JP2010001451A5 - - Google Patents

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JP2010001451A5
JP2010001451A5 JP2008280466A JP2008280466A JP2010001451A5 JP 2010001451 A5 JP2010001451 A5 JP 2010001451A5 JP 2008280466 A JP2008280466 A JP 2008280466A JP 2008280466 A JP2008280466 A JP 2008280466A JP 2010001451 A5 JP2010001451 A5 JP 2010001451A5
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水性洗浄剤の製造方法Method for producing aqueous detergent

本発明は、自動車、家電、電子産業などの加工品の脱脂洗浄を使用目的した界面活性剤などの有機物を全く含有しないVOC及びCO対策など環境対策を考慮した無機系の水性洗浄剤の製造方法に関する。 INDUSTRIAL APPLICABILITY The present invention manufactures an inorganic water-based cleaning agent considering environmental measures such as VOC and CO 2 measures that do not contain any organic matter such as a surfactant intended to be used for degreasing cleaning of processed products such as automobiles, home appliances, and electronics industries Regarding the method.

従来は、無機系洗浄剤として、メタケイ酸ナトリウム、炭酸カリウム、ホウ酸ナトリウム、硫酸ナトリウムを主成分とする洗浄剤の組成物が知られている。この洗浄剤の組成物の製造方法は、50〜80℃の温度にした水に、メタケイ酸ナトリウム、炭酸カリウム、ホウ酸ナトリウム、硫酸ナトリウムなどを順次適量加えて攪拌し、溶解して洗浄剤原液を製造することが効果的であると一般的に知られている。   Conventionally, as an inorganic detergent, a composition of a detergent mainly composed of sodium metasilicate, potassium carbonate, sodium borate, and sodium sulfate is known. A method for producing the composition of this cleaning agent is to add a proper amount of sodium metasilicate, potassium carbonate, sodium borate, sodium sulfate, and the like to water at a temperature of 50 to 80 ° C. Is generally known to be effective.

一方では、原水に塩類及びメタケイ酸ナトリウムを添加して電解質溶液とし、該電解質溶液中に空気による気泡(マイクロバブル)を発生させると同時に溶解度を維持する点から15〜20℃の温度を調整する装置を用いて超音波で気泡を圧壊させる工程を2時間以上かけて超微細気泡を含む溶液を製造する方法と洗浄剤がある。   On the other hand, salts and sodium metasilicate are added to the raw water to form an electrolyte solution, and air temperature (microbubbles) is generated in the electrolyte solution, and at the same time the temperature is adjusted to 15 to 20 ° C. from the viewpoint of maintaining solubility. There are a method and a cleaning agent for producing a solution containing ultrafine bubbles by taking a step of crushing bubbles with ultrasonic waves using an apparatus over 2 hours.

しかしながら、上記の無機系洗浄剤の組成物にあっては、それなにの洗浄効果が見られているが、製品化された溶液中の添加剤メタケイ酸ナトリウムの粒子(40〜50ミクロン)が大きすぎるために製品の長期的な安定した品質及び脱脂洗浄後に発生するシミの問題や優れた防錆力を得るために更に改良する必要性を要望されているのが現状である。
特許4064977(9頁)
However, in the above-mentioned inorganic detergent composition, no cleaning effect is observed, but particles of the additive sodium metasilicate (40 to 50 microns) in the commercialized solution are present. At present, there is a demand for further improvement in order to obtain a long-term stable quality of the product due to being too large, a problem of stains generated after degreasing and cleaning, and an excellent rust prevention ability.
Patent 4064977 (9 pages)

本発明は、上記問題点を解決するもので、環境負荷が少なく、製品の長期的な安定した品質及び脱脂洗浄後に発生するシミの問題や優れた防錆力を得るために水性洗浄剤を製造する方法を見出し、問題点を解決することを目的とする。   The present invention solves the above-mentioned problems, and produces an aqueous cleaning agent to obtain a long-term stable quality of the product and a problem of stains generated after degreasing and excellent rust-preventing power with low environmental impact. The purpose is to find a way to solve the problem.

上記課題を解決するための発明は、純水を原水とし、この原水にケイ酸二ナトリウム九水和物を添加して電解質溶液とし、該電解質溶液中に窒素ガスを送り続けると同時に超音波により気泡を圧壊させる工程を30分以上行い、その後工程で液体製品中に含まれる無機質のケイ酸二ナトリウム九水和物の粒子に高い圧力を加えて微砕化、均質化する機械であるホモジナイザーを用いて超微細気泡(5ミクロン)を含む溶液を製造することにより、上記目的の製造する方法と製品の長期的な安定した品質及び脱脂洗浄後に発生するシミの問題解決や優れた防錆力を得る事を特徴とする水性洗浄剤である。 Invention for solving the above problems, the pure water as the raw water, this raw water with the addition of silicic acid disodium Kyumizu sum was an electrolyte solution, ultrasonic simultaneously continuously feeding nitrogen gas into the electrolyte solution performs the step of crushing the bubble 30 minutes or more, then step in adding higher pressure into particles of silicic acid disodium Kyumizu sum of minerals contained in the liquid product fine砕化, a homogenizer is a machine for homogenizing By using this method to produce a solution containing ultrafine bubbles (5 microns), the above-mentioned production method and long-term stable quality of the product, as well as the problem of stains generated after degreasing and excellent rust prevention ability are achieved. It is an aqueous cleaning agent characterized by being obtained.

請求項1は、純水にケイ酸二ナトリウム九水和物を添加して電解質溶液とし、該電解質溶液中に窒素ガスを送り続けると同時に超音波により気泡を圧壊し微細気泡を含む溶液を製造する工程を少なくとも含むことを特徴とする水性洗浄剤の製造方法。 Claim 1, pure water was added to silicic acid disodium Kyumizu sum was an electrolyte solution, and crushing the bubble by ultrasonic at the same time continues to send nitrogen gas to the electrolyte solution producing a solution containing fine bubbles The manufacturing method of the aqueous cleaning agent characterized by including the process to do at least.

請求項1の発明のごとく、請求項2は、ケイ酸二ナトリウム九水和物の添加量が、10〜90ミリモル%である請求項1記載の水性洗浄剤の製造方法。   As in the first aspect of the invention, in the second aspect, the amount of disodium silicate nonahydrate added is 10 to 90 mmol%.

請求項3では、窒素ガスを送り続けると同時に超音波により気泡を圧壊させる工程を30分以上行い、その後工程で液体製品中に含まれる無機質のケイ酸二ナトリウム九水和物の粒子に高い圧力を加えて微砕化、均質化する機械であるホモジナイザーを用いて超微細気泡を含む溶液を製造する工程を含む、請求項1〜2の何れか一つに記載の水性洗浄剤の製造方法。 According to claim 3, continued feeding of nitrogen gas the step of collapsing bubbles by ultrasonic simultaneously carried out for 30 minutes or more, a high pressure into particles of subsequent silicate minerals contained in the liquid product in step disodium Kyumizu sum thereof was added finely砕化, using a homogenizer is a machine for homogenizing comprising the steps of producing a solution containing ultrafine bubbles, manufacturing method of the aqueous cleaning agent according to any one of claims 1-2 .

次に、請求項4では、請求項1〜3の何れか一つに記載の水性洗浄剤の製造方法により得られることを特徴とする水性洗浄剤。   Next, in Claim 4, the aqueous cleaning agent obtained by the manufacturing method of the aqueous cleaning agent as described in any one of Claims 1-3.

本発明によれば、純水にケイ酸二ナトリウム九水和物を添加して電解質溶液とし、該電解質溶液中に窒素ガスを送り続けると同時に超音波により気泡を圧壊させる工程を30分以上行い、その後工程で液体製品中に含まれる無機質のケイ酸二ナトリウム九水和物の粒子に高い圧力を加えて微砕化、均質化する機械であるホモジナイザーを用いて超微細気泡(5ミクロン)を含む溶液を製造することにより、ケイ酸二ナトリウム九水和物を主剤とした無機系の水性洗浄剤の長期的な安定した品質及び脱脂洗浄後に発生するシミの問題解決や優れた防錆力を得た水性洗浄剤の製造する方法が提供される。 According to the present invention, in pure water was added silicate Disodium Kyumizu sum was an electrolyte solution, a step of crushing the bubble by ultrasonic at the same time continues to send nitrogen gas to the electrolyte solution 30 minutes or more is performed , then step in adding higher pressure into particles of silicic acid disodium Kyumizu sum of minerals contained in the liquid product fine砕化, the ultrafine bubbles (5 microns) using a homogenizer is a machine for homogenizing by producing a solution containing, long-term stable quality and problem solving and excellent rust prevention of stain that occurs after degreasing of inorganic aqueous detergent that a main agent and silicate disodium Kyumizu sum thereof A method for producing the resulting aqueous detergent is provided.

本発明は図1に示すように、純水にケイ酸二ナトリウム九水和物を添加して電解質溶液とし、該電解質溶液中に窒素ガスを送り続けると同時に超音波により気泡を圧壊させる工程を30分以上行い、その後工程で液体製品中に含まれる無機質のケイ酸二ナトリウム九水和物の粒子に高い圧力を加えて微砕化、均質化する機械であるホモジナイザーを用いて超微細気泡(5ミクロン)を含む溶液を製造する工程を少なくとも含むことを特徴とするものである。 The present invention, as shown in FIG. 1, the pure water by the addition of silicic acid disodium Kyumizu sum was an electrolyte solution, the step of crushing the bubble by ultrasonic at the same time continues to send nitrogen gas to the electrolyte solution carried out for 30 minutes or more, then step in adding higher pressure into particles of silicic acid disodium Kyumizu sum of minerals contained in the liquid product fine砕化, ultrafine bubbles using a homogenizer is a machine that homogenization ( And at least a step of producing a solution containing 5 microns).

本発明に用いる原水としては、例えば、逆浸透膜浄水装置NK−ML1(日建社製)などを用いることにより得られる純水である。   The raw water used in the present invention is, for example, pure water obtained by using a reverse osmosis membrane water purifier NK-ML1 (manufactured by Nikken).

本発明に用いるケイ酸二ナトリウム九水和物は、原水を電解溶液とすると共に、洗浄力及び防錆力の成分として機能するものであり、メタケイ酸ナトリウムに属する中でも九水和物が電解溶液を製造するにあたり原水に一番溶解し易い性状を持っている。このケイ酸二ナトリウム九水和物の添加量は、好ましくは、全量に対して10〜90ミリモル%であるが、一般的には、アルカリ度の安全性面を考慮すると50ミリモル%前後とすることが好ましい。 Silicate Disodium Kyumizu sum was used in the present invention, together with the electrolyte solution raw water, which functions as a component of the detergency and rust prevention, the electrolytic solution nonahydrate Among belonging to sodium metasilicate Has the property of being most easily dissolved in raw water. The amount of the silicate Disodium Kyumizu sum thereof is preferably a 10 to 90 mmol% based on the total amount, in general, to 50 mmol% or so in consideration of the safety surface alkalinity It is preferable.

本発明の製造する方法では、純水の原水にケイ酸二ナトリウム九水和物を上述の如く好ましい範囲で添加し、必要により攪拌しながら電解質溶液を作り、この電解質溶液中に窒素ガスを送り続けると同時に超音波発振器により気泡を圧壊させる工程を30分以上行い、その後工程で液体製品中に含まれる無機質のケイ酸二ナトリウム九水和物の粒子に高い圧力を加えて微砕化、均質化する機械であるホモジナイザーを用いて超微細気泡(5ミクロン)を含む溶解液を製造する。 In the method of manufacturing of the present invention, the raw water to silicate disodium Kyumizu sum of pure water was added in the preferred range as described above, make stirring electrolytic solution necessary, sends a nitrogen gas to the electrolyte solution continuing at the same time performs a step of crushing the bubble 30 minutes or more by an ultrasonic oscillator, then step in adding higher pressure into particles of silicic acid disodium Kyumizu sum of minerals contained in the liquid product fine砕化, homogeneous A solution containing ultrafine bubbles (5 microns) is produced using a homogenizer which is a machine to be converted.

また、超音波発振器としては、例えば、超音波を照射する超音波振動子及び副射板型振動子を備えたUS−12B(USメック社製)で高耐圧S−Tトランジスタを使用することにより、高効率で軽量、小型となっており、又、振動子の共振周波調整・出力電力調整機能を有し使い易く、この照射される超音波の周波数は、30KHz前後であることが好ましい。   In addition, as an ultrasonic oscillator, for example, by using a high-voltage ST transistor in US-12B (manufactured by US Mec Co., Ltd.) provided with an ultrasonic vibrator that irradiates ultrasonic waves and a sub-split plate type vibrator. It is highly efficient, lightweight and compact, and has a function of adjusting the resonance frequency and output power of the vibrator and is easy to use. The frequency of the irradiated ultrasonic wave is preferably around 30 KHz.

本発明の製造する方法では、本発明の効果を更に発揮させる点から、気泡発生器として空気による気泡(マイクロバブル)発生方法を用いると電解質溶液中に多量の空気中の酸素(O)が吹き込まれるために電解質溶液が酸化劣化され易く製品の長期的な品質安定面において不安定な要因となり、その要因をクリアするために窒素ガスを送り続けると同時に超音波により気泡を圧壊させる工程を30分以上行い、その後工程で液体製品中に含まれる無機質のケイ酸二ナトリウム九水和物の粒子に高い圧力を加えて微砕化、均質化する機械であるホモジナイザーを用いて超微細気泡(5ミクロン)を含む溶解液を製造することにより、ケイ酸二ナトリウム九水和物を主剤とした無機系の水性洗浄剤の長期的な安定した品質及び脱脂洗浄後に発生するシミの問題解決や優れた防錆力を得た水性洗浄剤製造できる。 In the production method of the present invention, from the point of further exerting the effect of the present invention, when a bubble generation method using air as a bubble generator is used, a large amount of oxygen (O 2 ) in the air is contained in the electrolyte solution. Since the electrolyte solution is easily oxidatively deteriorated because it is blown in, it becomes an unstable factor in terms of long-term quality stability of the product, and in order to clear the factor, a process of crushing bubbles by ultrasonic waves while continuing to send nitrogen gas is performed 30 min conducted above, then fine adding high pressure into particles of silicic acid disodium Kyumizu sum of minerals contained in the liquid product in step砕化, ultrafine bubbles using a homogenizer is a machine for homogenizing (5 by producing a solution containing microns), after long-term stable quality and degreasing cleaning of inorganic aqueous detergent that a main agent and silicate disodium Kyumizu sum thereof It can produce an aqueous cleaning agent to obtain a problem-solving and excellent rust prevention of stains that live.

また、本発明の効果を高めるために上述の窒素ガスを送り続けると同時に超音波により気泡を圧壊させる工程を30分前後行うことが好ましく、また、その後工程で液体製品中に含まれる無機質のケイ酸二ナトリウム九水和物の粒子に高い圧力を加えて微砕化、均質化する機械であるホモジナイザーを用いて超微細気泡(5ミクロン)を含む溶解液を製造する工程は1時間前後することが好ましく、これらの工程の際の原水(電解質溶液)の温度は、一年を通して常温でよい。 Further, in order to enhance the effect of the present invention, it is preferable to carry out the step of crushing bubbles by ultrasonic waves at the same time as the above-mentioned nitrogen gas is continuously fed, and the inorganic silica contained in the liquid product in the subsequent step. process of producing the particles of disodium Kyumizu sum was added with high pressure fine砕化, a solution containing a machine in which a homogenizer ultrafine bubbles (5 microns) to homogenization and 1 hour before and after Preferably, the temperature of the raw water (electrolyte solution) during these steps may be normal temperature throughout the year.

このようにして、造られたケイ酸二ナトリウム九水和物含有の溶解液は、アルカリ度(pH)が12.8〜13.2であることを確認した。この基準値は、強アルカリ性の水性洗浄剤として示すものである。 Thus, lysates made silicic acid disodium Kyumizu sum Mono含 Yes, it was confirmed that alkalinity (pH) is 12.8 to 13.2. This reference value is shown as a strongly alkaline aqueous cleaning agent.

造られた溶解液は、濾過フィルターを通して製品貯槽へ移送され、製品貯槽から所定量の無機系の水性洗浄剤として小分けされて製品とされる。   The produced solution is transferred to a product storage tank through a filtration filter, and is subdivided into a predetermined amount of an inorganic aqueous cleaning agent from the product storage tank.

実施形態1
本発明の実施の一例について添付した図面に基づき説明する。図1に示すように、本発明の製造する方法は、原水(水道水)1の調整バルブ2を介して逆浸透膜浄水装置3に供給されて不溶解性の不純物及び残留塩素を除去して溶解槽15にバッチ形式で注入される。溶解槽15内の原水には、ケイ酸二ナトリウム九水和物を50ミリモル%添加し必要に応じて攪拌し窒素ガス8を送り続けると同時に超音波発振器4で周波数30KHzを副射板振動子5に伝導して気泡を圧壊させる工程を30分前後行う。また、移送ポンプ10にて、その後工程で液体製品中に含まれる無機質のケイ酸二ナトリウム九水和物の粒子に高い圧力を加えて微砕化、均質化する機械であるホモジナイザー12に送り超微細気泡(5ミクロン)を含む溶解液を製造する工程は、1時間前後する。これらの工程の際の原水(電解質溶液)の温度は、一年を通して常温でよい。このようにして、造られて水性洗浄剤は、アルカリ度(pH)の測定を行い、所定の基準値のチェツクをして無機系の水性洗浄剤として小分けされて製品とされる。
Embodiment 1
An embodiment of the present invention will be described with reference to the accompanying drawings. As shown in FIG. 1, the manufacturing method of the present invention removes insoluble impurities and residual chlorine by being supplied to a reverse osmosis membrane water purification device 3 via a regulating valve 2 of raw water (tap water) 1. It is injected into the dissolution tank 15 in a batch format. The raw water in the dissolving tank 15, silicate disodium Kyumizu sum was sub morphism plate vibrator frequency 30KHz ultrasonic oscillator 4 while at the same time continue to send nitrogen gas 8 and stirred as required by adding 50 mmol% The process of conducting bubbles to 5 and crushing bubbles is performed for about 30 minutes. Further, in the transfer pump 10, then step in the feed by adding a high pressure to the particles of silicic acid disodium Kyumizu sum of minerals contained in the liquid product fine砕化, the homogenizer 12 is a machine for homogenizing greater process for producing a solution containing fine bubbles (5 microns) is one hour before and after. The temperature of the raw water (electrolyte solution) during these steps may be room temperature throughout the year. The aqueous cleaning agent thus prepared is measured for alkalinity (pH), checked to a predetermined reference value, and subdivided into inorganic aqueous cleaning agents to obtain products.

本発明方法によって製造された無機系の水性洗浄剤は、1〜30%に希釈して自動車、家電、電子産業などの加工品の脱脂洗浄を使用目的した界面活性剤などの有機物を全く含有していない。また、この水性洗浄剤は、優れた洗浄力を持ち、発泡性がなく、防錆力も強く、油水分離性も良く、使用後の廃液処理が簡易的あり、長期的な安定した品質及び脱脂洗浄後に発生するシミの問題解決などをクリアーした無機系の水性洗浄剤である。そして、地球温暖化の一つの要因であるVOC及びCO対策など環境対策を考慮した取り扱いの易しく、安全性の高い無機系の水性洗浄剤を提供できる。 The inorganic water-based cleaning agent produced by the method of the present invention does not contain any organic substances such as surfactants that are diluted to 1 to 30% and used for degreasing cleaning of processed products such as automobiles, home appliances, and electronic industries. Not. In addition, this aqueous detergent has excellent detergency, no foaming, strong rust prevention, good oil / water separation, easy waste liquid treatment after use, long-term stable quality and degreasing cleaning It is an inorganic water-based cleaning agent that solves the problem of stains that occur later. In addition, it is possible to provide an inorganic water-based cleaning agent that is easy to handle and highly safe in consideration of environmental measures such as VOC and CO 2 countermeasures, which are one cause of global warming.

本発明の水性洗浄剤の製造工程の概略図。Schematic of the manufacturing process of the aqueous cleaning agent of this invention. ホモジナイザーによる溶解性能試験表Test table for dissolution performance with homogenizer

1.原水
2.調整バルブ
3.逆浸透膜浄水装置
4.超音波発振器
5.副射板振動子
6.溶解槽
7.ケイ酸二ナトリウム九水和
8.窒素ガス
9.移送バルブ
10.移送ポンプ
11.ろ過フィルター
12.ホモジナイザー
13.ろ過フィルター
14.供給バルブ
15.製品(洗浄剤)
1. Raw water Adjustment valve Reverse osmosis membrane water purification device 4. 4. Ultrasonic oscillator Sub-split plate vibrator 6. Dissolution tank 7. Silicic acid disodium Kyumizu sum object 8. Nitrogen gas 9. Transfer valve 10. Transfer pump 11. Filtration filter 12. Homogenizer 13. Filtration filter 14. Supply valve 15. Product (cleaning agent)

Claims (4)

純水にケイ酸二ナトリウム九水和物を添加して電解質溶液とし、該電解質溶液中に窒素ガスを送り続けると同時に超音波により気泡を圧壊し微細気泡を含む溶液を製造する工程を少なくとも含むことを特徴とする水性洗浄剤の製造方法。 In pure water was added silicate Disodium Kyumizu sum was an electrolyte solution, at least comprising the step of producing a solution containing fine bubbles crushing bubbles by ultrasonic at the same time continues to send nitrogen gas to the electrolyte solution The manufacturing method of the aqueous cleaning agent characterized by the above-mentioned. ケイ酸二ナトリウム九水和物の添加量が、10〜90ミリモル%である請求項1記載の水性洗浄剤の製造方法。   The method for producing an aqueous detergent according to claim 1, wherein the amount of disodium silicate nonahydrate added is 10 to 90 mmol%. 窒素ガスを送り続けると同時に超音波により気泡を圧壊させる工程を30分以上行い、その後工程で液体製品中に含まれる無機質のケイ酸二ナトリウム九水和物の粒子に高い圧力を加えて微砕化、均質化する機械であるホモジナイザーを用いて超微細気泡を含む溶液を製造する工程を含む、請求項1又は2記載の水性洗浄剤の製造方法。 Continuing feeding nitrogen gas the step of collapsing bubbles by ultrasonic simultaneously carried out for 30 minutes or more, the fine grinding by adding a high pressure to the particles of the subsequent silicate minerals contained in the liquid product in step disodium Kyumizu sum thereof of a machine that homogenized using a homogenizer comprising the step of producing a solution containing ultrafine bubbles the method according to claim 1 or 2 SL placing the aqueous detergent. 請求項1〜3の何れか一つに記載の洗浄剤の製造方法により得られる事を特徴とする水性洗浄剤。   An aqueous cleaning agent obtained by the method for producing a cleaning agent according to any one of claims 1 to 3.
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