JP2009148254A - Method for producing freeze-dried molded product - Google Patents

Method for producing freeze-dried molded product Download PDF

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JP2009148254A
JP2009148254A JP2008305146A JP2008305146A JP2009148254A JP 2009148254 A JP2009148254 A JP 2009148254A JP 2008305146 A JP2008305146 A JP 2008305146A JP 2008305146 A JP2008305146 A JP 2008305146A JP 2009148254 A JP2009148254 A JP 2009148254A
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freeze
molded product
freezing
dried molded
fruit
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JP5386157B2 (en
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Atsushi Yokoyama
篤 横山
Toshio Sakuma
利男 佐久間
Chie Ohashi
千枝 大橋
Fumiyoshi Shibata
文佳 柴田
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Nippon Freeze Drying Co Ltd
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Nippon Freeze Drying Co Ltd
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Abstract

<P>PROBLEM TO BE SOLVED: To provide a method for producing a freeze-dried molded product having foaming property and easily reconstituted in cold water solution, and to provide a freeze-dried molded product. <P>SOLUTION: The method for producing a freeze-dried molded product comprises the following processes: a process of making fruit flesh into pasty one, and/or crushing or finely cutting the fruit flesh into a shape from which the characteristic texture of the fruit can be confirmed after reconstituted, and mixing the fruit flesh; a process of adding highly sweet sweetener, a gelling agent and acidifier to the fruit flesh mixture, and heating the mixture; a first freezing process of keeping the mixture to at a temperature of -5°C to -12°C for 6-8 hours; a second freezing process of freezing the mixture at ≤-25°C after the first freezing process; and a freeze dry process freezing and drying the mixture after the second freezing process; wherein the gelling agent comprises agar. The freeze-dried molded product is produced by the method. <P>COPYRIGHT: (C)2009,JPO&INPIT

Description

本発明は、起泡性を有する冷たい水溶液中で容易に復元する凍結乾燥成型品の製造方法、及び該製造方法により製造した凍結乾燥成型品に関する。   The present invention relates to a method for producing a freeze-dried molded product that is easily restored in a cold aqueous solution having foamability, and a freeze-dried molded product produced by the production method.

酒類などの飲料において果実類の風味を楽しむために、各種の果汁を酒類に入れて飲用に供する機会は多いが、果肉の固形分を砕いて入れて飲用に供することはあまりない。しかし、比較的プレーンな味わいの焼酎などのアルコール飲料に果肉が入っていると、果実の持っている特有の味と舌ざわりや食感、および適度な甘味や酸味とともに、飲酒の楽しみが倍加すると考えられる。   In order to enjoy the flavor of fruits in beverages such as alcoholic beverages, there are many occasions where various fruit juices are put in alcoholic beverages and used for drinking, but the solid content of fruit pulp is not crushed and used for drinking. However, alcoholic beverages such as shochu, which have a relatively plain taste, are thought to double the enjoyment of drinking, along with the peculiar taste and texture of the fruit, texture, and moderate sweetness and acidity. It is done.

しかしながら、飲酒の度に果実を調製すると、例えば果実の一部が必要であっても、必要量以上の果実を用意したり、さらに各種の器具類を用意したりする必要があるなど、かなりの手間を要する。また、果実類は一旦包丁などで処理すると、鮮度を保つための保管、管理が必要となり、鮮度が落ちたものは廃棄せざるを得ないため無駄も生じやすくなる。この手間を省くために、予め乾燥品として作製しておくことで、必要なときに必要な量だけを使用できる簡便性のあるものになる。   However, when the fruit is prepared every time alcohol is consumed, for example, even if a part of the fruit is necessary, it is necessary to prepare more fruits than necessary, and to prepare various instruments. It takes time and effort. In addition, once the fruits are processed with a kitchen knife or the like, it is necessary to store and manage the fruits to maintain their freshness. In order to save this time and effort, by making it as a dry product in advance, it becomes easy to use only the necessary amount when necessary.

また、水分を含む果汁果実類を直接アルコール飲料に投入すると、アルコール濃度が低下して味わいも変ってしまう。そのため、水分のない乾燥状態の固形分にして投入することで、アルコール濃度の低下なしに飲酒を楽しむことができる利点がある。
さらに、果汁・果肉を含む乾燥品をアルコール飲料に溶解・分散させたときに、液体内に果肉の粒や塊が残りつつ、全体にほぼ均等に分散している状態にあることで、見た目にも楽しみが持てる利点がある。
Moreover, when the fruit juice fruit containing a water | moisture content is directly injected into alcoholic beverages, alcohol concentration will fall and taste will also change. Therefore, there is an advantage that drinking can be enjoyed without lowering the alcohol concentration by adding the solid content in a dry state without moisture.
In addition, when a dried product containing fruit juice and pulp is dissolved and dispersed in an alcoholic beverage, the pulp particles and lump remain in the liquid, but are distributed almost evenly throughout the appearance, There are also benefits to having fun.

このような生鮮食品の乾燥方法として、凍結乾燥が知られている(例えば、特許文献1を参照)。凍結乾燥は、食品を凍結したままの状態で乾燥する方法であり、食品中の水分が凍結して氷になった結晶を、固体から気体に昇華させて水蒸気として除去するため、乾燥による形態の変化が生じにくく、新鮮時又は調理時の形態のまま多孔質の乾燥品を製造することができる。
このようにして得られる凍結乾燥品は、タンパク質の変性も生じにくく、ビタミンなどの栄養成分を維持すことができ、色や香りも保持しやすい上、多孔質に仕上がるために復元性や溶解性も良いなどの利点がある。
特開昭61−271946号公報
As a method for drying such fresh food, freeze-drying is known (see, for example, Patent Document 1). Freeze-drying is a method in which food is dried in a frozen state, and the crystals in which the water in the food is frozen and frozen are sublimated from solid to gas and removed as water vapor. It is difficult to change, and a porous dry product can be produced in a fresh or cooked form.
The lyophilized product thus obtained is less prone to protein denaturation, can maintain nutrients such as vitamins, is easy to retain its color and fragrance, and has a resilience and solubility due to its porous finish. There are also advantages such as good.
JP-A-61-271946

しかしながら、従来の方法で凍結乾燥した果実類は、起泡性の炭酸含有の飲料には、溶解・分散させようとしてもなかなか復元・分散しない。
これは果実そのものに含まれる成分、特に糖成分の存在により、凍結温度が低下(氷点降下)するためと考えられる。そのため、凍結乾燥工程で十分な昇華による凍結乾燥が行なわれず、局部的に融解現象を来たし、その部分が水分の浸入を阻害しやすく、溶液中で起泡して復元・分散の阻害要因となる。同様に果汁部分の発泡現象や、果肉部分の収縮なども生じるため、標榜する即席性を実現するような、例えば1分以内の短時間で復元するには至らず、また、果実部分の食感に違和感を来たす結果となることが多かった。
However, fruits lyophilized by conventional methods do not readily recover or disperse in foaming carbonic acid-containing beverages even if they are dissolved or dispersed.
This is thought to be due to the freezing temperature being lowered (freezing point lowered) due to the presence of components, particularly sugar components, contained in the fruit itself. Therefore, freeze-drying with sufficient sublimation is not performed in the freeze-drying process, resulting in a local melting phenomenon, which easily inhibits the ingress of moisture, and foams in the solution and becomes an inhibiting factor for restoration and dispersion . In the same way, foaming of the fruit juice part and shrinkage of the fruit part also occur, so that it can not be restored in a short time, for example within one minute, so as to realize instant improvisation, and the texture of the fruit part It often resulted in discomfort.

一般に凍結乾燥製品は、熱湯あるいは冷水で復元して喫食する方法が取られているが、本発明においては、低温でしかも気泡の発生している炭酸含有飲料、特に炭酸含有アルコール飲料中で容易に復元することに主眼点を置いている。   In general, freeze-dried products are reconstituted with hot or cold water and eaten, but in the present invention, it is easily used in carbonated beverages, particularly carbonated alcoholic beverages that are low in temperature and have bubbles. The main point is to restore.

また、飲用に供する際の容器として、グラスを使用するのが一般的であるが、例えば350ml容のグラスに入る程度の大きさに作製するには、比較的少ない容積の中に中身の濃い効果的な量を含ませる必要があると同時に、しっかりした成型性を保持することが生産性を上げる上で要求される。   In addition, glass is generally used as a container for drinking, but for producing a size that can fit into a 350 ml glass, for example, the effect of having a deep content in a relatively small volume In order to increase productivity, it is necessary to maintain a solid moldability.

このしっかりした成型性に関しては、乾燥する製品の固形分を上げることで可能であるが、その場合は復元性に問題が生じやすい。一方、復元性を良くするために製品の固形分を下げると、薄味のフルーティ性の欠落したものとなりやすい。この相反する二面性を解決することが課題であった。   This firm moldability can be achieved by increasing the solid content of the product to be dried. On the other hand, when the solid content of the product is lowered in order to improve the restoration property, it tends to be thin and lack of fruitiness. It was a problem to solve the conflicting two-sidedness.

本発明は、上記事情に鑑みてなされたものであり、フルーティで濃厚な味わいと成型性を保持するとともに、起泡性を有する冷たい水溶液中で容易に復元する凍結乾燥成型品の製造方法、及び凍結乾燥成型品を提供することを目的とする。   The present invention has been made in view of the above circumstances, and maintains a fruity and rich taste and moldability, and a method for producing a freeze-dried molded product that can be easily restored in a cold aqueous solution having foamability, and An object is to provide a freeze-dried molded product.

本発明者らは、上記目的を達成するため鋭意研究を行った結果、甘味料として高甘味度甘味料を用いるとともに、成型性を保持するゲル化剤を添加し、さらに凍結工程を2段階で行なうことで、得られる凍結乾燥成型品の成型性と復元性が向上することを見出し、本発明を完成させた。すなわち、本発明は以下の構成を採用する。   As a result of intensive studies to achieve the above object, the present inventors have used a high-intensity sweetener as a sweetener, added a gelling agent that retains moldability, and further has a freezing process in two stages. As a result, it was found that the moldability and restoration property of the resulting freeze-dried molded product were improved, and the present invention was completed. That is, the present invention adopts the following configuration.

[1] 本発明は、起泡性を有する冷たい水溶液中で容易に復元する凍結乾燥成型品の製造方法であって、
果実果肉をペースト化し、及び/又は復元後にその特徴的テクスチャーが確認できる形状に、前記果実果肉を粗砕もしくは細断し、これらを混合する工程と、
高甘味度甘味料と、ゲル化剤と、酸味料を加えてさらに混合して加熱する工程と、
その混合体を、−5℃〜−12℃の温度で6〜8時間保持する第1凍結工程と、
前記第1凍結工程の後、−25℃以下の温度で凍結する第2凍結工程と、
前記第2凍結工程の後、凍結乾燥する凍結乾燥工程と、を有することを特徴とする凍結乾燥成型品の製造方法を提供するものである。
[2] また、本発明は、前記ゲル化剤が、寒天であることを特徴とする前記[1]記載の凍結乾燥成型品の製造方法を提供するものである。
[3] また、本発明は、前記高甘味度甘味料が、スクラロース、グリチルリチン酸ナトリウム、アスパルテーム、ステビアからなる群より選ばれるいずれか1以上であることを特徴とする前記[1]または[2]に記載の凍結乾燥成型品の製造方法を提供するものである。
[4] また、本発明は、前記混合体が、固形分含有率が9〜15%であることを特徴とする前記[1]〜[3]の何れかに記載の凍結乾燥成型品の製造方法を提供するものである。
[5] また、本発明は、前記酸味料が、クエン酸であることを特徴とする前記[1]〜[4]の何れかに記載の凍結乾燥成型品の製造方法を提供するものである。
[6] また、本発明は、前記[1]〜[5]の何れか記載の凍結乾燥成型品の製造方法によって製造された凍結乾燥成型品を提供するものである。
[1] The present invention is a method for producing a freeze-dried molded product that is easily restored in a cold aqueous solution having foaming properties,
Crushing or chopping the fruit pulp into a shape in which the fruit pulp is pasted and / or its characteristic texture can be confirmed after restoration, and mixing them;
Adding a high-intensity sweetener, a gelling agent, a sour agent, and further mixing and heating;
A first freezing step of holding the mixture at a temperature of −5 ° C. to −12 ° C. for 6 to 8 hours;
A second freezing step of freezing at a temperature of −25 ° C. or lower after the first freezing step;
And a freeze-drying step of freeze-drying after the second freezing step. A method for producing a freeze-dried molded product is provided.
[2] Further, the present invention provides the method for producing a freeze-dried molded product according to [1], wherein the gelling agent is agar.
[3] In the present invention, the high-intensity sweetener is any one or more selected from the group consisting of sucralose, sodium glycyrrhizinate, aspartame, and stevia. ] The manufacturing method of the freeze-dried molded product described in the above.
[4] Moreover, the present invention provides the freeze-dried molded article according to any one of [1] to [3], wherein the mixture has a solid content of 9 to 15%. A method is provided.
[5] The present invention also provides the method for producing a freeze-dried molded product according to any one of [1] to [4], wherein the acidulant is citric acid. .
[6] Further, the present invention provides a freeze-dried molded product produced by the method for producing a freeze-dried molded product according to any one of [1] to [5].

本発明の凍結乾燥成型品の製造方法によれば、果実果肉をペースト化し、及び/又は復元後にその特徴的テクスチャーが確認できる形状に、前記果実果肉を粗砕もしくは細断してこれらを混合し、高甘味度甘味料と、ゲル化剤と、酸味料を加えてさらに混合して加熱することで、固形分が低下するため、氷点降下を起こすことなく凍結乾燥することができ、凍結乾燥後もフルーティで濃厚な味わいと成型性を保持することができる。
さらに、その混合体を、−5℃〜−12℃の温度で6〜8時間保持する第1凍結工程と、−25℃以下の温度で凍結する第2凍結工程との2段階による凍結を行なった後、凍結乾燥することで、果実果肉中の水分が凍結する結晶が大きくなり、成型性と復元性が向上して、起泡性を有する冷たい水溶液中で容易に復元する凍結乾燥成型品を製造することができる。
According to the method for producing a freeze-dried molded product of the present invention, the fruit pulp is pasted and / or crushed or shredded into a shape in which the characteristic texture can be confirmed after restoration, and these are mixed. Addition of high-intensity sweetener, gelling agent, and sour agent, and further mixing and heating can reduce the solid content, so that it can be lyophilized without lowering the freezing point. Even fruity and rich taste and moldability can be maintained.
Furthermore, the mixture is frozen in two steps: a first freezing step in which the mixture is held at a temperature of −5 ° C. to −12 ° C. for 6 to 8 hours, and a second freezing step in which the mixture is frozen at a temperature of −25 ° C. or lower. After freeze-drying, the freeze-dried molded product can be easily restored in a cold aqueous solution with foaming properties by increasing the crystals that freeze the water in the fruit pulp, improving the moldability and recoverability. Can be manufactured.

本発明は、起泡性を有する冷たい水溶液中で容易に復元する凍結乾燥成型品の製造方法であって、果実果肉をペースト化し、及び/又は復元後にその特徴的テクスチャーが確認できる形状に、前記果実果肉を粗砕もしくは細断し、これらを混合する工程と、高甘味度甘味料と、ゲル化剤と、酸味料を加えてさらに混合して加熱する工程と、その混合体を、−5℃〜−12℃の温度で6〜8時間保持する第1凍結工程と、前記第1凍結工程の後、−25℃以下の温度で凍結する第2凍結工程と、前記第2凍結工程の後、凍結乾燥する凍結乾燥工程と、を有することを特徴とする。   The present invention is a method for producing a freeze-dried molded product that is easily reconstituted in a cold aqueous solution having foaming properties, wherein the fruit flesh is pasted and / or the shape whose characteristic texture can be confirmed after reconstitution is described above. Crushing or shredding fruit pulp, mixing these, adding high sweetness, gelling agent, acidulant, and heating and mixing the mixture, After the first freezing step, the second freezing step for freezing at a temperature of −25 ° C. or lower after the first freezing step, and after the second freezing step. And a freeze-drying step of freeze-drying.

飲用者の心理を忖度すると、凍結乾燥成型品を、起泡性を有する冷たい水溶液に投入した後、見ている間に速やかに復元することが良好である。そこで、本発明及び本願明細書中においては、凍結乾燥成型品を投入後、水溶液中で2分間以内に復元・分散する場合に、当該凍結乾燥成型品が「容易に復元する」と表現した。   If a drinker's psychology is deepened, it is good to restore | restore rapidly while seeing, after putting a freeze-dried molded article into the cold aqueous solution which has foamability. Therefore, in the present invention and the specification of the present application, when the freeze-dried molded product is charged and restored and dispersed within 2 minutes in an aqueous solution, the freeze-dried molded product is expressed as “easy to restore”.

(果実果肉)
本発明に用いる果実果肉は、特に限定されるものではなく、一般に食用される果実果肉であればよい。好ましくは、ブルーベリー、マンゴー、ピーチ、ブラックカーラント(カシス)、リンゴ、イチゴ、ウメ、キウイフルーツ、パインアップルなどである。これらは凍結乾燥後に溶液中で溶解・復元させても果実果肉の形状が保持されやすく、飲用の際にその特徴的なテクスチャーを確認することができる。これらの果実果肉は、果実全体を用いても、果実の一部であってもよい。リンゴなどのように皮が硬い果実は、予め剥皮して用いてもよい。
また、生鮮の状態で用いることが好ましいが、加工された状態であってもよく、例えば、収穫時に冷凍された果実果肉を解凍して用いることもできる。
(Fruit pulp)
The fruit pulp used for this invention is not specifically limited, What is necessary is just the fruit pulp generally edible. Preferred are blueberry, mango, peach, black currant (cassis), apple, strawberry, plum, kiwifruit, pineapple and the like. Even if these are dissolved and reconstituted in a solution after lyophilization, the shape of the fruit pulp is easily maintained, and its characteristic texture can be confirmed during drinking. These fruit pulps may use the whole fruit or may be a part of the fruit. A fruit having a hard skin such as an apple may be peeled in advance.
Although it is preferably used in a fresh state, it may be in a processed state. For example, it can be used by thawing fruit pulp frozen at the time of harvest.

(ペースト化)
果実果肉をペースト化する方法としては、例えば、ミキサーなどで破砕すればよい。または、市販のピューレやペーストを用いてもよい。
(Paste)
For example, the fruit pulp may be crushed with a mixer or the like. Alternatively, a commercially available puree or paste may be used.

(粗砕もしくは細断化)
特徴的テクスチャーが確認できる形状とは、果実果肉が有する特有の食感が確認できる形状になることを言う。具体的には、歯切れ、歯ざわり、のどごし、組織の形状や質感などが確認でき、例えば、リンゴならば少し硬めのサクサク感、マンゴーならば軟らかいヌメリ感、カシスならば口の中でプチッと潰れるような食感などが確認できる形状である。
このような果実果肉の特徴的テクスチャーが確認できる形状に、果実果肉を粗砕もしくは細断する方法としては、例えば、包丁などを用いてダイス状に切ればよい。好ましくは2〜10mm、より好ましくは3〜8mm、さらに好ましくは3〜5mmのダイス状にする。
(Crushed or shredded)
The shape in which the characteristic texture can be confirmed refers to the shape in which the unique texture of the fruit pulp can be confirmed. Specifically, you can check the crispness, texture, throat, tissue shape, texture, etc. For example, apples are a little hard and crunchy, mangoes are soft and slimy, and cassis is crushed in the mouth. It is a shape that can confirm such texture.
As a method for crushing or chopping the fruit pulp into a shape in which such a characteristic texture of the fruit pulp can be confirmed, for example, it may be cut into a dice using a knife or the like. Preferably it is 2-10 mm, More preferably, it is 3-8 mm, More preferably, it is 3-5 mm dice shape.

(水溶液)
起泡性を有する冷たい水溶液とは、例えば10℃以下、好ましくは5℃以下の、炭酸飲料や気泡性アルコール飲料などのことである。
例えば、チューハイのような起泡性のアルコール飲料に、各種の果汁類を混合して供することは一般的に行われているが、果肉が入っていれば、より本物感を味わうことができる。また、果肉でもピューレなどよりも、形のある果肉自体を投入することで、さらに高い満足感が得られる。
(Aqueous solution)
The cold aqueous solution having foamability is, for example, a carbonated beverage or a foamed alcoholic beverage having a temperature of 10 ° C. or lower, preferably 5 ° C. or lower.
For example, it is a common practice to mix various types of fruit juices with a foaming alcoholic beverage such as Chuhai, but if the pulp is contained, it can be more authentic. In addition, more satisfactory satisfaction can be obtained by adding shaped pulp itself than puree.

通常、このような果実・果汁の調製には、破砕のための器具類、その調製品を一時収納する容器類の準備、およびその使用後の後始末など、かなりの手間を必要とする。
ところが、果実果肉を小型の1個/1杯分ずつの乾燥品にすれば、使用に際しては器具類・容器類の準備も不要で、しかも短時間で済む。そして、この乾燥品を飲料に投入して、飲用前に復元させることで、生鮮果実と同様に高い満足感が得られることを見出した。
なお、復元とは、この溶液中の水分などが凍結乾燥成型品の乾燥した組織や空隙に浸入して、凍結乾燥前の形状や組織に近い状態になることである。
Usually, preparation of such fruit and fruit juice requires considerable labor, such as preparation of equipment for crushing, preparation of containers for temporarily storing the preparation, and cleaning up after use.
However, if the fruit flesh is made into small, one-by-one, dried products, it is not necessary to prepare instruments and containers for use, and it takes a short time. And it discovered that high satisfaction could be obtained like fresh fruit by throwing this dried product into a drink, and making it restore before drinking.
In addition, restoration | restoration is that the water | moisture content etc. in this solution penetrate | invade into the dry structure | tissue and space | gap of a freeze-dried molded article, and will be in the state close | similar to the shape and structure | tissue before lyophilization | freeze-dry.

しかしながら、従来の方法では価格的に高額になり、適用するチューハイに使用するには一般性が低くなるため、これらを商品化するにあたり、コンパクトなサイズにすることと、それに合わせた味の調整が必要であった。さらに乾燥品を取り扱う作業性を考慮して、型崩れのない適度な堅さを有し、しかも迅速に溶解・分散するような状態にする加工する方法を検討した。   However, the conventional method is expensive in price and less general for use in applied chu-hi, so when commercializing these, it is necessary to make them compact and adjust the taste accordingly. It was necessary. In addition, considering the workability of handling dried products, we studied a method of processing that has a moderate hardness without losing shape and that can be quickly dissolved and dispersed.

(溶解・分散性を良好にする手段)
凍結乾燥は、食品を凍結したままの状態で乾燥する方法であり、食品中の水分が凍結して氷になった結晶を、固体から気体に昇華させて水蒸気として除去するため、乾燥による形態の変化が生じにくく、新鮮時又は調理時の形態のまま多孔質の乾燥品を製造することができる。このようにして得られる凍結乾燥品は、タンパク質の変性も生じにくく、ビタミンなどの栄養成分を維持すことができ、色や香りも保持しやすい。
(Means for improving solubility and dispersibility)
Freeze-drying is a method in which food is dried in a frozen state, and the crystals in which the water in the food is frozen and frozen are sublimated from solid to gas and removed as water vapor. It is difficult to change, and a porous dry product can be produced in a fresh or cooked form. The freeze-dried product thus obtained is less prone to protein denaturation, can maintain nutrients such as vitamins, and easily retains color and fragrance.

凍結乾燥品は、その多孔質構造のゆえに復元性が良いとされ、多くの場合、熱湯を使用して復元に供するので、乾燥品中への浸入は比較的迅速である。しかし、本発明は、冷たい、しかも起泡性のある水溶液中での復元を目的にしているので、このような水溶液中に従来の乾燥品を投入した場合、乾燥品の表面に泡を生じ、その現象により復元が阻害されて遅延を来たす結果となる。   The freeze-dried product is considered to have good restorability due to its porous structure, and in many cases, it is used for restoration using hot water, so that the infiltration into the dry product is relatively quick. However, since the present invention aims at restoration in a cold and foaming aqueous solution, when a conventional dry product is introduced into such an aqueous solution, bubbles are generated on the surface of the dry product, This phenomenon hinders restoration and results in a delay.

その障碍を解決するべく着目した点が、凍結工程における操作である。一般的には、緩慢凍結法を採用することで、凍結工程における氷結晶の生成が大きくなり、その氷結晶の痕跡が昇華による乾燥後の空隙の大きい状態を作り出し、水分の浸入のための通路が確保されて復元が容易になることが知られている。しかし、単にこの緩慢凍結法を採用したとしても、肉や野菜の場合とは異なり、ペースト化した状態の果実や果肉類の小片を含んだしっかりした組織を持たない流動性のある食品においては、固形分と純粋の水分との分離がより多く生じやすく、局部的な部分で溶質の濃縮化が著しく生じてしまい、十分な凍結状態を保持し得ず、その部分が凍結乾燥の工程で発泡して、きれいな成型状態を維持できなくなり、結果として復元し難い乾燥品となってしまう。本発明においては、この欠点を解消するために、以下に記載する二段階の凍結工程を行うことに加えて、ゲル化剤、特に好ましくは低ゼリー強度を有する寒天を使用した。   The point which paid attention in order to solve the obstacle is operation in a freezing process. In general, by adopting the slow freezing method, the formation of ice crystals in the freezing process increases, and the traces of the ice crystals create a large state of voids after drying by sublimation, and the passage for moisture infiltration It is known that restoration is facilitated. However, even if this slow freezing method is adopted, unlike in the case of meat and vegetables, in a fluid food that does not have a solid tissue containing small pieces of pasty fruit and pulp, The separation of solids and pure water is more likely to occur, the concentration of solutes in the local part is significantly increased, and it is not possible to maintain a sufficient frozen state, and that part is foamed in the freeze-drying process. As a result, a beautiful molded state cannot be maintained, resulting in a dry product that is difficult to restore. In the present invention, in order to eliminate this drawback, in addition to performing the two-stage freezing process described below, a gelling agent, particularly preferably agar having low jelly strength, was used.

(甘味材の選択)
先ず、味の調整を行ったところ、甘味と酸味を強化した方が良いとの方向性から、甘味には砂糖の使用を、酸味にはクエン酸の使用を検討した。しかし、量産を考慮したコンパクトなサイズの制限の下、しかもたっぷり量の果実類の使用が必要とされる条件では、砂糖を使用した結果、果実類との混合体は凍結の工程で氷点降下の現象を来たした。また、一部には果実中の糖類成分と砂糖からなる濃縮部の現出を来たし、通常の−25℃程度の凍結庫では、十分に凍結し得ずに凍結乾燥に供される部分があり、乾燥の工程で発泡する現象を来たした。
(Selection of sweetener)
First, when the taste was adjusted, the use of sugar for sweetness and the use of citric acid for sourness were examined from the direction that sweetness and sourness should be enhanced. However, under conditions where compact size is limited in consideration of mass production and the use of plenty of fruits is required, the use of sugar will result in a freezing point drop in the mixture with fruits. Came the phenomenon. In addition, some of the fruits come out with a concentrated portion consisting of sugar components and sugar in the fruit, and in a normal freezer at about -25 ° C, there is a portion that cannot be fully frozen and used for lyophilization. The foaming phenomenon occurred during the drying process.

この発泡現象は、結果として膨らみのある乾燥品となり、形状の一定性を保持できず、また、吸湿性の増大を招くことになる。その他の糖類においても、呈味的に砂糖には匹敵し得ず、同様に凍結工程においては氷点降下の現象を生ずる。   This foaming phenomenon results in a swelled dry product, the shape cannot be kept constant, and the hygroscopicity is increased. Other sugars cannot be tastefully compared to sugar, and similarly, the freezing point phenomenon occurs in the freezing process.

そこで、この氷点降下の現象に影響しない程度の量で使用できる甘味料として、高甘味度甘味料の使用を検討した。高甘味度甘味料としては、例えば、グリチルリチン酸ナトリウム、アスパルテーム、ステビア、スクラロースが好ましく、凍結乾燥後の各種果実類への味のなじみ度をパネルにより官能評価した結果、スクラロース(化学名:トリクロロガラクトスクロース)が特に好ましい。これはごく少量の使用で砂糖に近い甘味を呈し、しかも凍結工程における氷点降下の現象が観られないことが確認できた。その濃度は、凍結乾燥に供する果実や果肉によって多少の差はあるが、溶液(混合体)中の0.01〜0.10%あれば良く、その効果は砂糖の600倍に相当すると言われている。実際に、甘味料として砂糖単独を用いて調整した試料と、同程度の甘味を有するようにスクラロース単独を用いて調整した試料とを比較すると、乾燥工程において、砂糖使用の試料では50%以上に発泡現象が観られたが、スクラロース使用の試料では発泡現象は観られないことが確認できた。   Therefore, the use of a high-intensity sweetener was examined as a sweetener that can be used in an amount that does not affect the phenomenon of freezing point depression. As the high-sweetness sweetener, for example, sodium glycyrrhizinate, aspartame, stevia, and sucralose are preferable. As a result of sensory evaluation of the familiarity of various lyophilized fruits with a panel, sucralose (chemical name: trichlorogalacto) Sucrose) is particularly preferred. It was confirmed that it exhibited sweetness similar to sugar with a very small amount of use, and that no freezing point phenomenon was observed in the freezing process. The concentration is somewhat different depending on the fruit and pulp subjected to freeze-drying, but it is sufficient to be 0.01-0.10% in the solution (mixture), and the effect is said to be equivalent to 600 times that of sugar. ing. In fact, when comparing a sample prepared using sugar alone as a sweetener and a sample prepared using sucralose alone to have the same degree of sweetness, in the drying process, the sample using sugar was 50% or more. Although the foaming phenomenon was observed, it was confirmed that the foaming phenomenon was not observed in the sample using sucralose.

(酸味料)
酸味料は、一般的に食用に用いられる酸味のある成分であれば、特に限定されるものではないが、果実果肉の風味を損なわない酸味料が好ましい。例えば、クエン酸、リンゴ酸、酒石酸、乳酸などが挙げられる。特に好ましくは、クエン酸である。
酸味料の濃度は、例えば、0.01〜1.0%程度にすればよく、好ましくは0.02〜0.7%である。
(Acidulant)
The acidulant is not particularly limited as long as it is a sour component generally used for food, but an acidulant that does not impair the flavor of the fruit pulp is preferable. For example, citric acid, malic acid, tartaric acid, lactic acid and the like can be mentioned. Particularly preferred is citric acid.
The concentration of the sour agent may be, for example, about 0.01 to 1.0%, and preferably 0.02 to 0.7%.

(固形分含有率)
小型のブロック状の形状の保持、乾燥品の包装作業等に支障を来たさないような堅さ、そして凍結および凍結乾燥の工程でトラブルの発生のないこと、さらに何よりも気泡性を有する液体中での復元、等の条件を考慮すると、乾燥に供する混合体の固形分含有率を、各種のテストの結果15%を超えると所望する状態にはなりにくいと判断し、効果的な範囲を12%前後と見込んだが、製品による構成成分、特に果実自体に含まれる糖類の相違による対凍結乾燥性などから9〜15%の範囲が適当とした。
(Solid content)
Liquid that has a small block-like shape, does not interfere with the packaging of dried products, and has no trouble in freezing and freeze-drying processes. In consideration of conditions such as restoration in the interior, the solid content of the mixture subjected to drying is determined to be less likely to be in a desired state when the result of various tests exceeds 15%. Although it is estimated to be around 12%, the range of 9 to 15% is appropriate from the viewpoint of freeze-drying properties due to differences in the constituent components of the product, particularly the sugars contained in the fruit itself.

(ゲル化剤)
通常、溶液状あるいはペースト状の製品を小型の成型容器に注入して凍結乾燥し、一定の大きさのブロック状にする際に、ある程度の粘性を付与する。成型容器に注入された果肉の固形成分を含む溶液あるいはペーストが一部沈降したりせずに、ほぼ均等な状態を維持し、さらに予備凍結工程が完了するまでにその中の水分が遊離しての移動を最小限に抑制し、全体がその均等な状態を保持した凍結乾燥製品にするためである。その成分として、ゲル化剤を用いることとした。
(Gelling agent)
Usually, a solution or paste-like product is poured into a small molding container and freeze-dried to give a certain degree of viscosity when it is made into a block of a certain size. The solution or paste containing the solid components of the pulp injected into the molding container does not settle partially, maintains an almost uniform state, and the water in it is released before the preliminary freezing process is completed. This is to minimize the movement of the lyophilized product and keep the entire state in a lyophilized product. A gelling agent was used as the component.

ゲル化剤としては、カラギーナン、ゼラチン、寒天、ファーセルラン等が挙げられ、このうち、寒天が好ましく、低ゼリー強度の寒天が特に好ましい。低ゼリー強度とは、緩やかに形状を保持しながらも、復元性や溶解性を阻害しない程度の硬さであり、例えば、寒天ならば、混合体における濃度を0.01〜2.0%程度にすればよく、好ましくは0.1〜1.0%である。例えば、ウルトラ寒天AX−100(伊那食品工業社製)が挙げられる。   Examples of the gelling agent include carrageenan, gelatin, agar, and farcellan. Among them, agar is preferable, and agar with low jelly strength is particularly preferable. The low jelly strength is a hardness that does not hinder the restorability and solubility while maintaining a gentle shape. For example, in the case of agar, the concentration in the mixture is about 0.01 to 2.0%. And preferably 0.1 to 1.0%. For example, Ultra Agar AX-100 (manufactured by Ina Food Industry Co., Ltd.) can be mentioned.

このようなゲル化剤を使用することにより、そのゲル化性およびそれに伴う成分の均等性の保持、果実類へのなじみ性が優れ、さらに凍結乾燥後の成型性、低温での分散性、乾燥品の形状の保持性においても、その効果を発揮し得る。
また、ゲル化剤の使用により固定化された果実ペースト・果肉の混合体は、固形分と水分とが分離しない状態を維持しつつ、比較的大きい氷結晶を形成させることができる。
By using such a gelling agent, its gelling property and the uniformity of the components accompanying it, excellent compatibility with fruits, moldability after freeze-drying, dispersibility at low temperature, drying The effect can be exhibited also in the retainability of the shape of the product.
Moreover, the fruit paste / fruit pulp mixture immobilized by the use of a gelling agent can form relatively large ice crystals while maintaining a state in which the solid content and moisture are not separated.

なお、一般的に即席みそ汁類・即席スープ類などの凍結乾燥製品には、でんぷん類、ペクチンやガム類などがゲル化剤として使用されるが、でんぷんやゼラチン、ペクチンを果実果肉に使用してみたところ、凍結工程までの均質性の保持には有効であったが、凍結乾燥後に冷たい焼酎等のアルコール飲料に適用すると、復元性及び分散性の乏しいものであった。   In general, freeze-dried products such as instant miso soups and instant soups use starches, pectin and gums as gelling agents, but starch, gelatin and pectin are used in fruit pulp. As a result, it was effective in maintaining homogeneity until the freezing step, but when applied to alcoholic beverages such as cold shochu after lyophilization, it was poor in restorability and dispersibility.

(混合加熱工程)
ペースト化された果実果肉、及び/又は粗砕もしくは細断された果実果肉を混合した後、高甘味度甘味料と、ゲル化剤と、酸味料を加えてさらに混合して加熱する。このとき、水や香料などを加えてもよい。
ペースト化された果実果肉と、粗砕もしくは細断された果実果肉の混合比は、特に限定されるものではなく、果実の種類にもよるが、例えば1:10〜10:1程度に混合すればよい。
(Mixing heating process)
After the pasted fruit pulp and / or the crushed or shredded fruit pulp are mixed, a high-intensity sweetener, a gelling agent, and an acidulant are added and further mixed and heated. At this time, water or a fragrance may be added.
The mixing ratio between the pasted fruit pulp and the crushed or shredded fruit pulp is not particularly limited, and depending on the type of fruit, for example, it may be mixed to about 1:10 to 10: 1. That's fine.

加熱温度は、特に制限はないが、80〜100℃が好ましい。また、加熱前にゲル化剤を予め湿潤させておくことが好ましく、その他の材料と混合した後、例えば10分程度ゆっくり攪拌すればよい。その後、同様にゆっくり攪拌しながら、加熱して混合する。   The heating temperature is not particularly limited, but is preferably 80 to 100 ° C. Moreover, it is preferable to pre-wet the gelling agent before heating, and after mixing with other materials, for example, it may be slowly stirred for about 10 minutes. Then, heat and mix with slow stirring as well.

(凍結工程)
果実の種類によって多少の温度巾はあるが、まず温度−5〜−12℃、好ましくは−6〜−8℃で凍結することにより、良好な氷結晶生成を開始する第1凍結工程を6〜8時間保持し、次に−25℃以下、好ましくは−25〜−35℃、より好ましくは−30〜−35℃で凍結することにより、この時点で未凍結の水分を氷結晶の生長に使用させる第2凍結工程からなる2段階の凍結工程である。
(Freezing process)
Although there are some temperature ranges depending on the type of fruit, first, the first freezing step for starting good ice crystal formation by freezing at a temperature of −5 to −12 ° C., preferably −6 to −8 ° C. Hold for 8 hours and then use the unfrozen water to grow ice crystals at this point by freezing at -25 ° C or lower, preferably -25 to -35 ° C, more preferably -30 to -35 ° C This is a two-stage freezing process comprising a second freezing process.

このように、第1凍結工程として、−5〜−12℃という氷点下の比較的高い温度で氷結晶生成を開始させた後、第2凍結工程として、−25℃以下で、生成された氷結晶を成長させることにより、未凍結の水分を十分に凍結させることができ、かつ十分に大きな氷結晶を得ることができる。
また、凍結工程の前処理として、抗酸化処理、着色変色防止処理、殺菌、軟化、pH調整などを行なってもよい。
Thus, after starting ice crystal generation at a relatively high temperature below the freezing point of −5 to −12 ° C. as the first freezing step, ice crystals generated at −25 ° C. or lower as the second freezing step By growing the crystal, unfrozen water can be sufficiently frozen and sufficiently large ice crystals can be obtained.
Further, as a pretreatment for the freezing step, an antioxidant treatment, a coloring discoloration prevention treatment, sterilization, softening, pH adjustment, and the like may be performed.

(凍結乾燥工程)
次に、凍結乾燥工程に移すと、この生長した大きな氷結晶が昇華により消失して、空隙が比較的大きいものとなり、復元の容易な乾燥品となる。
凍結乾燥工程は、6.12hPa以下の真空条件下で、エネルギーを加えて行なうことが好ましい。例えば80Pa以下を維持しながら、製品温度が例えば45℃を超えることのないようにコントロールして行えばよい。
(Freeze drying process)
Next, when transferred to a freeze-drying process, the grown large ice crystals disappear by sublimation, and the voids are relatively large, resulting in a dry product that can be easily restored.
The freeze-drying step is preferably performed by applying energy under a vacuum condition of 6.12 hPa or less. For example, the product temperature may be controlled so as not to exceed 45 ° C. while maintaining 80 Pa or less.

このようにすることで、食品中の氷の昇華によって乾燥が進むため、乾燥により収縮や亀裂など形態の変化が生じにくく、新鮮時や調理時の形態のまま多孔質の乾燥品となる。また、昇華促進のため加熱操作が加えられても、乾燥過程においては0℃以下の低温領域で乾燥が進行し、終期においても常温に近いため、乾燥中に極端な成分変化が起こらず、色・味・栄養成分等を保持したままの乾燥品となり、復元時にその食品本来の特性が生きる。   By doing in this way, since drying advances by the sublimation of the ice in a foodstuff, a change of form, such as a shrinkage | contraction and a crack, does not arise easily by drying, and it becomes a porous dry product with the form at the time of freshness or cooking. Even if a heating operation is applied to promote sublimation, the drying proceeds in a low temperature region of 0 ° C. or lower in the drying process and is close to room temperature even in the final stage, so that no extreme component change occurs during drying.・ It becomes a dry product that retains its taste and nutritional components, and the original characteristics of the food survive when restored.

また、空隙があらゆる所にあるような多孔質に仕上がるため、復元性及び分散性が非常に高い。
さらに、全重量の5%以下の非常に低水分まで乾燥できるため、包装等でその水分状態を維持すれば相当長期にわたる保管が可能である。しかも、常温の保管が可能であり、非常に軽量となるため輸送性が高い。
In addition, since it is finished in a porous form with voids everywhere, it has very high resilience and dispersibility.
Furthermore, since it can be dried to a very low moisture content of 5% or less of the total weight, it can be stored for a considerably long time if the moisture state is maintained by packaging or the like. In addition, it can be stored at room temperature and is very lightweight, so it is highly transportable.

以上説明したように、本発明の凍結乾燥成型品の製造方法によれば、高甘味度甘味料、ゲル化剤及び酸味料を用い、−5〜−12℃という氷点下の比較的高い温度での凍結及び−25℃以下での凍結という2段階の凍結工程を行い、その後凍結乾燥することで、成型性のしっかりした、起泡性の冷たい溶液中での復元性・分散性の良い凍結乾燥成型品を製造することができる。   As described above, according to the method for producing a freeze-dried molded product of the present invention, a high-intensity sweetener, a gelling agent and a sour agent are used, and at a relatively high temperature below the freezing point of −5 to −12 ° C. Freeze-drying molding with two steps of freezing and freezing at -25 ° C or lower, followed by freeze-drying, which has good moldability and good resilience and dispersibility in a foaming cold solution Product can be manufactured.

「実施例1」(カシス)
冷凍ブラックカーラント(カシス)果実をミキサーにて破砕し、粗めのペーストにし、これを350g用意した。別に、同じ冷凍ブラックカーラント果実を、凍結状態を少し緩めにして、ナイフにて4〜5mmのダイス状になるようにカットし、これを270g用意した。
"Example 1" (cassis)
Frozen black currant (cassis) fruit was crushed with a mixer to make a coarse paste, and 350 g of this was prepared. Separately, the same frozen black currant fruit was slightly loosened and cut with a knife into a 4-5 mm die, and 270 g of this was prepared.

これらを混合してベースとし、スクラロース0.5g、クエン酸10g、寒天2g、カシス香料0.7gを加えて混合し、さらに水400gを加えて分散溶液とした。この分散溶液を、寒天の湿潤のために約10分間ゆっくり撹拌した。その後、同様にゆっくり撹拌しながら80℃まで加熱して寒天を溶解し、3分間保持した後、攪拌しながら冷却した。60℃くらいになった時点で、プラスチック製小型成型トレーに注入した。この小型成型トレーはテーパー付で、その高さの中間部分の寸法は縦35.2mm、横40.3mm、高さ19mmで、容積はほぼ27mlであり、各区画に27gずつ注入して37区画分を得た。   These were mixed to form a base, and 0.5 g of sucralose, 10 g of citric acid, 2 g of agar, and 0.7 g of cassis flavor were added and mixed, and 400 g of water was further added to obtain a dispersion solution. The dispersion was slowly stirred for about 10 minutes to wet the agar. Thereafter, similarly, the mixture was heated to 80 ° C. with slow stirring to dissolve the agar, held for 3 minutes, and then cooled with stirring. When it reached about 60 ° C., it was poured into a small plastic tray. This small molded tray has a taper, the middle part of its height is 35.2mm in length, 40.3mm in width, 19mm in height, and the volume is approximately 27ml. Got the minute.

これを常温条件下に1時間静置して冷却し、ほぼ常温に達し、溶液が軽度のゲル化した状態を確認してから−8℃条件下の凍結庫に移し、凍結工程に供した。8時間経過後、全体が−8℃のほぼ軽い凍結状態にあることを確認して、さらに低温の−25℃の条件下に移し、その6時間後に強度の凍結状態になったことを確認して凍結乾燥に供した。   The solution was allowed to stand for 1 hour under normal temperature conditions and cooled. The temperature reached almost normal temperature. After confirming that the solution was slightly gelled, the solution was transferred to a freezer under −8 ° C. condition and subjected to a freezing step. After 8 hours, confirm that the whole is in a light frozen state at −8 ° C., move to a low temperature of −25 ° C., and confirm that it is in a frozen state after 6 hours. And subjected to freeze-drying.

凍結乾燥工程では、真空条件80Pa以下を維持し、製品温度が45℃を超えることのないようにコントロールして行い、水分含有率2.8%、平均重量3.5g(乾燥歩留:12.8%)の成型製品37個を得た。すなわち製品の固形分含有率は12.6%であった。この乾燥品は乾燥工程での発泡現象もなく、小型成型容器からの剥離性も良く、その後の取り扱い工程では型崩れも観られなかった。   In the freeze-drying process, the vacuum condition is maintained at 80 Pa or less, and the product temperature is controlled so as not to exceed 45 ° C., the water content is 2.8%, the average weight is 3.5 g (dry yield: 12.2. 37 pieces of 8%) molded products were obtained. That is, the solid content of the product was 12.6%. This dried product had no foaming phenomenon in the drying process, had good peelability from the small molded container, and was out of shape in the subsequent handling process.

約350ml容のグラスに氷を50gほど投入し、そこにチューハイをほぼ300mlになるまで注入してから、得られた乾燥品の1個を投入したところ、起泡するアルコール飲料溶液中で容易に分散し、ほぼ1分以内に復元・分散し、長方体の形状がなくなるようになり、軽く攪拌することで溶液全体に行き渡り、飲用すると幾分形状を残すカシスの果実の食感とともに、幾分酸味のあるカシスの風味を十分に堪能することができた。   About 50 g of ice is put into a glass of about 350 ml, and chu-hi is poured into the glass until it reaches about 300 ml. Then, when one of the obtained dried products is put into the glass, it is easily added to the foamed alcoholic beverage solution. Disperses and reconstitutes and disperses within approximately 1 minute. The shape of the rectangular parallelepiped disappears. Lightly agitate to spread the entire solution. I was able to fully enjoy the flavor of cassis with a sour taste.

「実施例2」(マンゴー)
冷凍状態のマンゴースライスを解凍して、包丁にて3〜4mmのダイス状にカットし、320gを用意した。そこにマンゴーピューレ−320gを注入して混合した。
"Example 2" (mango)
The frozen mango slice was thawed and cut into 3 to 4 mm dies with a knife to prepare 320 g. Thereto, 320 g of mango puree was injected and mixed.

その混合体をベースとし、スクラロース0.8g、クエン酸12g、寒天10g、マンゴー香料0.8gを加えて混合し、さらに水600gを加えて分散溶液とした。この分散溶液を寒天の湿潤のための時間約10分間ゆっくり撹拌した。その後、同様にゆっくり撹拌しながら80℃まで加熱して寒天を溶解し、3分間保持した後攪拌しながら冷却して60℃くらいになった時点でプラスチック製小型成型トレーに注入した。この小型成型トレーは、前記実施例1と同様、容積がほぼ27mlのものであり、得られた混合溶液を各区画に27gずつ注入して45区画分を得た。   Based on the mixture, 0.8 g of sucralose, 12 g of citric acid, 10 g of agar, and 0.8 g of mango fragrance were added and mixed, and 600 g of water was further added to obtain a dispersion solution. The dispersion was slowly stirred for about 10 minutes for the agar wetting. Thereafter, similarly, the mixture was heated to 80 ° C. with slow stirring to dissolve the agar, held for 3 minutes, then cooled with stirring to about 60 ° C., and poured into a small plastic tray. Similar to Example 1, this small molded tray had a volume of approximately 27 ml, and 27 g of the obtained mixed solution was injected into each compartment to obtain 45 compartments.

これを常温条件下に1時間静置して冷却し、ほぼ常温に達し、溶液が軽度のゲル化した状態を確認してから−10℃条件下の凍結庫に移し、凍結工程に供した。8時間経過後、全体が−10℃のほぼ軽い凍結状態にあることを確認して、さらに低温の−25℃の条件下に移し、その6時間後に強度の凍結状態になったことを確認して凍結乾燥に供した。   The solution was allowed to stand for 1 hour under normal temperature conditions and cooled. The temperature reached almost normal temperature. After confirming that the solution was slightly gelled, the solution was transferred to a freezer at −10 ° C. and subjected to a freezing step. After 8 hours, confirm that the whole is in a light frozen state at −10 ° C., move to a lower temperature of −25 ° C., and confirm that it is in a frozen state after 6 hours. And subjected to freeze-drying.

凍結乾燥工程では、真空条件60Pa以下を維持し、製品温度が45℃を超えることのないようにコントロールして行い、水分含有率1.9%、平均重量2.8g(乾燥歩留:10.4%)の成型製品45個を得た。すなわち製品の固形分含有率は10.2%であった。マンゴーはカシスに比較して糖成分含有率が高いので、水による希釈倍率を少し上げて、凍結乾燥に供する固形分含有率を下げて、すなわち乾燥歩留を下げて対応したものである。この乾燥品は乾燥工程での発泡現象もなく、小型成型容器からの剥離性も良く、その後の取り扱い工程では型崩れも観られなかった。   In the freeze-drying process, the vacuum condition is maintained at 60 Pa or less, and the product temperature is controlled so as not to exceed 45 ° C., the water content is 1.9%, the average weight is 2.8 g (drying yield: 10. 4%) molded products 45 were obtained. That is, the solid content of the product was 10.2%. Since mango has a higher sugar component content than cassis, mango is prepared by slightly increasing the dilution ratio with water and lowering the solid content used for freeze-drying, that is, lowering the drying yield. This dried product had no foaming phenomenon in the drying process, had good peelability from the small molded container, and was out of shape in the subsequent handling process.

約350ml容のグラスに氷を50gほど投入し、そこにチューハイをほぼ300mlになるまで注入してから、得られた乾燥品の1個を投入したところ、起泡するアルコール飲料溶液中で容易に分散し、ほぼ1分以内に復元・分散した。長方体の形状がなくなるようになり、小ダイス状のマンゴーとともに軽く攪拌することで溶液全体に行き渡った。飲用すると幾分形状を残すマンゴーの果実の食感とともに、幾分酸味を有するマンゴーの風味を十分に堪能することができた。   About 50 g of ice is put into a glass of about 350 ml, and chu-hi is poured into the glass until it reaches about 300 ml. Then, when one of the obtained dried products is put into the glass, it is easily added to the foamed alcoholic beverage solution. Dispersed and restored and dispersed within approximately 1 minute. The shape of the rectangular parallelepiped disappeared, and the whole solution was spread by lightly stirring with small dice-shaped mango. In addition to the texture of mango fruit that retains its shape when drunk, it was able to fully enjoy the taste of mango with a somewhat sour taste.

「実施例3」(リンゴ)
生鮮のリンゴを剥皮して、包丁にて3〜4mmのダイス状にカットし、190gを用意した。処理中の褐変防止のため0.2%食塩水溶液に浸漬して、浮き上がらないように重石をしておいた。浸漬後液切りを行い、そこに業務用のアップルペースト320gを注入して混合した。
"Example 3" (apple)
Fresh apples were peeled and cut into 3-4 mm dice with a knife to prepare 190 g. In order to prevent browning during the treatment, it was dipped in a 0.2% saline solution to keep it from rising. After dipping, the liquid was drained, and 320 g of commercial apple paste was poured and mixed there.

その混合体をベースとし、スクラロース0.4g、クエン酸16g、寒天8g、リンゴ香料0.6gを加えて混合し、さらに水350gを加えて分散溶液とした。この分散溶液を寒天の湿潤のための時間約10分間ゆっくり撹拌した。その後、同様にゆっくり撹拌しながら80℃まで加熱して寒天を溶解し、3分間保持した後攪拌しながら冷却して60℃くらいになった時点でプラスチック製小型成型トレーに注入した。この小型成型トレーは、実施例1と同様、容積がほぼ27mlのものだが、混合溶液を各区画に27gずつ注入して33区画分を得た。   Based on the mixture, 0.4 g of sucralose, 16 g of citric acid, 8 g of agar and 0.6 g of apple flavor were added and mixed, and 350 g of water was further added to obtain a dispersion solution. The dispersion was slowly stirred for about 10 minutes for the agar wetting. Thereafter, similarly, the mixture was heated to 80 ° C. with slow stirring to dissolve the agar, held for 3 minutes, then cooled with stirring to about 60 ° C., and poured into a small plastic tray. As in Example 1, this small molded tray had a volume of approximately 27 ml, and 27 g of the mixed solution was injected into each compartment to obtain 33 compartments.

これを常温条件下に1時間静置して冷却し、ほぼ常温に達し、溶液が軽度のゲル化した状態を確認してから−7℃条件下の凍結庫に移し、凍結工程に供した。8時間経過後、全体が−7℃のほぼ軽い凍結状態にあることを確認して、さらに低温の−25℃の条件下に移し、その6時間後に強度の凍結状態になったことを確認して凍結乾燥に供した。   The solution was allowed to stand for 1 hour under normal temperature conditions and cooled, and the temperature reached almost normal temperature. After confirming that the solution was slightly gelled, the solution was transferred to a freezer under −7 ° C. condition and subjected to a freezing step. After 8 hours, confirm that the whole is in a light frozen state at -7 ° C, move to a lower temperature of -25 ° C, and confirm that it is in a frozen state after 6 hours. And subjected to freeze-drying.

凍結乾燥工程では、真空条件80Pa以下を維持し、製品温度が45℃を超えることのないようにコントロールして行い、水分含有率2.2%、平均重量2.7g(乾燥歩留:10.0%)の成型製品33個を得た。すなわち製品の固形分含有率は9.8%であった。この乾燥品は乾燥工程での発泡現象もなく、小型成型容器からの剥離性も良く、その後の取り扱い工程では型崩れも観られなかった。   In the freeze-drying process, the vacuum condition is maintained at 80 Pa or less, and the product temperature is controlled so as not to exceed 45 ° C., the moisture content is 2.2%, the average weight is 2.7 g (drying yield: 10. 0%) 33 molded products were obtained. That is, the solid content of the product was 9.8%. This dried product had no foaming phenomenon in the drying process, had good peelability from the small molded container, and was out of shape in the subsequent handling process.

約350ml容のグラスに氷を50gほど投入し、そこにチューハイをほぼ300mlになるまで注入してから、得られた乾燥品の1個を投入したところ、起泡するアルコール飲料溶液中で容易に分散し、ほぼ1分以内に復元・分散した。長方体の形状がなくなるようになり、小ダイス状のりんごとともに軽く攪拌することで溶液全体に行き渡った。飲用すると幾分形状を残す特有のリンゴ果実の食感とともに、幾分酸味を有するリンゴの風味を十分に堪能することができた。   About 50 g of ice is put into a glass of about 350 ml, and chu-hi is poured into the glass until it reaches about 300 ml. Then, when one of the obtained dried products is put into the glass, it is easily added to the foamed alcoholic beverage solution. Dispersed and restored and dispersed within approximately 1 minute. The shape of the rectangular parallelepiped disappeared, and the whole solution was spread by lightly stirring with small dice-shaped apples. When drunk, it was able to fully enjoy the taste of an apple with a somewhat sour taste, along with the texture of the unique apple fruit that left some shape.

このように、300mlの起泡性を有する冷たい水溶液に対して、本発明の製造方法により得られた25〜30ml容の凍結乾燥成型品を投入した場合には、2分間以内に、復元・分散した。これらの結果から、本発明の凍結乾燥成型品の製造方法により得られる凍結乾燥成型品は、非常に復元性・分散性に優れていることが明らかである。   Thus, when 25 to 30 ml of lyophilized molded product obtained by the production method of the present invention is introduced into 300 ml of a cold aqueous solution having foaming properties, restoration and dispersion within 2 minutes. did. From these results, it is clear that the freeze-dried molded product obtained by the method for producing a freeze-dried molded product according to the present invention is very excellent in restoration property and dispersibility.

本発明に係る凍結乾燥成型品の製造方法は、起泡性を有する冷たい水溶液中で容易に復元する凍結乾燥成型品の製造に適用できる。また、得られた凍結乾燥成型品は、品質、復元性、嗜好性、貯蔵性、輸送性等の面から見て、いずれも優れた特徴を有するため、様々な飲料に広く利用することができる。   The method for producing a freeze-dried molded product according to the present invention can be applied to the production of a freeze-dried molded product that is easily restored in a cold aqueous solution having foamability. In addition, since the obtained freeze-dried molded product has excellent characteristics in terms of quality, restorability, palatability, storage properties, transportability, etc., it can be widely used for various beverages. .

Claims (6)

起泡性を有する冷たい水溶液中で容易に復元する凍結乾燥成型品の製造方法であって、
果実果肉をペースト化し、及び/又は復元後にその特徴的テクスチャーが確認できる形状に、前記果実果肉を粗砕もしくは細断し、これらを混合する工程と、
高甘味度甘味料と、ゲル化剤と、酸味料を加えてさらに混合して加熱する工程と、
その混合体を、−5℃〜−12℃の温度で6〜8時間保持する第1凍結工程と、
前記第1凍結工程の後、−25℃以下の温度で凍結する第2凍結工程と、
前記第2凍結工程の後、凍結乾燥する凍結乾燥工程と、を有することを特徴とする凍結乾燥成型品の製造方法。
A method for producing a freeze-dried molded product that is easily restored in a cold aqueous solution having foaming properties,
Crushing or chopping the fruit pulp into a shape in which the fruit pulp is pasted and / or its characteristic texture can be confirmed after restoration, and mixing them;
Adding a high-intensity sweetener, a gelling agent, a sour agent, and further mixing and heating;
A first freezing step of holding the mixture at a temperature of −5 ° C. to −12 ° C. for 6 to 8 hours;
A second freezing step of freezing at a temperature of −25 ° C. or lower after the first freezing step;
And a freeze-drying step of freeze-drying after the second freezing step.
前記ゲル化剤は、寒天であることを特徴とする請求項1記載の凍結乾燥成型品の製造方法。   The method for producing a freeze-dried molded product according to claim 1, wherein the gelling agent is agar. 前記高甘味度甘味料は、スクラロース、グリチルリチン酸ナトリウム、アスパルテーム、ステビアからなる群より選ばれる1以上であることを特徴とする請求項1または2に記載の凍結乾燥成型品の製造方法。   The method for producing a freeze-dried molded product according to claim 1 or 2, wherein the high-intensity sweetener is one or more selected from the group consisting of sucralose, sodium glycyrrhizinate, aspartame, and stevia. 前記混合体は、固形分含有率が9〜15%であることを特徴とする請求項1〜3の何れか1項に記載の凍結乾燥成型品の製造方法。   The method for producing a freeze-dried molded product according to any one of claims 1 to 3, wherein the mixture has a solid content of 9 to 15%. 前記酸味料は、クエン酸であることを特徴とする請求項1〜4の何れか1項に記載の凍結乾燥成型品の製造方法。   The method for producing a freeze-dried molded product according to any one of claims 1 to 4, wherein the acidulant is citric acid. 請求項1〜5の何れかに記載の凍結乾燥成型品の製造方法によって製造された凍結乾燥成型品。   A freeze-dried molded product produced by the method for producing a freeze-dried molded product according to any one of claims 1 to 5.
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