JP2009132664A - 非接触型防カビ剤組成物 - Google Patents
非接触型防カビ剤組成物 Download PDFInfo
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- JP2009132664A JP2009132664A JP2007312039A JP2007312039A JP2009132664A JP 2009132664 A JP2009132664 A JP 2009132664A JP 2007312039 A JP2007312039 A JP 2007312039A JP 2007312039 A JP2007312039 A JP 2007312039A JP 2009132664 A JP2009132664 A JP 2009132664A
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Abstract
【解決手段】 下記一般式(1)で表される化合物を含有する非接触型防カビ剤組成物、並びにこの非接触型防カビ剤組成物を、容器に収納してなる防カビ剤組成物包装体。
R1−O(PO)nH (1)
〔式中、R1は炭素数6〜11のアルキル基、Pは炭素数3のアルキレン基、nは平均付加モル数を示す1〜3の数であり、n個のPは同一でも異なっていても良い。〕
【選択図】 なし
Description
〔式中、R1は炭素数6〜11のアルキル基、Pは炭素数3のアルキレン基、nは平均付加モル数を示す1〜3の数であり、n個のPは同一でも異なっていても良い。〕
下記配合成分を用い、表1に示す配合処方の非接触型防カビ剤組成物を調製した。得られた非接触型防カビ剤組成物について、下記方法により防カビ性能を評価した。結果を表1に示す。
化合物(1)
a−1:プロピレングリコールモノヘキシルエーテル
a−2:プロピレングリコールモノオクチルエーテル
a−3:トリプロピレングリコールモノオクチルエーテル
a−4:ジプロピレングリコールモノ−2−エチルヘキシルエーテル
a−5:プロピレングリコールモノデシルエーテル
a−6:ジプロピレングリコールモノイソデシルエーテル
化合物(1)の比較品
a’−1:プロピレングリコールモノメチルエーテル
a’−2:プロピレングリコールモノ−n−プロピルエーテル
a’−3:プロピレングリコールモノドデシルエーテル
<防カビ性能評価法>
(1)試験菌の調製
ポテトデキストロース寒天培地(和光純薬工業製)に生育させたAspergillus.niger及びCladosporiumの胞子と菌糸を、滅菌した0.05%Tween80(レオドールTW-0120)水溶液に分散させ、1×106〜1×107cells/mLのカビ懸濁液を調製した。
3cm×3cmに裁断した木綿メリアス布及び黒染した木綿ブロード布を滅菌処理(オートクレーブ:2atm(202650Pa)、125℃/15min)し、図1に示すような90mmプラスチックシャーレ1(日水製薬製、ニッスイAシャーレ、滅菌済み浅型)に各2枚ずつ静置した。各試験布に滅菌処理した2.4%ポテトデキストロースブロス水溶液(和光純薬工業製)を200μL塗布し、上記のカビ懸濁液を100μL塗布したものをカビ試験片2,2’として用いた。
シャーレの蓋3の中央に表1に記載の非接触型防カビ剤組成物を含浸させた布4(木綿メリアス布、1.5cm×1.5cm)を貼り、25℃、100%RHにて7日間培養した後、カビの生育状態を目視にて観察し、下記の5段階の基準に基づいて評価した。この中で評価が−及び+のものは、カビの生育が抑えられ、抗カビ性効果が顕著に認識できる。なお、シャーレの蓋に非接触型防カビ剤組成物を含浸させた布を貼らないで同様にカビの生育状態を観察した場合は、防カビ効果が認められないことを確認している。結果を表1に示す。
−:カビの生育なし
+:カビ菌糸のみ僅かに生育している
++:カビ菌糸のみ生育している
+++:カビ菌糸に加え、カビ胞子が僅かに生育している
++++:カビ胞子、菌糸ともに十分に生育している
不織布(東洋紡績株式会社製、東洋紡スパンボンド、ボランス4301N)に、表1の実施例6に示す配合処方の非接触型防カビ剤組成物を150質量%含浸させて、非接触型防カビ剤組成物含浸不織布を調製した。内容積約60Lのプラスチック製収納ボックス(64cm×40cm×23cm、ヨシカワ製、ネオテナーミドルM23)内に、この非接触型防カビ剤組成物含浸不織布1.7g、及び実施例1と同じカビ試験片2,2’をシャーレ1の蓋を外した状態で静置した。25℃、100%RHにて7日間培養し、実施例1と同様の方法で防カビ効果を判定した。その結果、Aspergillus.niger及びCladosporiumのいずれに対しても防カビ性能を有していた。
2,2’ カビ試験片
3 シャーレの蓋
4 非接触型防カビ剤組成物を含浸させた布
Claims (3)
- 下記一般式(1)で表される化合物を含有する非接触型防カビ剤組成物。
R1−O(PO)nH (1)
〔式中、R1は炭素数6〜11のアルキル基、Pは炭素数3のアルキレン基、nは平均付加モル数を示す1〜3の数であり、n個のPは同一でも異なっていても良い。〕 - 一般式(1)において、R1が炭素数6〜11のアルキル基、Pがプロピレン基(プロパン−1,2−ジイル基)、nが1〜2の数である請求項1記載の非接触型防カビ剤組成物。
- 請求項1又は2記載の非接触型防カビ剤組成物を、容器に収納してなる防カビ剤組成物包装体。
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JP2009132665A (ja) * | 2007-12-03 | 2009-06-18 | Kao Corp | 非接触型防カビ剤組成物 |
JP2017002007A (ja) * | 2015-06-15 | 2017-01-05 | 大日本除蟲菊株式会社 | 水系防カビ剤 |
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JPS5176423A (ja) * | 1974-12-26 | 1976-07-02 | Kao Corp | Hiiryoyokokinzai |
JP2000319110A (ja) * | 1999-04-30 | 2000-11-21 | Shoko Kagaku Kenkyusho:Kk | 非接触タイプの低臭気性防虫防黴剤 |
JP2007097738A (ja) * | 2005-09-30 | 2007-04-19 | Kobayashi Pharmaceut Co Ltd | 空間除菌用組成物 |
JP2009132665A (ja) * | 2007-12-03 | 2009-06-18 | Kao Corp | 非接触型防カビ剤組成物 |
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JPS5176423A (ja) * | 1974-12-26 | 1976-07-02 | Kao Corp | Hiiryoyokokinzai |
JP2000319110A (ja) * | 1999-04-30 | 2000-11-21 | Shoko Kagaku Kenkyusho:Kk | 非接触タイプの低臭気性防虫防黴剤 |
JP2007097738A (ja) * | 2005-09-30 | 2007-04-19 | Kobayashi Pharmaceut Co Ltd | 空間除菌用組成物 |
JP2009132665A (ja) * | 2007-12-03 | 2009-06-18 | Kao Corp | 非接触型防カビ剤組成物 |
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Publication number | Priority date | Publication date | Assignee | Title |
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JP2009132665A (ja) * | 2007-12-03 | 2009-06-18 | Kao Corp | 非接触型防カビ剤組成物 |
JP2017002007A (ja) * | 2015-06-15 | 2017-01-05 | 大日本除蟲菊株式会社 | 水系防カビ剤 |
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