JP2009019297A - Color-developed processed product - Google Patents

Color-developed processed product Download PDF

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JP2009019297A
JP2009019297A JP2007182019A JP2007182019A JP2009019297A JP 2009019297 A JP2009019297 A JP 2009019297A JP 2007182019 A JP2007182019 A JP 2007182019A JP 2007182019 A JP2007182019 A JP 2007182019A JP 2009019297 A JP2009019297 A JP 2009019297A
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casein
colored
color
pigment
natural
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Tomehiko Nakajima
留彦 中島
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Nakajima KK
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Nakajima KK
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Abstract

<P>PROBLEM TO BE SOLVED: To provide a color-developed processed product of high durability and good design decorativeness using eco-friendly materials. <P>SOLUTION: The color-developed processed product where the surface of a coloring work is color-developed is obtained by the following process: casein and a polyisocyanate to crosslink the casein are mixed together to be pasty and applied to predetermined sites on the surface of the coloring work. Subsequently, casein, a solvent for casein and natural powdery pigment are mixed together into powder, which is sprinkled throughout the surface of the coloring work. The sprinkled powder is then imparted with moisture to dissolve the casein-containing natural powdery pigment to fix the natural powdery pigment onto the overall surface of the coloring work, and a finishing treatment is conducted to distribute the same-color pigment on sites with more natural powdery pigment and sites with less natural powdery pigment over the surface of the coloring work. <P>COPYRIGHT: (C)2009,JPO&INPIT

Description

本発明は、木材や布や和紙などの繊維材に顔料を定着させた発色加工品に関するものである。 The present invention relates to a color processed product in which a pigment is fixed to a fiber material such as wood, cloth or Japanese paper.

布製品や和紙製品などに顔料を定着した発色加工品を提供するには、環境を配慮した資材を用いることが望ましい。 It is desirable to use environmentally friendly materials in order to provide colored products with pigments fixed on fabric products and Japanese paper products.

特許文献1には、天然顔料としてベンガラを用いて、ブルーデニムのパンツ製品に対して凸状の棒状皺加工を施して、その後該デニムパンツ製品を高温でプレス処理して、ベンガラ染色を行うもので、その染色処理は当初ベンガラが生地に付きやすくするためのカチオン化処理を行い、このあとベンガラ粉末によるベンガラ染色を施し、最後に染色落ちしないようにバインダー処理を行う発色加工品が提案されている。 Patent Document 1 uses Bengala as a natural pigment and performs a convex rod-like wrinkle processing on a blue denim pants product, and then presses the denim pants product at a high temperature to perform Bengala dyeing. The dyeing process is initially a cationization treatment to make the bengara easy to attach to the fabric, then a bengara dyeing with bengara powder, and finally a color processing product that performs a binder treatment so that it does not fall off is proposed. Yes.

実用新案登録第3107650号公報Utility Model Registration No. 3107650

特許文献1で提案されているベンガラ染色を施した発色加工品では、赤銅色の古色蒼然たる色彩が得られるものが、凸状の棒状皺加工やカチオン化処理を行い、色落ちしないようウレタン樹脂液などでバインダー処理を行うので、作業工程が複雑であり、同色でベンガラの付着する量を変化させた配慮がされていないという問題がある。 In the color-processed product that has been subjected to Bengala dyeing proposed in Patent Document 1, a product with a bronze antique color can be obtained. Since the binder treatment is performed with a liquid or the like, the work process is complicated, and there is a problem that consideration is not given to changing the amount of bengara attached with the same color.

本発明の目的は、上記問題点を解消し、簡単な作業工程で耐水性または磨耗に威力を発揮した自然の風合いをもたせる発色加工品を提供することにある。 An object of the present invention is to provide a color processed product that solves the above-mentioned problems and has a natural texture that is effective in water resistance or wear in a simple work process.

本発明の被着色部材の表面を発色させる発色加工品は、被着色部材の表面を発色させる発色加工品において、カゼインおよびカゼインを架橋するポリイソシアネートを混合して糊状として前記被着色部材の表面の所定の箇所に塗布させて後、カゼインとカゼインの溶剤と天然の粉末顔料とを混合させて粉体として前記被着色部材の表面全体に散布して後、前記散布された粉体に水分を与えてカゼイン入り天然の粉末顔料を溶かして天然の粉末顔料を前記被着色部材の表面全体に定着させ、仕上げ処理をすることにより、前記被着色部材の表面で天然の粉末顔料が多く付着した箇所と少なく付着した箇所に同色の顔料を分布させたことを特徴とする。 The colored processed product for coloring the surface of the member to be colored according to the present invention is the colored processed product for coloring the surface of the member to be colored, wherein the surface of the member to be colored is mixed with casein and polyisocyanate that crosslinks casein to form a paste After being applied to a predetermined portion of the case, casein, a solvent of casein and a natural powder pigment are mixed and dispersed as a powder on the entire surface of the member to be colored, and then water is applied to the dispersed powder. The case where the natural powder pigment containing casein is dissolved to fix the natural powder pigment on the entire surface of the member to be colored, and the finishing treatment is performed, so that a lot of natural powder pigment adheres to the surface of the member to be colored. It is characterized in that pigments of the same color are distributed in the places where they are adhered to a small amount.

また、前記天然粉末顔料がベンガラであり、カゼインの溶剤が硼砂であることを特徴とする。 The natural powder pigment is bengara, and the casein solvent is borax.

さらに、前記被着色部材がジーンズの生地であるデニム素材であることを特徴とする。 Furthermore, the member to be colored is a denim material which is a fabric of jeans.

さらに、前記仕上げ処理にはコーティング処理を含み、天然の粉末顔料が多く付着した箇所と少なく付着した箇所に同色で分布してなる被着色部材の表面にコーティング層が形成されたことを特徴とする。 Further, the finishing treatment includes a coating treatment, wherein a coating layer is formed on the surface of a member to be colored which is distributed in the same color in a portion where a lot of natural powdered pigment adheres and a portion where the natural powder pigment adheres a little. .

本発明によれば、カゼインおよびカゼインを架橋するポリイソシアネートを混合して糊状として前記被着色部材の表面の所定の箇所に塗布させて後、カゼインとカゼインの溶剤と天然の粉末顔料とを混合させて粉体として前記被着色部材の表面全体に散布して後、前記散布された粉体に水分を与えてカゼイン入り天然の粉末顔料を溶かして天然の粉末顔料を前記被着色部材の表面全体に定着させ、仕上げ処理をすることにより、前記被着色部材の表面で天然の粉末顔料が多く付着した箇所と少なく付着した箇所に同色の顔料を分布させて前記被着色部材の表面で同色の天然の粉末顔料が付着する量を変化させているので、耐久性がよく、デザイン装飾性のよい自然の風合いを配慮した発色加工品を提供することができる。さらに、天然粉末顔料としてベンガラおよびカゼインの溶剤として硼砂をそれぞれ選定して環境にやさしい発色加工品を提供できる。また、ジーンズの生地であるデニム素材に適用すれば、古色調を施した商品が提供できる。 According to the present invention, casein and polyisocyanate that crosslinks casein are mixed and applied as a paste to a predetermined portion of the surface of the member to be colored, and then mixed with casein, a solvent for casein, and a natural powder pigment. After spraying as a powder on the entire surface of the member to be colored, the sprayed powder is given moisture to dissolve the natural powder pigment containing casein, and the natural powder pigment is applied to the entire surface of the member to be colored. By fixing and finishing to the surface of the colored member, the same color pigment is distributed on the surface of the colored member by distributing the same colored pigment on the surface of the colored member on the surface where the natural powdered pigment is adhered to a small amount. Since the amount of the powder pigment adhering is changed, it is possible to provide a color-processed product that takes into consideration the natural texture with good durability and good design decoration. Furthermore, environmentally friendly colored processed products can be provided by selecting borax as a solvent for bengara and casein as natural powder pigments. Moreover, if applied to denim material, which is a fabric for jeans, products with an old color tone can be provided.

以下、本発明の実施例を図1および図2に基づいて以下、説明する。 Embodiments of the present invention will be described below with reference to FIGS.

ポリイソシアネート入りカゼインの塗布工程100において、カゼインおよびカゼインを架橋するポリイソシアネートを混合して糊状として木材や布や和紙などの繊維材の被着色部材1の表面の所定の箇所に塗布することにより、所定のパターン模様のポリイソシアネート入りカゼインを分布させる。この場合、水70重量%で、カゼイン17重量%、カゼインの溶剤である硼砂8%、ポリイソシアネート5重量%で混合させて糊状としている。 In the coating process 100 of casein containing polyisocyanate, casein and polyisocyanate that crosslinks casein are mixed and applied as a paste to a predetermined portion of the surface of the member 1 to be colored such as wood, cloth or Japanese paper The casein containing polyisocyanate having a predetermined pattern is distributed. In this case, 70% by weight of water, 17% by weight of casein, 8% of borax as a solvent for casein, and 5% by weight of polyisocyanate are mixed to form a paste.

次に、カゼイン入り顔料の散布工程200において、カゼインとこのカゼインの溶剤である硼砂やアンモニアをベンガラのような酸化鉄や酸化チタンやカーボンを粉末状として被着色部材1の表面全体に散布する。この場合、カゼインと顔料とはそれぞれ0.5μおよび0.7μmmで45重量%のカゼイン、5重量%の硼砂やアンモニアをおよび50重量%のポリイソシアネートを混合させた粉体である。 Next, in the casein dispersion step 200 of casein-containing pigment, casein and borax or ammonia, which are solvents for this casein, are dispersed over the entire surface of the member 1 to be colored in the form of iron oxide, titanium oxide or carbon such as bengara. In this case, the casein and the pigment are powders of 0.5 μm and 0.7 μm mixed with 45 wt% casein, 5 wt% borax and ammonia, and 50 wt% polyisocyanate, respectively.

水分付与工程300において、被着色部材1の表面全体に水蒸気を付着させることにより、前記散布された粉体に水分を与えてカゼイン入り天然の粉末顔料を溶かして天然の粉末顔料を前記被着色部材の表面全体に定着させる。この場合、カゼイン入り天然の粉末顔料を溶かす水分の与え方は水蒸気に代えてスチームでもよく、水滴でもよい。 In the moisture application step 300, water is applied to the entire surface of the member 1 to be colored to give water to the dispersed powder to dissolve the natural powder pigment containing casein, thereby converting the natural powder pigment into the member to be colored. Let it settle on the whole surface. In this case, the method of supplying moisture for dissolving the natural powder pigment containing casein may be steam or water droplets instead of steam.

次に、仕上げ処理工程400において、種々の方法が用途によって選択できる。例えば、加熱乾燥または加熱加圧または自然乾燥(乾燥工程401)して後、水などで洗浄(洗浄工程402)し、乾燥(乾燥工程403)する。この方法は特に、前記被着色部材がジーンズの生地であるデニム素材に最適であり、古色調を施した商品を提供することができる。 Next, in the finishing process 400, various methods can be selected depending on the application. For example, after heat-drying, heat-pressing or natural drying (drying step 401), washing with water or the like (washing step 402) and drying (drying step 403) are performed. This method is particularly suitable for a denim material in which the member to be colored is a jeans fabric, and can provide a product with an old color tone.

また、上記洗浄工程402では水を用いず、加熱乾燥または加熱加圧または自然乾燥(乾燥工程401)して後、ふるい落としてもよい。この方法は、木材や布や和紙などの繊維材に広く利用をすることができる。 Further, in the cleaning step 402, water may be used, followed by heat drying, heat pressurization, or natural drying (drying step 401), followed by sieving. This method can be widely used for fiber materials such as wood, cloth and Japanese paper.

仕上げ処理工程400にコーティング処理工程404を付加すれば、天然の粉末顔料が多く付着した箇所と少なく付着した箇所に同色で分布してなる被着色部材の表面から天然の粉末顔料がさらに一層剥離しにくくなる。例えば、乾燥(乾燥工程403)させて後、シェラックニス、漆ニスや柿渋ニスのような天然ニスでコーティング層を形成する(コーティング処理工程404)方法を付加させると天然の粉末顔料が多く付着した箇所と少なく付着した箇所に同色で分布してなる被着色部材の表面から天然の粉末顔料が剥離しにくく発色効果の経年変化が保たれる発色加工品を提供することができる。この場合、コーティング層を形成する素材として天然ニスを用いることにより、天然の粉末顔料とともに環境にやさしい発色加工品を提供することができる。 If the coating treatment step 404 is added to the finishing treatment step 400, the natural powder pigment is further peeled off from the surface of the member to be colored which is distributed in the same color at the places where a lot of natural powder pigments adhere and the places where the natural powder pigments adhere little. It becomes difficult. For example, after drying (drying step 403), when a method of forming a coating layer with a natural varnish such as shellac varnish, lacquer varnish or straw shibu varnish (coating treatment step 404), a lot of natural powder pigments adhered. It is possible to provide a color-processed product in which the natural powder pigment is difficult to peel off from the surface of the member to be colored, which is distributed in the same color in the part and the part that adheres little, and the secular change of the coloring effect is maintained. In this case, by using natural varnish as a material for forming the coating layer, it is possible to provide an environment-friendly colored processed product together with natural powder pigment.

また、木材や紙であれば、加熱する工程を利用せず自然乾燥でよい。 Moreover, if it is wood and paper, natural drying may be sufficient without using the heating process.

上記手順により、図2に示すように、カゼインおよびカゼインを架橋するポリイソシアネートを混合して糊状として被着色部材1の表面に塗布させ箇所2には天然の粉末顔料が多く付着し、他の箇所3には天然の粉末顔料の付着する量が少なくなり、同色で天然の粉末顔料の付着量を変化させた発色加工品が得られる。 By the above procedure, as shown in FIG. 2, casein and polyisocyanate that crosslinks casein are mixed and applied as a paste to the surface of the member 1 to be colored, and a lot of natural powder pigment adheres to the part 2, The amount of the natural powder pigment adhering to the portion 3 is reduced, and a colored product having the same color and the natural powder pigment adhering amount is changed.

次に、天然顔料としてベンガラを用いて布の被着色部材に発色加工をする発色加工方法を説明する。 Next, a color processing method for performing color processing on a member to be colored using bengara as a natural pigment will be described.

水70重量%、カゼイン17重量%、硼砂8%およびポリイソシアネート5%を混合して糊状として布の被着色部材1の表面の所定の箇所2に塗布する(ポリイソシアネート入りカゼインの塗布工程100)。次に、カゼイン45重量%と硼砂5%とベンガラ50%の割合で混合させた粉体を布の被着色部材1の表面全体に散布する(カゼイン入り顔料の散布工程200)。引き続き、布の被着色部材1の表面全体に水蒸気を付着させると、この粉体に水分が与えられてベンガラが布の被着色部材1の表面全体に定着する(水分付与工程)。次に、加熱(乾燥工程401)し、水で洗浄(洗浄工程402)し、乾燥(乾燥工程403)させる仕上げ処理をすることにより、布の被着色部材1の表面でベンガラが多く付着した箇所2と少なく付着した箇所3にベンガラが分布して、ベンガラの付着する量を変化させた発色加工品が得られる。 70% by weight of water, 17% by weight of casein, 8% of borax, and 5% of polyisocyanate are mixed and applied as a paste to a predetermined portion 2 on the surface of the member 1 to be colored (application step 100 of casein containing polyisocyanate). ). Next, powder mixed in a ratio of 45% by weight of casein, 5% of borax, and 50% of bengara is sprayed on the entire surface of the member 1 to be colored (spreading process 200 of pigment containing casein). Subsequently, when water vapor is attached to the entire surface of the member to be colored 1 of the cloth, moisture is given to the powder and the bengara is fixed on the entire surface of the member to be colored 1 of the cloth (moisture application step). Next, a portion where a large amount of bengara adheres to the surface of the member 1 to be colored by performing a finishing process of heating (drying step 401), washing with water (washing step 402), and drying (drying step 403). As a result, a colored processed product is obtained in which the amount of bengal adheres to the portion 3 where the amount of adhering is less than 2 and the amount of the bengal adherence is changed.

本発明は、木材や布や和紙などの繊維材に天然の粉末顔料を定着させた発色加工品として、ジーンズのような衣料製品、壁材や欄間や柱のような建材、絵画のような美術品などに利用できる。 The present invention is a color processed product in which natural powder pigments are fixed on fiber materials such as wood, cloth and Japanese paper, clothing products such as jeans, wall materials, building materials such as balustrades and pillars, and art such as paintings. It can be used for goods.

本発明の実施例を示す作業工程図である。It is a work process figure which shows the Example of this invention. 発色加工の図である。It is a figure of color development.

符号の説明Explanation of symbols

1 被着色部材





























1 Colored member





























Claims (4)

被着色部材の表面を発色させる発色加工品において、カゼインおよびカゼインを架橋するポリイソシアネートを混合して糊状として前記被着色部材の表面の所定の箇所に塗布させて後、カゼインとカゼインの溶剤と天然の粉末顔料とを混合させて粉体として前記被着色部材の表面全体に散布して後、前記散布された粉体に水分を与えてカゼイン入り天然の粉末顔料を溶かして天然の粉末顔料を前記被着色部材の表面全体に定着させ、仕上げ処理をすることにより、前記被着色部材の表面で天然の粉末顔料が多く付着した箇所と少なく付着した箇所に同色の顔料を分布させたことを特徴とする発色加工品。 In a color processed product for coloring the surface of the member to be colored, casein and a polyisocyanate that crosslinks casein are mixed and applied as a paste to a predetermined portion of the surface of the member to be colored, and then the casein and the solvent of casein After the natural powder pigment is mixed and dispersed as a powder on the entire surface of the member to be colored, the natural powder pigment containing casein is dissolved by adding moisture to the dispersed powder to dissolve the natural powder pigment. By fixing to the entire surface of the member to be colored and performing a finishing treatment, the same color pigment is distributed on the surface of the member to be colored where the natural powder pigment has adhered to a large amount and where it has adhered a little. Colored processed product. 前記天然粉末顔料がベンガラであり、カゼインの溶剤が硼砂であることを特徴とする請求項1記載の発色加工品。 2. The color processed product according to claim 1, wherein the natural powder pigment is bengara and the solvent of casein is borax. 前記被着色部材がジーンズの生地であるデニム素材であることを特徴とする請求項1または請求項2記載の発色加工品。 3. The color processed product according to claim 1, wherein the member to be colored is a denim material which is a fabric of jeans. 前記仕上げ処理にはコーティング処理を含み、天然の粉末顔料が多く付着した箇所と少なく付着した箇所に同色で分布してなる被着色部材の表面にコーティング層が形成されたことを特徴とする請求項1または請求項2または請求項3記載の発色加工品。
The finishing process includes a coating process, wherein a coating layer is formed on a surface of a member to be colored which is distributed in the same color at a place where a lot of natural powder pigment is attached and a place where the natural powder pigment is attached a little. The colored product according to claim 1 or claim 2 or claim 3.
JP2007182019A 2007-07-11 2007-07-11 Color-developed processed product Pending JP2009019297A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101199258B1 (en) 2011-03-28 2012-11-12 정옥기 natural dyeing method
CN103556497A (en) * 2013-10-15 2014-02-05 山东岱银纺织集团股份有限公司 Dyeing method for multilevel-color jean yarns

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101199258B1 (en) 2011-03-28 2012-11-12 정옥기 natural dyeing method
CN103556497A (en) * 2013-10-15 2014-02-05 山东岱银纺织集团股份有限公司 Dyeing method for multilevel-color jean yarns

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