JP2010024217A - Shaving gel foam composition - Google Patents
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- JP2010024217A JP2010024217A JP2008208776A JP2008208776A JP2010024217A JP 2010024217 A JP2010024217 A JP 2010024217A JP 2008208776 A JP2008208776 A JP 2008208776A JP 2008208776 A JP2008208776 A JP 2008208776A JP 2010024217 A JP2010024217 A JP 2010024217A
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- agent
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- gel foam
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- 239000000203 mixture Substances 0.000 title claims abstract description 26
- 239000006260 foam Substances 0.000 title claims abstract description 23
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 39
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 18
- 239000000194 fatty acid Substances 0.000 claims abstract description 18
- 229930195729 fatty acid Natural products 0.000 claims abstract description 18
- 150000004665 fatty acids Chemical class 0.000 claims abstract description 16
- QWTDNUCVQCZILF-UHFFFAOYSA-N isopentane Chemical compound CCC(C)C QWTDNUCVQCZILF-UHFFFAOYSA-N 0.000 claims abstract description 12
- 229930195733 hydrocarbon Natural products 0.000 claims abstract description 10
- 150000002430 hydrocarbons Chemical class 0.000 claims abstract description 10
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 claims abstract description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000004215 Carbon black (E152) Substances 0.000 claims abstract description 7
- 239000004088 foaming agent Substances 0.000 claims abstract description 7
- 239000002736 nonionic surfactant Substances 0.000 claims abstract description 7
- 239000003513 alkali Substances 0.000 claims abstract description 6
- AFABGHUZZDYHJO-UHFFFAOYSA-N dimethyl butane Natural products CCCC(C)C AFABGHUZZDYHJO-UHFFFAOYSA-N 0.000 claims abstract description 6
- 230000003472 neutralizing effect Effects 0.000 claims abstract description 6
- 229920002545 silicone oil Polymers 0.000 claims abstract description 6
- 229940057995 liquid paraffin Drugs 0.000 claims description 4
- 238000005187 foaming Methods 0.000 abstract description 22
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 17
- -1 polyoxyethylene Polymers 0.000 description 10
- 239000003921 oil Substances 0.000 description 9
- 235000019198 oils Nutrition 0.000 description 9
- 238000002156 mixing Methods 0.000 description 5
- JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical compound OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 description 4
- 239000004359 castor oil Substances 0.000 description 4
- 235000019438 castor oil Nutrition 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 4
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 4
- 239000000344 soap Substances 0.000 description 4
- 239000002202 Polyethylene glycol Substances 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 239000000443 aerosol Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 229920001223 polyethylene glycol Polymers 0.000 description 3
- FDCJDKXCCYFOCV-UHFFFAOYSA-N 1-hexadecoxyhexadecane Chemical compound CCCCCCCCCCCCCCCCOCCCCCCCCCCCCCCCC FDCJDKXCCYFOCV-UHFFFAOYSA-N 0.000 description 2
- XDOFQFKRPWOURC-UHFFFAOYSA-N 16-methylheptadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCCCC(O)=O XDOFQFKRPWOURC-UHFFFAOYSA-N 0.000 description 2
- 235000021314 Palmitic acid Nutrition 0.000 description 2
- 235000021355 Stearic acid Nutrition 0.000 description 2
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 2
- 150000005215 alkyl ethers Chemical class 0.000 description 2
- 150000001413 amino acids Chemical class 0.000 description 2
- 239000002585 base Substances 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 239000003240 coconut oil Substances 0.000 description 2
- 235000019864 coconut oil Nutrition 0.000 description 2
- UKMSUNONTOPOIO-UHFFFAOYSA-N docosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 2
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 2
- 150000004671 saturated fatty acids Chemical class 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- PRAKJMSDJKAYCZ-UHFFFAOYSA-N squalane Chemical compound CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 description 2
- 239000008117 stearic acid Substances 0.000 description 2
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 2
- DSEKYWAQQVUQTP-XEWMWGOFSA-N (2r,4r,4as,6as,6as,6br,8ar,12ar,14as,14bs)-2-hydroxy-4,4a,6a,6b,8a,11,11,14a-octamethyl-2,4,5,6,6a,7,8,9,10,12,12a,13,14,14b-tetradecahydro-1h-picen-3-one Chemical compound C([C@H]1[C@]2(C)CC[C@@]34C)C(C)(C)CC[C@]1(C)CC[C@]2(C)[C@H]4CC[C@@]1(C)[C@H]3C[C@@H](O)C(=O)[C@@H]1C DSEKYWAQQVUQTP-XEWMWGOFSA-N 0.000 description 1
- OYHQOLUKZRVURQ-NTGFUMLPSA-N (9Z,12Z)-9,10,12,13-tetratritiooctadeca-9,12-dienoic acid Chemical compound C(CCCCCCC\C(=C(/C\C(=C(/CCCCC)\[3H])\[3H])\[3H])\[3H])(=O)O OYHQOLUKZRVURQ-NTGFUMLPSA-N 0.000 description 1
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- FFJCNSLCJOQHKM-CLFAGFIQSA-N (z)-1-[(z)-octadec-9-enoxy]octadec-9-ene Chemical compound CCCCCCCC\C=C/CCCCCCCCOCCCCCCCC\C=C/CCCCCCCC FFJCNSLCJOQHKM-CLFAGFIQSA-N 0.000 description 1
- UYZQWKKNVBJVOF-UHFFFAOYSA-N 1-decoxytetradecane Chemical compound CCCCCCCCCCCCCCOCCCCCCCCCC UYZQWKKNVBJVOF-UHFFFAOYSA-N 0.000 description 1
- JPPRXACMNPYJNK-UHFFFAOYSA-N 1-docosoxydocosane Chemical compound CCCCCCCCCCCCCCCCCCCCCCOCCCCCCCCCCCCCCCCCCCCCC JPPRXACMNPYJNK-UHFFFAOYSA-N 0.000 description 1
- CMCBDXRRFKYBDG-UHFFFAOYSA-N 1-dodecoxydodecane Chemical compound CCCCCCCCCCCCOCCCCCCCCCCCC CMCBDXRRFKYBDG-UHFFFAOYSA-N 0.000 description 1
- HBXWUCXDUUJDRB-UHFFFAOYSA-N 1-octadecoxyoctadecane Chemical compound CCCCCCCCCCCCCCCCCCOCCCCCCCCCCCCCCCCCC HBXWUCXDUUJDRB-UHFFFAOYSA-N 0.000 description 1
- 229940058020 2-amino-2-methyl-1-propanol Drugs 0.000 description 1
- RFVNOJDQRGSOEL-UHFFFAOYSA-N 2-hydroxyethyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCO RFVNOJDQRGSOEL-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- 239000004475 Arginine Substances 0.000 description 1
- 235000021357 Behenic acid Nutrition 0.000 description 1
- ODKSFYDXXFIFQN-BYPYZUCNSA-P L-argininium(2+) Chemical compound NC(=[NH2+])NCCC[C@H]([NH3+])C(O)=O ODKSFYDXXFIFQN-BYPYZUCNSA-P 0.000 description 1
- HNDVDQJCIGZPNO-YFKPBYRVSA-N L-histidine Chemical compound OC(=O)[C@@H](N)CC1=CN=CN1 HNDVDQJCIGZPNO-YFKPBYRVSA-N 0.000 description 1
- KDXKERNSBIXSRK-YFKPBYRVSA-N L-lysine Chemical compound NCCCC[C@H](N)C(O)=O KDXKERNSBIXSRK-YFKPBYRVSA-N 0.000 description 1
- 239000005639 Lauric acid Substances 0.000 description 1
- KDXKERNSBIXSRK-UHFFFAOYSA-N Lysine Natural products NCCCCC(N)C(O)=O KDXKERNSBIXSRK-UHFFFAOYSA-N 0.000 description 1
- 239000004472 Lysine Substances 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 239000004264 Petrolatum Substances 0.000 description 1
- 229920001214 Polysorbate 60 Polymers 0.000 description 1
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- DTOSIQBPPRVQHS-PDBXOOCHSA-N alpha-linolenic acid Chemical compound CC\C=C/C\C=C/C\C=C/CCCCCCCC(O)=O DTOSIQBPPRVQHS-PDBXOOCHSA-N 0.000 description 1
- 235000020661 alpha-linolenic acid Nutrition 0.000 description 1
- CBTVGIZVANVGBH-UHFFFAOYSA-N aminomethyl propanol Chemical compound CC(C)(N)CO CBTVGIZVANVGBH-UHFFFAOYSA-N 0.000 description 1
- 230000001166 anti-perspirative effect Effects 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 239000003213 antiperspirant Substances 0.000 description 1
- ODKSFYDXXFIFQN-UHFFFAOYSA-N arginine Natural products OC(=O)C(N)CCCNC(N)=N ODKSFYDXXFIFQN-UHFFFAOYSA-N 0.000 description 1
- 229940116226 behenic acid Drugs 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- 239000000645 desinfectant Substances 0.000 description 1
- 239000004205 dimethyl polysiloxane Substances 0.000 description 1
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 239000003925 fat Substances 0.000 description 1
- 235000019197 fats Nutrition 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 229940100242 glycol stearate Drugs 0.000 description 1
- HNDVDQJCIGZPNO-UHFFFAOYSA-N histidine Natural products OC(=O)C(N)CC1=CN=CN1 HNDVDQJCIGZPNO-UHFFFAOYSA-N 0.000 description 1
- 239000003906 humectant Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 150000007529 inorganic bases Chemical class 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- 239000001282 iso-butane Substances 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 229960004488 linolenic acid Drugs 0.000 description 1
- KQQKGWQCNNTQJW-UHFFFAOYSA-N linolenic acid Natural products CC=CCCC=CCC=CCCCCCCCC(O)=O KQQKGWQCNNTQJW-UHFFFAOYSA-N 0.000 description 1
- JXTPJDDICSTXJX-UHFFFAOYSA-N n-Triacontane Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCC JXTPJDDICSTXJX-UHFFFAOYSA-N 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 235000021313 oleic acid Nutrition 0.000 description 1
- 150000007530 organic bases Chemical class 0.000 description 1
- 238000010979 pH adjustment Methods 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 229940066842 petrolatum Drugs 0.000 description 1
- 235000019271 petrolatum Nutrition 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- WBHHMMIMDMUBKC-XLNAKTSKSA-N ricinelaidic acid Chemical compound CCCCCC[C@@H](O)C\C=C\CCCCCCCC(O)=O WBHHMMIMDMUBKC-XLNAKTSKSA-N 0.000 description 1
- 229960003656 ricinoleic acid Drugs 0.000 description 1
- FEUQNCSVHBHROZ-UHFFFAOYSA-N ricinoleic acid Natural products CCCCCCC(O[Si](C)(C)C)CC=CCCCCCCCC(=O)OC FEUQNCSVHBHROZ-UHFFFAOYSA-N 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 235000003441 saturated fatty acids Nutrition 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N sec-butylidene Natural products CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- 230000003381 solubilizing effect Effects 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 229940032094 squalane Drugs 0.000 description 1
- 239000011550 stock solution Substances 0.000 description 1
- 239000008399 tap water Substances 0.000 description 1
- 235000020679 tap water Nutrition 0.000 description 1
- 235000021122 unsaturated fatty acids Nutrition 0.000 description 1
- 150000004670 unsaturated fatty acids Chemical class 0.000 description 1
- 239000004034 viscosity adjusting agent Substances 0.000 description 1
- 230000037303 wrinkles Effects 0.000 description 1
Abstract
Description
本発明は、髭やむだ毛等の体毛を剃刀で剃る際に使用するシェービング剤の組成物に関し、更に詳しくはジェル状に吐出した内容物を、軽く擦ることにより、徐々に発泡してフォームを形成するシェービングジェルフォーム組成物に関する。 The present invention relates to a composition of a shaving agent used when shaving body hair such as wrinkles and unwanted hair with a razor, and more specifically, the contents discharged in a gel form are gradually foamed to form a foam. It relates to a shaving gel foam composition to be formed.
剃刀で髭や体毛を剃る際にはシェービング剤が用いられる。シェービング剤には脂肪酸石鹸を主基材としたものが多く、例えば一般的な固形または粉末のシェービングソープの他にシェービングクリーム、エアゾール型シェービングフォーム、後発泡シェービングジェルフォームなどがある。 A shaving agent is used when shaving swords and hair with a razor. Many shaving agents are mainly composed of fatty acid soaps, such as shaving creams, aerosol-type shaving foams, and post-foamed shaving gel foams in addition to general solid or powder shaving soaps.
後発泡タイプのシェービングフォームは、石鹸によりジェルを形成し、ジェルの粘性によって物理的に発泡を抑えるエアゾール組成物は公知である(特許文献1)。また、吐出されたジェルが高い透明性を有する後発泡エアゾール組成物が提案されている(特許文献2)。また、圧縮ガスを水性原液に溶解させ、吐出された後に適度に抑制された気泡性で発泡する徐気泡型後発泡性組成物が提案されている(特許文献3)。 As the post-foaming type shaving foam, an aerosol composition in which gel is formed with soap and foaming is physically suppressed by the viscosity of the gel is known (Patent Document 1). Moreover, the post-foaming aerosol composition which the discharged gel has high transparency is proposed (patent document 2). In addition, a slow-foaming type post-foaming composition has been proposed in which a compressed gas is dissolved in an aqueous stock solution and foamed with moderately suppressed foaming after being discharged (Patent Document 3).
しかしながら、特許文献1及び2の技術は石鹸により形成したジェルは経時的に安定とするために粘度が高く、肌に塗り伸ばしたときにジェルの一部が完全に発泡せず、肌にジェルのまま残って、良好な発泡状態ではなかった。また、特許文献3の技術は水性原液の粘度を調整して、圧縮ガスが溶解して発泡させる方法は、圧縮ガスの溶解する量が少なく、ペンタンなどの後発泡剤と比較して発泡量が少なく、シェービングジェルフォームとして満足できるものではなかった。 However, in the techniques of Patent Documents 1 and 2, the gel formed with soap has a high viscosity because it is stable over time, and part of the gel does not completely foam when spread on the skin, and the gel does not form on the skin. It remained and was not in a good foamed state. Moreover, the technique of patent document 3 adjusts the viscosity of the aqueous undiluted solution, and the method in which the compressed gas dissolves and foams has a small amount of the compressed gas dissolved, and the amount of foaming compared with a post-foaming agent such as pentane. The amount was not satisfactory as a shaving gel foam.
本発明者は、上記課題を解決すべく鋭意研究を重ねてきた。その結果、水、脂肪酸、HLBが10以上の非イオン系界面活性剤、中和剤としてアルカリ剤、ノルマルペンタンもしくはイソペンタンからなる後発泡剤に0.05〜5重量%配合のジェルの硬さ調整剤である炭化水素またはシリコーン油からなる油剤を添加することにより、肌に塗り伸ばしたときにジェルが完全に発泡した良好な発泡状態で、発泡によりシェービングジェルフォームとして満足できるシェービングジェルフォーム組成物を見出し、ここに本発明を完成するに至った。 The present inventor has intensively studied to solve the above problems. As a result, the hardness of the gel containing 0.05 to 5% by weight in a post-foaming agent comprising water, a fatty acid, a nonionic surfactant having an HLB of 10 or more, and an alkali agent, normal pentane or isopentane as a neutralizing agent is adjusted. By adding an oil agent consisting of a hydrocarbon or silicone oil as a preparation agent, a shaving gel foam composition that can be satisfied as a shaving gel foam by foaming in a good foamed state in which the gel is completely foamed when spread on the skin. The headline and here came to complete the present invention.
即ち、本発明は、下記のシェービングジェルフォーム組成物を提供するものである。
1.水、脂肪酸、HLBが10以上の非イオン系界面活性剤、中和剤としてアルカリ剤、ノルマルペンタンもしくはイソペンタンからなる後発泡剤と0.05〜5重量%配合のジェルの硬さ調整剤である炭化水素またはシリコーン油からなる油剤を必須成分とするシェービングジェルフォーム組成物。
2.前記炭化水素からなる油剤が流動パラフィンであることを特徴とする請求項1記載のシェービングジェルフォーム組成物。
本発明のシェービングジェルフォーム組成物は水、脂肪酸、HLBが10以上の非イオン系界面活性剤、中和剤としてアルカリ剤、ノルマルペンタンもしくはイソペンタンからなる後発泡剤と0.05〜5重量%配合のジェルの硬さ調整剤である炭化水素またはシリコーン油からなる油剤を必須成分とするものである。以下、本発明のシェービングジェル組成物について具体的に説明する。That is, the present invention provides the following shaving gel foam composition.
1. It is a nonionic surfactant having water, fatty acid, HLB of 10 or more, a post foaming agent composed of an alkali agent, normal pentane or isopentane as a neutralizing agent, and a gel hardness adjusting agent of 0.05 to 5% by weight. A shaving gel foam composition comprising as an essential component an oil comprising a hydrocarbon or silicone oil.
2. 2. The shaving gel foam composition according to claim 1, wherein the oil agent comprising hydrocarbon is liquid paraffin.
The shaving gel foam composition of the present invention contains 0.05 to 5% by weight of water, a fatty acid, a nonionic surfactant having an HLB of 10 or more, a post-foaming agent comprising an alkali agent, normal pentane or isopentane as a neutralizing agent. An oil agent comprising a hydrocarbon or silicone oil which is a gel hardness adjusting agent is an essential component. Hereinafter, the shaving gel composition of the present invention will be specifically described.
本発明に用いる水は組成物の基剤となるものであり、通常水道水、蒸留水、イオン交換水等を用い、組成物中40〜98重量%、好ましくは60〜95重量%である。40重量%未満であれば十分な発泡が得られず、また98重量%を超えると他の成分が少なくなり、シェービング剤として好ましくない。 The water used in the present invention serves as a base of the composition, and usually comprises tap water, distilled water, ion exchange water, etc., and is 40 to 98% by weight, preferably 60 to 95% by weight in the composition. If it is less than 40% by weight, sufficient foaming cannot be obtained, and if it exceeds 98% by weight, other components are reduced, which is not preferable as a shaving agent.
脂肪酸は例えば炭素数10〜22の直鎖又は分岐鎖の飽和または不飽和脂肪酸が挙げられる。具体的にはラウリン酸、ミリスチン酸、パルミチン酸、ステアリン酸、オレイン酸、ベヘン酸、イソステアリン酸、リノール酸、リノレン酸、リシノール酸等の脂肪酸、及び前記脂肪酸類を多く含む天然油脂由来の脂肪酸等が挙げられる。好ましくは炭素数12〜18の直鎖又は分岐鎖の飽和脂肪酸を用いる。この中で特にミリスチン酸、パルミチン酸、ステアリン酸等の直鎖脂肪酸、及び前記脂肪酸類を多く含むヤシ油脂肪酸が好ましい。これらの脂肪酸は、単独で又は適宜組み合わせて配合することができる。 Examples of the fatty acid include linear or branched saturated or unsaturated fatty acids having 10 to 22 carbon atoms. Specifically, fatty acids such as lauric acid, myristic acid, palmitic acid, stearic acid, oleic acid, behenic acid, isostearic acid, linoleic acid, linolenic acid, ricinoleic acid, and fatty acids derived from natural fats and oils containing many of the above fatty acids Is mentioned. Preferably, a linear or branched saturated fatty acid having 12 to 18 carbon atoms is used. Of these, linear fatty acids such as myristic acid, palmitic acid and stearic acid, and coconut oil fatty acid containing a large amount of the fatty acids are particularly preferred. These fatty acids can be blended alone or in appropriate combination.
HLBが10以上の非イオン系界面活性剤はポリオキシエチレン(以下POE)(9)ラウリルエーテル〔HLB(以下省略):14.5〕、POE(7)セチルエーテル〔11.5〕、POE(20)ステアリルエーテル〔18.0〕、POE(7)オレイルエーテル〔10.5〕、POE(20)ベヘニルエーテル〔18.0〕などのPOEアルキルエーテル類、POE(10)ポリオキシプロピレン(以下POP)(4)セチルエーテル〔10.5〕、POE(20)POP(6)デシルテトラデシルエーテルなどのPOE・POPアルキルエーテル類、モノラウリン酸ポリエチレングリコール(10E.O.)〔12.5〕、モノステアリン酸ポリエチレングリコール(10E.O.)〔11.0〕、モノオレイン酸ポリエチレングリコール(10E.O.)〔11.0〕などのポリエチレングリコール脂肪酸エステル類、POE(20)ヒマシ油〔10.5〕、POE(30)硬化ヒマシ油〔11.0〕などのPOEヒマシ油・硬化ヒマシ油類、モノヤシ油脂肪酸POE(20)ソルビタン〔16.9〕、モノパルミチン酸POE(20)ソルビタン〔15.6〕、モノステアリン酸POE(20)ソルビタン〔14.9〕、モノオレイン酸POE(20)ソルビタン〔15.0〕などのPOEソルビタン脂肪酸エステル類等が挙げられる。非イオン系界面活性剤のHLBは10以上、好ましくは10.5以上、更に好ましくは12.0以上である。HLBが10未満であれば、炭化水素からなる油剤を安定的に可溶化できず、ジェルの硬さを一定にすることができない。配合割合は特に規定されないが油剤を可溶化できる配合割合が好ましく0.1〜12重量%、より好ましくは0.3〜7重量%である。 Nonionic surfactants having an HLB of 10 or more are polyoxyethylene (hereinafter POE) (9) lauryl ether [HLB (hereinafter abbreviated): 14.5], POE (7) cetyl ether [11.5], POE ( 20) POE alkyl ethers such as stearyl ether [18.0], POE (7) oleyl ether [10.5], POE (20) behenyl ether [18.0], POE (10) polyoxypropylene (hereinafter POP) ) (4) POE / POP alkyl ethers such as cetyl ether [10.5], POE (20) POP (6) decyltetradecyl ether, polyethylene glycol monolaurate (10E.O.) [12.5], mono Polyethylene glycol stearate (10E.O.) [11.0], polyethylene monooleate Polyethylene glycol fatty acid esters such as coal (10E.O.) [11.0], POE castor oil such as POE (20) castor oil [10.5], POE (30) hydrogenated castor oil [11.0] Hardened castor oil, mono coconut oil fatty acid POE (20) sorbitan [16.9], monopalmitic acid POE (20) sorbitan [15.6], monostearic acid POE (20) sorbitan [14.9], monooleic acid POE sorbitan fatty acid esters such as POE (20) sorbitan [15.0] are exemplified. The HLB of the nonionic surfactant is 10 or more, preferably 10.5 or more, more preferably 12.0 or more. If HLB is less than 10, the oil agent which consists of hydrocarbons cannot be solubilized stably, and the hardness of a gel cannot be made constant. The blending ratio is not particularly specified, but the blending ratio capable of solubilizing the oil is preferably 0.1 to 12% by weight, more preferably 0.3 to 7% by weight.
上記脂肪酸を中和するためのアルカリ剤は特に限定されないが、例えばアルカノールアミンや塩基性アミノ酸等の有機塩基、水酸化アルカリ金属等の無機塩基が挙げられる。具体的には、アルカノールアミンとして、トリエタノールアミン、2−アミノ−2−メチル−1−プロパノール等、塩基性アミノ酸として、アルギニン、リジン、ヒスチジン等、水酸化アルカリ金属として、水酸化ナトリウム、水酸化カリウム等が挙げられる。中和用塩基はpHが上がり過ぎることがない点と、塩の結晶が析出せず保存安定性が良い点から、前記有機塩基化合物が好ましい。 Although the alkali agent for neutralizing the said fatty acid is not specifically limited, For example, organic bases, such as alkanolamine and a basic amino acid, inorganic bases, such as an alkali metal hydroxide, are mentioned. Specifically, as alkanolamine, triethanolamine, 2-amino-2-methyl-1-propanol, etc., as basic amino acid, arginine, lysine, histidine, etc., as alkali metal hydroxide, sodium hydroxide, hydroxide Potassium etc. are mentioned. The base for neutralization is preferably the organic base compound from the viewpoint that the pH does not increase excessively and the salt stability does not precipitate and the storage stability is good.
後発泡剤としては、ノルマルペンタンもしくはイソペンタンが必須であり、その他ではイソブタン、ノルマルブタンを適宜組み合わせることも可能である。良好な発泡を得るために配合割合としては2〜15重量%が好ましく、更に好ましくは3〜10重量%である。配合割合が2重量%未満であれば、発泡が少なすぎてシェービング剤として好ましくなく、15重量%を超えると発泡が多すぎて泡がパサつき、シェービング剤として好ましくない。 As the post-foaming agent, normal pentane or isopentane is essential, and in other cases, isobutane and normal butane can be appropriately combined. In order to obtain good foaming, the blending ratio is preferably 2 to 15% by weight, more preferably 3 to 10% by weight. If the blending ratio is less than 2% by weight, the foaming is too small to be preferred as a shaving agent, and if it exceeds 15% by weight, the foaming is too much to cause foaming, which is not preferred as a shaving agent.
油剤としては、流動パラフィン、ワセリン、セレシン、固体パラフィン、スクワラン等の炭化水素類、ジメチルポリシロキサン、メチルフェニルポリシロキサン等のシリコーン油が好ましい。この中で、炭化水素からなる油剤で、流動パラフィンは常温で液状であり、取扱いや使用感から特に好ましい。配合割合は0.05〜5重量%が好ましく、0.3〜3重量%が更に好ましい。0.05重量%未満であれば、ジェルが柔らかすぎてシェービング剤として好ましくなく、5重量%を超えるとジェルが硬すぎてシェービング剤として好ましくない。 As the oil agent, hydrocarbons such as liquid paraffin, petrolatum, ceresin, solid paraffin and squalane, and silicone oil such as dimethylpolysiloxane and methylphenylpolysiloxane are preferable. Among these, liquid oils composed of hydrocarbons and liquid paraffin are liquid at room temperature, and are particularly preferable from the viewpoint of handling and usability. The blending ratio is preferably 0.05 to 5% by weight, more preferably 0.3 to 3% by weight. If it is less than 0.05% by weight, the gel is too soft to be preferred as a shaving agent, and if it exceeds 5% by weight, the gel is too hard to be preferred as a shaving agent.
本発明の制汗スプレー組成物には、上記の必須構成成分に加え、本発明の効果を損なわない範囲で化粧料に使用される一般的なその他の成分、例えば保湿剤、防腐剤、pH調整剤、粘度調整剤、酸化防止剤、清涼剤、殺菌剤、香料、色素等を適宜配合することができる。 In the antiperspirant spray composition of the present invention, in addition to the above essential components, other general components used in cosmetics within a range not impairing the effects of the present invention, such as humectants, preservatives, pH adjustment An agent, a viscosity modifier, an antioxidant, a refreshing agent, a disinfectant, a fragrance, a pigment, and the like can be appropriately blended.
以下、本発明のシェービングジェルフォーム組成物の実施例について説明するが、本発明はこれらに限定されるものではない。 Examples of the shaving gel foam composition of the present invention will be described below, but the present invention is not limited thereto.
実施例1〜2及び比較例1〜4
下記表1に示す組成に従って、シェービングジェルフォーム組成物の成分を調整し、それぞれ二重容器型エアゾール容器内に充填した。下記評価方法により(イ)吐出後のジェルの状態、(ロ)肌に塗布し、塗り伸ばした状態、(ハ)シェービング剤としての満足度について評価を行った。その評価結果を併せて表1に示す。実施例及び比較例中の単位は重量%を示す。Examples 1-2 and Comparative Examples 1-4
In accordance with the composition shown in Table 1 below, the ingredients of the shaving gel foam composition were prepared and filled into double container type aerosol containers. The following evaluation methods were used to evaluate (i) the state of the gel after ejection, (b) the state where the gel was applied and spread on the skin, and (c) the satisfaction as a shaving agent. The evaluation results are also shown in Table 1. The unit in an Example and a comparative example shows weight%.
(イ)吐出後のジェル状態
20℃において、シェービングジェル組成物を2〜3g吐出させ、吐出してから発泡するまでの時間を測定し、下記の基準により評価した。
○:吐出させてから発泡するまでの時間が60秒以上であるもの
△:吐出させてから発泡するまでの時間が30秒以上60秒未満であるもの
×:吐出させてから発泡するまでの時間が30秒未満であるもの(I) Gel state after discharge At 20 ° C., 2 to 3 g of the shaving gel composition was discharged, the time from discharge to foaming was measured, and evaluated according to the following criteria.
○: The time from foaming to foaming is 60 seconds or more Δ: The time from ejection to foaming is 30 seconds or more and less than 60 seconds ×: Time from foaming to foaming Is less than 30 seconds
(ロ)肌に塗布し、塗り伸ばした状態
20℃において、シェービングジェル組成物を2〜3g吐出させ、肌の上に指で軽く伸ばした時のジェルの状態を観察した。
○:肌の上にジェルが残らず、全て発泡しているもの
△:肌の上にジェルが粒で少量残っているもの
×:肌の上にジェルが粒で多量残っているもの(B) State applied and spread on skin At 20 ° C., 2 to 3 g of the shaving gel composition was discharged, and the state of the gel when lightly extended with a finger on the skin was observed.
○: No gel remains on the skin and everything is foamed △: A small amount of gel remains on the skin ×: A large amount of gel remains on the skin
(ハ)シェービング剤としての満足度
実施例1〜2、比較例1〜4のシェービングジェル組成物を用いて、10名の成人男性により髭剃りをさせ、シェービング剤としての満足度の評価を行った。
○:シェービング剤として満足と評価した人数が8名以上
△:シェービング剤として満足と評価した人数が5〜7名
×:シェービング剤として満足と評価した人数が4名以下(C) Satisfaction as a shaving agent Using the shaving gel compositions of Examples 1 and 2 and Comparative Examples 1 to 4, shaving was performed by 10 adult men, and the satisfaction as a shaving agent was evaluated. It was.
○: 8 or more people evaluated as satisfactory as a shaving agent Δ: 5-7 people evaluated as satisfied as a shaving agent ×: 4 or less people evaluated as satisfied as a shaving agent
本発明のシェービングジェル組成物は吐出後の安定したジェル状態を保ち、肌の上に伸ばした時の発泡状態が良好で、シェービング剤として満足度が高いものである。 The shaving gel composition of the present invention maintains a stable gel state after ejection, has a good foamed state when stretched on the skin, and is highly satisfactory as a shaving agent.
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JP2016522706A (en) * | 2013-04-24 | 2016-08-04 | ザ ジレット コンパニー | Lubrication of skin engaging members |
JP2017104627A (en) * | 2013-04-24 | 2017-06-15 | ザ ジレット カンパニー リミテッド ライアビリティ カンパニーThe Gillette Company Llc | Lubricating shaving aid member |
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CN106265314A (en) * | 2016-08-31 | 2017-01-04 | 广州欧慕生物科技有限公司 | One is applicable to sensitive flesh shaving foam composition and cosmetics thereof and application |
CN108785112A (en) * | 2018-06-21 | 2018-11-13 | 上海西西艾尔启东日用化学品有限公司 | Foam moisturizing shower gel after one kind |
CN108670887A (en) * | 2018-06-21 | 2018-10-19 | 上海西西艾尔启东日用化学品有限公司 | Moisturizing of foaming after one kind is shaved gel |
CN108618985A (en) * | 2018-06-21 | 2018-10-09 | 上海西西艾尔启东日用化学品有限公司 | Foam moisturizing face cleaning gel after one kind |
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JP2016522706A (en) * | 2013-04-24 | 2016-08-04 | ザ ジレット コンパニー | Lubrication of skin engaging members |
JP2017104627A (en) * | 2013-04-24 | 2017-06-15 | ザ ジレット カンパニー リミテッド ライアビリティ カンパニーThe Gillette Company Llc | Lubricating shaving aid member |
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