JP2009172502A - Polymeric emulsifier, and polyolefin resin emulsion employing the same - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To provide a polymeric emulsifier capable of producing a dried coating film having an improved film-forming capability at a low temperature, improved transparency, and improved surface smoothness. <P>SOLUTION: The polymeric emulsifier includes 5 to 20 mole% of a structural unit derived from a polymerizable monomer having a structure comprised of a polymerizable double bond and a hydrophilic group bound together via at least 4 to 16 atoms therebetween as its copolymerizable component, with the 1/2 method temperature of the resulting copolymer measured by a flow tester being not lower than 40°C and not higher than 140°C. <P>COPYRIGHT: (C)2009,JPO&INPIT

Description

  The present invention relates to a polymer emulsifier having a dry film excellent in low-temperature film-forming property and transparency, and a polyolefin resin emulsion and a polypropylene resin adhesive using the polymer emulsifier.

  In recent years, polyolefin resins such as polypropylene and polyethylene have been used for daily necessities, automotive parts, building materials and the like from the viewpoints of versatility, strength, physical properties, ease of molding, solvent resistance, and appearance.

  These polyolefin resins were difficult to bond due to the low polarity of the polyolefin resins themselves. Therefore, it was necessary to use an adhesion-imparting component such as chlorinated polypropylene dissolved in an organic solvent for bonding these polyolefin resins.

  However, in recent years, there has been a strong demand for solvent-free paints for environmental protection and safety and health, and conventional solvent-based paints are being made water-based (see Patent Documents 1 and 2). In addition, it has been pointed out that chlorinated polyolefin resins may generate highly toxic dioxins when discarded by incineration.

  For example, in the case of an ethylene / vinyl acetate copolymer, the ethylene / vinyl acetate copolymer is first heated and melted, and then an anionic or nonionic emulsifier is added and stirred. Then, the method obtained by adding hot water and emulsifying using mechanical shear force, such as a homomixer, is mentioned (refer patent document 3).

  However, when the above-mentioned anionic emulsifier and nonionic emulsifier are used, there is a risk of bleeding out when the obtained product is used. On the other hand, a method for producing an aqueous polymer dispersion using a neutralized product of a specific acrylic copolymer with improved emulsion stability as an anionic water-soluble polymer dispersant is known (Patent Document 4). reference).

  However, this anionic water-soluble polymer dispersant can improve the dispersion stability. However, when water, volatile base, etc. evaporate from the obtained polymer dispersion, Carboxyl groups cause intramolecular or intermolecular association, resulting in an increase in melt viscosity, hindering the fusion of emulsion resin particles, resulting in poor film formation at low temperatures, and low temperature of the resulting dried film. Adhesiveness and transparency may be inferior, and its application may be limited.

  On the other hand, a method for producing an aqueous polymer dispersion using a neutralized product of a specific acrylic copolymer having excellent low-temperature film-forming properties as a cationic water-soluble polymer dispersant is known (see Patent Document 5). .

  However, the dry film obtained using this cationic water-soluble polymer dispersant is improved in low-temperature film-forming property, low-temperature adhesiveness, and transparency, but with an anionic aqueous dispersion used for general purposes. There is a restriction that it is difficult to use the mixture.

  As an improvement method, Japanese Patent Application No. 2006-195891 discloses an anionic monomer having (meth) acrylic acid as a main component and a cationic monomer having N, N-dimethylaminoethyl methacrylate as a main component. A method of using an amphoteric polymer emulsifier obtained by polymerizing a monomer mixture containing benzene has been studied.

Japanese Patent Laid-Open No. 06-336568 JP-A-11-106600 JP 57-61035 A JP 58-127752 A JP 58-118843 A

However, when using a polymeric emulsifier of the amphoteric, when a carboxyl group forming a film having the polymeric emulsifiers of this amphoteric occur between particles barriers by hydrogen bond formation adversely affect film formation, a thin film of surface smoothness May be insufficient.

  Accordingly, an object of the present invention is to solve such problems and to obtain a polymer emulsifier in which the obtained dry film has improved low-temperature film-forming properties, transparency, and surface smoothness.

  In the present invention, a structural unit derived from a polymerizable monomer having a structure in which a polymerizable double bond and a hydrophilic group are bonded to each other with a minimum of 4 to 16 atoms interposed, The above problem was solved by obtaining a polymer emulsifier containing 5 to 20 mol% as a polymerizable component and having a 1/2 method temperature of 40 to 140 ° C. by a flow tester of the copolymer. It is.

  According to this invention, since the number of atoms between the polymerizable double bond and the hydrophilic group is within a predetermined range, a sufficient distance between the hydrophilic group and the polymer main chain can be ensured. For this reason, at the time of film formation, it can suppress that the barrier between particle | grains by hydrogen bond formation arises, film formation can be improved, and the surface smoothness of a thin film can be improved. And transparency can also be improved.

Hereinafter, the present invention will be described in detail.
The polymer emulsifier according to the present invention refers to an emulsifier containing a copolymer having a structural unit derived from a specific polymerizable monomer as a copolymerizable component.

[(A) component]
The specific polymerizable monomer (hereinafter referred to as “component (A)”) is a polymerizable double bond and a hydrophilic group, and has a minimum of 4 to 16 atoms between them. This is a polymerizable monomer having a structure bonded with intervening.

  The polymerizable double bond refers to a double bond capable of causing radical polymerization, and includes a double bond of a (meth) acryloyl group, a double bond of styrenes, and the like. In the present specification, “(meth) acryloyl” and “(meth) acryl” mean “acryloyl or methacryloyl” and “acryl or methacryl”.

  Examples of the hydrophilic group include a carboxyl group, a sulfonic acid group, a phosphoric acid group, and an acidic phosphate group, and at least one of them is used.

  The number of atoms intervening between the polymerizable double bond and the hydrophilic group is 4 or more, preferably 6 or more. On the other hand, the upper limit of the number of atoms is 16, and 8 is preferable. When the number of intervening atoms is within the above predetermined range, the atomic chain constituted by the intervening atoms acts as a soft segment in the copolymer containing the component (A) as a copolymerization component. The 1/2 method temperature by the coalescence flow tester can be lowered.

  If the number of intervening atoms is less than 4 between the polymerizable double bond and the hydrophilic group, the polymerizable double bond and the hydrophilic group are too close, and the polymer according to the present invention When a film is formed using an emulsion obtained using an emulsifier, a barrier is generated between the particles due to hydrogen bonds generated by the hydrophilic group, which may affect the film forming property. On the other hand, when the number is more than 16, the balance between the hydrophilic group and the hydrophobic group is deteriorated, and the emulsifying power may be lowered.

  By the way, the number of atoms interposed between the polymerizable double bond and the hydrophilic group is the number of atoms of the shortest atomic chain among the atomic chains connecting the polymerizable double bond and the hydrophilic group. Say. This is not a problem when this atomic chain is one, but when this atomic chain is cyclic, there are two atomic chains interposed between the polymerizable double bond and the hydrophilic group. It will be. In this case, the number of atoms in the shortest atomic chain, that is, the shortest atomic chain is used. This is because, as described above, the atomic chain interposed between the polymerizable double bond and the hydrophilic group acts as a soft segment in the copolymer containing the component (A) as a copolymer component. However, this effect is because a chain with a small number of atoms in the atomic chain has a greater effect than a chain with a large number of atoms.

  Examples of the hydrophilic group include a carboxyl group, a sulfonic acid group, a sulfuric acid ester group, a phosphoric acid group, and an acidic phosphoric acid ester group, and at least one of them is used. Examples of carboxyl group-containing monomers include 2-methacryloyloxyethyl succinic acid (number of intervening atoms: 8), β-carboxyethyl acrylate (number of intervening atoms: 8), ω-carboxy-polycaprolactam monoacrylate (intervening atoms) Number: 14), 2-methacryloyloxyethyl hydrophthalic acid (number of intervening atoms: 8), and the like. Examples of the sulfonic acid group-containing monomer include acrylamide-2-methylpropanesulfonic acid (the number of intervening atoms: 4). Examples of the acidic phosphate group-containing monomer include mono (2-methacryloyloxyethyl) acid phosphate (number of intervening atoms: 4). Two or more of these components may be used in combination. In particular, 2-methacryloyloxyethyl succinic acid (number of intervening atoms: 8) is preferable.

[(B) component to (D) component]
The copolymer constituting the polymer emulsifier according to the present invention has a structural unit derived from the component (A). The copolymer component used as a raw material for the copolymer is a carboxyl other than the component (A). Group-containing monomer (hereinafter referred to as “component (B)”), amino group-containing monomer (hereinafter referred to as “component (C)”), (meth) acrylic acid ester of aliphatic alcohol having 1 to 22 carbon atoms (Hereinafter referred to as “component (D)”).

  The component (B) is used as a component having a hydrophilic group to develop the emulsifying ability of the polymer emulsifier. Examples of the component (B) include (meth) acrylic acid, itaconic acid, citraconic acid, maleic acid, crotonic acid, fumaric acid, maleic acid monoalkyl ester, and fumaric acid monoalkyl ester. These may use only 1 type and may mix and use 2 or more types.

  The component (C) is used to develop the film forming property and the adhesion of the substrate. Examples of the component (C) include (meth) acrylic acid alkylamino esters and N-aminoalkyl (meth) acrylamides.

  Moreover, the alkyl group substituted with the alkylamino group of the said (meth) acrylic-acid alkylaminoalkyl has a C1-C6 alkyl group.

  Examples of such alkylaminoalkyl (meth) acrylates include N, N-dimethylaminoethyl (meth) acrylate, N, N-diethylaminoethyl (meth) acrylate, and N, N- (meth) acrylate. And dimethylamino-2-aminoethyl. These may use only 1 type and may mix and use 2 or more types.

  Examples of the cationic monomer other than the above-mentioned alkylaminoalkyl (meth) acrylate include N-aminoalkyl (meth) acrylamides such as N, N-dimethylaminoethyl (meth) acrylamide.

  The component (D) is used as a component having a hydrophobic group to develop the emulsifying ability of the polymer emulsifier. Examples of the component (D) include methyl (meth) acrylate, ethyl (meth) acrylate, n-propyl (meth) acrylate, iso-propyl (meth) acrylate, and n-butyl (meth) acrylate. , Iso-butyl (meth) acrylate, t-butyl (meth) acrylate, 2-ethylhexyl (meth) acrylate, lauryl (meth) acrylate, tridecyl (meth) acrylate, stearyl (meth) acrylate, etc. It is done. Moreover, in order to improve heat fluidity and emulsifying power, two or more of these components may be mixed and used.

[Content ratio of each component]
In the copolymer constituting the polymer emulsifier according to the present invention, the content of the structural unit derived from the component (A) is required to be 5 mol% or more as the copolymerizable component, and preferably 10 mol% or more. When it is less than 5 mol%, the emulsifying ability of the polymer emulsifier tends to decrease. On the other hand, the upper limit of the content is preferably 20 mol%, and preferably 15 mol%. If it is more than 20 mol%, the emulsifying ability of the polymer emulsifier tends to decrease, and the film-forming temperature of the resulting emulsion increases, which may deteriorate the low-temperature adhesion and transparency of the resulting film.

  Further, the total amount of the component (A) and the component (B) and the ratio of the component (C) (((A) + (B)) / (C)) are 1.0 or more in terms of molar ratio. Is preferably 1.1 or more. If it is less than 1.0, the cationic property becomes strong, and it tends to be difficult to use together with an emulsion using an anionic emulsifier which is generally used. On the other hand, the upper limit of the molar ratio is preferably 2.0 and is preferably 1.9. If it is greater than 2.0, the film-forming temperature of the resulting emulsion will be high, and the low-temperature adhesiveness and transparency of the resulting film may be deteriorated, and its use tends to be limited.

  Next, when the copolymer (A) component to the component (D) are used, the constituent ratio of each component is (A) / (B) in terms of a molar ratio when the total amount is 100 mol%. / (C) / (D) = 5 to 20/10 to 40/5 to 40/7 to 50 is preferable, and 10 to 15/15 to 30/15 to 35/30 to 40 is preferable.

  When each component is out of the above preferred range, the intended effect of the present invention may not be sufficiently obtained.

[Method for producing copolymer]
The copolymer constituting the polymer emulsifier according to the present invention can be produced by the following method.
First, the above components (A) to (D) are each weighed at a predetermined mixing ratio. Next, each component is added separately to the polymerization vessel for polymerization, or each monomer is mixed in advance and then added to the polymerization vessel for polymerization. Thereby, a copolymer can be manufactured.

  The copolymerization is carried out in the presence of a polymerization initiator at 0 to 180 ° C., preferably 40 to 120 ° C. for 0.5 to 20 hours, preferably 2 to 10 hours. This copolymerization is preferably carried out in the presence of a hydrophilic solvent such as ethanol, isopropanol or cellosolve or water.

  As the polymerization initiator, an initiator comprising a persulfate such as ammonium persulfate, potassium persulfate, sodium persulfate, etc., a redox initiator using the persulfate in combination with a sulfite, a thiosulfate reducing agent, Redox initiators using organic peroxides such as lauroyl peroxide, t-butyl hydroperoxide, cumene hydroperoxide or the like, and iron (II) salt, sulfite, thiosulfate reducing agents, etc. -Azobis (isobutyronitrile), 2,2'-azobis [2-methyl-N- (2-hydroxyethyl) propionamide], 2,2'-azobis [2- (2-imidazolin-2-yl) Propane] dihydrochloride, 2,2'-azobis (2-methylpropionamidine) dihydrochloride and other azo compounds, t-butyl Over oxy isobutyrate, 1,1-bis (t-butylperoxy) cyclohexene, t- butyl peroxybenzoate, and the like. The amount of the polymerization initiator used is preferably 0.01 to 10% by weight based on the total amount of monomers used.

  In order to improve the heat flow characteristics, it is also possible to reduce the molecular weight using a chain transfer agent or the like. In this case, mercaptans which are known chain transfer agents can be used for adjusting the degree of polymerization.

  By the way, an acidic hydrophilic group is contained in said (A) component and (B) component. Therefore, it is preferable that at least a part of the acidic hydrophilic group is neutralized with a basic substance. By neutralizing at least a part, the solubility in water is improved, the resulting polymer particle size is reduced, and the characteristics that the dispersion state in water is stabilized can be exhibited.

  The degree of neutralization, that is, the degree of neutralization is preferably 50 mol% or more, and preferably 100 mol% or more. If it is less than 50 mol%, the solubility of the resulting copolymer in water tends to be insufficient. On the other hand, the upper limit of the degree of neutralization is preferably 200 mol%, and preferably 150 mol%. When it is larger than 200 mol%, the water resistance tends to be insufficient.

  Examples of the basic substance include basic compounds such as alkali metal and alkaline earth metal hydroxides, ammonia, alkylamines, alkanolamines, morpholine, and the like. Examples of the alkali metal or alkaline earth metal hydroxide include sodium hydroxide, potassium hydroxide, magnesium hydroxide and the like, and specific examples of alkylamines include methylamine, dimethylamine, trimethylamine, ethylamine, Examples include diethylamine, and specific examples of alkanolamines include 2-amino-2-methylpropanol. Among these, it is preferable to use ammonia having volatility during low-temperature drying in order to improve the water resistance of the resulting film. Moreover, in order to raise emulsification power, sodium hydroxide and potassium hydroxide are preferable.

  Neutralization reaction is performed by making the said copolymer and a basic compound react at 20-100 degreeC for 0.1 to 3 hours.

  Alternatively, the component (A) or the component (B) may be previously neutralized with a basic compound and used for copolymerization.

[Melting temperature]
The melt temperature of the copolymer thus obtained is a ½ method temperature of 40 ° C. or higher, preferably 50 ° C. or higher, and more preferably 60 ° C. or higher in the measurement of melt viscosity by a flow tester. When it is lower than 40 ° C, the dry film of the polymer emulsifier tends to be easily blocked. On the other hand, the upper limit of the 1/2 method temperature is preferably 140 ° C., and preferably 130 ° C. If it is higher than 140 ° C., the low-temperature film-forming property tends to decrease.

  The copolymer obtained by the above method is a polymer emulsifier by adding additives such as a fungicide, an antioxidant and a UV absorber as it is or within a range not inhibiting the effects of the present invention. It becomes.

  This polymer emulsifier can be used as an emulsifier for emulsifying a polymer substance. When an emulsified polymer substance is formed into a film, a dry film having good low-temperature film-forming property, transparency, and surface smoothness is obtained. It becomes easy to obtain. Further, it can be used as a compatibilizing agent in kneading two or more kinds of polymer substances.

  As such a polymer substance, a general polymer substance such as a polyolefin resin can be used. For example, by using the above polymer emulsifier, a polyolefin resin can be emulsified to obtain a polyolefin resin emulsion. This polyolefin resin emulsion can be used as an adhesive for polyolefin resins such as polypropylene resins.

  These are substances that are conventionally difficult to make into an aqueous dispersion and have been used by being dissolved in an organic solvent, and have been highly effective as adhesives for polypropylene resins. By using a polymer emulsifier, it is possible to remove the solvent, and it is possible to produce an adhesive for polypropylene resin having a small environmental load.

  As a method for producing an emulsion of polyolefin resin using the polymer emulsifier of the present invention, melted polyolefin resin is added to water containing the polymer emulsifier or a neutralized product thereof, and homogenized by a homomixer. And a method of stirring. The most preferred embodiment uses a multi-screw extruder having two or more screws in a casing, and continuously supplies a polyolefin resin from the hopper of the multi-screw extruder or a midway supply port, which is heated, melted and kneaded. In addition, an aqueous solution containing the above polymer emulsifier or a neutralized product thereof is supplied under pressure from at least one supply port provided in the compression zone, metering zone, and degassing zone of the multi-screw extruder, And the above-mentioned molten polyolefin resin can be kneaded with a screw to continuously produce an emulsion from a die.

  The amount of water used is preferably used so that the solid concentration of the aqueous dispersion obtained is 20 to 65% by weight. Moreover, you may mix | blend an antifoamer, a viscosity modifier, an anionic or nonionic surfactant, and antioxidant with the obtained aqueous dispersion.

  The emulsion produced in this manner is dispersed in water with polyolefin resin particles having an average particle size of 5 μm or less and a particle size of 1 μm or less of 10 wt% or more, preferably 20 wt% or more. The viscosity at 25 ° C. is 10 to 10,000 mPa · s, preferably 50 to 5,000 mPa · s. A more preferable viscosity is 50 to 2,000 mPa · s.

  The aqueous dispersion can be used as a paint, a pressure-sensitive adhesive, an ink binder, an adhesive, or an emulsion modifier, depending on the type of polyolefin resin used.

  Hereinafter, the present invention will be described more specifically with reference to examples. First, the evaluation method and the raw materials used will be described.

<Evaluation method>
[Non-volatile content]
About 1 g of the polymer emulsifier sample obtained in each production example or various emulsion samples obtained in the examples and comparative examples are precisely weighed and dried in a hot air circulating dryer at 105 ° C. for 3 hours, and then released in a desiccator. Cooled and weighed. The nonvolatile content was calculated according to the following formula.
Nonvolatile content [%] = (weight of sample after drying / weight of sample before drying) × 100

[Measurement of weight average molecular weight (Mw) by GPC]
The sample is dried at room temperature for 24 hours, dried at room temperature under reduced pressure (using a vacuum dryer LHV-122 (manufactured by Tabai Espec Co., Ltd.)) for 5 hours or more, added chloroform and methanol, and then an esterifying agent (trimethylsilyldiazomethane). The hexane solution was stirred at room temperature until allowed to dissolve (48-72 hours). Then, it was made to dry at room temperature.
The dried sample was adjusted to 0.2% with tetrahydrofuran (THF) and used as a sample.
The sample was measured under the following conditions using Shimadzu Corporation GPC-6A.
・ Flow rate: 1 ml / min
Column: PL gel 10 μm mix B (manufactured by Polymer Laboratories)
Standard sample: monodispersed PS (manufactured by Polymer Laboratories)
Reference: Sumilizer BHT (manufactured by Sumitomo Chemical Co., Ltd.)
・ Detector: RI, UV

[viscosity]
Various emulsion samples obtained in Examples and Comparative Examples were taken in a 500 ml beaker, and using VISCOMETER TV-10M (manufactured by Toki Sangyo Co., Ltd., rotor No. 1), rotating at 30 rpm and liquid temperature of 25 ° C. Measured under conditions.

[PH]
Samples of polymer emulsifier samples obtained in each production example, or various emulsion samples obtained in Examples and Comparative Examples, using a glass electrode type hydrogen ion concentration meter HM-14P (manufactured by Toa Denpa Kogyo Co., Ltd.) Was measured after adjusting the liquid temperature to 25 ° C.

[Particle size]
Various emulsion samples obtained in Examples and Comparative Examples were measured with a laser diffraction particle size distribution analyzer SALD-2100 (manufactured by Shimadzu Corporation) under the following conditions.
-Refractive index 1.50-0.20i
・ Volume distribution (median diameter)

[Melting temperature (1/2 method temperature)]
The polymer emulsifier sample obtained in each production example was allowed to stand at room temperature for 24 hours, and then vacuum-dried at room temperature for 5 hours. About 1 g was weighed and used as a sample, and an elevated flow tester (Shimadzu Corporation ( Using a CFT-500), 1/2 method temperature was measured.
Specifically, an elevated flow tester shown in FIG. 1 was used. This consists of a vertically standing cylinder 2, a plunger (piston) that can move up and down in the cylinder 2, a die 4 disposed at the lower end of the cylinder 2, and a die presser 5 that fixes the die 4. The area A of the tip surface of the plunger 1 in the cylinder 2 is 1 cm ² , and the nozzle (discharge hole) provided in the die 4 has a diameter of 1 mm and a length of 1 mm.
First, the above-mentioned weighed sample 3 is placed in the cylinder 2 and the plunger 1 is inserted into the cylinder 2. Next, a load of 10 kgf is applied to the upper portion of the plunger 1 as a load P, and the apparatus is heated so that the temperature increase rate is 6.0 ° C./min.
Then, the temperature and the descending amount of the plunger 1 were measured, and the relationship between the two was graphed. The result is as shown in the plunger drop-temperature curve (flow tester outflow curve) in FIG. In FIG. 2, the temperature at the time when the sample 3 flows out from the nozzle of the die 4 is defined as an outflow start point (flow start temperature), and the height between the outflow start point and the highest point of the obtained S-shaped curve. When h is h, the temperature at h / 2 is the ½ method temperature.

[Film-forming properties]
Various emulsion samples obtained in Examples and Comparative Examples were applied to a corona-treated surface of an OPP film (Gunze Co., Ltd .: film thickness 50 μm) with a bar coater so as to have a film thickness of 10 μm. And dried.
The film transparency when dried at 80 ° C. for 5 minutes or 120 ° C. for 5 minutes was judged visually by the following criteria.
◎: Transparency, △ Some transparency, ×: No transparency

[Adhesion evaluation]
Various emulsion samples obtained in the examples and comparative examples were placed on a polypropylene plate (thickness 5 mm) so that the thickness of the dried film was 10 μm. 16 was applied. This was heat-dried in an 80 ° C. oven for 5 minutes to obtain a film.
Based on JIS-K5400 (cross-cut peeling tape method test), the obtained film was cut with a grid-like cut with a clearance of 5 mm, and then the cellophane tape (trade name, manufactured by Nichiban Co., Ltd.) ) Was pasted. Next, one to two minutes after applying the cellophane tape, one end of the tape was held and peeled off at a right angle, and the adhesion was evaluated according to the following criteria.
○: There was no peeling at a glance at the intersection of the cuts and the square.
Δ: The area of peeling was less than 65% of the square area.
X: The area of peeling was 65% or more of the square area.

<Raw materials>
[(A) component]
2-methacryloyloxyethyl succinic acid: manufactured by Kyoeisha Chemical Co., Ltd .: light ester HO-MS, hereinafter abbreviated as “HOMS”.
Β-carboxyethyl acrylate: Rhodia Nikka Co., Ltd .: SIPOMER β-CEA-J, hereinafter abbreviated as “β-CEA”.
Ω-carboxy-polycaprolactam monoacrylate (n is approximately 2): manufactured by Daiichi Kogyo Seiyaku Co., Ltd .: Aronix M-5300, hereinafter abbreviated as “M-5300”.
Mono (2-methacryloyloxyethyl) acid phosphate: manufactured by Kyoeisha Chemical Co., Ltd .: light ester PM, hereinafter abbreviated as “PM”.
Acrylamide-2-methylpropanesulfonic acid: manufactured by Toa Gosei Chemical Industry Co., Ltd .: ATBS, hereinafter abbreviated as “ATBS”.

[Component (B)]
Acrylic acid: manufactured by Mitsubishi Chemical Corporation, hereinafter abbreviated as “AA”.
Methacrylic acid: Mitsubishi Rayon Co., Ltd., hereinafter abbreviated as “MAA”.

[Component (C)]
N, N-dimethylaminoethyl methacrylate: Sanyo Chemical Industries, Ltd .: Methacrylate DMA, hereinafter abbreviated as “DMA”.

[(D) component]
Lauryl methacrylate: manufactured by Mitsubishi Rayon Co., Ltd., hereinafter abbreviated as “SLMA”.
・ Methyl methacrylate: manufactured by Mitsubishi Rayon Co., Ltd., hereinafter abbreviated as “MMA”.

[solvent]
Isopropyl alcohol: manufactured by Tokuyama Corporation, hereinafter abbreviated as “IPA”.
[Polyolefin resin for emulsification]
Polypropylene resin: Mitsui Chemicals, Inc .: Toughmer XM-7070

<Manufacture of polymer emulsifier>
(Production Example 1)
[Monomer adjustment]
IPA was added to a 50 L stainless steel bucket (addition amount was 5% by weight based on the total amount of monomers), and cooling was started in an ice bath while stirring. Subsequently, MMA and SLMA in amounts shown in Table 1 were added. Further, a mixture of AA, MAA, and HOMS in the amounts shown in Table 1 was added. Further, the amount of DMA described in Table 1 was gradually added dropwise so that the temperature did not exceed 25 ° C., to prepare a monomer mixture.

<Polymerization reaction>
A 100 L reactor equipped with a cooling pipe, a nitrogen introduction pipe, a stirrer, a dropping funnel and a heating jacket was charged with 30 kg of IPA and 20 kg of ion-exchanged water, and the internal temperature was adjusted to 80 ° C. while stirring. After the reaction vessel was purged with nitrogen, 4 kg of the monomer mixed solution was charged all at once. Furthermore, 0.4 kg of 2,2′-azobisisobutyronitrile (manufactured by Otsuka Chemical Co., Ltd., hereinafter abbreviated as “AIBN”) was added to initiate polymerization. Furthermore, the remaining monomer mixed solution 16Kg was dropped over 4 hours to carry out polymerization. While continuing the dropwise addition of the monomer mixture for 4 hours, 0.12 kg of the polymerization initiator was added 4 times every 1 hour. After completion of dropping under the monomer mixture, aging was performed for 2 hours.
The internal temperature rose from 80 to 83 ° C., water was added while distilling off the IPA, and the water was replaced to make 25% ammonia water (corresponding to the neutralization degree described in Table 1 of the total amount of AA, MAA and HOMS) After neutralization, a viscous acrylic copolymer neutralized aqueous solution was finally obtained. (Yield 97%).
Hereinafter, the obtained polymer emulsifier is referred to as “polymer emulsifier 1”.

(Production Examples 2 to 13)
Polymer emulsifiers 2 to 13 were obtained in the same manner as in Production Example 1 except that the respective monomers and the like described in Tables 1 and 2 were used.

Example 1
[Production of emulsion by kneader]
110 g of polypropylene resin is melted at 110 ° C. in a bi-directional kneader with different rotations (Irie Shokai Co., Ltd .: PBV-03), 23 g of the polymer emulsifier 1 is added and mixed for 5 minutes, and then ion-exchanged water. 110 g was added and mixed for 10 minutes, and the obtained milky white emulsion was used for evaluation. The results are shown in Table 3.

[Emulsion production by screw extruder (TEX-30)]
Polypropylene resin 83g / min is continuously supplied from the hopper of the same direction rotation meshing twin screw extruder (manufactured by Nippon Steel Works: TEX-30, double thread deep groove type, L / D = 31.5) did.
In addition, a polymer emulsifier of 18 g / min was pressurized with a gear pump (discharge pressure 3 Kg / cm ² G) continuously from the supply port provided in the vent portion of the extruder, and 101 g / min was supplied from the same place. While continuously supplying hot water with a plunger pump, the heating temperature (cylinder temperature, the same applies hereinafter) was continuously extruded at 110 to 130 ° C. (screw rotation speed: 300 rpm) to obtain a milky white emulsion. Evaluation was performed using the obtained emulsion. The results are shown in Table 3.

(Examples 2 to 10, Comparative Examples 1 to 3)
Instead of the polymer emulsifier 1, the same operation as in Example 1 was carried out except that the polymer emulsifiers 2 to 13 were used to obtain respective milky white emulsions. Evaluation was performed using the obtained emulsion. The results are shown in Tables 3-4.

Schematic showing an example of a flow tester used to measure 1/2 method temperature Plunger drop-temperature curve

Explanation of symbols

1 Plunger 2 Cylinder 3 Sample 4 Die 5 Die presser

Claims (10)

  A structural unit derived from a polymerizable monomer (component (A)) having a structure in which a polymerizable double bond and a hydrophilic group are bonded with a minimum of 4 to 16 atoms interposed therebetween. A polymer emulsifier containing 5 to 20 mol% as a copolymerizable component and having a 1/2 method temperature of 40 to 140 ° C. by a flow tester of the copolymer.   The polymeric emulsifier according to claim 1, wherein the polymerizable double bond is a double bond of a (meth) acryloyl group.   The polymer emulsifier according to claim 1 or 2, wherein the hydrophilic group is at least one selected from a carboxyl group, a sulfonic acid group, a phosphoric acid group, and an acidic phosphate group.   The polymeric emulsifier according to any one of claims 1 to 3, wherein the polymerizable monomer (component (A)) is 2-methacryloyloxyethyl succinic acid.   (B) component which consists of a carboxyl group-containing monomer, (C) component which consists of an amino group-containing monomer, and (meth) acrylic acid of a C1-C22 aliphatic alcohol as copolymerization components other than the said (A) component The polymer emulsifier according to any one of claims 1 to 4, wherein a component (D) comprising an ester is used.   The composition ratio of each component of the above (A), (B), (C), (D) is a molar ratio, (A) / (B) / (C) / (D) = 5-20 / 10 The polymer emulsifier according to claim 5, which is ˜40 / 5 to 40/7 to 50 (provided that the total amount is 100).   The total amount of the component (A) and the component (B) and the ratio of the component (C) are molar ratios ((A) + (B)) / (C) = 1.0 to 2.0. The polymer emulsifier according to claim 5 or 6.   The polymeric emulsifier according to any one of claims 5 to 7, wherein at least a part of the acidic hydrophilic group contained in the component (A) and the component (B) is neutralized with a basic substance.   A polyolefin resin emulsion obtained by emulsifying a polyolefin resin using the polymer emulsifier according to claim 1.   An adhesive for polyolefin resin using the polyolefin resin emulsion according to claim 9.

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