JP2009521723A - 化学的に製造された多孔質トナー - Google Patents
化学的に製造された多孔質トナー Download PDFInfo
- Publication number
- JP2009521723A JP2009521723A JP2008547570A JP2008547570A JP2009521723A JP 2009521723 A JP2009521723 A JP 2009521723A JP 2008547570 A JP2008547570 A JP 2008547570A JP 2008547570 A JP2008547570 A JP 2008547570A JP 2009521723 A JP2009521723 A JP 2009521723A
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- JP
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- Prior art keywords
- toner
- polymer
- organic solution
- monomer
- pore
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- 239000002245 particle Substances 0.000 claims abstract description 42
- 239000000178 monomer Substances 0.000 claims abstract description 37
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims abstract description 21
- 238000004519 manufacturing process Methods 0.000 claims abstract description 12
- 229920002554 vinyl polymer Polymers 0.000 claims abstract description 9
- 229920000642 polymer Polymers 0.000 claims description 51
- 238000000034 method Methods 0.000 claims description 35
- 239000011324 bead Substances 0.000 claims description 28
- 239000000203 mixture Substances 0.000 claims description 23
- 239000011230 binding agent Substances 0.000 claims description 17
- 150000001875 compounds Chemical class 0.000 claims description 16
- 239000003795 chemical substances by application Substances 0.000 claims description 15
- 239000003086 colorant Substances 0.000 claims description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 11
- 239000000243 solution Substances 0.000 claims description 9
- 229920002545 silicone oil Polymers 0.000 claims description 8
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 claims description 6
- 239000007864 aqueous solution Substances 0.000 claims description 5
- 239000003381 stabilizer Substances 0.000 claims description 5
- 238000009833 condensation Methods 0.000 claims description 4
- 230000005494 condensation Effects 0.000 claims description 4
- 239000003505 polymerization initiator Substances 0.000 claims description 4
- 239000011347 resin Substances 0.000 claims description 4
- 229920005989 resin Polymers 0.000 claims description 4
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 4
- 150000001335 aliphatic alkanes Chemical class 0.000 claims description 3
- 239000000314 lubricant Substances 0.000 claims description 2
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims 3
- 239000012756 surface treatment agent Substances 0.000 claims 2
- IWBUOAHJGJZERP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;butyl prop-2-enoate;styrene Chemical compound C=CC1=CC=CC=C1.CCCCOC(=O)C=C.C=CC1=CC=CC=C1C=C IWBUOAHJGJZERP-UHFFFAOYSA-N 0.000 claims 1
- 239000002152 aqueous-organic solution Substances 0.000 claims 1
- 230000001804 emulsifying effect Effects 0.000 claims 1
- 230000000379 polymerizing effect Effects 0.000 claims 1
- 229920001577 copolymer Polymers 0.000 abstract description 6
- 229920000728 polyester Polymers 0.000 abstract description 4
- 238000006116 polymerization reaction Methods 0.000 description 13
- 239000002904 solvent Substances 0.000 description 13
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 12
- 239000000843 powder Substances 0.000 description 9
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 8
- -1 alkyl methacrylate Chemical compound 0.000 description 8
- 238000009826 distribution Methods 0.000 description 7
- 238000000605 extraction Methods 0.000 description 7
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- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 6
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 6
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 6
- 238000012856 packing Methods 0.000 description 6
- 239000012074 organic phase Substances 0.000 description 5
- 230000008569 process Effects 0.000 description 5
- QLOKJRIVRGCVIM-UHFFFAOYSA-N 1-[(4-methylsulfanylphenyl)methyl]piperazine Chemical compound C1=CC(SC)=CC=C1CN1CCNCC1 QLOKJRIVRGCVIM-UHFFFAOYSA-N 0.000 description 4
- ORISNEOOCIBVOL-UHFFFAOYSA-N 2-(methylamino)-1,4-dioxecane-5,10-dione Chemical compound CNC1COC(=O)CCCCC(=O)O1 ORISNEOOCIBVOL-UHFFFAOYSA-N 0.000 description 4
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 4
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 4
- 239000000654 additive Substances 0.000 description 4
- 238000004220 aggregation Methods 0.000 description 4
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- 238000004581 coalescence Methods 0.000 description 4
- 239000012153 distilled water Substances 0.000 description 4
- 238000001704 evaporation Methods 0.000 description 4
- 239000011148 porous material Substances 0.000 description 4
- 238000004626 scanning electron microscopy Methods 0.000 description 4
- 239000000725 suspension Substances 0.000 description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 230000002411 adverse Effects 0.000 description 3
- 125000005250 alkyl acrylate group Chemical group 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 239000000839 emulsion Substances 0.000 description 3
- 230000008020 evaporation Effects 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 2
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
- 241000596422 Pithecellobium Species 0.000 description 2
- 235000002194 Pithecellobium dulce Nutrition 0.000 description 2
- 235000007891 Pithecellobium lobatum Nutrition 0.000 description 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 2
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 2
- 239000007900 aqueous suspension Substances 0.000 description 2
- TUZBYYLVVXPEMA-UHFFFAOYSA-N butyl prop-2-enoate;styrene Chemical compound C=CC1=CC=CC=C1.CCCCOC(=O)C=C TUZBYYLVVXPEMA-UHFFFAOYSA-N 0.000 description 2
- 239000006229 carbon black Substances 0.000 description 2
- NEHMKBQYUWJMIP-UHFFFAOYSA-N chloromethane Chemical compound ClC NEHMKBQYUWJMIP-UHFFFAOYSA-N 0.000 description 2
- 239000003431 cross linking reagent Substances 0.000 description 2
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 2
- 150000001993 dienes Chemical class 0.000 description 2
- 238000004090 dissolution Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
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- 230000004927 fusion Effects 0.000 description 2
- 238000000227 grinding Methods 0.000 description 2
- 238000003384 imaging method Methods 0.000 description 2
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 2
- 239000002480 mineral oil Substances 0.000 description 2
- 235000010446 mineral oil Nutrition 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- YKYONYBAUNKHLG-UHFFFAOYSA-N n-Propyl acetate Natural products CCCOC(C)=O YKYONYBAUNKHLG-UHFFFAOYSA-N 0.000 description 2
- 239000012071 phase Substances 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 229920005596 polymer binder Polymers 0.000 description 2
- 239000002491 polymer binding agent Substances 0.000 description 2
- 229940090181 propyl acetate Drugs 0.000 description 2
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 2
- NQPDZGIKBAWPEJ-UHFFFAOYSA-N valeric acid Chemical compound CCCCC(O)=O NQPDZGIKBAWPEJ-UHFFFAOYSA-N 0.000 description 2
- UOCLXMDMGBRAIB-UHFFFAOYSA-N 1,1,1-trichloroethane Chemical compound CC(Cl)(Cl)Cl UOCLXMDMGBRAIB-UHFFFAOYSA-N 0.000 description 1
- WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-Dichloroethane Chemical compound ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 description 1
- XHAFIUUYXQFJEW-UHFFFAOYSA-N 1-chloroethenylbenzene Chemical compound ClC(=C)C1=CC=CC=C1 XHAFIUUYXQFJEW-UHFFFAOYSA-N 0.000 description 1
- GZBSIABKXVPBFY-UHFFFAOYSA-N 2,2-bis(hydroxymethyl)propane-1,3-diol;prop-2-enoic acid Chemical compound OC(=O)C=C.OC(=O)C=C.OC(=O)C=C.OC(=O)C=C.OCC(CO)(CO)CO GZBSIABKXVPBFY-UHFFFAOYSA-N 0.000 description 1
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 1
- GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 description 1
- WDQMWEYDKDCEHT-UHFFFAOYSA-N 2-ethylhexyl 2-methylprop-2-enoate Chemical compound CCCCC(CC)COC(=O)C(C)=C WDQMWEYDKDCEHT-UHFFFAOYSA-N 0.000 description 1
- FGLBSLMDCBOPQK-UHFFFAOYSA-N 2-nitropropane Chemical compound CC(C)[N+]([O-])=O FGLBSLMDCBOPQK-UHFFFAOYSA-N 0.000 description 1
- VPWNQTHUCYMVMZ-UHFFFAOYSA-N 4,4'-sulfonyldiphenol Chemical class C1=CC(O)=CC=C1S(=O)(=O)C1=CC=C(O)C=C1 VPWNQTHUCYMVMZ-UHFFFAOYSA-N 0.000 description 1
- DBCAQXHNJOFNGC-UHFFFAOYSA-N 4-bromo-1,1,1-trifluorobutane Chemical compound FC(F)(F)CCCBr DBCAQXHNJOFNGC-UHFFFAOYSA-N 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- 229930185605 Bisphenol Natural products 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 1
- 239000004971 Cross linker Substances 0.000 description 1
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 description 1
- FSYKKLYZXJSNPZ-UHFFFAOYSA-N N-methylaminoacetic acid Natural products C[NH2+]CC([O-])=O FSYKKLYZXJSNPZ-UHFFFAOYSA-N 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 108010077895 Sarcosine Proteins 0.000 description 1
- DAKWPKUUDNSNPN-UHFFFAOYSA-N Trimethylolpropane triacrylate Chemical compound C=CC(=O)OCC(CC)(COC(=O)C=C)COC(=O)C=C DAKWPKUUDNSNPN-UHFFFAOYSA-N 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- ORLQHILJRHBSAY-UHFFFAOYSA-N [1-(hydroxymethyl)cyclohexyl]methanol Chemical compound OCC1(CO)CCCCC1 ORLQHILJRHBSAY-UHFFFAOYSA-N 0.000 description 1
- HSZUHSXXAOWGQY-UHFFFAOYSA-N [2-methyl-3-prop-2-enoyloxy-2-(prop-2-enoyloxymethyl)propyl] prop-2-enoate Chemical compound C=CC(=O)OCC(C)(COC(=O)C=C)COC(=O)C=C HSZUHSXXAOWGQY-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 239000012736 aqueous medium Substances 0.000 description 1
- 239000008346 aqueous phase Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 229960001701 chloroform Drugs 0.000 description 1
- 238000004587 chromatography analysis Methods 0.000 description 1
- 230000015271 coagulation Effects 0.000 description 1
- 238000005345 coagulation Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 150000002009 diols Chemical class 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000012377 drug delivery Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 238000010556 emulsion polymerization method Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 description 1
- STVZJERGLQHEKB-UHFFFAOYSA-N ethylene glycol dimethacrylate Substances CC(=C)C(=O)OCCOC(=O)C(C)=C STVZJERGLQHEKB-UHFFFAOYSA-N 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- 239000004816 latex Substances 0.000 description 1
- 229920000126 latex Polymers 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- HMZGPNHSPWNGEP-UHFFFAOYSA-N octadecyl 2-methylprop-2-enoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)C(C)=C HMZGPNHSPWNGEP-UHFFFAOYSA-N 0.000 description 1
- 238000007645 offset printing Methods 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 238000000399 optical microscopy Methods 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 238000012643 polycondensation polymerization Methods 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 238000000518 rheometry Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229940043230 sarcosine Drugs 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 238000000638 solvent extraction Methods 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 229920001909 styrene-acrylic polymer Polymers 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 238000010558 suspension polymerization method Methods 0.000 description 1
- 238000010557 suspension polymerization reaction Methods 0.000 description 1
- KAKZBPTYRLMSJV-UHFFFAOYSA-N vinyl-ethylene Natural products C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Images
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
- G03G9/00—Developers
- G03G9/08—Developers with toner particles
- G03G9/087—Binders for toner particles
- G03G9/08702—Binders for toner particles comprising macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- G03G9/08706—Polymers of alkenyl-aromatic compounds
- G03G9/08708—Copolymers of styrene
- G03G9/08711—Copolymers of styrene with esters of acrylic or methacrylic acid
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
- G03G9/00—Developers
- G03G9/08—Developers with toner particles
- G03G9/0802—Preparation methods
- G03G9/0804—Preparation methods whereby the components are brought together in a liquid dispersing medium
- G03G9/0806—Preparation methods whereby the components are brought together in a liquid dispersing medium whereby chemical synthesis of at least one of the toner components takes place
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
- G03G9/00—Developers
- G03G9/08—Developers with toner particles
- G03G9/0825—Developers with toner particles characterised by their structure; characterised by non-homogenuous distribution of components
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
- G03G9/00—Developers
- G03G9/08—Developers with toner particles
- G03G9/087—Binders for toner particles
- G03G9/08775—Natural macromolecular compounds or derivatives thereof
- G03G9/08782—Waxes
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
- G03G9/00—Developers
- G03G9/08—Developers with toner particles
- G03G9/087—Binders for toner particles
- G03G9/08784—Macromolecular material not specially provided for in a single one of groups G03G9/08702 - G03G9/08775
- G03G9/08795—Macromolecular material not specially provided for in a single one of groups G03G9/08702 - G03G9/08775 characterised by their chemical properties, e.g. acidity, molecular weight, sensitivity to reactants
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
- G03G9/00—Developers
- G03G9/08—Developers with toner particles
- G03G9/087—Binders for toner particles
- G03G9/08784—Macromolecular material not specially provided for in a single one of groups G03G9/08702 - G03G9/08775
- G03G9/08797—Macromolecular material not specially provided for in a single one of groups G03G9/08702 - G03G9/08775 characterised by their physical properties, e.g. viscosity, solubility, melting temperature, softening temperature, glass transition temperature
Landscapes
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Developing Agents For Electrophotography (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US11/313,612 US8192909B2 (en) | 2005-12-21 | 2005-12-21 | Chemically prepared porous toner |
| PCT/US2006/048886 WO2007075941A1 (en) | 2005-12-21 | 2006-12-21 | Chemically prepared porous toner |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2009521723A true JP2009521723A (ja) | 2009-06-04 |
| JP2009521723A5 JP2009521723A5 (enExample) | 2011-02-24 |
Family
ID=38009739
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2008547570A Pending JP2009521723A (ja) | 2005-12-21 | 2006-12-21 | 化学的に製造された多孔質トナー |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US8192909B2 (enExample) |
| EP (1) | EP1963926A1 (enExample) |
| JP (1) | JP2009521723A (enExample) |
| WO (1) | WO2007075941A1 (enExample) |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7754409B2 (en) * | 2007-01-18 | 2010-07-13 | Eastman Kodak Company | Toner manufacturing method |
| US7887984B2 (en) * | 2007-01-18 | 2011-02-15 | Eastman Kodak Company | Toner porous particles containing hydrocolloids |
| US7888410B2 (en) * | 2007-04-24 | 2011-02-15 | Eastman Kodak Company | Method of making porous particles |
| US7867679B2 (en) * | 2007-04-24 | 2011-01-11 | Eastman Kodak Company | Porous particles |
| US8652637B2 (en) * | 2007-10-11 | 2014-02-18 | Eastman Kodak Company | Porous particles with non-porous shell |
| US8940362B2 (en) * | 2007-10-11 | 2015-01-27 | Eastman Kodak Company | Method for manufacturing porous particles with non-porous shell |
| US8299141B2 (en) * | 2007-12-21 | 2012-10-30 | Eastman Kodak Company | Mixed phase method of manufacturing ink |
| US8299140B2 (en) * | 2007-12-21 | 2012-10-30 | Eastman Kodak Company | Discrete ink particle with solid phase and liquid phase |
| US8252414B2 (en) * | 2008-07-24 | 2012-08-28 | Eastman Kodak Company | Polymer particles with additives encapsulated in microvoids |
| US20120003581A1 (en) * | 2010-06-30 | 2012-01-05 | Xiqiang Yang | Method of manufacturing wax-containing polymer particles |
| US20150111148A1 (en) * | 2013-10-18 | 2015-04-23 | Xerox Corporation | Porous Resin Particles |
| US12147010B2 (en) | 2020-12-17 | 2024-11-19 | Eastman Kodak Company | Coating providing ultraviolet scattering |
| US12454622B2 (en) | 2020-12-17 | 2025-10-28 | Eastman Kodak Company | Coating providing controlled absorption and scattering |
| US12240957B2 (en) | 2020-12-17 | 2025-03-04 | Eastman Kodak Company | Method for fabricating impermeable porous particles |
| US12428566B2 (en) | 2020-12-17 | 2025-09-30 | Eastman Kodak Company | Coating providing panchromatic scattering |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2005017582A (ja) * | 2003-06-25 | 2005-01-20 | Ricoh Co Ltd | 静電荷像現像用トナー、現像剤、画像形成方法、画像形成装置及びプロセスカートリッジ |
Family Cites Families (45)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2229513A (en) | 1938-06-24 | 1941-01-21 | Atwood Vacuum Machine Co | Lid support |
| US2932629A (en) | 1955-03-28 | 1960-04-12 | Dow Chemical Co | Quiescent suspension polymerization |
| US2934530A (en) | 1955-03-28 | 1960-04-26 | Dow Chemical Co | Suspension polymerization |
| US3615972A (en) | 1967-04-28 | 1971-10-26 | Dow Chemical Co | Expansible thermoplastic polymer particles containing volatile fluid foaming agent and method of foaming the same |
| US3893935A (en) | 1972-05-30 | 1975-07-08 | Eastman Kodak Co | Electrographic toner and developer composition |
| CA995953A (en) | 1972-05-30 | 1976-08-31 | Eastman Kodak Company | Electrographic toner and developer composition |
| USRE31072E (en) | 1973-07-18 | 1982-11-02 | Eastman Kodak Company | Electrographic developing composition and process |
| US3979342A (en) | 1973-07-24 | 1976-09-07 | E. I. Du Pont De Nemours And Company | Manufacture of vesiculated polymer granules |
| CA1060696A (en) | 1975-07-09 | 1979-08-21 | Eastman Kodak Company | Electrographic toner and developer composition |
| US4323634A (en) | 1975-07-09 | 1982-04-06 | Eastman Kodak Company | Electrographic toner and developer composition containing quaternary ammonium salt charge control agent |
| US4079014A (en) | 1976-07-21 | 1978-03-14 | Eastman Kodak Company | Electrographic toner and developer composition containing a 4-aza-1-azoniabicyclo(2.2.2) octane salt as a charge control agent |
| JPS5348740A (en) | 1976-10-15 | 1978-05-02 | Ricoh Co Ltd | Pressure sensitive adhesive electrostatic photographic toner |
| US4160644A (en) | 1977-06-13 | 1979-07-10 | Streck Laboratories, Inc. | Platelet reference control and method of preparation |
| DE2927249A1 (de) | 1978-07-07 | 1980-01-17 | Sinloihi Co Ltd | Feine kugelfoermige polymerteilchen mit einem gehalt an einem anorganischen pigment und/oder einem schwarzen faerbungsmittel, sowie verfahren zu deren herstellung |
| GB2072362B (en) | 1980-02-14 | 1983-06-08 | Canon Kk | Porous electropstatographic toner and preparation process thereof |
| US4379825A (en) | 1980-02-14 | 1983-04-12 | Canon Kabushiki Kaisha | Porous electrophotographic toner and preparation process of making |
| US4394430A (en) | 1981-04-14 | 1983-07-19 | Eastman Kodak Company | Electrophotographic dry toner and developer compositions |
| US4414152A (en) | 1981-05-18 | 1983-11-08 | Eastman Kodak Company | Bis aryl-azo derivatives of 2,3-naphthalenediol |
| US4416965A (en) | 1982-07-14 | 1983-11-22 | Eastman Kodak Company | Electrostatographic developers comprising toners containing a polyester having p-hydroxybenzoic acid recurring units |
| US4489174A (en) | 1983-07-26 | 1984-12-18 | The Sherwin-Williams Company | Vesiculated beads |
| EP0180655B1 (en) | 1984-11-05 | 1988-04-06 | Hodogaya Chemical Co., Ltd. | Electrophotographic toner |
| JPS6253944A (ja) | 1985-05-28 | 1987-03-09 | Hodogaya Chem Co Ltd | 電子写真用トナー |
| US4683188A (en) | 1985-05-28 | 1987-07-28 | Hodogaya Chemical Co., Ltd. | Electrophotographic toner containing metal complex charge control agent |
| EP0247248B1 (en) * | 1986-05-29 | 1990-08-08 | Agfa-Gevaert N.V. | A process for image production containing the heat-and-pressure fixing of a still wet or moist toner image |
| US4814250A (en) | 1987-03-17 | 1989-03-21 | Eastman Kodak Company | Electrophotographic toner and developer compositions containing dioctylsulfosuccinate and sodium benzoate charge control agents |
| FR2617982B1 (fr) | 1987-07-09 | 1989-10-27 | Labo Electronique Physique | Dispositif d'elimination d'echos fixes pour echographe ultrasonore |
| US4814253A (en) * | 1987-10-29 | 1989-03-21 | Xerox Corporation | Toner compositions with release agents therein |
| US4840864A (en) | 1987-12-17 | 1989-06-20 | Eastman Kodak Company | New electrostatographic toners and developers containing new charge-control agents |
| US4834920A (en) | 1987-12-17 | 1989-05-30 | Eastman Kodak Company | New quaternary ammonium salts |
| US4833060A (en) | 1988-03-21 | 1989-05-23 | Eastman Kodak Company | Polymeric powders having a predetermined and controlled size and size distribution |
| US4965131A (en) | 1988-03-21 | 1990-10-23 | Eastman Kodak Company | Colloidally stabilized suspension process |
| US5102765A (en) * | 1990-08-06 | 1992-04-07 | Eastman Kodak Company | Toner compositions containing 2-imidazolines, imidazoles or benzimidazoles as charge control agents |
| US5247034A (en) | 1992-10-05 | 1993-09-21 | The Goodyear Tire & Rubber Company | Process for producing toner resin with amino acid soaps |
| EP0651292B1 (en) * | 1993-10-20 | 1998-07-15 | Canon Kabushiki Kaisha | Toner for developing electrostatic images, and process for its production |
| EP0686881A1 (en) | 1994-06-08 | 1995-12-13 | Eastman Kodak Company | Particulate polymer, electrophotographic toner, and preparation method |
| US5545504A (en) * | 1994-10-03 | 1996-08-13 | Xerox Corporation | Ink jettable toner compositions and processes for making and using |
| US6075105A (en) | 1996-08-26 | 2000-06-13 | Xerox Corporation | Polymerization processes and resin particles formed thereby |
| JP4199353B2 (ja) * | 1998-12-24 | 2008-12-17 | シンジーテック株式会社 | 基材上に多孔質被覆層を形成するための方法 |
| JP2003029463A (ja) | 2001-07-18 | 2003-01-29 | Fuji Xerox Co Ltd | 画像形成方法 |
| EP1654056A4 (en) * | 2003-07-03 | 2007-08-08 | Lg Chemical Ltd | METHOD FOR THE PRODUCTION OF MICRO-CAPSULES BY MINI-EMULSION POLYMERIZATION |
| EP1720077B1 (en) | 2004-02-03 | 2012-10-03 | Ricoh Company, Ltd. | Toner and developing agent, container packed with toner, and image forming method |
| US7754409B2 (en) | 2007-01-18 | 2010-07-13 | Eastman Kodak Company | Toner manufacturing method |
| US7887984B2 (en) | 2007-01-18 | 2011-02-15 | Eastman Kodak Company | Toner porous particles containing hydrocolloids |
| US7867679B2 (en) | 2007-04-24 | 2011-01-11 | Eastman Kodak Company | Porous particles |
| US7888410B2 (en) | 2007-04-24 | 2011-02-15 | Eastman Kodak Company | Method of making porous particles |
-
2005
- 2005-12-21 US US11/313,612 patent/US8192909B2/en active Active
-
2006
- 2006-12-21 WO PCT/US2006/048886 patent/WO2007075941A1/en not_active Ceased
- 2006-12-21 EP EP06847963A patent/EP1963926A1/en not_active Withdrawn
- 2006-12-21 JP JP2008547570A patent/JP2009521723A/ja active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2005017582A (ja) * | 2003-06-25 | 2005-01-20 | Ricoh Co Ltd | 静電荷像現像用トナー、現像剤、画像形成方法、画像形成装置及びプロセスカートリッジ |
Also Published As
| Publication number | Publication date |
|---|---|
| US20070141501A1 (en) | 2007-06-21 |
| WO2007075941A1 (en) | 2007-07-05 |
| US8192909B2 (en) | 2012-06-05 |
| EP1963926A1 (en) | 2008-09-03 |
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