JP2009178618A - Coating method for obtaining metal-like product by applying coating on substrate - Google Patents

Coating method for obtaining metal-like product by applying coating on substrate Download PDF

Info

Publication number
JP2009178618A
JP2009178618A JP2008017236A JP2008017236A JP2009178618A JP 2009178618 A JP2009178618 A JP 2009178618A JP 2008017236 A JP2008017236 A JP 2008017236A JP 2008017236 A JP2008017236 A JP 2008017236A JP 2009178618 A JP2009178618 A JP 2009178618A
Authority
JP
Japan
Prior art keywords
coating
coating film
metal
substrate
film
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP2008017236A
Other languages
Japanese (ja)
Inventor
Satoshi Miyajima
聡 宮島
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kanto Jidosha Kogyo KK
Toyota Motor East Japan Inc
Original Assignee
Kanto Jidosha Kogyo KK
Kanto Auto Works Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kanto Jidosha Kogyo KK, Kanto Auto Works Ltd filed Critical Kanto Jidosha Kogyo KK
Priority to JP2008017236A priority Critical patent/JP2009178618A/en
Publication of JP2009178618A publication Critical patent/JP2009178618A/en
Pending legal-status Critical Current

Links

Images

Abstract

<P>PROBLEM TO BE SOLVED: To provide a coating method for obtaining a metal-like product by applying a coating on the substrate which overcomes the conventional problems that the feeling of cold metallic tactile cannot be obtained by the coating on a resin material, for example, the problems that the tactile becomes the plasticky feeling and that coolish feeling particular to metal cannot be obtained because the heat conductivity is small in comparison with metal. <P>SOLUTION: In the coating method for obtaining metal-like appearance by applying the coating on the substrate 1, it is characterized by forming a coating film 3 by conducting the metallic base coating on the substrate 1 after forming a coating film 2 by conducting the high heat conductive color base coating, and then applying a coating in which a glycerol ester is added to the coating comprised of a flexible resin to form a clear coating film 4. <P>COPYRIGHT: (C)2009,JPO&INPIT

Description

この発明は、基材、例えば樹脂素材等の上に塗料を塗装して金属調(メタリック調)の外観や触感を得る塗装方法に関する。詳細には自動車部品等の中で樹脂素材で構成されながら金属調を求められる部品に塗装して金属調の外観、触感を得る塗装方法に関する。   The present invention relates to a coating method in which a paint is applied on a base material such as a resin material to obtain a metallic (metallic) appearance and feel. More particularly, the present invention relates to a coating method for obtaining a metallic appearance and feel by painting a part that is made of a resin material and is required to have a metallic tone in an automobile part or the like.

金属表面でない素材、例えば合成樹脂等の上に塗料を塗装して、金属調の光沢や質感を感じる外観を付与する塗装方法は、従来から行なわれている。   2. Description of the Related Art Conventionally, a coating method has been performed in which a paint is applied on a material that is not a metal surface, such as a synthetic resin, to give an appearance that feels metallic luster and texture.

例えば、従来技術1として図6に示すようにABSなどの樹脂素材(基材)100上に、ポリエステル樹脂系樹脂顔料からなるカラーベース塗膜101を形成し、その上にアクリル又はポリエステル樹脂系樹脂光輝顔料からなるメタリックベース塗膜102を形成し、更にその上にアクリル樹脂系硬質樹脂からなるクリア塗膜103を形成することによって行なわれていた。   For example, as shown in FIG. 6 as prior art 1, a color base coating film 101 made of a polyester resin resin pigment is formed on a resin material (base material) 100 such as ABS, and acrylic or polyester resin resin glitter is formed thereon. It has been carried out by forming a metallic base coating film 102 made of a pigment and further forming a clear coating film 103 made of an acrylic resin hard resin thereon.

また、特開2004−358329号公報(従来技術2)には、「アルミニウム顔料及び微小鱗片状顔料を含有してなる金属調第1コート塗料、および微小鱗片状顔料、または微小鱗片状顔料及びアルミニウム顔料を含有してなる光輝性第2コート塗料、及びクリヤコート塗料である第3コート塗料を順次塗装して、塗膜を形成し、硬化させることを特徴とする金属調光輝性塗膜形成方法」が開示されている。   JP 2004-358329 A (Prior Art 2) states that “a metallic first coat coating material containing an aluminum pigment and a fine flaky pigment, and a fine flaky pigment, or a fine flaky pigment and aluminum. A method for forming a metallic brilliant coating film, characterized in that a glittering second coating composition containing a pigment and a third coating composition, which is a clear coating composition, are sequentially applied to form a coating film and to be cured. Is disclosed.

更に、特開2003−19765号公報(従来技術3)には、「基材上に下塗り塗膜及び金属膜をこの順に被覆して成り、下塗り塗膜は水酸基価が91〜203[mgKOH/g]である塗料より形成され、表面粗度が0.004〜0.148μm、水接触角が28〜60°であり、金属膜を下塗り塗膜上に直接被覆して成る金属調塗装塗膜である。下塗り塗膜は塩化スズを顔料重量濃度で0.1〜2.0%含有しており、基材上に下塗り塗膜を形成後、下塗り塗膜上に銀鏡反応による銀膜を形成して金属調塗装塗膜を製造する。」との開示がある。   Furthermore, Japanese Patent Laid-Open No. 2003-19765 (Prior Art 3) states that “a base coat and a metal film are coated in this order on a substrate, and the base coat has a hydroxyl value of 91 to 203 [mgKOH / g. A metallic paint film that has a surface roughness of 0.004 to 0.148 μm, a water contact angle of 28 to 60 °, and a metal film directly coated on the undercoat film. The undercoating film contains 0.1 to 2.0% of tin chloride in the pigment weight concentration, and after forming the undercoating film on the substrate, a silver film is formed on the undercoating film by a silver mirror reaction. Manufacturing a metallic paint film. "

また、特開2001−314813号公報(従来技術4)には、「光が透過するベース材料に金属を含む塗料で成形品に塗装膜を薄く形成し、成形品の色調を成形品の素材から反射する反射光と塗料中の金属から反射する反射光との混合光により金属調の色を得るようにする。」技術の開示がある。
特開2004−358329号公報(従来技術2) 特開2003−19765号公報(従来技術3) 特開2001−314813号公報(従来技術4)
Further, Japanese Patent Laid-Open No. 2001-314813 (prior art 4) states that “a coating film is thinly formed on a molded product with a paint containing a metal as a base material through which light is transmitted, and the color tone of the molded product is changed from the material of the molded product. A metallic tone color is obtained by the mixed light of the reflected light reflected and the reflected light reflected from the metal in the paint.
JP 2004-358329 A (Prior Art 2) JP 2003-19765 A (Prior Art 3) JP 2001-314813 A (Prior Art 4)

しかし従来技術は、樹脂素材に塗装しているため「金属の冷たい触感」が感じられないという問題点があった。これらの原因は、従来技術が「視覚上の金属感付与」を狙いとしているため、外観重視のため触感に対する機能は付与していないためである。   However, the conventional technique has a problem that a “metal cold tactile sensation” cannot be felt because the resin material is coated. This is because the conventional technology aims to “provide a visual metallic feeling”, and therefore a function for tactile sensation is not imparted because the appearance is important.

例えば、従来技術では、図6に示すように基材(樹脂素材)上に、硬質樹脂であるアクリル樹脂又はポリエステル樹脂系の樹脂素材を上塗りするため、触感がプラスチッキーな感触となる課題があった。   For example, in the prior art, as shown in FIG. 6, since a hard resin such as an acrylic resin or a polyester resin-based resin material is overcoated on a base material (resin material), there is a problem that the tactile sensation becomes a plasticy feeling. It was.

更に、基材(樹脂素材)上に樹脂素材を上塗りした塗装では、金属と比較して熱伝導率が小さいため、金属特有の「冷感」が感じられない課題があった。   Furthermore, the coating with the resin material overcoated on the base material (resin material) has a problem that the “cool feeling” peculiar to the metal cannot be felt because the thermal conductivity is smaller than that of the metal.

上記課題を解決するために、基材上に塗料を塗装して金属調外観を得る塗装方法において、
基材の上に、高熱伝導カラーベース塗装を行い塗膜形成後、メタリックベース塗装を行なって塗膜を形成し、その上に軟質樹脂からなる塗料にグリセリンエステルを添加した塗料を塗布してクリヤ塗膜を形成してなる金属調製品を得る塗装方法を提案する。
In order to solve the above problems, in a coating method for obtaining a metallic appearance by painting a paint on a substrate,
A high thermal conductive color base coating is formed on the base material to form a coating film, then a metallic base coating is applied to form a coating film, and a coating made of a soft resin with a glycerin ester added is applied to the substrate to form a clear coating. We propose a painting method to obtain a metal preparation with a film.

この発明によれば、樹脂等の基材上に塗装する塗装方法において、金属調の視覚上の色を得るとともに、金属に近い触感を得ることができた。   According to the present invention, in a coating method for coating on a substrate such as a resin, a metallic visual color can be obtained and a tactile sensation close to metal can be obtained.

これは樹脂材料のプラスチッキーな硬さではない軟質化を表面に加え凹み感を作成できるとともに、熱伝導上も金属に近い冷感を得ることにより、従来技術より格段に金属感を感じる触感を得ることができた。   In addition to the softness of the resin material, which is not plastic, the surface can be softened to create a feeling of dents. I was able to get it.

この発明の実施形態である基材上に塗料を塗装して金属調外観を得る塗装方法に関する図1乃至図5に基づいて説明する。図1は、この発明の塗装方法による塗膜の説明図である。   An explanation will be given based on FIGS. 1 to 5 relating to a coating method for obtaining a metallic appearance by applying a paint on a base material according to an embodiment of the present invention. FIG. 1 is an explanatory view of a coating film by the coating method of the present invention.

この発明の実施形態である金属調外観を得る塗装方法は、硬質合成樹脂素材からなる基材1の上に、高熱伝導カラーベース塗装を行い高熱伝導カラーベース塗膜2を形成する。高熱伝導カラーベース塗膜2は、塗料樹脂に比較的高伝導率のシリコーンを用いてカラーベースを作成しているが、シリコーン以外でも熱伝導率が比較的高い素材であればよい。   In the coating method for obtaining a metallic appearance according to an embodiment of the present invention, a high thermal conductivity color base coating is performed on a base material 1 made of a hard synthetic resin material to form a high thermal conductivity color base coating film 2. The high heat conductive color base coating film 2 is made of a color base using silicone having a relatively high conductivity as a coating resin, but may be any material other than silicone that has a relatively high heat conductivity.

その上に後、メタリックベース塗装を行なってメタリックベース塗膜3を形成する。   Thereafter, metallic base coating is performed to form a metallic base coating film 3.

更にその上に軟質樹脂からなる塗料にグリセリンエステルを添加した塗料を塗布してなるクリヤ塗膜4を形成して成る。クリヤ塗膜4は、ユニバーサル硬さ(40mN)測定時の塗膜の凹み量が、15μm以上である。また、クリヤ塗膜4は、グリセリンエステルを添加されることによって親水甚が付与される。   Further, a clear coating film 4 is formed by applying a paint obtained by adding a glycerin ester to a paint made of a soft resin. The clear coating film 4 has a dent amount of 15 μm or more when the universal hardness (40 mN) is measured. Further, the clear coating film 4 is imparted with hydrophilic soot by adding a glycerin ester.

この発明の塗装方法による塗膜と、従来技術の金属調塗装方法による塗膜との比較を図2乃至図5に示す。図2は熱伝導率に関する比較表であり、この発明によれば硬質合成樹脂素材からなる基材1の上に、高熱伝導カラーベース塗膜2を形成することにより熱伝導率が大きくなり、手で触ったときの冷感が従来より、より感じやすくなることが解る。   A comparison between the coating film by the coating method of the present invention and the coating film by the metal-tone coating method of the prior art is shown in FIGS. FIG. 2 is a comparative table regarding thermal conductivity. According to the present invention, the thermal conductivity is increased by forming the high thermal conductive color base coating film 2 on the base material 1 made of a hard synthetic resin material. It can be seen that the cool feeling when touched is easier to feel than before.

また、図3はクリヤ塗膜4にグリセリンエステルを添加することによって親水甚を存在させたことによる触感の比較表であり、塗膜表面のIR分析の結果である水酸基のピーク強度比をしめしている。図3に示すようにこの発明によればクリヤ塗膜4にグリセリンエステルを添加することによって親水甚を存在させ、瑞々しい触感を付与させ触った手に冷感を感じさせることができる。   FIG. 3 is a tactile comparison table showing the presence of hydrophilic wrinkles by adding glycerin ester to the clear coating film 4, and shows the peak intensity ratio of hydroxyl groups as a result of IR analysis of the coating film surface. Yes. As shown in FIG. 3, according to the present invention, by adding a glycerin ester to the clear coating film 4, a hydrophilic wrinkle is present, and a fresh touch is imparted to the touched hand so that a cold feeling can be felt.

また、図4は、40mNでのユニバーサル硬さ測定時の塗膜の凹み量μmを従来品と比較した表である。図4に示すようにクリヤ塗膜4を軟質樹脂によって形成することにより、凹み量が従来の3倍となり、接触する指と塗膜面との間に存在する空気を少なくするとともに接触面積を大きくすることにより熱伝導率を良くすることができる。   FIG. 4 is a table comparing the dent amount μm of the coating film when measuring the universal hardness at 40 mN with a conventional product. As shown in FIG. 4, by forming the clear coating film 4 with a soft resin, the dent amount is three times that of the conventional one, reducing the air existing between the finger and the coating surface in contact and increasing the contact area. By doing so, the thermal conductivity can be improved.

図5は、この発明の塗装方法による塗膜と、従来の塗装方法による塗膜と、金属を金属官能ランクとして冷感を比較した比較表である。図5に示すように、この発明の塗装方法による塗膜は、冷感が従来品と比較して金属に近くなっている。   FIG. 5 is a comparison table comparing the feeling of cooling with a coating film formed by the coating method of the present invention, a coating film formed by the conventional coating method, and metal as a metal functional rank. As shown in FIG. 5, the coating film by the coating method of this invention is close to a metal in the cool feeling compared with the conventional product.

この発明は、自動車等の外装や外装部品の塗装に利用される。   The present invention is used for coating exteriors and exterior parts of automobiles and the like.

この発明の実施形態である塗装方法による塗膜の説明図Explanatory drawing of the coating film by the coating method which is embodiment of this invention この発明の塗装方法による塗膜と、従来の塗装方法による塗膜とに関する熱伝導率に関する比較表Comparison table regarding thermal conductivity of coating film by coating method of this invention and coating film by conventional coating method この発明の塗装方法による塗膜と、従来の塗装方法による塗膜とに関する触感の比較表Comparison table of tactile sensation regarding the coating film by the coating method of the present invention and the coating film by the conventional coating method この発明の塗装方法による塗膜と、従来の塗装方法による塗膜とに関する凹み量の比較表Comparison table of the dent amount regarding the coating film by the coating method of the present invention and the coating film by the conventional coating method この発明の塗装方法による塗膜と、従来の塗装方法による塗膜とに関する金属官能ランクの比較表Comparison table of metal sensory ranks regarding the coating film by the coating method of the present invention and the coating film by the conventional coating method 従来技術の金属調塗装方法による塗膜の説明図Explanatory drawing of the coating film by the conventional metallic-tone coating method

符号の説明Explanation of symbols

1 基材
2 高熱伝導カラーベース塗膜
3 メタリックベース塗膜
4 グリセリンエステルを添加したクリヤ塗膜
DESCRIPTION OF SYMBOLS 1 Base material 2 High heat conductive color base coating film 3 Metallic base coating film 4 Clear coating film which added glycerol ester

Claims (1)

基材上に塗料を塗装して金属調外観を得る塗装方法において、
基材の上に、高熱伝導カラーベース塗装を行い塗膜形成後、メタリックベース塗装を行なって塗膜を形成し、その上に軟質樹脂からなる塗料にグリセリンエステルを添加した塗料を塗布してクリヤ塗膜を形成してなる金属調製品を得る塗装方法。
In a painting method to obtain a metallic appearance by painting a paint on a substrate,
A high thermal conductive color base coating is formed on the base material to form a coating film, then a metallic base coating is applied to form a coating film, and a coating made of a soft resin with a glycerin ester added is applied to the substrate to form a clear coating. A coating method to obtain a metal preparation by forming a film.
JP2008017236A 2008-01-29 2008-01-29 Coating method for obtaining metal-like product by applying coating on substrate Pending JP2009178618A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2008017236A JP2009178618A (en) 2008-01-29 2008-01-29 Coating method for obtaining metal-like product by applying coating on substrate

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2008017236A JP2009178618A (en) 2008-01-29 2008-01-29 Coating method for obtaining metal-like product by applying coating on substrate

Publications (1)

Publication Number Publication Date
JP2009178618A true JP2009178618A (en) 2009-08-13

Family

ID=41033007

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2008017236A Pending JP2009178618A (en) 2008-01-29 2008-01-29 Coating method for obtaining metal-like product by applying coating on substrate

Country Status (1)

Country Link
JP (1) JP2009178618A (en)

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2003212947A (en) * 2001-01-29 2003-07-30 Ohashi Kagaku Kogyo Kk Low temperature curing type coating composition with pleasant touch
JP2004231803A (en) * 2003-01-30 2004-08-19 Origin Electric Co Ltd Paint composition and article with painted film
JP2004358329A (en) * 2003-06-03 2004-12-24 Nippon Yushi Basf Coatings Kk Method for forming bright metallic coating film
JP2005081225A (en) * 2003-09-08 2005-03-31 Calsonic Kansei Corp Method of manufacturing plastic automobile component having metallic feeling

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2003212947A (en) * 2001-01-29 2003-07-30 Ohashi Kagaku Kogyo Kk Low temperature curing type coating composition with pleasant touch
JP2004231803A (en) * 2003-01-30 2004-08-19 Origin Electric Co Ltd Paint composition and article with painted film
JP2004358329A (en) * 2003-06-03 2004-12-24 Nippon Yushi Basf Coatings Kk Method for forming bright metallic coating film
JP2005081225A (en) * 2003-09-08 2005-03-31 Calsonic Kansei Corp Method of manufacturing plastic automobile component having metallic feeling

Similar Documents

Publication Publication Date Title
JP4695631B2 (en) Decorative resin molded product and manufacturing method thereof
US8435607B2 (en) Housing and method of manufacturing the same
JP2010058112A (en) Surface treatment method of plastic molded article
CN101730408A (en) Housing and method for making same
CN101879799A (en) Shell and manufacturing method thereof
US8309183B2 (en) Method of making magnesium alloy housing
CN104908380B (en) A kind of transfevent decorating film
CN103184411A (en) Film-coating member and manufacturing method thereof
TW201244588A (en) Housing and method for making same
JP2009178618A (en) Coating method for obtaining metal-like product by applying coating on substrate
JP2017178999A (en) Hard coat coating composition and hard coat film for molding
JP6508758B1 (en) Metal member subjected to polishing pattern and method for manufacturing the same
TW201041482A (en) Housing and method for making the same
JP2010234798A (en) Manufacturing method of patterning molding and patterning molding obtained thereby
CN101888753A (en) Shell and manufacturing method thereof
JP5091667B2 (en) Surface-treated metal products
JP4578331B2 (en) Painted steel sheet for writing board
JP2007014911A (en) Designed coating film, its forming method and coated article
TWI406911B (en) Coating composition
TW201041755A (en) Housing and method for making the same
JP3994434B2 (en) Metallic appearance multilayer coating film and method for forming the same
TW201039712A (en) Housing and method for making the same
JP2006123373A (en) Decorative steel sheet and its manufacturing method
JP2010110701A (en) Method of forming metallic luster thin film and metallic luster decorated article using the same
US20100047525A1 (en) Film structure and a manufacturing method thereof

Legal Events

Date Code Title Description
A977 Report on retrieval

Free format text: JAPANESE INTERMEDIATE CODE: A971007

Effective date: 20110126

A131 Notification of reasons for refusal

Effective date: 20110201

Free format text: JAPANESE INTERMEDIATE CODE: A131

A02 Decision of refusal

Effective date: 20111101

Free format text: JAPANESE INTERMEDIATE CODE: A02