JP2009258747A - Plastic lens for spectacles - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To solve the problem of insufficient antishock property of plastic lenses for spectacles, where primer layers are formed on the plastic substrates, hard coat layers are formed on the primer layers, and antireflexion films are formed on the hard coat layers, the antireflection film made thicker than the prescribed film thickness and being formed with convex and concave surfaces. <P>SOLUTION: A primer layer is formed on a plastic base material, a hard coat layer is formed on the primer layer, and an antireflection film is formed on the hard coat layer. In the antireflection film, the optical film thickness on the convex face side of a specific low refractive index layer and the optical film thickness on the concave face side of the specific low refractive index layer are formed to have prescribed ranges, and consequently excellent characteristics, such as the improved hardness of the convex face of a fragile plastic lens, the firmer adherence of the film, improved interference colors and improved shock resistance, are obtained. <P>COPYRIGHT: (C)2010,JPO&INPIT

Description

  The present invention relates to an antireflection film and a plastic lens provided with the same.

When a plastic lens is used as spectacles, there is a merit of lightness and ease of processing, but there is a problem that it is easily damaged because of insufficient hardness. As a countermeasure, a hard coat layer made of metal oxide fine particles and an organosilicon compound is widely formed on the surface of a plastic lens. Further, for the purpose of suppressing reflection of light occurring on the surface thereof, it has become common to form an antireflection film on the hard coat surface on the plastic lens. Moreover, since the substance constituting the antireflection film is a metal oxide such as SiO ₂ or ZrO ₂ , it is greatly involved in the effect of increasing the hardness of the lens surface in addition to the original antireflection effect. As a method of obtaining a desired surface hardness by using an antireflection film, a method of increasing the hardness by devising a film forming method and a method of increasing the film thickness are conceivable. In general, a method of increasing the thickness of a predetermined layer in the multilayer film is employed.
Regarding such an antireflection film, there are the following prior art documents.

Japanese Patent Laid-Open No. 11-30703 JP 2002-122820 A JP 2003-294906 A

  However, after forming the primer layer on the plastic lens substrate, a hard coat layer is formed on the primer layer, and the film thickness of a specific layer as described in Patent Documents 1 to 3 is further formed on the hard coat layer. A plastic lens in which a thick antireflection film is formed on a convex surface and a concave surface has a problem of low impact resistance.

  An object of the present invention is to provide a plastic lens antireflection film that is made in view of the above circumstances and can secure the convex surface hardness, film adhesion, good interference color, and impact resistance of easily damaged plastic lenses. To do.

  The present inventors conducted extensive studies to solve the problems of the antireflection film. After forming a primer layer on a plastic lens substrate, a hard coat layer was formed on the primer layer, and In the antireflection film laminated on the hard coat layer, the optical film thickness of the specific low refractive index layer on the convex side and the optical film thickness of the specific low refractive index layer on the concave side are within a predetermined range. It was found that excellent properties were obtained in terms of the hardness of the convex surface of the plastic lens, the adhesion of the film, the interference color, and even the impact resistance.

In the first invention, after a primer layer is formed on a plastic lens substrate, a hard coat layer is formed on the primer layer, and a low refractive index layer and a high refractive index layer are alternately laminated on the hard coat layer. The antireflection film has a design principal wavelength λ _{0 in} the range of 480 nm to 560 nm, and the layer closest to the base material is the first layer and is directed to the outside in order. The layer is a low refractive index layer, the even number layer is a high refractive index layer, the low refractive index layer is composed of a SiO ₂ layer, and the high refractive index layer is TiO ₂ , Nb ₂ O ₅ , Ta ₂ O ₅ , ZrO ₂ , LaTiO ₂ . The optical film thickness of a specific low refractive index layer on the convex side, which is a surface opposite to the surface facing the eyeball side of the lens, and the surface facing the eyeball side, which is composed of a layer made of one substance selected from ₃ The optical film thickness of a specific low refractive index layer on the concave side is predetermined Providing a plastic lens characterized by being formed by a range of values.

The second aspect of the invention is the antireflection film according to the first aspect of the invention, wherein the convex side is an antireflection film consisting of five layers, and the concave side is an antireflection film consisting of five layers. The optical film thickness of the layer is 0.350λ ₀ ≦ The optical film thickness of the low refractive index layer ≦ 0.650λ ₀
The optical thickness of the first low refractive index layer on the concave side is 0.030λ ₀ ≦ the optical thickness of the low refractive index layer ≦ 0.300λ ₀
A plastic lens is provided.

The third invention is the antireflection film according to the first invention, wherein the convex side is an antireflection film consisting of five layers, and the concave side is an antireflection film consisting of seven layers. The optical film thickness of the layer is 0.350λ ₀ ≦ The optical film thickness of the low refractive index layer ≦ 0.650λ ₀
The optical thicknesses of the first and third low refractive index layers on the concave side are 0.030λ ₀ ≦ the optical thickness of the low refractive index layer ≦ 0.300λ ₀
A plastic lens is provided.

The fourth invention is the antireflection film according to the first invention, wherein the convex side is an antireflection film consisting of seven layers, and the concave side is an antireflection film consisting of five layers. The optical film thickness of the low refractive index layer of the eye is 0.350λ ₀ ≦ The optical film thickness of the low refractive index layer ≦ 0.650λ ₀
The optical thickness of the first low refractive index layer on the concave side is 0.030λ ₀ ≦ the optical thickness of the low refractive index layer ≦ 0.300λ ₀
A plastic lens is provided.

The fifth invention is the antireflection film according to the first invention, wherein the convex side is an antireflection film consisting of seven layers, and the concave side is an antireflection film consisting of seven layers. The optical film thickness of the low refractive index layer of the eye is 0.350λ ₀ ≦ The optical film thickness of the low refractive index layer ≦ 0.650λ ₀
The optical thicknesses of the first and third low refractive index layers on the concave side are 0.030λ ₀ ≦ the optical thickness of the low refractive index layer ≦ 0.300λ ₀
A plastic lens is provided.

  1st-5th invention provides the plastic lens spectacles which were excellent also in the hardness of the convex surface of a plastic lens which is easy to be damaged, adhesiveness, and also in impact resistance.

Since SiO ₂ which is a low refractive index layer is superior in hardness to high refractive index layers such as TiO ₂ , Nb ₂ O ₅ , Ta ₂ O ₅ , ZrO ₂ , LaTiO _3, etc., a film of a specific low refractive index layer By increasing the thickness, the scratch resistance can be improved. In order to obtain a good interference color, it is necessary to increase the thickness of the first or third low refractive index layer when the antireflection film is a five-layer film and when the antireflection film is seven layers. However, when the antireflection film has seven layers, if the first and third low refractive index layers are simultaneously thickened, a good interference color cannot be obtained. However, if the specific low refractive index layer is made thick, the antireflection film becomes inflexible and impact resistance is lowered. In addition, as the experiment progresses, the impact resistance is not affected by the convex antireflection film, but is greatly affected by the concave antireflection film, and if the film thickness of the low refractive index layer is too thick, the antireflection is It has also been found that the adhesion between the film and the hard coat is lowered, and conversely, the adhesion between the antireflection film and the hard coat is lowered even if the film thickness of the low refractive index layer is made too thin.

  According to the first to fifth inventions, when the convex-side antireflection film is 5 layers, the first low refractive index layer is used. When the antireflection film is 7 layers, the first layer or the third layer is used. Thickness of the low refractive index layer within a prescribed range ensures the hardness of the convex surface of the plastic lens, the adhesion of the film, and the good interference color, which are easily scratched. When the first low refractive index layer is 7 layers and the antireflection film is 7 layers, the low refractive index layer of the first layer or the third layer is thinned within a predetermined range, so that the film adhesion and good interference color are achieved. , And succeeded in ensuring impact resistance.

  The sixth invention provides a plastic spectacle lens excellent in impact resistance, water resistance, and adhesion between a coating film and a lens substrate. According to the sixth invention, the primer layer absorbs the impact by providing the primer layer between the lens substrate and the hard coat, and the impact resistance is improved. Water-based acrylic-urethane resins and polyester-based thermoplastic elastomers are excellent in weather resistance and water resistance, and also work as an adhesive between the hard coat and the lens base material, thereby improving the adhesion between the hard coat and the lens base material. improves.

  A seventh invention provides the plastic lens according to the first to sixth inventions, wherein the hard coat layer contains at least the following components (A) and (B) as main components.

  (A). Fine particles composed of one or more metal oxides selected from Al, Sn, Sb, Ta, Ce, La, Fe, Zn, W, Zr, In, and Ti having a particle diameter of 1 to 100 nm and / or Si, Al, Sn , Sb, Ta, Ce, La, Fe, Zn, W, Zr, In, Ti, composite fine particles composed of two or more kinds of metal oxides.

(B). General formula R ¹ R ² _n SiX _3-n (1)
(Wherein R ¹ is an organic group having a polymerizable reactive group, R ² is a hydrocarbon group having 1 to 6 carbon atoms, X is a hydrolyzable group, and n is 0 or 1) According to the seventh invention, the hard coat having the above composition is excellent in scratch resistance, water resistance, and light resistance, and the primer layer and the hard coat layer, and the hard coat layer and the antireflection film. Adhesion can be secured.

  An eighth invention provides a plastic lens characterized in that the hard coat described in the seventh invention contains the following component (C).

(C) Polyfunctional epoxy compound According to the eighth invention, the hard coat dyeability can be ensured by containing the component (C) in the hard coat.

  After forming a primer layer on a plastic lens substrate, a hard coat layer is formed on the primer layer and further laminated on the hard coat layer, a specific low refractive index layer on the convex surface side. By forming the optical film thickness and the optical film thickness of the specific low refractive index layer on the concave side with a value within a predetermined range, the hardness of the convex surface of the plastic lens that is easily damaged, the adhesion of the film, the interference color, Furthermore, it is possible to provide a plastic lens that is excellent in impact resistance.

  Hereinafter, although embodiment of this invention is described, this invention is not limited to the following embodiment.

  As described above, the plastic lens of the present invention has a structure in which a primer layer is formed on a plastic substrate, a hard coat layer is formed on the primer layer, and an antireflection film is further formed on the hard coat layer. .

  Although it does not restrict | limit especially as a plastics lens base material, Allyl carbonate resins, such as (meth) acrylic resin, styrene resin, polycarbonate resin, allyl resin, diethylene glycol bisallyl carbonate resin (CR-39), vinyl resin, polyester resin , Polyether resins, urethane resins obtained by reaction of isocyanate compounds with hydroxy compounds such as diethylene glycol, thiourethane resins obtained by reacting isocyanate compounds with polythiol compounds, and having one or more disulfide bonds in the molecule (thio ) A transparent resin obtained by curing a polymerizable composition containing an epoxy compound can be exemplified.

Further, when the thickness of the antireflection film is increased for the purpose of increasing the hardness of the plastic lens surface by the antireflection film, a low refractive index layer made of SiO ₂ and TiO ₂ , Nb ₂ O ₅ , Ta ₂ O ₅ , ZrO _{2 When} investigating which of the layers made of a high refractive index material such as LaTiO ₃ is more effective, it is more effective to increase the thickness of the low refractive index layer made of SiO _2. It was found to be effective in increasing the thickness.

Furthermore, when the convex surface side of the antireflection film is composed of 5 layers and the concave surface side is composed of 5 layers, the optical film thickness of the low refractive index layer of the first convex surface side is 0.350λ ₀ ≦ optical film thickness of the low refractive index layer ≤ 0.650λ ₀
The optical thickness of the first low refractive index layer on the concave side is 0.030λ ₀ ≦ the optical thickness of the low refractive index layer ≦ 0.300λ ₀

When the convex surface side of the antireflection film is composed of 5 layers and the concave surface side is composed of 7 layers, the optical film thickness of the low refractive index layer of the first convex surface side is 0.350λ ₀ ≦ Optical film thickness of the low refractive index layer ≦ 0 .650λ ₀
The optical thicknesses of the first and third low refractive index layers on the concave side are

0.030λ ₀ ≦ Optical film thickness of low refractive index layer ≦ 0.300λ ₀
When the convex surface side of the antireflection film is composed of 7 layers and the concave surface side is composed of 5 layers, the optical film thickness of the low refractive index layer of the first or third convex surface side is 0.350λ ₀ ≦ Optical of the low refractive index layer Film thickness ≦ 0.650λ ₀
The optical thickness of the first low refractive index layer on the concave side is 0.030λ ₀ ≦ the optical thickness of the low refractive index layer ≦ 0.300λ ₀

When the antireflective film is an antireflective film comprising seven layers on the convex side and seven layers on the concave side, the optical film thickness of the first refractive index layer or the third low refractive index layer is 0.350λ ₀ ≦ low Optical film thickness of refractive index layer ≦ 0.650λ ₀
The optical thicknesses of the first and third low refractive index layers on the concave side are 0.030λ ₀ ≦ the optical thickness of the low refractive index layer ≦ 0.300λ ₀
It was found that the hardness of the convex surface, the adhesion of the film, a good interference color can be secured and the impact resistance can be improved when the value is in the range of.

Moreover, if the antireflection film of the convex surface consists of five layers, the optical thickness of the first layer of the low refractive index layer, reduces the thinner scratch resistance than 0.350Ramuda _0, from 0.650Ramuda ₀ If it is too thick, the adhesion between the hard coat and the antireflection film will be reduced. Similarly, when the convex antireflection film is composed of seven layers, if the optical thickness of the low refractive index layer of the first layer or the third layer is thinner than 0.350λ ₀ , the scratch resistance decreases, When the thickness is larger than 0.650λ _0, the adhesion between the hard coat and the antireflection film is lowered.

When the concave antireflection film is composed of five layers, if the optical film thickness of the first low refractive index layer is thinner than 0.030λ ₀ , the adhesion between the hard coat and the antireflection film decreases, and 0 When the thickness is larger than 300λ _{0, the} impact resistance is lowered. Similarly, when the concave antireflection film is composed of seven layers, if the optical film thickness of the first and third low refractive index layers is smaller than 0.030λ ₀ , the hard coat and the antireflection film adhesion decreases, the impact resistance is lowered thicker than 0.300λ _0.

  In addition, the primer layer can improve the impact resistance of the plastic lens, is excellent in water resistance and light resistance, and is excellent in adhesion to the hard coat layer described later, or a water-based acrylic-urethane resin or polyester-based thermoplastic. Elastomers are preferred.

The hard coat layer contains at least the following components (A) and (B). The component (A) used in the present invention is composed of one or more metal oxides selected from Al, Sn, Sb, Ta, Ce, La, Fe, Zn, W, Zr, In, and Ti having a particle diameter of 1 to 100 nm. Specific examples of composite fine particles composed of fine particles and / or two or more metal oxides selected from Si, Al, Sn, Sb, Ta, Ce, La, Fe, Zn, W, Zr, In, and Ti _{the, SiO 2, Al 2 O 3} , SnO 2, Sb 2 O 5, Ta 2 O 5, CeO 2, La 2 O 3, Fe 2 O 3, ZnO, WO 3, ZrO 2, in 2 O 3, TiO ₂ inorganic oxide fine particles are colloidally dispersed in a dispersion medium such as water, alcohols or other organic solvents. Or the composite fine particle comprised by 2 or more types of these inorganic oxides disperse | distributed colloidally in water, alcohol type, or another organic solvent. In any case, the particle size is preferably about 1 to 100 nm, and the type and amount used for the coating composition of the present invention are determined by the intended film performance, but the amount used is 10 to 10% solids. 50% by weight is desirable. That is, if it is less than 10% by weight, the adhesion to the inorganic antireflection film becomes insufficient, or the scratch resistance of the coating film becomes insufficient. On the other hand, if it exceeds 50% by weight, cracks occur in the coating film.

(B) General formula R ¹ R ² _n SiX _3-n (1)
The organosilicon compound represented by the formula functions as a vehicle component. In the general formula, R ¹ is an organic group having a polymerizable reactive group. Examples of the polymerizable reactive group include a vinyl group, an allyl group, an acrylic group, a methacryl group, an epoxy group, a mercapto group, a cyano group, and an isocyano group. , Amino groups and the like. R ² is a hydrocarbon group having 1 to 6 carbon atoms, and specific examples thereof include a methyl group, an ethyl group, a butyl group, a vinyl group, and a phenyl group. X is a hydrolyzable functional group, and specific examples thereof include alkoxy groups such as methoxy group, ethoxy group, and methoxyethoxy group, halogen groups such as chloro group and bromo group, and acyloxy groups. .

  Examples of the organosilicon compound of component (B) include vinyltrialkoxysilane, vinyltrichlorosilane, vinyltri (β-methoxy-ethoxy) silane, allyltrialkoxysilane, acryloxypropyltrialkoxysilane, and methacryloxypropyltrialkoxysilane. , Methacryloxypropyl dialkoxymethylsilane, γ-glycidoxypropyltrialkoxysilane, β- (3,4-epoxycyclohexyl) -ethyltrialkoxysilane, mercaptopropyltrialkoxysilane, γ-aminopropyltrialkoxysilane, N -Β (aminoethyl) -γ-aminopropylmethyl dialkoxysilane and the like. The component (B) may be used as a mixture of two or more. It is more effective to use after hydrolysis.

The amount of component (B) used is desirably in the range of 10 to 70% by weight, particularly 20 to 60% by weight of the solid content in the hard coat composition. If the amount is too small, the adhesion to the antireflection film may be insufficient. On the other hand, if the amount is too large, it may cause cracks in the cured coating.
Moreover, in order to improve the dyeability of a film, it is also possible to contain (C) component. The polyfunctional epoxy compound (C) functions as a dyeing component of the hard coat layer. A polyfunctional epoxy compound is excellent in adhesiveness specifically with respect to the water-based acrylic-urethane resin and polyester-type thermoplastic elastomer of the primer layer mentioned above. Furthermore, due to the presence of the primer layer, the dyeability is much higher than when a dyeable hard coat layer is formed as a single layer on a plastic lens substrate. Therefore, when a primer layer is provided, it is possible to reduce the blending amount of the polyfunctional epoxy compound in the dyeable hard coat, and after ensuring sufficient dyeability, it is more hard, that is, scratch resistant. A plastic lens with improved properties can be obtained. In addition, the polyfunctional epoxy compound can improve the water resistance and warm water resistance of the hard coat layer, and effectively suppress the generation of cracks even if it is immersed in a high temperature dyeing solution for a long time during dyeing. can do.

  Polyfunctional epoxy compounds are widely used for adhesives, casting, and the like, and can be obtained from, for example, polyolefin epoxy resins synthesized by a peroxidation method, cyclopentadiene oxide, cyclohexene oxide, hexahydrophthalic acid and epichlorohydrin. Alicyclic epoxy resins such as polyglycidyl esters, polyhydric phenols such as bisphenol A, catechol, and resorcinol, or (poly) ethylene glycol, (poly) propylene glycol, neopentyl glycol, glycerin, trimethylolpropane, pentaerythritol, diglycerol , Polyglycidyl ether obtained from polyhydric alcohols such as sorbitol and epichlorohydrin, epoxidized vegetable oil, obtained from novolac phenolic resin and epichlorohydrin Epoxy novolac, epoxy resin obtained from phenolphthalein and epichlorohydrin, glycidyl methacrylate and methyl methacrylate acrylic monomer or copolymer such as styrene, and glycidyl group of the above epoxy compound and monocarboxylic acid-containing (meth) acrylic acid Examples thereof include epoxy acrylate obtained by a ring-opening reaction.

  Specific examples of the polyfunctional epoxy compound include 1,6-hexanediol diglycidyl ether, ethylene glycol diglycidyl ether, diethylene glycol diglycidyl ether, triethylene glycol diglycidyl ether, tetraethylene glycol diglycidyl ether, and nonaethylene glycol diester. Glycidyl ether, propylene glycol diglycidyl ether, dipropylene glycol diglycidyl ether, tripropylene glycol diglycidyl ether, tetrapropylene glycol diglycidyl ether, nonapropylene glycol diglycidyl ether, neopentyl glycol diglycidyl ether, neopentyl glycol hydroxyhyvalic acid Diglycidyl ether of ester, trimethylolpropa Diglycidyl ether, trimethylolpropane triglycidyl ether, glycerol diglycidyl ether, glycerol triglycidyl ether, diglycerol diglycidyl ether, diglycerol triglycidyl ether, diglycerol tetraglycidyl ether, pentaerythritol diglycidyl ether, pentaerythritol triglycidyl ether Aliphatic such as pentaerythritol tetraglycidyl ether, dipentaerythritol tetraglycidyl ether, sorbitol tetraglycidyl ether, diglycidyl ether of tris (2-hydroxyethyl) isocyanurate, triglycidyl ether of tris (2-hydroxyethyl) isocyanurate Epoxy compound, isophoronediol diglycid Ether, alicyclic epoxy compounds such as bis-2,2-hydroxycyclohexylpropane diglycidyl ether, resorcin diglycidyl ether, bisphenol A diglycidyl ether, bisphenol F diglycidyl ether, bisphenol S diglycidyl ether, orthophthalic acid diglycidyl ester And aromatic epoxy compounds such as phenol novolac polyglycidyl ether and cresol novolac polyglycidyl ether.

  The hard coat composition thus obtained can be diluted with a solvent and used as necessary. As the solvent, solvents such as alcohols, esters, ketones, ethers and aromatics are used.

  In addition to the above components, the hard coat composition of the present invention may contain a small amount of surfactant, antistatic agent, ultraviolet absorber, antioxidant, disperse dye / oil-soluble dye / fluorescent dye / pigment, Addition of a photochromic compound, a light and heat resistant stabilizer such as a hindered amine / hindered phenol, and the like can also improve the coatability of the hard coat solution and the coating performance after curing. In particular, by adding one or more light-resistant heat-resistant stabilizers such as ultraviolet absorbers, antioxidants, hindered amines, and hindered phenols, it is possible to impart excellent weather resistance to the hard coat film. It is.

  The hard coat composition is applied and cured by applying the hard coat composition to a plastic lens substrate on which a primer layer has been formed by dipping, spinner, spray or flow, and then at a temperature of 40 to 200 ° C. A film can be formed by heating and drying for several hours.

The film thickness of the hard coat layer is preferably in the range of 0.05 to 30 μm, particularly about 0.1 to 20 μm. If it is too thin, basic performance may not be exhibited, while if it is too thick, optical distortion may occur. Hereinafter, the present invention will be described in more detail with reference to examples.
(Example 1)
(1-1) Formation of primer layer After mixing 626.2 g of methanol and 221.8 g of a commercially available aqueous emulsion polyurethane (manufactured by Nikka Chemical Co., Ltd., trade name “Neo Sticker 700”, solid content concentration 37%), 309.6 g of methanol-dispersed titanium dioxide antimony pentoxide-silicon dioxide composite fine particle sol (manufactured by Catalyst Kasei Kogyo Co., Ltd., solid content concentration 20 wt%), silicon surfactant (manufactured by Nippon Unicar Co., Ltd., trade name “L- 7604 ") 0.25 g was mixed and stirred well to obtain a primer solution.

  This primer composition was applied on a plastic lens substrate for Seiko Super Sovereign (trade name) (manufactured by Seiko Epson Corporation, refractive index 1.67) by a dipping method (pickup speed 15 cm / min). The applied substrate lens was heat-cured at 100 ° C. for 20 minutes to form a primer layer having a film thickness of 1.0 μm and a refractive index of 1.67 on the substrate.

(1-2) Formation of Hard Coat Layer 78 g of methanol, 100.3 g of butyl cellosolve, methanol-dispersed titanium dioxide antimony pentoxide-silicon dioxide composite fine particle sol (manufactured by Catalyst Chemical Industry Co., Ltd., solid content concentration 20% by weight) 1380. 99.9 g of methanol-dispersed colloidal silica (trade name “Oscar 1132”, solid content concentration 30 wt%) manufactured by Catalyst Kasei Kogyo Co., Ltd., 61.42 g was mixed, and then 289.9 g of γ-glycidoxypropyltrimethoxysilane. Were mixed. To this mixture, 80.1 g of 0.05N hydrochloric acid aqueous solution was added dropwise with stirring, and the mixture was further stirred for 4 hours and then aged overnight. In this liquid, 4.4 g of magnesium perchlorate, 0.6 g of silicon surfactant (manufactured by Nihon Unicar Co., Ltd., trade name “L-7001”) and hindered amine light stabilizer (manufactured by Sankyo Co., Ltd., trade name) “Sanol LS-770”) 2.3 g was added, stirred for 4 hours, and then aged overnight to prepare a coating solution.

  This hard coat composition was applied on the primer layer obtained by (1-1) formation of the primer layer by a dipping method (pickup speed 25 cm / min). The coated base lens was heat-cured at 80 ° C. for 30 minutes and then heat-cured at 120 ° C. for 180 minutes. Thus, a hard coat layer having a thickness of 2.2 μm and a refractive index of 1.67 was formed on the primer layer.

(1-3) Formation of Convex Antireflection Film The SiO ₂ layer was formed by a vacuum vapor deposition method (vacuum degree: 1.0 × 10 ⁻⁴ Pa). The Ta ₂ O ₅ layer was formed by an oxygen ion assisted vapor deposition method (vacuum degree: 6.0 × 10 ⁻³ Pa). The ion assist conditions for forming the Ta ₂ O ₅ layer by oxygen ion assist vapor deposition are acceleration voltage of 550 V, acceleration current value of 290 mA, and the degree of vacuum is maintained at 6.0 × 10 ⁻³ Pa by introducing oxygen. did. Counted from the substrate side, SiO ₂ layer (refractive index 1.46) the first layer having an optical thickness of 0.450λ _0, the second layer Ta ₂ O ₅ having an optical film thickness of 0.122λ ₀ Layer (refractive index 2.20), the third layer is an SiO ₂ layer having an optical thickness of 0.049λ ₀ , the fourth layer is a Ta ₂ O ₅ layer having an optical thickness of 0.305λ ₀ , and a fifth layer Was formed on the convex surface of the lens obtained by (1-2) forming the hard coat layer by sequentially laminating SiO ₂ layers having an optical film thickness of 0.263λ ₀ .

(1-4) Formation of concave antireflection film The SiO ₂ layer was formed by a vacuum deposition method (vacuum degree: 2.0 × 10 ⁻⁴ Pa). The TiO ₂ layer was formed by oxygen ion assisted vapor deposition (vacuum degree: 4.0 × 10 ⁻³ Pa). The ion assist conditions for forming the TiO ₂ layer by oxygen ion assist vapor deposition were an acceleration voltage of 520 V, an acceleration current value of 270 mA, and a vacuum degree of oxygen was introduced to maintain 4.0 × 10 ⁻³ Pa. Counted from the substrate side, SiO ₂ layer the first layer having an optical thickness of 0.080λ ₀ (refractive index 1.46), TiO ₂ layer and the second layer having an optical thickness of 0.071λ ₀ ( (Refractive index 2.40), the third layer is an SiO ₂ layer having an optical thickness of 0.094λ ₀ , the fourth layer is a TiO ₂ layer having an optical thickness of 0.235λ ₀ , and the fifth layer is 0.040λ SiO ₂ layer having an optical thickness of _0, the sixth layer TiO ₂ layer having an optical thickness of 0.165Ramuda _0, the seventh layer sequentially laminated SiO ₂ layer having an optical thickness of 0.248Ramuda ₀ An antireflection film was formed on the concave surface of the lens obtained by (1-2) formation of the hard coat layer to obtain a plastic lens.
(Example 2)
(2-1) Formation of primer layer and hard coat layer Primer on a plastic lens base material for Seiko Super Sovereign (trade name) (Seiko Epson Corporation, refractive index 1.67) in the same manner as in Example 1. A layer and a hard coat layer were formed.

(2-2) Formation of convex antireflection film The SiO ₂ layer was formed by a vacuum deposition method (vacuum degree: 2.0 × 10 ⁻⁴ Pa). The LaTiO ₃ layer was formed by an oxygen ion assisted vapor deposition method (vacuum degree: 4.0 × 10 ⁻³ Pa). The ion assist conditions for forming the LaTiO ₃ layer by oxygen ion assist deposition were an acceleration voltage of 520 V, an acceleration current value of 270 mA, and oxygen was introduced to maintain 4.0 × 10 ⁻³ Pa. Counted from the substrate side, SiO ₂ layer the first layer having an optical thickness of 0.400λ ₀ (refractive index 1.46), LaTiO ₃ layer a second layer having an optical thickness of 0.115λ ₀ ( (Refractive index 2.14), the third layer is a SiO ₂ layer having an optical thickness of 0.049λ ₀ , the fourth layer is a LaTiO ₃ layer having an optical thickness of 0.288λ ₀ , and the fifth layer is 0.250λ. _An antireflection film formed by sequentially laminating a SiO ₂ layer having an optical thickness of ₀ was formed on the convex surface of the lens obtained by (2-1) formation of the primer layer and the hard coat layer.

(2-3) Formation of concave antireflection film The SiO ₂ layer was formed by a vacuum vapor deposition method (vacuum degree: 4.0 × 10 ⁻⁴ Pa). The TiO ₂ layer was formed by oxygen ion assisted vapor deposition (vacuum degree: 5.0 × 10 ⁻³ Pa). The ion assist conditions for forming the TiO ₂ layer by oxygen ion assisted deposition were an acceleration voltage of 500 V, an acceleration current value of 250 mA, and a vacuum degree of 5.0 × 10 ⁻³ Pa by introducing oxygen. Counted from the substrate side, SiO ₂ layer the first layer having an optical thickness of 0.033λ ₀ (refractive index 1.46), TiO ₂ layer and the second layer having an optical thickness of 0.080λ ₀ ( (Refractive index 2.40), the third layer is an SiO ₂ layer having an optical thickness of 0.098λ ₀ , the fourth layer is a TiO ₂ layer having an optical thickness of 0.538λ ₀ , and the fifth layer is 0.265λ. _An antireflection film formed by sequentially laminating an SiO ₂ layer having an optical thickness of ₀ was formed on the concave surface of the lens obtained by (2-1) formation of the primer layer and the hard coat layer to obtain a plastic lens.
(Example 3)
(3-1) Formation of Primer Layer Commercially available aqueous polyester “A-160P” (manufactured by Takamatsu Yushi Co., Ltd., solid content concentration 25%) 572.0 g, methanol 854.1.6 g, water 54.5 g, methanol-dispersed dioxide Titanium-zirconium dioxide-silicon dioxide composite fine particle sol (trade name “OPTRAICK 1120Z (S-7 / A8), solid content concentration 20% by weight” manufactured by Catalyst Kasei Kogyo Co., Ltd.) 715.1 is mixed and silicon-based 0.44 g of a surfactant (trade name “L-7604” manufactured by Nippon Unicar Co., Ltd.) was added and stirred for 3 hours. This primer composition was applied on a plastic lens substrate for Seiko Prestige (trade name) (Seiko Epson Corporation, refractive index 1.74) by a dipping method (pickup speed 15 cm / min). The coated substrate lens was heat-cured at 60 ° C. for 20 minutes to form a primer layer having a thickness of 0.9 μm and a refractive index of 1.67 on the substrate.

(3-2) Formation of hard coat layer 601.9 g of butyl cellosolve and 399.7 g of methanol-dispersed titanium dioxide-zirconium dioxide-silicon dioxide composite fine particle sol (manufactured by Catalyst Chemical Industry Co., Ltd., solid content concentration 30 wt%) Thereafter, 127.9 g of γ-glycidoxypropyltrimethoxysilane was mixed. To this mixed solution, 40 g of 0.05N hydrochloric acid aqueous solution was added dropwise with stirring, and the mixture was further stirred for 4 hours and then aged overnight. To this solution, 29.5 g of glycerol diglycidyl ether (manufactured by Nagase ChemteX Corp., trade name “Denacol EX-313”) was added, and then 2.9 g of iron (III) acetylacetonate, silicon surfactant (Japan) 0.2 g of Unicar Co., Ltd., trade name “L-7001”) was added, and the mixture was stirred for 4 hours and then aged overnight to prepare a coating solution.

  This hard coat composition was applied on the primer layer obtained by (3-1) formation of the primer layer by a dipping method (pulling speed of 35 cm / min). The coated substrate lens was heat-cured at 90 ° C. for 20 minutes and then heat-cured at 125 ° C. for 120 minutes. Thus, a hard coat layer having a thickness of 1.9 μm and a refractive index of 1.67 was formed on the primer layer.

(3-3) Formation of Convex Antireflection Film The SiO ₂ layer was formed by a vacuum deposition method (vacuum degree: 1.0 × 10 ⁻⁴ Pa). The Ta ₂ O ₅ layer was formed by an oxygen ion assisted vapor deposition method (vacuum degree: 6.0 × 10 ⁻³ Pa). The ion assist conditions for forming the Ta ₂ O ₅ layer by oxygen ion assist vapor deposition are acceleration voltage of 550 V, acceleration current value of 290 mA, and the degree of vacuum is maintained at 6.0 × 10 ⁻³ Pa by introducing oxygen. did. Counted from the substrate side, SiO ₂ layer (refractive index 1.46) the first layer having an optical thickness of 0.084λ _0, the second layer Ta ₂ O ₅ having an optical film thickness of 0.026λ ₀ Layer (refractive index 2.20), third layer is SiO ₂ layer having an optical thickness of 0.491λ ₀ , fourth layer is Ta ₂ O ₅ layer having an optical thickness of 0.133λ ₀ , fifth layer Is a SiO ₂ layer having an optical thickness of 0.082λ _0, a sixth layer is a Ta ₂ O ₅ layer having an optical thickness of 0.194λ ₀ , and a seventh layer is a SiO ₂ layer having an optical thickness of 0.298λ _{0. An} antireflection film formed by sequentially laminating _two layers was formed on the convex surface of the lens obtained by (3-2) formation of the hard coat layer.

(3-4) Formation of concave antireflection film The SiO ₂ layer was formed by a vacuum vapor deposition method (vacuum degree: 2.0 × 10 ⁻⁴ Pa). The Nb ₂ O ₅ layer was formed by an oxygen ion assisted vapor deposition method (vacuum degree: 4.0 × 10 ⁻³ Pa). The ion assist conditions for forming the Nb ₂ O ₅ layer by oxygen ion assisted deposition are an acceleration voltage of 520 V, an acceleration current value of 270 mA, and a vacuum degree of 4.0 × 10 ⁻³ Pa by introducing oxygen. did. Counted from the substrate side, SiO ₂ layer (refractive index 1.46) the first layer having an optical thickness of 0.031λ _0, the second layer Nb ₂ O ₅ having an optical film thickness of 0.065λ ₀ Layer (refractive index 2.30), the third layer is an SiO ₂ layer having an optical thickness of 0.097λ ₀ , the fourth layer is an Nb ₂ O ₅ layer having an optical thickness of 0.521λ ₀ , and a fifth layer Is formed on the concave surface of the lens obtained by (3-2) formation of the hard coat layer to form a plastic lens by sequentially laminating SiO ₂ layers having an optical film thickness of 0.260λ ₀ . .
Example 4
(4-1) Formation of primer layer and hard coat layer Primer layer on Seiko Prestige (trade name) plastic lens substrate (Seiko Epson Corporation, refractive index 1.74) in the same manner as in Example-3. And a hard coat layer was formed.

(4-2) Formation of Convex Antireflection Film The SiO ₂ layer was formed by a vacuum vapor deposition method (vacuum degree: 2.0 × 10 ⁻⁴ Pa). The TiO ₂ layer was formed by ion-assisted deposition (vacuum degree: 4.0 × 10 ⁻³ Pa). The ion assist conditions for forming the TiO ₂ layer by ion-assisted deposition were an acceleration voltage of 520 V and an acceleration current value of 270 mA, and the degree of vacuum was maintained at 4.0 × 10 ⁻³ Pa by introducing oxygen. Counted from the substrate side, SiO ₂ layer the first layer having an optical thickness of 0.075λ ₀ (refractive index 1.46), TiO ₂ layer and the second layer having an optical thickness of 0.030λ ₀ ( (Refractive index 2.40), the third layer is an SiO ₂ layer having an optical thickness of 0.563λ ₀ , the fourth layer is a TiO ₂ layer having an optical thickness of 0.135λ ₀ , and the fifth layer is 0.080λ SiO ₂ layer having an optical thickness of _0, the sixth layer TiO ₂ layer having an optical thickness of 0.170Ramuda _0, the seventh layer sequentially laminated SiO ₂ layer having an optical thickness of 0.283Ramuda ₀ The antireflection film thus formed was formed on the convex surface of the lens obtained by the formation of (4-1) primer layer and hard coat layer.

(4-3) Formation of concave antireflection film The SiO ₂ layer was formed by a vacuum deposition method (vacuum degree: 2.0 × 10 ⁻⁴ Pa). The ZrO ₂ layer was formed at a vacuum degree of 4.0 × 10 ⁻³ Pa. SiO ₂ layer the first layer having an optical thickness of 0.088λ ₀ (refractive index 1.46), ZrO ₂ layer and the second layer having an optical thickness of 0.159λ ₀ (refractive index 2.05), The third layer has a SiO ₂ layer with an optical thickness of 0.050λ ₀ , the fourth layer has a ZrO ₂ layer with an optical thickness of 0.270λ ₀ , and the fifth layer has an optical thickness of 0.265λ _0. An antireflection film formed by sequentially laminating SiO ₂ layers was formed on the concave surface of the lens obtained by the formation of the (4-1) primer layer and the hard coat layer to obtain a plastic lens.
(Example 5)
(5-1) Formation of primer layer 125.0 g of commercially available aqueous polyester “A-163G” (manufactured by Takamatsu Yushi Co., Ltd., solid concentration 28%), 354.7 g of butyl cellosolve, 43.9 g of water, methanol-dispersed titanium dioxide 175.0 g of zirconium dioxide-silicon dioxide composite fine particle sol (manufactured by Catalyst Kasei Kogyo Co., Ltd., trade name “OPTRAIK 1120Z (S-7 / A8), solid content concentration 20% by weight”)) was mixed to obtain a silicon-based surface activity. 0.14 g of an agent (made by Nippon Unicar Co., Ltd., trade name “L-7604”) was added and stirred for 3 hours. This primer composition was applied by a dipping method (pickup speed 20 cm / min) onto a plastic lens substrate for Seiko Super Lucius (trade name) (manufactured by Seiko Epson Corporation, refractive index 1.60). The coated substrate lens was heat-cured at 80 ° C. for 20 minutes to form a primer layer having a film thickness of 1.1 μm and a refractive index of 1.60 on the substrate.

(5-2) Formation of Hard Coat Layer After mixing 295.4 g of isopropyl cellosolve and 364.3 g of methanol-dispersed tin dioxide-tungsten dioxide composite fine particle sol (manufactured by Nissan Chemical Industries, Ltd., solid content concentration 30 wt%), γ -16.1 g of methacryloxypropyltrimethoxysilane, 7.2 g of tetramethoxysilane, and 67.2 g of γ-glycidoxypropyltrimethoxysilane were mixed. To this mixed solution, 35.1 g of 0.1N hydrochloric acid aqueous solution was added dropwise with stirring. The mixture was further stirred for 5 hours and then aged overnight. In this liquid, 14.5 g of 1,6-hexanediol diglycidyl ether (manufactured by Nagase ChemteX Corporation, trade name “Denacol EX-212”) and 1.5 g of Fe (III) acetylacetonate, a silicon surfactant ( 0.3 g of Nippon Unicar Co., Ltd., trade name “L-7604”) was added, and the mixture was stirred for 4 hours and then aged overnight to prepare a coating solution.

  This hard coat composition was applied by spraying onto the primer layer obtained in (5-1) Formation of the primer layer.

  Spraying was performed using an Iwata Weider 61 (Iwata Coating Machine Co., Ltd .; nozzle diameter 1 mm) at a spray pressure of 3 Kg / square cm and a paint discharge rate of 100 ml / min.

  After the coating, it was air-dried at 80 ° C. for 20 minutes and then baked at 130 ° C. for 2 hours. In this way, a hard coat layer having a thickness of about 2.5 μm and a refractive index of 1.60 was formed on the primer layer.

(5-3) Formation of Convex Antireflection Film The SiO ₂ layer was formed by a vacuum deposition method (vacuum degree 2.0 × 10 ⁻⁴ Pa). The Nb ₂ O ₅ layer was formed by an oxygen ion assisted vapor deposition method (vacuum degree: 4.0 × 10 ⁻³ Pa). The ion assist conditions for forming the Nb ₂ O ₅ layer by oxygen ion assisted deposition are an acceleration voltage of 520 V, an acceleration current value of 270 mA, and a vacuum degree of 4.0 × 10 ⁻³ Pa by introducing oxygen. did. Counted from the substrate side, SiO ₂ layer (refractive index 1.46) the first layer having an optical thickness of 0.475λ _0, the second layer Nb ₂ O ₅ having an optical film thickness of 0.018λ ₀ Layer (refractive index 2.30), the third layer is an SiO ₂ layer having an optical thickness of 0.038λ ₀ , the fourth layer is an Nb ₂ O ₅ layer having an optical thickness of 0.112λ ₀ , and a fifth layer Is an SiO ₂ layer having an optical thickness of 0.090λ ₀ , the sixth layer is an Nb ₂ O ₅ layer having an optical thickness of 0.143λ ₀ , and the seventh layer is an SiO ₂ layer having an optical thickness of 0.283λ _{0. An} antireflection film formed by sequentially laminating _two layers was formed on the convex surface of the lens obtained by (5-2) formation of the hard coat layer.

(5-4) Formation of concave antireflection film The SiO ₂ layer was formed by a vacuum deposition method (vacuum degree: 3.0 × 10 ⁻⁴ Pa). The Ta ₂ O ₅ layer was formed by an oxygen ion assisted vapor deposition method (vacuum degree: 6.0 × 10 ⁻³ Pa). The ion assist conditions for forming the Ta ₂ O ₅ layer by oxygen ion assist vapor deposition are an acceleration voltage of 460 V, an acceleration current value of 220 mA, and the degree of vacuum is maintained at 6.0 × 10 ⁻³ Pa by introducing oxygen. did. Counted from the substrate side, SiO ₂ layer (refractive index 1.46) the first layer having an optical thickness of 0.102λ _0, the second layer Ta ₂ O ₅ having an optical film thickness of 0.057λ ₀ Layer (refractive index 2.20), third layer is SiO ₂ layer having an optical thickness of 0.072λ ₀ , fourth layer is Ta ₂ O ₅ layer having an optical thickness of 0.201λ ₀ , fifth layer SiO ₂ layer having an optical thickness of 0.025Ramuda ₀ is, Ta ₂ O ₅ layer is the sixth layer having an optical thickness of 0.204λ _0, SiO seventh layer having an optical film thickness of 0.250λ _{0 An} antireflection film formed by sequentially laminating _two layers was formed on the concave surface of the lens obtained by forming the (5-2) hard coat layer to obtain a plastic lens.
(Example 6)
(6-1) Formation of primer layer and hard coat layer Primer on plastic lens base material (Seiko Epson Corporation, refractive index 1.60) for Seiko Super Lucious (trade name) by the same method as Example-5 A layer and a hard coat layer were formed.

(6-2) Formation of Convex Antireflection Film The SiO ₂ layer was formed by a vacuum vapor deposition method (vacuum degree: 4.0 × 10 ⁻⁴ Pa). The ZrO ₂ layer was formed at a vacuum degree of 4.0 × 10 ⁻³ Pa. SiO ₂ layer the first layer having an optical thickness of 0.425λ ₀ (refractive index 1.46), ZrO ₂ layer and the second layer having an optical thickness of 0.125λ ₀ (refractive index 2.05), The third layer is an SiO ₂ layer having an optical thickness of 0.060λ ₀ , the fourth layer is a ZrO ₂ layer having an optical thickness of 0.238λ ₀ , and the fifth layer has an optical thickness of 0.268λ _0. An antireflection film formed by sequentially laminating SiO ₂ layers was formed on the convex surface of the lens obtained by (6-1) formation of the primer layer and the hard coat layer.

(6-3) Formation of concave antireflection film The SiO ₂ layer was formed by a vacuum deposition method (vacuum degree: 4.0 × 10 ⁻⁴ Pa). The LaTiO ₃ layer was formed by an oxygen ion assisted vapor deposition method (vacuum degree: 4.5 × 10 ⁻³ Pa). The ion assist conditions for forming the LaTiO ₃ layer by oxygen ion assist vapor deposition were an acceleration voltage of 530 V, an acceleration current value of 220 mA, and the degree of vacuum was maintained at 4.5 × 10 ⁻³ Pa by introducing oxygen. Counted from the substrate side, SiO ₂ layer the first layer having an optical thickness of 0.090λ ₀ (refractive index 1.46), LaTiO ₃ layer a second layer having an optical thickness of 0.075λ ₀ ( (Refractive index 2.14), the third layer is a SiO ₂ layer having an optical thickness of 0.060λ ₀ , the fourth layer is a LaTiO ₃ layer having an optical thickness of 0.480λ ₀ , and the fifth layer is 0.250λ. _An antireflection film formed by sequentially laminating a SiO ₂ layer having an optical thickness of ₀ was formed on the concave surface of the lens obtained by (6-1) formation of the primer layer and the hard coat layer to obtain a plastic lens.

(Comparative Example 1)
To obtain a plastic lens at all except that the 0.025Ramuda ₀ the optical thickness of the convex surface the first layer of the SiO ₂ layer in Example 1 a similar manner.

(Comparative Example 2)
To obtain a plastic lens at all except that the 0.800Ramuda ₀ the optical thickness of the convex surface the first layer of the SiO ₂ layer in Example 2 the same method.

(Comparative Example 3)
To obtain a plastic lens at all, except that the optical film thickness of the convex third layer of the SiO ₂ layer and 0.300Ramuda ₀ In Example 3 the same method.

(Comparative Example 4)
To obtain a plastic lens at all, except that the optical film thickness of the convex surface the first layer of the SiO ₂ layer and 0.700Ramuda ₀ In Example 5 the same method.

(Comparative Example 5)
To obtain a plastic lens at all, except that the optical film thickness of the concave first layer of the SiO ₂ layer and 0.020Ramuda ₀ In Example 4 the same method.

(Comparative Example 6)
To obtain a plastic lens in all the same manner except that the 0.025Ramuda ₀ the optical thickness of the concave third layer of the SiO ₂ layer in Example 1.

(Comparative Example 7)
To obtain a plastic lens at all, except that the optical film thickness of the concave third layer of the SiO ₂ layer and 0.750Ramuda ₀ In Example 5 the same method.

(Comparative Example 8)
To obtain a plastic lens at all except that the 0.330Ramuda ₀ the optical thickness of the concave first layer of the SiO ₂ layer in Example 6 the same method.

  The following evaluation methods were performed on the plastic lenses obtained in these examples and comparative examples.

  (A) Impact resistance: A 16.3 g hard ball is naturally dropped from a height of 127 cm to the center of the convex surface of the lens and the lens is cracked or cracked. The weight of 2.7 was 2.7 times and dropped from a height of 127 cm. The center thickness of the lens used in this test was 1.1 mm.

(B) Scratch resistance: A load of 1 kg was applied to the convex surface of the lens with Bonstar # 0000 steel wool (manufactured by Nippon Steel Wool Co., Ltd.), the 10 reciprocating surfaces were rubbed, and the degree of damage was visually observed.
A: No scratches in the range of 1 cm * 3 cm B: 1-10 scratches in the above range C: 10-100 scratches in the above range D: Innumerable scratches 、 Smooth surface remains E ： Smooth surface does not remain due to scratches on the surface

  (C) Weather resistance: A sample having no change in the surface condition after being exposed to a sunshine weather meter with a xenon lamp for 250 hours was evaluated as ◯.

  (D) Moisture resistance: A sample having no change in surface condition after being left in an atmosphere of 60 ° C. × 99% for 10 days was marked with “◯”.

  (E) Adhesion of surface treatment layer: Adhesion between the lens base material and the surface treatment layer (hard coat layer and antireflection film) is the same as in JIS D-0202 for the tests (c) and (d). The cross cut tape test was conducted accordingly. That is, using a knife, cuts are made on the substrate surface at intervals of 1 mm to form 100 squares of 1 mm square. Next, heserophan adhesive tape (manufactured by Nichiban Co., Ltd .: trade name “Cellotape” (registered trademark)) was strongly pressed, and then suddenly pulled away from the surface in the direction of 90 degrees, and then the coating layer remained. The squares were visually observed as an adhesion index. The ranking of evaluation was made into 4 grades of AD.

A: A state in which 100 to 99 grids remain (good)
B: 98-95 remaining in a grid pattern (relatively good)
C: State with 94 to 65 grids remaining (slightly poor)
D: A state where 64-0 grids remain (defect)

(F) Dyeability (confirmed with lens after hard coat application and firing): 2 g of Seiko Plax diamond coat stain Amber D was dispersed in 1 liter of 92 ° C. pure water to prepare a dye solution. The lens before vapor deposition was immersed in this dyeing solution for 5 minutes for dyeing. The difference in total light transmittance between before dyeing and after dyeing was 40% or more was A, and 40% or less was B.
The results are shown in Table 1.

比較例１は実施例１の凸面側反射防止膜の第１層目低屈折率層の光学的膜厚を０．３５０λ₀よりも薄くした水準であり、比較例３は実施例３の凸面側反射防止膜の第３層目低屈折率層の光学的膜厚を０．３５０λ₀よりも薄くした水準である。比較例１および３ともに実施例１から６に比べ耐擦傷性が低下している。従って、凸面側反射防止膜が５層膜のとき第１層目低屈折率層が、凸面側反射防止膜が７層のときは第１層目もしくは第３層目の低屈折率層の光学的膜厚が０．３５０λ₀以上でないと優れた耐擦傷性が得られない。

Comparative Example 1 is a level in which the optical thickness of the first low refractive index layer of the convex side antireflection film of Example 1 is made thinner than 0.350λ ₀ , and Comparative Example 3 is the convex side of Example 3 The optical film thickness of the third low-refractive index layer of the antireflection film is at a level made thinner than 0.350λ ₀ . In both Comparative Examples 1 and 3, the scratch resistance is lower than in Examples 1 to 6. Accordingly, when the convex-side antireflection film is a five-layer film, the first low-refractive index layer is used. When the convex-side antireflection film is seven layers, the first or third low-refractive index layer is optical. Excellent scratch resistance cannot be obtained unless the target film thickness is 0.350λ ₀ or more.

Comparative Example 2 is a level in which the optical thickness of the first low refractive index layer of the convex-side antireflection film of Example 2 is greater than 0.650λ ₀ , and Comparative Example 4 is the convex surface of Example 5. The optical film thickness of the first layer of the side antireflection film is at a level greater than 0.650λ ₀ , and Comparative Example 7 is the third layer low refractive index film of the concave side antireflection film of Example 5. the optical film thickness is at a level that was thicker than 0.650λ _0. Comparative Example 1 is a level in which the first low refractive index layer of the convex side antireflection film of Example 1 is made thinner than 0.030λ ₀ , and Comparative Example 5 is the concave side antireflection film of Example 4. The optical film thickness of the first low refractive index layer of the first layer was made thinner than 0.030λ ₀ , and Comparative Example 6 is an optical film of the third low refractive index layer on the concave surface side of Example 1. the thickness is at a level that was thinner than 0.030λ _0. The degree of adhesion on the convex surface side of Comparative Example 1, Comparative Example 2, and Comparative Example 4 is less than the degree of adhesion on the convex surface side of Examples 1 to 6, and the adhesion on the concave surface side of Comparative Example 5, Comparative Example 6, and Comparative Example 7 The degree of the property is not as good as the adhesion on the concave side of Examples 1 to 6. Therefore, when the antireflection film is a five-layer film, the optical thickness of the first low refractive index layer is 1, and when the antireflection film is 7, the optical thickness of the first or third low refractive index layer is Excellent adhesion cannot be obtained unless it is thicker than 0.030λ ₀ and thinner than 0.650λ ₀ .

Comparative Example 7 is a level in which the optical thickness of the third low refractive index layer of the concave-side antireflection film of Example 5 is greater than 0.300λ ₀ , and Comparative Example 8 is the convex side of Example 6 the optical thickness of the first layer low refractive index layer of the antireflection film is a level which is thicker than 0.300λ _0. Both the comparative examples 7 and 8 have lower impact resistance than the examples 1 to 6. Accordingly, when the concave-side antireflection film is a five-layer film, the first low-refractive index layer is used. When the concave-side antireflection film is seven layers, the first or third low-refractive index optical layer is used. Excellent impact resistance cannot be obtained unless the target film thickness is 0.300λ ₀ or less.

  Since Example 1, Example 2, Comparative Example 1, Comparative Example 2, and Comparative Example 6 do not use a polyfunctional epoxy compound in the composition of the hard coat, dyeability is not obtained.

  It has become possible to provide a plastic spectacle lens with an antireflection film that is excellent in the hardness, adhesion and impact resistance of the convex surface of the plastic lens. This is a technique that can become the mainstream in the future with plastic spectacle lenses with antireflection films.

Claims (8)

An antireflection film comprising a primer layer formed on a plastic lens substrate, a hard coat layer formed on the primer layer, and a low refractive index layer and a high refractive index layer alternately laminated on the hard coat layer The antireflection film has a design principal wavelength λ _{0 in} a range of 480 nm to 560 nm, and the odd layer is formed with a low refractive index in order from the outermost layer as the first layer to the outside. The low refractive index layer is composed of a SiO ₂ layer, and the high refractive index layer is selected from TiO ₂ , Nb ₂ O ₅ , Ta ₂ O ₅ , ZrO ₂ , and LaTiO _3. The optical film thickness of a specific low refractive index layer on the convex side, which is the opposite side of the surface facing the eyeball side of the lens, and the concave side, which is the surface facing the eyeball side. The optical film thickness of the low refractive index layer is within a predetermined range. Plastic lens characterized by being made. 2. The antireflection film according to claim 1, wherein the convex side is an antireflection film consisting of five layers and the concave side is an antireflection film consisting of five layers. 0.350λ ₀ ≦ Optical film thickness of the low refractive index layer ≦ 0.650λ ₀
The optical thickness of the first low refractive index layer on the concave side is 0.030λ ₀ ≦ the optical thickness of the low refractive index layer ≦ 0.300λ ₀
The plastic lens characterized by being. 2. The antireflection film according to claim 1, wherein the convex side is an antireflection film consisting of five layers, and the concave side is an antireflection film consisting of seven layers. 0.350λ ₀ ≦ Optical film thickness of the low refractive index layer ≦ 0.650λ ₀
The optical thicknesses of the first and third low refractive index layers on the concave side are 0.030λ ₀ ≦ the optical thickness of the low refractive index layer ≦ 0.300λ ₀
The plastic lens characterized by being. 2. The antireflective film according to claim 1, wherein the convex side is an antireflective film comprising seven layers and the concave side is an antireflective film comprising five layers. The first or third low refractive index layer on the convex side The optical film thickness of 0.350λ ₀ ≦ the optical film thickness of the low refractive index layer ≦ 0.650λ ₀
The optical thickness of the first low refractive index layer on the concave side is 0.030λ ₀ ≦ the optical thickness of the low refractive index layer ≦ 0.300λ ₀
The plastic lens characterized by being. 2. The antireflective film according to claim 1, wherein the convex side is an antireflective film consisting of seven layers, and the concave side is an antireflective film consisting of seven layers. The optical film thickness of 0.350λ ₀ ≦ the optical film thickness of the low refractive index layer ≦ 0.650λ ₀
The optical thicknesses of the first and third low refractive index layers on the concave side are 0.030λ ₀ ≦ the optical thickness of the low refractive index layer ≦ 0.300λ ₀
The plastic lens characterized by being.   The plastic lens according to any one of claims 1 to 5, wherein the primer layer contains a water-based acrylic-urethane resin or a polyester-based thermoplastic elastomer as a main component. The plastic lens according to any one of claims 1 to 6, wherein the hard coat layer contains at least the following components (A) and (B) as main components.
(A). Fine particles composed of one or more metal oxides selected from Si, Al, Sn, Sb, Ta, Ce, La, Fe, Zn, W, Zr, In, and Ti and / or Si, Al having a particle diameter of 1 to 100 nm , Sn, Sb, Ta, Ce, La, Fe, Zn, W, Zr, In, Ti, composite fine particles composed of two or more metal oxides (B). General formula R ¹ R ² _n SiX _3-n (1)
(Wherein R ¹ is an organic group having a polymerizable reactive group, R ² is a hydrocarbon group having 1 to 6 carbon atoms, X is a hydrolyzable group, and n is 0 or 1) 8. The plastic lens according to claim 7, wherein the hard coat contains the following component (C).
(C) Polyfunctional epoxy compound