JP2009021411A - Method of manufacturing metallized polypropylene film capacitor - Google Patents

Method of manufacturing metallized polypropylene film capacitor Download PDF

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JP2009021411A
JP2009021411A JP2007183116A JP2007183116A JP2009021411A JP 2009021411 A JP2009021411 A JP 2009021411A JP 2007183116 A JP2007183116 A JP 2007183116A JP 2007183116 A JP2007183116 A JP 2007183116A JP 2009021411 A JP2009021411 A JP 2009021411A
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polypropylene film
metallized
capacitor
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metallized polypropylene
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JP4803748B2 (en
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Yoriko Takeya
依里子 竹谷
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Nichicon Corp
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Abstract

<P>PROBLEM TO BE SOLVED: To provide a product which has a stable breakdown voltage by suppressing a beat sound when using a dry type metallized polypropylene film capacitor with a high voltage at high frequency. <P>SOLUTION: A device formed by winding a metallized polypropylene film is heat-pressed at a temperature of 80 to 120°C under a press pressure of 500×10<SP>4</SP>to 800×10<SP>4</SP>Pa, then metallized contact portions are formed on both winding end surfaces, and heat aging is performed at 80 to 120°C. <P>COPYRIGHT: (C)2009,JPO&INPIT

Description

本発明は、金属化ポリプロピレンフィルムを用いた電子機器用乾式金属化ポリプロピレンフィルムコンデンサで、特にうなり音の低減に関するものである。   The present invention relates to a dry-type metallized polypropylene film capacitor for electronic equipment using a metallized polypropylene film, and particularly relates to reduction of beat noise.

金属化ポリプロピレンフィルムコンデンサの用途は多岐に渡っており、特に電子機器・自動車分野におけるインバータ回路では、高電圧・高周波での使用が主流であり、商用周波に比べてフィルムコンデンサのフィルムの振動によりうなり音が大きくなるという問題を有していた。
この問題を解決するために、コンデンサ素子から発生するうなり音を、吸音材を用いて外部に漏れることを防止することが提案されている(例えば、特許文献1)。
また、ポリエステルフィルムにアルミニウムを蒸着したメタライズドフィルムを巻回したコンデンサ素子を、横断面の上下および左右方向から加熱・加圧成形して、うなり音を低減させる方法も提案されている(例えば、特許文献2)。
Metalized polypropylene film capacitors have a wide range of applications, especially in inverter circuits in the field of electronic equipment and automobiles, which are mainly used at high voltages and high frequencies. Had the problem of loud sounds.
In order to solve this problem, it has been proposed to prevent the beat sound generated from the capacitor element from leaking to the outside using a sound absorbing material (for example, Patent Document 1).
Also proposed is a method for reducing the beat noise by heating and pressure-molding a capacitor element in which a metallized film in which aluminum is vapor-deposited on a polyester film is wound from the top and bottom and from the left and right of the cross section (for example, patents). Reference 2).

特開2005−93515号公報JP 2005-93515 A 特開2000−12371号公報JP 2000-12371 A

しかしながら、上記特許文献1の技術では、コンデンサ素子から発生するうなり音を、吸音材を用いて外部に漏れることを防止するために、適正吸音材の材質、厚さ等の検討が必要であり、構造が複雑になるだけでなく、吸音材使用によりコストが高くなる欠点を有している。従って、より簡易な構造、および製造方法でうなり音を低減することが求められていた。
また、上記特許文献2による方法で、ポリエステルフィルムにアルミニウムを蒸着したメタライズドフィルムを巻回したコンデンサ素子を、横断面の上下および左右方向から加熱・加圧成形した場合でも、うなり音を十分に低減させることはできなかった。従って、これに代わり、うなり音を十分に低減させる方策が求められていた。
However, in the technology of Patent Document 1, it is necessary to examine the material, thickness, and the like of an appropriate sound absorbing material in order to prevent the beat sound generated from the capacitor element from leaking outside using the sound absorbing material. Not only is the structure complicated, but there is a disadvantage that the cost increases due to the use of a sound absorbing material. Therefore, it has been demanded to reduce beat noise with a simpler structure and manufacturing method.
Moreover, even when a capacitor element obtained by winding a metallized film in which aluminum is vapor-deposited on a polyester film is heated and pressure-molded from the top and bottom of the cross section and from the left and right directions by the method according to Patent Document 2, the roaring noise is sufficiently reduced. I couldn't make it. Therefore, instead of this, there has been a demand for a method for sufficiently reducing the beat sound.

本発明は上記課題を解決するもので、片面に金属蒸着膜が設けられたポリプロピレンフィルムを重ね合わせて巻回するか、または両面に金属蒸着膜が設けられたポリプロピレンフィルムと表面に金属蒸着膜が設けられていないポリプロピレンフィルムとを重ね合わせて巻回したコンデンサ素子を有する金属化ポリプロピレンフィルムコンデンサの製造方法に関し、前記巻回した素子を、温度80〜120℃、プレス圧力500×10〜800×10Paで熱プレスした後、両巻回端面にメタリコン部を形成し、その後80〜120℃で熱エージングを施すことを特徴とする。 The present invention solves the above-mentioned problem, and a polypropylene film provided with a metal vapor deposition film on one side is rolled and wound, or a polypropylene film provided with a metal vapor deposition film on both sides and a metal vapor deposition film on the surface. The present invention relates to a method of manufacturing a metallized polypropylene film capacitor having a capacitor element that is wound by overlapping with a polypropylene film that is not provided. The wound element is subjected to a temperature of 80 to 120 ° C. and a press pressure of 500 × 10 4 to 800 ×. After hot pressing at 10 4 Pa, a metallicon part is formed on both winding end faces, and then heat aging is performed at 80 to 120 ° C.

本発明の方法によって製造された金属化ポリプロピレンフィルムコンデンサは、巻回素子を温度80〜120℃、プレス圧力500×10〜800×10Paで熱プレスした後にメタリコン部を形成し、その後80〜120℃で熱エージングすることにより、高電圧・高周波使用時にうなり音を低減することができ、ポリエステルフィルムにアルミニウムを蒸着した金属化フィルムを用いた場合と比較して、うなり音を17〜32%程度まで、抑えることができる。
また、定格電圧、電流通電後の破壊電圧の安定化を図ることができる。
In the metallized polypropylene film capacitor manufactured by the method of the present invention, the winding element is hot-pressed at a temperature of 80 to 120 ° C. and a pressing pressure of 500 × 10 4 to 800 × 10 4 Pa, and then a metallicon part is formed. Heat aging at ˜120 ° C. can reduce beat noise when using high voltage and high frequency. Compared to the case of using a metallized film in which aluminum is vapor-deposited on a polyester film, the beat sound is reduced by 17 to 32. % Can be suppressed.
In addition, the breakdown voltage after the rated voltage and current application can be stabilized.

本発明の製造方法において、熱プレスの時間は、熱プレス温度・プレス圧力・ポリプロピレンフィルムの厚さ等によって適宜調節すればよい。一般的には3〜20分であり、好ましくは5〜15分である。   In the production method of the present invention, the hot pressing time may be appropriately adjusted depending on the hot pressing temperature, the pressing pressure, the thickness of the polypropylene film, and the like. Generally, it is 3 to 20 minutes, preferably 5 to 15 minutes.

本発明の製造方法において、熱エージングは、コンデンサ素子を気中で80〜120℃に保つことによって行う。例えば、恒温槽を用いて大気雰囲気中で行うことができる。熱エージングの時間は、10〜30時間が好ましく、15〜25時間がより好ましい。   In the production method of the present invention, thermal aging is performed by keeping the capacitor element at 80 to 120 ° C. in the air. For example, it can be performed in an air atmosphere using a thermostatic bath. The heat aging time is preferably 10 to 30 hours, and more preferably 15 to 25 hours.

本発明の製造方法において、ポリプロピレンフィルムの好適な厚さは3〜12μmである。   In the production method of the present invention, the preferred thickness of the polypropylene film is 3 to 12 μm.

本発明において、コンデンサ素子を構成するポリプロピレンフィルムや蒸着金属、蒸着金属の膜厚等は、通常の乾式金属化ポリプロピレンフィルムコンデンサと同様でよい。また、コンデンサ素子やコンデンサの他の製造工程は、通常の乾式金属化ポリプロピレンフィルムコンデンサの製造工程と同様でよい。
例えば、本発明にかかるコンデンサ素子を熱エージングした後は、通常の方法によりリード線を溶接し、樹脂ケースに入れてエポキシまたはウレタンなどの樹脂を充填することによって、またはディップコーティングすることによって、乾式金属化ポリプロピレンフィルムコンデンサを製造することができる。
In the present invention, the polypropylene film constituting the capacitor element, the deposited metal, the film thickness of the deposited metal, and the like may be the same as those of a normal dry metallized polypropylene film capacitor. Moreover, the other manufacturing process of a capacitor | condenser element and a capacitor | condenser may be the same as the manufacturing process of a normal dry-type metallized polypropylene film capacitor.
For example, after heat aging the capacitor element according to the present invention, a lead wire is welded by a normal method, and then put into a resin case and filled with a resin such as epoxy or urethane, or by dip coating, Metalized polypropylene film capacitors can be manufactured.

以下、実施例により本発明を詳細に説明する。各実施例・比較例において使用したコンデンサは、以下の方法により製造した。
10μmのポリプロピレンフィルムの片面にアルミニウムを蒸着した金属化ポリプロピレンフィルム(蒸着金属の厚さ0.015μm、膜抵抗5Ω/□)を重ねて巻回してコンデンサ素子を形成し、後述する温度と圧力で10分間上下方向から加熱・加圧成形することにより扁平形となるよう熱プレスを施した後、両巻回端面に錫系合金をメタリコンし、その後、後述する温度にて熱エージングを16時間行った。
その後、両メタリコン電極にリード線を溶接し、当該コンデンサ素子をディップコーティングし、硬化して乾式金属化ポリプロピレンフィルムコンデンサ(定格電圧:630V、静電容量:10μF)を作製した。
Hereinafter, the present invention will be described in detail by way of examples. The capacitors used in each example and comparative example were manufactured by the following method.
A metallized polypropylene film (deposited metal thickness: 0.015 μm, film resistance: 5Ω / □) deposited on one side of a 10 μm polypropylene film is wound and overlapped to form a capacitor element. After hot pressing to form a flat shape by heating and pressing from above and below for a minute, tin-based alloy was metallized on both winding end faces, and then heat aging was performed for 16 hours at a temperature described later. .
Thereafter, lead wires were welded to both metallicon electrodes, the capacitor element was dip-coated, and cured to produce a dry metallized polypropylene film capacitor (rated voltage: 630 V, capacitance: 10 μF).

[実施例1-1〜1-7]
表1に示す試験条件のとおり、熱プレス温度を80、100、120℃とし、熱プレス圧力を500×10、650×10、800×10Paとして熱プレスを行った。また、熱エージング温度は80、100、120℃とした。
[Examples 1-1 to 1-7]
According to the test conditions shown in Table 1, hot pressing was performed at a hot pressing temperature of 80, 100, and 120 ° C. and a hot pressing pressure of 500 × 10 4 , 650 × 10 4 , and 800 × 10 4 Pa. The heat aging temperature was 80, 100, and 120 ° C.

(比較例1-1〜1-7)
また、比較例として、熱プレス温度を70、130℃とし、熱プレス圧力を400×10、900×10Paとして熱プレスを行った。また、熱エージング温度は70、130℃とした。そして、熱エージングによる効果確認のため、熱エージング無しのものも加えた。
(Comparative Examples 1-1 to 1-7)
Moreover, as a comparative example, hot pressing was performed at a hot pressing temperature of 70 and 130 ° C. and a hot pressing pressure of 400 × 10 4 and 900 × 10 4 Pa. The heat aging temperature was 70 and 130 ° C. And the thing without heat aging was also added for the effect confirmation by heat aging.

(比較例2-1〜2-14)
そして、他の比較例として、上記ポリプロピレンフィルムに代えて、ポリエステルフィルムについて、上記実施例1-1〜1-7、比較例1-1〜1-7と同様の条件にて金属化フィルムコンデンサを作製し、比較を行った。
(Comparative Examples 2-1 to 2-14)
And as another comparative example, instead of the polypropylene film, for the polyester film, the metallized film capacitor in the same conditions as in Examples 1-1 to 1-7 and Comparative Examples 1-1 to 1-7. Fabricated and compared.

Figure 2009021411
Figure 2009021411

[性能試験]
上記した実施例・比較例の金属化ポリプロピレンフィルムコンデンサ、金属化ポリエステルフィルムコンデンサについて、10,20kHzの周波数で70Vrmsを通電した時の音の振動を測定した。
なお、うなり音の測定については、上記の金属化フィルムコンデンサからマイクを2cm離して測定した。測定には積分騒音計:LA4350(小野計測器製)およびFFT分析器:DS−2004(小野計器製)を使用した。
うなり音および、定格電圧・電流通電試験1000時間後の破壊試験結果を表1に示す。測定は、各実施例または比較例のコンデンサ10個について1つずつ行い、平均値を算出した。評価は、10kHzでのうなり音が15dB未満、20kHzでのうなり音が20dB未満、破壊電圧3.0kV以上の全てを満たすかどうかを基準にして行った。
[performance test]
For the metallized polypropylene film capacitor and the metallized polyester film capacitor of the above-described Examples and Comparative Examples, the vibration of sound when 70 Vrms was applied at a frequency of 10, 20 kHz was measured.
In addition, about the measurement of the roaring sound, the microphone was measured 2 cm away from the metallized film capacitor. For the measurement, an integral sound level meter: LA4350 (manufactured by Ono Keiki Co., Ltd.) and an FFT analyzer: DS-2004 (manufactured by Ono Keiki Co., Ltd.) were used.
Table 1 shows the roaring sound and the destructive test result after 1000 hours of the rated voltage / current energization test. The measurement was performed one by one for each of the capacitors of each example or comparative example, and the average value was calculated. The evaluation was performed based on whether or not the beat sound at 10 kHz was less than 15 dB, the beat sound at 20 kHz was less than 20 dB, and the breakdown voltage was 3.0 kV or more.

上記の表1の結果から、実施例1-1〜1-7では、うなり音、破壊電圧レベルが良好であることがわかる。また、比較例1-1、1-3、1-6では、熱プレス温度80〜120℃、熱プレス圧力500×10〜800×10Pa、熱エージング温度80〜120℃の3条件のうち、いずれか1つが下限を外れる場合は、コンデンサ素子の巻回が緩くなり、うなり音が高くなり、振動の影響で通電試験後の破壊電圧が低下するために特性が良好でないことが分かる。
また、比較例1-2、1-4、1-7から、上記3条件(熱プレス温度・熱プレス圧力・熱エージング温度)の1つが上限を外れる場合にも、うなり音が高くなり、破壊電圧が低下するので好ましくないことが分かる。特に比較例1-2、1-4から、熱プレス温度または熱プレス圧力が上限を外れる場合、下限を外れる場合と比較して、うなり音は改善されるものの、破壊電圧レベルはかえって悪化することが分かる。
また、比較例1-5の熱エージング無しの条件では、コンデンサ素子の巻回が緩くなり、空隙が生じることから、うなり音が高くなり、破壊電圧が低下するため、好ましくない。
そして、本発明による、金属化ポリプロピレンフィルムコンデンサの製造方法を用いた場合、ポリエステルフィルムにアルミニウムを蒸着した金属化フィルムを用いた比較例2-1〜2-14と比較して、うなり音を17〜32%程度まで、抑えることができた。
From the results of Table 1 above, it can be seen that in Examples 1-1 to 1-7, the beat sound and breakdown voltage level are good. In Comparative Examples 1-1, 1-3, and 1-6, three conditions of a hot press temperature of 80 to 120 ° C., a hot press pressure of 500 × 10 4 to 800 × 10 4 Pa, and a heat aging temperature of 80 to 120 ° C. Of these, when one of the values falls outside the lower limit, the winding of the capacitor element becomes loose, the beat noise becomes high, and the breakdown voltage after the energization test is reduced due to the influence of vibration, which indicates that the characteristics are not good.
In addition, from Comparative Examples 1-2, 1-4, and 1-7, even when one of the above three conditions (hot press temperature, hot press pressure, thermal aging temperature) deviates from the upper limit, the roaring noise increases and breaks down. It can be seen that the voltage decreases, which is not preferable. In particular, from Comparative Examples 1-2 and 1-4, when the hot press temperature or hot press pressure is outside the upper limit, the beat noise is improved compared to the case where the hot press temperature is outside the lower limit, but the breakdown voltage level is rather deteriorated. I understand.
Further, the condition of Comparative Example 1-5 without thermal aging is not preferable because the winding of the capacitor element becomes loose and voids are generated, and the beat noise becomes high and the breakdown voltage decreases.
And when the manufacturing method of the metallized polypropylene film capacitor | condenser by this invention is used, compared with Comparative Examples 2-1 to 2-14 using the metallized film which vapor-deposited aluminum on the polyester film, a roar is 17 Up to about 32% could be suppressed.

本発明の金属化ポリプロピレンフィルムコンデンサは電子機器、自動車分野におけるインバータ回路等の高電圧・高周波において低うなり音で使用が可能であり、民生、産業用電気機器に幅広く利用できる。   The metallized polypropylene film capacitor of the present invention can be used with low roaring noise at high voltage and high frequency, such as an inverter circuit in the field of electronic equipment and automobiles, and can be widely used in consumer and industrial electrical equipment.

Claims (1)

片面に金属蒸着膜が設けられたポリプロピレンフィルムを重ね合わせて巻回するか、または両面に金属蒸着膜が設けられたポリプロピレンフィルムと表面に金属蒸着膜が設けられていないポリプロピレンフィルムとを重ね合わせて巻回したコンデンサ素子を有する金属化ポリプロピレンフィルムコンデンサの製造方法であって、
前記の巻回した素子を、温度80〜120℃、プレス圧力500×10〜800×10Paで熱プレスした後、両巻回端面にメタリコン部を形成し、その後80〜120℃で熱エージングを施すことを特徴とする金属化ポリプロピレンフィルムコンデンサの製造方法。
A polypropylene film with a metal vapor-deposited film on one side is overlapped and wound, or a polypropylene film with a metal vapor-deposited film on both sides and a polypropylene film without a metal vapor-deposited film on the surface are superimposed. A method for producing a metallized polypropylene film capacitor having a wound capacitor element,
The wound element was hot-pressed at a temperature of 80 to 120 ° C. and a press pressure of 500 × 10 4 to 800 × 10 4 Pa, and then a metallicon part was formed on both winding end faces, and then heated at 80 to 120 ° C. A method for producing a metallized polypropylene film capacitor, characterized by performing aging.
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Cited By (3)

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DE102013201207A1 (en) 2012-01-25 2013-07-25 Honda Motor Co., Ltd. Vehicle and steering device
JP2015146374A (en) * 2014-02-03 2015-08-13 王子ホールディングス株式会社 Method for manufacturing capacitor element
CN116661317A (en) * 2023-06-01 2023-08-29 六和电子(江西)有限公司 Stepped temperature, time and pressure hot-pressing method for thin film capacitor

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JPS61145812A (en) * 1984-12-19 1986-07-03 松下電器産業株式会社 Film capacitor
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Publication number Priority date Publication date Assignee Title
DE102013201207A1 (en) 2012-01-25 2013-07-25 Honda Motor Co., Ltd. Vehicle and steering device
JP2015146374A (en) * 2014-02-03 2015-08-13 王子ホールディングス株式会社 Method for manufacturing capacitor element
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CN116661317B (en) * 2023-06-01 2024-04-12 六和电子(江西)有限公司 Stepped temperature, time and pressure hot-pressing method for thin film capacitor

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