JP2009529528A5 - - Google Patents
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- Publication number
- JP2009529528A5 JP2009529528A5 JP2008558261A JP2008558261A JP2009529528A5 JP 2009529528 A5 JP2009529528 A5 JP 2009529528A5 JP 2008558261 A JP2008558261 A JP 2008558261A JP 2008558261 A JP2008558261 A JP 2008558261A JP 2009529528 A5 JP2009529528 A5 JP 2009529528A5
- Authority
- JP
- Japan
- Prior art keywords
- process according
- octene
- acid
- feedstock
- produce
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000034 method Methods 0.000 claims 12
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-Octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 claims 8
- 150000008065 acid anhydrides Chemical class 0.000 claims 4
- ZWRUINPWMLAQRD-UHFFFAOYSA-N 1-Nonanol Chemical compound CCCCCCCCCO ZWRUINPWMLAQRD-UHFFFAOYSA-N 0.000 claims 3
- 239000002253 acid Substances 0.000 claims 3
- 239000003054 catalyst Substances 0.000 claims 3
- 229920000915 polyvinyl chloride Polymers 0.000 claims 3
- WNLRTRBMVRJNCN-UHFFFAOYSA-N Adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 claims 2
- 150000001336 alkenes Chemical class 0.000 claims 2
- 150000002148 esters Chemical class 0.000 claims 2
- VQTUBCCKSQIDNK-UHFFFAOYSA-N isobutene Chemical compound CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 claims 2
- 238000006384 oligomerization reaction Methods 0.000 claims 2
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 claims 1
- XNGIFLGASWRNHJ-UHFFFAOYSA-N Phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 claims 1
- LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Chemical compound C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 claims 1
- 235000011037 adipic acid Nutrition 0.000 claims 1
- 239000001361 adipic acid Substances 0.000 claims 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims 1
- 229910002091 carbon monoxide Inorganic materials 0.000 claims 1
- 238000006243 chemical reaction Methods 0.000 claims 1
- 238000007037 hydroformylation reaction Methods 0.000 claims 1
- 239000000203 mixture Substances 0.000 claims 1
- 239000002808 molecular sieve Substances 0.000 claims 1
- SRPWOOOHEPICQU-UHFFFAOYSA-N trimellitic anhydride Chemical compound OC(=O)C1=CC=C2C(=O)OC(=O)C2=C1 SRPWOOOHEPICQU-UHFFFAOYSA-N 0.000 claims 1
Claims (12)
- 原料油中のオレフィンの重量に対し少なくとも１２ｗｔ％を越えるイソブテンを含む原料油と、少なくとも１つの１０または１２員環チャンネル系を含み、ＭＦＳ型構造を有する多次元モレキュラーシーブとを、オクテンの全重量に対し１０ｗｔ％未満の三分岐鎖オクテンを含み、オクテン分岐指数が２未満のオクテンを含有する生成物を製造するオリゴマー化条件下で接触させ、オリゴマー化条件が、反応器入り口で測定した温度が少なくとも約２２０℃であることを特徴とするプロセス。
- 触媒が、完全におよび／または一部がプロトン化されたＺＳＭ−５７である、請求項１に記載のプロセス。
- 触媒の９０ｗｔ％が、完全におよび／または一部がプロトン化されたＺＳＭ−５７である、請求項１または請求項２に記載のプロセス。
- 原料油がラフィネート−１である、請求項１から請求項３のいずれか１項に記載のプロセス。
- オクテンを含む生成物は、全オクテンの重量に対し８ｗｔ％未満の三分岐鎖オクテンを含有する請求項１から請求項４のいずれか１項に記載のプロセス。
- 原料油が、原料油中のオレフィンの重量に対し１２から４０ｗｔ％のイソブテンを含む、請求項１から請求項５のいずれか１項に記載のプロセス。
- 生成物が、オクテン分岐指数１．９未満のオクテンを含む、請求項１から請求項６のいずれか１項に記載のプロセス。
- オリゴマー化条件に、さらにブテンのシングルパス転化率が８０％から約９５％であることが含まれる、請求項１から請求項７のいずれか１項に記載のプロセス。
- さらに、オクテンを含む生成物を、ヒドロホルミル化触媒の存在下で、Ｃ９アルコールを生じる条件下で一酸化炭素およびＨ２と接触させるステップを備える、請求項１から請求項８のいずれか１項に記載のプロセス。
- さらに、生じたＣ９アルコールを少なくとも１の酸または酸無水物と接触させ、このＣ９アルコールと少なくとも１の酸または酸無水物とのエステルを生成させるステップを備える、請求項１から請求項９のいずれか１項に記載のプロセス。
- 少なくとも１の酸または酸無水物が、フタル酸および／または無水物、メリット酸および／またはトリメリット酸無水物、アジピン酸、およびこれらの混合物からなる群から選択される、請求項１０に記載のプロセス。
- エステルをＰＶＣと混合して可塑化されたＰＶＣを製造し、この可塑化されたＰＶＣを押出成型して成型品を形成するステップを含む、請求項１１に記載のプロセス。
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US11/373,360 | 2006-03-10 | ||
| US11/373,360 US7501548B2 (en) | 2006-03-10 | 2006-03-10 | Oligomerization of isobutene-containing feedstocks |
| PCT/US2007/001211 WO2007106215A1 (en) | 2006-03-10 | 2007-01-16 | Oligomerization of isobutene-containing feedstocks |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2009529528A JP2009529528A (ja) | 2009-08-20 |
| JP2009529528A5 true JP2009529528A5 (ja) | 2012-03-01 |
| JP5281902B2 JP5281902B2 (ja) | 2013-09-04 |
Family
ID=37025164
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2008558261A Expired - Fee Related JP5281902B2 (ja) | 2006-03-10 | 2007-01-16 | イソブテンを含む原料油のオリゴマー化 |
Country Status (8)
| Country | Link |
|---|---|
| US (2) | US7501548B2 (ja) |
| EP (1) | EP1993981B1 (ja) |
| JP (1) | JP5281902B2 (ja) |
| CN (1) | CN101400630B (ja) |
| AT (1) | ATE522485T1 (ja) |
| TW (1) | TWI339649B (ja) |
| WO (1) | WO2007106215A1 (ja) |
| ZA (1) | ZA200807050B (ja) |
Families Citing this family (28)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7667086B2 (en) * | 2005-01-31 | 2010-02-23 | Exxonmobil Chemical Patents Inc. | Olefin oligomerization and biodegradable compositions therefrom |
| US7501548B2 (en) * | 2006-03-10 | 2009-03-10 | Exxonmobil Chemical Patents Inc. | Oligomerization of isobutene-containing feedstocks |
| EP2098498A1 (en) | 2008-03-04 | 2009-09-09 | ExxonMobil Chemical Patents Inc. | Selective oligomerization of isobutene |
| US7786338B2 (en) * | 2007-10-26 | 2010-08-31 | Exxonmobil Research And Engineering Company | Selective oligomerization of isobutene |
| US8669407B2 (en) * | 2008-08-28 | 2014-03-11 | Exxonmobil Chemical Patents Inc. | Method of isolating linear butenes from a mixed hydrocarbon feed |
| US8440864B2 (en) * | 2008-10-10 | 2013-05-14 | Exxonmobil Chemical Patents Inc. | Process for producing sec-butylbenzene |
| US8476350B2 (en) | 2008-12-24 | 2013-07-02 | Exxonmobil Research And Engineering Company | Triglyceride plasticizer and process of making |
| US8771815B2 (en) | 2009-12-17 | 2014-07-08 | Exxonmobil Research And Engineering Company | Process for making triglyceride plasticizer |
| US8703683B2 (en) | 2010-04-23 | 2014-04-22 | Exxonmobil Research And Engineering Company | Poly (alkyl epdxides), process for making, and lubricant compositions having same |
| US20120022224A1 (en) * | 2010-07-22 | 2012-01-26 | Geraldine Tosin | Particles Including Zeolite Catalysts And Their Use In Oligomerization Processes |
| JP5767875B2 (ja) * | 2011-06-29 | 2015-08-26 | 出光興産株式会社 | 混合ｃ４留分を原料とするジイソブチレンの製造方法 |
| US9914672B2 (en) | 2012-10-19 | 2018-03-13 | Lummus Technology Inc. | Conversion of alcohols to distillate fuels |
| US9834492B2 (en) | 2012-11-12 | 2017-12-05 | Uop Llc | Process for fluid catalytic cracking oligomerate |
| US9644159B2 (en) | 2012-11-12 | 2017-05-09 | Uop Llc | Composition of oligomerate |
| WO2014074833A1 (en) | 2012-11-12 | 2014-05-15 | Uop Llc | Process for making gasoline by oligomerization |
| US9522373B2 (en) | 2012-11-12 | 2016-12-20 | Uop Llc | Apparatus for oligomerizing light olefins |
| US9914673B2 (en) | 2012-11-12 | 2018-03-13 | Uop Llc | Process for oligomerizing light olefins |
| US9434891B2 (en) | 2012-11-12 | 2016-09-06 | Uop Llc | Apparatus for recovering oligomerate |
| US9663415B2 (en) | 2012-11-12 | 2017-05-30 | Uop Llc | Process for making diesel by oligomerization of gasoline |
| US9567267B2 (en) | 2012-11-12 | 2017-02-14 | Uop Llc | Process for oligomerizing light olefins including pentenes |
| US9441173B2 (en) | 2012-11-12 | 2016-09-13 | Uop Llc | Process for making diesel by oligomerization |
| US9522375B2 (en) | 2012-11-12 | 2016-12-20 | Uop Llc | Apparatus for fluid catalytic cracking oligomerate |
| US10508064B2 (en) | 2012-11-12 | 2019-12-17 | Uop Llc | Process for oligomerizing gasoline without further upgrading |
| US9498772B2 (en) * | 2013-11-26 | 2016-11-22 | Saudi Arabian Oil Company | Unsupported metal substituted heteropolyacid catalysts for dimerization and/or oligomerization of olefins |
| US20150148572A1 (en) * | 2013-11-27 | 2015-05-28 | Saudi Arabian Oil Company | Process for the Dimerization/Oligomerization of Mixed Butenes Over an Ion-Exchange Resin Catalyst |
| CN113929549B (zh) * | 2020-06-29 | 2023-12-08 | 中国石油化工股份有限公司 | 一种混合碳四选择性叠合方法 |
| KR102580498B1 (ko) * | 2021-07-02 | 2023-09-20 | 한국화학연구원 | 이산화탄소의 탄화수소로의 전환 시스템 및 그 전환 공정 |
| US20240166776A1 (en) * | 2022-11-23 | 2024-05-23 | Braskem S.A. | Use of proton-form zeolite catalyst to produce light-polyisobutylene |
Family Cites Families (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR1603512A (ja) * | 1968-10-31 | 1971-05-03 | ||
| US5026933A (en) * | 1987-10-07 | 1991-06-25 | Mobil Oil Corporation | Olefin oligomerization with surface modified zeolite catalyst |
| US4962249A (en) * | 1988-06-23 | 1990-10-09 | Mobil Oil Corporation | High VI lubricants from lower alkene oligomers |
| ATE155454T1 (de) | 1992-01-30 | 1997-08-15 | Exxon Chemical Patents Inc | Alkenoligomerisierung |
| GB9312245D0 (en) | 1993-06-14 | 1993-07-28 | Exxon Chemical Patents Inc | Hydrocarbon treatment |
| WO1995022516A1 (en) | 1994-02-22 | 1995-08-24 | Exxon Chemical Patents Inc. | Oligomerization and catalysts therefor |
| GB0010433D0 (en) | 2000-04-28 | 2000-06-14 | Exxon Chemical Patents Inc | Alkene oligomerization process |
| US7112711B2 (en) * | 2000-04-28 | 2006-09-26 | Exxonmobil Chemical Patents Inc. | Alkene oligomerization process |
| ATE247612T1 (de) | 2000-06-26 | 2003-09-15 | Saudi Basic Ind Corp | Dimerisierung von olefinen |
| US6875899B2 (en) * | 2001-02-01 | 2005-04-05 | Exxonmobil Chemical Patents Inc. | Production of higher olefins |
| AU2003220593A1 (en) * | 2002-03-29 | 2003-10-13 | Exxonmobil Chemical Patents Inc. | Improved cobalt flash process |
| US7196238B2 (en) * | 2003-03-10 | 2007-03-27 | Fortum Oyj | Process for dimerizing light olefins |
| US6969736B1 (en) * | 2004-05-27 | 2005-11-29 | Exxonmobil Chemical Patents Inc. | Plasticizers from less branched nonyl alcohols |
| US7501548B2 (en) | 2006-03-10 | 2009-03-10 | Exxonmobil Chemical Patents Inc. | Oligomerization of isobutene-containing feedstocks |
-
2006
- 2006-03-10 US US11/373,360 patent/US7501548B2/en not_active Expired - Fee Related
-
2007
- 2007-01-16 JP JP2008558261A patent/JP5281902B2/ja not_active Expired - Fee Related
- 2007-01-16 EP EP07716715A patent/EP1993981B1/en not_active Not-in-force
- 2007-01-16 WO PCT/US2007/001211 patent/WO2007106215A1/en active Application Filing
- 2007-01-16 CN CN2007800084147A patent/CN101400630B/zh not_active Expired - Fee Related
- 2007-01-16 AT AT07716715T patent/ATE522485T1/de not_active IP Right Cessation
- 2007-01-18 TW TW096101945A patent/TWI339649B/zh active
-
2008
- 2008-08-15 ZA ZA200807050A patent/ZA200807050B/xx unknown
-
2009
- 2009-01-28 US US12/361,030 patent/US7737315B2/en not_active Expired - Fee Related
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