JP2009025230A5 - - Google Patents
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- JP2009025230A5 JP2009025230A5 JP2007190705A JP2007190705A JP2009025230A5 JP 2009025230 A5 JP2009025230 A5 JP 2009025230A5 JP 2007190705 A JP2007190705 A JP 2007190705A JP 2007190705 A JP2007190705 A JP 2007190705A JP 2009025230 A5 JP2009025230 A5 JP 2009025230A5
- Authority
- JP
- Japan
- Prior art keywords
- measurement method
- electrochemical measurement
- complex molecule
- metal complex
- conjugated
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 238000002848 electrochemical method Methods 0.000 claims 6
- 150000004696 coordination complex Chemical class 0.000 claims 5
- 229910052751 metal Inorganic materials 0.000 claims 3
- 239000002184 metal Substances 0.000 claims 3
- 239000000758 substrate Substances 0.000 claims 3
- 150000001768 cations Chemical class 0.000 claims 2
- 239000003792 electrolyte Substances 0.000 claims 2
- NJMWOUFKYKNWDW-UHFFFAOYSA-N 1-ethyl-3-methylimidazolium Chemical compound CCN1C=C[N+](C)=C1 NJMWOUFKYKNWDW-UHFFFAOYSA-N 0.000 claims 1
- 229910052804 chromium Inorganic materials 0.000 claims 1
- 229910052803 cobalt Inorganic materials 0.000 claims 1
- 229910052802 copper Inorganic materials 0.000 claims 1
- 229910052741 iridium Inorganic materials 0.000 claims 1
- 239000007788 liquid Substances 0.000 claims 1
- 229910052748 manganese Inorganic materials 0.000 claims 1
- 229910052750 molybdenum Inorganic materials 0.000 claims 1
- 229910052759 nickel Inorganic materials 0.000 claims 1
- 229910052763 palladium Inorganic materials 0.000 claims 1
- 229910052697 platinum Inorganic materials 0.000 claims 1
- 229910052703 rhodium Inorganic materials 0.000 claims 1
- 229910052707 ruthenium Inorganic materials 0.000 claims 1
- 229910052723 transition metal Inorganic materials 0.000 claims 1
- 150000003624 transition metals Chemical class 0.000 claims 1
- 229910052720 vanadium Inorganic materials 0.000 claims 1
- 239000011800 void material Substances 0.000 claims 1
Claims (5)
- 導電性基板と電解質を含む液体とを用いる電気化学測定方法であって、
前記導電性基板は、該導電性基板の上にπ共役金属錯体分子が固定化された電極であり、
前記電解質は、前記π共役金属錯体分子の分子間に形成される空隙に接する球の半径と同一又は該半径よりも大きいイオン半径の陽イオンを含むことを特徴とする電気化学測定方法。 - 前記π共役金属錯体分子の中心金属が遷移金属であることを特徴とする請求項１に記載の電気化学測定方法。
- 前記π共役金属錯体分子の中心金属が、Ｏｓ、Ｆｅ、Ｒｕ、Ｃｏ、Ｃｕ、Ｎｉ、Ｖ、Ｍｏ、Ｃｒ、Ｍｎ、Ｐｔ、Ｒｈ、Ｐｄ及びＩｒのいずれかであることを特徴とする請求項１又は２に記載の電気化学測定方法。
- 前記π共役金属錯体分子の中心金属が、Ｃｏであることを特徴とする請求項１乃至３のいずれか一項に記載の電気化学測定方法。
- 前記陽イオンが１−エチル−３−メチル−イミダゾリウムイオンであることを特徴とする請求項１乃至４のいずれか一項に記載の電気化学測定方法。
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2007190705A JP4883796B2 (ja) | 2007-07-23 | 2007-07-23 | 電気化学測定方法 |
| US12/168,599 US7964071B2 (en) | 2007-07-23 | 2008-07-07 | Device with π-conjugated metal complex immobilized substrate in aqueous electrolyte |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2007190705A JP4883796B2 (ja) | 2007-07-23 | 2007-07-23 | 電気化学測定方法 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2009025230A JP2009025230A (ja) | 2009-02-05 |
| JP2009025230A5 true JP2009025230A5 (ja) | 2010-12-24 |
| JP4883796B2 JP4883796B2 (ja) | 2012-02-22 |
Family
ID=40294286
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2007190705A Expired - Fee Related JP4883796B2 (ja) | 2007-07-23 | 2007-07-23 | 電気化学測定方法 |
Country Status (2)
| Country | Link |
|---|---|
| US (1) | US7964071B2 (ja) |
| JP (1) | JP4883796B2 (ja) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5104052B2 (ja) * | 2007-06-14 | 2012-12-19 | ソニー株式会社 | 抵抗素子、ニューロン素子、及びニューラルネットワーク情報処理装置 |
| JP5258252B2 (ja) * | 2007-10-04 | 2013-08-07 | キヤノン株式会社 | 金属錯体化合物および金属錯体固定化基板 |
| WO2011057769A1 (en) * | 2009-11-10 | 2011-05-19 | Daimler Ag | Composite proton conducting electrolyte with improved additives for fuel cells |
| US20150353389A1 (en) * | 2012-12-26 | 2015-12-10 | Koninklijke Philips N.V. | Ph adjustor, apparatus including the ph adjustor and method for adjusting ph |
| CN111650267B (zh) * | 2020-06-11 | 2023-02-28 | 南京师范大学 | 一种系列共轭芳香分子掺杂蛋白质的制备及调节蛋白质电子传输带隙的方法 |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB8817997D0 (en) * | 1988-07-28 | 1988-09-01 | Cambridge Life Sciences | Enzyme electrodes & improvements in manufacture thereof |
| US8859151B2 (en) * | 2003-11-05 | 2014-10-14 | St. Louis University | Immobilized enzymes in biocathodes |
| JP4910314B2 (ja) * | 2005-06-13 | 2012-04-04 | ソニー株式会社 | 機能性分子素子及び機能性分子装置 |
| US7687186B2 (en) * | 2005-09-30 | 2010-03-30 | Canon Kabushiki Kaisha | Enzyme electrode, and sensor and biofuel cell using the same |
-
2007
- 2007-07-23 JP JP2007190705A patent/JP4883796B2/ja not_active Expired - Fee Related
-
2008
- 2008-07-07 US US12/168,599 patent/US7964071B2/en not_active Expired - Fee Related
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