電池の内部抵抗によって、出力する電流量と負の相関を有する。このため、燃料電池を好適に運転できる臨界上限電圧と臨海下限電圧とを予め設定することが多い。 Hereinafter, the operation | movement with respect to the current collector 1 and its control method are demonstrated.
The operating temperature of the fuel cell according to the present invention is from room temperature to 90 °. When the temperature is lower than room temperature (about 30 ° C.), the power generation capacity is lowered. When the temperature is higher than 90 ° C., the membrane / electrode assembly 11 is damaged by heat. For this reason, a critical temperature at which the fuel cell can be suitably operated is often set in advance. The critical temperature can include an upper critical temperature and a lower critical temperature.
In particular, when starting the fuel cell, it is preferable to raise the temperature of the fuel cell to, for example, the critical lower limit temperature by performing a low temperature starting operation because the fuel cell cannot perform sufficiently when the outside air temperature is low. In many cases, the low temperature start application temperature is set in advance as a reference for the outside air temperature for determining whether or not to perform the low temperature start operation.
Further, in the fuel cell according to the present invention, the load output voltage has a negative correlation with the output current amount due to the internal resistance of the fuel cell. For this reason, the critical upper limit voltage and the coastal lower limit voltage at which the fuel cell can be suitably operated are often set in advance.

本発明は、前記燃料電池用集電装置を制御する方法であって、制御装置が、外気の温度を測定する段階と、外気の温度と予め設定した低温始動適用温度とを比較する段階と、外気の温度が低温始動適用温度より低い場合は選択スイッチを自己放電モードに切り替える段階と、自己放電モードに於いて燃料電池スタックの温度を測定し、燃料電池スタックの温度を予め定めた正常モード時の臨界下限温度と比較する段階と、燃料電池スタックの温度が臨界下限温度より高くなった場合に選択スイッチを正常モードに切り替える段階と、を含んで燃料電池用集電装置を制御することができる。   The present invention is a method of controlling the fuel cell current collector, wherein the control device measures the temperature of the outside air, and compares the temperature of the outside air with a preset cold start application temperature; When the outside air temperature is lower than the cold start application temperature, switch the selection switch to the self-discharge mode, measure the temperature of the fuel cell stack in the self-discharge mode, and set the temperature of the fuel cell stack in the normal mode set in advance And a step of switching the selection switch to a normal mode when the temperature of the fuel cell stack becomes higher than the critical lower limit temperature, and the fuel cell current collector can be controlled. .

燃料電池４の低温始動時の制御過程を、更に詳細に説明すると下記の通りである。
図３は、本発明に１実施例による燃料電池の低温始動時の動作を示フローチャートである。
図３に示すように、燃料電池の始動時に制御装置７０は、外気温度（Ｔａｉｒ）を測定する（Ｓ１０１）。
次いで、制御装置７０は、外気温度と予め設定した低温始動適用温度（Ｔ１）とを比較し、外気温度が低温始動適用温度以上であれば（Ｔａｉｒ≧Ｔ１、Ｓ１０２、Ｎｏ）そのまま燃料電池４を始動する。もし、外気温度が低温始動適用温度より低いと判断すると（Ｔａｉｒ＜Ｔ１、Ｓ１０２、Ｙｅｓ）、制御装置７０は、燃料電池４の低温始動条件が満たされたと判断し、制御装置７０の制御により選択スイッチ６０を自己放電モードに切り替える（Ｓ１０３）。 The control process when the fuel cell 4 is started at a low temperature will be described in more detail as follows.
FIG. 3 is a flowchart showing the operation of the fuel cell according to one embodiment of the present invention at the low temperature start.
As shown in FIG. 3, the control device 70 measures the outside air temperature (T air ) when starting the fuel cell (S101).
Next, the control device 70 compares the outside air temperature with a preset low temperature start application temperature (T 1 ), and if the outside air temperature is equal to or higher than the low temperature start application temperature (T air ≧ T 1 , S102, No), the fuel is used as it is. The battery 4 is started. If it is determined that the outside air temperature is lower than the low temperature start application temperature (T air <T 1 , S102, Yes), the control device 70 determines that the low temperature start condition of the fuel cell 4 is satisfied, and the control of the control device 70 is performed. Thus, the selection switch 60 is switched to the self-discharge mode (S103).

これによって、燃料電池スタック２で発電された電流は、図２に太線で示した自己放電モードの電流の流れに沿って、燃料電池スタック２と、抵抗（Ｒ＝Ｖｍａｘ／Ｉｍｉｎ）を有する第１集電板５２と、第１電極５６と、選択スイッチ６０と、で構成された回路に沿って、膜・電極接合体１１の耐久損傷を引き起こさずに自己放電を行うことができ、燃料電池スタック２を加温することができる。 Accordingly, the current generated by the fuel cell stack 2 has the resistance (R = V max / I min ) along the flow of the current in the self-discharge mode shown by the thick line in FIG. A self-discharge can be performed along the circuit constituted by the first current collector plate 52, the first electrode 56, and the selection switch 60 without causing durable damage to the membrane-electrode assembly 11, and the fuel. The battery stack 2 can be heated.

制御装置７０は、自己放電モードに於いて燃料電池スタック２の温度（Ｔｓｔａｃｋ）を測定し、該燃料電池スタック２の温度が予め定めた正常モードの臨界下限温度（Ｔ２）以下であれば（Ｔｓｔａｃｋ≦Ｔ２、Ｓ１０４、Ｎｏ）自己放電モードを継続する。燃料電池スタック２の温度が予め定めた臨界下限温度より高くなれば（Ｔｓｔａｃｋ＞Ｔ２、Ｓ１０４、Ｙｅｓ）、制御装置７０は選択スイッチ６０を正常モードに切り替える（Ｓ１０５）。 The control device 70 measures the temperature (T stack ) of the fuel cell stack 2 in the self-discharge mode, and if the temperature of the fuel cell stack 2 is equal to or lower than a predetermined critical mode lower limit temperature (T 2 ). (T stack ≦ T 2 , S104, No) The self-discharge mode is continued. If the temperature of the fuel cell stack 2 becomes higher than the predetermined critical lower limit temperature (T stack > T 2 , S104, Yes), the control device 70 switches the selection switch 60 to the normal mode (S105).

これによって、燃料電池スタック２で生成された電気エネルギーは、図２の実線で示した正常モードの電流の流れ、即ち、燃料電池スタック２と、良導体で形成された第２集電板５４と、第２電極５８と、選択スイッチ６０と、で構成される回路に沿って燃料電池４の電流が電気エネルギーを必要とする負荷４０に供給される。   Accordingly, the electric energy generated in the fuel cell stack 2 is a normal mode current flow indicated by a solid line in FIG. 2, that is, the fuel cell stack 2 and the second current collector plate 54 formed of a good conductor, A current of the fuel cell 4 is supplied to a load 40 that requires electric energy along a circuit constituted by the second electrode 58 and the selection switch 60.

低温始動時のように燃料電池４の自己発熱による加温が必要な場合は、抵抗を有する第１集電板５２を通して燃料電池スタック２の自己電流が放電されるようにすることによって、燃料電池スタック２の温度をより早く正常水準まで回復することができるため、低温始動運転時間を短縮することにより低温始動性を改善することができる。更に、電気は燃料電池スタック２の温度が正常モードの臨界下限温度以上になってから供給されるので、供給される電気の電圧偏差が小さく、安定な電力を供給することができる。   When heating by self-heating of the fuel cell 4 is required as at low temperature start, the self-current of the fuel cell stack 2 is discharged through the first current collecting plate 52 having resistance, whereby the fuel cell Since the temperature of the stack 2 can be recovered to the normal level earlier, the low temperature startability can be improved by shortening the low temperature start operation time. Furthermore, since electricity is supplied after the temperature of the fuel cell stack 2 becomes equal to or higher than the critical lower limit temperature of the normal mode, the voltage deviation of the supplied electricity is small and stable power can be supplied.

次に、燃料電池４の低パワー動作時の制御過程を説明する。
本発明は、前記燃料電池用集電装置を制御する方法であって、制御装置が、燃料電池４の低パワー動作、例えばアイドリングまたは回生制動が行われているかどうかを判断する段階と、アイドリングまたは回生制動が行われていることを確認した際に、燃料電池スタックの電圧を測定し、燃料電池スタックの電圧を予め定めた正常モード時の臨界上限電圧と比較する段階と、燃料電池スタックの電圧が臨界上限電圧より高い場合に選択スイッチを自己放電モードに切り替える段階と、自己放電モードに於いて、燃料電池スタックの電圧が臨界上限電圧より低いか又は同一となった場合に選択スイッチを正常モードに切り替える段階と、を含むことが好ましい。 Next, a control process during low power operation of the fuel cell 4 will be described.
The present invention is a method for controlling the fuel cell current collector, wherein the controller determines whether low power operation of the fuel cell 4 is being performed, for example, idling or regenerative braking, When the regenerative braking is confirmed, the voltage of the fuel cell stack is measured, and the voltage of the fuel cell stack is compared with a predetermined critical upper limit voltage in normal mode, and the voltage of the fuel cell stack Switching the selection switch to the self-discharge mode when the voltage is higher than the critical upper limit voltage, and in the self-discharge mode, when the voltage of the fuel cell stack is lower than or equal to the critical upper limit voltage, the selection switch is set to the normal mode. Preferably, the step of switching to is included.

図４は、本発明の１実施例による燃料電池の低パワー作動時の動作を説明するフローチャートである。
第４図によれば、制御装置７０は、アイドリング中または回生制動中などの原因によって燃料電池４が低パワー作動中であるという情報を上位制御装置から受信し確認する（Ｓ２０１）。次いで、制御装置７０は、燃料電池スタック２の出力電圧（Ｖｓｔａｃｋ）を測定する。 FIG. 4 is a flowchart for explaining the operation of the fuel cell according to one embodiment of the present invention during low power operation.
According to FIG. 4, the control device 70 receives and confirms information from the host control device that the fuel cell 4 is operating at low power due to idling or regenerative braking (S201). Next, the control device 70 measures the output voltage (V stack ) of the fuel cell stack 2.

制御装置７０は、燃料電池スタック２の出力電圧と予め定めた正常モード時の臨界上限電圧（Ｖ１）とを比較し、燃料電池スタック２の出力電圧が臨界上限電圧以下の場合（Ｖｓｔａｃｋ≦Ｖ１、Ｓ２０２、Ｎｏ）は、情報確認段階（Ｓ２０１）へ戻る。燃料電池スタック２の出力電圧が臨界上限電圧より高いと判断すると（Ｖｓｔａｃｋ＞Ｖ１、Ｓ２０２、Ｙｅｓ）、制御装置７０の制御により選択スイッチ６０を自己放電モードに切り替え、燃料電池スタック２の電流を自己放電する（Ｓ２０３）。 The control device 70 compares the output voltage of the fuel cell stack 2 with a predetermined critical upper limit voltage (V 1 ) in the normal mode, and when the output voltage of the fuel cell stack 2 is equal to or lower than the critical upper limit voltage (Vstack ≦ V 1 , S202, No) returns to the information confirmation stage (S201). If it is determined that the output voltage of the fuel cell stack 2 is higher than the critical upper limit voltage (V stack > V 1 , S202, Yes), the selection switch 60 is switched to the self-discharge mode under the control of the control device 70, and the current of the fuel cell stack 2 is Is self-discharged (S203).

制御装置７０は、自己放電モード中は燃料電池スタック２の電圧を測定し、燃料電池スタック２の電圧が臨界上限電圧より大きい場合（Ｖｓｔａｃｋ＞Ｖ１、Ｓ２０４、Ｎｏ）は、自己放電モードを継続する。
その後、燃料電池スタックの電圧が臨界上限電圧以下になると（Ｖｓｔａｃｋ≦Ｖ１、Ｓ２０４、Ｎｏ）、制御装置７０の制御により選択スイッチ６０は正常モードに切り替えられ、燃料電池４が正常モードで運転される（Ｓ２０５）。 The control device 70 measures the voltage of the fuel cell stack 2 during the self-discharge mode. If the voltage of the fuel cell stack 2 is larger than the critical upper limit voltage (V stack > V 1 , S204, No), the control device 70 sets the self-discharge mode. continue.
Thereafter, when the voltage of the fuel cell stack becomes equal to or lower than the critical upper limit voltage (V stack ≦ V 1 , S204, No), the selection switch 60 is switched to the normal mode by the control of the control device 70, and the fuel cell 4 is operated in the normal mode. (S205).

これによって、燃料電池スタック２で生成された電気エネルギーは、図２の実線で示した正常モードの電流の流れ、即ち、燃料電池スタック２と、良導体で形成された第２集電板５４と、第２電極５８と、選択スイッチ６０と、で構成された回路に沿って燃料電池４の電流が電気エネルギーを必要とする負荷４０に供給される。   Accordingly, the electric energy generated in the fuel cell stack 2 is a normal mode current flow indicated by a solid line in FIG. 2, that is, the fuel cell stack 2 and the second current collector plate 54 formed of a good conductor, A current of the fuel cell 4 is supplied to a load 40 that requires electric energy along a circuit constituted by the second electrode 58 and the selection switch 60.

このように、アイドリング時や回生制動時のように、燃料電池４からの低パワーを使用する際、燃料電池４スタックの自己電流（例えば、ＯＣＶによる電流）が、大きい抵抗を有する第１集電板を通して消耗されるようにすることで、燃費向上のために燃料電池４と負荷間の電気的接続を人為的にショートさせるときに、無負荷出力電圧（ＯＣＶによる電流）により膜・電極接合体（ＭＥＡ）に過酸化水素が発生し、この過酸化水素により膜・電極接合体（ＭＥＡ）の耐久寿命が低下するという現象を阻止することができる。   As described above, when the low power from the fuel cell 4 is used during idling or regenerative braking, the self-current (for example, current due to the OCV) of the fuel cell 4 stack has a large resistance. When the electrical connection between the fuel cell 4 and the load is artificially short-circuited so that the fuel consumption is improved by exhausting through the plate, the membrane / electrode assembly is caused by the no-load output voltage (current by OCV). The phenomenon that hydrogen peroxide is generated in (MEA) and the durable life of the membrane-electrode assembly (MEA) is reduced by this hydrogen peroxide can be prevented.

本発明による燃料電池の集電装置を示す概略図である。It is the schematic which shows the current collector of the fuel cell by this invention. 本発明による燃料電池の集電装置の正常モード及び自己放電モードのための回路構成図である。FIG. 3 is a circuit configuration diagram for a normal mode and a self-discharge mode of a fuel cell current collector according to the present invention; 本発明の１実施例による燃料電池の低温始動時の動作を示すフローチャートである。3 is a flowchart showing an operation at a low temperature start of the fuel cell according to one embodiment of the present invention. 水素を燃料とする燃料電池の一般的な構成例による一部分解概略図である。It is a partial decomposition schematic diagram by the general structural example of the fuel cell which uses hydrogen as a fuel. 水素を燃料とする通常の燃料電池の構成を示す一部分解概略図である。It is a partial decomposition schematic diagram showing the composition of the usual fuel cell which uses hydrogen as fuel. 水素を燃料とする燃料電池スタックの一般的な構成例を示す概略断面図である。It is a schematic sectional drawing which shows the general structural example of the fuel cell stack which uses hydrogen as a fuel. 通常の燃料電池スタックの低温始動時の分離板の温度分布を説明するグラフである。It is a graph explaining the temperature distribution of the separation plate at the time of low temperature start of a normal fuel cell stack. 従来の水素を燃料とする燃料電池の集電装置を示す概略図である。It is the schematic which shows the current collector of the fuel cell which uses the conventional hydrogen as a fuel.

符号の説明Explanation of symbols

１ 集電装置
２ 燃料電池スタック
３ 単位セル
４ 燃料電池
１０ 電解質膜
１１ 膜・電極接合体
１２ カソード
１４ アノード
１６ ガス拡散層
１８ ガスケット
２０ 分離板
３０ エンドプレート
３２ 絶縁板
３４ 集電板
４０ 負荷
５２ 第１集電板
５４ 第２集電板
５６ 第１電極
５８ 第２電極
６０ 選択スイッチ
７０ 制御装置 DESCRIPTION OF SYMBOLS 1 Current collector 2 Fuel cell stack 3 Unit cell 4 Fuel cell 10 Electrolyte membrane 11 Membrane electrode assembly 12 Cathode 14 Anode 16 Gas diffusion layer 18 Gasket 20 Separation plate 30 End plate 32 Insulation plate 34 Current collection plate 40 Load 52 First 1 current collector plate 54 2nd current collector plate 56 first electrode 58 second electrode 60 selection switch 70 control device

Claims (5)

複数の単位電池を積層して構成された燃料電池スタックの、単位電池を積層した方向の最外側に設置された一対のエンドプレートと、
該エンドプレートの内側に積層されて設置された一対の絶縁板と、
前記絶縁板の内側に、前記燃料電池スタックと接続し、互いに異なる抵抗値を持ち、互に絶縁され、相互に積層されて設置された複数個の集電板と、
前記集電板の各々に一体に連結されて設置され前記エンドプレートの外部側に延伸された電極と、
によって構成されたことを特徴とする燃料電池用集電装置。 A pair of end plates installed on the outermost side in the direction in which the unit cells are stacked in a fuel cell stack configured by stacking a plurality of unit cells,
A pair of insulating plates stacked inside the end plate; and
A plurality of current collector plates connected to the fuel cell stack inside the insulating plate, having different resistance values, insulated from each other, and stacked on each other;
An electrode integrally connected to each of the current collector plates and extended to the outside of the end plate;
A current collector for a fuel cell, comprising: 前記絶縁板の内側に膜・電極接合体の損傷を引き起こさない最大電圧と最小電流とに対応する抵抗を有する第１集電板が付着して設置され、前記第１集電板の内側に絶縁材を間に置いて、最小抵抗特性を有する第２集電板が付着して設置され、前記第１集電板から第１電極が前記エンドプレートの外側に延伸され、前記第２集電板から第２電極が前記エンドプレートの外側に延伸されたことを特徴とする請求項１記載の燃料電池用集電装置。   A first current collector plate having a resistance corresponding to a maximum voltage and a minimum current that does not cause damage to the membrane-electrode assembly is attached to the inside of the insulating plate, and is insulated inside the first current collector plate. A second current collector plate having a minimum resistance characteristic is attached with a material in between, and a first electrode is extended from the first current collector plate to the outside of the end plate, and the second current collector plate 2. The current collector for a fuel cell according to claim 1, wherein the second electrode extends from the end plate to the outside of the end plate. 前記第１電極と前記第２電極とに前記燃料電池を正常モードまたは自己放電モードに切り替える選択スイッチを連結し、前記選択スイッチに制御装置を連結することを特徴とする、請求項２記載の燃料電池用集電装置。   The fuel according to claim 2, wherein a selection switch for switching the fuel cell to a normal mode or a self-discharge mode is connected to the first electrode and the second electrode, and a control device is connected to the selection switch. Battery current collector. 外気温度を検出する段階と、
外気温度が低温始動適用温度より低い場合に、制御装置の制御命令により選択スイッチを自己放電モードに転換して燃料電池スタックの電流を放電する段階と、
前記自己放電モードに於いて、前記燃料電池スタックの温度が正常モード時の臨界下限温度以上になった場合に、前記制御装置の制御命令により前記選択スイッチを正常モードに転換して、前記燃料電池スタックを正常モードに転換する段階と、
を含むことを特徴とする燃料電池用集電装置制御方法。 Detecting the outside air temperature;
When the outside air temperature is lower than the cold start application temperature, the step of switching the selection switch to the self-discharge mode by the control command of the control device and discharging the current of the fuel cell stack,
In the self-discharge mode, when the temperature of the fuel cell stack becomes equal to or higher than the critical lower limit temperature in the normal mode, the selection switch is switched to the normal mode by a control command of the control device, and the fuel cell Switching the stack to normal mode;
A method of controlling a current collector for a fuel cell, comprising: アイドリングまたは回生制動が行われることを判断する段階と、
アイドリングまたは回生制動時、燃料電池スタックの電圧が正常モード時の臨界上限電圧より高い場合、制御装置の制御命令により選択スイッチを自己放電モードに転換して、前記燃料電池スタックの電流を放電する段階と、
前記自己放電モードに於いて、前記燃料電池スタックの電圧が臨界上限電圧以下の場合に、前記制御装置の制御命令により前記選択スイッチを正常モードに転換して、前記燃料電池スタックを正常モードに転換する段階と、
を含むことを特徴とする燃料電池用集電装置制御方法。
Determining that idling or regenerative braking will occur;
When idling or regenerative braking, when the voltage of the fuel cell stack is higher than the critical upper limit voltage in the normal mode, the selection switch is switched to the self-discharge mode according to the control command of the control device to discharge the current of the fuel cell stack When,
In the self-discharge mode, when the voltage of the fuel cell stack is equal to or lower than the critical upper limit voltage, the selection switch is switched to the normal mode by the control command of the control device, and the fuel cell stack is switched to the normal mode. And the stage of
A method of controlling a current collector for a fuel cell, comprising:
JP2008315772A 2008-10-21 2008-12-11 Fuel cell current collector and control method thereof Expired - Fee Related JP5472898B2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
KR1020080103002A KR101071769B1 (en) 2008-10-21 2008-10-21 Endplate collector for fuel cell and method for controlling the same
KR10-2008-0103002 2008-10-21

Publications (2)

Publication Number Publication Date
JP2010103076A true JP2010103076A (en) 2010-05-06
JP5472898B2 JP5472898B2 (en) 2014-04-16

Family

ID=42108940

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2008315772A Expired - Fee Related JP5472898B2 (en) 2008-10-21 2008-12-11 Fuel cell current collector and control method thereof

Country Status (3)

Country Link
US (1) US8178253B2 (en)
JP (1) JP5472898B2 (en)
KR (1) KR101071769B1 (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8697307B2 (en) 2011-08-17 2014-04-15 Samsung Sdi Co., Ltd. Solid oxide fuel cell stack
US8835072B2 (en) 2011-10-05 2014-09-16 Samsung Sdi Co., Ltd. Solid oxide fuel cell stacks and fuel cell module having the same
JP2016219337A (en) * 2015-05-25 2016-12-22 本田技研工業株式会社 Fuel cell stack
CN114649549A (en) * 2022-03-30 2022-06-21 潍柴动力股份有限公司 Battery heating control method, device and system and storage medium

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101271858B1 (en) 2011-03-08 2013-06-07 로베르트 보쉬 게엠베하 Battery pack with enhanced radiating ability
KR101328336B1 (en) * 2011-12-27 2013-11-11 주식회사 포스코 Cathode current collector for solid oxide fuel cell, method for manufacturing the same and solid oxide fuel cell comprising the same
KR101646380B1 (en) 2014-11-20 2016-08-08 현대자동차주식회사 Apparatus for preventing moisture condensation
CN113299944A (en) * 2020-02-24 2021-08-24 上海神力科技有限公司 Fuel cell capable of being started at low temperature
CN112952153B (en) * 2021-01-28 2022-09-20 华中科技大学 Proton exchange membrane fuel cell loaded with cold start system

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2003331891A (en) * 2002-05-13 2003-11-21 Mitsubishi Heavy Ind Ltd Fuel cell system, and starting method of fuel cell system
JP2005093282A (en) * 2003-09-18 2005-04-07 Matsushita Electric Ind Co Ltd Polymer electrolyte fuel cell system and its operating method
JP2005093143A (en) * 2003-09-12 2005-04-07 Nec Corp Fuel cell system and its method of use
JP2005293928A (en) * 2004-03-31 2005-10-20 Nissan Motor Co Ltd Fuel cell system
JP2006294274A (en) * 2005-04-06 2006-10-26 Nippon Soken Inc Fuel cell and fuel cell module
JP2009176609A (en) * 2008-01-25 2009-08-06 Toyota Motor Corp Fuel cell stack and current-collecting plate used for the fuel cell stack
JP2009218092A (en) * 2008-03-11 2009-09-24 Toyota Motor Corp Fuel cell system and fuel cell stack

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4303899B2 (en) * 2001-07-30 2009-07-29 本田技研工業株式会社 Fuel cell stack and operation method thereof
US20040151971A1 (en) * 2003-01-31 2004-08-05 Rock Jeffrey Allan PEM fuel cell with flow-field having a branched midsection
JP2005174600A (en) * 2003-12-08 2005-06-30 Nissan Motor Co Ltd Fuel cell system
JP2005310700A (en) 2004-04-26 2005-11-04 Toyota Motor Corp Fuel cell
US7078119B2 (en) 2004-06-29 2006-07-18 Nissan Motor Co., Ltd. Fuel cell system and method for generating electricity from a fuel cell system comprising a fuel cell stack divided into sub-tracks
US7323267B2 (en) * 2004-10-07 2008-01-29 Tekion, Inc. Liquid feed fuel cell with nested sealing configuration
KR100760132B1 (en) 2005-02-28 2007-09-18 산요덴키가부시키가이샤 Composite membrane and fuel cell using composite membrane
JP2006286454A (en) 2005-04-01 2006-10-19 Denso Corp Fuel cell system
JP4934985B2 (en) 2005-04-14 2012-05-23 トヨタ自動車株式会社 Fuel cell system
JP2007026784A (en) 2005-07-13 2007-02-01 Toyota Motor Corp Fuel cell, fuel cell system and operation method for fuel cell system
JP2007035410A (en) 2005-07-26 2007-02-08 Nissan Motor Co Ltd Fuel cell system
JP2008004292A (en) 2006-06-20 2008-01-10 Toyota Motor Corp Current collector for fuel cell
KR100747865B1 (en) 2006-08-16 2007-08-08 현대자동차주식회사 Fuel cell stack
KR100862467B1 (en) 2006-12-12 2008-10-08 현대자동차주식회사 Multi-Function Resister for fuel cell-super capacitor hybrid electric vehicle
US8227145B2 (en) * 2008-03-18 2012-07-24 GM Global Technology Operations LLC Interlockable bead seal

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2003331891A (en) * 2002-05-13 2003-11-21 Mitsubishi Heavy Ind Ltd Fuel cell system, and starting method of fuel cell system
JP2005093143A (en) * 2003-09-12 2005-04-07 Nec Corp Fuel cell system and its method of use
JP2005093282A (en) * 2003-09-18 2005-04-07 Matsushita Electric Ind Co Ltd Polymer electrolyte fuel cell system and its operating method
JP2005293928A (en) * 2004-03-31 2005-10-20 Nissan Motor Co Ltd Fuel cell system
JP2006294274A (en) * 2005-04-06 2006-10-26 Nippon Soken Inc Fuel cell and fuel cell module
JP2009176609A (en) * 2008-01-25 2009-08-06 Toyota Motor Corp Fuel cell stack and current-collecting plate used for the fuel cell stack
JP2009218092A (en) * 2008-03-11 2009-09-24 Toyota Motor Corp Fuel cell system and fuel cell stack

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8697307B2 (en) 2011-08-17 2014-04-15 Samsung Sdi Co., Ltd. Solid oxide fuel cell stack
US8835072B2 (en) 2011-10-05 2014-09-16 Samsung Sdi Co., Ltd. Solid oxide fuel cell stacks and fuel cell module having the same
JP2016219337A (en) * 2015-05-25 2016-12-22 本田技研工業株式会社 Fuel cell stack
CN114649549A (en) * 2022-03-30 2022-06-21 潍柴动力股份有限公司 Battery heating control method, device and system and storage medium

Also Published As

Publication number Publication date
JP5472898B2 (en) 2014-04-16
US20100098977A1 (en) 2010-04-22
KR20100043806A (en) 2010-04-29
KR101071769B1 (en) 2011-10-11
US8178253B2 (en) 2012-05-15

Similar Documents

Publication Publication Date Title
JP5472898B2 (en) Fuel cell current collector and control method thereof
US6953632B2 (en) Fuel cell stack and a method of operating the same
US8212516B2 (en) Power supply system
JP4733664B2 (en) Fuel cell circuit connection control system and driving method thereof
US20050214607A1 (en) Polymer electrolyte fuel cell power generation system and stationary co-generation system using the same
EP1998397B1 (en) Fuel cell system and method of starting operation of fuel cell system
JP5580991B2 (en) Humidification of fuel cells
US8647784B2 (en) Fuel cell stack start method preventing cathode deterioration
US8258740B2 (en) Fuel cell system and method of starting operation of fuel cell system
JP5303419B2 (en) Fuel cell power generation system and operation method thereof
KR101782353B1 (en) Freeze startup method for a fuel cell system
WO2011158295A1 (en) Fuel cell
US7078116B2 (en) Method of warming up fuel cell system
JP5145778B2 (en) FUEL CELL SYSTEM AND METHOD FOR OPERATING FUEL CELL SYSTEM
JP2008171601A (en) Fuel cell system
JP2007280678A (en) Fuel cell
JP2005346979A (en) Regeneration control unit of fuel cell
JP2007042441A (en) Fuel cell and operation method of the same
JP2014073003A (en) Fuel cell, fuel cell system including lead storage battery and charging method
JP5452135B2 (en) Fuel cell power generation system
KR101558343B1 (en) fuel cell management method
CN111381176B (en) Device and method for controlling the measurement of the cell voltage of a fuel cell
JP2006114440A (en) Fuel cell
JP5049487B2 (en) Fuel cell device
JP2008146937A (en) Fuel cell system

Legal Events

Date Code Title Description
A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20110829

A977 Report on retrieval

Free format text: JAPANESE INTERMEDIATE CODE: A971007

Effective date: 20130130

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20130212

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20130513

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20130910

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20131205

TRDD Decision of grant or rejection written
A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

Effective date: 20140107

A61 First payment of annual fees (during grant procedure)

Free format text: JAPANESE INTERMEDIATE CODE: A61

Effective date: 20140129

R150 Certificate of patent or registration of utility model

Ref document number: 5472898

Country of ref document: JP

Free format text: JAPANESE INTERMEDIATE CODE: R150

Free format text: JAPANESE INTERMEDIATE CODE: R150

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

LAPS Cancellation because of no payment of annual fees