JP2009017825A - Method for producing packaged coffee beverage - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To provide a method for producing a packaged coffee beverage having high concentration of chlorogenic acid and a small mass ratio of hydroxyhydroquinone to the chlorogenic acid, excellent in flavor, and targeting distribution sales. <P>SOLUTION: The method for producing a packaged coffee beverage comprises: (1) a process of treating coffee extract liquid extracted from roasted coffee beans having an L value of 14-25 with an adsorbent to obtain coffee extract (a); a process of obtaining coffee extract (b) from the extract liquid extracted from roasted coffee beans having an L-value of 40-55; a process of mixing the respective extracts (a) and (b) together to obtain coffee solution; and a process of subjecting the coffee solution to heat sterilization. <P>COPYRIGHT: (C)2009,JPO&INPIT

Description

  The present invention relates to a method for producing a containerized coffee beverage.

  Antihypertensive drugs include various neuroleptic agents that act on the regulatory system of neural factors, ACE inhibitors that act on the regulatory system of humoral factors, AT receptor antagonists, and regulatory systems of vascular endothelium-derived substances Drugs such as Ca antagonists and antihypertensive diuretics related to the body fluid regulation system in the kidney can be mentioned, and these are mainly used in medical institutions for patients with severe hypertension. However, drugs currently used for the purpose of antihypertensive measures are satisfactory in terms of efficacy, but the burden on patients is large due to the side effects that are present.

  For this reason, general therapies based on lifestyle improvements such as diet therapy, exercise therapy, restriction of drinking and smoking are widely applied to people with normal hypertension including mild to severe hypertension. With the increasing awareness of the importance of general therapy, it has been said that improving dietary habits is particularly important. And the search of the blood pressure antihypertensive material derived from the food from the food which has a blood pressure lowering action is performed abundantly, and isolation | separation and identification of the active ingredient are performed a lot.

On the other hand, it has been reported that the action of lowering blood pressure is observed by reducing the hydroxyhydroquinone contained in the coffee beverage composition and making the weight ratio of hydroxyhydroquinone / chlorogenic acids in the coffee beverage composition less than 10/10000. (Patent Document 1).
WO05 / 72533

  An object of the present invention is to provide a method for producing a packaged coffee beverage and a packaged coffee beverage for the purpose of distribution and sales that have a high chlorogenic acid concentration, a low mass ratio of hydroxyhydroquinone and chlorogenic acid, and excellent flavor. is there.

  As a result of various investigations in providing a container-packed coffee beverage that maintains the flavor peculiar to roasted coffee beans, the present inventor performs an adsorbent treatment on a coffee extract extracted from roasted coffee beans having an L value of 14 to 25. It was found that the above-mentioned object can be achieved by mixing the coffee extract obtained by the above and a coffee extract extracted from roasted coffee beans having an L value of 40 to 55 and subjecting the obtained coffee solution to heat sterilization treatment. .

That is, the present invention
(1) A step of obtaining a coffee extract (a) by subjecting a coffee extract extracted from roasted coffee beans having an L value of 14 to 25 to an adsorbent;
(2) obtaining a coffee extract (b) from roasted coffee beans having an L value of 40 to 55;
(3) mixing each extract (a) and (b) to obtain a coffee solution;
(4) a step of heat sterilizing the coffee solution;
The manufacturing method of the container-packed coffee drink containing this is provided.

  According to the present invention, since the chlorogenic acid concentration is high and the mass ratio of hydroxyhydroquinone and chlorogenic acids is small, an excellent blood pressure lowering action can be expected, and a packaged coffee beverage excellent in flavor can be easily obtained. .

  In the production method of the present invention, at least two kinds of beans with different roasting degrees are used. One type of coffee beans is roasted coffee beans having an L value of 14 to 25 (hereinafter also referred to as “deep roasted beans”), and the other type is roasted coffee beans having an L value of 40 to 55 (hereinafter “shallow roasted beans”). It is also called “bean”. The measuring method of L value is based on the method described in the examples described later. Although the kind of coffee bean used by this invention is not specifically limited, For example, Brazil, Colombia, Tanzania, Mocha, Kilimangelo, Mandelin, Blue Mountain etc. are mentioned. Coffee beans include Arabica and Robusta. One kind of coffee beans may be used, or a plurality of kinds may be blended. Regarding the method of making roasted coffee beans, preferred roasting methods include a direct-fire type, a hot air type, and a semi-hot air type, and a type having a rotating drum is more preferable. The roasting temperature is usually 100 to 300 ° C, more preferably 150 to 250 ° C. From the viewpoint of flavor, it is preferable to cool to 0 to 100 ° C. within 1 hour after roasting, more preferably 10 to 60 ° C.

In the present invention, first, a coffee extract (a) is obtained by treating the coffee extract extracted from deep roasted beans with an adsorbent (step (1)). Deep roasted beans are strongly drawn out of the flavor and aroma of coffee and can enhance palatability. The preferred L value range is 16-25, especially 17-24.
On the other hand, the deep roasted bean extract contains a relatively large amount of hydroxyhydroquinone generated during the roasting process. Therefore, before mixing with the coffee extract (b) described later, adsorbent treatment is performed to reduce the mass ratio of hydroxyhydroquinone and chlorogenic acids in the deep roast bean extract. At this time, it is preferable to control to be less than 10/10000, particularly 5/10000 or less when mixed with the coffee extract (b) described later.

Examples of the adsorbent include activated carbon and reverse phase chromatographic carrier.
As a method for treating the coffee extract with an adsorbent, for example, as a batch method, for example, an adsorbent is added to a liquid containing a coffee extract and stirred at −10 to 100 ° C. for 0.5 minutes to 5 hours. Remove it. Examples of the atmosphere during the treatment include air and inert gas (nitrogen gas, argon gas, helium gas, carbon dioxide gas), but inert gas is preferred from the viewpoint of flavor.
In the column liquid passing method, for example, an adsorbent is filled in the column, and a liquid containing a coffee extract is passed from the lower or upper part of the column and discharged from the other. The amount of the adsorbent packed into the column may be an amount that can be filled into the adsorbent column before passing the liquid. It is sufficient that at least one of the upper and lower stages of the adsorbent column has a separation structure that has a mesh (netting) or punching metal and does not substantially leak the adsorbent.

  The amount of adsorbent is usually 0.01 to 100 times the coffee bean-derived soluble solid content (Brix) in the coffee extract. From the viewpoint of flavor, it is preferable to use 0.02 to 1.0 times in the case of activated carbon, and 2 to 100 times in the case of a resin carrier for reverse phase chromatography.

As the activated carbon, the average pore radius in the micropore region is preferably 5 angstroms (Å) or less, more preferably in the range of 2 to 5 angstroms, and particularly preferably in the range of 3 to 5 angstroms. In the present invention, the micropore region indicates 10 angstroms or less, and the average pore radius is a value of the pore radius indicating the peak top of the pore distribution curve obtained by measurement by the MP method. The MP method is a pore measurement method described in the literature (Colloid and Interface Science, 26, 46 (1968)), and is a method adopted by Sumika Chemical Analysis Center, Inc. and Toray Research Center, Inc. .
Moreover, as a kind of activated carbon, coconut shell activated carbon is preferable, and also water vapor activated coconut shell activated carbon is preferable. As a commercially available product of activated carbon, Shirakaba WH2C, WH2CL, W2CL, W2C, EH (Nippon Envirochemicals), Taiko CW (Nikamura Chemical), Kuraray Coal GW (Kuraray Chemical), etc. can be used.
The adsorbent treatment method using activated carbon not only can reduce the hydroxyhydroquinone content selectively without reducing the amount of chlorogenic acids, but also has a good flavor, and the potassium content relative to the chlorogenic acids is 1/5 or more by mass ratio. In particular, it is preferable from the standpoint that the potassium content is not lowered by maintaining ½ or more.
The adsorbent treatment step is preferably performed only with the coffee extract, but may be performed after mixing raw materials such as sodium hydrogen carbonate.

  In this invention, the process (process (2)) which obtains a coffee extract (b) from a light roast bean is included. The preferred L value of lightly roasted beans is 42-52, especially 43-50. Such roasted beans contain a large amount of chlorogenic acid and have a very low hydroxyhydroquinone content. Therefore, by mixing the extract (b) from the extract extracted from the coffee beans with the coffee extract (a), it is possible to produce a coffee beverage that can be expected to have a blood pressure lowering effect while enhancing palatability. It becomes. In the present specification, the coffee extract (b) means both a coffee extract itself extracted from lightly roasted beans and a product obtained by adding some treatment to the latter, and the latter is referred to as “coffee extract (or simply extract)”. Also called.

  As a preferred embodiment of the present invention, a coffee extract obtained by concentrating a coffee bean extract extracted from this coffee bean is used. This has the merit that it is easy to increase the solid content concentration of the coffee beverage. Here, the concentration method of the coffee extract may be any method such as a reduced pressure method, an ultrafiltration membrane method, or a freeze-drying method. The coffee solid content concentration in the obtained coffee extract is 15 to 100% by mass, preferably 20 to 95% by mass, more preferably 25 to 90% by mass, and the mixing and homogenization at the time of coffee beverage production is easy. The concentration is easy to increase, which is preferable for production.

  Moreover, the extract of shallow roasted beans may be treated with an adsorbent or may not be treated with an adsorbent. When the adsorbent treatment is performed, the aroma is mild and a light taste is obtained, so that even people who are not good at coffee can easily drink. In addition, the blood pressure lowering effect is further ensured. On the other hand, when the adsorbent treatment is not performed, the original fragrance, richness and body feeling of coffee can be left, so that it is easy for people who like coffee to drink and blood pressure drop due to continuous drinking can be expected. In addition, as described above, the shallow roasted beans of the present invention have a low hydroxyhydroquinone content that is thought to hinder the blood pressure lowering action, so that no adsorbent treatment is necessary to expect the blood pressure lowering action. Therefore, the process can be simplified, which is preferable in terms of production efficiency and cost.

Next, the coffee extract (a) obtained in the step (1) and the coffee extract (b) obtained in the step (2) are mixed to obtain a coffee solution (step (3)).
The mixing ratio of the two is 4: 6 to 8: 2, particularly 4.5: 5.5 to 7: 3 in terms of solid content (Brix standard) in each coffee extract, in terms of flavor and storage stability. preferable.

  Regardless of the roasting degree, the extraction method from roasted coffee beans includes, for example, a method of extracting from roasted coffee beans or pulverized products thereof using an extraction solvent such as water to hot water (0 to 100 ° C.). Can be mentioned. The degree of pulverization is as follows. Examples include extremely coarse grinding (1.000-2.500 mm) and a cut product of a large particle size pulverized product having an average particle size of about 3 mm to 10 mm. Examples of the extraction method include a boiling type, an espresso type, a siphon type, and a drip type (paper, flannel, etc.).

  Examples of the extraction solvent include water, alcohol-containing water, milk, carbonated water, and the like. The pH of the extraction solvent is usually 4 to 10, and 5 to 7 is preferable from the viewpoint of flavor. In addition, a pH adjusting agent such as sodium bicarbonate, sodium bicarbonate, L-ascorbic acid, or L-alcorbic acid Na may be contained in the extraction solvent, and the pH may be adjusted appropriately.

  Extractors include paper drip, non-woven drip, siphon, nel drip, espresso machine, coffee machine, percolator, coffee press, ibrick, water drip, boiling, heatable kettle, stirring and stirring kettle, coffee cup Paper or non-woven bag-like structure that can be suspended, drip extractor having a structure (such as mesh or punching metal) that is substantially capable of solid-liquid separation of coffee beans at the bottom of the spray nozzle, at the top and bottom Examples thereof include a column extractor having a structure (mesh, punching metal, etc.) that can substantially separate coffee beans from solid and liquid. The extractor may have a structure that can be heated or cooled (for example, an electric heater, a jacket through which hot water, steam, or cold water can flow).

  Examples of the extraction method include a batch extraction method, a semi-batch extraction method, and a continuous extraction method. The extraction time of the batch type extraction method or the semi-batch type extraction method is 10 seconds to 120 minutes. From the viewpoint of flavor, 30 seconds to 30 minutes are preferable.

The container-packed coffee beverage produced by the method of the present invention is produced by performing a heat sterilization treatment with the F0 value (lethal value) set to a certain value or more. The F0 value is 5 to 60, preferably 10 to 50, more preferably 15 to 40, and still more preferably 17 to 35 in terms of microbiological stability. Here, the F0 value is a value for evaluating the heat sterilization effect when the canned coffee beverage is heat sterilized, and indicates the heating time (minutes) at the reference temperature (121.1 ° C.). The F0 value is calculated by multiplying the lethality rate (1 at 121.1 ° C.) with respect to the temperature in the container by the heating time (minutes). The fatality rate can be obtained from the fatality rate table (Masao Fujimaki et al., “Food Industry”, Hoshiseisha Koseikaku, 1985, page 1049). To calculate the F0 value, a commonly used area calculation method, formula method, or the like can be employed (see, for example, Tanikawa et al. << Canned Manufacturing Science >> page 220, Koseikaku).
In the present invention, in order to set the F0 value to be a predetermined value, for example, an appropriate heating temperature and heating time may be determined from a preliminarily obtained lethality curve.

  As the sterilizer, a batch sterilizer or a continuous sterilizer can be used. There is a retort pot as a batch type sterilizer. Continuous sterilizers include tube-type sterilizers, plate-type sterilizers, HTST plate-type sterilizers, UHT sterilizers, etc. (revised soft drinks, pages 546-558, pages 633-638, supervised by Seiyo Nationwide) Beverage Manufacturers Association, published by Korin). From the viewpoint of flavor, a continuous sterilizer is preferred. In particular, it is preferable to fill under aseptic conditions after continuous heat sterilization.

  In the present invention, the sterilization time is within 10 minutes, preferably from 100 seconds to 9 minutes, more preferably from 110 seconds to 7 minutes, from the viewpoint of effectively suppressing the increase in hydroxyhydroquinone.

  The sterilization temperature is preferably 123 ° C. or higher in view of microbiological stability, more preferably 123 to 150 ° C., more preferably 126 to 141 ° C., and still more preferably 129 to 140 ° C.

  In addition to the above conditions, the heat sterilization treatment is performed under the sterilization conditions stipulated in the Food Sanitation Law if the container can be heat sterilized after being filled into a container like a metal can. It should be noted that the temperature rise and cooling to the heat sterilization setting conditions should be performed promptly and not accompanied by an excessive heat history. In addition, the metal can may be filled after heat sterilization. The same applies to paper, bottles, and the like, and heat sterilization after filling or filling after heat sterilization is possible considering the heat resistance of the container.

  The container-packed coffee beverage of the present invention can be produced by filling a container such as a can (aluminum, steel), paper, a retort pouch, a bottle (glass) or the like. In this case, the container can be packed into a 50 to 500 mL canned coffee beverage. The canned coffee beverage is preferably single-strength. Here, “single strength” refers to what can be drunk as it is after opening the packaged beverage. Moreover, as a constituent ratio of monocaffeoylquinic acid in the canned black coffee beverage obtained by the present invention, the 4-caffeoylquinic acid / 3-caffeoylquinic acid mass ratio is 0.6 to 1.2, The mass ratio of 5-caffeoylquinic acid / 3-caffeoylquinic acid is preferably 0.01 to 3. Moreover, in order to make the effect | action of this invention effective, it is good also considering a container-packed coffee drink as a container-packed black coffee drink. Here, the black coffee beverage refers to a product in which milk is not blended regardless of the presence or absence of so-called sweeteners such as unsweetened black, sweetened black and fine sugar black.

As the container, a container having a low oxygen permeability is preferable from the viewpoint of preventing changes in the ingredients in the coffee. For example, a can made of aluminum or steel, a glass bottle, or the like may be used. In the case of cans and bottles, resealable ones that can be recapped are also included. Here, the oxygen permeability is an oxygen permeability (cc · mm / m ² · day · atm) measured in an environment of 20 ° C. and a relative humidity of 50%, and the oxygen permeability is preferably 5 or less. Hereinafter, 1 or less is particularly preferable.

  The production method of the present invention is used to produce a packaged coffee beverage having (A) a concentration of chlorogenic acids of 0.14 to 0.5% by mass and (B) a mass ratio of hydroxyhydroquinone to chlorogenic acids of 5 / 10,000 or less. Is suitable. Such a coffee beverage is excellent in blood pressure lowering action and excellent in flavor.

The chlorogenic acid content in the coffee beverage is preferably 0.145 to 0.4% by mass, more preferably 0.15 to 0.3% by mass, still more preferably 0.155 to 0.25% by mass, and particularly preferably Contains 0.16-0.2 mass%. The chlorogenic acids include (A ¹ ) monocaffeoylquinic acid, (A ² ) ferulaquinic acid, and (A ³ ) dicaffeoylquinic acid. Here, (A ¹ ) monocaffeoylquinic acid includes at least one selected from 3-caffeoylquinic acid, 4-caffeoylquinic acid and 5-caffeoylquinic acid. Examples of (A ² ) ferulquinic acid include one or more selected from 3-ferlaquinic acid, 4-ferlaquinic acid and 5-ferlaquinic acid. (A ³ ) Examples of dicaffeoylquinic acid include one or more selected from 3,4-dicaffeoylquinic acid, 3,5-dicaffeoylquinic acid, and 4,5-dicaffeoylquinic acid. The content of the chlorogenic acids can be measured by high performance liquid chromatography (HPLC). As a detection means in HPLC, UV detection is generally used, but it can also be detected with higher sensitivity by CL (chemiluminescence) detection, EC (electrochemical) detection, LC-Mass detection, or the like.

  Further, the mass ratio of hydroxyhydroquinone and chlorogenic acids in the coffee beverage of the present invention is preferably 3/10000 or less, particularly 1 / 10,000 or less, because the blood pressure lowering action becomes remarkable.

In the container-packed coffee beverage of the present invention, the content of H ₂ O ₂ (hydrogen peroxide) is preferably 1 ppm or less, more preferably 0.1 ppm or less, and particularly preferably 0.01 ppm or less from the viewpoint of the original flavor of coffee. The measurement of hydrogen peroxide can be performed using a commonly used hydrogen peroxide meter. For example, a high-sensitivity hydrogen peroxide meter Super Orientor Model 5 (SUPER ORITECTOR MODEL 5) manufactured by Central Science Co., Ltd. can be used. .

  The container-packed coffee beverage of the present invention has a peak substantially in the time range of 0.54 to 0.61 relative retention time with respect to gallic acid when gallic acid is used as a standard substance in analysis by high performance liquid chromatography. Preferably not. In order to confirm that there is substantially no peak in the time domain, general HPLC can be used. For example, a gradient of 0.05 M acetic acid aqueous solution and 0.05 M acetic acid 100% acetonitrile solution is used as an eluent. It can be confirmed by using an ODS column and detecting with an ultraviolet absorptiometer or the like.

  In the present invention, the fact that the relative retention time with respect to gallic acid does not substantially have a peak in the time range of 0.54 to 0.61 means that the area value at the time of analysis of a 1 ppm solution of gallic acid is S1, and coffee under the same conditions. When the sum of the peak areas derived from the components eluted in the specific region when the beverage composition is analyzed is S2, it means that S2 / S1 <0.01.

  The container-packed coffee beverage of the present invention can be added with sugars such as sucrose, glucose, fructose, xylose, fructose glucose solution, sugar alcohol, antioxidants, pH adjusters, emulsifiers, fragrances and the like as desired. . The pH of the coffee composition is preferably 5 to 7, more preferably 5.4 to 6.5, and particularly preferably 5.5 to 6.2 from the viewpoint of beverage flavor and stability.

L value measurement of roasted coffee beans:
The L value was measured with a colorimetric color difference meter ZE-2000 (Nippon Denshoku Industries Co., Ltd.).
The roasted coffee beans were pulverized to a particle size of 500 μm or less with a high-cut coffee mill (made by Karita, scale: 1). The ground beans were put so as to fill the measurement cell, and the ground beans were lightly pressed from above so that there was no gap at the bottom of the cell. The measurement was performed at least three times, and the reflectance of the sample when the reflectance of the standard white plate was 100 was taken as the L value.
Analysis of chlorogenic acids:
A method for analyzing chlorogenic acids in a packaged coffee beverage is as follows. The analytical instrument used was HPLC. The model numbers of the unit units are as follows. UV-VIS detector: L-2420 (Hitachi High-Technologies Corporation), column oven: L-2300 (Hitachi High-Technologies Corporation), pump: L-2130 (Hitachi High-Technologies Corporation), autosampler: L-2200 (Hitachi High-Technologies Corporation), column: Cadenza CD-C18 inner diameter 4.6 mm × length 150 mm, particle diameter 3 μm (intact Inc.).
The analysis conditions are as follows. Sample injection volume: 10 μL, flow rate: 1.0 mL / min, UV-VIS detector set wavelength: 325 nm, column oven set temperature: 35 ° C., eluent A: 0.05 M acetic acid, 0.1 mM 1-hydroxyethane-1 , 1-diphosphonic acid, 10 mM sodium acetate, 5 (V / V)% acetonitrile solution, eluent B: acetonitrile.

Concentration gradient condition Time Eluent A Eluent B
0.0 minutes 100% 0%
10.0 minutes 100% 0%
15.0 minutes 95% 5%
20.0 minutes 95% 5%
22.0 minutes 92% 8%
50.0 minutes 92% 8%
52.0 minutes 10% 90%
60.0 minutes 10% 90%
60.1 minutes 100% 0%
70.0 minutes 100% 0%

In HPLC, 1 g of a sample was precisely weighed, made up to 10 mL with eluent A, filtered through a membrane filter (GL chromatodisc 25A, pore size 0.45 μm, GL Sciences Inc.), and subjected to analysis.
Retention time of chlorogenic acids (unit: minutes)
(A ¹ ) Monocafe oil quinic acid: 5.3, 8.8, 11.6, total 3 points (A ² ) Ferlaquinic acid: 13.0, 19.9, 21.0, total 3 points (A ³ ) Dicafe oil quinic acid: 36.6
37.4, 44.2. From the area values of the nine types of chlorogenic acids determined here, 5-caffeoylquinic acid was used as a standard substance, and the mass% was determined.

Example 1
Filled with 50% by weight of activated carbon (Shirakaba WH2C) with respect to Brix with respect to the soluble solid content of the extract extracted with ion-exchanged water (95 ° C) 8 times the amount of roasted coffee beans of L value 18. The coffee extract was passed through a column (inner diameter: 45 mm, length: 150 mm) under the conditions of 25 ° C. and SV20 [1 / volume [m ³ ] / flow rate [m ³ / hr]]. A powder extract (coffee extract (b1)) obtained by spray-drying an extract obtained by continuous multi-tube extraction of roasted coffee beans having an L value of 50 with the blending ratio shown in Table 1 in the obtained activated carbon treatment liquid; After mixing, pH was adjusted with an aqueous solution in which sodium bicarbonate was dissolved, and then diluted with ion-exchanged water. After heating to 75 ° C., filling and sealing a 190 g can container, sterilization was performed at 129 ° C. for 7 minutes to prepare a canned coffee drink.

Examples 2-6
Using an activated carbon treatment liquid obtained in the same manner as in Example 1 from roasted coffee beans having an L value described in Table 1, and each coffee extract described in Table 1, the can can be obtained in the same manner as in Example 1. Made coffee.
The coffee extracts (b2) to (b4) used in Examples 4 to 6 are as follows.
・ Coffee extract (b2): Coffee extract obtained by continuous multi-tube extraction of roasted coffee beans with L value of 50 at an extraction temperature of 150 ° C. and an extraction ratio of 1.3 times. Coffee extract (b3); L value 50 roasted coffee beans extracted at 95 ° C., extraction rate 12 times, and then extracted by heating and concentrating under reduced pressure (b4); L value 50 roasted coffee beans extracted at 95 ° C. After extraction at an extraction ratio of 12 times, ethanol was added so as to be a 60% by mass aqueous ethanol solution, impurities were removed, and the coffee extract obtained by concentrating with heating under reduced pressure Example 7
Table 1 shows the activated carbon treatment liquid of roasted bean extract having L value of 16.5 and L value of 18 obtained in the same manner as in Example 1, and the coffee extract (b4) and other auxiliary materials. The mixture was mixed at a blending ratio, adjusted to pH with an aqueous solution in which sodium hydrogencarbonate was dissolved, and diluted with ion-exchanged water. After heating up to 75 ° C., filling a can container containing 190 g and sealing, sterilization was performed at 129 ° C. for 7 minutes to prepare a canned milk coffee beverage.

Examples 8-10
Canned coffee is prepared in the same manner as in Example 1, using the activated carbon treatment liquid obtained from roasted coffee beans having an L value of 22 in the same manner as in Example 1 and the coffee extracts described in Table 1. did. The sterilization condition was 118 ° C. for 10 minutes.
The coffee extracts (b5) to (b7) used in Examples 8 to 10 are as follows.
-Coffee extract (b5): Coffee extract obtained by subjecting the extract obtained by continuous multi-pipe extraction of roasted coffee beans having an L value of 50 under the same conditions as deep roasted beans of Example 1 to extract coffee / coffee Product (b6): Coffee obtained by extracting roasted coffee beans with an L value of 50 at an extraction temperature of 95 ° C. and an extraction ratio of 12 times, then treating with activated carbon under the same conditions as those of deep roasted beans of Example 1, and heating and concentrating under reduced pressure. Extract / coffee extract (b7): Extracted roasted coffee beans with an L value of 50 at an extraction temperature of 95 ° C. and an extraction ratio of 12 times, concentrated by heating under reduced pressure, and treated with activated carbon under the same conditions as the deep roasted beans of Example 1 Coffee extract

Example 11
Table 1 shows the activated carbon treatment liquid of roasted bean extract having L value of 16.5 and L value of 18 obtained in the same manner as in Example 7, and the coffee extract (b7) and other auxiliary materials. The mixture was mixed at a blending ratio, adjusted to pH with an aqueous solution in which sodium hydrogencarbonate was dissolved, and diluted with ion-exchanged water. The can was heated to 75 ° C., filled in a can container containing 190 g, sealed, and then sterilized at 118 ° C. for 10 minutes to prepare a canned milk coffee beverage.

Comparative Example 1
Except for using roasted coffee beans having an L value of 22, an extract was extracted and treated with activated carbon in the same manner as in Example 1 to obtain an activated carbon-treated solution. Subsequently, after adjusting pH with the aqueous solution which melt | dissolved sodium hydrogencarbonate by the mixture ratio shown in Table 1, it diluted with ion-exchange water. The mixture was heated to 75 ° C., filled into a 190 g can container, sealed, and then sterilized at 118 ° C. for 10 minutes.

Comparative Example 2
Using the activated carbon treatment liquid obtained in the same manner as in Comparative Example 1, an auxiliary raw material was prepared at a mixing ratio shown in Table 1, adjusted to pH with an aqueous solution in which sodium bicarbonate was dissolved, and diluted with ion-exchanged water. The mixture was heated to 75 ° C., filled into a 190 g can container, sealed, and then sterilized at 118 ° C. for 10 minutes.

Examples 12 and 13
An activated carbon treatment liquid obtained in the same manner as in Example 1 from roasted coffee beans having an L value of 16.5 and the coffee extracts (b1) and (b6) were prepared at the blending ratios shown in Table 1. , Made a canned coffee.
The sensory evaluation was based on the following indices, and the body feeling and aroma were evaluated. The results are shown in Table 1.
・ Evaluation index for body feeling 1; Body is rich 2; Body is slightly rich 3; Neither can be said 4; Lightness 5; Very light • Evaluation index 1 for aroma Rich 2; aroma is slightly rich 3; neither can be said 4; aroma is soft 5; aroma is thin

  As is clear from the results shown in Table 1, when an extract obtained by subjecting a deep roast bean extract to activated carbon treatment and a shallow roast bean extract not treated with an adsorbent were mixed (Examples 1 to 7, 12) It can be seen that the body feeling or aroma feeling (or both) is enriched and the attractiveness as a coffee drink is improved as compared with the case where one kind of bean extract is treated with activated carbon (Comparative Examples 1 and 2). . On the other hand, when both the deep roast bean extract and the shallow roast bean extract are mixed after the activated carbon treatment (Examples 8 to 11 and 13), the body feel is light and the aroma becomes soft, so coffee is not good. It becomes easy for people to drink.

Claims (7)

(1) A step of obtaining a coffee extract (a) by subjecting a coffee extract extracted from roasted coffee beans having an L value of 14 to 25 to an adsorbent;
(2) obtaining a coffee extract (b) from roasted coffee beans having an L value of 40 to 55;
(3) mixing each extract (a) and (b) to obtain a coffee solution;
(4) a step of heat sterilizing the coffee solution;
A method for producing a containerized coffee beverage, comprising:   The manufacturing method of the container-packed coffee drink of Claim 1 or 2 which uses for the process (3), without performing an adsorbent process to the extract liquid extracted from the coffee beans of L value 40-55 in the said process (2). .   The manufacture of the container-packed coffee drink of any one of Claims 1-3 which mixes the said extract (a) and (b) by the ratio of the coffee solid content contained in each 4: 6-8: 2. Method.   The container-packed coffee drink of Claim 1 including the process of obtaining a coffee extract (b) by concentrating the extract extracted from the roasted coffee beans whose L value is 40-55 in the said process (2). Manufacturing method.   The sterilization temperature of the said coffee solution is 123 degreeC or more, The manufacturing method of the container-packed coffee drink in any one of Claims 1-4.   The method for producing a containerized coffee beverage according to any one of claims 1 to 5, wherein the heat sterilization treatment is performed after the coffee solution is packed in a container. Manufactured by the method according to any one of claims 1 to 6,
(A) Chlorogenic acid concentration of 0.14 to 0.5% by mass,
(B) a mass ratio of hydroxyhydroquinone and chlorogenic acids of 5 / 10,000 or less,
Is a containerized coffee drink.