JP2008500910A - Air inlet of composite structure of charcoal dissimilar materials for human-friendly housing - Google Patents

Air inlet of composite structure of charcoal dissimilar materials for human-friendly housing Download PDF

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JP2008500910A
JP2008500910A JP2007510625A JP2007510625A JP2008500910A JP 2008500910 A JP2008500910 A JP 2008500910A JP 2007510625 A JP2007510625 A JP 2007510625A JP 2007510625 A JP2007510625 A JP 2007510625A JP 2008500910 A JP2008500910 A JP 2008500910A
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ファヒョン リ
ユンミン チョ
ハンサン パック
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ザ インダストリー アンド アカデミック クーパレイション イン チュンナン ナショナル ユニバーシティー(アイエーシー)
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B9/00Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
    • B32B9/04Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B9/00Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
    • B32B9/04Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B9/042Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material of wood
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B21/00Layered products comprising a layer of wood, e.g. wood board, veneer, wood particle board
    • B32B21/12Layered products comprising a layer of wood, e.g. wood board, veneer, wood particle board next to a particulate layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B21/00Layered products comprising a layer of wood, e.g. wood board, veneer, wood particle board
    • B32B21/04Layered products comprising a layer of wood, e.g. wood board, veneer, wood particle board comprising wood as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04FFINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
    • E04F13/00Coverings or linings, e.g. for walls or ceilings
    • E04F13/007Outer coverings for walls with ventilating means
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04FFINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
    • E04F13/00Coverings or linings, e.g. for walls or ceilings
    • E04F13/07Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor
    • E04F13/08Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements
    • E04F13/10Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements of wood or with an outer layer of wood
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2264/00Composition or properties of particles which form a particulate layer or are present as additives
    • B32B2264/10Inorganic particles
    • B32B2264/107Ceramic
    • B32B2264/108Carbon, e.g. graphite particles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2313/00Elements other than metals
    • B32B2313/04Carbon
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2317/00Animal or vegetable based
    • B32B2317/16Wood, e.g. woodboard, fibreboard, woodchips
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2419/00Buildings or parts thereof
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2439/00Containers; Receptacles
    • B32B2439/70Food packaging
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2607/00Walls, panels

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  • Engineering & Computer Science (AREA)
  • Architecture (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Civil Engineering (AREA)
  • Structural Engineering (AREA)
  • Ceramic Engineering (AREA)
  • Building Environments (AREA)
  • Dry Formation Of Fiberboard And The Like (AREA)

Abstract

各種壁紙、ペイント及びVOC(揮発性有機化合物)排出資材のような建物内の仕上げ材によって引き起こされる、人体健康に影響を与えるシックハウス(Sick House)問題を解決するための具体的な方法として、炭の性質を経済的に利用する。炭の特性をいかした炭ボードの表面が黒色であって住居環境に使用されるとき美的飾り効果が落ちるので、本発明は、複合構造として、表面は木材及び木質材料を配置させて木材の自然美と長所をいかし、裏面に炭ボード(活性炭ボード)又は多孔性の炭充填箱を配置する。炭の機能性が落ちないように木材及び木質材料と炭及び活性炭ボード又は炭充填箱との複合構造の間の連結方法は、スライダー式、ルーバー式又はサイディング式を使う。木材及び木質材料と炭及び活性炭充填体との複合構造の炭の性質を前面に移動させるための空気流入空隙構造に関する空気流入口の適正比率を、2.5〜5%にする。As a concrete method to solve the Sick House problem affecting human health caused by various finishing materials in buildings such as wallpaper, paint and VOC (Volatile Organic Compound) emissions, charcoal Use the nature of the economy. Since the surface of the charcoal board that takes advantage of charcoal is black and the aesthetic decoration effect is reduced when used in a residential environment, the present invention is a composite structure in which the surface is made of wood and woody material so that the natural beauty of the wood Taking advantage of this, a charcoal board (activated carbon board) or a porous charcoal filling box is placed on the back. In order to prevent the functionality of charcoal from falling, the connection method between the composite structure of wood and wood material and charcoal and activated carbon board or charcoal-filled box uses a slider type, a louver type or a siding type. The appropriate ratio of the air inlet for the air inflow gap structure for moving the charcoal properties of the composite structure of wood and wood material and charcoal and activated carbon filler to the front is 2.5-5%.

Description

本発明は木材及び木質材料と炭及び活性炭ボード又は多孔性の炭充填箱(porous charcoal box)との複合構造の製造方法であって、これらをスライダー式(Slider Model)、ルーバー式(Louver Model)、サイディング式(Siding Model)で結合して、裏面に配置された炭特性を空気流入空隙構造の流入口面積によって十分に移動させるものであって、空気流入空隙構造の流入口面積比率を2.5〜5%とする方法に関する。   The present invention is a method of manufacturing a composite structure of wood and woody material and charcoal and activated carbon board or porous charcoal box, which is a slider type, a louver type. The siding type (Siding Model) is used to sufficiently move the charcoal characteristics arranged on the back surface according to the inlet area of the air inlet gap structure, and the inlet area ratio of the air inlet gap structure is 2. It relates to a method of 5 to 5%.

一般的に、炭は補修、通気、吸着、蓄熱性を持っているので悪臭、有害ガスを吸着して空気浄化作用はもちろん遠赤外線と陰イオンを放射し、騷音防止、電磁波及び有害波長まで遮断して血液循環と新陳代謝及び心身安定を与える材料として現在市中では炭の固まりをいくつずつ容器に入れてコンピュータやテレビの横に又はたんすの中や居室のコーナーにそのまま置いて使っているので、美観上良くない。   In general, charcoal has repair, ventilation, adsorption, and heat storage properties, so it absorbs bad odors and harmful gases, radiates far-infrared rays and anions as well as purifies air, prevents noise, prevents electromagnetic waves and harmful wavelengths. As a material that blocks blood circulation, metabolism, and physical and mental stability, the charcoal lump is put in a container in the container and placed next to the computer or TV, in the chest, or in the corner of the room. , Not aesthetically pleasing.

築地に埋炭する方法は紀元前から古墳で活用した方法で住居環境に電位を上げ陰イオンを放出し、酸化防止、空気浄化、ガス吸着、湿度調節、遠赤外線放出などで材料と人体に最適な環境が造成される。最近建築内部の場合には床や居室の下に不織布袋に炭の粉を内装したシートを壁の中に入れてさわやかな気持ちになるように誘導している。   The method of burying coal in Tsukiji is a method that has been used in ancient tombs in BC and raises the potential to the residential environment to release anions, which is optimal for materials and the human body with oxidation prevention, air purification, gas adsorption, humidity adjustment, far infrared emission, etc. An environment is created. Recently, in the case of the interior of a building, a sheet made of non-woven bag with charcoal powder is placed under the floor or living room, and the sheet is guided into a refreshing feeling.

炭化による炭板製造即ちウッドセラミックス方法(日本特開平4−164806)には、一般木炭炭化の時生ずるスプリッティング(Splitting)やツイスティング(twisting)等の問題を解決する方法が開示されている。この製品は工程を4段階含む複雑なものであり、フェノール樹脂もたくさん消費(繊維板の60〜100%)される欠点があった。   Carbon plate manufacturing by carbonization, that is, a wood ceramics method (Japanese Patent Laid-Open No. 4-164806) discloses a method for solving problems such as splitting and twisting that occur during carbonization of general charcoal. This product has a complicated process including four stages, and has a drawback that a large amount of phenolic resin is consumed (60 to 100% of the fiberboard).

前記のような問題点を改善した2002年大韓民国特許出願(10‐2002‐0003999)には、多孔質炭素材料である粘土・木材セラミックス製造工程を開発して、その工程を2段階に減らした方法が開始されている。   The 2002 Korean Patent Application (10-2002-0003999), which improved the above-mentioned problems, developed a process for producing a porous carbon material clay / wood ceramics and reduced the process to two stages. Has been started.

しかし、ウッドセラミックスでも粘土木材セラミックスでも建築用で使おうとすれば大面積の板に炭化しなければならないので、長期間連続式の大面積炭化装置はおびただしい投資設備と精密度が要求される。   However, if wood ceramics or clay wood ceramics are to be used for construction, they must be carbonized into large-area plates, so long-term continuous large-area carbonization equipment requires a great deal of investment equipment and precision.

従って、既存の炭化炉又は連続式炭化炉を利用して製造された炭やチップ状の炭化物、又は市販される活性炭のパーティクルの大きさを適切に加工及び利用しながら接着剤の影響で炭の機能が落ちないようにすると共にホルマリンと揮発性溶媒によるVOC(揮発性有機化合物)問題なしにフォーミングと熱圧がよくできて製造された多孔質炭素材料である炭ボードは建築材料として施工できるように十分な強度と表面性を持つように人体親和的住居環境材料として多孔質炭素材料機能性ボード複合材料製造(2002年大韓民国特許出願:10‐2003‐0048137)を本出願人が出願した。   Therefore, charcoal produced by using an existing carbonization furnace or continuous carbonization furnace, chip-like carbide, or commercially available activated carbon particles are appropriately processed and used, and the effect of the charcoal is influenced by the adhesive. Charcoal board, which is a porous carbon material manufactured with good forming and heat pressure without VOC (volatile organic compound) problems caused by formalin and volatile solvents, can be applied as a building material. The applicant has applied for the manufacture of a porous carbon material functional board composite material (2002 Korean patent application: 10-2003-0048137) as a human-friendly housing environment material having sufficient strength and surface properties.

日本等の先進国ではシックハウス(Sick House)問題で2003年7月から建築基準法改正が適用されたのでゼロホルマリンに近いEOタイプ(パーティクルボード)の無ホルマリン内装仕上げ材を使うなど住宅業界と木材産業界は素早い環境問題に対応をしている。   In developed countries such as Japan, the Building Standards Act was revised in July 2003 due to the Sick House issue, so the EO type (particle board) non-formalin interior finishing material close to zero formalin was used, and the housing industry and wood. The industry is responding to quick environmental problems.

環境府によると2000年韓国内の室内環境汚染VOC(揮発性有機化合物)濃度は紙壁紙(3833μg/m2h)、各種ペイント、木質材料製造に使われるホルマリン系接着剤などで新築後3ヶ月以上になった国内建物の室内汚染が600ppbとして基準値の約8倍以上であると明らかにした。 According to the Ministry of the Environment, indoor environmental pollution VOC (Volatile Organic Compound) concentration in Korea in 2000 was 3 months after the new construction with paper wallpaper (3833μg / m 2 h), various paints, formalin adhesives used for the production of wood materials, etc. It was clarified that the indoor pollution of the domestic building becomes 600 ppb, which is more than about 8 times the standard value.

従って、建築材料として炭を利用した製品はこのような揮発性有機化合物を浄化させて悪臭を除去し、補修、通気、吸着、蓄熱性を持っているので空気浄化作用はもちろん遠赤外線と陰イオンを放射して騷音防止、電磁波及び有害波長まで遮断する炭の性質をそのまま発現したら建築材料として最高の人体親和的材料になるのである。   Therefore, products that use charcoal as a building material purify such volatile organic compounds to remove bad odors, and have repair, ventilation, adsorption, and heat storage properties, so of course not only air purification but also far infrared rays and anions If the characteristics of charcoal that radiates the noise to prevent noise, block electromagnetic waves and harmful wavelengths are expressed as they are, it will be the best human-friendly material as a building material.

しかし、コンクリートやセメント主の国内建築で内装材として炭製品の機能性を生かすためには、機能性だけでは炭ボードの表面色が黒色なので住居環境資材としての利用度が落ちるので飾り性をいかすための複合材料が必要である。   However, in order to take advantage of the functionality of charcoal products as interior materials in domestic buildings, mainly concrete and cement, the surface color of the charcoal board is black because of the functionality alone, so the use as a residential environmental material is reduced. A composite material is needed.

本出願人によって既に出願された薄い木の断板をオーバーレイするとか有孔合板を複合化して建築内装材として活用できるように表面性を良くなるようにしたがこれだけで多様な消費者の要求である自然的な木材の自然美と飾り性を確保することは難しい。そのため、より機能性をいかしながら飾り性を追加する新しい複合材料の技術が必要になった。   Overlaying thin wooden panels already filed by the present applicant or combining perforated plywood to improve the surface quality so that it can be used as a building interior material, this alone is a requirement of various consumers It is difficult to ensure the natural beauty and decorativeness of some natural wood. Therefore, a new composite material technology that adds decorativeness while using more functionality is required.

本発明は前記のような問題点を解消することで提起された要求条件を満足させるために案出されたものである。本発明の目的は、複合構造として、表面は木材及び木質材料を配置させて木材の自然美と木材の長所をいかして、裏面に炭ボード(活性炭ボード)又は炭充填箱を配置する。炭の機能が空気流入空隙構造の流入口によって移動するように、複合構造の空気流入空隙構造と関連する空気流入口の適正比率を決める方法を提供することである。   The present invention has been devised in order to satisfy the requirements posed by solving the above problems. An object of the present invention is to arrange a charcoal board (activated carbon board) or a charcoal-filled box on the back surface by arranging wood and woody material on the surface as a composite structure, taking advantage of the natural beauty of wood and the advantages of wood. It is to provide a method for determining the proper ratio of the air inlet associated with the composite air inlet gap structure so that the charcoal function is moved by the inlet of the air inlet gap structure.

また、本発明の他の目的は、既に出願された機能性炭ボード製造と黒色炭ボードの表面飾り性のために、木の断板をオーバーレイするとか有孔合板を複合化して建築内装材として使うことは制限された使用なので複合材料の先方には木材及び木質材料として木材の強度など機能と飾り性をいかして、裏面には炭ボードを付着、炭の粉又は活性炭粒子が充填された多孔性の箱(材料は金属、プラスチック、木質材料)構造で複合化して製造するが、木材及び木質材料と炭及び活性炭ボード又は炭充填箱との複合構造の間の連結方法でスライダー式、サイディング式、ルーバー式を使って複合構造の裏面に位置する炭の性質を前面に移動させて人体親和型住居環境材料として使われるように複合構造の空気流入空隙構造に関連する空気流入口の適正な比率を決める方法を提供することである。   In addition, another object of the present invention is to build a functional charcoal board that has already been filed and to decorate the surface of black charcoal board, by overlaying wood cut boards or combining perforated plywood as a building interior material. Since the use is limited, the composite material has a porous material filled with charcoal powder or activated carbon particles on the back, using charcoal board on the back, utilizing the strength and function of wood as wood and woody material on the other side of the composite material It is manufactured by compositing with the structure of metal box (material is metal, plastic, wood material), but it is slider type, siding type by connecting method between the composite structure of wood and wood material and charcoal and activated carbon board or charcoal filled box The louver method is used to move the properties of charcoal located on the back of the composite structure to the front so that it can be used as a human-friendly living environment material. To provide a method for determining the a ratio.

前記のような目的を果たすために本発明は、木材及び木質材料を表面材で裏面を炭ボード(又は活性炭ボード)にして複合化させて壁材料又は住居環境材料として使うようにするが複合材料の間の連結をスライダー式、ルーバー式、サイディング式で適当な空気流通間隙を構成して、裏面の炭ボードの機能を活性化できるように開発した。   In order to achieve the above-mentioned object, the present invention uses a wood and a wood material as a wall material or a residential environment material by combining them with a surface material and a back surface with a charcoal board (or activated carbon board). The connection between the sliders, louvers, and sidings has been developed so that an appropriate air circulation gap can be configured and the functions of the charcoal board on the back can be activated.

また、木材及び木質材料を表面材にして、裏面に炭ボード代りに炭の粉や活性炭の粉を充填した多孔性の箱(活性炭粉や炭の粉が漏れないように多孔性の空隙率39%:例で金属網など、表1、材料は金属、プラスチック、木質材料)を構成して壁の材料又は住居環境材料として使うようにするが、複合材料の間の連結をスライダー式、サイディング式、ルーバー式で適当な空気流通間隙を構成して裏面の炭の機能が活性化できるように開発した。   Also, a porous box with wood and wood material as the surface material and filled with charcoal powder or activated carbon powder instead of charcoal board on the back surface (porous porosity 39 so that activated carbon powder or charcoal powder does not leak) %: In the example, metal mesh, etc. Table 1, materials are metal, plastic, wood material) and used as wall material or residential environment material, but the connection between composite materials is slider type, siding type It has been developed so that the function of the charcoal on the back side can be activated by configuring a suitable air circulation gap with a louver type.

従って表面材である木材及び木質材料と複合材料の間にどの位の空気流入空隙構造と関連する炭ボード又は炭パーティクル充填箱の面積に対する空気流入口面積比率が裏面に位置する炭ボード又は炭パーティクルの機能を活性化するのかに鍵になるので以下実施例を通じて本発明を説明する。   Therefore, the ratio of the air inlet area to the area of the charcoal board or charcoal particle filling box related to the air inflow gap structure between the wood and the wood material which is the surface material and the composite material is the charcoal board or charcoal particle on the back surface. Therefore, the present invention will be described below through examples.

[実施例1]
木材及び木質材料と炭ボード複合材料の裏面に位置する炭ボードの炭の性質を前面に移動させるための空気流入空隙構造と関連する空気流入口の適正比率を決定するにあたり、多孔質炭素材料炭ボード製造のための炭として、江原道原州産オリエンタルオーク(ブナ科コナラ属の落葉高木で、学名はQuercus variabilis)ファインチャコール(fine charcoal)と、椰子果実の皮を原料で作られた輸入産活性炭(パーティクルサイズ6‐18メッシュ)とを使った。本出願人が出願した多孔質炭素材料機能性ボード及び炭ボード複合材料製造(2002年大韓民国特許出願:10‐2003‐0048137)方法によって、ファインチャコールボードとして、製造しやすくて効果が良い混合型で製造して複合材料を製造した。
表面材料は木材及び木質材料を使って、裏面はファインチャコール炭ボード及び活性炭ボードを複合させることで複合材料製造は構成材料の種類と厚さによってその性質を推定できる。この分野の当業者には自明な事なのでここでは略して本発明の特徴である表面の飾り性を現わす木材及び木質材料の裏面に構成された炭ボードの炭の性質を現わすため複合材料の間の連結をスライダー式(図1)、サイディング式(図2)、ルーバー式(図3)で空気流入空隙構造(空気流入口面積)を構成して裏面の炭ボードの機能を活性化させるように炭ボード全体面積に対する空気流入間隙の流入口面積の比率がどのように炭の機能性をいかすかどうかを糾明するのに焦点を合わせて説明する。
[Example 1]
Porous carbon material charcoal is used in determining the appropriate ratio of air inlets associated with air inlet void structure to move charcoal properties of charcoal board located on the backside of wood and wood material and charcoal board composites to the front. As a charcoal for board production, Oriental Oak from Wonju, Gangwon Province (a deciduous tree of the beech family Quercus genus, scientific name is Quercus variabilis) imported charcoal (fine charcoal) and imported coconut fruit skin Activated carbon (particle size 6-18 mesh) was used. By the method of manufacturing porous carbon material functional board and charcoal board composite material (2002 Korean patent application: 10-2003-0048137) filed by the present applicant, it is a mixed charcoal board that is easy to manufacture and effective. Manufactured to produce a composite material.
The surface material is made of wood and wood material, and the back surface is made by combining fine charcoal charcoal board and activated carbon board, so that the properties of the composite material production can be estimated by the type and thickness of the constituent materials. Since it is obvious to those skilled in the art, a composite material is used here to show the charcoal properties of the charcoal board constructed on the back of the wood and wood material, which is a feature of the present invention for the sake of brevity. The connection between the sliders (FIG. 1), siding (FIG. 2), and louver (FIG. 3) constitutes an air inflow gap structure (air inlet area) to activate the function of the charcoal board on the back surface. Thus, a focus will be given to clarify how the ratio of the inlet area of the air inlet gap to the total area of the charcoal board takes advantage of the charcoal functionality.

図1のように複合材料間連結における空気流入空隙構造の流入口面積比率による複合材料裏面の炭ボードのエチレンガス吸着性能を調べて見ると、ファインチャコールボード面積対空気流入空隙構造の流入口面積の比率が20%の場合、3時間が経つと、室内壁裏面に位置するファインチャコールボードが室内前面の表面に全部100%露出されたことと同じ結果になり、ガスの約55%を吸着してガス残存量が45%位になった。   As shown in Fig. 1, when examining the ethylene gas adsorption performance of the charcoal board on the back of the composite material according to the inlet area ratio of the air inlet gap structure in the connection between the composite materials, the fine charcoal board area versus the inlet area of the air inlet gap structure If the ratio of 20% is 3%, after 3 hours, all the fine charcoal boards located on the back of the indoor wall are exposed to 100% on the front surface of the room, and about 55% of the gas is absorbed. As a result, the residual gas amount was about 45%.

空気流入口面積比率が10%の場合、6時間後に、室内壁裏面に位置する複合材料の裏側のファインチャコールボードが室内壁前面の表面に全部100%露出されたことと同じ効果を現わした。空気流入間隙の流入口面積比率が5%の場合、24時間後に、室内壁裏面に位置するファインチャコールボードが室内前面の表面に全部100%露出されたことと同じ効果を現わした。   When the air inlet area ratio was 10%, after 6 hours, the same effect was obtained that the fine charcoal board on the back side of the composite material located on the back surface of the indoor wall was 100% exposed on the front surface of the indoor wall. . When the inlet area ratio of the air inflow gap was 5%, the same effect was obtained that after 24 hours, 100% of the fine charcoal board located on the back surface of the indoor wall was exposed on the front surface of the indoor surface.

活性炭ボードはファインチャコールボードよりガス吸着機能がさらに高くて、室内壁裏面に位置する活性炭ボードの面積対空気流入空隙構造の流入口面積比率が5%の場合、室内壁裏面に位置する活性炭ボードが、3時間以内に、室内前面の表面に全部100%露出されたことと同じ効果を現わした。   The activated carbon board has a higher gas adsorption function than the fine charcoal board, and when the ratio of the area of the activated carbon board located on the back of the indoor wall to the inlet area of the air inflow gap structure is 5%, the activated carbon board located on the back of the indoor wall is Within 3 hours, the same effect as 100% exposure on the front surface of the room was obtained.

空気流入空隙構造の流入口面積比率が2.5%に小さくなっても、室内壁裏面に位置する活性炭ボードが12時間の内に約90%のガスを吸着したので、室内前面の表面に活性炭ボードが100%露出されたことと同じ効果を現わした。   Even if the inlet area ratio of the air inflow gap structure is reduced to 2.5%, the activated carbon board located on the back of the indoor wall adsorbs about 90% of the gas within 12 hours. It showed the same effect as the board was 100% exposed.

従って、複合材料の間の連結をスライダー式、サイディング式、ルーバー式とし、炭ボード面積に対する空気流入空隙構造の流入口面積比率を5%にする場合、複合材料の裏面に位置する活性炭ボードは12時間の内にファインチャコールボードは24時間の内に炭ボードが室内前面の表面に100%露出されたことと同じのように同等な吸着機能を発揮することが分かった。そのため、住居用機能性材料として表面は木材及び木質材料の自然美と木材の長所をいかしながらも、裏面の炭の特性をいかすことができた。
表1.複合材料間連結間の空気流入空隙構造の流入口面積比率による複合材料裏面炭ボードのエチレンガス吸着性能
Therefore, when the connection between the composite materials is a slider type, a siding type, and a louver type, and the inlet area ratio of the air inflow gap structure to the charcoal board area is 5%, the activated carbon board located on the back surface of the composite material is 12 It was found that the fine charcoal board exhibited an adsorption function equivalent to the fact that the charcoal board was exposed 100% on the front surface of the room within 24 hours. Therefore, as a functional material for residential use, the surface was able to take advantage of the charcoal on the back side while taking advantage of the natural beauty of wood and wood materials and the advantages of wood.
Table 1. Ethylene gas adsorption performance of composite backside charcoal board by inlet area ratio of air inflow gap structure between connections between composite materials

Figure 2008500910
Figure 2008500910

*1:複合材料裏面炭ボード面積対空気流入空隙構造の流入口面積比率(%)
*2:測定容器内のエチレンガスブランク(blank)濃度変化、ppm単位
*3:測定容器に炭ボード(大きさ、5cm×5cm×1cm)を装入して表面だけにガスが吸着されるように処理して時間による容器のエチレンガスの残存濃度変化、ppm単位.測定数値が少ないのがガスを多く吸着したことである。
* 1: Ratio of composite material backside charcoal board area to inlet area of air inflow gap structure
* 2: Ethylene gas blank concentration change in the measurement vessel, ppm unit
* 3: Charcoal board (size, 5cm x 5cm x 1cm) was placed in the measurement container and treated so that the gas was adsorbed only on the surface. The fact that the measured value is small is that a large amount of gas was adsorbed.

[実施例2]
木材及び木質材料と炭パーティクル及び活性炭パーティクル充填体複合構造の炭の性質を現わすための空気流入空隙構造に関する空気流入口の適正比率。
[Example 2]
Appropriate ratio of air inlet to air inflow gap structure to reveal charcoal properties of wood and wood material and charcoal particle and activated carbon particle filler composite structure.

木材及び木質材料と炭パーティクルを充填した箱との複合構造のための炭は、江原道原州産オリエンタルオーク(ブナ科コナラ属の落葉高木で、学名は Quercus variabilis)ファインチャコールと、椰子果実の皮を原料で作った輸入産活性炭(パーティクルサイズ6〜18メッシュ)を使った。   Charcoal for the composite structure of wood and wood materials and boxes filled with charcoal particles is a fine charcoal of oriental oak (Waconaceae Quercus variabilis) fine charcoal from Wonju, Gangwon-do, and coconut fruit Imported activated carbon (particle size 6-18 mesh) made from leather was used.

室内に向ける表面方向には木材及び木質材料を、その反対方向には炭ボードを配置するようにした実施例1との違いは、実施例2では、炭ボードの代りに炭パーティクルを箱に入れて箱の蓋に当たる外板を炭パーティクルが外に出ないように、微細細孔を配置して炭機能を現わすようにしながら、室内反対方向の壁の方に炭及び活性炭パーティクル充填体を配置する複合構造にしたことである。   The difference from Example 1 in which wood and wood material are arranged in the surface direction facing the room and charcoal board is arranged in the opposite direction is that in Example 2, charcoal particles are put in a box instead of charcoal board. In order to prevent the charcoal particles from coming out of the outer plate that hits the lid of the box, the charcoal and activated carbon particle fillers are arranged on the opposite wall in the room while arranging the fine pores to show the charcoal function This is a composite structure.

また箱の蓋の外板を網の代わりとすることによって、必要なとき、炭パーティクルを交換することができる長所がある。表1のように炭パーティクル充填箱の材料はアルミニウム又はステンレス鋼にするとかプラスチック、又は合板など木質材料として構成することができる。複合材料製造は構成材料の種類による厚さと性質によってその性質を計算できるし、この分野の通常の知識を持った者にはよく知られている方法なのでここでは略する。   Moreover, there is an advantage that charcoal particles can be exchanged when necessary by replacing the outer plate of the box lid with a net. As shown in Table 1, the material of the charcoal particle filling box can be made of aluminum or stainless steel, plastic, or wood material such as plywood. Composite material manufacturing can be calculated by thickness and properties depending on the type of component, and is omitted here because it is a method well known to those having ordinary knowledge in the field.

本発明の特徴は、表面に木材及び木質材料を使って木材の自然美と木材の長所をいかして、木材及び木質材料の裏面に構成された炭パーティクル充填体から炭の性質を現わすようにするのである。   A feature of the present invention is to use wood and wood materials on the surface to take advantage of the natural beauty of wood and the advantages of wood to reveal the charcoal properties from the charcoal particle packing constructed on the back of the wood and wood material. It is.

木材及び木質材料の裏面に構成された炭パーティクル充填体から炭の性質を現わすため複合構造の間の連結方法は実施例1と同じくスライダー式、サイディング式、ルーバー式を採択して、この方法を使うとき、適当な間隔(空気流通口)で裏面の炭の機能を活性化させるように炭パーティクル充填面積に対する空気流入空隙構造の流入口面積比率がどのように炭パーティクルの機能性をいかすかを解明することに焦点を合わせて説明する。   In order to show the properties of charcoal from the charcoal particle packing formed on the back surface of the wood and wood material, the method of connecting the composite structures is the same as in Example 1, adopting the slider type, siding type, and louver type. How to use the charcoal particle functionality by the ratio of the inlet area of the air inflow gap structure to the charcoal particle filling area so as to activate the charcoal function on the back side at an appropriate interval (air circulation port) To focus on elucidating

表2のようにファインチャコールパーティクル充填体の面積対空気流入空隙構造の空気流入口面積比率が20%の場合、3時間が経つと、ファインチャコールパーティクル充填箱が室内の内側表面に全部100%露出されたことと同じガス吸着量を現わして16ppmで1.4ppm水準に落ちた。   As shown in Table 2, when the ratio of the fine charcoal particle packing area to the air inlet area of the air inflow gap structure is 20%, the fine charcoal particle filling box is 100% exposed on the inner surface of the room after 3 hours. As a result, the same gas adsorption amount as shown in FIG.

空気流入口面積比率が10%の場合、6時間後に、ファインチャコールパーティクル充填箱が室内の内側表面に全部100%露出されたことと同じ効果を現わした。空気流入空隙構造の空気流入口面積の比率が2.5%の場合、12時間が経つとガス濃度が15.31ppmから1.3ppmに1/11.8の水準に落ちてファインチャコールパーティクル充填箱が室内の内側表面に全部100%露出されたことと同じ効果を現わした。   When the air inlet area ratio was 10%, after 6 hours, the same effect was obtained that 100% of the fine charcoal particle packed box was exposed on the inner surface of the room. When the ratio of the air inlet area of the air inflow gap structure is 2.5%, the gas concentration drops to the level of 1 / 11.8 from 15.31ppm to 1.3ppm after 12 hours, and the fine charcoal particle packed box Had the same effect as being 100% exposed on the inner surface of the room.

活性炭パーティクル充填箱はファインチャコールパーティクル充填箱よりガス吸着機能が高く、6時間で15ppm濃度から1ppm水準に落ちることが見られる。空気流入空隙構造の空気流入口面積の比率が2.5%であるとき、12時間が経つとガス濃度が15.31ppmから0.62〜0.75ppmに1/20水準まで落ちて、活性炭パーティクル充填箱が室内の内側表面に全部100%露出されたことと同じ効果を現わす。   The activated carbon particle packed box has a higher gas adsorption function than the fine charcoal particle packed box, and it can be seen that the concentration drops from 15 ppm to 1 ppm in 6 hours. When the ratio of the air inlet area of the air inlet gap structure is 2.5%, the gas concentration drops from 15.31 ppm to 0.62 to 0.75 ppm to 1/20 level after 12 hours, and activated carbon particles The effect is the same as if the filled box was 100% exposed on the inner surface of the room.

もし室内のエアコンや扇風機で空気が強制循環されたら前記例示された時間よりもっと早い速度で効果が良くなる。即ち、前記結果は一般的に空気の中でHCHO濃度が1ppmなら非常に高いことなのに12時間の内に室内の気流が動かないとしてもファインチャコールの場合安全な水準の0.08ppmに、活性炭の場合0.05ppmに低減される。   If air is forcibly circulated by an indoor air conditioner or fan, the effect is improved at a speed faster than the time exemplified above. That is, the above results are generally very high if the HCHO concentration is 1 ppm in the air, but even if the air flow in the room does not move within 12 hours, the fine charcoal has a safe level of 0.08 ppm. In this case, it is reduced to 0.05 ppm.

従って複合構造の間の連結方法をスライダー式、サイディング式、ルーバー式にして時間を二倍にふやして(24時間)、空気流入口も二倍(5%)にすれば、ファインチャコールの場合1/19、活性炭の場合1/30水準にガス濃度が下がって複合構造裏面に位置する炭パーティクルの機能を充分に発揮できるので、炭充填面積に対する空気流入空隙構造の流入口面積の比率を2.5〜5%にしても適当である。   Therefore, if the connection method between the composite structures is the slider type, siding type, and louver type, the time is doubled (24 hours), and the air inlet is doubled (5%). / 19, in the case of activated carbon, the gas concentration is reduced to 1/30 level and the function of the charcoal particles located on the back of the composite structure can be fully exerted, so the ratio of the inlet area of the air inflow gap structure to the charcoal filling area is 2. Even 5 to 5% is appropriate.

次に連結方法を具体的に説明する。スライダー式(図1)は炭充填全体面積に対する空気流入口面積の比率を2.5〜5%にした(平面図)。例えば炭パーティクル充填箱の面積が20m2(高さ2m×長さ10m)であるとき、1.2mの長さを持つスライド10個で複合する場合9個の流入口になるのに空気流入口全体面積は0.5〜1m2になる。 Next, the connection method will be specifically described. In the slider type (FIG. 1), the ratio of the air inlet area to the entire charcoal filling area was set to 2.5 to 5% (plan view). For example, when the area of the charcoal particle filling box is 20 m 2 (height 2 m × length 10 m), when combining with 10 slides having a length of 1.2 m, the air inlet becomes 9 inlets. The total area is 0.5-1 m 2 .

一つのスライド当たり流入口面積(高さ2m×厚さ方向0.0275m〜0.055m)にすれば適正である。サイディング式(図2)はスクエアチャンネルサイド(Square Channel Side)の形態で、正面からは空気流入口が見えないようにしながらサイディング自体にサイディング面積当たり2.5〜5%の空気流入口になる間隙を作る。従って一つのスクエアチャンネルサイドに他のスクエアチャンネルサイドを連結すれば四角形形態(表2.正面)で2.5〜5%の空気流入口が自動的に構成できるようになる。 It is appropriate if the inlet area per slide (height 2 m × thickness direction 0.0275 m to 0.055 m) is used. The siding type (Fig. 2) is in the form of a square channel side, and the air inlet is not visible from the front, while the siding itself has a 2.5-5% air inlet per siding area. make. Therefore, if another square channel side is connected to one square channel side, an air inlet of 2.5 to 5% can be automatically configured in a quadrangular form (Table 2. Front).

ルーバー式(図3)はルーバーの付着角度を最大限立てる方法にして裏面に位置する炭パーティクル充填箱全体面積に対する空気流入口面積比率(ルーバー付着間隔面積)を2.5〜5%になるようにする。   The louver type (FIG. 3) is a method that maximizes the adhesion angle of the louver so that the air inlet area ratio (louver adhesion interval area) to the entire area of the charcoal particle filling box located on the back surface is 2.5 to 5%. To.

表2.複合構造の空気流入空隙構造の流入口面積比率による複合構造裏面に位置する炭パーティクル充填体のエチレンガス吸着性能   Table 2. Ethylene gas adsorption performance of charcoal particle packing located on the back side of the composite structure based on the inlet area ratio of the air flow gap structure of the composite structure

Figure 2008500910
Figure 2008500910

*1:炭パーティクル充填体面積に対する空気流入空隙構造の流入口面積比率(%)
*2:測定容器内のエチレンガスブランク濃度変化、ppm単位
*3:測定容器に炭パーティクル箱(表面積:25cm)を装入して箱の蓋は39%の空隙になっている網で作って炭の機能を表出するようにした。時間によってガスが吸着されて容器のエチレンガスの残存濃度は少なくなる。ppm単位.測定数値が少ない方がガスを多く吸着したことである。
* 1: Ratio of inlet area of air inflow gap structure to charcoal particle filler area (%)
* 2: Ethylene gas blank concentration change in the measurement container, ppm unit
* 3: Charcoal particle box (surface area: 25 cm 2 ) was placed in the measurement container, and the lid of the box was made of a net with 39% voids to reveal the charcoal function. The gas is adsorbed over time, and the residual concentration of ethylene gas in the container decreases. ppm units. The smaller the measured value, the more gas was adsorbed.

[実施例3]
木材及び炭の遠赤外線放射率
表3のように、木材及び炭は、常温で遠赤外線を90%放出し、その寿命は材料の寿命と同じ程度に長い。
[Example 3]
Far-infrared emissivity of wood and charcoal As shown in Table 3, wood and charcoal emit 90% of far-infrared rays at room temperature, and their lifetime is as long as the lifetime of the material.

1976年遠赤外線を利用して病気を治療して以来、遠赤外線を利用した商業的医療機器が生産利用されている。遠赤外線が人体に及ぶ効果は、皮下層の温度上昇、微細血液の拡張、血液循環の促進、血液と人体とその他組職との新陳代謝強化、血液障害の解消、組職の再生能力の増加、同時に知覚神経の異常興奮抑制、自律神経の機能調整効果もあると知られてある。   Since the treatment of diseases using far infrared rays in 1976, commercial medical devices using far infrared rays have been produced and used. The effects of far-infrared rays on the human body are the increase in the temperature of the subcutaneous layer, the expansion of fine blood, the promotion of blood circulation, the strengthening of metabolism between the blood, the human body and other organizations, the elimination of blood disorders, the increase in the ability to regenerate the organization, At the same time, it is known to have abnormal excitation suppression of sensory nerves and function adjustment of autonomic nerves.

人体は70%位が水で構成されている。水分子の波長帯は10μmであって、人体が放射する波長帯は3〜50μmで、この中8〜14μmの波長で46%が放射している。この波長帯は人体が受け入れやすい波長帯であり、常温で弱いとしても遠赤外線が人体に放射されば水分子が活性化されて血液循環が良くなると考えられる。   About 70% of the human body is composed of water. The wavelength band of water molecules is 10 μm, and the wavelength band emitted by the human body is 3 to 50 μm, of which 46% radiates at a wavelength of 8 to 14 μm. This wavelength band is a wavelength band that is easy for the human body to accept, and even if it is weak at room temperature, if far infrared rays are emitted to the human body, water molecules are activated and blood circulation is improved.

従って、人体内細胞を構成する水分と蛋白質分子に遠赤外線が放射されて細胞を1分で2000回ずつ微細に振ってくれる振動を通じて早く暖かくなって血液循環を促進させて、細胞組織を活性化させて生命活動をより旺盛にさせてくれるし、同じく植物の同化作用も促進させてくれるので、遠赤外線は生育光線だとも呼ばれる。従って木材と炭の複合材料は、常温で遠赤外線を90%以上放出するので、住居環境材料としては最高の材料だと言える。   Therefore, far-infrared rays are radiated to the water and protein molecules that make up human body cells, and the cells warm up rapidly through vibrations that shake the cells minutely 2000 times per minute, promoting blood circulation and activating cellular tissues. This makes it more vigorous for life and also promotes the assimilation of plants, so far-infrared rays are also called growth rays. Therefore, the composite material of wood and charcoal emits 90% or more of far infrared rays at room temperature, so it can be said that it is the best material for residential environment.

表3.オーバーレイファインチャコールボードの遠赤外線放射率(5〜20μm) Table 3. Far-infrared emissivity of overlay fine charcoal board (5-20μm)

Figure 2008500910
Figure 2008500910

[実施例4]
炭ボードの電磁波遮蔽効果
ファインチャコールボードは、薄紙を付けても木材を付けてもその中に炭ボードがあれば電磁波を遮蔽するのでその遮蔽効果を表4に示した。実際に携帯電話を炭ボード箱に入れて置けばベルが鳴らない。
[Example 4]
Electromagnetic wave shielding effect of charcoal board Fine charcoal board shields electromagnetic waves if there is charcoal board in thin paper or wood, and the shielding effect is shown in Table 4. If you put your mobile phone in a charcoal board box, the bell will not ring.

表4.平面材料の平面波による電磁波遮蔽効果 Table 4. Electromagnetic wave shielding effect of plane material by plane wave

Figure 2008500910
Figure 2008500910

以上の説明で本発明はこの分野の通常の知識を持った者には明確となり、前記実施例は本発明を説明するためのものであって、その実施例に限定されることはない。   From the above description, the present invention will be clear to those having ordinary knowledge in this field, and the above-described embodiments are for explaining the present invention and are not limited to the embodiments.

以上のように、住居環境資材が耐久性と強度を主として発展し、特に石灰石の豊かな韓国はセメント建物が主になって各種壁紙とペイント及びVOC(揮発性有機化合物)排出資材を内部に持っているのでシックハウス(Sick House)問題を解決するためには炭の性質(除湿、補修、通気、吸着、蓄熱性を持っていて悪臭、有害ガスを吸着する空気浄化作用はもちろん遠赤外線と陰イオンを放射して騷音防止、電磁波及び有害波長まで遮断して血液循環と新陳代謝及び心身安定を与える材料)を効果的に利用する方案を講究しなければならない。   As described above, residential environmental materials have developed mainly in terms of durability and strength. Especially in South Korea where limestone is rich, mainly cement buildings have various wallpaper, paint and VOC (volatile organic compound) discharge materials inside. Therefore, in order to solve the Sick House problem, the nature of charcoal (dehumidification, repair, ventilation, adsorption, heat storage, and the air purification action that absorbs odors and harmful gases is of course far infrared and anion. Must be studied to effectively utilize the material that prevents blood stuttering, blocks electromagnetic waves and harmful wavelengths, and provides blood circulation, metabolism, and physical and mental stability.

従って本願発明は、炭の特性をいかした炭ボードの表面が黒色なので住居環境に使用される時美的飾り効果が落ちるので、本発明は複合構造として表面は木材及び木質材料を配置させて木材の自然美と長所をいかして裏面に炭ボード(活性炭ボード)又は炭充填箱を配置するが炭の機能性が落ちないように木材及び木質材料と炭及び活性炭ボード又は炭充填箱との複合構造の間の連結方法はスライダー式、サイディング式、ルーバー式を使って木材及び木質材料と炭及び活性炭充填体複合構造の炭の性質を現わすための空気流入空隙構造に関する空気流入口の適正比率を提供して、住居環境に使用される時壁材、天井材などに人体親和的建築内装材で使われることができるし、又は博物館の保管庫、食品や果物等の包装用材としても充分に活用されることができる。   Therefore, since the surface of the charcoal board utilizing the characteristics of charcoal is black because the surface of the charcoal board is used in a residential environment, the aesthetic decoration effect is reduced. Between the composite structure of wood and wood material and charcoal and activated carbon board or charcoal filled box so that charcoal board (activated charcoal board) or charcoal filled box is placed on the back using natural beauty and advantages The connection method uses slider, siding, and louver methods to provide the proper ratio of air inlets to the air inlet gap structure to reveal the charcoal properties of wood and wood materials and charcoal and activated carbon filler composite structures. When used in a residential environment, it can be used as a human-friendly building interior material for wall materials, ceiling materials, etc., or it can be used as a storage for museums and packaging materials for food and fruits. It is the can.

図1は本発明によるスライダー式での複合材料の連結を現わした図面である。FIG. 1 is a diagram showing the connection of composite materials in a slider type according to the present invention. 図2は本発明によるサイディング式での複合材料の連結を現わした図面である。FIG. 2 is a view showing the connection of composite materials in a siding type according to the present invention. 図3は本発明のルーバー式での複合材料の連結を現わした図面である。FIG. 3 is a drawing showing the connection of composite materials in the louver type of the present invention.

Claims (2)

表面装飾のために表面に配置された木材及び木質材料と、その裏面に配置された炭ボードとを備えた居住環境用複合材料を製造する方法であって、
前記木材及び木質材料と前記炭ボードとを、スライダー式、サイディング式、または、ルーバー式で結合することによって、前記裏面に配置された前記炭ボードの機能を空気流入空隙構造の流入口によって活性化させるものであって、前記空気流入空隙構造の流入口面積比率を前記炭ボード全体面積の2.5〜5%とする方法。
A method for producing a composite material for residential environment comprising wood and wood material arranged on the surface for surface decoration and charcoal board arranged on the back surface thereof,
The function of the charcoal board arranged on the back surface is activated by the inlet of the air inflow gap structure by combining the wood and wood material and the charcoal board by a slider type, a siding type, or a louver type. A method of adjusting the inlet area ratio of the air inflow gap structure to 2.5 to 5% of the total area of the charcoal board.
表面装飾のために表面に配置された木材及び木質材料と、その裏面に配置された、炭パーティクル又は活性炭パーティクルが充填された多孔性の炭充填箱とを備えた居住環境用複合材料を製造する方法であって、
前記木材及び木質材料と前記炭充填箱とを、スライダー式、サイディング式、または、ルーバー式で結合することによって、前記裏面に配置された前記炭の特性を空気流入空隙構造の流入口によって前面へと移動させるものであって、前記空気流入空隙構造の流入口面積比率を前記炭充填箱全体面積の2.5〜5%とする方法。
Manufacture a composite material for residential environment comprising wood and wood material arranged on the surface for surface decoration and a porous charcoal-filled box filled with charcoal particles or activated carbon particles arranged on the back surface thereof A method,
By combining the wood and wood material and the charcoal filling box in a slider type, a siding type, or a louver type, the charcoal characteristics arranged on the back side are brought to the front side by an inlet of an air inflow gap structure. And moving the inlet area ratio of the air inflow gap structure to 2.5 to 5% of the total area of the charcoal-filled box.
JP2007510625A 2004-04-29 2005-04-29 Air inlet of composite structure of charcoal dissimilar materials for human-friendly housing Pending JP2008500910A (en)

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JPH10310466A (en) * 1997-05-09 1998-11-24 Yamashita Mikumo Charcoal panel and production of charcoal panel
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JPH10310466A (en) * 1997-05-09 1998-11-24 Yamashita Mikumo Charcoal panel and production of charcoal panel
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