JP2009242764A - Coating liquid reduced in adhesion of dactylogram, method for producing the same, and article coated with the same - Google Patents

Coating liquid reduced in adhesion of dactylogram, method for producing the same, and article coated with the same Download PDF

Info

Publication number
JP2009242764A
JP2009242764A JP2008094548A JP2008094548A JP2009242764A JP 2009242764 A JP2009242764 A JP 2009242764A JP 2008094548 A JP2008094548 A JP 2008094548A JP 2008094548 A JP2008094548 A JP 2008094548A JP 2009242764 A JP2009242764 A JP 2009242764A
Authority
JP
Japan
Prior art keywords
solution
coating liquid
adhesion
mixed solution
dactylogram
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
JP2008094548A
Other languages
Japanese (ja)
Inventor
Takuro Okubo
大久保拓朗
Tatsuya Kojima
龍也 小嶋
Takashi Takahashi
崇 高橋
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Topcon Corp
Original Assignee
Topcon Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Topcon Corp filed Critical Topcon Corp
Priority to JP2008094548A priority Critical patent/JP2009242764A/en
Priority to TW098104990A priority patent/TW200948913A/en
Priority to CNA2009101268134A priority patent/CN101550293A/en
Publication of JP2009242764A publication Critical patent/JP2009242764A/en
Withdrawn legal-status Critical Current

Links

Images

Landscapes

  • Paints Or Removers (AREA)

Abstract

<P>PROBLEM TO BE SOLVED: To provide: a coating liquid being reduced in the adhesion of a dactylogram which gives an interannual antifouling function over several months to a base material consisting of a substance such as glass or a metal and which semipermanently prevents the adhesion of an oily substance of dactylogram; its production method; and an article prepared by coating a base material with the dactylogram adhesion reduction coating liquid. <P>SOLUTION: The coating liquid being reduced in the adhesion of dactylogram is produced by mixing an organic compound having a ketone group with an organic nitrogen compound, each in an amount of 10-40% solid content per total solution, to make a mixed solution and then adding an antifouling additive in an amount of 0.1-20.0% of a solid content of the mixed solution to the mixed solution. A method for producing the coating liquid and an article coated with the dactylogram adhesion reduction coating liquid are also provided. <P>COPYRIGHT: (C)2010,JPO&INPIT

Description

本発明は、ガラスや金属などにおいて指紋付着を防止する指紋付着低減コート液、及びその製造方法、並びに指紋付着低減コート液を塗布した物品に関する。   The present invention relates to a fingerprint adhesion reducing coating liquid for preventing fingerprint adhesion in glass or metal, a manufacturing method thereof, and an article coated with the fingerprint adhesion reducing coating liquid.

一般に、指紋の成分は、汗などの水性物質と油性物質からなっており、指紋の汚れは、水性物質と油性物質が複合化した汚れであると考えられる。   Generally, the fingerprint component is composed of an aqueous substance such as sweat and an oily substance, and the fingerprint stain is considered to be a composite of an aqueous substance and an oily substance.

一方、汗は水の他に塩化ナトリウム・塩化カリウムなどの無機成分や乳酸・アミノ酸などの有機成分、さらには遊離脂肪酸などを含んでいる。そのため、汗に対しては、水性汚れを付着しにくくするとともに、水性汚れを落ちやすくする撥水性と、油性汚れを付着しにくくするとともに、油汚れを落ちやすくする撥油性の両方の機能を持つ成分を表面にコートする必要がある。   On the other hand, sweat contains inorganic components such as sodium chloride and potassium chloride, organic components such as lactic acid and amino acids, and free fatty acids in addition to water. Therefore, it has both functions of making water resistant to sweat, making it easier to remove water-based stains, and making it easier to remove oil-based stains and making it easier to remove oil stains. It is necessary to coat the surface with ingredients.

従来から、例えば特許文献１に示すように、撥水性の溶液コート液をガラスや金属を塗膜し、指紋の付着を防止する溶液コートが知られている。   Conventionally, as shown in Patent Document 1, for example, a solution coat is known in which a water-repellent solution coating solution is coated with glass or metal to prevent adhesion of fingerprints.

すなわち、特許文献１には、（Ａ）ヒドロキシル基、カルボキシル基およびカルボン酸塩のうちの少なくとも１種を有している官能基含有含フッ素エチレン性単量体を共重合してえられる官能基含有含フッ素エチレン性重合体、（Ｂ）金属酸化物ゾル、および（Ｃ）溶剤からなる被覆用組成物が記載されている。   That is, Patent Document 1 discloses (A) a functional group obtained by copolymerizing a functional group-containing fluorinated ethylenic monomer having at least one of a hydroxyl group, a carboxyl group, and a carboxylate. A coating composition comprising a fluorine-containing ethylenic polymer, (B) a metal oxide sol, and (C) a solvent is described.

官能基を有している前記含フッ素エチレン性重合体（Ａ）は、
式：ＣＸ２＝ＣＸ１−Ｒｆ−Ｙ
（式中、Ｙは−ＣＨ２ＯＨ、−ＣＯＯＨ、カルボン酸塩またはエポキシ基であり、Ｘ２およびＸ１は同じかまたは異なり、いずれも、水素原子またはフッ素原子であり、Ｒｆは炭素数１〜４０の２価の含フッ素アルキレン基または炭素数１〜４０のエーテル結合を含有している２価の含フッ素アルキレン基を表わす）
で示される少なくとも１種の官能基含有含フッ素エチレン性単量体である。 The fluorine-containing ethylenic polymer (A) having a functional group is
Formula: CX2 = CX1-Rf-Y
(In the formula, Y is —CH 2 OH, —COOH, a carboxylate or an epoxy group, X 2 and X 1 are the same or different, both are hydrogen atoms or fluorine atoms, and Rf has 1 to 40 carbon atoms. A divalent fluorine-containing alkylene group or a divalent fluorine-containing alkylene group containing an ether bond having 1 to 40 carbon atoms)
And at least one functional group-containing fluorine-containing ethylenic monomer.

該官能基含有含フッ素エチレン性単量体０．０５〜５０モル％と、共重合可能な少なくとも１種の含フッ素エチレン性単量体５０〜９９．９５モル％を共重合して、官能基を有している含フッ素エチレン性重合体が得られる。   The functional group-containing fluorine-containing ethylenic monomer 0.05 to 50 mol% is copolymerized with at least one copolymerizable fluorine-containing ethylenic monomer 50 to 99.95 mol% to obtain a functional group. A fluorine-containing ethylenic polymer having

また、撥水性の溶液コート液では、指紋の油性物質を充分に除去できないことから、例えば特許文献２に示されているように、親水性の溶液コート液を用いたコート液が知られている。基材上に、ａ）親水性ポリマーと、ｂ）Ｓｉ、Ｔｉ、Ｚｒ、Ａｌから選択される金属アルコキシド化合物と、ｃ）金属錯体触媒を含有する親水性被膜とを塗設して親水性部材を形成する。前記ｃ）の金属錯体触媒が、周期律表の２Ａ，３Ｂ，４Ａ及び５Ａ族から選ばれる金属元素とβ−ジケトン、ケトエステル、ヒドロキシカルボン酸又はそのエステル、アミノアルコール、エノール性活性水素化合物の中から選ばれるオキソ又はヒドロキシ酸素含有化合物から構成される。
特許３３８９６０５号公報 特開２００７−２５４２６５号公報 In addition, since the water-repellent solution coating liquid cannot sufficiently remove the oily substance of fingerprints, a coating liquid using a hydrophilic solution coating liquid is known as disclosed in Patent Document 2, for example. . On the base material, a) a hydrophilic polymer, b) a metal alkoxide compound selected from Si, Ti, Zr, and Al, and c) a hydrophilic film containing a metal complex catalyst are coated to form a hydrophilic member. Form. The metal complex catalyst of c) is a metal element selected from groups 2A, 3B, 4A and 5A of the periodic table and a β-diketone, ketoester, hydroxycarboxylic acid or ester thereof, amino alcohol, enolic active hydrogen compound. It is comprised from the oxo or hydroxy oxygen containing compound chosen from these.
Japanese Patent No. 3389605 JP 2007-254265 A

しかしながら、特許文献２に示されているような親水性部材では、Ｓｉ、Ｔｉ、Ｚｒ、Ａｌから選択される金属アルコキシド化合物を必要とすることから、親水性ポリマーと金属錯体触媒を含有する親水性被膜との結合が弱く、数ヶ月程度の経年的な防汚機能の劣化が生じてしまう可能性がある。   However, since the hydrophilic member as shown in Patent Document 2 requires a metal alkoxide compound selected from Si, Ti, Zr, and Al, the hydrophilic member contains a hydrophilic polymer and a metal complex catalyst. Bonding with the film is weak, and there is a possibility that deterioration of the antifouling function over a period of several months may occur.

そこで、本発明は、ガラスや金属等の物質からなる基材に、数ヶ月程度の経年的な防汚機能を与えることができ、その防汚機能の劣化が生じることなく、半永久的に指紋の油性物質の付着を防止することができる指紋付着低減コート液、及びその製造方法、並びに指紋付着低減コート液を塗布した物品を提供することを目的とする。   Accordingly, the present invention can provide a substrate made of a material such as glass or metal with an antifouling function over a period of several months, and without causing deterioration of the antifouling function, the fingerprint is semipermanently obtained. It is an object of the present invention to provide a fingerprint adhesion reducing coating liquid capable of preventing the adhesion of an oily substance, a manufacturing method thereof, and an article coated with the fingerprint adhesion reducing coating liquid.

上記課題を解決するため、本発明は、特許請求の範囲の各請求項に記載した事項を特徴とする。   In order to solve the above-described problems, the present invention is characterized by matters described in the claims.

以上から、本発明によれば、ガラスや金属等の物質に、数ヶ月程度の経年的な防汚機能を与えることができ、その防汚機能の劣化を生じることなく、半永久的に指紋等の油性物質の付着を防止することができる。   As described above, according to the present invention, a material such as glass or metal can be provided with an antifouling function over a period of several months, and without causing deterioration of the antifouling function, such as fingerprints semipermanently. The adhesion of oily substances can be prevented.

本発明に係る指紋付着低減コート液は、ケトン基を有する有機化合物と有機窒素化合物とを、全溶液に対して、それぞれ固形分で１０％〜４０％ずつ混合して、混合溶液をつくり、その混合溶液に混合溶液の固形分に対して０．１％〜２０．０％の防汚性添加剤を添加して作る。残部は、プロピレングリコールモノメチルエーテルおよびメチルイソブチルケトンを主とする有機溶媒である。   The fingerprint adhesion-reducing coating liquid according to the present invention is a mixture of an organic compound having a ketone group and an organic nitrogen compound at a solid content of 10% to 40%, respectively, with respect to the total solution. It is made by adding 0.1% to 20.0% antifouling additive to the mixed solution based on the solid content of the mixed solution. The balance is an organic solvent mainly composed of propylene glycol monomethyl ether and methyl isobutyl ketone.

好ましくは、ＪＲＳ製のＫＺ６１５４（商品名）と、荒川化学製のビームセット５７５ＣＢ（商品名）を配合して、混合溶液をつくって精製する。   Preferably, KRS6154 (trade name) manufactured by JRS and Beam Set 575CB (trade name) manufactured by Arakawa Chemical are blended to prepare a mixed solution for purification.

上述したＪＲＳ製のＫＺ６１５４（商品名）は、メチルエチルケトン、メチルイソブチルケトン、シクロヘキサノンを主成分としている。荒川化学製のビームセット５７５ＣＢ（商品名）は、Ｎ−ビニルホルムアミド（ＮＶＦ）、化学式ＣＨ＝ＣＨ−ＮＨ−ＣＨＯを主成分としている。   The above-mentioned KZ6154 (trade name) manufactured by JRS is mainly composed of methyl ethyl ketone, methyl isobutyl ketone, and cyclohexanone. Arakawa Chemical's beam set 575CB (trade name) is mainly composed of N-vinylformamide (NVF) and the chemical formula CH = CH-NH-CHO.

精製された混合溶液に、撥水撥油機能が非常に高い成分を含有する防汚性添加剤を添加して混入させる。例えば、防汚性添加剤としてオプツールＤＡＣ（ダイキン製）を使用する。   An antifouling additive containing a component having a very high water and oil repellency function is added to and mixed with the purified mixed solution. For example, Optool DAC (manufactured by Daikin) is used as an antifouling additive.

混合溶液の固形分に対して添加剤が固形分比で０．５〜４０．０％になるように添加する。防汚性添加剤は１．０〜１０．０％、とくに４．０％程度が最も良い。   Addition is performed so that the additive is 0.5 to 40.0% by solid content ratio with respect to the solid content of the mixed solution. The antifouling additive is most preferably 1.0 to 10.0%, particularly about 4.0%.

ガラス、レンズ、金属などの基材好ましくは基板の表面に指紋付着低減コート液を塗布する。それによって、半永久的に指紋の油性物質の付着を防止する指紋付着低減コートが基板の表面に形成される。   A coating solution for reducing fingerprint adhesion is applied to a substrate such as glass, a lens, or a metal, preferably the surface of the substrate. As a result, a fingerprint adhesion reduction coat that prevents the adhesion of the oily substance of the fingerprint semi-permanently is formed on the surface of the substrate.

例えば、まず、図１の左側に示すように、ケトン基を有する有機化合物と有機窒素化合物との混合溶液からなる撥水撥油効果のあるハードコート剤３をガラス、レンズ、金属などの基板１の表面に塗布する。そのあと、撥水撥油機能が非常に高い成分を含有する防汚性添加剤４を添加する。すると、図１の右側に示す混合状態になる。そのあと、溶剤を飛ばした後にＵＶ照射による硬化処理を行い、撥水撥油機能のある指紋付着低減コート２を形成する。指紋付着低減コート２の表面付近の薄い層（好ましくは厚さ０．０１〜０．１０μｍの層）には、撥水撥油機能が高い成分５が高密度に配列される。   For example, first, as shown on the left side of FIG. 1, a hard coat agent 3 having a water / oil repellent effect made of a mixed solution of an organic compound having a ketone group and an organic nitrogen compound is used as a substrate 1 made of glass, lens, metal or the like. Apply to the surface. Thereafter, the antifouling additive 4 containing a component having a very high water / oil repellent function is added. Then, it will be in the mixed state shown on the right side of FIG. Thereafter, after the solvent is blown off, a curing treatment by UV irradiation is performed to form a fingerprint adhesion reduction coat 2 having a water and oil repellent function. In a thin layer (preferably a layer having a thickness of 0.01 to 0.10 μm) in the vicinity of the surface of the fingerprint adhesion reducing coat 2, the components 5 having a high water and oil repellency function are arranged at high density.

以上により、ケトン基を有する有機化合物と有機窒素化合物とを、全溶液に対して、それぞれ固形分で１０％〜４０％ずつ混合し、混合された混合溶液に、その混合溶液の固形分に対して０．１％〜２０．０％の防汚性添加剤を添加して溶液コート液を製造することによって、指紋付着低減コート液を製造することができる。そして、ガラス、レンズ、金属などの表面に指紋付着低減性コートを形成することにより、それらの物品の表面の艶（鏡面状態）を保ったまま指紋の付着を低減させることができる。しかも、数ヶ月程度の経年的な防汚機能を与え、その防汚機能の劣化を生じることなく、半永久的に指紋等の油性物質の付着を防止することができる。   As described above, the organic compound having a ketone group and the organic nitrogen compound are mixed in a solid content of 10% to 40% with respect to the total solution, respectively, and the mixed solution is mixed with the solid content of the mixed solution. By adding 0.1% to 20.0% antifouling additive to produce a solution coating solution, a fingerprint adhesion reducing coating solution can be produced. Then, by forming a fingerprint adhesion reducing coat on the surface of glass, lens, metal, etc., it is possible to reduce the adhesion of fingerprints while maintaining the gloss (mirror surface state) of the surface of those articles. In addition, the antifouling function over a period of several months is given, and the adhesion of oily substances such as fingerprints can be prevented semipermanently without causing deterioration of the antifouling function.

本発明の具体的な実施例を以下に示す。   Specific examples of the present invention are shown below.

配合比Ｉ
有機化合物：有機窒素化合物＝１０：３０
混合溶液の固形分に対して７．５％防汚性添加剤を添加
配合比II
有機化合物：有機窒素化合物＝１０：４０
混合溶液の固形分に対して１０．５％防汚性添加剤を添加
配合比III
有機化合物：有機窒素化合物＝２０：４０
混合溶液の固形分に対して１６．５％防汚性添加剤を添加
実際に使用した混合溶液について述べると、有機化合物は、ＫＺ６１５４であり、有機窒化合物は、ビームセット５７５ＣＢであった。防汚性添加剤は、オプツールＤＡＣであった。 Mixing ratio I
Organic compound: Organic nitrogen compound = 10: 30
Add 7.5% antifouling additive to the solid content of the mixed solution.
Organic compound: Organic nitrogen compound = 10: 40
10.5% antifouling additive is added to the solid content of the mixed solution.
Organic compound: Organic nitrogen compound = 20: 40
Addition of 16.5% antifouling additive to the solid content of the mixed solution Referring to the actually used mixed solution, the organic compound was KZ6154 and the organic nitrogen compound was Beamset 575CB. The antifouling additive was Optool DAC.

ケトン基を有する有機化合物と有機窒素化合物と防汚性添加剤を除いた残部は、プロピレングリコールモノメチルエーテルであった。   The balance other than the organic compound having a ketone group, the organic nitrogen compound, and the antifouling additive was propylene glycol monomethyl ether.

硬化処理は、８０℃×３ｍｉｎ ＵＶ３６５ｎｍ ８００ｍＪ／ｃｍ２であった。 The curing treatment was 80 ° C. × 3 min UV 365 nm 800 mJ / cm 2 .

なお、本明細書において、「％」は、すべて「モル％」である。   In the present specification, “%” is all “mol%”.

撥水撥油効果のあるハードコート剤をケトン基を有する有機化合物と有機窒素化合物との混合溶液としてガラス、レンズ、金属などの基板の表面に塗布するとともに、撥水撥油機能が非常に高い成分を含有する添加剤を防汚性添加剤として添加して、硬化処理を行い、表面に撥水撥油機能が高い成分が高密度に配列され、撥水撥油機能のある指紋付着低減コートが形成される様子を示す説明図。A water-repellent and oil-repellent hard coat agent is applied as a mixed solution of an organic compound having a ketone group and an organic nitrogen compound to the surface of a substrate such as glass, lens, or metal. Additives containing ingredients are added as antifouling additives, cured, and the surface with high water and oil repellency functions are arranged in high density on the surface. Explanatory drawing which shows a mode that is formed.

符号の説明Explanation of symbols

１ 基板
２ 紋付着低減コート
３ 撥水撥油効果があるハードコート剤
４ 防汚性添加剤
５ 撥水撥油機能が非常に高い成分 DESCRIPTION OF SYMBOLS 1 Substrate 2 Coat adhesion reduction coat 3 Hard coat agent with water / oil repellent effect 4 Antifouling additive 5 Ingredient with very high water / oil repellent function

Claims (4)

ケトン基を有する有機化合物と有機窒素化合物とが、全溶液に対して、それぞれ固形分で１０％〜４０％ずつ混合された混合溶液と、その混合溶液に混合溶液の固形分に対して０．１％〜２０．０％添加する防汚性添加剤との組成物であることを特徴とする指紋付着低減コート液。   A mixed solution in which an organic compound having a ketone group and an organic nitrogen compound are mixed in a solid content of 10% to 40% with respect to the total solution, and the mixed solution has a solid content of 0. A coating solution for reducing fingerprint adhesion, which is a composition with an antifouling additive added at 1% to 20.0%. ケトン基を有する有機化合物と有機窒素化合物とを、全溶液に対して、それぞれ固形分で１０％〜４０％ずつ混合して、混合溶液をつくり、その混合溶液に混合溶液の固形分に対して０．１％〜２０．０％の防汚性添加剤を添加して、溶液コート液を製造することを特徴とする指紋付着低減コート液の製造方法。   An organic compound having a ketone group and an organic nitrogen compound are mixed at a solid content of 10% to 40% with respect to the total solution to form a mixed solution, and the mixed solution is added to the solid content of the mixed solution. A method for producing a coating solution for reducing fingerprint adhesion, comprising adding 0.1% to 20.0% of an antifouling additive to produce a solution coating solution. ケトン基を有する有機化合物と有機窒素化合物とが、全溶液に対して、それぞれ固形分で１０％〜４０％ずつ混合されて、混合溶液になって、その混合溶液に混合溶液の固形分に対して０．１％〜２０．０％の防汚性添加剤が添加されて指紋付着低減コート液が形成されており、その指紋付着低減コート液が基材に塗布されていることを特徴とする物品。   An organic compound having a ketone group and an organic nitrogen compound are mixed in a solid content of 10% to 40% with respect to the total solution to form a mixed solution, and the mixed solution is mixed with the solid content of the mixed solution. 0.1% to 20.0% of an antifouling additive is added to form a fingerprint adhesion reducing coating liquid, and the fingerprint adhesion reducing coating liquid is applied to a substrate. Goods. 指紋付着低減コート液が硬化された状態で、表面に撥水撥油機能が高い成分が高密度に配列されて、撥水撥油機能のある指紋付着低減コートが形成されていることを特徴とする請求項３に記載の物品。   The fingerprint adhesion reduction coating solution is cured, and the surface has high water and oil repellency components arranged in high density to form a fingerprint adhesion reduction coat with water and oil repellency. The article according to claim 3.
JP2008094548A 2008-04-01 2008-04-01 Coating liquid reduced in adhesion of dactylogram, method for producing the same, and article coated with the same Withdrawn JP2009242764A (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
JP2008094548A JP2009242764A (en) 2008-04-01 2008-04-01 Coating liquid reduced in adhesion of dactylogram, method for producing the same, and article coated with the same
TW098104990A TW200948913A (en) 2008-04-01 2009-02-17 Coating liquid for reducing fingerprint adhesion, manufacturing method thereof, and article to which coating liquid is applied
CNA2009101268134A CN101550293A (en) 2008-04-01 2009-03-18 Coating liquid capable of reducing fingerprint adhesion, manufacturing method thereof, and products coated with the coating liquid

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2008094548A JP2009242764A (en) 2008-04-01 2008-04-01 Coating liquid reduced in adhesion of dactylogram, method for producing the same, and article coated with the same

Publications (1)

Publication Number Publication Date
JP2009242764A true JP2009242764A (en) 2009-10-22

Family

ID=41154795

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2008094548A Withdrawn JP2009242764A (en) 2008-04-01 2008-04-01 Coating liquid reduced in adhesion of dactylogram, method for producing the same, and article coated with the same

Country Status (3)

Country Link
JP (1) JP2009242764A (en)
CN (1) CN101550293A (en)
TW (1) TW200948913A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2012072283A (en) * 2010-09-29 2012-04-12 Neos Co Ltd Fingerprint resistance-improving agent, active energy ray-curable hard coating agent using the improving agent, cured film obtained by using them, and article having the cured film
JP2012177054A (en) * 2011-02-28 2012-09-13 Topcon Corp Coating liquid for reducing fingerprint attachment, method for producing the same, and article coated with the coating liquid for reducing fingerprint attachment
JP2015212107A (en) * 2014-05-01 2015-11-26 矢崎総業株式会社 Vehicle rear side imaging device

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH06106756A (en) * 1992-09-25 1994-04-19 Fuji Xerox Co Ltd Thermal head and manufacture thereof
JPH0829946A (en) * 1994-02-15 1996-02-02 Konica Corp Automatic developing device
JP2007264281A (en) * 2006-03-28 2007-10-11 Dainippon Printing Co Ltd Hard coat layer provided with antifouling property
JP2009053691A (en) * 2007-08-02 2009-03-12 Dainippon Printing Co Ltd Antireflection film and method for manufacturing the same
JP2009075354A (en) * 2007-09-20 2009-04-09 Dainippon Printing Co Ltd Optical laminate, polarizing plate, and image display

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH06106756A (en) * 1992-09-25 1994-04-19 Fuji Xerox Co Ltd Thermal head and manufacture thereof
JPH0829946A (en) * 1994-02-15 1996-02-02 Konica Corp Automatic developing device
JP2007264281A (en) * 2006-03-28 2007-10-11 Dainippon Printing Co Ltd Hard coat layer provided with antifouling property
JP2009053691A (en) * 2007-08-02 2009-03-12 Dainippon Printing Co Ltd Antireflection film and method for manufacturing the same
JP2009075354A (en) * 2007-09-20 2009-04-09 Dainippon Printing Co Ltd Optical laminate, polarizing plate, and image display

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2012072283A (en) * 2010-09-29 2012-04-12 Neos Co Ltd Fingerprint resistance-improving agent, active energy ray-curable hard coating agent using the improving agent, cured film obtained by using them, and article having the cured film
JP2012177054A (en) * 2011-02-28 2012-09-13 Topcon Corp Coating liquid for reducing fingerprint attachment, method for producing the same, and article coated with the coating liquid for reducing fingerprint attachment
JP2015212107A (en) * 2014-05-01 2015-11-26 矢崎総業株式会社 Vehicle rear side imaging device

Also Published As

Publication number Publication date
CN101550293A (en) 2009-10-07
TW200948913A (en) 2009-12-01

Similar Documents

Publication Publication Date Title
Schlaich et al. Mussel‐inspired polymer‐based universal spray coating for surface modification: fast fabrication of antibacterial and superhydrophobic surface coatings
EP2512696B1 (en) Sulfonate-functional coatings and methods
JP2016107465A (en) Curing liquid for stereoscopic molding, stereoscopic molding material set, and method for producing stereoscopic molding
JP2009538377A5 (en)
EP3109206A1 (en) Material set for manufacturing glass object, liquid material for manufacturing glass object, method of manufacturing glass object, glass object, and device for manufacturing glass object
EP1506986A4 (en) Hydrophilization-accelerating and hydrophilicity -keeping agents for polysilazane-containing coating films
JPWO2018123126A1 (en) Film forming liquid composition and method for producing the same
JP2009242764A (en) Coating liquid reduced in adhesion of dactylogram, method for producing the same, and article coated with the same
WO2013007203A4 (en) Coating material for aluminum substrate for inkjet computer-to-plate and preparation and use of same
JP6405015B1 (en) Active energy ray-curable resin composition, laminate, method for producing the same, and article
JP6753765B2 (en) Liquid composition for film formation
KR20170065050A (en) Coating composition for excellent anti-corrosion and anti-finger, stainless steel having etching pattern, and method of manufacturing the stainless steel
JP4842599B2 (en) Water-based paint for architectural civil engineering
TW201247040A (en) Film including metal oxide particles, transfer film and fabricating method thereof, and laminating body and fabricating method thereof
JP2012219215A (en) Coating material composition
JP2007217739A (en) Method for forming water-repellent film
KR100700684B1 (en) Plastic sheet comprising hard coat layer with antifouling property, hard coating composition, and coating method of plastic sheet using it
KR20090105828A (en) Coating liquid for reducing fingerprint adhesion, manufacturing method thereof, and article to which coating liquid is applied
JP2012177054A (en) Coating liquid for reducing fingerprint attachment, method for producing the same, and article coated with the coating liquid for reducing fingerprint attachment
JP3895433B2 (en) Agricultural plastic film
JP2008156427A (en) Water repellent and soil preventive hard coat composition
JP2010007008A (en) Heat-curable protective liquid for glass mask and glass mask
KR20110074391A (en) Glass frit composition with low melting temperature for adhering on superhydrophobic nano-coating material and superhydrophobic nano-coating substrate using the same
JP6252205B2 (en) Hydrophilic film-forming article, hydrophilic film-forming coating liquid, and method for producing hydrophilic film-forming article
JP5095527B2 (en) Thermosetting protective liquid for glass mask and glass mask

Legal Events

Date Code Title Description
A977 Report on retrieval

Free format text: JAPANESE INTERMEDIATE CODE: A971007

Effective date: 20100903

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20100914

A521 Written amendment

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20101115

A02 Decision of refusal

Free format text: JAPANESE INTERMEDIATE CODE: A02

Effective date: 20120110

A521 Written amendment

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20120403

A911 Transfer of reconsideration by examiner before appeal (zenchi)

Free format text: JAPANESE INTERMEDIATE CODE: A911

Effective date: 20120412

A912 Removal of reconsideration by examiner before appeal (zenchi)

Free format text: JAPANESE INTERMEDIATE CODE: A912

Effective date: 20120713

A761 Written withdrawal of application

Free format text: JAPANESE INTERMEDIATE CODE: A761

Effective date: 20121129