JP2008530417A - 排出後処理装置及びアンチアイドル装置sofcapuのための燃料の改質と供給とを複合したシステムの機構及び方法 - Google Patents
排出後処理装置及びアンチアイドル装置sofcapuのための燃料の改質と供給とを複合したシステムの機構及び方法 Download PDFInfo
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- B01D53/34—Chemical or biological purification of waste gases
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- F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
- F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
- F01N3/0807—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by using absorbents or adsorbents
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
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- F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
- F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
- F01N3/10—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
- F01N3/18—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control
- F01N3/20—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control specially adapted for catalytic conversion ; Methods of operation or control of catalytic converters
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- F01N9/00—Electrical control of exhaust gas treating apparatus
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- H—ELECTRICITY
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- H01M8/0606—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants
- H01M8/0612—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants from carbon-containing material
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- F01N2240/00—Combination or association of two or more different exhaust treating devices, or of at least one such device with an auxiliary device, not covered by indexing codes F01N2230/00 or F01N2250/00, one of the devices being
- F01N2240/30—Combination or association of two or more different exhaust treating devices, or of at least one such device with an auxiliary device, not covered by indexing codes F01N2230/00 or F01N2250/00, one of the devices being a fuel reformer
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Abstract
Description
4NO+4NH3+O3 ⇔ 4N2+6H2O
等の接触反応を引き起こす。この反応の触媒は、NOxの他の種類をも還元するであろう。NOxは、それらに限定しないが、NO、NO2、N2O、及びN2O2である。SCR触媒の例は、例えば、Cu、Zn、V、Cr、Al、Ti、Mn、Co、Fe、Ni、Pd、Pt、Rh、Rd、Mo、及びW等の金属の酸化物を含む。アンモニアSCR触媒の他の例は、例えば、Cu、Co、Ag、Zn、あるいはPt等の金属イオンに置換されたZSM-5あるいはZSM-11等のゼオライト、及び活性炭を含む。好ましい触媒は、WO3、V2O5、及びMoO3の1つ以上を伴うTiO2の組合せであって、例えば、TiO2重量約70〜約95%、WO3、及び/又はMoO3重量約5〜20%、及びV2O3重量約0〜5%である。このタイプの触媒は、工業用に利用することができると共に、製造者によって特定目的に合わせて製造することができる。これらの触媒の特有の有用温度領域は、約230〜約500℃である。触媒温度が過剰に高い場合、アンモニアはNOxを還元する以前に分解する。
Claims (10)
- 駆動軸(13)を駆動して排気を発生するように構成された内燃機関(11)と、
排気からNOxを排出するNOx除去装置(14)と、
改質油を生成する燃料改質装置(16)と、
少なくとも一部の改質油を受け取ってそれを発電に利用する燃料電池(15)と、
を備える動力発生システム(10)であって、
前記システム(10)は一部の改質油を用いてNOx除去装置(14)を再生し、
前記システム(10)は、動力発生システム(10)がウォームアップ後安定して運転しているときはいつでも、燃料改質装置(16)が連続してNOx除去装置(14)を再生するのに十分な速度で運転されるように構成されることにより、システム(10)の定常運転中、燃料改質装置(16)は、前記機関(11)を停止することなく、NOx除去装置(14)の再生の間に停止しないことを特徴とする動力発生システム。 - 前記システム(10)は、改質油を機関(11)に供給しないことを特徴とする請求項1に記載の動力発生システム(10)。
- 前記システムは、改質油を燃料電池(15)に既定値で供給し、燃料電池(15)から供給される改質油の一部を再生への必要に応じて、燃料改質装置(16)の運転状況を有意に修正することなくNOx除去装置(14)に迂回させることを特徴とする請求項1に記載の動力発生システム(10)。
- 前記燃料改質装置(16)は、NOx除去装置(14)の再生期間とNOx除去装置(14)の非再生期間とで有意に変化しないように設計された環境に応じて運転することを特徴とする請求項1に記載の動力発生システム(10)。
- さらに駆動軸(13)を駆動する電動モータ(12)を含むことを特徴とする請求項1に記載の動力発生システム(10)。
- さらにバッテリ蓄積システム(20)を含み、前記動力発生システム(10)は、バッテリ蓄積システム(20)内のエネルギー蓄積を制限して電力を電動モータ(12)に供給することを特徴とする請求項5に記載の動力発生システム(10)。
- 前記システム(10)は、機関(11)なしで電力需要に対応することができる期間中、駆動軸(13)を連続して駆動するのと同時に、内燃機関(11)を自動的に停止することを特徴とする請求項5に記載の動力発生システム(10)。
- 前記システム(10)は、燃料改質装置(16)を始動及び停止するが、実質的に一定の給油速度で燃料改質装置(16)を運転することを特徴とする請求項1に記載の動力発生システム(10)。
- 請求項1に記載の動力発生システム(10)を備えてなる自動車。
- さらにアクセルペダルを含み、前記システム(10)は、運転者がアクセルペダルから足を離した時に自動的に機関(11)を停止することを特徴とする請求項9に記載の自動車。
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Application Number | Priority Date | Filing Date | Title |
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US11/052,647 | 2005-02-07 | ||
US11/052,647 US7213397B2 (en) | 2005-02-07 | 2005-02-07 | Mechanism and method of combined fuel reformer and dosing system for exhaust aftertreatment and anti-idle SOFC APU |
PCT/IB2006/000225 WO2006082512A2 (en) | 2005-02-07 | 2006-02-07 | Mechanism and method of combined fuel reformer and dosing system for exhaust aftertreatment and anti-idle sofc apu |
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JP2008530417A true JP2008530417A (ja) | 2008-08-07 |
JP5229610B2 JP5229610B2 (ja) | 2013-07-03 |
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EP (1) | EP1886371A2 (ja) |
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US20060048502A1 (en) * | 2004-07-29 | 2006-03-09 | Washington Kirk B | Integrated system for reducing fuel consumption and emissions in an internal combustion engine |
US8463529B2 (en) | 2004-09-17 | 2013-06-11 | Eaton Corporation | System and method of operating internal combustion engines at fuel rich low-temperature- combustion mode as an on-board reformer for solid oxide fuel cell-powered vehicles |
US7818959B2 (en) * | 2004-09-17 | 2010-10-26 | Eaton Corporation | Clean power system |
US7418816B2 (en) * | 2005-09-01 | 2008-09-02 | Ford Global Technologies, Llc | Exhaust gas aftertreatment systems |
WO2007081016A1 (ja) * | 2006-01-13 | 2007-07-19 | Matsushita Electric Industrial Co., Ltd. | 水素生成装置、燃料電池システム及びそれらの運転方法 |
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JP5229610B2 (ja) | 2013-07-03 |
US7213397B2 (en) | 2007-05-08 |
US20060174608A1 (en) | 2006-08-10 |
EP1886371A2 (en) | 2008-02-13 |
WO2006082512A2 (en) | 2006-08-10 |
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