JP2008303368A - Epoxy resin composition for sealing semiconductor and semiconductor device using the same - Google Patents

Epoxy resin composition for sealing semiconductor and semiconductor device using the same Download PDF

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JP2008303368A
JP2008303368A JP2007154572A JP2007154572A JP2008303368A JP 2008303368 A JP2008303368 A JP 2008303368A JP 2007154572 A JP2007154572 A JP 2007154572A JP 2007154572 A JP2007154572 A JP 2007154572A JP 2008303368 A JP2008303368 A JP 2008303368A
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epoxy resin
resin composition
semiconductor
sealing
granular
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Tatsumi Kawaguchi
竜巳 河口
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Sumitomo Bakelite Co Ltd
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Sumitomo Bakelite Co Ltd
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<P>PROBLEM TO BE SOLVED: To provide an epoxy resin composition for sealing a semiconductor, which can enhance the yield and quality of a semiconductor device on compression molding, when the semiconductor element is sealed by a compression molding method to manufacture a semiconductor device. <P>SOLUTION: The present invention relates to the granular epoxy resin composition for sealing a semiconductor, used for sealing a semiconductor element by a compression molding method, to produce the semiconductor device, characterized by having a compacted bulk density of ≥0.8 g/cm<SP>3</SP>and ≤1.1 g/cm<SP>3</SP>, as measured with a measurement container having an inner diameter of 50.46 mm, a depth of 50 mm and a volume of 100 cm<SP>3</SP>. <P>COPYRIGHT: (C)2009,JPO&INPIT

Description

本発明は、顆粒状の半導体封止用エポキシ樹脂組成物及びそれを用いた半導体装置に関するものであり、特に圧縮成形により半導体素子を封止するのに適した顆粒状の半導体封止用エポキシ樹脂組成物及びそれを用いた半導体装置に関するものである。   TECHNICAL FIELD The present invention relates to a granular semiconductor sealing epoxy resin composition and a semiconductor device using the same, and particularly to a granular semiconductor sealing epoxy resin suitable for sealing a semiconductor element by compression molding. The present invention relates to a composition and a semiconductor device using the composition.

圧縮成形により半導体素子を封止した半導体装置に関する技術としては、金型内を減圧下にしつつ圧縮成形をして樹脂封止する方法(例えば、特許文献1参照。)や封止用の成形材料を厚さ3.0mm以下のペレット状又はシート状としたものを用いる方法(例えば、特許文献2参照。)等が開示されている。   As a technique related to a semiconductor device in which a semiconductor element is sealed by compression molding, a method of performing resin molding by compression molding while reducing the pressure inside a mold (see, for example, Patent Document 1) and a molding material for sealing A method using a pellet or sheet having a thickness of 3.0 mm or less (for example, see Patent Document 2) is disclosed.

特開2000−021908JP2000-021908 特開2006−216899JP 2006-216899 A

本発明は、圧縮成形により半導体素子を封止して半導体装置を得る場合において、圧縮成形時の歩留まりや半導体装置における品質を高めることができる半導体封止用エポキシ樹脂組成物を提供するものである。   The present invention provides an epoxy resin composition for semiconductor encapsulation that can increase the yield during compression molding and the quality in the semiconductor device when a semiconductor device is obtained by sealing a semiconductor element by compression molding. .

このような目的は、下記[1]〜[3]に記載の本発明により達成される。
[1] 圧縮成形により半導体素子を封止してなる半導体装置に用いる半導体封止用エポキシ樹脂組成物であって、内径50.46mm、深さ50mm、容積100cmの測定容器を用いて測定した、固めかさ密度が0.8g/cm以上、1.1g/cm以下であることを特徴とする顆粒状の半導体封止用エポキシ樹脂組成物。
[2] 2mm以上の粗粒の割合が3重量%以下であり、106μm未満の微粉の割合が7重量%以下であることを特徴とする第[1]項記載の顆粒状の半導体封止用エポキシ樹脂組成物。
[3] 第[1]項又は第[2]項記載の顆粒状の半導体封止用エポキシ樹脂組成物を用いて半導体素子を封止してなることを特徴とする半導体装置。
Such an object is achieved by the present invention described in the following [1] to [3].
[1] An epoxy resin composition for encapsulating a semiconductor used for a semiconductor device in which a semiconductor element is encapsulated by compression molding, and measured using a measuring container having an inner diameter of 50.46 mm, a depth of 50 mm, and a volume of 100 cm 3 . A granular epoxy resin composition for encapsulating semiconductors, wherein the bulk density is 0.8 g / cm 3 or more and 1.1 g / cm 3 or less.
[2] The ratio of coarse particles of 2 mm or more is 3% by weight or less, and the proportion of fine powders of less than 106 μm is 7% by weight or less, for sealing a granular semiconductor according to item [1] Epoxy resin composition.
[3] A semiconductor device obtained by sealing a semiconductor element using the granular epoxy resin composition for sealing a semiconductor according to [1] or [2].

本発明に従うと、圧縮成形により半導体素子を封止して半導体装置を得る場合において、圧縮成形時の歩留まりや半導体装置における品質を高めることができる半導体封止用エポキシ樹脂組成物を得ることができる。   According to the present invention, when a semiconductor device is obtained by encapsulating a semiconductor element by compression molding, an epoxy resin composition for semiconductor encapsulation that can increase the yield during compression molding and the quality of the semiconductor device can be obtained. .

本発明は、圧縮成形により半導体素子を封止してなる半導体装置に用いる半導体封止用エポキシ樹脂組成物であって、内径50.46mm、深さ50mm、容積100cmの測定容器を用いて測定した、固めかさ密度が0.8g/cm以上、1.1g/cm以下である顆粒状の半導体封止用エポキシ樹脂組成物である。
粉末状のエポキシ樹脂組成物を用いて、圧縮成形により半導体素子を封止して半導体装置を得る場合において、圧縮成形時の歩留まりや半導体装置における品質を向上させるためには、粉末状のエポキシ樹脂組成物を圧縮成形金型のキャビティへの均質な投入と、圧縮成形金型のキャビティに投入される粉末状のエポキシ樹脂組成物の秤量精度が重要である。また、エポキシ樹脂組成物の投入準備と秤量とを、振動フィーダー等の搬送装置により行う場合においては、振動によりエポキシ樹脂組成物の粉末が均質に送り出されること(以下、「搬送性」という。)が重要である。
本発明の顆粒状の半導体封止用エポキシ樹脂組成物を用いると、圧縮成形により半導体素子を封止して半導体装置を得る場合において、半導体封止用エポキシ樹脂組成物を圧縮成形金型のキャビティへ投入する際の秤量精度と搬送性が良好となり、圧縮成形時の歩留まりや半導体装置における品質を向上させることができるものである。
以下、本発明について詳細に説明する。
The present invention is an epoxy resin composition for semiconductor encapsulation used in a semiconductor device in which a semiconductor element is encapsulated by compression molding, and is measured using a measurement container having an inner diameter of 50.46 mm, a depth of 50 mm, and a volume of 100 cm 3. It is a granular epoxy resin composition for encapsulating a semiconductor having a bulk density of 0.8 g / cm 3 or more and 1.1 g / cm 3 or less.
In the case of obtaining a semiconductor device by sealing a semiconductor element by compression molding using a powdered epoxy resin composition, in order to improve the yield at the time of compression molding and quality in the semiconductor device, a powdered epoxy resin It is important that the composition is uniformly charged into the cavity of the compression mold and the weighing accuracy of the powdered epoxy resin composition charged into the cavity of the compression mold. In addition, when the preparation and weighing of the epoxy resin composition are performed by a conveying device such as a vibration feeder, the powder of the epoxy resin composition is homogeneously sent out by vibration (hereinafter referred to as “conveyability”). is important.
When the granular epoxy resin composition for encapsulating a semiconductor of the present invention is used to obtain a semiconductor device by encapsulating a semiconductor element by compression molding, the epoxy resin composition for semiconductor encapsulation is compressed into a cavity of a compression mold. As a result, the weighing accuracy and the transportability when it is put into the wafer are improved, and the yield at the time of compression molding and the quality of the semiconductor device can be improved.
Hereinafter, the present invention will be described in detail.

従来用いられてきた圧縮成形用の半導体封止用エポキシ樹脂組成物は、各原料成分をミキサーで予備混合後、ロール、ニーダー又は押出機等の混練機により加熱混練後、冷却、粉砕工程を経て粉砕物としたものであり、内径50.46mm、深さ50mm、容積100cmの測定容器を用いて測定した、固めかさ密度が1.2g/cm以上、1.4g/cm以下程度のものであった。
本発明によって得られる顆粒状の半導体封止用エポキシ樹脂組成物は、内径50.46mm、深さ50mm、容積100cm測定容器を用いて測定した、固めかさ密度が0.8g/cm以上、1.1g/cm以下であることが好ましく、0.8g/cm以上、1.0g/cm以下であることがより好ましい。固めかさ密度は、容量のわかっている測定容器の上部に円筒を取り付けたものにエポキシ樹脂組成物の試料をゆるやかに入れた後、180回のタッピングを行い、その後、上部円筒を取り除き、測定容器上部に堆積した試料をブレードですりきり、測定容器に充填された試料の重量を測定することにより求めることができる。固めかさ密度は、振動フィーダー等の搬送装置における搬送経路中での粉体の圧密状態を表す指標であり、この値が大きいほど粉体層の空隙率が低いことを示し、固結やブリッジによる閉塞状態になりやすく、搬送不良の原因となる。逆に、この値が小さ過ぎる場合は、比較的粒径の大きな粗粒が大半を占めることで空隙率が高くなっている状態であり、秤量精度が低下することとなる。
固めかさ密度が上記範囲内となる顆粒状の半導体封止用エポキシ樹脂組成物とするには、以下に詳細に説明する製造方法により得ることができる。
A conventionally used epoxy resin composition for semiconductor molding for compression molding is prepared by premixing each raw material component with a mixer, followed by heating and kneading with a kneader such as a roll, kneader or extruder, followed by cooling and pulverization steps. It is a pulverized product and measured with a measuring container having an inner diameter of 50.46 mm, a depth of 50 mm, and a volume of 100 cm 3 , and has a solid bulk density of 1.2 g / cm 3 or more and 1.4 g / cm 3 or less. It was a thing.
The granular epoxy resin composition for semiconductor encapsulation obtained according to the present invention has an inside diameter of 50.46 mm, a depth of 50 mm, a volume density of 100 g 3 measured using a measuring container of 0.8 cm / cm 3 or more, It is preferably 1.1 g / cm 3 or less, and more preferably 0.8 g / cm 3 or more and 1.0 g / cm 3 or less. The bulk density is determined by gently putting a sample of the epoxy resin composition on the top of a measuring container with a known capacity and then tapping 180 times, then removing the upper cylinder and measuring container. This can be obtained by grinding the sample deposited on the top with a blade and measuring the weight of the sample filled in the measurement container. The compacted bulk density is an index representing the compaction state of the powder in the transport path in a transport device such as a vibration feeder. The larger the value, the lower the porosity of the powder layer. It is likely to be in a closed state, causing a conveyance failure. On the other hand, when this value is too small, coarse particles having a relatively large particle size occupy the majority, so that the porosity is high, and the weighing accuracy is lowered.
In order to obtain a granular epoxy resin composition for encapsulating a semiconductor having a solid bulk density within the above range, it can be obtained by a production method described in detail below.

また、本発明によって得られる半導体封止用エポキシ樹脂組成物は、顆粒状の半導体封止用エポキシ樹脂組成物であるが、圧縮成形における安定した搬送性と良好な秤量精度を得るため、2mm以上の粗粒の割合が3重量%以下であることが好ましく、1重量%以下であることがより好ましい。これは、粒子サイズが大きくなるほどその粒子の重量も大きくなることから、2mm以上の粗粒の割合が多いほど、秤量時の秤量精度が低下し、成形後の半導体装置における品質低下の一因となるためである。
また、本発明の顆粒状のエポキシ樹脂組成物は、安定した秤量精度を得るため、106μm未満の微粉の割合が7重量%以下であることが好ましく、3重量%以下であることがより好ましい。これは、106μm未満の微粉が、微粉の搬送経路上での固結や搬送装置への付着を生じ、搬送不良の原因となるためである。
2mm以上の粗粒と106μm未満の微粉の割合が少ない顆粒状の半導体封止用エポキシ樹脂組成物とするには、下記に詳細に説明する製造方法により得ることができる。
Moreover, the epoxy resin composition for semiconductor encapsulation obtained by the present invention is a granular epoxy resin composition for semiconductor encapsulation, but 2 mm or more in order to obtain stable transportability and good weighing accuracy in compression molding. The ratio of the coarse particles is preferably 3% by weight or less, and more preferably 1% by weight or less. This is because the larger the particle size, the larger the weight of the particle, so the larger the proportion of coarse particles of 2 mm or more, the lower the weighing accuracy at the time of weighing, which contributes to the quality deterioration in the semiconductor device after molding. It is to become.
In addition, in the granular epoxy resin composition of the present invention, the proportion of fine powder of less than 106 μm is preferably 7% by weight or less, and more preferably 3% by weight or less in order to obtain stable weighing accuracy. This is because fine powder of less than 106 μm causes solidification of the fine powder on the conveyance path and adhesion to the conveyance device, which causes conveyance failure.
In order to obtain a granular epoxy resin composition for semiconductor encapsulation having a small proportion of coarse particles of 2 mm or more and fine powders of less than 106 μm, it can be obtained by a production method described in detail below.

本発明の顆粒状の半導体封止用エポキシ樹脂組成物は、エポキシ樹脂、硬化剤、無機充填剤、及び硬化促進剤、並びに必要に応じて、着色剤、離型剤、低応力成分、酸化防止剤等の添加剤を含むものである。   The granular epoxy resin composition for semiconductor encapsulation of the present invention comprises an epoxy resin, a curing agent, an inorganic filler, a curing accelerator, and, if necessary, a colorant, a release agent, a low stress component, and an antioxidant. It contains additives such as agents.

本発明のエポキシ樹脂組成物に用いられるエポキシ樹脂は、1分子内にエポキシ基を2個以上有するモノマー、オリゴマー、ポリマー全般であり、その分子量、分子構造を特に限定するものではないが、例えば、ビフェニル型エポキシ樹脂、ビスフェノールA型エポキシ樹脂、ビスフェノールF型エポキシ樹脂、スチルベン型エポキシ樹脂、ハイドロキノン型エポキシ樹脂等の結晶性エポキシ樹脂;クレゾールノボラック型エポキシ樹脂、フェノールノボラック型エポキシ樹脂、ナフトールノボラック型エポキシ樹脂等のノボラック型エポキシ樹脂;フェニレン骨格含有フェノールアラルキル型エポキシ樹脂、ビフェニレン骨格含有フェノールアラルキル型エポキシ樹脂、フェニレン骨格含有ナフトールアラルキル型エポキシ樹脂等のフェノールアラルキル型エポキシ樹脂;トリフェノールメタン型エポキシ樹脂及びアルキル変性トリフェノールメタン型エポキシ樹脂等の3官能型エポキシ樹脂;ジシクロベンタジエン変性フェノール型エポキシ樹脂、テルペン変性フェノール型エポキシ樹脂等の変性フェノール型エポキシ樹脂;トリアジン核含有エポキシ樹脂等の複素環含有エポキシ樹脂等が挙げられ、これらは1種類を単独で用いても2種類以上を組み合わせて用いてもよい。   The epoxy resin used in the epoxy resin composition of the present invention is a monomer, oligomer, or polymer in general having two or more epoxy groups in one molecule, and its molecular weight and molecular structure are not particularly limited. Crystalline epoxy resins such as biphenyl type epoxy resin, bisphenol A type epoxy resin, bisphenol F type epoxy resin, stilbene type epoxy resin, hydroquinone type epoxy resin; cresol novolac type epoxy resin, phenol novolac type epoxy resin, naphthol novolak type epoxy resin Phenolic epoxy resins such as phenylene skeleton-containing phenol aralkyl epoxy resins, biphenylene skeleton-containing phenol aralkyl epoxy resins, phenylene skeleton-containing naphthol aralkyl epoxy resins, etc. Luaralkyl type epoxy resin; Trifunctional epoxide resin such as triphenolmethane type epoxy resin and alkyl modified triphenolmethane type epoxy resin; Modified phenol type epoxy such as dicyclopentadiene modified phenol type epoxy resin and terpene modified phenol type epoxy resin Resins; heterocyclic ring-containing epoxy resins such as triazine nucleus-containing epoxy resins, and the like may be used, and these may be used alone or in combination of two or more.

本発明のエポキシ樹脂組成物に用いられる硬化剤としては、エポキシ樹脂と反応して硬化させるものであれば特に限定されず、例えば、エチレンジアミン、トリメチレンジアミン、テトラメチレンジアミン、ヘキサメチレンジアミン等の炭素数2〜20の直鎖脂肪族ジアミン、メタフェニレンジアミン、パラフェニレンジアミン、パラキシレンジアミン、4,4’−ジアミノジフェニルメタン、4,4’−ジアミノジフェニルプロパン、4,4’−ジアミノジフェニルエーテル、4,4’−ジアミノジフェニルスルホン、4,4’−ジアミノジシクロヘキサン、ビス(4−アミノフェニル)フェニルメタン、1,5−ジアミノナフタレン、メタキシレンジアミン、パラキシレンジアミン、1,1−ビス(4−アミノフェニル)シクロヘキサン、ジシアノジアミド等のアミノ類;アニリン変性レゾール樹脂やジメチルエーテルレゾール樹脂等のレゾール型フェノール樹脂;フェノールノボラック樹脂、クレゾールノボラック樹脂、tert−ブチルフェノールノボラック樹脂、ノニルフェノールノボラック樹脂等のノボラック型フェノール樹脂;ポリパラオキシスチレン等のポリオキシスチレン;フェノールアラルキル樹脂等のフェノール樹脂や酸無水物等が例示されるが、特にこれらに限定されるものではない。また、これらの内、半導体封止材料に用いる硬化剤としては、耐湿性、信頼性等の点から、1分子内に少なくとも2個のフェノール性水酸基を有する化合物が好ましく、フェノールノボラック樹脂、クレゾールノボラック樹脂、tert−ブチルフェノールノボラック樹脂、ノニルフェノールノボラック樹脂等のノボラック型フェノール樹脂;レゾール型フェノール樹脂;ポリパラオキシスチレン等のポリオキシスチレン;フェノールアラルキル樹脂等が例示される。   The curing agent used in the epoxy resin composition of the present invention is not particularly limited as long as it is cured by reacting with an epoxy resin. For example, carbon such as ethylenediamine, trimethylenediamine, tetramethylenediamine, hexamethylenediamine, etc. 2-20 linear aliphatic diamine, metaphenylenediamine, paraphenylenediamine, paraxylenediamine, 4,4′-diaminodiphenylmethane, 4,4′-diaminodiphenylpropane, 4,4′-diaminodiphenyl ether, 4, 4′-diaminodiphenylsulfone, 4,4′-diaminodicyclohexane, bis (4-aminophenyl) phenylmethane, 1,5-diaminonaphthalene, metaxylenediamine, paraxylenediamine, 1,1-bis (4-amino) Phenyl) cyclohexane Aminos such as dicyanodiamide; resol type phenol resins such as aniline-modified resole resin and dimethyl ether resole resin; Examples of such polyoxystyrenes include phenol resins such as phenol aralkyl resins and acid anhydrides, but are not limited thereto. Of these, the curing agent used for the semiconductor encapsulating material is preferably a compound having at least two phenolic hydroxyl groups in one molecule from the viewpoint of moisture resistance, reliability, etc., and a phenol novolac resin and cresol novolac. Examples thereof include novolak-type phenol resins such as resins, tert-butylphenol novolak resins, and nonylphenol novolak resins; resol-type phenol resins; polyoxystyrenes such as polyparaoxystyrene; and phenolaralkyl resins.

本発明のエポキシ樹脂組成物に用いられる無機充填剤としては、一般に半導体封止材料に用いられているものであれば、特に制限はなく、溶融破砕シリカ粉末、溶融球状シリカ粉末、結晶シリカ粉末、2次凝集シリカ粉末等のシリカ粉末;アルミナ、チタンホワイト、水酸化アルミニウム、タルク、クレー、マイカ、ガラス繊維等が挙げられる。これらの中でも、特に溶融球状シリカ粉末が好ましい。また、形状は限りなく真球状であることが好ましく、また、粒子の大きさの異なるものを混合することにより充填量を多くすることができる。   The inorganic filler used in the epoxy resin composition of the present invention is not particularly limited as long as it is generally used for a semiconductor sealing material, and is a fused crushed silica powder, a fused spherical silica powder, a crystalline silica powder, Silica powder such as secondary agglomerated silica powder; alumina, titanium white, aluminum hydroxide, talc, clay, mica, glass fiber and the like. Among these, fused spherical silica powder is particularly preferable. Further, the shape is preferably infinitely spherical, and the amount of filling can be increased by mixing particles having different particle sizes.

本発明のエポキシ樹脂組成物に用いられる硬化促進剤としては、エポキシ基とフェノール性水酸基との硬化反応を促進させるものであればよく、一般に封止材料に使用するものを用いることができる。例えば、1,8−ジアザビシクロ(5,4,0)ウンデセン−7等のジアザビシクロアルケン及びその誘導体;トリブチルアミン、ベンジルジメチルアミン等のアミン系化合物;2−メチルイミダゾール等のイミダゾール化合物;トリフェニルホスフィン、メチルジフェニルホスフィン等の有機ホスフィン類;テトラフェニルホスホニウム・テトラフェニルボレート、テトラフェニルホスホニウム・テトラ安息香酸ボレート、テトラフェニルホスホニウム・テトラナフトイックアシッドボレート、テトラフェニルホスホニウム・テトラナフトイルオキシボレート、テトラフェニルホスホニウム・テトラナフチルオキシボレート等のテトラ置換ホスホニウム・テトラ置換ボレート;ベンゾキノンをアダクトしたトリフェニルホスフィン等が挙げられ、これらは1種類を単独で用いても2種類以上を組み合わせて用いてもよい。   As a hardening accelerator used for the epoxy resin composition of this invention, what accelerates | stimulates the hardening reaction of an epoxy group and a phenolic hydroxyl group should just be used, and what is generally used for a sealing material can be used. For example, diazabicycloalkenes such as 1,8-diazabicyclo (5,4,0) undecene-7 and derivatives thereof; amine compounds such as tributylamine and benzyldimethylamine; imidazole compounds such as 2-methylimidazole; triphenyl Organic phosphines such as phosphine and methyldiphenylphosphine; tetraphenylphosphonium / tetraphenylborate, tetraphenylphosphonium / tetrabenzoic acid borate, tetraphenylphosphonium / tetranaphthoic acid borate, tetraphenylphosphonium / tetranaphthoyloxyborate, tetraphenyl Tetra-substituted phosphonium / tetra-substituted borate such as phosphonium / tetranaphthyloxyborate; triphenylphosphine adducted with benzoquinone Is, they may be used in combination of two or more be used one kind alone.

本発明のエポキシ樹脂組成物には、上記の成分以外に、必要に応じて、γ−グリシドキシプロピルトリメトキシシラン等のカップリング剤;カーボンブラック等の着色剤;天然ワックス、合成ワックス、高級脂肪もしくはその金属塩類、パラフィン等の離型剤;シリコーンオイル、シリコーンゴム等の低応力成分;酸化防止剤等の各種添加剤を配合することができる。   In addition to the above components, the epoxy resin composition of the present invention includes a coupling agent such as γ-glycidoxypropyltrimethoxysilane; a colorant such as carbon black; Release agents such as fat or metal salts thereof, paraffin, etc .; low stress components such as silicone oil and silicone rubber; various additives such as antioxidants can be blended.

本発明の顆粒状の半導体封止用エポキシ樹脂組成物を得る方法は特に限定するものではないが、例えば、複数の小孔を有する円筒状外周部と円盤状の底面から構成される回転子の内側に、溶融混練されたエポキシ樹脂組成物を供給し、そのエポキシ樹脂組成物を、前記回転子を回転させて得られる遠心力によって前記小孔を通過させて得る方法(以下、「遠心製粉法」と称す。)で、得ることができる。遠心製粉法において、溶融混練されたエポキシ樹脂組成物を回転子の内側に供給する手段として、冷媒を用いて冷却された2重管式円筒体を通して回転子の内側に供給されることが好ましい。これにより、溶融混練されたエポキシ樹脂組成物が通過する円筒体の内壁へ付着するのを防止することができる。また、遠心製粉法において、複数の小孔を有する円筒状外周部は、直接又は間接的加熱手段により温度調節されることができるようにしたものが好ましい。これにより、小孔を通過するエポキシ樹脂組成物の溶融粘度を調整することができ、円筒状外周部への樹脂付着や小孔の目詰まりを防ぐことができる。   The method for obtaining the granular epoxy resin composition for semiconductor encapsulation of the present invention is not particularly limited. For example, a rotor composed of a cylindrical outer peripheral portion having a plurality of small holes and a disc-shaped bottom surface is provided. A method (hereinafter referred to as “centrifugal milling method”) in which a melt-kneaded epoxy resin composition is supplied inside and the epoxy resin composition is obtained by passing through the small holes by centrifugal force obtained by rotating the rotor. "). In the centrifugal milling method, as a means for supplying the melt-kneaded epoxy resin composition to the inside of the rotor, it is preferably supplied to the inside of the rotor through a double-pipe cylindrical body cooled with a refrigerant. Thereby, it can prevent that the melt-kneaded epoxy resin composition adheres to the inner wall of the cylindrical body which passes. In the centrifugal milling method, it is preferable that the cylindrical outer peripheral portion having a plurality of small holes can be adjusted in temperature by direct or indirect heating means. Thereby, the melt viscosity of the epoxy resin composition passing through the small holes can be adjusted, and resin adhesion to the cylindrical outer peripheral portion and clogging of the small holes can be prevented.

また、本発明の顆粒状の半導体封止用エポキシ樹脂組成物を得る方法は、上記の遠心製粉法のほか、例えば、各原料成分をミキサーで予備混合後、ロール、ニーダー又は押出機等の混練機により加熱混練後、冷却、粉砕工程を経て粉砕物としたものを、篩を用いて粗粒と微紛の除去を行って得る方法(以下、「粉砕物篩分法」と称す。)や、各原料成分をミキサーで予備混合後、スクリュー先端部に小径を複数配置したダイを設置した押出機を用いて、加熱混練を行うとともに、ダイに配置された小孔からストランド状に押し出されてくる溶融樹脂をダイ面に略平行に摺動回転するカッターで切断して得る方法(以下、「ホットカット法」と称す。)等によっても得ることもできる。これらの製法の中でも、特に遠心製粉法により得られる顆粒状の半導体封止用エポキシ樹脂組成物を用いると、圧縮成形における秤量精度と搬送性が最も良好となり、圧縮成形時の歩留まりや半導体装置における品質を最も向上させることができるのでより好ましい。   In addition to the above-mentioned centrifugal milling method, the method for obtaining the granular epoxy resin composition for encapsulating a semiconductor of the present invention is, for example, premixing each raw material component with a mixer and then kneading with a roll, a kneader, an extruder, or the like. A method of obtaining a pulverized product after heating and kneading by a machine, followed by cooling and pulverizing steps, by removing coarse particles and fine powder using a sieve (hereinafter referred to as “pulverized product sieving method”), After each raw material component is premixed with a mixer, it is heated and kneaded using an extruder equipped with a die having a plurality of small diameters arranged at the tip of the screw, and extruded from a small hole arranged in the die. It can also be obtained by a method (hereinafter referred to as “hot cut method”) obtained by cutting the molten resin with a cutter that slides and rotates substantially parallel to the die surface. Among these production methods, the use of a granular semiconductor sealing epoxy resin composition obtained by centrifugal milling method provides the best weighing accuracy and transportability in compression molding, yield in compression molding and in semiconductor devices. Since quality can be improved most, it is more preferable.

次に本発明の顆粒状の半導体封止用エポキシ樹脂組成物を得るための製法の一例である遠心製粉法について、図面を用いてより詳細に説明する。図1に半導体封止用エポキシ樹脂組成物の顆粒を得るための樹脂組成物の溶融混練から顆粒捕集までの一実施例の概略図、図2に回転子及び回転子の円筒状外周部を加熱するための励磁コイルの一実施例の断面図、図3に溶融混練された樹脂組成物を回転子に供給する2重管式円筒体の一実施例の断面図を示す。   Next, the centrifugal milling method, which is an example of the production method for obtaining the granular epoxy resin composition for semiconductor encapsulation of the present invention, will be described in detail with reference to the drawings. FIG. 1 is a schematic view of an embodiment from melt kneading to granule collection of a resin composition for obtaining granules of an epoxy resin composition for semiconductor encapsulation, and FIG. 2 shows a rotor and a cylindrical outer peripheral portion of the rotor. FIG. 3 shows a cross-sectional view of an embodiment of an exciting coil for heating, and FIG. 3 shows a cross-sectional view of an embodiment of a double-pipe cylinder that supplies a melted and kneaded resin composition to a rotor.

二軸押出機9で溶融混練されたエポキシ樹脂組成物は、内壁と外壁の間に冷媒を通し冷却された2重管式円筒体5を通して回転子1の内側に供給される。この時、2重管式円筒体5は、溶融混練されたエポキシ樹脂組成物が2重管式円筒体5の壁に付着しないよう、冷媒を用いて冷却されていることが好ましい。2重管式円筒体5を通して、エポキシ樹脂組成物を回転子1に供給することにより、エポキシ樹脂組成物が連続した糸状で供給された場合でもあっても、回転子1が高速回転している影響によりエポキシ樹脂組成物が回転子1から飛び出すことなく安定した供給が可能となる。   The epoxy resin composition melt-kneaded by the twin-screw extruder 9 is supplied to the inside of the rotor 1 through a double-pipe cylindrical body 5 cooled by passing a refrigerant between the inner wall and the outer wall. At this time, the double-pipe cylinder 5 is preferably cooled using a refrigerant so that the melt-kneaded epoxy resin composition does not adhere to the wall of the double-pipe cylinder 5. By supplying the epoxy resin composition to the rotor 1 through the double-pipe cylindrical body 5, the rotor 1 rotates at a high speed even when the epoxy resin composition is supplied in a continuous thread form. Due to the influence, the epoxy resin composition can be stably supplied without jumping out of the rotor 1.

回転子1はモーター10と接続されており、任意の回転数で回転させることができる。回転子1の外周上に設置した複数の小孔を有する磁性材料3で形成された円筒状外周部2は、その近傍に備えられた励磁コイル4に交流電源発生装置6により発生させた交流電源を通電させることによって発生する交番磁束の通過に伴う、うず電流損やヒステリシス損により加熱される。なお、この磁性材料3としては、例えば鉄材や珪素鋼等が挙げられ、1種類又は2種類以上の磁性材料3を複合して使用することができる。複数の小孔を有する円筒状外周部2は、磁性材料3に限定されるものではなく、たとえば熱伝導率の高い非磁性材料をもって形成され、その上下に磁性材料3を備えることにより、加熱された磁性材料3を熱源として熱伝導により円筒状外周部2を加熱することもできる。非磁性材料としては銅やアルミ等が挙げられ、1種類又は2種類以上の非磁性材料を複合して使用することができる。エポキシ樹脂組成物は回転子1の内側に供給された後、モーター10により回転子1を回転させて得られる遠心力によって、加熱された円筒状外周部2に飛行移動する。   The rotor 1 is connected to a motor 10 and can be rotated at an arbitrary number of rotations. A cylindrical outer peripheral portion 2 formed of a magnetic material 3 having a plurality of small holes installed on the outer periphery of the rotor 1 has an AC power source generated by an AC power generator 6 in an excitation coil 4 provided in the vicinity thereof. Is heated by the eddy current loss and hysteresis loss accompanying the passage of the alternating magnetic flux generated by energizing. In addition, as this magnetic material 3, an iron material, silicon steel, etc. are mentioned, for example, One type or two or more types of magnetic materials 3 can be combined and used. The cylindrical outer peripheral portion 2 having a plurality of small holes is not limited to the magnetic material 3, and is formed of, for example, a nonmagnetic material having high thermal conductivity, and is heated by providing the magnetic material 3 above and below it. The cylindrical outer peripheral portion 2 can be heated by heat conduction using the magnetic material 3 as a heat source. Examples of the nonmagnetic material include copper and aluminum, and one type or two or more types of nonmagnetic materials can be used in combination. After the epoxy resin composition is supplied to the inside of the rotor 1, the epoxy resin composition flies to the heated cylindrical outer peripheral portion 2 by centrifugal force obtained by rotating the rotor 1 by the motor 10.

加熱された複数の小孔を有する円筒状外周部2に接触したエポキシ樹脂組成物は、溶融粘度が上昇することなく、容易に円筒状外周部2の小孔を通過し吐出される。加熱する温度は、適用するエポキシ樹脂組成物の特性により任意に設定することができる。一般的には、加熱温度を上げすぎるとエポキシ樹脂組成物の硬化が進み、特性の劣化や円筒状外周部2の小孔に詰まることがあるが、適切な温度条件の場合においては、樹脂組成物と円筒状外周部2の接触時間が極めて短いために特性への影響は極めて少ない。また、複数の小孔を有する円筒状外周部2は均一に加熱されているため、局所的な特性の変化は極めて少ない。また、円筒状外周部2の複数の小孔は、使用する樹脂組成物の性状や顆粒の粒度分布に合わせ、孔径を任意に調整できる。   The epoxy resin composition in contact with the heated cylindrical outer peripheral portion 2 having a plurality of small holes easily passes through the small holes of the cylindrical outer peripheral portion 2 and is discharged without increasing the melt viscosity. The heating temperature can be arbitrarily set depending on the characteristics of the epoxy resin composition to be applied. In general, if the heating temperature is raised too much, the epoxy resin composition is hardened and may deteriorate in characteristics or clog the small holes in the cylindrical outer peripheral portion 2. However, under appropriate temperature conditions, the resin composition Since the contact time between the object and the cylindrical outer peripheral portion 2 is extremely short, the influence on the characteristics is extremely small. Further, since the cylindrical outer peripheral portion 2 having a plurality of small holes is heated uniformly, there is very little local change in characteristics. Further, the plurality of small holes in the cylindrical outer peripheral portion 2 can arbitrarily adjust the hole diameter in accordance with the properties of the resin composition to be used and the particle size distribution of the granules.

円筒状外周部2の小孔を通過し吐出された顆粒状の樹脂組成物は、例えば、回転子1の周囲に設置した外槽8で捕集される。外槽8は顆粒状のエポキシ樹脂組成物が内壁へ付着したり、顆粒状のエポキシ樹脂組成物同士の融着を防止するために、円筒状外周部2の小孔を通過して飛行してくる顆粒状のエポキシ樹脂組成物が衝突する衝突面が、顆粒状のエポキシ樹脂組成物の飛行方向に対して10〜80度、好ましくは25〜65度の傾斜をもって設置されていることが好ましい。エポキシ樹脂組成物の飛行方向に対する衝突面の傾斜が上記上限値以下であると、顆粒状のエポキシ樹脂組成物の衝突エネルギーを充分分散させることができ、壁面への付着を生じる恐れが少ない。また、エポキシ樹脂組成物の飛行方向に対する衝突面の傾斜が上記下限値以上であると、顆粒状のエポキシ樹脂組成物の飛行速度を充分に減少させることができるため、外槽壁面に2次衝突した場合でもその外装壁面に付着する恐れが少ない。   The granular resin composition discharged through the small holes in the cylindrical outer peripheral portion 2 is collected, for example, in an outer tub 8 installed around the rotor 1. The outer tub 8 flies through a small hole in the cylindrical outer peripheral portion 2 in order to prevent the granular epoxy resin composition from adhering to the inner wall and preventing the fusion between the granular epoxy resin compositions. It is preferable that the collision surface with which the granular epoxy resin composition collides is installed with an inclination of 10 to 80 degrees, preferably 25 to 65 degrees with respect to the flight direction of the granular epoxy resin composition. When the inclination of the collision surface with respect to the flight direction of the epoxy resin composition is not more than the above upper limit value, the collision energy of the granular epoxy resin composition can be sufficiently dispersed, and there is little possibility of causing adhesion to the wall surface. Moreover, since the flight speed of a granular epoxy resin composition can fully be reduced when the inclination of the collision surface with respect to the flight direction of an epoxy resin composition is more than the said lower limit, secondary collision with the outer tank wall surface is possible. Even if it does, there is little fear of adhering to the exterior wall surface.

また、顆粒状のエポキシ樹脂組成物が衝突する衝突面の温度が高くなると、顆粒状のエポキシ樹脂組成物が付着しやすくなるため、衝突面外周には冷却ジャケット7を設けて、衝突面を冷却することが好ましい。外槽8の内径は、顆粒状のエポキシ樹脂組成物が充分に冷却され、顆粒状のエポキシ樹脂組成物の内壁への付着や、顆粒状のエポキシ樹脂組成物同士の融着が生じない程度の大きさとすることが望ましい。一般には、回転子1の回転により空気の流れが生じ、冷却効果が得られるが、必要に応じて冷風を導入しても良い。外槽8の大きさは処理する樹脂量にもよるが、例えば回転子1の直径が20cmの場合、外槽8の内径は100cm程度あれば付着や融着を防ぐことができる。   In addition, when the temperature of the collision surface on which the granular epoxy resin composition collides increases, the granular epoxy resin composition tends to adhere, so a cooling jacket 7 is provided on the outer periphery of the collision surface to cool the collision surface. It is preferable to do. The inner diameter of the outer tub 8 is such that the granular epoxy resin composition is sufficiently cooled so that adhesion of the granular epoxy resin composition to the inner wall and fusion between the granular epoxy resin compositions do not occur. The size is desirable. In general, an air flow is generated by the rotation of the rotor 1 and a cooling effect is obtained, but cold air may be introduced as necessary. Although the size of the outer tub 8 depends on the amount of resin to be processed, for example, when the diameter of the rotor 1 is 20 cm, adhesion and fusion can be prevented if the inner diameter of the outer tub 8 is about 100 cm.

本発明を実施例により更に詳しく説明するが、これらの実施例に限定されるものではない。
<半導体封止用エポキシ樹脂組成物の配合(重量部)>
・クレゾールノボラック型エポキシ樹脂 8.0重量部
・臭素化エポキシ樹脂 2.0重量部
・フェノールノボラック樹脂 4.0重量部
・硬化剤(2−メチルイミダゾール) 0.3重量部
・無機充填剤(シリカ) 84.0重量部
・カルナバワックス 0.1重量部
・低分子量ポリエチレン 0.1重量部
・カーボンブラック 0.3重量部
・カップリング剤 0.2重量部
・三酸化アンチモン 1.0重量部
<溶融混練されたエポキシ樹脂組成物の準備>
上記配合の半導体封止用エポキシ樹脂組成物の原材料をスーパーミキサーにより5分間粉砕混合したのち、この混合原料を図1に示す直径65mmのシリンダー内径を持つ同方向回転二軸押出機9にてスクリュー回転数30RPM、110℃の樹脂温度で溶融混練することで溶融混練されたエポキシ樹脂組成物を準備した。
The present invention will be described in more detail with reference to examples. However, the present invention is not limited to these examples.
<Formulation of epoxy resin composition for semiconductor encapsulation (parts by weight)>
-Cresol novolac type epoxy resin 8.0 parts by weight-Brominated epoxy resin 2.0 parts by weight-Phenol novolac resin 4.0 parts by weight-Curing agent (2-methylimidazole) 0.3 part by weight-Inorganic filler (silica ) 84.0 parts by weight, carnauba wax 0.1 part by weight, low molecular weight polyethylene 0.1 part by weight, carbon black 0.3 part by weight, coupling agent 0.2 part by weight, antimony trioxide 1.0 part by weight Preparation of melt-kneaded epoxy resin composition>
The raw material of the epoxy resin composition for semiconductor encapsulation having the above composition is pulverized and mixed for 5 minutes by a super mixer, and then the mixed raw material is screwed in a co-rotating twin screw extruder 9 having a cylinder inner diameter of 65 mm shown in FIG. A melt-kneaded epoxy resin composition was prepared by melt-kneading at a rotation speed of 30 RPM and a resin temperature of 110 ° C.

<半導体封止用エポキシ樹脂組成物の製造>
実施例1
図1に示す円筒状外周部2の素材として孔径2.5mmの小孔を有している鉄製の打ち抜き金網を使用した。直径20cmの回転子1の外周上に円筒状に加工した高さ25mm、厚さ1.5mmの上記打ち抜き金網を取り付け、円筒状外周部2を形成した。上記回転子1を3000RPMで回転させ、円筒状外周部2を励磁コイルで115℃に加熱した。上記回転子1の回転数と、上記円筒状外周部2の温度が定常状態になった後、回転子1の上方より溶融混練されたエポキシ樹脂組成物を2kg/hrの割合で供給して、前記回転子1を回転させて得られる遠心力によって前記円筒状外周部2の複数の小孔を通過させることで、顆粒状の半導体封止用エポキシ樹脂組成物を得た。
<Manufacture of epoxy resin composition for semiconductor encapsulation>
Example 1
As a material for the cylindrical outer peripheral portion 2 shown in FIG. 1, an iron punched wire net having a small hole with a hole diameter of 2.5 mm was used. The punched wire mesh having a height of 25 mm and a thickness of 1.5 mm was attached to the outer periphery of the rotor 1 having a diameter of 20 cm to form a cylindrical outer peripheral portion 2. The rotor 1 was rotated at 3000 RPM, and the cylindrical outer peripheral portion 2 was heated to 115 ° C. with an exciting coil. After the rotational speed of the rotor 1 and the temperature of the cylindrical outer peripheral portion 2 are in a steady state, an epoxy resin composition melt-kneaded from above the rotor 1 is supplied at a rate of 2 kg / hr, Granular epoxy resin composition for semiconductor encapsulation was obtained by passing through the plurality of small holes in the cylindrical outer peripheral portion 2 by centrifugal force obtained by rotating the rotor 1.

比較例1
溶融混練されたエポキシ樹脂組成物をクーリングベルトで冷却後、ハンマーミルにて粗粉砕を行い平均粒径800μm、粒度分布40μm〜10mmの粗粉砕物を得た。これを更にパルペライザーにて4000回転で粉砕して、半導体封止用エポキシ樹脂組成物を得た。
Comparative Example 1
The melt-kneaded epoxy resin composition was cooled with a cooling belt and then coarsely pulverized with a hammer mill to obtain a coarsely pulverized product having an average particle size of 800 μm and a particle size distribution of 40 μm to 10 mm. This was further pulverized with a pulverizer at 4000 rpm to obtain an epoxy resin composition for semiconductor encapsulation.

実施例並びに比較例における半導体封止用エポキシ樹脂脂組成物を下記の方法で評価し、その評価結果を表1、表2に示した。   The epoxy resin fat compositions for semiconductor encapsulation in Examples and Comparative Examples were evaluated by the following methods, and the evaluation results are shown in Tables 1 and 2.

評価方法
106μm未満の微粉量及び2mm以上の粗粒量
ロータップ振動機に備え付けた目開き2.00mm及び0.106mmのJIS標準篩を用いて決定した。これらの篩を20分間に亘って振動させながら40gの試料を篩に通して分級して各篩に残る粒状体や粒体の重量を計測した。このように計測した重量を分級前の試料の重量を基準にして粒径が106μm未満の微粉量及び2mm以上の粗粒量の重量比を算出した。
Evaluation method Fine powder amount of less than 106 μm and coarse particle amount of 2 mm or more It was determined using JIS standard sieves with openings of 2.00 mm and 0.106 mm provided in a low tap vibrator. While shaking these sieves for 20 minutes, 40 g of the sample was passed through the sieve and classified, and the weight of the granules and granules remaining on each sieve was measured. Based on the weight measured in this way, the weight ratio of the amount of fine powder having a particle size of less than 106 μm and the amount of coarse particles having a particle size of 2 mm or more was calculated based on the weight of the sample before classification.

固めかさ密度
パウダーテスター(ホソカワミクロン株式会社製)を用い、内径50.46mm、深さ50mm、容積100cmの測定容器の上部に円筒を取り付けたものにエポキシ樹脂組成物の試料をゆるやかに入れた後、180回のタッピングを行い、その後、上部円筒を取り除き、測定容器上部に堆積した試料をブレードですりきり、測定容器に充填された試料の重量を測定することにより求めた。
After the sample of the epoxy resin composition was gently put into a solid vessel with a powder tester (manufactured by Hosokawa Micron Co., Ltd.) and a cylinder attached to the top of a measuring container having an inner diameter of 50.46 mm, a depth of 50 mm, and a volume of 100 cm 3 Then, tapping was performed 180 times, and then the upper cylinder was removed, the sample deposited on the upper part of the measurement container was ground with a blade, and the weight of the sample filled in the measurement container was measured.

搬送経路上で固結・付着
エポキシ樹脂組成物の試料100gを振動フィーダー(450mm長×55mm幅)のホッパーに供給した後、搬送量が18g/分となるように振動の強さを調整し、10g搬送した後、3分停止を繰返し100g全量搬送した。搬送後に、試料同士の固結や振動フィーダーへの付着状況を観察しその有無を求めた。
秤量精度
エポキシ樹脂組成物の試料100gを振動フィーダー(450mm長×55mm幅)のホッパーに供給した後、搬送量が18g/分となるように振動の強さを調整し、10g搬送した後、3分停止を繰返し100g全量搬送した時の、各10gを搬送するに要した時間を計測し、その平均値および標準偏差を求めた。
Consolidation / adhesion on the transport path After supplying 100 g of the epoxy resin composition sample to the hopper of the vibration feeder (450 mm length × 55 mm width), adjust the strength of vibration so that the transport amount is 18 g / min, After conveying 10 g, the stop was repeated for 3 minutes, and 100 g of the entire amount was conveyed. After transportation, the samples were consolidated and observed for adhesion to the vibration feeder to determine the presence or absence.
Weighing accuracy After supplying 100 g of the epoxy resin composition sample to the hopper of the vibration feeder (450 mm length × 55 mm width), adjusting the strength of vibration so that the conveyance amount becomes 18 g / min and conveying 10 g, 3 The time required to transport each 10 g when 100 g of the total amount was repeatedly transported was measured, and the average value and standard deviation were obtained.

Figure 2008303368
Figure 2008303368

Figure 2008303368
Figure 2008303368

上の表からも明らかなように、本発明の実施例では、固めかさ密度が適正な範囲であるため、所定量を搬送したときの所要時間のバラツキが小さく、搬送経路上での固結や付着を生じない良好な搬送性を示すことが判明した。すなわち、固結や付着の原因である微粉量が少ないために、搬送経路上でも固結や付着を生じることなく搬送することが可能である。また重量の大きな粗粒が少ないために搬送量のバラツキが小さく、なおかつ、固めかさ密度も適正な範囲であるため搬送中に固結やブリッジによる閉塞状態になりにくく、安定した搬送が可能であることが確認された。   As is clear from the above table, in the embodiment of the present invention, the hardness density is in an appropriate range, so the variation in the required time when a predetermined amount is transported is small, and the consolidation on the transport path is It has been found that it exhibits good transportability without causing adhesion. That is, since the amount of fine powder that causes caking and adhesion is small, it is possible to carry the material without causing caking or adhesion on the conveyance path. In addition, since there are few coarse particles with large weight, the variation in the conveyance amount is small, and the hardness density is also in an appropriate range, so that it is difficult to be blocked by consolidation or bridge during conveyance, and stable conveyance is possible. It was confirmed.

本発明の顆粒状の半導体封止用エポキシ樹脂組成物は、圧縮成形時の歩留まりや半導体装置における品質を高めることができるため、圧縮成形により半導体素子を封止してなる半導体装置に好適に用いることができる。   Since the granular epoxy resin composition for semiconductor encapsulation of the present invention can improve the yield at the time of compression molding and the quality of the semiconductor device, it is suitably used for a semiconductor device in which a semiconductor element is sealed by compression molding. be able to.

本発明の顆粒状の半導体封止用エポキシ樹脂組成物を得るための、樹脂組成物の溶融混練から顆粒捕集までの一実施例の概略図を示す。The schematic of one Example from the melt-kneading of a resin composition to granule collection for obtaining the granular epoxy resin composition for semiconductor sealing of this invention is shown. 本発明に使用する回転子及び回転子の円筒状外周部を加熱するための励磁コイルの一実施例の断面図を示す。Sectional drawing of one Example of the exciting coil for heating the rotor used for this invention and the cylindrical outer peripheral part of a rotor is shown. 溶融混練された樹脂組成物を回転子に供給する2重管式円筒体の一実施例の断面図を示す。Sectional drawing of one Example of the double tube | pipe cylindrical body which supplies the resin composition melt-kneaded to a rotor is shown.

符号の説明Explanation of symbols

1 回転子
2 円筒状外周部
3 磁性材料
4 励磁コイル
5 2重管式円筒体
6 交流電源発生装置
7 冷却ジャケット
8 外槽
9 二軸押出機
10 モーター
DESCRIPTION OF SYMBOLS 1 Rotor 2 Cylindrical outer peripheral part 3 Magnetic material 4 Excitation coil 5 Double pipe | tube type cylindrical body 6 AC power supply device 7 Cooling jacket 8 Outer tank 9 Twin screw extruder 10 Motor

Claims (3)

圧縮成形により半導体素子を封止してなる半導体装置に用いる半導体封止用エポキシ樹脂組成物であって、
内径50.46mm、深さ50mm、容積100cmの測定容器を用いて測定した、固めかさ密度が0.8g/cm以上、1.1g/cm以下であることを特徴とする顆粒状の半導体封止用エポキシ樹脂組成物。
An epoxy resin composition for semiconductor sealing used in a semiconductor device formed by sealing a semiconductor element by compression molding,
Inner diameter 50.46Mm, depth 50 mm, was measured using a measurement reservoir volume 100 cm 3, compacted bulk density of 0.8 g / cm 3 or more, granular, characterized in that it is 1.1 g / cm 3 or less Epoxy resin composition for semiconductor encapsulation.
2mm以上の粗粒の割合が3重量%以下であり、106μm未満の微粉の割合が7重量%以下であることを特徴とする請求項1記載の顆粒状の半導体封止用エポキシ樹脂組成物。   2. The granular epoxy resin composition for semiconductor encapsulation according to claim 1, wherein the proportion of coarse particles of 2 mm or more is 3% by weight or less and the proportion of fine powder of less than 106 μm is 7% by weight or less. 請求項1又は請求項2記載の顆粒状の半導体封止用エポキシ樹脂組成物を用いて半導体素子を封止してなることを特徴とする半導体装置。   A semiconductor device comprising a semiconductor element sealed using the granular epoxy resin composition for sealing a semiconductor according to claim 1.
JP2007154572A 2007-06-11 2007-06-11 Epoxy resin composition for sealing semiconductor and semiconductor device using the same Withdrawn JP2008303368A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2008303367A (en) * 2007-06-11 2008-12-18 Sumitomo Bakelite Co Ltd Epoxy resin composition for sealing semiconductor and semiconductor device using the same
JP2010159400A (en) * 2008-12-10 2010-07-22 Sumitomo Bakelite Co Ltd Granulated epoxy resin composition for semiconductor encapsulation, semiconductor device using the same, and method for manufacturing the semiconductor device
TWI618733B (en) * 2015-06-30 2018-03-21 三星Sdi股份有限公司 Granular epoxy resin composition for encapsulating a semiconductor device, method of encapsulating a semiconductor device and semiconductor device encapsulated using the same

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2008303367A (en) * 2007-06-11 2008-12-18 Sumitomo Bakelite Co Ltd Epoxy resin composition for sealing semiconductor and semiconductor device using the same
JP2010159400A (en) * 2008-12-10 2010-07-22 Sumitomo Bakelite Co Ltd Granulated epoxy resin composition for semiconductor encapsulation, semiconductor device using the same, and method for manufacturing the semiconductor device
TWI618733B (en) * 2015-06-30 2018-03-21 三星Sdi股份有限公司 Granular epoxy resin composition for encapsulating a semiconductor device, method of encapsulating a semiconductor device and semiconductor device encapsulated using the same

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