JP2009233942A - Method for producing decorative plate - Google Patents

Method for producing decorative plate Download PDF

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JP2009233942A
JP2009233942A JP2008080850A JP2008080850A JP2009233942A JP 2009233942 A JP2009233942 A JP 2009233942A JP 2008080850 A JP2008080850 A JP 2008080850A JP 2008080850 A JP2008080850 A JP 2008080850A JP 2009233942 A JP2009233942 A JP 2009233942A
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veneer
adhesive
wood
paper
adhesive layer
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JP5004357B2 (en
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Akinori Akiyama
明功 秋山
Yasushi Oyama
靖 大山
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Daiken Corp
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Daiken Corp
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Abstract

<P>PROBLEM TO BE SOLVED: To produce a decorative plate which is excellent in caster resistance, injury resistance, and decoration properties and suppresses the occurrence of a veneer splitting phenomenon. <P>SOLUTION: An adhesive layer 2 having elasticity in a cured state is formed on the surface of a woody substrate 1. While the adhesive layer 2 is semi-cured, a woody thin veneer 5 having an air dry water content or a high water content is laminated/unified on/with its surface through a paper layer 3. <P>COPYRIGHT: (C)2010,JPO&INPIT

Description

本発明は、耐キャスター性に優れた化粧板の製造方法に関する。   The present invention relates to a method for producing a decorative board having excellent caster resistance.

従来、例えば特許文献1に示されるように、木質板の片面に接着剤を介して表面仕上材が貼着されている床材の製造方法として、木質板の片面に、ゴム系接着剤と樹脂系接着剤とを混合した混合接着剤を下塗りして乾燥した後、この上面に表面仕上材を載置して貼着する方法が知られている。この方法で製造すると、ゴム系接着剤を用いているので、キャスター付きの椅子や家具の移動に際して、床板が傷付くのを防ぐために効果的である。
特開2003−211420号公報
Conventionally, as shown in, for example, Patent Document 1, as a method of manufacturing a flooring material in which a surface finishing material is attached to one side of a wooden board via an adhesive, a rubber adhesive and a resin are provided on one side of the wooden board. A method is known in which a mixed adhesive mixed with a system adhesive is subbed and dried, and then a surface finishing material is placed on the upper surface and adhered. When manufactured by this method, since a rubber adhesive is used, it is effective to prevent the floor board from being damaged when a chair or furniture with casters is moved.
JP 2003-21420 A

しかし、その場合、表面仕上材として、気乾含水率(5〜7%程度)よりも含水率の高い木質薄単板を熱圧プレスにて貼着した場合は、単板自体の収縮によって単板割れが発生するという問題がある。この現象は、特に板目模様の高含水率木質単板を使用したときに顕著に現れる。   However, in that case, when a wood thin veneer with a moisture content higher than the air dry moisture content (about 5 to 7%) is attached as a surface finish by a hot press, the single plate itself contracts due to shrinkage. There is a problem that cracks occur. This phenomenon is particularly prominent when a high moisture content wood veneer having a grain pattern is used.

また、基材としてMDFのように表面が略面一の材料を使用することにより、均一な厚みの接着層の形成が可能であるが、合板のように表面が凹凸や吸い込みムラのある材料を使用した場合には、その表面の凹凸や吸い込みムラに起因して木質薄単板の下の接着層の厚みが場所により異なるようになり、特に接着剤層が薄くなった部分でキャスター使用時の単板剥離が生じ易くなる。   In addition, it is possible to form an adhesive layer with a uniform thickness by using a material with a substantially uniform surface, such as MDF, as the base material. However, a material with uneven surface or uneven suction, such as plywood, can be used. When used, the thickness of the adhesive layer under the thin wood veneer varies depending on the location due to unevenness of the surface and uneven suction, especially when the caster is used in the thinned adhesive layer Single plate peeling tends to occur.

本発明は斯かる点に鑑みてなされたもので、その目的は、基材として合板のように表面が凹凸や吸い込みムラのある材料を使用した場合でも、耐キャスター性に優れるとともに、単板割れの現象が発生し難い耐傷性と化粧性に優れた化粧板が得られるようにすることにある。   The present invention has been made in view of such points, and its purpose is to provide excellent caster resistance and a single plate cracking even when a material having uneven surface or uneven suction is used as a base material such as plywood. This is to obtain a decorative board excellent in scratch resistance and cosmetic properties in which the above phenomenon hardly occurs.

上記の目的を達成するために、この発明では、木質基材の表面に、硬化状態で弾性を持つ接着剤の層を設け、この接着剤の層が半硬化にある状態で、その表面に紙層を介して気乾含水率ないし高含水率の木質薄単板を積層して一体化するようにした。   In order to achieve the above object, according to the present invention, an adhesive layer having elasticity in a cured state is provided on the surface of a wooden substrate, and the surface of the adhesive layer is semi-cured, and the paper is applied to the surface. Air-dry moisture content or high moisture content wood thin veneer was laminated and integrated through the layers.

具体的には、請求項1の発明では、木質基材の表面に木質薄単板を、接着剤を介して熱圧プレスにて積層一体化する化粧板の製造方法として、上記木質基材の表面に、硬化状態で弾性を有する基材側接着剤を塗布して半硬化させることで、半硬化状態の接着層を形成する接着層形成工程と、この半硬化状態の接着層上に薄葉紙を載置して紙層を積層する紙層積層工程と、この紙層上に単板側接着剤を塗布する単板側接着剤塗布工程と、この単板側接着剤上に上記木質薄単板を積層して積層体を得る積層工程と、この積層体を熱圧プレスして積層一体化することで、上記接着層の厚みが30μm以上でかつ75μm以下であるとともに、該接着層の硬度がタイプAデュロメーターで30°以下となる化粧基材を得る熱圧プレスエ程と、この化粧基材の表面に化粧加工を行う化粧加工工程とを含むことを特徴とする。   Specifically, in the invention of claim 1, as a method for producing a decorative board in which a wood thin veneer is laminated and integrated on a surface of a wood substrate by a hot press through an adhesive, An adhesive layer forming step for forming a semi-cured adhesive layer by applying a base-side adhesive having elasticity in a cured state and semi-curing the surface, and a thin paper on the semi-cured adhesive layer A paper layer laminating step for placing and laminating paper layers, a single plate side adhesive applying step for applying a single plate side adhesive on the paper layer, and the wood thin veneer on the single plate side adhesive And laminating and integrating the laminate by hot-pressing the laminate, and the thickness of the adhesive layer is 30 μm or more and 75 μm or less, and the hardness of the adhesive layer is The hot-press press process to obtain a cosmetic base material of 30 ° or less with a type A durometer, and this cosmetic base Characterized in that it comprises a cosmetic process step for decorative processing on the surface of the.

請求項2の発明では、木質基材の表面に木質薄単板を、接着剤を介して熱圧プレスにて積層一体化する化粧板の製造方法として、上記木質基材の表面に、硬化状態で弾性を有する基材側接着剤を塗布して半硬化させることで、半硬化状態の接着層を形成する接着層形成工程と、この半硬化状態の接着層上に紙貼り接着剤を塗布しかつその紙貼り接着剤上に薄葉紙を載置して紙層を積層する紙層積層工程と、この紙層上に単板側接着剤を塗布する単板側接着剤塗布工程と、この単板側接着剤上に上記木質薄単板を積層して積層体を得る積層工程と、この積層体を熱圧プレスして積層一体化することで、上記接着層の厚みが30μm以上でかつ75μm以下であるとともに、該接着層の硬度がタイプAデュロメーターで30°以下となる化粧基材を得る熱圧プレス工程と、この化粧基材の表面に化粧加工を行う化粧加工工程とを含むことを特徴とする。   In the invention of claim 2, as a method for producing a decorative board in which a wood thin veneer is laminated and integrated by a hot press through an adhesive on the surface of the wood substrate, the surface of the wood substrate is cured. The adhesive layer forming process for forming a semi-cured adhesive layer by applying an elastic base material side adhesive and semi-curing, and applying the paper adhesive on the semi-cured adhesive layer And a paper layer laminating step in which thin paper is placed on the paper adhesive and laminating a paper layer, a single plate side adhesive applying step for applying a single plate side adhesive on the paper layer, and this single plate By laminating the wood thin single plate on the side adhesive to obtain a laminate, and by laminating and integrating the laminate by hot pressing, the thickness of the adhesive layer is 30 μm or more and 75 μm or less. And a decorative base material having a hardness of the adhesive layer of 30 ° or less with a type A durometer And Runetsu圧 pressing step, characterized in that it comprises a cosmetic process step for decorative processing on the surface of the decorative substrate.

これら請求項1又は2の発明では、木質基材表面に基材側接着剤が塗布されて半硬化状態の接着層が形成され、この半硬化状態の接着層上に直接又は紙貼り接着剤を介して紙層が積層された後に単板側接着剤が塗布され、さらに木質薄単板が積層され、その積層体が熱圧プレスされて積層一体化されて化粧基材が得られ、その化粧基材の表面に化粧加工が行われて化粧板が得られる。そのとき、基材側接着剤が半硬化状態なので、基材側接着剤の木質薄単板への染み上がりが抑制される。   In these inventions of claim 1 or 2, the base material side adhesive is applied to the surface of the wooden base material to form a semi-cured adhesive layer, and the paper adhesive is applied directly or on the semi-cured adhesive layer. After the paper layer is laminated, the veneer side adhesive is applied, and the thin wood veneer is further laminated, and the laminated body is hot-pressed to be laminated and integrated to obtain a cosmetic base material. A decorative process is performed on the surface of the substrate to obtain a decorative board. At that time, since the base material side adhesive is in a semi-cured state, the base material side adhesive is prevented from seeping into the thin wood veneer.

また、接着層は厚みが30μm以上でかつ75μm以下であり、硬度がタイプAデュロメーターで30°以下となる、すなわち、硬化物がこのような状態になる基材側接着剤が使用される。しかも、半硬化状態の接着層上に紙層及び木質薄単板が積層されるので、接着層の厚みを十分大に確保できる。このため、十分な厚みと柔軟性を有した接着層が介装された化粧板を得ることができ、長期的なキャスターの使用に対しても、木質薄単板の剥離が抑制される。   Moreover, the adhesive layer has a thickness of 30 μm or more and 75 μm or less and a hardness of 30 ° or less with a type A durometer, that is, a base material side adhesive in which the cured product is in such a state is used. In addition, since the paper layer and the thin wood veneer are laminated on the semi-cured adhesive layer, a sufficiently large thickness of the adhesive layer can be ensured. For this reason, a decorative board in which an adhesive layer having sufficient thickness and flexibility can be obtained, and peeling of the thin wood veneer is suppressed even when the caster is used for a long time.

請求項3の発明の化粧板の製造方法は、木質基材の表面に、硬化状態で弾性を有する基材側接着剤を塗布して半硬化させることで、半硬化状態の接着層を形成する接着層形成工程と、この半硬化状態の接着層上に紙貼り接着剤を塗布しかつその紙貼り接着剤上に薄葉紙を載置して紙層を積層する紙層積層工程と、上記木質基材と接着層と紙層とを熱圧プレスして積層一体化することで、該接着層の厚みを30μm以上でかつ75μm以下とするとともに、接着層の硬度をタイプAデュロメーターで30°以下とする第1熱圧プレス工程と、この第1熱圧プレス工程を経た紙層上に単板側接着剤を塗布する単板側接着剤塗布工程と、この単板側接着剤上に木質薄単板を積層して積層体を得る積層工程と、この積層体を熱圧プレスして積層一体化することで、化粧基材を得る第2熱圧プレス工程と、この化粧基材の表面に化粧加工を行う化粧加工工程とを含むことを特徴とする。   In the method for producing a decorative board according to claim 3, a semi-cured adhesive layer is formed by applying a base material-side adhesive having elasticity in a cured state and semi-curing the surface of the wooden substrate. An adhesive layer forming step, a paper layer laminating step of applying a paper adhesive on the semi-cured adhesive layer and placing a thin paper on the paper adhesive to laminate the paper layer; The thickness of the adhesive layer is 30 μm or more and 75 μm or less, and the hardness of the adhesive layer is 30 ° or less with a type A durometer. The first hot-pressing step, the single-plate-side adhesive applying step for applying the single-plate-side adhesive on the paper layer that has undergone the first hot-pressing step, and the wood thin unit on the single-plate-side adhesive. A laminating process for laminating plates to obtain a laminate, and laminating and integrating the laminate by hot pressing It is a second hot pressing step of obtaining a decorative substrate, characterized in that it comprises a cosmetic process step for decorative processing on the surface of the decorative substrate.

この請求項3の発明では、木質基材に基材側接着剤が塗布されて半硬化状態の接着層が形成され、この半硬化状態の接着層上に紙貼り接着剤を介して紙層が積層され、これらが熱圧プレスされて積層一体化されて、木質基材と紙材との間に基材側接着剤により接着層が形成される。さらに、紙層上に単板側接着剤が塗布されて木質薄単板が積層され、再び熱圧プレスによりこれらが積層一体化されて化粧基材が得られ、その化粧基材の表面に化粧加工が行われて化粧板が得られる。そのとき、基材側接着剤が半硬化状態となるので、基材側接着剤の木質薄単板への染み上がりが抑制される。しかも、木質基材に半硬化状態の接着層が形成され、この半硬化状態の接着層上に紙層及び木質薄単板が積層されるので、十分な厚みと柔軟性を有した接着層が介装された化粧板を得ることができ、長期的なキャスターの使用に対しても、木質薄単板の剥離が抑制される。   In this invention of Claim 3, the base material side adhesive agent is apply | coated to the woody base material, and the adhesive layer of a semi-hardened state is formed, and a paper layer is formed on this semi-hardened state adhesive layer via a paper sticking adhesive. These are laminated, these are hot-pressed and laminated and integrated, and an adhesive layer is formed between the wood base material and the paper material by the base material side adhesive. Further, the veneer side adhesive is applied on the paper layer to laminate the thin wood veneer, and these are laminated and integrated again by hot-pressing to obtain a decorative base material. Processing is performed to obtain a decorative board. At that time, since the base material side adhesive is in a semi-cured state, the base material side adhesive is prevented from seeping into the woody thin single plate. Moreover, a semi-cured adhesive layer is formed on the wood substrate, and a paper layer and a thin wood veneer are laminated on the semi-cured adhesive layer, so that an adhesive layer having sufficient thickness and flexibility can be obtained. An interposed decorative board can be obtained, and peeling of the thin wood veneer is suppressed even when the caster is used for a long time.

請求項4の発明では、上記請求項1〜3のいずれか1つの化粧板の製造方法での木質基材は合板とする。   In invention of Claim 4, the wooden base material by the manufacturing method of the decorative board of any one of the said Claims 1-3 shall be plywood.

この請求項4の発明では、木質基材としての合板に半硬化状態の接着層が形成され、この半硬化状態の接着層上に紙層及び木質薄単板が積層されるので、表面が凹凸や吸い込みムラのある合板であっても、接着層の厚みを十分に確保でき、キャスター使用時の木質薄単板の剥離を抑制することができる。   In this invention of claim 4, since the semi-cured adhesive layer is formed on the plywood as the wood substrate, and the paper layer and the wood thin veneer are laminated on the semi-cured adhesive layer, the surface is uneven. Even if it is a plywood with uneven suction, the thickness of the adhesive layer can be sufficiently secured, and peeling of the thin wood veneer when using casters can be suppressed.

請求項5の発明では、上記請求項1又は2の化粧板の製造方法において、上記熱圧プレス工程の後でかつ化粧加工工程の前に、ショットブラスト法により、木質薄単板の表面に上記単板側接着剤の木質薄単板裏面からの染み上がり部分に至る深さまで、浮造り加工を施す浮造り加工工程をさらに含むことを特徴とする。   According to a fifth aspect of the present invention, in the method for manufacturing a decorative board according to the first or second aspect, the surface of the wood thin veneer is formed by shot blasting after the hot-pressing step and before the decorative processing step. It further includes a float processing step of performing a float processing to a depth from the back of the wood thin single plate to the depth of the single plate side adhesive.

また、請求項6の発明では、上記請求項3の化粧板の製造方法において、上記第2熱圧プレス工程の後でかつ化粧加工工程の前に、ショットブラスト法により、木質薄単板の表面に上記単板側接着剤の木質薄単板裏面からの染み上がり部分に至る深さまで、浮造り加工を施す浮造り加工工程をさらに含むことを特徴とする。   In the invention of claim 6, in the method for manufacturing a decorative board according to claim 3, the surface of the wood thin veneer is formed by shot blasting after the second hot-pressing step and before the decorative processing step. In addition, the method further includes a float processing step of performing a float processing to a depth from the back of the wood thin single plate to the depth of the above-mentioned single plate side adhesive.

すなわち、上記ショットブラスト法による浮造り加工では、木質薄単板の接着剤が染み上がった部分は研削され難くなる。上記の構成によると、木質薄単板に単板側接着剤が染み上がった部分まで浮造り加工を施すことで、単板側接着剤の染み上がり量を調整して浮造り加工の凹凸深さが決定される。   In other words, in the floating process by the shot blasting method, the portion of the wood thin veneer that has oozed the adhesive becomes difficult to be ground. According to the above configuration, the depth of unevenness of the floating process is adjusted by adjusting the amount of soaking of the adhesive on the veneer side by applying the float process to the wood sheet veneer where the veneer side adhesive has soaked. Is determined.

請求項7の発明では、上記請求項5又は6の化粧板の製造方法において、上記化粧加工工程では、浮造り加工を施した木質薄単板を加熱した状態で、この木質薄単板に浮造り加工をした凹部を埋めないように透明性含浸樹脂を塗布、含浸及び硬化させることを特徴とする。こうすれば、耐傷性や化粧性に優れた化粧板が得られる。その後、この凹部に着色充填樹脂を充填し、面均一サンダーを施し、さらにこの表面に透明性塗膜層を形成することにより、表面面均一な耐傷性や化粧性に優れた化粧板を得ることできる。   According to a seventh aspect of the present invention, in the method for manufacturing a decorative board according to the fifth or sixth aspect, in the decorative processing step, the wooden thin veneer subjected to the floating process is heated and floated on the wooden thin veneer. A transparent impregnating resin is applied, impregnated, and cured so as not to fill the recessed portion that has been processed. In this way, a decorative board having excellent scratch resistance and cosmetic properties can be obtained. Then, a colored filling resin is filled in the recesses, a surface uniform sander is applied, and a transparent coating film layer is formed on the surface, thereby obtaining a decorative plate having excellent surface surface scratch resistance and cosmetic properties. it can.

以上説明したように、本発明の化粧板の製造方法によると、木質基材の表面に接着層を設け、その半硬化状態の接着層の表面に紙層を介して木質薄単板を積層一体化することにより、基材が合板であっても、安定的に十分な厚みの接着層を確保して耐キャスター性に優れるとともに、単板割れの現象が発生し難い耐傷性と化粧性に優れた化粧板が得られる。   As described above, according to the method for producing a decorative board of the present invention, an adhesive layer is provided on the surface of the wooden substrate, and the thin wooden board is laminated and integrated on the surface of the semi-cured adhesive layer via the paper layer. As a result, even if the base material is plywood, a stable and sufficient adhesive layer is ensured and caster resistance is excellent. A decorative veneer is obtained.

以下、本発明の最良の実施形態を図面に基づいて詳細に説明する。以下の好ましい実施形態の説明は、本質的に例示に過ぎず、本発明、その適用物或いはその用途を制限することを意図するものでは全くない。   Hereinafter, the best embodiment of the present invention will be described in detail with reference to the drawings. The following description of the preferred embodiments is merely exemplary in nature and is in no way intended to limit the invention, its application, or its application.

図1は本発明の実施形態に係る化粧板の製造方法の工程を、また図2はその製造方法により製造される化粧板Pをそれぞれ示し、この化粧板Pは床材として使用されるものである。   FIG. 1 shows a process of a decorative board manufacturing method according to an embodiment of the present invention, and FIG. 2 shows a decorative board P manufactured by the manufacturing method. The decorative board P is used as a flooring. is there.

(化粧板)
すなわち、図2において、1は木質基材、2は該木質基材1の表面に形成された硬化状態で弾性を有する基材側接着剤からなる接着層、3は該接着層2上に積層された薄葉紙からなる紙層、4は該紙層3上に形成された単板側接着剤層、5は該単板側接着剤層4上に積層された木質薄単板であり、これらによって化粧基材6が形成され、この化粧基材6の表面に化粧加工が施されている。
(Decorative board)
That is, in FIG. 2, 1 is a wood base material, 2 is an adhesive layer made of a base material side adhesive having elasticity in a cured state formed on the surface of the wood base material 1, and 3 is laminated on the adhesive layer 2 4 is a single plate side adhesive layer formed on the paper layer 3, and 5 is a wood thin single plate laminated on the single plate side adhesive layer 4. A decorative base 6 is formed, and a cosmetic process is applied to the surface of the decorative base 6.

(1)木質基材
木質基材1は、例えば木材でもよいし、インシュレーションボードやMDF、ハードボード等の木質繊維板でもよいし、合板、パーティクルボードでもよい。
(1) Wood base material The wood base material 1 may be, for example, wood, a wood fiber board such as an insulation board, MDF, or hard board, or a plywood or particle board.

木質基材1は、その少なくとも表面が硬質であることが望ましい。この木質基材1の表面を硬く強化する強化方法としては、単純に、表層にメラミン系樹脂、フェノール系樹脂、エポキシ系樹脂、ウレタン系樹脂やイソシアネート系樹脂を含浸させてもよいし、メラミン樹脂含浸紙、フェノール樹脂含浸紙等の各種樹脂含浸紙による強化層を表層に設けてもよい。また、樹脂含浸紙に代えて、木粉や木質繊維、木質切片等を主体とし、これらを各種樹脂と共に混練成形した硬質の人工樹脂木材や、MDF、ハードボード等の木質繊維板等の硬質な木質基材で表面を強化してもよい。   It is desirable that at least the surface of the wooden substrate 1 is hard. As a strengthening method for strongly reinforcing the surface of the wooden substrate 1, the surface layer may be simply impregnated with melamine resin, phenol resin, epoxy resin, urethane resin or isocyanate resin, or melamine resin. A reinforcing layer made of various resin-impregnated paper such as impregnated paper or phenol resin-impregnated paper may be provided on the surface layer. Also, instead of resin-impregnated paper, hard artificial resin wood mainly made of wood powder, wood fiber, wood slices, etc., and kneaded and molded with various resins, or hard wood fiber boards such as MDF, hardboard, etc. The surface may be reinforced with a wooden substrate.

また、合板等の表面にMDFやハードボード等の硬質木質基材を貼着してもよい。この場合、MDFやハードボード等は樹脂含浸強化されたものでもよい。   Moreover, you may stick hard wooden base materials, such as MDF and a hard board, on the surface, such as a plywood. In this case, the MDF, the hard board and the like may be reinforced with resin impregnation.

いずれの場合でも、軟質な木質基材1の表面は長期的かつ連続的なキャスターの使用に耐え得るように強化されている必要がある。   In any case, the surface of the soft wooden substrate 1 needs to be strengthened so that it can withstand long-term and continuous use of casters.

(2)接着層
上記接着層2は、厚みが30〜75μmであって、硬度がタイプAデュロメーターで30°以下である、軟質の基材側接着剤の硬化物で構成されている。このように、接着層2が十分な厚みと弾性とを有することにより、キャスターの長期的かつ連続的な荷重に対しても、木質薄単板5の剥離を抑制することができる。
(2) Adhesive layer The adhesive layer 2 is composed of a cured product of a soft base-side adhesive having a thickness of 30 to 75 μm and a hardness of 30 ° or less with a type A durometer. Thus, when the adhesive layer 2 has sufficient thickness and elasticity, peeling of the thin wood veneer 5 can be suppressed even for a long-term and continuous load of the caster.

接着層2となる基材側接着剤としては、例えばアクリル系樹脂、酢ビ系樹脂、ラテックス系樹脂、ゴム系樹脂、ビニルウレタン系樹脂、ウレタン系樹脂やこれらの変性物、また、これらの樹脂と尿素メラミン系樹脂、エポキシ系樹脂、フェノール系樹脂、イソシアネート系樹脂等との混合物等が好適に用いられる。   Examples of the base material side adhesive to be the adhesive layer 2 include acrylic resins, vinyl acetate resins, latex resins, rubber resins, vinyl urethane resins, urethane resins and modified products thereof, and these resins. And a mixture of urea melamine resin, epoxy resin, phenol resin, isocyanate resin and the like are preferably used.

さらに、基材側接着剤の塗布量を増やし、適正な接着剤層を形成するために、各種増粘剤や増量剤を添加して高粘度にすることが好ましい。増粘剤としては、例えば小麦粉やポバール等が使用される。また増量剤としては、炭酸カルシウム、アルミナ、酸化チタン等が使用される。また、基材側接着剤には、適宜硬化剤を添加して硬化性を促進させてもよい。その硬化剤としては熱反応型、湿気硬化型の反応開始剤を適宜添加する。   Furthermore, in order to increase the application amount of the base-side adhesive and form an appropriate adhesive layer, it is preferable to add various thickeners and extenders to increase the viscosity. As the thickener, for example, flour or poval is used. As the extender, calcium carbonate, alumina, titanium oxide or the like is used. Moreover, you may accelerate | stimulate sclerosis | hardenability by adding a hardening | curing agent suitably to a base material side adhesive agent. As the curing agent, a thermal reaction type or moisture curing type reaction initiator is appropriately added.

また、基材側接着剤には、木質基材1の隠蔽性を向上させるために、各種顔料が添加されて着色されていてもよい。   Moreover, in order to improve the concealing property of the woody base material 1, various pigments may be added and colored to the base material side adhesive.

(3)紙層
上記紙層3としては、上記基材側接着剤や後述する単板側接着剤の含浸を妨げず、プレスによって容易に基材側接着剤が紙層の表面に染み出してしまわない程度の厚みと目付量とを有する紙を用いることができる。この紙層3により、基材側接着剤の木質薄単板5への染み上がりが抑制されるとともに、該基材側接着剤及び単板側接着剤により紙層3が含浸強化されるようになっている。
(3) Paper layer As the paper layer 3, the base-side adhesive oozes out easily on the surface of the paper layer by pressing without impeding the impregnation of the base-side adhesive and the single-plate-side adhesive described below. Paper having a thickness and weight per unit area that does not streak can be used. The paper layer 3 suppresses the penetration of the base material side adhesive into the woody thin veneer 5, and the paper layer 3 is impregnated and strengthened by the base material side adhesive and the veneer side adhesive. It has become.

一般的に使用される耐クラック用薄葉紙は、厚さ30〜60μm程度、目付量25〜40g/m程度のもので、方向性があり、長手方向に平行になるように繊維方向が向いている。この場合、一般的なクラック(表面割れ)を防ぐためには、この繊維方向を合板からなる基材1と直交する方向に向ける。しかし、長手方向が3mや4m等の長尺の化粧板を製造する場合には、このような長さの幅を持つ紙を得ることができない。 The crack-resistant thin paper generally used has a thickness of about 30 to 60 μm and a weight per unit area of about 25 to 40 g / m 2 , has directionality, and the fiber direction is parallel to the longitudinal direction. Yes. In this case, in order to prevent general cracks (surface cracks), the fiber direction is directed in a direction orthogonal to the base material 1 made of plywood. However, when a long decorative board having a longitudinal direction of 3 m or 4 m is manufactured, paper having such a width cannot be obtained.

そこで、紙の厚みを増したものを使い、繊維方向を平行にする。この場合、特に長網式抄造により製造された方向性の少ない紙を使用するのが好ましい。このような方向性の少ない紙は方向性のある紙より強度が小さいため、ある程度の厚みと目付け量とが必要である。さらに、パルプに化学繊維を混合させるとより好ましい。具体的には、パルプとレーヨンとの比率が7:3又は5:5程度で、厚みが70〜120μm程度、目付量が30〜50g/m程度で長網式抄造で製造された紙を好適に使用する。 Therefore, using a paper with increased thickness, the fiber directions are parallel. In this case, it is preferable to use a paper having a low directionality produced by long net-type papermaking. Since such a paper with less directionality has a lower strength than paper with directionality, a certain amount of thickness and weight per unit area are required. Furthermore, it is more preferable to mix chemical fiber with pulp. Specifically, a paper produced by long net-making with a ratio of pulp to rayon of about 7: 3 or 5: 5, a thickness of about 70 to 120 μm, and a basis weight of about 30 to 50 g / m 2. Preferably used.

(4)単板側接着剤層
上記紙層3の上には、紙層3と木質薄単板5とを強固に接着させるために硬質の単板側接着剤を塗布して単板側接着剤層4を形成し、この単板側接着剤層4によって紙層3と木質薄単板5とを接合一体化することが好ましい。
(4) Veneer side adhesive layer A hard veneer side adhesive is applied on the paper layer 3 to firmly adhere the paper layer 3 and the thin wood veneer 5 to the veneer side. It is preferable that the agent layer 4 is formed and the paper layer 3 and the wood thin veneer 5 are joined and integrated by the veneer side adhesive layer 4.

上記単板側接着剤は、木質基材1と紙層3と木質薄単板5とが積層された積層物を熱圧プレスして積層一体化する際に、所望の強度が実現できるものが好ましい。   The above single veneer-side adhesive is capable of realizing a desired strength when the laminated body in which the wood base material 1, the paper layer 3, and the wood thin veneer 5 are laminated by hot pressing. preferable.

具体的には、単板側接着剤としては、例えばアクリル系樹脂、酢ビ系樹脂、ラテックス系樹脂、ゴム系樹脂、ビニルウレタン系樹脂、ウレタン系樹脂やこれらの変性樹脂、尿素メラミン系樹脂、エポキシ系樹脂、フェノール系樹脂、イソシアネート系樹脂等及びこれらの樹脂の混合物等が用いられる。化粧板Pの使用時における乾湿による単板の割れを効果的に抑制するためには、単板側接着剤として、尿素メラミン系樹脂やイソシアネート系樹脂等の硬化物が硬質である接着剤を主剤として用いることが好ましい。また、単板側接着剤には、基材側接着剤と同様に、適宜硬化剤を添加して硬化性を促進させてもよい。   Specifically, as the single plate side adhesive, for example, acrylic resin, vinyl acetate resin, latex resin, rubber resin, vinyl urethane resin, urethane resin and their modified resins, urea melamine resin, Epoxy resins, phenol resins, isocyanate resins, etc., and mixtures of these resins are used. In order to effectively suppress cracking of the veneer due to dry and wet conditions when using the decorative board P, an adhesive having a hardened product such as urea melamine-based resin or isocyanate-based resin as a main veneer side adhesive is used as a main agent. It is preferable to use as. Moreover, you may accelerate | stimulate sclerosis | hardenability by adding a hardening | curing agent suitably to a veneer-side adhesive like a base material side adhesive.

上記単板側接着剤の塗布量は、木質薄単板5への染み上がりを抑制するために必要最低限の量であることが好ましい。すなわち、単板側接着剤の木質薄単板5への染み上がりは、木質薄単板5の厚みの50%以下であることが好ましく、染み上がり量をこのように抑えることにより、後述するショットブラスト法による浮造り加工を効果的に行うことができる。   The amount of the single-plate adhesive applied is preferably the minimum amount necessary to prevent the wood thin single plate 5 from spreading. That is, it is preferable that the amount of stain on the wood thin veneer 5 of the veneer side adhesive is 50% or less of the thickness of the wood thin veneer 5, and by controlling the amount of stain in this way, a shot to be described later Floating process by the blast method can be performed effectively.

そして、上記紙層3は、基材側接着剤及び単板側接着剤が表裏両方から含浸することで、その全体が含浸強化されている。   The entire paper layer 3 is impregnated and strengthened by impregnating the base material side adhesive and the veneer side adhesive from both the front and back sides.

(5)木質薄単板
木質薄単板5としては、天然木質材や、これらの積層物をスライスした薄切片を使用することができる。天然木質材は、針葉樹、広葉樹、いわゆる早生樹等、どのようなものでも使用することができる。また、天然木質材の積層物をスライスしたものとは、いわゆる人工突板といわれるものである。
(5) Wood thin veneer As the wood thin veneer 5, a natural wood material or a thin slice obtained by slicing these laminates can be used. As the natural wood material, any material such as conifers, broad-leaved trees, so-called fast-growing trees can be used. Moreover, what sliced the laminated body of natural wooden material is what is called an artificial veneer.

また、木質薄単板5には、乾燥単板や生単板(いわゆる濡れ単板)を使用することができる。木質薄単板5の厚みが厚過ぎると、硬くなるだけでなく、単板5自体の耐干割れ性が悪くなってしまうので、木質薄単板5の厚みは、0.15〜1.0mm程度が好ましく、後の浮造り工程を考慮すると、より好ましくは0.25〜0.6mm程度の厚みがよい。   In addition, the wood thin veneer 5 can be a dry veneer or a raw veneer (so-called wet veneer). If the thickness of the wood thin veneer 5 is too thick, not only will it become hard, but the resistance to dry cracking of the veneer 5 itself will deteriorate, so the thickness of the wood thin veneer 5 is 0.15 to 1.0 mm. The degree is preferable, and the thickness of about 0.25 to 0.6 mm is more preferable in consideration of the subsequent floating process.

(製造方法)
次に、本発明の実施形態に係る化粧板の製造方法について説明する。この製造方法は、図1に示すように、接着層形成工程、紙層積層工程、単板側接着剤塗布工程、積層工程、熱圧プレスエ程、浮造り加工工程及び化粧加工工程を含んでいる。
(Production method)
Next, the manufacturing method of the decorative board which concerns on embodiment of this invention is demonstrated. As shown in FIG. 1, this manufacturing method includes an adhesive layer forming step, a paper layer laminating step, a veneer side adhesive applying step, a laminating step, a hot press process, a float forming step, and a cosmetic processing step. .

(1)接着層形成工程
まず、上記木質基材1上に基材側接着剤を塗布し、その基材側接着剤を半硬化させることで、半硬化状態の接着層2を形成する。基材側接着剤を塗布する手段としては、フローコーター又はロールコーターが好適に用いられる。この基材側接着剤によって、30〜75μmの厚みの接着層2が形成されるように塗布する。
(1) Adhesive layer formation process First, the base material side adhesive agent is apply | coated on the said wooden base material 1, The adhesive layer 2 of a semi-hardened state is formed by semi-hardening the base material side adhesive agent. As a means for applying the substrate side adhesive, a flow coater or a roll coater is preferably used. It applies so that the adhesive layer 2 of 30-75 micrometers thickness may be formed with this base material side adhesive agent.

基材側接着剤を半硬化させる方法としては、例えば熱硬化型接着剤を使用した場合は、赤外線や通風ドライヤー等の加熱手段を用いる。また、例えば紫外線硬化型の接着剤を使用した場合は、湿気硬化型や熱硬化型の反応開始剤を併用し、紫外線照射により半硬化状態とする。   As a method of semi-curing the substrate side adhesive, for example, when a thermosetting adhesive is used, heating means such as infrared rays or a ventilating dryer is used. Further, for example, when an ultraviolet curable adhesive is used, a moisture curable or thermosetting reaction initiator is used in combination, and a semi-cured state is obtained by ultraviolet irradiation.

半硬化状態とは、液体状の接着剤が存在しない程度に硬化が進んだ状態であって、例えば接着剤の表面のみが皮膜硬化し、中に硬化していない液体状の接着剤が存在する状態は含まない。接着剤の全体的なゲル化が終了しており、かつ熱圧プレス工程により表面の木質薄単板5を接着することが可能な状態のことをいう。   The semi-cured state is a state where curing has progressed to the extent that no liquid adhesive is present, for example, only the surface of the adhesive is film-cured and there is an uncured liquid adhesive. Does not include state. It means a state in which the entire gelation of the adhesive has been completed and the surface thin wood veneer 5 can be bonded by a hot press process.

例えば熱による半硬化の場合は、加熱温度や加熱時間により適宜調整する。また、例えば紫外線照射による半硬化の場合は、紫外線照射量や紫外線照射時間により適宜調整する。   For example, in the case of semi-curing by heat, the temperature is appropriately adjusted depending on the heating temperature and the heating time. For example, in the case of semi-curing by ultraviolet irradiation, the amount is appropriately adjusted depending on the ultraviolet irradiation amount and the ultraviolet irradiation time.

硬化が足りないと、適正な接着層2の厚みを確保できないため、耐キャスター性に劣る化粧板となってしまう。また、硬化が進み過ぎると接着層2と木質薄単板5との接着が悪く、耐キャスター試験や耐熱乾燥試験により、様々な不具合が発生する。   If the curing is insufficient, an appropriate thickness of the adhesive layer 2 cannot be ensured, resulting in a decorative board having inferior caster resistance. Moreover, when hardening progresses too much, adhesion | attachment with the contact bonding layer 2 and the thin wood board 5 will be bad, and various malfunction will generate | occur | produce by a caster-proof test and a heat-resistant drying test.

(2)紙層積層工程
次に、上記半硬化状態の接着層2上に薄葉紙を載置して紙層3を積層する。尚、半硬化状態の接着層2上に紙貼り接着剤を塗布し、その紙貼り接着剤上に薄葉紙を載置して紙層3を積層することもできる。
(2) Paper Layer Laminating Step Next, a thin paper is placed on the semi-cured adhesive layer 2 to laminate the paper layer 3. The paper layer 3 can also be laminated by applying a paper adhesive on the semi-cured adhesive layer 2 and placing thin paper on the paper adhesive.

また、この紙層積層工程の後に、上記木質基材1、接着層2及び紙層3を予め熱圧プレスして積層一体化してもよい(第1熱圧プレス工程)。熱圧プレスの方法は、一般的なロールプレスや平板プレス等、様々な方法があるが、好ましくは平板プレスが使用される。熱圧プレスは、100〜130℃でかつ0.2〜1.0MPaの条件下で、30〜90秒程度行われる。これにより、基材側接着剤が完全に硬化され、接着層2の厚みが30μm以上でかつ75μm以下であるとともに、接着層2の硬度がタイプAデュロメーターで30°以下となる。第1熱圧プレス工程後は、冷却して養生させることが望ましい。   Further, after the paper layer laminating step, the wood substrate 1, the adhesive layer 2 and the paper layer 3 may be preliminarily hot-pressed to be laminated and integrated (first hot-pressing step). There are various hot pressing methods such as a general roll press and a flat plate press, and a flat plate press is preferably used. The hot press is performed for 30 to 90 seconds at 100 to 130 ° C. and 0.2 to 1.0 MPa. Thereby, the base material side adhesive is completely cured, the thickness of the adhesive layer 2 is 30 μm or more and 75 μm or less, and the hardness of the adhesive layer 2 is 30 ° or less with a type A durometer. After the first hot press process, it is desirable to cool and cure.

(3)単板側接着剤塗布工程
上記紙層3上に単板側接着剤を塗布して単板側接着剤層4を形成する。単板側接着剤を塗布する塗布手段は特に限定されない。目的とする単板側接着剤の塗布量に応じた塗布方法を選択すればよく、例えばロールコーターやフローコーター、スプレー等が好適である。
(3) Single-plate-side adhesive application step A single-plate-side adhesive layer 4 is formed by applying a single-plate-side adhesive on the paper layer 3. The application means for applying the veneer side adhesive is not particularly limited. What is necessary is just to select the application | coating method according to the application quantity of the target single-plate side adhesive agent, for example, a roll coater, a flow coater, a spray etc. are suitable.

(4)積層工程
次に、単板側接着剤層4上に木質薄単板5を積層して積層体を得る。載置した木質薄単板5は仮固定してもよい。仮固定の方法としては、高周波等で仮固定部分の水分を飛ばし、単板側接着剤を固化させる方法が好適に用いられる。
(4) Lamination process Next, the thin wood veneer 5 is laminated | stacked on the veneer side adhesive bond layer 4, and a laminated body is obtained. The wood thin veneer 5 placed may be temporarily fixed. As a method for temporary fixing, a method in which moisture in the temporarily fixed portion is blown off by high frequency or the like and the single plate side adhesive is solidified is preferably used.

(5)熱圧プレス工程
さらに、上記積層体を熱圧プレスして積層一体化して化粧基材6を得る。上記紙層積層工程の後に、木質基材1、接着層2及び紙層3を熱圧プレスして積層一体化した場合(第1熱圧プレス工程を経た場合)も、単板側接着剤を介して木質薄単板5を積層した後にもう一度熱圧プレスする(第2熱圧プレス工程)。熱圧プレスの方法は、上述した方法と同じである。これにより、基材側接着剤及び単板側接着剤が完全に硬化される。
(5) Hot-pressing step Further, the laminate is hot-pressed and laminated and integrated to obtain a decorative base 6. Even after the paper layer laminating step, the wood base material 1, the adhesive layer 2 and the paper layer 3 are hot-pressed and laminated and integrated (when the first hot-pressing step is performed), the veneer side adhesive is also used. Then, after the wood thin veneer 5 is laminated, hot pressing is performed again (second hot pressing process). The method of hot pressing is the same as the method described above. Thereby, the base material side adhesive and the veneer side adhesive are completely cured.

このとき、単板側接着剤の木質薄単板5への染み上がりは、木質薄単板5の厚みの50%以下となっている。   At this time, the stain on the wood thin veneer 5 of the veneer side adhesive is 50% or less of the thickness of the wood thin veneer 5.

(6)浮造り加工工程
次に、上記化粧基材6の表面に、単板側接着剤の木質薄単板5裏面からの染み上がり部分に至る深さまで、ショットブラスト法による浮造り加工を施す。ショットブラスト法とは、硬質で微細なブラスト用研磨材を木質薄単板5の表面に衝突させて表面に微細な傷を付ける加工である。これにより、木質薄単板5の軟らかい部分が研削され、硬い部分が残り、表面に凹凸を有する化粧基材6を得ることができる。
(6) Floating process Next, the surface of the decorative base 6 is subjected to a floating process by shot blasting to the depth from the back of the wood sheet veneer 5 of the veneer side adhesive to the part that has penetrated. . The shot blasting process is a process in which a hard and fine blasting abrasive is made to collide with the surface of the thin wood veneer 5 to make fine scratches on the surface. Thereby, the soft part of the wood thin veneer 5 is ground, a hard part remains, and the decorative base material 6 which has an unevenness | corrugation on the surface can be obtained.

ブラスト用研磨材としては、ガラスビーズ、ガラスパウダー、ケイ素質等の無機質粒子、アルミナ等の金属粒子、胡桃や桃の種等を粉砕した硬質有機粒子、或いはドライアイスを細かく粉砕したドライアイス粒子等が用いられる。このようなブラスト用研磨材をノズルから噴出させ、化粧基材6の表面に衝突させて浮造り加工を施す。尚、化粧基材6に必ず浮造り加工を施す必要はない。   As abrasives for blasting, glass beads, glass powder, inorganic particles such as silicon, metal particles such as alumina, hard organic particles pulverized with walnuts and peach seeds, or dry ice particles pulverized with dry ice Is used. Such an abrasive for blasting is ejected from the nozzle and is made to collide with the surface of the decorative substrate 6 to carry out a floating process. Note that the decorative base 6 does not necessarily have to be floated.

(7)化粧加工工程
最後に、上記浮造り加工が施された又は施されていない化粧基材6の表面に様々な化粧加工を施して化粧板を得る。例えば浮造り加工された表面に着色を施し、この上に、浮造り加工による凹凸加工を充填しない程度の薄膜で均一な透明塗膜層を設けてもよい。
(7) Cosmetic processing step Finally, various decorative processings are applied to the surface of the decorative base 6 with or without the float processing to obtain a decorative board. For example, the surface that has been float-processed may be colored, and a uniform transparent coating layer may be provided on the surface that is thin enough not to fill the unevenness by the float-process.

さらに、別の方法としては、上記ショットブラスト法により含浸性が上がった木質薄単板5に浸透性樹脂を塗布含浸させ、紫外線硬化や電子線硬化、熱硬化等させることにより木質薄単板5中に樹脂を含浸硬化させ、さらに、この表面に浮造り加工による凹凸加工を充填しない程度の薄膜で均一な透明塗膜層を設けてもよい。   Furthermore, as another method, the wood thin veneer 5 is coated and impregnated with a permeable resin on the wood veneer 5 that has been improved in impregnation by the shot blasting method, and then cured by ultraviolet curing, electron beam curing, heat curing, or the like. The resin may be impregnated and cured, and a uniform transparent coating layer may be provided on the surface with a thin film that does not fill the surface with unevenness by floating.

また、別の方法としては、上記ショットブラスト法により含浸性が上がった木質薄単板5に浸透性樹脂を塗布含浸させ、紫外線硬化や電子線硬化、熱硬化等させることにより木質薄単板5中に樹脂を含浸硬化させる。さらに、この表面に浮造り加工による凹凸加工を充填する程度に透明性着色充填樹脂を充填し、紫外線硬化や電子線硬化、熱硬化等させることにより面均一にする。この面均一な表面に透明性樹脂により薄膜で均一な透明塗膜層を設けてもよい。   As another method, the wood thin veneer 5 is made by applying and impregnating a permeable resin to the wood thin veneer 5 having improved impregnation property by the shot blasting method, followed by ultraviolet curing, electron beam curing, heat curing or the like. The resin is impregnated and cured. Further, a transparent colored filling resin is filled to such an extent that the surface is filled with unevenness processing by floating processing, and the surface is made uniform by ultraviolet curing, electron beam curing, heat curing or the like. A uniform transparent coating film layer with a thin film may be provided on the uniform surface by a transparent resin.

これらの場合、浸透性樹脂、透明性着色充填樹脂、透明性樹脂等としては、アクリル系、ウレタン系、エポキシ系、ポリエステル系、ビニルウレタン系、酢ビ系、尿素−メラミン系、フェノール系、イソシアネート系の樹脂やこれらの変性物や混合物が使用される。   In these cases, the permeable resin, the transparent colored filling resin, the transparent resin, etc. include acrylic, urethane, epoxy, polyester, vinyl urethane, vinyl acetate, urea-melamine, phenol, isocyanate. System resins and their modified products and mixtures are used.

特に、浮造り加工を施した透明性着色充填樹脂としては、これらに光開始剤やイソシアネート系の湿気硬化型樹脂を添加することにより、湿気硬化特性と紫外線硬化特性とを付与するのが好ましい。   In particular, as a transparent colored filling resin subjected to a float process, it is preferable to add moisture curing properties and ultraviolet curing properties by adding a photoinitiator or an isocyanate moisture curing resin to them.

(実施形態の効果)
このように、本発明の実施形態に係る製造方法によると、製造された化粧板Pは、接着層2が30μm以上でかつ75μm以下の厚みを有し、タイプAデュロメーターで30°以下の硬度となり弾性を有するので、柔軟でかつ十分な厚みを有する接着層2が木質基材1と木質薄単板5との間に介装されることになる。また、化粧板Pの製造の際に木質基材1に半硬化状態の接着層2を形成して、その半硬化状態の接着層2上に紙層3及び木質薄単板5を積層するので、木質基材1が表面に凹凸や吸い込みムラのある合板であったとしても、上記接着層2の厚みを十分に確保することができる。これらの結果、化粧板Pは、長期的かつ連続的にキャスターを使用しても、その応力が分散されて木質薄単板5の剥離を効果的に抑制することができる。
(Effect of embodiment)
Thus, according to the manufacturing method according to the embodiment of the present invention, the manufactured decorative board P has a thickness of 30 μm or more and 75 μm or less, and a hardness of 30 ° or less with a type A durometer. Since it has elasticity, the adhesive layer 2 that is flexible and has a sufficient thickness is interposed between the wood base material 1 and the wood thin veneer 5. In addition, when the decorative board P is manufactured, the semi-cured adhesive layer 2 is formed on the wooden substrate 1, and the paper layer 3 and the thin wood veneer 5 are laminated on the semi-cured adhesive layer 2. Even if the wooden substrate 1 is a plywood having irregularities and suction unevenness on the surface, the thickness of the adhesive layer 2 can be sufficiently ensured. As a result, even if the decorative board P uses a caster for a long period of time, the stress is dispersed and the peeling of the wood thin veneer 5 can be effectively suppressed.

また、接着層2と木質薄単板5との間に紙層3を設けたことにより、この紙層3で接着層2となる基材側接着剤を含浸して、木質薄単板5への基材側接着剤の染み上がりを抑制することができる。   Further, by providing the paper layer 3 between the adhesive layer 2 and the wood thin veneer 5, the paper layer 3 is impregnated with the base material side adhesive to be the adhesive layer 2, and the wood thin veneer 5 is obtained. Suppression of the base material side adhesive can be suppressed.

また、紙層3と木質薄単板5とを単板側接着剤により接合一体化するので、紙層3と木質薄単板5とが強固に接着されるとともに、紙層3の全体に基材側接着剤と単板側接着剤が含浸して含浸強化される。   In addition, since the paper layer 3 and the wood thin veneer 5 are joined and integrated by the veneer-side adhesive, the paper layer 3 and the wood thin veneer 5 are firmly bonded, and the paper layer 3 is based on the whole. The material side adhesive and the veneer side adhesive are impregnated and reinforced.

また、基材側接着剤の木質薄単板5への染み上がりを抑制するとともに、単板側接着剤の木質薄単板5への染み上がりの抑制も考慮することで、この化粧板にショットブラスト法により浮造り加工を施した場合に、ムラが生じ難くなり、意匠性に優れた化粧板Pを得ることができる。   In addition, while suppressing the spread of the base material side adhesive to the woody thin veneer 5 and taking into account the suppression of the veneering of the veneer side adhesive to the woody thin veneer 5, this decorative board is shot. When the floating process is performed by the blast method, unevenness hardly occurs and the decorative board P having excellent design properties can be obtained.

また、単板側接着剤の木質薄単板5への染み上がりを木質薄単板5の厚みの50%以下とすることで、木質薄単板5の表面への単板側接着剤の染み上がりがないだけでなく、ショットブラスト法による浮造り加工の際、より確実にムラの発生を抑制することができ、意匠性により一層優れた化粧板Pを得ることができる。   Moreover, the stain of the veneer side adhesive on the surface of the wood thin veneer 5 is made less than 50% of the thickness of the wood thin veneer 5 by making the stain on the veneer thin veneer 5 less than 50% of the thickness of the wood veneer 5 Not only is there no rise, but also the occurrence of unevenness can be more reliably suppressed during the float-making process by the shot blast method, and a decorative board P that is more excellent in design can be obtained.

さらに、木質薄単板5への単板側接着剤の染み上がり部分まで浮造り加工を施すことによって、単板側接着剤の染み上がり量を調整することで浮造り加工の凹凸深さを決定することができるので、効果的に浮造り加工を施すことができる。   Furthermore, the depth of unevenness of the float-making process is determined by adjusting the amount of soaking of the adhesive on the veneer side by applying the float process to the wood sheet veneer 5 where the veneer-side adhesive has spread. Therefore, it is possible to effectively carry out floating processing.

次に、具体的に実施した実施例について説明する。   Next, specific examples will be described.

(実施例1)
複数の単板が互いに直交するように積層され、表層の単板が長手方向に配置された厚さ11.5mmの基材合板を310×1850mmの矩形に切断した。この基材合板の表面にエチレン酢ビ系の軟質の基材接着剤を100g/m塗布した後、ドライヤーにより60℃の温度で通風して10分間養生し、半硬化させて接着層を形成した。これを冷却し、その接着層の表面にメラミン系の紙貼り接着剤を77g/m塗布して、その上に目付量が25g/mの薄葉紙を載置し、さらに単板側接着剤としてメラミン系の硬質接着剤を77g/m塗布した。
Example 1
A substrate plywood having a thickness of 11.5 mm, in which a plurality of single plates were stacked so as to be orthogonal to each other and the surface single plates were arranged in the longitudinal direction, was cut into a rectangle of 310 × 1850 mm. After applying 100 g / m 2 of an ethylene vinyl based soft base adhesive to the surface of this base plywood, it is ventilated with a dryer at a temperature of 60 ° C. for 10 minutes and semi-cured to form an adhesive layer. did. This is cooled, 77 g / m 2 of melamine paper adhesive is applied to the surface of the adhesive layer, and a thin paper with a basis weight of 25 g / m 2 is placed thereon. As a coating, 77 g / m 2 of a melamine-based hard adhesive was applied.

この上に厚さ0.25mmでかつ気乾含水率(7%)の米栂の板目木質薄単板を載置し、熱圧プレス(120℃、50秒、0.8MPa)にて接着を行い、化粧基材を得た。   On top of this, a wood grain thin veneer of rice bran having a thickness of 0.25 mm and an air dry moisture content (7%) is placed, and bonded by a hot press (120 ° C., 50 seconds, 0.8 MPa). The cosmetic base material was obtained.

この化粧基材表面を観察したところ、単板割れがなく良好な状況であった。この表面に水系着色剤を塗布し、乾燥後、さらに、この表面にアクリル系の紫外線硬化型塗料により、表面に面均一な薄膜の透明塗膜層を設けた。   When this decorative base material surface was observed, there was no single plate cracking and it was in a good situation. A water-based colorant was applied to the surface, and after drying, a transparent coating layer having a uniform surface was formed on the surface with an acrylic ultraviolet curable coating.

この表面に対し耐キャスター試験を行ったところ、化粧板表面の凹み量は0.1mm程度で、大きな問題はなかった。さらに、試験後の単板の剥離等も観察されなかった。また、耐熱乾燥試験(80℃・24時間)を行ったところ、全く問題はなかった。   When a caster resistance test was performed on this surface, the amount of dents on the surface of the decorative board was about 0.1 mm, and there was no major problem. Furthermore, peeling of the veneer after the test was not observed. Moreover, when the heat-resistant drying test (80 degreeC * 24 hours) was done, there was no problem at all.

(実施例2)
実施例1で得られる化粧基材にショットブラスト加工を施し、表面の軟質部分を研削して浮造り加工を施した。この表面に浮造り加工による凹凸を充填しない程度にアクリル系の紫外線硬化型塗料により、表面に面均一な薄膜の透明塗膜層を設けた。
(Example 2)
The decorative base material obtained in Example 1 was subjected to shot blasting, and the soft part of the surface was ground to carry out floating processing. A transparent coating layer of a thin film with a uniform surface was provided on the surface with an acrylic UV-curing paint to such an extent that the surface was not filled with irregularities due to the floating process.

この表面に対し耐キャスター試験を行った。浮造り加工を行っているため、凹み量の測定はできなかったが、試験後の単板の剥離等の不具合は観察されなかった。また、耐熱乾燥試験(80℃・24時間)を行ったところ、全く問題はなかった。   A caster resistance test was performed on this surface. Since the float process was performed, the amount of dents could not be measured, but defects such as peeling of the veneer after the test were not observed. Moreover, when the heat-resistant drying test (80 degreeC * 24 hours) was done, there was no problem at all.

(実施例3)
実施例1で得られる化粧基材にショットブラスト加工を施し、表面の軟質部分を研削して浮造り加工を施した。この化粧基材を表面温度が40℃になるように調整し、表面に透明性浸透樹脂を100g/mを塗布含浸させた。この透明性浸透樹脂は、エポキシアクリレート40質量部、トリプロピレングリコールジアクリレート30質量部、2−ヒドロキシプロピルメタクリレート30質量部、ヘキサメチレンジイソシアネート20質量部、ポリオール10質量部、染料0.5質量部、2−ヒドロキシ−2−メチルー1−フェニループロパンー1−オン3質量部を配合したものである。
(Example 3)
The decorative base material obtained in Example 1 was subjected to shot blasting, and the soft part of the surface was ground to carry out floating processing. The decorative substrate was adjusted so that the surface temperature was 40 ° C., and 100 g / m 2 of transparent penetrating resin was applied and impregnated on the surface. This transparent penetrating resin comprises 40 parts by weight of epoxy acrylate, 30 parts by weight of tripropylene glycol diacrylate, 30 parts by weight of 2-hydroxypropyl methacrylate, 20 parts by weight of hexamethylene diisocyanate, 10 parts by weight of polyol, 0.5 parts by weight of dye, 2-hydroxy-2-methyl-1-phenyl-propan-1-one (3 parts by mass) is blended.

その後、60秒間放置して、全ての含浸樹脂が浸透した後に紫外線を照射し、単板内の樹脂を硬化させた。さらに、浮造り加工による凹凸を充填する程度にゴムコー夕ーで塗布した後に、鉄製のリバースコーターで面均一になる程度に透明性着色充填樹脂を充填して面均一とした。この透明性着色充填樹脂は、エポキシアクリレート30質量部、トリプロピレングリコールジアクリレート40質量部、アクリロイルモルフォリン5質量部、ヘキサメチレンジイソシアネート5質量部、染料0.7質量部、ビスアシルフォスフィンオン0.7質量部、2−ヒドロキシ−2−メチルー1−フェニループロパンー1−オン3質量部を配合したものである。   Then, it was allowed to stand for 60 seconds, and after all the impregnating resin had permeated, it was irradiated with ultraviolet rays to cure the resin in the single plate. Furthermore, after coating with a rubber coater to the extent that the irregularities due to the float process were filled, the surface was made uniform by filling with a transparent colored filling resin to the extent that the surface was uniform with an iron reverse coater. This transparent colored filler resin comprises 30 parts by weight of epoxy acrylate, 40 parts by weight of tripropylene glycol diacrylate, 5 parts by weight of acryloylmorpholine, 5 parts by weight of hexamethylene diisocyanate, 0.7 parts by weight of dye, bisacylphosphine 0 0.7 parts by mass and 3 parts by mass of 2-hydroxy-2-methyl-1-phenyl-propan-1-one.

この表面に紫外線照射を行い、透明性着色充填樹脂を硬化させた。さらに、表面全体に面均一サンダーを施した後、この表面に面均一な薄膜の透明塗膜層を設けた。   This surface was irradiated with ultraviolet rays to cure the transparent colored filling resin. Furthermore, after the surface uniform sander was given to the whole surface, the transparent coating layer of the thin film with a uniform surface was provided in this surface.

この表面を耐キャスター試験を行ったところ、凹み量は0.08mmで問題はなかった。また、試験後の単板の剥離等の不具合は観察されなかった。また、耐熱乾燥試験(80℃・24時間)を行ったところ、全く問題はなかった。   When this surface was subjected to a caster resistance test, the dent amount was 0.08 mm, and there was no problem. In addition, defects such as peeling of the single plate after the test were not observed. Moreover, when the heat-resistant drying test (80 degreeC * 24 hours) was done, there was no problem at all.

(比較例1)
上記実施例1において、紙貼り接着剤及び薄葉紙を用いない以外は同じ条件で化粧基材を得た。
(Comparative Example 1)
In the said Example 1, the cosmetic base material was obtained on the same conditions except not using a paper sticking adhesive and a thin paper.

この化粧基材表面を観察したところ、木質薄単板表面からは接着剤が染み出しており、一方、所々で単板割れ(クラック)が発生しており、木質薄単板の割れ目から接着剤層が露出していた。   When the surface of this decorative base material was observed, the adhesive oozed out from the surface of the thin wood veneer, and on the other hand, the veneer cracks (cracks) occurred in some places. The layer was exposed.

この化粧基材の表面に水系着色剤を塗布し、乾燥後、さらに、この表面にアクリル系の紫外線硬化型塗料により、表面に面均一な薄膜の透明塗膜層を設けた。この場合、特に単板割れした部分から接着剤層が所々露出した、意匠性の悪い化粧材しか得ることはできなかった。   A water-based colorant was applied to the surface of this decorative substrate, and after drying, a transparent coating layer having a uniform surface was provided on the surface with an acrylic ultraviolet curable coating. In this case, it was only possible to obtain a decorative material with poor design, in which the adhesive layer was exposed in some parts from the part where the single plate was broken.

この表面を耐キャスター試験を行った。化粧板表面の凹み量は0.1mm程度で、大きな問題はなかった。また、耐熱乾燥試験(80℃・24時間)を行ったところ、透明塗膜層表面の所々にクラック(塗膜割れ)が発生していた。   This surface was subjected to a caster resistance test. The amount of dents on the decorative plate surface was about 0.1 mm, and there was no major problem. Moreover, when the heat-resistant drying test (80 degreeC * 24 hours) was conducted, the crack (coating film crack) had generate | occur | produced in the places of the transparent coating-film layer surface.

(比較例2)
実施例1において、基材接着剤を半硬化させない(上記60℃の通風により10分間養生して半硬化させた後に冷却し、接着剤層表面にメラミン系の紙貼り接着剤を77g/m塗布しする処理を行わない)以外は同じ条件で化粧基材を得た。この化粧基材表面を観察したところ、好適な意匠外観の化粧基材を得ることができた。
(Comparative Example 2)
In Example 1, the base material adhesive is not semi-cured (cured for 10 minutes by ventilation at 60 ° C. and then semi-cured and then cooled, and 77 g / m 2 of melamine-based paper adhesive is applied to the surface of the adhesive layer. A cosmetic base material was obtained under the same conditions except that the coating process was not performed. When the surface of this decorative base material was observed, a decorative base material having a suitable design appearance could be obtained.

この化粧基材の表面に水系着色剤を塗布し、乾燥後、さらに、この表面にアクリル系の紫外線硬化型塗料により、表面に面均一な薄膜の透明塗膜層を設けた。   A water-based colorant was applied to the surface of this decorative substrate, and after drying, a transparent coating layer having a uniform surface was provided on the surface with an acrylic ultraviolet curable coating.

また、耐熱乾燥試験(80℃・24時間)を行ったところ、全く問題はなかった。   Moreover, when the heat-resistant drying test (80 degreeC * 24 hours) was done, there was no problem at all.

しかし、この表面に対し耐キャスター試験を行ったところ、化粧板表面の単板に剥離が見られた。剥離部分の断面を観察すると、接着剤層が一番薄いところで、15μmしか形成されていなかった。   However, when a caster resistance test was conducted on this surface, peeling was observed on the veneer surface. When the cross section of the peeled portion was observed, only 15 μm was formed where the adhesive layer was the thinnest.

本発明は、耐キャスター性に優れた床材として利用される化粧板の製造方法において極めて有用であり、産業上の利用可能性が高い。   INDUSTRIAL APPLICATION This invention is very useful in the manufacturing method of a decorative board utilized as a flooring excellent in caster resistance, and its industrial applicability is high.

図1は、本発明の実施形態に係る化粧板の製造方法を示す工程図である。FIG. 1 is a process diagram showing a method for manufacturing a decorative board according to an embodiment of the present invention. 図2は、製造される化粧板の断面図である。FIG. 2 is a cross-sectional view of a decorative board to be manufactured.

符号の説明Explanation of symbols

P 化粧板
1 木質基材
2 接着層
3 紙層
4 単板側接着剤層
5 木質薄単板
6 化粧基材
P veneer 1 wood substrate 2 adhesive layer 3 paper layer 4 veneer side adhesive layer 5 wood thin veneer 6 veneer substrate

Claims (7)

木質基材の表面に木質薄単板を、接着剤を介して熱圧プレスにて積層一体化する化粧板の製造方法であって、
上記木質基材の表面に、硬化状態で弾性を有する基材側接着剤を塗布して半硬化させることで、半硬化状態の接着層を形成する接着層形成工程と、
上記半硬化状態の接着層上に薄葉紙を載置して紙層を積層する紙層積層工程と、
上記紙層上に単板側接着剤を塗布する単板側接着剤塗布工程と、
上記単板側接着剤上に上記木質薄単板を積層して積層体を得る積層工程と、
上記積層体を熱圧プレスして積層一体化することで、上記接着層の厚みが30μm以上でかつ75μm以下であるとともに、該接着層の硬度がタイプAデュロメーターで30°以下となる化粧基材を得る熱圧プレスエ程と、
上記化粧基材の表面に化粧加工を行う化粧加工工程と
を含むことを特徴とする化粧板の製造方法。
A method for producing a decorative board, in which a wood thin veneer is laminated on a surface of a wood substrate by a hot press through an adhesive,
An adhesive layer forming step for forming a semi-cured adhesive layer by applying a semi-cured base material side adhesive having elasticity in a cured state to the surface of the wooden substrate;
A paper layer laminating step of placing a thin paper on the semi-cured adhesive layer and laminating the paper layer;
A veneer side adhesive application step of applying a veneer side adhesive on the paper layer;
A laminating step of laminating the wood thin veneer on the veneer side adhesive to obtain a laminate;
A decorative base material in which the thickness of the adhesive layer is 30 μm or more and 75 μm or less, and the hardness of the adhesive layer is 30 ° or less with a type A durometer, by hot-pressing the laminate and integrating the layers. And hot press press
A method for producing a decorative board, comprising: a cosmetic processing step of performing cosmetic processing on the surface of the decorative base material.
木質基材の表面に木質薄単板を、接着剤を介して熱圧プレスにて積層一体化する化粧板の製造方法であって、
上記木質基材の表面に、硬化状態で弾性を有する基材側接着剤を塗布して半硬化させることで、半硬化状態の接着層を形成する接着層形成工程と、
上記半硬化状態の接着層上に紙貼り接着剤を塗布しかつ該紙貼り接着剤上に薄葉紙を載置して紙層を積層する紙層積層工程と、
上記紙層上に単板側接着剤を塗布する単板側接着剤塗布工程と、
上記単板側接着剤上に上記木質薄単板を積層して積層体を得る積層工程と、
上記積層体を熱圧プレスして積層一体化することで、上記接着層の厚みが30μm以上でかつ75μm以下であるとともに、該接着層の硬度がタイプAデュロメーターで30°以下となる化粧基材を得る熱圧プレス工程と、
上記化粧基材の表面に化粧加工を行う化粧加工工程と
を含むことを特徴とする化粧板の製造方法。
A method for producing a decorative board, in which a wood thin veneer is laminated on a surface of a wood substrate by a hot press through an adhesive,
An adhesive layer forming step for forming a semi-cured adhesive layer by applying a semi-cured base material side adhesive having elasticity in a cured state to the surface of the wooden substrate;
A paper layer laminating step of applying a paper adhesive on the semi-cured adhesive layer and placing a thin paper on the paper adhesive to laminate the paper layer;
A veneer side adhesive application step of applying a veneer side adhesive on the paper layer;
A laminating step of laminating the wood thin veneer on the veneer side adhesive to obtain a laminate;
A decorative base material in which the thickness of the adhesive layer is 30 μm or more and 75 μm or less, and the hardness of the adhesive layer is 30 ° or less with a type A durometer, by hot-pressing the laminate and integrating the layers. A hot press process to obtain
A method for producing a decorative board, comprising: a cosmetic processing step of performing cosmetic processing on the surface of the decorative base material.
木質基材の表面に、硬化状態で弾性を有する基材側接着剤を塗布して半硬化させることで、半硬化状態の接着層を形成する接着層形成工程と、
上記半硬化状態の接着層上に紙貼り接着剤を塗布しかつ該紙貼り接着剤上に薄葉紙を載置して紙層を積層する紙層積層工程と、
上記木質基材と接着層と紙層とを熱圧プレスして積層一体化することで、該接着層の厚みを30μm以上でかつ75μm以下とするとともに、接着層の硬度をタイプAデュロメーターで30°以下とする第1熱圧プレス工程と、
上記第1熱圧プレス工程を経た上記紙層上に単板側接着剤を塗布する単板側接着剤塗布工程と、
上記単板側接着剤上に木質薄単板を積層して積層体を得る積層工程と、
上記積層体を熱圧プレスして積層一体化することで、化粧基材を得る第2熱圧プレス工程と、
上記化粧基材の表面に化粧加工を行う化粧加工工程と
を含むことを特徴とする化粧板の製造方法。
An adhesive layer forming step for forming a semi-cured adhesive layer by applying a semi-cured base material side adhesive having elasticity in a cured state on the surface of the wooden substrate;
A paper layer laminating step of applying a paper adhesive on the semi-cured adhesive layer and placing a thin paper on the paper adhesive to laminate the paper layer;
The wood substrate, the adhesive layer, and the paper layer are laminated together by hot pressing, so that the thickness of the adhesive layer is 30 μm or more and 75 μm or less, and the hardness of the adhesive layer is 30 with a type A durometer. A first hot-pressing step of less than or equal to °;
A single-plate-side adhesive application step of applying a single-plate-side adhesive on the paper layer that has undergone the first hot-pressing step;
A laminating step of laminating a thin wood veneer on the veneer side adhesive to obtain a laminate;
A second hot-pressing step of obtaining a decorative base material by hot-pressing the laminated body and integrating the layers;
A method for producing a decorative board, comprising: a cosmetic processing step of performing cosmetic processing on the surface of the decorative base material.
木質基材が合板であることを特徴とする請求項1〜3のいずれか1つの化粧板の製造方法。   The method for producing a decorative board according to any one of claims 1 to 3, wherein the wooden substrate is plywood. 請求項1又は2の化粧板の製造方法において、
熱圧プレス工程の後でかつ化粧加工工程の前に、ショットブラスト法により、木質薄単板の表面に上記単板側接着剤の木質薄単板裏面からの染み上がり部分に至る深さまで、浮造り加工を施す浮造り加工工程をさらに含むことを特徴とする化粧板の製造方法。
In the manufacturing method of the decorative board of Claim 1 or 2,
After the hot-pressing process and before the decorative processing process, the surface of the wood thin veneer is floated on the surface of the wood thin veneer to the depth from the back of the wood thin veneer to the portion that has penetrated by the shot blast method. A method for producing a decorative board, further comprising a float processing step of performing a manufacturing process.
請求項3の化粧板の製造方法において、
第2熱圧プレス工程の後でかつ化粧加工工程の前に、ショットブラスト法により、木質薄単板の表面に上記単板側接着剤の木質薄単板裏面からの染み上がり部分に至る深さまで、浮造り加工を施す浮造り加工工程をさらに含むことを特徴とする化粧板の製造方法。
In the manufacturing method of the decorative board of Claim 3,
After the second hot-pressing step and before the cosmetic processing step, by shot blasting, the surface of the wood thin veneer is deepened up to the depth from the back of the wood thin veneer on the veneer side of the wood veneer. A method for producing a decorative board, further comprising a float process step for performing a float process.
請求項5又は6の化粧板の製造方法において、
化粧加工工程では、浮造り加工を施した木質薄単板を加熱した状態で、この木質薄単板に浮造り加工をした凹部を埋めないように透明性含浸樹脂を塗布、含浸及び硬化させることを特徴とする化粧板の製造方法。
In the manufacturing method of the decorative board of Claim 5 or 6,
In the decorative process, with the heated wooden thin veneer, a transparent impregnated resin is applied, impregnated and cured so as not to fill the recessed concave portion of the wooden thin veneer. A method for producing a decorative board characterized by the above.
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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2011226199A (en) * 2010-04-22 2011-11-10 Panasonic Electric Works Co Ltd Method of manufacturing direct bonding floor material
JP2012031632A (en) * 2010-07-30 2012-02-16 Daiken Corp Floor material and manufacturing method thereof
JP2012245637A (en) * 2011-05-25 2012-12-13 Daiken Corp Methods for manufacturing of sliced veneer sheet for irregular processing and of irregular decoration plate
JP2013174504A (en) * 2012-02-24 2013-09-05 Mitsubishi Heavy Ind Ltd Method of fixing wall thickness measurement sensor
KR101464689B1 (en) * 2013-02-18 2014-11-27 김영민 Access floor and Manufactruring method thereof

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Publication number Priority date Publication date Assignee Title
JPH04269506A (en) * 1991-02-25 1992-09-25 Matsushita Electric Works Ltd Floor wood
JPH0938906A (en) * 1995-07-26 1997-02-10 Matsushita Electric Works Ltd Floor board

Patent Citations (2)

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JPH04269506A (en) * 1991-02-25 1992-09-25 Matsushita Electric Works Ltd Floor wood
JPH0938906A (en) * 1995-07-26 1997-02-10 Matsushita Electric Works Ltd Floor board

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2011226199A (en) * 2010-04-22 2011-11-10 Panasonic Electric Works Co Ltd Method of manufacturing direct bonding floor material
JP2012031632A (en) * 2010-07-30 2012-02-16 Daiken Corp Floor material and manufacturing method thereof
JP2012245637A (en) * 2011-05-25 2012-12-13 Daiken Corp Methods for manufacturing of sliced veneer sheet for irregular processing and of irregular decoration plate
JP2013174504A (en) * 2012-02-24 2013-09-05 Mitsubishi Heavy Ind Ltd Method of fixing wall thickness measurement sensor
KR101464689B1 (en) * 2013-02-18 2014-11-27 김영민 Access floor and Manufactruring method thereof

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