JP2009005685A - Packaged beverage - Google Patents
Packaged beverage Download PDFInfo
- Publication number
- JP2009005685A JP2009005685A JP2008100388A JP2008100388A JP2009005685A JP 2009005685 A JP2009005685 A JP 2009005685A JP 2008100388 A JP2008100388 A JP 2008100388A JP 2008100388 A JP2008100388 A JP 2008100388A JP 2009005685 A JP2009005685 A JP 2009005685A
- Authority
- JP
- Japan
- Prior art keywords
- mass
- green tea
- tea extract
- packaged beverage
- container
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 235000013361 beverage Nutrition 0.000 title claims abstract description 60
- ADRVNXBAWSRFAJ-UHFFFAOYSA-N catechin Natural products OC1Cc2cc(O)cc(O)c2OC1c3ccc(O)c(O)c3 ADRVNXBAWSRFAJ-UHFFFAOYSA-N 0.000 claims abstract description 68
- 235000005487 catechin Nutrition 0.000 claims abstract description 68
- 150000001765 catechin Chemical class 0.000 claims abstract description 54
- 229940094952 green tea extract Drugs 0.000 claims abstract description 45
- 235000020688 green tea extract Nutrition 0.000 claims abstract description 45
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims abstract description 21
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 claims abstract description 14
- ZSIAUFGUXNUGDI-UHFFFAOYSA-N hexan-1-ol Chemical compound CCCCCCO ZSIAUFGUXNUGDI-UHFFFAOYSA-N 0.000 claims abstract description 14
- UFLHIIWVXFIJGU-ARJAWSKDSA-N (Z)-hex-3-en-1-ol Chemical compound CC\C=C/CCO UFLHIIWVXFIJGU-ARJAWSKDSA-N 0.000 claims abstract description 7
- UFLHIIWVXFIJGU-UHFFFAOYSA-N hex-3-en-1-ol Natural products CCC=CCCO UFLHIIWVXFIJGU-UHFFFAOYSA-N 0.000 claims abstract description 7
- 235000019260 propionic acid Nutrition 0.000 claims abstract description 7
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 claims abstract description 7
- HNAGHMKIPMKKBB-UHFFFAOYSA-N 1-benzylpyrrolidine-3-carboxamide Chemical compound C1C(C(=O)N)CCN1CC1=CC=CC=C1 HNAGHMKIPMKKBB-UHFFFAOYSA-N 0.000 claims abstract description 6
- OBNCKNCVKJNDBV-UHFFFAOYSA-N butanoic acid ethyl ester Natural products CCCC(=O)OCC OBNCKNCVKJNDBV-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229920000642 polymer Polymers 0.000 claims description 53
- LNTHITQWFMADLM-UHFFFAOYSA-N gallic acid Chemical compound OC(=O)C1=CC(O)=C(O)C(O)=C1 LNTHITQWFMADLM-UHFFFAOYSA-N 0.000 claims description 33
- 244000269722 Thea sinensis Species 0.000 claims description 27
- 235000013616 tea Nutrition 0.000 claims description 20
- 235000004515 gallic acid Nutrition 0.000 claims description 11
- 229940074391 gallic acid Drugs 0.000 claims description 11
- 239000012264 purified product Substances 0.000 claims description 8
- 235000003599 food sweetener Nutrition 0.000 claims description 7
- 239000003765 sweetening agent Substances 0.000 claims description 7
- 235000019658 bitter taste Nutrition 0.000 abstract description 26
- 235000019606 astringent taste Nutrition 0.000 abstract description 20
- -1 1-p-menthane-8-thiol Chemical compound 0.000 abstract description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 33
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 27
- 239000003463 adsorbent Substances 0.000 description 27
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 26
- 238000011282 treatment Methods 0.000 description 25
- 238000000034 method Methods 0.000 description 22
- 239000007864 aqueous solution Substances 0.000 description 19
- 239000000203 mixture Substances 0.000 description 19
- 108010038851 tannase Proteins 0.000 description 18
- 239000004927 clay Substances 0.000 description 17
- 239000007788 liquid Substances 0.000 description 15
- 239000003960 organic solvent Substances 0.000 description 15
- PFTAWBLQPZVEMU-DZGCQCFKSA-N (+)-catechin Chemical compound C1([C@H]2OC3=CC(O)=CC(O)=C3C[C@@H]2O)=CC=C(O)C(O)=C1 PFTAWBLQPZVEMU-DZGCQCFKSA-N 0.000 description 14
- 229950001002 cianidanol Drugs 0.000 description 14
- 239000000284 extract Substances 0.000 description 14
- 235000002639 sodium chloride Nutrition 0.000 description 12
- 238000000605 extraction Methods 0.000 description 11
- LVJJFMLUMNSUFN-UHFFFAOYSA-N gallocatechin gallate Natural products C1=C(O)C=C2OC(C=3C=C(O)C(O)=CC=3)C(O)CC2=C1OC(=O)C1=CC(O)=C(O)C(O)=C1 LVJJFMLUMNSUFN-UHFFFAOYSA-N 0.000 description 11
- RYYVLZVUVIJVGH-UHFFFAOYSA-N caffeine Chemical compound CN1C(=O)N(C)C(=O)C2=C1N=CN2C RYYVLZVUVIJVGH-UHFFFAOYSA-N 0.000 description 10
- 239000007787 solid Substances 0.000 description 10
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 9
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 9
- 239000002253 acid Substances 0.000 description 9
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 9
- 238000010828 elution Methods 0.000 description 9
- XMOCLSLCDHWDHP-IUODEOHRSA-N epi-Gallocatechin Chemical compound C1([C@H]2OC3=CC(O)=CC(O)=C3C[C@H]2O)=CC(O)=C(O)C(O)=C1 XMOCLSLCDHWDHP-IUODEOHRSA-N 0.000 description 9
- 239000000796 flavoring agent Substances 0.000 description 9
- 235000019634 flavors Nutrition 0.000 description 9
- 239000000047 product Substances 0.000 description 9
- 239000000126 substance Substances 0.000 description 9
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 8
- WMBWREPUVVBILR-UHFFFAOYSA-N GCG Natural products C=1C(O)=C(O)C(O)=CC=1C1OC2=CC(O)=CC(O)=C2CC1OC(=O)C1=CC(O)=C(O)C(O)=C1 WMBWREPUVVBILR-UHFFFAOYSA-N 0.000 description 8
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 8
- 230000000694 effects Effects 0.000 description 8
- 238000000746 purification Methods 0.000 description 8
- LSHVYAFMTMFKBA-PZJWPPBQSA-N (+)-catechin-3-O-gallate Chemical compound O([C@H]1CC2=C(O)C=C(C=C2O[C@@H]1C=1C=C(O)C(O)=CC=1)O)C(=O)C1=CC(O)=C(O)C(O)=C1 LSHVYAFMTMFKBA-PZJWPPBQSA-N 0.000 description 7
- 230000002378 acidificating effect Effects 0.000 description 7
- 230000000052 comparative effect Effects 0.000 description 7
- 238000001914 filtration Methods 0.000 description 7
- 235000015203 fruit juice Nutrition 0.000 description 7
- 150000002500 ions Chemical class 0.000 description 7
- 150000003839 salts Chemical class 0.000 description 7
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 6
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 6
- XMOCLSLCDHWDHP-UHFFFAOYSA-N L-Epigallocatechin Natural products OC1CC2=C(O)C=C(O)C=C2OC1C1=CC(O)=C(O)C(O)=C1 XMOCLSLCDHWDHP-UHFFFAOYSA-N 0.000 description 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 6
- 239000012141 concentrate Substances 0.000 description 6
- 235000008504 concentrate Nutrition 0.000 description 6
- DZYNKLUGCOSVKS-UHFFFAOYSA-N epigallocatechin Natural products OC1Cc2cc(O)cc(O)c2OC1c3cc(O)c(O)c(O)c3 DZYNKLUGCOSVKS-UHFFFAOYSA-N 0.000 description 6
- 229910052500 inorganic mineral Inorganic materials 0.000 description 6
- XMGQYMWWDOXHJM-UHFFFAOYSA-N limonene Chemical compound CC(=C)C1CCC(C)=CC1 XMGQYMWWDOXHJM-UHFFFAOYSA-N 0.000 description 6
- 235000010755 mineral Nutrition 0.000 description 6
- 239000011707 mineral Substances 0.000 description 6
- 239000011259 mixed solution Substances 0.000 description 6
- 229920005597 polymer membrane Polymers 0.000 description 6
- 239000011148 porous material Substances 0.000 description 6
- 238000000926 separation method Methods 0.000 description 6
- 239000011734 sodium Substances 0.000 description 6
- 229910052708 sodium Inorganic materials 0.000 description 6
- 229910001415 sodium ion Inorganic materials 0.000 description 6
- WMBWREPUVVBILR-WIYYLYMNSA-N (-)-Epigallocatechin-3-o-gallate Chemical compound O([C@@H]1CC2=C(O)C=C(C=C2O[C@@H]1C=1C=C(O)C(O)=C(O)C=1)O)C(=O)C1=CC(O)=C(O)C(O)=C1 WMBWREPUVVBILR-WIYYLYMNSA-N 0.000 description 5
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 5
- LPHGQDQBBGAPDZ-UHFFFAOYSA-N Isocaffeine Natural products CN1C(=O)N(C)C(=O)C2=C1N(C)C=N2 LPHGQDQBBGAPDZ-UHFFFAOYSA-N 0.000 description 5
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 5
- 229960001948 caffeine Drugs 0.000 description 5
- VJEONQKOZGKCAK-UHFFFAOYSA-N caffeine Natural products CN1C(=O)N(C)C(=O)C2=C1C=CN2C VJEONQKOZGKCAK-UHFFFAOYSA-N 0.000 description 5
- 235000009569 green tea Nutrition 0.000 description 5
- 239000012528 membrane Substances 0.000 description 5
- 229910001414 potassium ion Inorganic materials 0.000 description 5
- 238000002360 preparation method Methods 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- 238000001179 sorption measurement Methods 0.000 description 5
- WMBWREPUVVBILR-GHTZIAJQSA-N (+)-gallocatechin gallate Chemical compound O([C@H]1CC2=C(O)C=C(C=C2O[C@@H]1C=1C=C(O)C(O)=C(O)C=1)O)C(=O)C1=CC(O)=C(O)C(O)=C1 WMBWREPUVVBILR-GHTZIAJQSA-N 0.000 description 4
- CHRJZRDFSQHIFI-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;styrene Chemical compound C=CC1=CC=CC=C1.C=CC1=CC=CC=C1C=C CHRJZRDFSQHIFI-UHFFFAOYSA-N 0.000 description 4
- 244000274847 Betula papyrifera Species 0.000 description 4
- 235000009113 Betula papyrifera Nutrition 0.000 description 4
- 235000009109 Betula pendula Nutrition 0.000 description 4
- 235000010928 Betula populifolia Nutrition 0.000 description 4
- 235000002992 Betula pubescens Nutrition 0.000 description 4
- 229920000858 Cyclodextrin Polymers 0.000 description 4
- 108090000790 Enzymes Proteins 0.000 description 4
- 102000004190 Enzymes Human genes 0.000 description 4
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 4
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 4
- 229930006000 Sucrose Natural products 0.000 description 4
- 150000001720 carbohydrates Chemical class 0.000 description 4
- 235000014633 carbohydrates Nutrition 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 230000035622 drinking Effects 0.000 description 4
- 229940088598 enzyme Drugs 0.000 description 4
- 229940030275 epigallocatechin gallate Drugs 0.000 description 4
- 238000011156 evaluation Methods 0.000 description 4
- 229920000139 polyethylene terephthalate Polymers 0.000 description 4
- 239000005020 polyethylene terephthalate Substances 0.000 description 4
- 235000011496 sports drink Nutrition 0.000 description 4
- 239000005720 sucrose Substances 0.000 description 4
- XMOCLSLCDHWDHP-SWLSCSKDSA-N (+)-Epigallocatechin Natural products C1([C@H]2OC3=CC(O)=CC(O)=C3C[C@@H]2O)=CC(O)=C(O)C(O)=C1 XMOCLSLCDHWDHP-SWLSCSKDSA-N 0.000 description 3
- LSHVYAFMTMFKBA-TZIWHRDSSA-N (-)-epicatechin-3-O-gallate Chemical compound O([C@@H]1CC2=C(O)C=C(C=C2O[C@@H]1C=1C=C(O)C(O)=CC=1)O)C(=O)C1=CC(O)=C(O)C(O)=C1 LSHVYAFMTMFKBA-TZIWHRDSSA-N 0.000 description 3
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 description 3
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 description 3
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- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 3
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- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 description 3
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- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 235000019408 sucralose Nutrition 0.000 description 1
- BAQAVOSOZGMPRM-QBMZZYIRSA-N sucralose Chemical compound O[C@@H]1[C@@H](O)[C@@H](Cl)[C@@H](CO)O[C@@H]1O[C@@]1(CCl)[C@@H](O)[C@H](O)[C@@H](CCl)O1 BAQAVOSOZGMPRM-QBMZZYIRSA-N 0.000 description 1
- 125000000185 sucrose group Chemical group 0.000 description 1
- 150000005846 sugar alcohols Chemical class 0.000 description 1
- 150000008163 sugars Chemical class 0.000 description 1
- 230000009469 supplementation Effects 0.000 description 1
- 230000001629 suppression Effects 0.000 description 1
- 210000004243 sweat Anatomy 0.000 description 1
- 239000006188 syrup Substances 0.000 description 1
- 235000020357 syrup Nutrition 0.000 description 1
- 239000008399 tap water Substances 0.000 description 1
- 235000020679 tap water Nutrition 0.000 description 1
- 239000000892 thaumatin Substances 0.000 description 1
- 235000010436 thaumatin Nutrition 0.000 description 1
- 238000002834 transmittance Methods 0.000 description 1
- 229940074410 trehalose Drugs 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 238000009423 ventilation Methods 0.000 description 1
- 235000019155 vitamin A Nutrition 0.000 description 1
- 239000011719 vitamin A Substances 0.000 description 1
- 235000019156 vitamin B Nutrition 0.000 description 1
- 239000011720 vitamin B Substances 0.000 description 1
- 235000019154 vitamin C Nutrition 0.000 description 1
- 239000011718 vitamin C Substances 0.000 description 1
- 235000019166 vitamin D Nutrition 0.000 description 1
- 239000011710 vitamin D Substances 0.000 description 1
- 150000003710 vitamin D derivatives Chemical class 0.000 description 1
- 235000019165 vitamin E Nutrition 0.000 description 1
- 229940046009 vitamin E Drugs 0.000 description 1
- 239000011709 vitamin E Substances 0.000 description 1
- 229940045997 vitamin a Drugs 0.000 description 1
- 229940046008 vitamin d Drugs 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
- 239000000811 xylitol Substances 0.000 description 1
- 235000010447 xylitol Nutrition 0.000 description 1
- HEBKCHPVOIAQTA-SCDXWVJYSA-N xylitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)CO HEBKCHPVOIAQTA-SCDXWVJYSA-N 0.000 description 1
- 229960002675 xylitol Drugs 0.000 description 1
Landscapes
- Tea And Coffee (AREA)
- Non-Alcoholic Beverages (AREA)
Abstract
Description
本発明は、非重合体カテキン類含有容器詰飲料に関する。 The present invention relates to a non-polymer catechin-containing container-packed beverage.
カテキン類の効果としてはαアミラーゼ活性阻害作用などが報告されている。このような生理効果を発現させるためには、より簡便に大量のカテキン類を摂取する必要があるため、飲料にカテキン類を高濃度配合する技術が望まれていた。 As an effect of catechins, α amylase activity inhibitory action and the like have been reported. In order to express such a physiological effect, since it is necessary to ingest a large amount of catechins more easily, a technique for blending a high concentration of catechins in a beverage has been desired.
この方法の一つとして、緑茶抽出物の濃縮物などの茶抽出物を利用して、カテキン類を飲料に添加する方法が用いられている。しかしながら、例えば紅茶抽出液にカテキン類を高濃度に配合した場合、カフェイン及び緑茶由来の苦渋みの残存が飲料の商品価値を大きく損ねることがわかっている。 As one of the methods, a method of adding catechins to a beverage using a tea extract such as a concentrate of a green tea extract is used. However, for example, when catechins are blended at a high concentration in black tea extract, it has been found that the residual bitterness derived from caffeine and green tea greatly impairs the commercial value of beverages.
紅茶等の発酵茶抽出液に対してタンナーゼ処理を行い、低温冷却時の懸濁、すなわちティークリーム形成を抑制できることは古くから知られていた。又、特許文献1に見られるカテキンガレート体にタンナーゼ処理を行い、一部又は全部を没食子酸とすることにより、カテキン類と没食子酸との混合物を得る方法によれば、苦味の原因となるカテキンガレート体を低減することができるが、苦味をなくすこと、特に、後味の悪さについては、課題として残った。また、茶抽出物からカフェイン等の苦味を有する夾雑物を取り除く方法としては、吸着法(特許文献2〜4)、抽出法(特許文献5)等が知られている。
しかしながら、緑茶抽出物を配合した非重合体カテキン類を高濃度に含有する飲料において、非重合体カテキン類特有の苦みや渋みが気になり、途中で飲用を中止してしまう場合がある。また、飲料保存時に非重合体カテキン類特有の苦みや渋みが強調され嗜好性が下がる場合がある。
従って、本発明の目的は、高濃度に非重合体カテキン類を配合した飲料における苦みや渋みを緩和した容器詰飲料を提供することにある。
However, in beverages containing a high concentration of non-polymer catechins blended with green tea extract, the bitterness and astringency peculiar to non-polymer catechins may be worrisome and drinking may be stopped in the middle. Moreover, the bitterness and astringency peculiar to non-polymer catechins may be emphasized at the time of drink preservation, and palatability may fall.
Accordingly, an object of the present invention is to provide a packaged beverage that alleviates bitterness and astringency in beverages containing non-polymer catechins at a high concentration.
そこで本発明者は、緑茶抽出物を配合した非重合体カテキン類を高濃度に含有する飲料に、種々のフレーバー成分を配合して、苦みや渋みに対する影響を検討してきたところ、柑橘類に多く含まれているリモネンに比べて、特定の成分を非重合体カテキン類に対して一定の比率で配合することにより、非重合体カテキン類特有の苦みや渋みが緩和され、おいしく飲める飲料が得られることを見出した。 Therefore, the present inventor has examined the influence on bitterness and astringency by blending various flavor components into a beverage containing a high concentration of non-polymer catechins blended with a green tea extract, and it contains a lot of citrus fruits. Compared to limonene, certain ingredients are blended at a certain ratio with respect to non-polymer catechins, so that the bitterness and astringency peculiar to non-polymer catechins are alleviated and a drink that can be enjoyed deliciously is obtained. I found.
すなわち、本発明は、緑茶抽出物を配合したpH2〜6の容器詰飲料であって、
次の成分(A)及び(B):
(A)非重合体カテキン類 0.03〜0.6質量%、
(B)ヘキサノール、cis−3−ヘキセノール、プロピオン酸、酢酸エチル、1−p−メンタン−8−チオール及び酪酸エチルよりなる群から選ばれる1種以上
を(B)/(A)(質量比)が0.0001〜5の範囲で含有する容器詰飲料を提供するものである。
That is, the present invention is a packaged beverage having a pH of 2 to 6 containing a green tea extract,
The following components (A) and (B):
(A) Non-polymer catechins 0.03-0.6 mass%,
(B) One or more selected from the group consisting of hexanol, cis-3-hexenol, propionic acid, ethyl acetate, 1-p-menthane-8-thiol and ethyl butyrate (B) / (A) (mass ratio) Is a container-packed beverage containing 0.0001-5.
本発明の容器詰飲料は、生理効果を奏するのに十分な量の非重合体カテキン類を含有しながら、非重合体カテキン類特有の苦みや渋みが緩和され、苦みや渋みが不得手な方にとっても飲みやすい飲料である。 The container-packed beverage of the present invention contains a sufficient amount of non-polymer catechins to exert a physiological effect, while bitterness and astringency peculiar to non-polymer catechins are alleviated, and bitterness and astringency are poor It is a drink that is easy to drink.
本発明で非重合体カテキン類とは、カテキン、ガロカテキン、カテキンガレート、ガロカテキンガレートなどの非エピ体カテキン、及びエピカテキン、エピガロカテキン、エピカテキンガレート、エピガロカテキンガレートなどのエピ体カテキンをあわせての総称である。なお、非重合体カテキン類の濃度は上記8種の合計量に基づいて定義される。 Non-polymer catechins in the present invention include non-epimeric catechins such as catechin, gallocatechin, catechin gallate, and gallocatechin gallate, and epi-catechins such as epicatechin, epigallocatechin, epicatechin gallate, and epigallocatechin gallate. It is a collective term. In addition, the density | concentration of non-polymer catechin is defined based on the said 8 types total amount.
本発明で非重合体カテキンガレート体とは、カテキンガレート、ガロカテキンガレート、エピカテキンガレート、エピガロカテキンガレートなどをあわせての総称である。非重合体カテキン類中のガレート体率とは、カテキン、ガロカテキン、カテキンガレート、ガロカテキンガレート、エピカテキン、エピガロカテキン、エピカテキンガレート、エピガロカテキンガレートの質量和に対する非重合体カテキンガレート体4種の質量和の比率を100分率で示した値である。
また、非重合体カテキンガロ体とは、ガロカテキン、ガロカテキンガレート、エピガロカテキン、エピガロカテキンガレートなどをあわせての総称である。
In the present invention, the non-polymer catechin gallate body is a general term including catechin gallate, gallocatechin gallate, epicatechin gallate, epigallocatechin gallate and the like. The percentage of gallate body in the non-polymer catechins means catechin, gallocatechin, catechin gallate, gallocatechin gallate, epicatechin, epigallocatechin, epicatechin gallate, epigallocatechin gallate mass sum of non-polymer catechin gallate 4 It is the value which showed the ratio of the mass sum of a seed | species by 100 fraction.
Further, the non-polymer catechin gallo form is a general term including gallocatechin, gallocatechin gallate, epigallocatechin, epigallocatechin gallate and the like.
本発明の容器詰飲料中には、非重合体カテキン類を0.03〜0.6質量%含有するが、その上限値は好ましくは0.55質量%、より好ましくは0.52質量%、更に好ましくは0.4質量%、特に好ましくは0.3質量%、殊更0.2質量%であり、他方下限値は好ましくは0.04質量%、より好ましくは0.06質量%、更に0.08質量%、特に0.1質量%である。非重合体カテキン類の濃度がこの範囲にあると、多量の非重合カテキン類を容易に摂取しやすく、風味及び色調、並びに非重合体カテキン類の安定性の点からも好ましい。 The container-packed beverage of the present invention contains 0.03 to 0.6% by mass of non-polymer catechins, but the upper limit is preferably 0.55% by mass, more preferably 0.52% by mass, More preferably 0.4% by weight, particularly preferably 0.3% by weight, especially 0.2% by weight, while the lower limit is preferably 0.04% by weight, more preferably 0.06% by weight, furthermore 0%. 0.08% by weight, in particular 0.1% by weight. When the concentration of the non-polymer catechins is within this range, a large amount of the non-polymer catechins can be easily ingested, which is preferable from the viewpoint of flavor and color, and stability of the non-polymer catechins.
また、本発明の容器詰飲料中の没食子酸含有量は、苦味、酸味の低減効果、更には風味及び色調、並びに非重合体カテキン類の保存安定性の点から0.0004〜29mg/100mLであることが好ましく、更に0.0004〜20mg/100mLであることが好ましく、更に0.0004〜10mg/100mL、特に0.0004〜5mg/100mLであるのが好ましい。没食子酸含有量の調整は、樹脂による吸着などにより行われる。 In addition, the gallic acid content in the packaged beverage of the present invention is 0.0004 to 29 mg / 100 mL from the viewpoints of bitterness, sourness reducing effect, flavor and color tone, and storage stability of non-polymer catechins. It is preferable that the concentration is 0.0004 to 20 mg / 100 mL, more preferably 0.0004 to 10 mg / 100 mL, and particularly preferably 0.0004 to 5 mg / 100 mL. Adjustment of the gallic acid content is performed by adsorption with a resin or the like.
本発明の容器詰飲料には、苦み、渋みを低減させる点から、(B)ヘキサノール、cis−3−ヘキセノール、プロピオン酸、酢酸エチル、1−p−メンタン−8−チオール及び酪酸エチルから選ばれる1種以上を含有する。好ましくは、ヘキサノール、cis−3−ヘキセノール、プロピオン酸及び1−p−メンタン−8−チオールから選ばれる1種以上を含有することである。
(B)/(A)(質量比)は、0.0001〜5の範囲であるが、好ましくは0.0001〜1、更に好ましくは、0.0001〜0.5、特に好ましくは0.001〜0.5である。本発明者は、これら特定の成分が、リモネン等の他のフレーバー成分に比べて特に顕著に苦み、渋み抑制効果に優れていることを見出したのである。また、成分(B)は、本発明の容器詰飲料中に0.0001〜1質量%、更に0.0001〜0.5質量%、特に0.0001〜0.2質量%含有するのが好ましい。リモネンの含有量は、0.0002質量%未満、好ましくは0.0001質量%未満である。
The packaged beverage of the present invention is selected from (B) hexanol, cis-3-hexenol, propionic acid, ethyl acetate, 1-p-menthane-8-thiol and ethyl butyrate from the viewpoint of reducing bitterness and astringency. Contains one or more. Preferably, it contains one or more selected from hexanol, cis-3-hexenol, propionic acid and 1-p-menthane-8-thiol.
(B) / (A) (mass ratio) is in the range of 0.0001 to 5, preferably 0.0001 to 1, more preferably 0.0001 to 0.5, and particularly preferably 0.001. ~ 0.5. The present inventor has found that these specific components are particularly bitter as compared with other flavor components such as limonene, and are excellent in astringency suppressing effect. Moreover, it is preferable to contain a component (B) 0.0001-1 mass% in the container-packed drink of this invention, 0.0001-0.5 mass%, especially 0.0001-0.2 mass%. . The limonene content is less than 0.0002% by mass, preferably less than 0.0001% by mass.
本発明の容器詰飲料としては非茶系容器詰飲料が好ましく、具体的には、炭酸飲料、エンハンスドウォーター、ボトルドウォーター、スポーツドリンク、エネルギードリンク、ニアウォーター、アイソトニック飲料、ハイポトニック飲料、ハイパートニック飲料等の形態が挙げられる。 As the packaged beverage of the present invention, a non-tea-based packaged beverage is preferable. Specifically, carbonated beverage, enhanced water, bottled water, sports drink, energy drink, near water, isotonic beverage, hypotonic beverage, hypertonic beverage And the like.
酸性飲料とする場合の甘味料の含有量は甘味付加の点から容器詰飲料中に0.0001〜20質量%、更に0.005〜10質量%、特に0.005〜5質量%が好ましい。また上記成分以外のフルーツフレーバーの含有量は、風味向上の点から容器詰飲料中に、0.001〜5質量%、更に0.001〜3質量%、特に0.01〜2質量%が好ましい。また、pH(25℃)は2〜6であるが、更に、2〜5.5、更に3〜5が好ましい。 In the case of an acidic beverage, the content of the sweetener is preferably 0.0001 to 20% by mass, more preferably 0.005 to 10% by mass, and particularly preferably 0.005 to 5% by mass in the packaged beverage from the viewpoint of sweetness addition. Moreover, content of fruit flavors other than the said component is 0.001-5 mass% in a container-packed drink from the point of a flavor improvement, Furthermore, 0.001-3 mass%, Especially 0.01-2 mass% is preferable. . Moreover, although pH (25 degreeC) is 2-6, 2-5.5 and 3-5 are still more preferable.
本発明の容器詰飲料に用いられる甘味料としては、人工甘味料類、炭水化物類、グリセロール類(例えばグリセリン)が用いられる。本発明で使用できる人工甘味料としては、サッカリン及びサッカリンナトリウム、アスパルテーム、アセサルフェーム−K、スクラロース、ネオテーム、ソーマチン、ステビアなどの高甘度甘味料、ソルビトール、エリスリトール、キシリトール、トレハロースなどの糖アルコールを使用できる。商品としては、アスパルテームからなるスリムアップシュガー(登録商標)、エリスリトールを含んだラカントS(登録商標)、エリスリトールとアスパルテームからなるパルスイート(登録商標)などが挙げられる。 As the sweetener used in the packaged beverage of the present invention, artificial sweeteners, carbohydrates, and glycerol (for example, glycerin) are used. Examples of artificial sweeteners that can be used in the present invention include saccharin and saccharin sodium, aspartame, acesulfame-K, high-sweetness sweeteners such as sucralose, neotame, thaumatin, stevia, and sugar alcohols such as sorbitol, erythritol, xylitol, and trehalose. Can be used. Examples of the products include Slim Up Sugar (registered trademark) made of aspartame, Lacanto S (registered trademark) containing erythritol, Pulsweet (registered trademark) made of erythritol and aspartame, and the like.
本発明の容器詰飲料には、単糖、オリゴ糖、複合多糖及びそれらの混合物を含む炭水化物類の甘味料を使用するのが好ましい。本発明の容器詰飲料中のグルコースの量は、0.0001〜20質量%、更に0.001〜15質量%、特に0.001〜10質量%であるのが好ましい。 In the packaged beverage of the present invention, it is preferable to use a sweetener of carbohydrates containing monosaccharides, oligosaccharides, complex polysaccharides and mixtures thereof. The amount of glucose in the packaged beverage of the present invention is preferably 0.0001 to 20% by mass, more preferably 0.001 to 15% by mass, and particularly preferably 0.001 to 10% by mass.
本発明で使用できる炭水化物類甘味料のうち、オリゴ糖としては、これら2種の単糖を体内で生成する炭水化物(すなわち、スクロース、マルトデキストリン、コーンシロップ、高フルクトースコーンシロップ)が挙げられる。この糖の中では二糖が好ましい。二糖の例は、ショ糖又はテンサイ糖として知られるスクロースである。本発明の容器詰飲料中のスクロースの量は、0.001〜20質量%、更に0.001〜15質量%、特に0.001〜10質量%であるのが好ましい。 Among the carbohydrate sweeteners that can be used in the present invention, examples of oligosaccharides include carbohydrates that produce these two monosaccharides in the body (that is, sucrose, maltodextrin, corn syrup, high fructose corn syrup). Of these sugars, disaccharides are preferred. An example of a disaccharide is sucrose known as sucrose or sugar beet sugar. The amount of sucrose in the packaged beverage of the present invention is preferably 0.001 to 20% by mass, more preferably 0.001 to 15% by mass, and particularly preferably 0.001 to 10% by mass.
本発明では、ヘキサノール、cis−3−ヘキセノール、プロピオン酸、酢酸エチル、1−p−メンタン−8−チオール及び酪酸エチルを含む天然又は合成香料や果汁が使用できる。また果汁は本発明の容器詰飲料中に0.001〜20質量%、更に0.002〜10質量%含有するのが好ましい。フルーツフレーバー、植物フレーバー及びそれらの混合物も果汁として使用できる。これらのフレーバーはフルーツジュース及び香油のような天然源から誘導しても、又は合成してもよい。 In the present invention, natural or synthetic fragrances and fruit juices containing hexanol, cis-3-hexenol, propionic acid, ethyl acetate, 1-p-menthane-8-thiol and ethyl butyrate can be used. Moreover, it is preferable to contain fruit juice 0.001-20 mass% in the container-packed drink of this invention, and also 0.002-10 mass%. Fruit flavors, plant flavors and mixtures thereof can also be used as fruit juice. These flavors may be derived from natural sources such as fruit juices and perfume oils, or may be synthesized.
本発明の容器詰飲料を、スポーツドリンク又はアイソトニック飲料とする場合には、ナトリウムイオン及び/又はカリウムイオンを含有させるのが好ましい。スポーツドリンク又はアイソトニック飲料とは、身体運動後に汗として失われる水分、ミネラルを速やかに補給できる飲料をいう。 When the packaged beverage of the present invention is a sports drink or an isotonic beverage, it is preferable to contain sodium ions and / or potassium ions. A sports drink or isotonic drink refers to a drink that can quickly replenish moisture and minerals lost as sweat after physical exercise.
主な生理電解質の中にはナトリウム及びカリウムがある。これらのイオン成分はそれらに対応する水溶性成分ないし、無機塩を添加することで含有させることができる。それらは果汁及び茶抽出物中にも存在する。電解質濃度はイオン濃度で示される。カリウムイオン成分は、塩化カリウム、炭酸カリウム、硫酸カリウム、酢酸カリウム、炭酸水素カリウム、クエン酸カリウム、リン酸カリウム、リン酸水素カリウム、酒石酸カリウム、ソルビン酸カリウム等又はそれらの混合物のような塩として、あるいは加えられた果汁又は茶の成分として本発明の容器詰飲料に配合できる。カリウムイオンは、本発明の容器詰飲料中に0.001〜0.2質量%、更に0.002〜0.15質量%、特に0.003〜0.12質量%含有することが好ましい。同様に、ナトリウムイオン成分は、塩化ナトリウム、炭酸ナトリウム、炭酸水素ナトリウム、クエン酸ナトリウム、リン酸ナトリウム、リン酸水素ナトリウム、酒石酸ナトリウム、安息香酸ナトリウム等及びそれらの混合物のような容易に入手しうるナトリウム塩として、あるいは加えられた果汁又は茶の成分として配合できる。ナトリウム濃度は浸透圧による水の吸収を容易にさせる上で低い方が望ましいが、体から腸に水を浸透圧吸引しない程度であることが、好ましい。これを行うために必要なナトリウムの濃度は、血漿ナトリウムの場合よりも低いことが好ましい。ナトリウムイオンは、本発明の容器詰飲料中に0.001〜0.5質量%、更に0.002〜0.4質量%、特に0.003〜0.2質量%含有するのが好ましい。カリウム及びナトリウムイオンに加えて、本発明の容器詰飲料には0.001〜0.5質量%、好ましくは0.002〜0.4質量%、最も好ましくは0.003〜0.3質量%の塩化物イオンを更に含有させることができる。塩化物イオン成分は塩化ナトリウム又は塩化カリウムのような塩の形態で配合できる。カルシウム及びマグネシウム、亜鉛、鉄のような他の微量イオンも配合できる。これらのイオンも塩として配合してよい。本発明の容器詰飲料中に存在するイオンの合計量には、添加されたイオン量と共に、当該容器詰飲料中に天然で存在するイオン量を含む。例えば、塩化ナトリウムが添加された場合、その量のナトリウムイオン及びその量の塩化物イオンも、それに応じて各イオンの合計量に含まれる。
ここで、ナトリウムイオンやカリウムイオン濃度が低すぎると、飲む場面によっては味が物足りなく感じ、効果的なミネラル補給ができなくて好ましくない。一方、多すぎると、塩類自体の味が強くなり長期間の飲用に好ましくない。
Among the main physiological electrolytes are sodium and potassium. These ionic components can be contained by adding water-soluble components or inorganic salts corresponding thereto. They are also present in fruit juices and tea extracts. The electrolyte concentration is indicated by the ion concentration. The potassium ion component is a salt such as potassium chloride, potassium carbonate, potassium sulfate, potassium acetate, potassium bicarbonate, potassium citrate, potassium phosphate, potassium hydrogen phosphate, potassium tartrate, potassium sorbate, etc. or a mixture thereof. Or it can mix | blend with the container-packed drink of this invention as a component of added fruit juice or tea. Potassium ions are preferably contained in the packaged beverage of the present invention in an amount of 0.001 to 0.2% by mass, further 0.002 to 0.15% by mass, particularly 0.003 to 0.12% by mass. Similarly, sodium ion components are readily available such as sodium chloride, sodium carbonate, sodium bicarbonate, sodium citrate, sodium phosphate, sodium hydrogen phosphate, sodium tartrate, sodium benzoate and the like and mixtures thereof. It can be blended as a sodium salt or as a component of added fruit juice or tea. The sodium concentration is preferably low in order to facilitate the absorption of water by osmotic pressure, but it is preferable that the sodium concentration is not osmotically sucked from the body into the intestine. The concentration of sodium required to do this is preferably lower than that of plasma sodium. Sodium ions are preferably contained in the packaged beverage of the present invention in an amount of 0.001 to 0.5% by mass, further 0.002 to 0.4% by mass, and particularly 0.003 to 0.2% by mass. In addition to potassium and sodium ions, the packaged beverages of the present invention have 0.001 to 0.5 mass%, preferably 0.002 to 0.4 mass%, most preferably 0.003 to 0.3 mass%. Of chloride ions can be further contained. The chloride ion component can be formulated in the form of a salt such as sodium chloride or potassium chloride. Other trace ions such as calcium and magnesium, zinc, iron can also be incorporated. These ions may also be blended as salts. The total amount of ions present in the packaged beverage of the present invention includes the amount of ions naturally present in the packaged beverage together with the amount of ions added. For example, when sodium chloride is added, that amount of sodium ions and that amount of chloride ions are accordingly included in the total amount of each ion.
Here, if the concentration of sodium ions or potassium ions is too low, the taste may be unsatisfactory depending on the scene of drinking, and effective mineral supplementation cannot be achieved. On the other hand, if too much, the taste of the salt itself becomes strong, which is not preferable for long-term drinking.
本発明の容器詰飲料は、苦渋味抑制剤を配合すると飲用しやすくなり好ましい。用いる苦渋味抑制剤としては、例えば、サイクロデキストリンが好ましい。サイクロデキストリンとしては、α−、β−、γ−サイクロデキストリン及び分岐α−、β−、γ−サイクロデキストリンが使用できる。本発明の容器詰飲料には、酸化防止剤、各種エステル類、有機酸類、有機酸塩類、無機酸類、無機酸塩類、色素類、乳化剤、保存料、調味料、甘味料、酸味料、ガム、油、ビタミン、アミノ酸、野菜エキス類、花蜜エキス類、pH調整剤、品質安定剤等の添加剤を単独、あるいは併用して配合できる。 The container-packed beverage of the present invention is preferably mixed with a bitter and astringent taste suppressant because it is easy to drink. As the bitter and astringent taste inhibitor to be used, for example, cyclodextrin is preferable. As the cyclodextrin, α-, β-, γ-cyclodextrin and branched α-, β-, γ-cyclodextrin can be used. The packaged beverage of the present invention includes antioxidants, various esters, organic acids, organic acid salts, inorganic acids, inorganic acid salts, pigments, emulsifiers, preservatives, seasonings, sweeteners, acidulants, gums, Additives such as oil, vitamins, amino acids, vegetable extracts, nectar extracts, pH adjusters and quality stabilizers can be used alone or in combination.
更に必要により、本発明の容器詰飲料は酸味料を含有してもよい。酸味料としては、リンゴ酸、クエン酸、酒石酸、フマル酸等のような食用酸が挙げられる。酸味料は本発明の容器詰飲料のpHを調整するために用いてもよい。本発明の容器詰飲料のpH(25℃)は2〜6であるが、pH調整剤として有機及び無機の食用酸を用いることができる。例えばリン酸水素カリウム又はそのナトリウム塩、リン酸二水素カリウム又はそのナトリウム塩のような形態で用いてもよい。好ましい酸は、クエン酸、リンゴ酸、フマル酸、アジピン酸、リン酸、グルコン酸、酒石酸、アスコルビン酸、酢酸、リン酸又はそれらの混合物を含めた食用有機酸である。最も好ましい酸はクエン酸及びリンゴ酸である。酸味料は飲料成分を安定化させる酸化防止剤としても役立つ。また常用される酸化防止剤の例には、アスコルビン酸、EDTA(エチレンジアミン四酢酸)及びそれらの塩、植物抽出エキス等が挙げられる。 Furthermore, if necessary, the packaged beverage of the present invention may contain a sour agent. Examples of acidulants include edible acids such as malic acid, citric acid, tartaric acid, fumaric acid and the like. A sour agent may be used to adjust the pH of the packaged beverage of the present invention. Although the pH (25 degreeC) of the container-packed drink of this invention is 2-6, an organic and inorganic edible acid can be used as a pH adjuster. For example, it may be used in the form of potassium hydrogen phosphate or a sodium salt thereof, potassium dihydrogen phosphate or a sodium salt thereof. Preferred acids are edible organic acids including citric acid, malic acid, fumaric acid, adipic acid, phosphoric acid, gluconic acid, tartaric acid, ascorbic acid, acetic acid, phosphoric acid or mixtures thereof. The most preferred acids are citric acid and malic acid. The sour agent also serves as an antioxidant that stabilizes the beverage ingredients. Examples of commonly used antioxidants include ascorbic acid, EDTA (ethylenediaminetetraacetic acid) and salts thereof, plant extract and the like.
本発明の容器詰飲料には、ビタミンを更に含有させることができる。好ましくは、ビタミンA、ビタミンC及びビタミンEが加えられる。ビタミンD及びビタミンBのような他のビタミンを加えてもよい。ミネラルも本発明の容器詰飲料に用いることができる。好ましいミネラルはカルシウム、クロム、銅、フッ素、ヨウ素、鉄、マグネシウム、マンガン、リン、セレン、ケイ素、モリブデン及び亜鉛である。特に好ましいミネラルはマグネシウム、リン及び鉄である。 The container-packed beverage of the present invention can further contain vitamins. Preferably vitamin A, vitamin C and vitamin E are added. Other vitamins such as vitamin D and vitamin B may be added. Minerals can also be used in the packaged beverage of the present invention. Preferred minerals are calcium, chromium, copper, fluorine, iodine, iron, magnesium, manganese, phosphorus, selenium, silicon, molybdenum and zinc. Particularly preferred minerals are magnesium, phosphorus and iron.
また、本発明の容器詰飲料は、色調の保存安定性が良好であるため透明容器詰飲料としても有用である。ここで透明容器とは、無色透明又は有色透明の容器をいう。 Moreover, since the container-packed drink of this invention has favorable storage stability of a color tone, it is useful also as a transparent container-packed drink. Here, the transparent container means a colorless transparent or colored transparent container.
本発明の容器詰飲料に使用される容器は、ポリエチレンテレフタレートを主成分とする成形容器(いわゆるPETボトル)、瓶等の通常の形態で提供することができるものである。ここでいう容器詰飲料とは希釈せずに飲用できるものをいう。 The container used for the container-packed beverage of the present invention can be provided in a normal form such as a molded container (so-called PET bottle), a bottle or the like mainly composed of polyethylene terephthalate. The term “packaged beverage” as used herein means a beverage that can be drunk without dilution.
本発明の容器詰飲料は、例えば、金属缶のように容器に充填後、加熱殺菌できる場合にあっては食品衛生法に定められた殺菌条件で製造されるが、PETボトル、紙容器のようにレトルト殺菌できないものについては、あらかじめ上記と同等の殺菌条件、例えばプレート式熱交換器等で高温短時間殺菌後、一定の温度迄冷却して容器に充填する等の方法が採用される。また無菌下で、充填された容器に別の成分を配合して充填してもよい。 The container-packed beverage of the present invention is manufactured under the sterilization conditions stipulated in the Food Sanitation Law when it can be sterilized by heating after filling into a container like a metal can, for example, a PET bottle, a paper container, etc. For those that cannot be retort sterilized, a sterilization condition equivalent to the above, for example, a method of sterilizing at high temperature and short time in a plate heat exchanger or the like and then cooling to a certain temperature and filling the container is adopted. Moreover, you may mix | blend another component with the filled container under aseptic conditions.
本発明の容器詰飲料には、緑茶抽出物が配合される。
本発明で用いる緑茶抽出物としては、緑茶葉から得られた抽出液が挙げられる。使用する茶葉としては、より具体的には、Camellia属、例えばC.sinensis、C.assamica、及びやぶきた種又はそれらの雑種等から得られる茶葉から製茶された茶葉が挙げられる。製茶された茶葉には、煎茶、番茶、玉露、てん茶、釜炒り茶等の緑茶類がある。本発明で用いる緑茶抽出物としては、緑茶の茶葉から得られた抽出液を乾燥したもの等が好ましい。
The packaged beverage of the present invention is mixed with a green tea extract.
Examples of the green tea extract used in the present invention include an extract obtained from green tea leaves. More specifically, the tea leaves to be used include tea leaves made from tea leaves obtained from the genus Camellia, for example, C. sinensis, C. assamica, and Yabuki species or hybrids thereof. The tea leaves produced include green teas such as sencha, bancha, gyokuro, tencha, and kettle roasted tea. As the green tea extract used in the present invention, those obtained by drying an extract obtained from green tea leaves are preferable.
茶葉からの抽出は、抽出溶媒として水を使用し、攪拌抽出等により行われる。抽出の際、水にあらかじめアスコルビン酸等の有機酸又はその塩(例えば、アスコルビン酸ナトリウム)を添加してもよい。また、煮沸脱気や窒素ガス等の不活性ガスの通気により、溶存酸素を除去しつつ、いわゆる非酸化的雰囲気下で抽出する方法を併用してもよい。このようにして得られた抽出液を、乾燥、濃縮して本発明に使用する茶抽出物を得る。茶抽出物の形態としては、液体、スラリー、半固体、固体の状態が挙げられる。 Extraction from tea leaves is performed by stirring extraction or the like using water as an extraction solvent. At the time of extraction, an organic acid such as ascorbic acid or a salt thereof (for example, sodium ascorbate) may be added to water in advance. Moreover, you may use together the method of extracting in what is called a non-oxidative atmosphere, removing dissolved oxygen by ventilation | gas_flowing of boil deaeration or inert gas, such as nitrogen gas. The extract thus obtained is dried and concentrated to obtain a tea extract used in the present invention. Examples of the tea extract include liquid, slurry, semi-solid, and solid state.
また、緑茶抽出物としては、超臨界状態の二酸化炭素接触処理を施した茶葉を用いて抽出した抽出物を用いてもよい。 Moreover, as a green tea extract, you may use the extract extracted using the tea leaf which gave the carbon dioxide contact process of the supercritical state.
本発明に使用する緑茶抽出物としては、緑茶抽出物の濃縮物又は緑茶抽出物の精製物が好ましい。ここで、緑茶抽出物の濃縮物とは、茶葉から熱水又は水溶性有機溶媒により抽出された抽出物を単に濃縮したものであり、例えば、特開昭59−219384号公報、特開平4−20589号公報、特開平5−260907号公報、特開平5−306279号公報等に記載されている方法により調製したものをいう。また緑茶抽出物の濃縮物として、市販の東京フードテクノ社製「ポリフェノン」、伊藤園社製「テアフラン」、太陽化学社製「サンフェノン」等を用いることも可能である。更に、それらを原料として更に精製処理して緑茶抽出物の精製物としても良い。ここで、緑茶抽出物の精製物とは、緑茶抽出物又はその濃縮物を溶剤やカラムを用いて沈殿物を除去等したものをいう。 The green tea extract used in the present invention is preferably a concentrate of green tea extract or a purified product of green tea extract. Here, the concentrate of green tea extract is obtained by simply concentrating an extract extracted from tea leaves with hot water or a water-soluble organic solvent. For example, JP-A-59-219384 and JP-A-4- This refers to those prepared by the methods described in JP-A-20589, JP-A-5-260907, JP-A-5-306279, and the like. Further, as a concentrate of green tea extract, commercially available “Polyphenone” manufactured by Tokyo Food Techno Co., “Theafuran” manufactured by ITO EN Co., Ltd., “Sunphenon” manufactured by Taiyo Kagaku Co., Ltd., etc. can be used. Furthermore, it is good also as a refinement | purification of green tea extract by further refine | purifying them as a raw material. Here, the purified product of the green tea extract refers to a product obtained by removing a precipitate from the green tea extract or its concentrate using a solvent or a column.
本発明の容器詰飲料の非重合体カテキン類中のガレート体率は特に限定されないが、ガレート体率が50質量%未満である緑茶抽出物の精製物を配合することが好ましい。このような緑茶抽出物の精製物は、精製工程のいずれかの段階でタンナーゼ処理することにより非重合体カテキン類中のガレート体率を50質量%未満に調整したものが好ましい。
非重合体カテキン類中のカテキンガレート体率の上限値は50質量%(未満)であるのが好ましく、更に、49質量%、48質量%、45質量%、44質量%、40質量%、39質量%、30質量%、特に20質量%が苦味抑制の点から好ましい。他方、下限値は、0質量%、0.1質量%、1質量%、2質量%、3質量%、更に4質量%、特に5質量%であるのが、非重合体カテキン類の生理効果の有効性及び苦味低減の点で好ましい。
Although the gallate body rate in the non-polymer catechins of the packaged beverage of the present invention is not particularly limited, it is preferable to blend a purified product of green tea extract having a gallate body rate of less than 50% by mass. Such a purified product of green tea extract is preferably one in which the gallate content in the non-polymer catechins is adjusted to less than 50 mass% by performing tannase treatment at any stage of the purification process.
The upper limit of the catechin gallate content in non-polymer catechins is preferably 50% by mass (less than), and 49% by mass, 48% by mass, 45% by mass, 44% by mass, 40% by mass, 39%. From the viewpoint of bitterness suppression, it is preferable that the content is 30% by mass, 30% by mass, particularly 20% by mass. On the other hand, the lower limit is 0% by mass, 0.1% by mass, 1% by mass, 2% by mass, 3% by mass, further 4% by mass, especially 5% by mass, and physiological effects of non-polymer catechins. It is preferable in terms of the effectiveness and the bitterness reduction.
前記の緑茶抽出物、その濃縮物又は精製物をタンナーゼ処理することにより、非重合体カテキン類中のガレート体率を低下させることができる。ここで使用するタンナーゼは、一般に市販されている500〜5,000U/gの酵素活性を有することが好ましく、500U/g以上であると充分な活性を得ることができる。また、5,000U/g以上であると酵素反応速度が速すぎる為、反応系を制御することが困難となる。
タンナーゼとしては、タンニンアシルヒドラーゼEC3.1.1.20が好適である。市販品としては、商品名「タンナーゼ」キッコーマン(株)製及びタンナーゼ「三共」三共(株)製などが挙げられる。
By subjecting the green tea extract, its concentrate or purified product to tannase treatment, the gallate content in non-polymer catechins can be reduced. The tannase used here preferably has a commercially available enzyme activity of 500 to 5,000 U / g, and if it is 500 U / g or more, sufficient activity can be obtained. Moreover, since the enzyme reaction rate is too high when it is 5,000 U / g or more, it becomes difficult to control the reaction system.
As the tannase, tannin acyl hydrolase EC 3.1.1.20 is preferred. As a commercial item, brand name "Tannase" product made by Kikkoman Co., Ltd., tannase "Sankyo" product made by Sankyo Co., Ltd., etc. are mentioned.
タンナーゼ処理の具体的な手法としては、例えば、非重合体カテキン類中のガレート体率の低減効果、及び最適な非重合体カテキン類中のガレート体率で酵素反応を停止する観点から、緑茶抽出物の水溶液に、緑茶抽出物中の非重合体カテキン類に対してタンナーゼを0.5〜10質量%の範囲になるように添加することが好ましく、更に好ましくは0.5〜5質量%、特に2〜4質量%添加することが好ましい。
タンナーゼ処理の温度は、最適な酵素活性が得られる15〜40℃が好ましく、更に好ましくは20〜30℃である。
Specific methods for tannase treatment include, for example, green tea extraction from the viewpoint of reducing the gallate content in non-polymer catechins and stopping the enzyme reaction at the optimal gallate content in non-polymer catechins. It is preferable to add tannase to the aqueous solution of the product in a range of 0.5 to 10% by mass with respect to the non-polymer catechins in the green tea extract, more preferably 0.5 to 5% by mass, It is particularly preferable to add 2 to 4% by mass.
The temperature of the tannase treatment is preferably 15 to 40 ° C., more preferably 20 to 30 ° C. at which the optimum enzyme activity can be obtained.
タンナーゼ反応を終了させるには、酵素活性を失活させる必要がある。酵素失活の温度は、70〜90℃が好ましい。又、所定の失活温度に到達してから10秒以上20分以下の保持時間であると好ましい。酵素反応の失活方法は、バッチ式もしくはプレート型熱交換機のような連続式で加熱を行うことで停止することができる。又、タンナーゼ処理の失活終了後、遠心分離などの操作により緑茶抽出物の水溶液を清浄化することができる。 In order to terminate the tannase reaction, it is necessary to deactivate the enzyme activity. The enzyme deactivation temperature is preferably 70 to 90 ° C. Further, it is preferable that the holding time is 10 seconds or more and 20 minutes or less after reaching a predetermined deactivation temperature. The deactivation method of the enzyme reaction can be stopped by heating in a batch system or a continuous system such as a plate heat exchanger. Further, after the inactivation of the tannase treatment, the aqueous solution of the green tea extract can be cleaned by an operation such as centrifugation.
また、本発明に用いる緑茶抽出物の精製処理は、タンナーゼ処理の前又は後に、以下の精製処理をしたものが、風味、安定性等の点から好ましい。具体的な精製処理手段としては、(1)合成吸着剤処理、(2)有機溶媒と水との混合液による抽出、(3)活性炭処理、(4)活性白土及び/又は酸性白土処理、(5)固液分離等の操作を単独で又は組み合せた手段が挙げられる。 Moreover, as for the purification process of the green tea extract used for this invention, what performed the following purification processes before or after a tannase process is preferable from points, such as flavor and stability. Specific purification treatment means include (1) synthetic adsorbent treatment, (2) extraction with a mixture of an organic solvent and water, (3) activated carbon treatment, (4) activated clay and / or acidic clay treatment, ( 5) Means including operations such as solid-liquid separation alone or in combination.
合成吸着剤処理としては、緑茶抽出物を合成吸着剤に吸着させ、次いで非重合体カテキン類を溶出させる方法が挙げられる。より具体的には、緑茶抽出物を合成吸着剤に吸着させ、合成吸着剤を洗浄し、次いで塩基性水溶液を接触させて非重合体カテキン類を溶出させる。当該合成吸着剤処理により、カフェイン及び没食子酸が低減できる。用いる合成吸着剤としては、スチレン−ジビニルベンゼン、修飾スチレン−ジビニルベンゼン又はメタクリル酸メチルを母体とするものが挙げられる。スチレン−ジビニルベンゼン系の合成吸着剤の例としては、ダイヤイオンHP−20、HP−21、セパビーズSP70、SP700、SP825、SP−825(三菱化学社製)やアンバーライトXAD4、XAD16HP、XAD1180、XAD2000(オルガノ社製)、デュオライトS874、S876(住友化学社製)等が挙げられる。臭素原子を核置換して吸着力を強めた修飾スチレン−ジビニルベンゼン系の合成吸着剤の例としては、セパビーズSP205、SP206、SP207(三菱化学社製)等が挙げられる。メタクリル酸メチル系の合成吸着剤の例としては、セパビーズHP1MG、HP2MG(三菱化学社製)やXAD7HP(オルガノ社製)、デュオライトS877(住友化学社製)等が挙げられる。
合成吸着剤としては具体的には、SP207などの修飾ポリスチレン系合成吸着剤(三菱化学社製)、HP2MGなどのメタクリル系合成吸着剤(三菱化学社製)が挙げられるが、特に、SP207が好ましい。
Examples of the synthetic adsorbent treatment include a method in which a green tea extract is adsorbed on a synthetic adsorbent and then non-polymer catechins are eluted. More specifically, the green tea extract is adsorbed on a synthetic adsorbent, the synthetic adsorbent is washed, and then a basic aqueous solution is contacted to elute non-polymer catechins. Caffeine and gallic acid can be reduced by the synthetic adsorbent treatment. Examples of the synthetic adsorbent used include those based on styrene-divinylbenzene, modified styrene-divinylbenzene, or methyl methacrylate. Examples of synthetic adsorbents based on styrene-divinylbenzene include Diaion HP-20, HP-21, Sepa beads SP70, SP700, SP825, SP-825 (manufactured by Mitsubishi Chemical Corporation), Amberlite XAD4, XAD16HP, XAD1180, XAD2000 (Manufactured by Organo), duolite S874, S876 (manufactured by Sumitomo Chemical Co., Ltd.), and the like. Examples of the modified styrene-divinylbenzene-based synthetic adsorbent in which the bromine atom is replaced with a nucleus to enhance the adsorptive power include Sepabeads SP205, SP206, SP207 (manufactured by Mitsubishi Chemical Corporation). Examples of methyl methacrylate-based synthetic adsorbents include Sepabeads HP1MG, HP2MG (manufactured by Mitsubishi Chemical), XAD7HP (manufactured by Organo), Duolite S877 (manufactured by Sumitomo Chemical), and the like.
Specific examples of the synthetic adsorbent include a modified polystyrene synthetic adsorbent such as SP207 (manufactured by Mitsubishi Chemical Corporation) and a methacrylic synthetic adsorbent such as HP2MG (manufactured by Mitsubishi Chemical Corporation). SP207 is particularly preferable. .
合成吸着剤が充填されたカラムに対し、予めSV(空間速度)=1〜10[h-1]、合成吸着剤に対する通液倍数として2〜10[v/v]の通液条件で95vol%エタノール水溶液による洗浄処理を行い、合成吸着剤中の原料モノマーや原料モノマー由来の不純物等を除去するのが好ましい。そして、その後SV=1〜10[h-1]、合成吸着剤に対する通液倍数として1〜10[v/v]の通液条件により水洗を行い、エタノールを除去してカラム内の溶媒を水系に置換すると非重合体カテキン類の吸着能が向上する。 With respect to the column packed with the synthetic adsorbent, SV (space velocity) = 1 to 10 [h −1 ] in advance, and 95 vol% under the liquid passing condition of 2 to 10 [v / v] as the liquid passing ratio with respect to the synthetic adsorbent. It is preferable to perform a washing treatment with an aqueous ethanol solution to remove the raw material monomer in the synthetic adsorbent, impurities derived from the raw material monomer, and the like. Then, after washing with water under conditions of SV = 1 to 10 [h −1 ] and a passage ratio of 1 to 10 [v / v] as a passage ratio for the synthetic adsorbent, ethanol is removed and the solvent in the column is changed to an aqueous system. When substituted, the adsorbability of non-polymer catechins is improved.
緑茶抽出物を合成吸着剤に吸着させる手段としては、合成吸着剤が充填されたカラムに緑茶抽出物水溶液を通液するのが好ましい。緑茶抽出物を合成吸着剤を充填したカラムに通液する条件としては、SV(空間速度)=0.5〜10[h-1]の通液速度、合成吸着剤に対する通液倍数0.5〜20[v/v]が好ましい。10[h-1]以上の通液速度や20[v/v]以上の通液量であると非重合体カテキン類の吸着が不十分となる。
更に、緑茶抽出物を合成吸着剤に吸着させた後に水洗浄を行うが、SV=0.5〜10[h-1]の通液速度、合成吸着剤に対する通液倍数として1〜10[v/v]の通液条件で、合成吸着剤に付着した没食子酸や不純物を除去するのが好ましい。10[h-1]以上の通液速度や10[v/v]以上の通液量で水洗浄すると非重合体カテキン類が溶出する場合があり、1[v/v]以下の通液量であると没食子酸の除去が不充分である。
As a means for adsorbing the green tea extract onto the synthetic adsorbent, it is preferable to pass the green tea extract aqueous solution through a column packed with the synthetic adsorbent. The conditions for passing the green tea extract through the column filled with the synthetic adsorbent are: SV (space velocity) = 0.5 to 10 [h −1 ], liquid passing rate with respect to the synthetic adsorbent: 0.5 -20 [v / v] is preferable. Adsorption of non-polymer catechins becomes insufficient when the flow rate is 10 [h -1 ] or more and the flow rate is 20 [v / v] or more.
Further, the green tea extract is adsorbed on the synthetic adsorbent and then washed with water. The liquid passing speed is SV = 0.5 to 10 [h −1 ], and the liquid passing rate for the synthetic adsorbent is 1 to 10 [v. / V], it is preferable to remove gallic acid and impurities adhering to the synthetic adsorbent. Non-polymer catechins may be eluted when washed with water at a flow rate of 10 [h -1 ] or higher or a flow rate of 10 [v / v] or higher, and a flow rate of 1 [v / v] or lower. If it is, the removal of gallic acid is insufficient.
非重合体カテキン類の溶出に用いる塩基性水溶液としては、例えば水酸化ナトリウム水溶液、炭酸ナトリウム水溶液等を好適に用いることができる。また、アルカリ性水溶液のpHは7〜14の範囲が好ましい。pH7〜14のナトリウム系水溶液としては、4%以下の水酸化ナトリウム水溶液、1N−炭酸ナトリウム水溶液等が挙げられる。 As the basic aqueous solution used for elution of non-polymer catechins, for example, a sodium hydroxide aqueous solution, a sodium carbonate aqueous solution and the like can be suitably used. The pH of the alkaline aqueous solution is preferably in the range of 7-14. Examples of the sodium-based aqueous solution having a pH of 7 to 14 include a 4% or less sodium hydroxide aqueous solution and a 1N-sodium carbonate aqueous solution.
溶出工程においては、溶出水として互いにpHが異なる2種以上の水溶液を用い、これら溶出水をpHが低い順に合成吸着剤に接触させることができる。このように溶出水としてpHが異なる2種以上の溶出水を用いる例としては、pH3〜7の溶出水により溶出させた後に、pH9〜11の塩基性水溶液により溶出させる例が挙げられる。 In the elution step, two or more kinds of aqueous solutions having different pH values are used as the elution water, and these elution waters can be brought into contact with the synthetic adsorbent in the order of lower pH. Examples of using two or more kinds of elution water having different pH as the elution water include elution with a basic aqueous solution of pH 9-11 after elution with elution water of pH 3-7.
本発明で使用される合成吸着剤は精製処理後に所定の方法を用いることにより再使用できる。具体的には、水酸化ナトリウムのようなアルカリ水溶液を通液・洗浄し、合成吸着剤上に残存する水溶性成分をすべて脱着させる。 The synthetic adsorbent used in the present invention can be reused by using a predetermined method after the purification treatment. Specifically, an aqueous alkali solution such as sodium hydroxide is passed through and washed to desorb all water-soluble components remaining on the synthetic adsorbent.
非重合体カテキン類の溶出液は、塩基性水溶液で溶出したため、非重合体カテキン類の安定化の観点から中和することが好ましい。中和方法として、アルカリ金属イオンの除去できるカチオン交換樹脂、特にH型のカチオン交換樹脂を用いるのが好ましい。カチオン交換樹脂としては、具体的には、アンバーライト200CT、IR120B、IR124、IR118(住友化学社製)、ダイヤイオンSK1B、SK102、PK208、PK212(三菱化学社製)等を用いることができる。 Since the eluate of non-polymer catechins is eluted with a basic aqueous solution, it is preferably neutralized from the viewpoint of stabilizing the non-polymer catechins. As a neutralization method, it is preferable to use a cation exchange resin capable of removing alkali metal ions, particularly an H-type cation exchange resin. Specifically, Amberlite 200CT, IR120B, IR124, IR118 (manufactured by Sumitomo Chemical Co., Ltd.), Diaion SK1B, SK102, PK208, PK212 (manufactured by Mitsubishi Chemical Corporation), etc. can be used as the cation exchange resin.
上記の精製処理のうち、(2)有機溶媒と水との混合液による抽出と(3)活性炭処理、又は(2)有機溶媒と水との混合液による抽出と(4)活性白土及び/又は酸性白土処理は組み合せて行うのが好ましい。更に、(2)有機溶媒と水の混合液による抽出、(3)活性炭処理及び(4)活性白土及び/及び酸性白土処理を組み合せるのが特に好ましい。 Among the above purification treatments, (2) extraction with a mixture of an organic solvent and water and (3) activated carbon treatment, or (2) extraction with a mixture of an organic solvent and water, and (4) activated clay and / or The acid clay treatment is preferably performed in combination. Further, it is particularly preferable to combine (2) extraction with a mixture of an organic solvent and water, (3) activated carbon treatment, and (4) activated clay and / or acidic clay treatment.
有機溶媒と水の混合液で抽出するためには、緑茶抽出物を有機溶媒と水の混合溶液中に分散する。この分散液中の有機溶媒と水との含有質量比は、最終的に60/40〜97/3、より好ましくは、(i)茶葉由来の水不溶性成分、たとえば、セルロース類等を除去する場合には、60/40〜75/25で処理する。又(ii)茶葉由来のフレーバー成分を除去する場合には、85/15〜95/5とするのが、非重合体カテキン類の抽出効率、及び長期間の飲用性等の点で好ましい。 In order to extract with a mixed solution of an organic solvent and water, the green tea extract is dispersed in a mixed solution of the organic solvent and water. The mass ratio of the organic solvent and water in this dispersion is finally 60/40 to 97/3, more preferably (i) when removing water-insoluble components derived from tea leaves, such as celluloses Is processed at 60/40 to 75/25. Moreover, when removing the flavor component derived from (ii) tea leaves, it is preferable to use 85/15 to 95/5 in terms of extraction efficiency of non-polymer catechins and long-term drinking properties.
有機溶媒としては、エタノール、メタノール等のアルコール類、アセトン等のケトン類、酢酸エチル等のエステル類が挙げられる。これらのうち、メタノール、エタノール等のアルコール類、アセトン等のケトン類の親水性有機溶媒が好ましく、特に食品への使用を考慮すると、アルコール類、特にエタノールが好ましい。水として、イオン交換水、水道水、天然水等が挙げられる。この有機溶媒と水は、両者を混合してから緑茶抽出物と混合するか又はそれぞれ別々に精密ろ過された緑茶抽出物と混合してもよいが、混合溶液としてから緑茶抽出物と混合処理するのが好ましい。 Examples of the organic solvent include alcohols such as ethanol and methanol, ketones such as acetone, and esters such as ethyl acetate. Of these, hydrophilic organic solvents such as alcohols such as methanol and ethanol, and ketones such as acetone are preferable, and alcohols, particularly ethanol, are particularly preferable in consideration of use in foods. Examples of water include ion exchange water, tap water, and natural water. The organic solvent and water may be mixed with the green tea extract after mixing them together, or may be mixed with the green tea extract that has been microfiltered separately. Is preferred.
有機溶媒と水の混合溶液100質量部に対して、緑茶抽出物(乾燥質量換算)を10〜40質量部、更に10〜30質量部、特に15〜30質量部添加して処理するのが、緑茶抽出物を効率よく処理できるので好ましい。 10 to 40 parts by weight, further 10 to 30 parts by weight, especially 15 to 30 parts by weight of green tea extract (dry weight conversion) is added to 100 parts by weight of a mixed solution of an organic solvent and water. It is preferable because the green tea extract can be processed efficiently.
有機溶媒と水の混合溶液の添加終了後は10〜180分程度の熟成時間を設けると更に好ましい。
これらの処理は、10〜60℃で行うことができ、更に10〜50℃、特に10〜40℃で行うのが好ましい。
It is more preferable to provide an aging time of about 10 to 180 minutes after the addition of the mixed solution of the organic solvent and water.
These treatments can be performed at 10 to 60 ° C., more preferably 10 to 50 ° C., particularly preferably 10 to 40 ° C.
活性炭処理に用いる活性炭としては、一般に工業レベルで使用されているものであれば特に制限されず、例えば、ZN−50(北越炭素社製)、クラレコールGLC、クラレコールPK−D、クラレコールPW−D(クラレケミカル社製)、白鷲AW50、白鷲A、白鷲M、白鷲C(武田薬品工業社製)等の市販品を用いることができる。
活性炭の細孔容積は0.01〜0.8mL/g、特に0.1〜0.8mL/gが好ましい。また、比表面積は800〜1600m2/g、特に900〜1500m2/gの範囲のものが好ましい。なお、これらの物性値は窒素吸着法に基づく値である。
The activated carbon used for the activated carbon treatment is not particularly limited as long as it is generally used at an industrial level. For example, ZN-50 (made by Hokuetsu Carbon Co., Ltd.), Kuraray Coal GLC, Kuraray Coal PK-D, Kuraray Coal PW Commercially available products such as -D (manufactured by Kuraray Chemical Co., Ltd.), white birch AW50, white birch A, white birch M, white birch C (manufactured by Takeda Pharmaceutical Company Limited) can be used.
The pore volume of the activated carbon is preferably 0.01 to 0.8 mL / g, particularly preferably 0.1 to 0.8 mL / g. The specific surface area is preferably in the range of 800 to 1600 m 2 / g, particularly 900 to 1500 m 2 / g. These physical property values are values based on the nitrogen adsorption method.
活性炭処理は、緑茶抽出物を前記有機溶媒と水との混合溶液に添加した後に行うのが好ましい。活性炭は、有機溶媒と水の混合溶液100質量部に対して0.5〜8質量部、特に0.5〜3質量部添加するのが、精製効果、ろ過工程におけるケーク抵抗が小さい点で好ましい。 The activated carbon treatment is preferably performed after the green tea extract is added to the mixed solution of the organic solvent and water. Activated carbon is preferably added in an amount of 0.5 to 8 parts by mass, particularly 0.5 to 3 parts by mass, with respect to 100 parts by mass of a mixed solution of an organic solvent and water, in terms of purification effect and small cake resistance in the filtration step. .
酸性白土又は活性白土は、ともに一般的な化学成分として、SiO2、Al2O3、Fe2O3、CaO、MgO等を含有するものであるが、SiO2/Al2O3比が3〜12、特に4〜9であるのが好ましい。またFe2O3を2〜5質量%、CaOを0〜1.5質量%、MgOを1〜7質量%含有する組成のものが好ましい。
活性白土は天然に産出する酸性白土(モンモリロナイト系粘土)を硫酸等の鉱酸で処理したものであり、大きい比表面積と吸着能を有する多孔質構造をもった化合物である。
Both acidic clay and activated clay contain SiO 2 , Al 2 O 3 , Fe 2 O 3 , CaO, MgO, etc. as general chemical components, but the SiO 2 / Al 2 O 3 ratio is 3 It is preferably -12, particularly 4-9. The Fe 2 O 3 2 to 5 wt%, the CaO 0 to 1.5 wt%, preferably from compositions containing MgO 1 to 7% by weight.
Activated clay is a naturally occurring acidic clay (montmorillonite clay) treated with a mineral acid such as sulfuric acid, and is a compound having a porous structure having a large specific surface area and adsorption capacity.
酸性白土又は活性白土の比表面積は、酸処理の程度等により異なるが、50〜350m2/gであるのが好ましく、pH(5質量%サスペンジョン)は2.5〜8、特に3.6〜7のものが好ましい。例えば、酸性白土としては、ミズカエース#600(水澤化学社製)等の市販品を用いることができる。 The specific surface area of the acid clay or activated clay varies depending on the degree of acid treatment, etc., but is preferably 50 to 350 m 2 / g, and the pH (5 mass% suspension) is 2.5 to 8, particularly 3.6 to 7 is preferred. For example, as the acid clay, commercially available products such as Mizuka Ace # 600 (manufactured by Mizusawa Chemical Co., Ltd.) can be used.
また、活性炭と酸性白土又は活性白土を併用する場合の割合は、質量比で活性炭1に対して1〜10がよく、活性炭:酸性白土又は活性白土=1:1〜1:6であるのが好ましい。 Moreover, the ratio in the case of using together activated carbon and acidic clay or activated clay is 1-10 with respect to activated carbon 1 by mass ratio, and activated carbon: acid clay or activated clay = 1: 1 to 1: 6. preferable.
得られた緑茶抽出物の精製物は、製品の安定性向上のため、必要に応じて除濁することが好ましい。除濁の具体的な操作としては、ろ過及び/又は遠心分離処理により固形分と水溶性部分とを固液分離することが挙げられる。 It is preferable that the purified product of the obtained green tea extract is turbidized as necessary to improve the stability of the product. Specific operation of turbidity includes solid-liquid separation of solid content and water-soluble part by filtration and / or centrifugation.
固液分離をろ過で行う場合は、ろ過条件としては、温度が5〜70℃、更に10〜40℃であるのが好ましい。圧力は、使用する膜モジュールの耐圧範囲であることが望ましい。例えば、30〜400kPa、更に50〜400kPa、特に50〜350kPaであるのが好ましい。膜孔径は、所定の濁度になるという点から、1〜30μmが好ましく、更に2〜25μm、特に2〜20μmであるのが好ましい。膜孔径の測定方法は、水銀圧入法、バブルポイント試験、細菌ろ過法などを用いた一般的な測定方法が挙げられるが、バブルポイント試験で求めた値を用いるのが好ましい。 When solid-liquid separation is performed by filtration, the filtration conditions are preferably a temperature of 5 to 70 ° C, and more preferably 10 to 40 ° C. The pressure is preferably within the pressure resistance range of the membrane module to be used. For example, it is preferably 30 to 400 kPa, more preferably 50 to 400 kPa, and particularly preferably 50 to 350 kPa. The membrane pore diameter is preferably from 1 to 30 μm, more preferably from 2 to 25 μm, particularly preferably from 2 to 20 μm, from the viewpoint of achieving a predetermined turbidity. Examples of the method for measuring the membrane pore diameter include general measurement methods using a mercury intrusion method, a bubble point test, a bacterial filtration method, and the like, but it is preferable to use a value obtained by a bubble point test.
また、遠心分離機は、分離板型、円筒型、デカンター型などの一般的な機器が好ましい。遠心分離条件としては、温度が5〜70℃、更に10〜40℃であるのが好ましく、回転数と時間は、所定の濁度になるように調整された条件であることが望ましい。例えば分離板型の場合、3000〜10000r/min、更に5000〜10000r/min、特に6000〜10000r/minで、0.2〜30分、更に0.2〜20分、特に0.2〜15分であるのが好ましい。 The centrifuge is preferably a general device such as a separation plate type, a cylindrical type, or a decanter type. As the centrifugation conditions, the temperature is preferably 5 to 70 ° C., more preferably 10 to 40 ° C., and the rotation speed and time are preferably adjusted so as to have a predetermined turbidity. For example, in the case of a separator plate type, it is 3000 to 10000 r / min, further 5000 to 10000 r / min, particularly 6000 to 10000 r / min, 0.2 to 30 minutes, further 0.2 to 20 minutes, particularly 0.2 to 15 minutes. Is preferred.
固液分離は膜ろ過が好ましい。膜ろ過で使用する高分子膜は、炭化水素系、フッ素化炭化水素系又はスルホン系高分子膜であって、例えばポリエチレン、ポリプロピレン等のポリオレフィン系高分子膜;ポリテトラフルオロエチレン(PTFE)、ポリビニリデンジフルオライド(PVDF)等のフッ素化ポリオレフィン系高分子膜;ポリスルフォン(PSU)、ポリエーテルスルフォン(PES)等のスルホン系高分子膜等が挙げられる。高分子膜の膜孔径は、0.05〜0.8μmであるが、更に0.05〜0.5μm、特に0.08〜0.5μmであるのが好ましい。膜孔径が小さすぎる場合には、著しくろ過速度が低下し、一方、大きすぎる場合には、分離できず、色調が悪化する。また、膜厚としては、0.1〜2.5mm、更に0.3〜2.0mm、特に0.3〜1.5mmであるのが好ましい。 The solid-liquid separation is preferably membrane filtration. The polymer membrane used in the membrane filtration is a hydrocarbon-based, fluorinated hydrocarbon-based or sulfone-based polymer membrane, for example, a polyolefin-based polymer membrane such as polyethylene or polypropylene; polytetrafluoroethylene (PTFE), poly Examples include fluorinated polyolefin polymer membranes such as vinylidene difluoride (PVDF); sulfone polymer membranes such as polysulfone (PSU) and polyethersulfone (PES). The pore size of the polymer membrane is 0.05 to 0.8 μm, more preferably 0.05 to 0.5 μm, and particularly preferably 0.08 to 0.5 μm. When the membrane pore size is too small, the filtration rate is remarkably reduced. On the other hand, when the membrane pore size is too large, separation is impossible and the color tone deteriorates. The film thickness is preferably 0.1 to 2.5 mm, more preferably 0.3 to 2.0 mm, and particularly preferably 0.3 to 1.5 mm.
本発明に用いる緑茶抽出物は、その固形分中に、非重合体カテキン類を25〜95質量%、更に40〜90質量%、更に50〜88質量%、特に60〜85質量%含有するものが好ましい。
本発明の容器詰飲料の濁度は、好ましくは0.1〜80、より好ましくは0.5〜80、更に好ましくは1〜75、更に好ましくは1〜70の範囲である。ただし、濁度は0〜100の範囲で、イオン交換水を0とする。容器詰飲料の濁度が上記範囲にある場合、成分が均一に分散して存在していることを示し、光照射による色調安定性に優れる。なお、濁度は、村上色彩技術研究所製のヘイズ・透過率計(型式HR−100)を用い、ガラスセル(光路長10mm 横35mm 縦40mm)に容器詰飲料を入れてヘイズ値(H)を25℃で測定したものである。
The green tea extract used in the present invention contains 25 to 95 mass%, further 40 to 90 mass%, further 50 to 88 mass%, particularly 60 to 85 mass% of non-polymer catechins in the solid content. Is preferred.
The turbidity of the packaged beverage of the present invention is preferably in the range of 0.1 to 80, more preferably 0.5 to 80, still more preferably 1 to 75, and still more preferably 1 to 70. However, the turbidity is in the range of 0 to 100, and the ion exchange water is 0. When the turbidity of the packaged beverage is in the above range, it indicates that the components are uniformly dispersed and is excellent in color tone stability by light irradiation. The turbidity is determined by using a haze / transmittance meter (model HR-100) manufactured by Murakami Color Research Laboratory, putting a packaged beverage in a glass cell (optical path length 10 mm, width 35 mm, length 40 mm) and haze value (H). Was measured at 25 ° C.
本発明に用いられる緑茶抽出物中のカフェイン濃度は、非重合体カテキン類に対して、カフェイン/非重合体カテキン類(質量比)=0〜0.1、更に0.005〜0.08、特に0.01〜0.04であるのが好ましい。 The caffeine concentration in the green tea extract used in the present invention is caffeine / non-polymer catechins (mass ratio) = 0 to 0.1, and further 0.005 to 0.00. It is preferably 08, particularly 0.01 to 0.04.
非重合体カテキン類の測定
非重合体カテキン類含有組成物を蒸留水で希釈し、フィルター(0.8μm)でろ過後、島津製作所社製、高速液体クロマトグラフ(型式SCL−10AVP)を用い、オクタデシル基導入液体クロマトグラフ用パックドカラム L−カラムTM ODS(4.6mmφ×250mm:財団法人 化学物質評価研究機構製)を装着し、カラム温度35℃で、A液及びB液を用いたグラジエント法によって行った。移動相A液は酢酸を0.1mol/L含有の蒸留水溶液、B液は酢酸を0.1mol/L含有のアセトニトリル溶液とし、試料注入量は20μL、UV検出器波長は280nmの条件で行った。
Measurement of non-polymer catechins After diluting a non-polymer catechin-containing composition with distilled water and filtering with a filter (0.8 μm), a Shimadzu Corporation high-performance liquid chromatograph (model SCL-10AVP) was used. Packed column for octadecyl group-introduced liquid chromatograph L-column TM ODS (4.6 mmφ × 250 mm: manufactured by Chemicals Evaluation and Research Institute), gradient method using liquid A and liquid B at a column temperature of 35 ° C. Went by. The mobile phase A solution was a distilled aqueous solution containing 0.1 mol / L of acetic acid, the B solution was an acetonitrile solution containing 0.1 mol / L of acetic acid, the sample injection amount was 20 μL, and the UV detector wavelength was 280 nm. .
没食子酸の測定
非重合体カテキン類と同様の手法で、高速液体クロマトグラフ(型式 島津LC-VPシリーズ)を用いて行った。
Measurement of gallic acid A high performance liquid chromatograph (model Shimadzu LC-VP series) was used in the same manner as non-polymer catechins.
苦み・渋み評価方法
市販飲料のなかで、スポーツドリンク類を飲用するユーザーを対象に、一回に一品ずつ飲用する官能評価試験を行った(10名)。比較例2((B)成分無添加品)を基準として、下記の基準で評価した。
5;比較例2より苦みや渋みが増した。
4;比較例2より苦みや渋みがやや増した。
3;比較例2と苦みや渋みが同等。
2;比較例2より苦みや渋みがやや弱くなった。
1;比較例2より苦みや渋みが弱くなった。
Bitterness / Astringency Evaluation Method Among commercially available beverages, a sensory evaluation test was conducted (10 persons) to drink one item at a time for users who drink sports drinks. Based on Comparative Example 2 ((B) component-free product), the following criteria were used for evaluation.
5: Bitterness and astringency increased from Comparative Example 2.
4: Bitterness and astringency increased slightly from Comparative Example 2.
3; Bitterness and astringency are equivalent to Comparative Example 2.
2; Bitterness and astringency became slightly weaker than Comparative Example 2.
1; Bitterness and astringency were weaker than Comparative Example 2.
(1)カテキン製剤水溶液(a)
非重合体カテキン類含量が30質量%の緑茶抽出物にタンナーゼ処理(タンナーゼ濃度2質量%;反応温度20℃)を行い、スプレードライ法により噴霧乾燥させた。得られたパウダーをエタノールと水の混合溶媒(水:エタノール=15:85)で非重合体カテキン類を抽出した後に混合液に対して8質量部の活性炭を添加して精製を行って、カテキン製剤水溶液(a)を得た。得られたカテキン製剤(緑茶抽出物の精製物)の非重合体カテキン類中のガレート体率は44質量%であった。固形分中の非重合体カテキン類濃度は71質量%であった。固形分は23.2質量%であった。固形分中の没食子酸濃度は3.1質量%であった。
(1) Catechin preparation aqueous solution (a)
The green tea extract having a non-polymer catechin content of 30% by mass was subjected to tannase treatment (tannase concentration 2% by mass; reaction temperature 20 ° C.) and spray-dried by a spray drying method. The obtained powder was extracted with non-polymer catechins with a mixed solvent of ethanol and water (water: ethanol = 15: 85), and then purified by adding 8 parts by mass of activated carbon to the mixture. A pharmaceutical aqueous solution (a) was obtained. The percentage of gallate body in non-polymer catechins of the obtained catechin preparation (purified product of green tea extract) was 44% by mass. The concentration of non-polymer catechins in the solid content was 71% by mass. The solid content was 23.2% by mass. The gallic acid concentration in the solid content was 3.1% by mass.
(2)カテキン製剤水溶液(b)
非重合体カテキン類含量が30質量%の緑茶抽出物にタンナーゼ処理を行わず、スプレードライ法により噴霧乾燥させた。得られたパウダーをエタノールと水の混合溶媒(水:エタノール=15:85)で非重合体カテキン類を抽出した後に混合液に対して8質量部の活性炭を添加して精製を行ってカテキン製剤水溶液(b)を得た。得られたカテキン製剤(緑茶抽出物)の非重合体カテキン類中のガレート体率は54質量%であった。固形分中の非重合体カテキン類濃度は71質量%であった。固形分は23.2質量%であった。固形分中の没食子酸濃度は0.33質量%であった。
(2) Catechin preparation aqueous solution (b)
The green tea extract having a non-polymer catechin content of 30% by mass was not subjected to tannase treatment and spray-dried by a spray drying method. The obtained powder was extracted with a mixed solvent of ethanol and water (water: ethanol = 15: 85), and then purified by adding 8 parts by mass of activated carbon to the mixture to obtain a catechin preparation. An aqueous solution (b) was obtained. The gallate content in the non-polymer catechins of the obtained catechin preparation (green tea extract) was 54% by mass. The concentration of non-polymer catechins in the solid content was 71% by mass. The solid content was 23.2% by mass. The gallic acid concentration in the solid content was 0.33% by mass.
実施例1〜7及び比較例1、2
表1記載の処方で、酸性飲料(pH3.5、25℃)を製造した。飲料は、UHT殺菌装置により98℃30秒間殺菌し、透明PETボトルに充填した。
Examples 1 to 7 and Comparative Examples 1 and 2
An acidic beverage (pH 3.5, 25 ° C.) was produced according to the formulation shown in Table 1. The beverage was sterilized at 98 ° C. for 30 seconds using a UHT sterilizer and filled in a transparent PET bottle.
表1から明らかなように、ヘキサノール、cis−3−ヘキセノール、プロピオン酸、酢酸エチル、1−p−メンタン−8−チオール及び酪酸エチルから選ばれる1種以上を特定の範囲で含有することにより、苦みや渋みの感じ方が緩和されることが判明した。これに対し、これらの成分を含まない飲料においては、苦みや渋みの感じ方が強調されることがわかった。 As apparent from Table 1, by containing one or more selected from hexanol, cis-3-hexenol, propionic acid, ethyl acetate, 1-p-menthane-8-thiol and ethyl butyrate in a specific range, It has been found that the feeling of bitterness and astringency is alleviated. On the other hand, it was found that in beverages that do not contain these components, the feeling of bitterness and astringency is emphasized.
Claims (8)
次の成分(A)及び(B):
(A)非重合体カテキン類 0.03〜0.6質量%、
(B)ヘキサノール、cis−3−ヘキセノール、プロピオン酸、酢酸エチル、1−p−メンタン−8−チオール及び酪酸エチルよりなる群から選ばれる1種以上
を(B)/(A)(質量比)が0.0001〜5の範囲で含有する容器詰飲料。 It is a packaged beverage having a pH of 2 to 6 and containing a green tea extract,
The following components (A) and (B):
(A) Non-polymer catechins 0.03-0.6 mass%,
(B) One or more selected from the group consisting of hexanol, cis-3-hexenol, propionic acid, ethyl acetate, 1-p-menthane-8-thiol and ethyl butyrate (B) / (A) (mass ratio) Is contained in a range of 0.0001-5.
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JP2012130254A (en) * | 2010-12-20 | 2012-07-12 | Kao Corp | Packaged beverage |
JP2012139146A (en) * | 2010-12-28 | 2012-07-26 | Kao Corp | Packaged beverage |
JP2013009670A (en) * | 2011-05-31 | 2013-01-17 | Uha Mikakuto Co Ltd | Green tea beverage |
JP2013165690A (en) * | 2012-02-16 | 2013-08-29 | Kirin Holdings Co Ltd | Highly aromatic decaffeinated tea beverage |
JP2015006167A (en) * | 2013-05-28 | 2015-01-15 | 大正製薬株式会社 | Carbon acid beverage |
JP2015142563A (en) * | 2013-12-26 | 2015-08-06 | 花王株式会社 | Production method of catechin-including beverage |
JP2016104038A (en) * | 2016-03-03 | 2016-06-09 | キリンホールディングス株式会社 | Highly flavoring decaffeinated tea beverage |
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JP2005143467A (en) * | 2003-11-20 | 2005-06-09 | Kiyomitsu Kawasaki | Green tea flavored composition |
JP2006217815A (en) * | 2005-02-08 | 2006-08-24 | Kao Corp | Non-tea-based packaged beverage |
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JP2005143467A (en) * | 2003-11-20 | 2005-06-09 | Kiyomitsu Kawasaki | Green tea flavored composition |
JP2006217815A (en) * | 2005-02-08 | 2006-08-24 | Kao Corp | Non-tea-based packaged beverage |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
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JP2012130254A (en) * | 2010-12-20 | 2012-07-12 | Kao Corp | Packaged beverage |
JP2012139146A (en) * | 2010-12-28 | 2012-07-26 | Kao Corp | Packaged beverage |
JP2013009670A (en) * | 2011-05-31 | 2013-01-17 | Uha Mikakuto Co Ltd | Green tea beverage |
JP2013165690A (en) * | 2012-02-16 | 2013-08-29 | Kirin Holdings Co Ltd | Highly aromatic decaffeinated tea beverage |
JP2015006167A (en) * | 2013-05-28 | 2015-01-15 | 大正製薬株式会社 | Carbon acid beverage |
JP2015142563A (en) * | 2013-12-26 | 2015-08-06 | 花王株式会社 | Production method of catechin-including beverage |
JP2016104038A (en) * | 2016-03-03 | 2016-06-09 | キリンホールディングス株式会社 | Highly flavoring decaffeinated tea beverage |
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