JP2008289972A - Rustproof working method for long steel material - Google Patents

Rustproof working method for long steel material Download PDF

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JP2008289972A
JP2008289972A JP2007136447A JP2007136447A JP2008289972A JP 2008289972 A JP2008289972 A JP 2008289972A JP 2007136447 A JP2007136447 A JP 2007136447A JP 2007136447 A JP2007136447 A JP 2007136447A JP 2008289972 A JP2008289972 A JP 2008289972A
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steel
wire
long steel
raw material
rust
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Yasuo Taguchi
保男 田口
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TIMES ENGINEERING KK
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TIMES ENGINEERING KK
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Abstract

<P>PROBLEM TO BE SOLVED: To provide a method of manufacturing a rustproof coated steel twisted wire by which rustproof coating is carried out without causing pin holes, the rustproof treatment is carried out simultaneously with a heat treatment of a steel wire, a steel rod and a steel twisted wire and a gap between single wires in the steel twisted wire, that is, the internal gap of the steel twisted wire, is easily and surely filled. <P>SOLUTION: The long steel material such as the steel wire or the steel rod is subjected to heat treatment such as bluing-and/or heat-stretching-treatment and after that, the long steel material in a heated state by the heat treatment is brought into contact with a powdery synthetic resin coating raw material comprising an ethylene-vinyl acetate copolymer (EVA), an ethylene-vinyl acetate copolymer saponified material (EVOH), an ethylene-methacrylate copolymer (EMAA), an ionomer resin, a thermoplastic resin having a polar group such as ethylene ethyl acrylate or the like or fluororesin, and coated with the coating raw material melted by the heat of the heat treatment of the long steel material on the outer peripheral surface and then cooled to solidify the melted and deposited coating raw material. <P>COPYRIGHT: (C)2009,JPO&INPIT

Description

本発明は、コンクリート補強鋼材である鋼線、鋼棒や、主としてプレストレストコンクリート(以下PCと記す)の応力導入や斜張橋等の吊り材、更には張弦梁の引張材などに使用する内部空隙が合成樹脂防錆材にて充填されている防錆被覆鋼撚線などの長尺鋼材に対して防錆被覆を施す長尺鋼材に対する防錆加工方法に関する。   The present invention has internal voids used for steel wires, steel rods, which are concrete reinforced steel materials, mainly for stress introduction of prestressed concrete (hereinafter referred to as PC), suspension materials such as cable-stayed bridges, and tension materials for tension strings. The present invention relates to a rust-proofing method for a long steel material that applies a rust-proof coating to a long steel material such as a rust-proof coated steel stranded wire filled with a synthetic resin rust-proof material.

従来、コンクリート補強鋼材である鉄筋や棒鋼、PC鋼棒等の防錆処理としては、エポキシなどの熱硬化性樹脂を使用した静電粉体塗装が使用されている。   Conventionally, electrostatic powder coating using a thermosetting resin such as epoxy has been used as a rust-proofing treatment for reinforcing bars, steel bars, PC steel bars, etc., which are concrete reinforced steel materials.

また、PC線材や張弦梁用の緊張用弦材等に用いられる防錆被覆鋼撚線は、鋼製の単素線からなる芯線の周りに複数の鋼製の単素線からなる側線を配し、それを撚線機により撚り合せて鋼撚線となすか、心線の回りに多数の単素線からなる中層線を1又は複数層状に撚り合せ、その外側に複数の単素線からなる外層線を撚り合せて鋼撚線となし、その製造に際しては、各鋼素線を撚り合せた後、鋼撚線を300℃〜350℃に加熱してブルーイング処理を施して鋼撚線の引張強さ、弾性限、疲労限等を改善したり、鋼撚線を300℃〜350℃程度に加熱しながら引張荷重を加えるなどして一定の永久歪を与え、その後冷却すること(所謂、ヒートストレッチング処理又はホットストレッチング処理)によりレラクセーションの低下を図ったりしている。   In addition, the rust-proof coated steel stranded wire used for tension wires for PC wires and string strings has multiple side wires made of single steel wire around the core wire made of single steel wire. , It is twisted by a twisting machine to make a steel stranded wire, or an intermediate layer consisting of a large number of single strands is twisted in one or more layers around the core wire, and it consists of a plurality of single strands on the outside The outer layer wire is twisted to form a steel stranded wire. In the production thereof, after twisting each steel wire, the steel stranded wire is heated to 300 ° C. to 350 ° C. and subjected to a blueing treatment to form a steel stranded wire. Improve the tensile strength, elastic limit, fatigue limit, etc., apply a tensile load while heating the steel stranded wire to about 300 ° C. to 350 ° C., etc., and then cool it (so-called Reduction of relaxation by heat stretching process or hot stretching process) It is.

この鋼撚線の、防錆被覆処理においては、製造された鋼撚線を200℃〜300℃程度に予備加熱し、それをクロスヘッド型の合成樹脂押出成形機に通し、鋼撚線の各単素線間の空隙に熱可塑性の合成樹脂材を充填するとともに、鋼撚線の外周を合成樹脂材で被覆する方法がある。
特開昭57−198211号公報 特許第2537457号公報
In the rust-proof coating treatment of this steel stranded wire, the manufactured steel stranded wire is preheated to about 200 ° C. to 300 ° C., and is passed through a crosshead type synthetic resin extrusion molding machine. There is a method in which a gap between single strands is filled with a thermoplastic synthetic resin material and the outer periphery of a steel stranded wire is covered with a synthetic resin material.
JP-A-57-198211 Japanese Patent No. 2537457

しかし、上述の如き従来の技術では、長尺鋼材のヒートストレッチングなどの熱処理と防錆被覆工程とを別の場所にて行う為、両作業場間で製品、即ち鋼撚線を輸送するのに費用がかかり、製品のコストアップの要因となっているという問題があり、また、作業するにあたり、鋼撚線のディスケール(錆落とし)処理を必ず施さなければならない等の問題があった。   However, in the conventional technology as described above, heat treatment such as heat stretching of a long steel material and rust prevention coating process are performed in different places, so that a product, that is, a steel stranded wire, is transported between both workplaces. There is a problem that it is expensive and causes an increase in the cost of the product. In addition, there is a problem that the steel stranded wire must be subjected to a descale (rust removal) treatment when working.

また、熱硬化性樹脂を使用して静電粉体塗装したものは、ピンホールが多く防錆処理が十分ではない場合が多く発生するという問題があった。   In addition, electrostatic powder coating using a thermosetting resin has a problem in that there are many cases where pinholes are large and rust prevention treatment is not sufficient.

また、鋼撚線の防錆処理にあっては、撚り加工後に単素線間の空隙内に防錆材を充填する作業を行っているため、十分な充填状態を得るには高度の技術を要し、完成品の歩留まりが悪くなって、コスト高とならざるを得ないという問題があった。   In addition, in the rust prevention treatment of steel stranded wire, since the work of filling the rust prevention material in the gaps between the single strands after twisting, advanced technology is required to obtain a sufficient filling state. In short, there is a problem that the yield of finished products deteriorates and the cost is inevitably high.

本発明はこのような従来の問題に鑑み、熱可塑性樹脂によってピンホールのない防錆被覆がなされ、また、鋼線、鋼棒及び鋼撚線の熱処理と同時に防錆加工ができ、また、鋼撚線にあっては単素線間の空隙、即ち鋼撚線内の内部空隙の充填が容易かつ確実におこなうことができ、歩留まりが良く、低コストで製造できる防錆被覆鋼撚線の製造方法の提供を目的としてなされたものである。   In view of such a conventional problem, the present invention has a rust-proof coating without a pinhole made of a thermoplastic resin, and can be rust-proofed simultaneously with the heat treatment of a steel wire, a steel rod and a steel stranded wire, For stranded wires, the space between single strands, that is, the internal space in the steel stranded wire, can be filled easily and reliably, and the production of rust-proof coated steel stranded wire with good yield and low cost It was made for the purpose of providing a method.

上述の如き従来の問題を解決し、初期の目的を達成するための請求項1に記載の発明の特徴は、鋼線、鋼棒等の長尺鋼材にブルーイング処理及び/又はヒートストレッチング処理等の熱処理を施した後、該熱処理によって加熱状態にある該長尺鋼材にエチレン酢酸ビニル共重合体(EVA)、エチレン酢酸ビニル共重合体ケン化物(EVOH)、エチレン−メタクリル酸共重合体(EMAA)、アイオノマー樹脂、エチレンエチルアクリルレート等の極性基を有する熱可塑性の樹脂又はフッソ樹脂からなる粉末合成樹脂塗装原料を接触させることにより、該塗装原料を長尺鋼材の前記熱処理の際の熱によって溶融させて外周面に被着させ、然る後冷却することにより前記長尺鋼材に溶融被着したに塗装原料を固化させることにある。   In order to solve the conventional problems as described above and achieve the initial object, the feature of the invention described in claim 1 is that a long steel material such as a steel wire or a steel bar is subjected to a blueing treatment and / or a heat stretching treatment. After the heat treatment such as the above, the long steel material heated by the heat treatment is subjected to ethylene vinyl acetate copolymer (EVA), ethylene vinyl acetate copolymer saponified product (EVOH), ethylene-methacrylic acid copolymer ( EMAA), ionomer resin, powder synthetic resin coating raw material made of a thermoplastic resin having a polar group such as ethylene ethyl acrylate or fluorine resin, and the coating raw material is heated during the heat treatment of the long steel material. In this case, the coating raw material is solidified after being melted and deposited on the long steel material by being melted and deposited on the outer peripheral surface.

請求項2に記載の発明の特徴は、前記請求項1の構成に加え、前記長尺鋼材が、PC鋼材であることにある。   The feature of the invention described in claim 2 is that, in addition to the configuration of claim 1, the long steel material is a PC steel material.

請求項3に記載の発明の特徴は、前記請求項1の構成に加え、前記長尺鋼材が、異型鋼棒であることにある。   The feature of the invention described in claim 3 is that, in addition to the structure of claim 1, the long steel material is a deformed steel bar.

請求項4に記載の発明の特徴は、前記請求項1〜3のいずれか1の請求項の構成に加え、前記粉末合成樹脂塗装原料の長尺鋼材に対する接触は、空気によって粉末状の塗装原料を浮遊させた粉末塗装原料浮遊槽内に、前記長尺鋼材を連続して通過させることによって行わせることにある。   According to a fourth aspect of the present invention, in addition to the configuration of any one of the first to third aspects, the contact of the powdered synthetic resin coating raw material with the long steel material is performed by a powdered coating raw material by air. The long steel material is continuously passed through the powder coating raw material floating tank in which the material is suspended.

請求項5に記載の発明の特徴は、前記請求項1〜3のいずれか1の請求項の構成に加え、前記粉末合成樹脂塗装原料の長尺鋼材に対する接触は、長尺鋼材をアースさせておき、これに静電気を帯電させた粉末状の塗装原料を吹き付けることにより静電引力により付着させることによって行わせることにある。   According to a fifth aspect of the present invention, in addition to the structure of any one of the first to third aspects, the contact of the powdered synthetic resin coating raw material with the long steel material is caused by grounding the long steel material. In addition, it is performed by spraying a powdery coating material charged with static electricity to the surface by electrostatic attraction.

請求項6に記載の発明の特徴は、心線の外周に側線を、又は心線の外周に1層又は複数層状に撚り合せ中層線の外側に外層線を拠り合せて鋼撚線となす撚り加工をなし、該鋼撚線に対してブルーイング処理及び/又はヒートストレッチング処理等の熱処理を施すとともに、前記鋼撚線を構成している各単素線間の空隙を防錆材で埋め、かつ前記鋼撚線の外周を防錆材で被覆する長尺鋼材に対する防錆加工方法において、前記該撚り加工時における撚り合せ位置に加熱溶融させた熱可塑性合成樹脂からなる防錆材を供給して該防錆材により前記鋼撚線の各単素線間の空隙を埋め、然る後該鋼撚線に対して前記熱処理を施した後、該熱処理によって加熱状態にある該鋼撚線にエチレン酢酸ビニル共重合体(EVA)、エチレン酢酸ビニル共重合体ケン化物(EVOH)、エチレン−メタクリル酸共重合体(EMAA)、アイオノマー樹脂、エチレンエチルアクリルレート等の極性基を有する熱可塑性の樹脂又はフッソ樹脂からなる粉末合成樹脂塗装原料を接触させることにより、該塗装原料を長尺鋼材の熱によって溶融させて外周面に被着させ、然る後冷却することにより前記長尺鋼材に溶融被着したに塗装原料を固化させることにある。   The invention according to claim 6 is characterized in that a side wire is wound around the outer periphery of the core wire, or one or more layers are twisted around the outer periphery of the core wire, and an outer layer wire is applied outside the middle layer wire to form a steel stranded wire. The steel stranded wire is processed and subjected to a heat treatment such as a blueing treatment and / or a heat stretching treatment, and a gap between each single strand constituting the steel stranded wire is filled with a rust preventive material. In addition, in the rust-proofing method for a long steel material in which the outer periphery of the steel stranded wire is coated with a rust-proofing material, a rust-proofing material comprising a thermoplastic synthetic resin heated and melted at the twisting position at the time of the twisting is supplied. Then, the space between the single strands of the steel stranded wire is filled with the rust preventive material, and then the steel stranded wire is heated by the heat treatment after being subjected to the heat treatment. Ethylene vinyl acetate copolymer (EVA), ethylene vinyl acetate copolymer By contacting a powdered synthetic resin coating raw material made of a thermoplastic resin or a fluororesin having a polar group such as a cyanide (EVOH), an ethylene-methacrylic acid copolymer (EMAA), an ionomer resin, or ethylene ethyl acrylate, The coating raw material is melted by the heat of the long steel material and deposited on the outer peripheral surface, and then cooled to solidify the coating raw material after being melted and deposited on the long steel material.

上述の如く、本発明においては、鋼線、鋼棒等の長尺鋼材にブルーイング処理及び/又はヒートストレッチング処理等の熱処理を施した後、該熱処理によって加熱状態にある該長尺鋼材に、エチレン酢酸ビニル共重合体(EVA)、エチレン酢酸ビニル共重合体ケン化物(EVOH)、エチレン−メタクリル酸共重合体(EMAA)、アイオノマー樹脂、エチレンエチルアクリルレート等の極性基を有する熱可塑性の樹脂又はフッソ樹脂からなる粉末合成樹脂塗装原料を接触させることにより、該塗装原料を長尺鋼材の前記熱処理の際の熱によって溶融させて外周面に被着させ、然る後冷却することにより前記長尺鋼材に溶融被着したに塗装原料を固化させるようにしたことにより、鋼材製造時の熱処理の熱を利用するため、経済的に、しかもさび落とし処理を施すことなく樹脂による防錆被覆ができ、また、長尺鋼材の外周に、曲げ加工やPC鋼材として設置した際においても、防錆に必要な厚さに塗装原料を溶融被着させることができ、より完全な防錆処理が歩留まりよくなされる。   As described above, in the present invention, the long steel material such as a steel wire and a steel rod is subjected to heat treatment such as brewing treatment and / or heat stretching treatment, and then the long steel material in a heated state by the heat treatment is used. Thermoplastics having polar groups such as ethylene vinyl acetate copolymer (EVA), saponified ethylene vinyl acetate copolymer (EVOH), ethylene-methacrylic acid copolymer (EMAA), ionomer resin, ethylene ethyl acrylate, etc. By bringing a powdered synthetic resin coating raw material made of resin or fluorine resin into contact, the coating raw material is melted by the heat during the heat treatment of the long steel material and deposited on the outer peripheral surface, and then cooled by the cooling Because the coating raw material is solidified after being melted and deposited on a long steel material, the heat of heat treatment during the manufacture of the steel material is used. Rust-proof coating with resin can be performed without rust removal treatment, and the coating raw material is melted and deposited to the thickness required for rust prevention even when installed on the outer periphery of long steel as bending or PC steel Therefore, a more complete rust prevention treatment can be performed with a high yield.

また、前記粉末合成樹脂塗装原料の長尺鋼材に対する接触は、空気によって粉末状の塗装原料を浮遊させた粉末塗装原料浮遊槽内に、前記長尺鋼材を連続して通過させることによって行わせることにより、連続して送られる熱処理後の長尺鋼材に対して効率よく樹脂層を被着させることができる。   Further, the contact of the powdered synthetic resin coating raw material with the long steel material is performed by continuously passing the long steel material through a powder coating raw material floating tank in which the powdered coating raw material is suspended by air. Thus, the resin layer can be efficiently applied to the long steel material after the heat treatment that is continuously fed.

更に、鋼撚線の撚り加工時における撚り合せ位置に加熱溶融させた熱可塑性合成樹脂からなる防錆材を供給して該防錆材により前記鋼撚線の各単素線間の空隙を埋め、然る後該鋼撚線に対して前記熱処理を施した後、該鋼撚線の外周を熱可塑性合成樹脂からなる防錆材にて被覆することとしたことにより、鋼撚線への加工と同時に防錆加工ができ、また、単素線間の空隙、即ち鋼撚線内の内部空隙の充填が容易かつ確実におこなうことができ、歩留まりが良く、低コストで製造できる。   Furthermore, a rust preventive material made of a thermoplastic synthetic resin heated and melted at a twisting position at the time of twisting of the steel stranded wire is supplied, and the space between the single strands of the steel stranded wire is filled with the rust preventive material. Then, after the heat treatment is applied to the steel stranded wire, the outer periphery of the steel stranded wire is covered with a rust preventive material made of a thermoplastic synthetic resin, thereby processing the steel stranded wire. At the same time, the rust-proofing can be performed, and the gaps between the single strands, that is, the internal gaps in the steel stranded wires can be filled easily and reliably, and the yield can be improved and the production can be performed at low cost.

また、前記撚り加工における単素線の撚り合せ位置の外周を熱可塑性樹脂が供給される容器にて囲み、該容器内に加熱溶融させた前記熱可塑性樹脂を供給することによって前記各単素線間の空隙を鋼撚線の撚り加工時に加熱溶融した熱可塑性合成樹脂からなる防錆材で埋めるようにすることにより、鋼撚線内部の空間を容易かつ的確に防錆材で埋めることができる。   Further, each single strand is provided by surrounding the outer periphery of the twisted position of the single strands in the twisting process with a container to which a thermoplastic resin is supplied, and supplying the thermoplastic resin heated and melted in the container. By filling the gap between them with a rust preventive material made of thermoplastic synthetic resin that is heated and melted during the twisting process of the steel stranded wire, the space inside the steel stranded wire can be filled with the rust preventive material easily and accurately. .

更に、熱処理の後に、該処理による鋼撚線の加熱状態が維持されている間に、該鋼撚線をクロスヘッド型の合成樹脂押出成形機に通してその外周を熱可塑性合成樹脂からなる防錆材にて被覆することにより、従来行っていた被覆工程の前処理としての加熱作業が不要になり、コストが削減される。   Further, after the heat treatment, while the heated state of the steel stranded wire by the treatment is maintained, the steel stranded wire is passed through a crosshead type synthetic resin extrusion molding machine and the outer periphery thereof is made of a thermoplastic synthetic resin. By coating with a rust material, the heating work as a pretreatment of the conventional coating process becomes unnecessary, and the cost is reduced.

また、前記熱処理後に、該熱処理による鋼撚線の加熱状態が維持されている間に、該鋼撚線を熱可塑性合成樹脂粉体層内に通すことによって該粉体を鋼撚線外周に被着させる粉体塗装方式によって鋼撚線外周を被覆することにより、塗装のための装置が簡略化される。   In addition, after the heat treatment, while the heated state of the steel stranded wire by the heat treatment is maintained, the steel stranded wire is passed through the thermoplastic synthetic resin powder layer to cover the powder around the steel stranded wire. By coating the outer periphery of the steel stranded wire by the powder coating method to be applied, the apparatus for coating is simplified.

更に、防錆材としてエチレン酢酸ビニル共重合体(EVA)、エチレン酢酸ビニル共重合体ケン化物(EVOH)、エチレン−メタクリル酸共重合体(EMAA)、アイオノマー樹脂、エチレンエチルアクリルレート等の極性基を有する熱可塑性の樹脂又はフッソ樹脂からなる粉末合成樹脂塗装原料を使用することにより、防錆材の固化後において鋼撚線の変形に対する追随性が良くなって剥れにくくなり、使用時における作業性がよく、耐久性が向上する。   Furthermore, polar groups such as ethylene vinyl acetate copolymer (EVA), ethylene vinyl acetate copolymer saponified product (EVOH), ethylene-methacrylic acid copolymer (EMAA), ionomer resin, ethylene ethyl acrylate and the like as rust preventive materials. By using a powder synthetic resin coating raw material made of a thermoplastic resin or a fluororesin having a good resistance to deformation of the steel stranded wire after solidification of the rust preventive material, it becomes difficult to peel off and work in use Good durability and improved durability.

次に本発明の実施の形態を図面について説明する。   Next, embodiments of the present invention will be described with reference to the drawings.

図1は本発明の第一実施例の概略構成を示しており、更に詳しくは、単素線である心線1の周囲に、同じく単素線である側線2を一重配置により合せた鋼撚線3、例えば通常の防錆を施さない7本撚り鋼撚線3に対して、図7に示すように、鋼撚線3内部単素線間の空隙(以下内部空隙)4を内部充填防錆材5によって埋めるとともに、外周を外部被覆防錆材6によって被覆した防錆被覆鋼撚線7を製造するための全体の概略構成を示している。   FIG. 1 shows a schematic configuration of a first embodiment of the present invention, and more specifically, a steel twist in which side wires 2 which are also single strands are aligned around a core wire 1 which is a single strand by a single arrangement. As shown in FIG. 7, a space between the single strands of the steel stranded wire 3 (hereinafter referred to as an internal space) 4 is internally filled and prevented with respect to the wire 3, for example, a seven-stranded steel stranded wire 3 not subjected to normal rust prevention. An overall schematic configuration for producing a rust-proof coated steel stranded wire 7 that is filled with a rust material 5 and whose outer periphery is coated with an external coating rust-proof material 6 is shown.

この実施例において使用する防錆材は、外部被覆防錆材としてエチレン酢酸ビニル共重合体(EVA)、エチレン酢酸ビニル共重合体ケン化物(EVOH)、エチレン−メタクリル酸共重合体(EMAA)、アイオノマー樹脂、エチレンエチルアクリルレート等の極性基を有する熱可塑性の樹脂又はフッソ樹脂からなる粉末合成樹脂塗装原料を使用する。また、内部充填防錆材5としてはこの他にポリエチレンなども使用できる。   The rust preventive material used in this example is an ethylene vinyl acetate copolymer (EVA), an ethylene vinyl acetate copolymer saponified product (EVOH), an ethylene-methacrylic acid copolymer (EMAA) as an outer coating rust preventive material, A powder synthetic resin coating raw material made of a thermoplastic resin having a polar group such as an ionomer resin or ethylene ethyl acrylate or a fluorine resin is used. In addition, polyethylene or the like can also be used as the internal filling anticorrosive material 5.

図1において、符号10は鋼線撚り加工機である。この加工機は機台11の水平支軸12を中心に回転駆動される回転盤13を有し、この回転盤13の前面には撚り合せ本数分の撚り線用リール14が設けられ、これに予め側線2が巻き付けられている。また回転盤13の中心には貫通孔が開口されており、その中心部分に心線1が通されるようになっている。心線1は、心線用リール15に予め巻き付けられている。そして、心線1を中心線として移動させつつ回転盤13を旋回させることによって心線1の外周に側線2が螺旋状に撚り合せられるようになっている。   In FIG. 1, the code | symbol 10 is a steel wire twist processing machine. This processing machine has a rotating disk 13 that is driven to rotate about a horizontal support shaft 12 of a machine base 11, and a stranded wire reel 14 corresponding to the number of twists is provided on the front surface of the rotating disk 13. The side wire 2 is wound beforehand. Further, a through hole is opened at the center of the rotating disk 13, and the core wire 1 is passed through the central portion thereof. The core wire 1 is wound around a core wire reel 15 in advance. Then, the side wire 2 is spirally twisted around the outer periphery of the core wire 1 by turning the rotating disk 13 while moving the core wire 1 as a center line.

機台11には、心線1からなる中心線を加熱する加熱器17が固定されている。尚、この加熱器17は、心線11のリール15からの繰り出し位置後部にて、該心線が予備加熱される位置にあればよい。この予備加熱は内部充填防錆材5を各単素線に接着させるためのものであり、約200℃程度に加熱するようになっている。加熱器17としては、電熱線式加熱器の他高周波誘導加熱器が使用できる。   A heater 17 is fixed to the machine base 11 to heat the center line made of the core wire 1. In addition, this heater 17 should just exist in the position where this core wire is pre-heated in the rear part of the feeding position from the reel 15 of the core wire 11. This preheating is for bonding the internally filled anticorrosive material 5 to each single strand, and is heated to about 200 ° C. As the heater 17, a high-frequency induction heater can be used in addition to a heating wire heater.

心線1に対する側線2の撚り合せ位置には、内部充填防錆材5が供給され、撚り合せ加工と同時に鋼撚線内の内部空隙が防錆材5によって埋められるようになっている。即ち、撚り合せ位置を囲む配置に防錆材供給用の容器20を有しており、この容器20内に加熱溶融させた内部充填防錆材5を加圧注入することによって前記撚り合せ位置に防錆材を充満させ、これが単素線撚り合せ時に鋼撚線3内に巻き込まれ、内部空隙を埋めるようになっている。   The internally filled anticorrosive material 5 is supplied to the twisting position of the side wire 2 with respect to the core wire 1, and the internal voids in the steel twisted wire are filled with the anticorrosive material 5 simultaneously with the twisting process. That is, the container 20 for supplying a rust preventive material is disposed around the twisting position, and the inner filled rust preventive material 5 heated and melted in the container 20 is pressurized and injected to the twisting position. A rust preventive material is filled, and this is wound into the steel stranded wire 3 when the single strands are twisted together to fill the internal gap.

この容器20は、図2に示すように、内周面21が側線2の繰り出し角度に合せてテーパ状に形成されており、その内周面に開口させた防錆材供給口22より樹脂加熱溶融押し出し機23から加熱溶融された防錆材5が容器20内に加圧注入されるようになっている。尚、容器20は全体が電熱器29によって樹脂の所定の溶融温度が維持させるようになっている。   As shown in FIG. 2, the container 20 has an inner peripheral surface 21 formed in a taper shape in accordance with the feeding angle of the side line 2, and is heated by resin from a rust preventive material supply port 22 opened on the inner peripheral surface. The rust preventive material 5 heated and melted from the melt extruder 23 is pressurized and injected into the container 20. The container 20 is entirely maintained at a predetermined melting temperature of the resin by the electric heater 29.

容器20の背面は回転する蓋体24によって閉鎖され、その蓋体24には心線1及び側線2が通過する導入口25,26が開口されているとともにテーパ状をした先細り側の端部に撚り加工後の鋼撚線が通過する撚線通過孔27が貫通開口されている。この通過孔27内に鋼撚線3の外周形状に対応させたダイス28が回転可能に嵌合されており、鋼撚線3の外周に付着した内部充填防錆材5の殆どが除去されるようになっている。   The back surface of the container 20 is closed by a rotating lid body 24, and the lid body 24 has opening ports 25 and 26 through which the core wire 1 and the side wire 2 pass, and at the tapered tapered end portion. A stranded wire passage hole 27 through which the twisted steel stranded wire passes is opened. A die 28 corresponding to the outer peripheral shape of the steel stranded wire 3 is rotatably fitted in the passage hole 27, and most of the internally filled rust preventive material 5 attached to the outer periphery of the steel stranded wire 3 is removed. It is like that.

このようにして図6に示すように内部空隙を防錆材5で満たした状態に撚り加工された鋼撚線3は、次に加工歪を除去するための熱処理であるブルーイング炉30に通し、撚り加工による残留応力を除去する。このブルーイング炉30には誘導加熱炉が使用でき、図には詳示してないが内部に高周波電流を流す誘導子を有し、その誘導子の中心を鋼撚線3が通過するようになっている。   As shown in FIG. 6, the steel stranded wire 3 twisted in a state in which the internal space is filled with the rust preventive material 5 is then passed through a brewing furnace 30 which is a heat treatment for removing the processing strain. The residual stress due to twisting is removed. An induction heating furnace can be used as the brewing furnace 30. Although not shown in detail in the drawing, an inductor for passing a high-frequency current is provided therein, and the steel stranded wire 3 passes through the center of the inductor. ing.

ブルーイング炉30を通過した鋼撚線3は、次いでレラクゼーションを低下させるための熱処理であるヒートストレッチング装置31に送られる。このヒートストレッチング装置31は、一例として加熱炉32とその前後にあって鋼撚線3に所定の張力を付加する送り機構33a,33bとからなり、所定の張力を付加させつつ加熱し、後述の冷却処理を施すことによってレラクゼーション性能を向上させる。   The stranded steel wire 3 that has passed through the brewing furnace 30 is then sent to a heat stretching device 31 that is a heat treatment for reducing relaxation. The heat stretching device 31 includes, as an example, a heating furnace 32 and feed mechanisms 33a and 33b that are provided before and after the heating furnace 32 and apply a predetermined tension to the steel stranded wire 3. The relaxation performance is improved by performing the cooling process.

ヒートストレッチング処理が施された鋼撚線3を必要に応じてディスケール装置34にかけて表面の錆落しを行った後、鋼撚線温度が樹脂の被着に必要な温度(例えば250℃程度)より低くなる前に、該鋼撚線3の外周に防錆被覆を施す。この防錆被覆処理は、ヒートストレッチング処理における加熱炉32による加熱を利用して鋼撚線3の外周面に合成樹脂被覆を施すものであり、一例として図3に示す如き、流動浸漬式の粉体塗装装置35を使用する。   The steel stranded wire 3 that has been subjected to the heat stretching treatment is subjected to rust removal on the surface by applying to the descaling device 34 as necessary, and then the steel stranded wire temperature is a temperature required for resin deposition (for example, about 250 ° C.) Before becoming lower, a rust-proof coating is applied to the outer periphery of the steel stranded wire 3. This rust-proof coating treatment is to apply a synthetic resin coating to the outer peripheral surface of the steel stranded wire 3 by using the heating by the heating furnace 32 in the heat stretching treatment. As an example, as shown in FIG. A powder coating device 35 is used.

この粉体塗装装置35は、粉末合成樹脂塗装原料36を空気によって浮遊させる原料浮遊槽37を有している。この原料浮遊槽37は、底面に多数の噴気孔を有する底板38を有し、その底板下にエア導入室39を有し、該エア導入室39内にブロワー40からエアを導入させている。   This powder coating apparatus 35 has a raw material floating tank 37 for floating a powder synthetic resin coating raw material 36 by air. The raw material floating tank 37 has a bottom plate 38 having a large number of fumaroles on the bottom surface, an air introduction chamber 39 under the bottom plate, and air is introduced from the blower 40 into the air introduction chamber 39.

この原料浮遊槽37には、その中間高さ位置の互いに対向する壁面に、鋼撚線3を連続して通過させることができるように、長尺鋼材挿通孔41a,41bが開口されている。また、原料浮遊槽37の上部には、その内部に塗装原料36を供給するホッパー37aが備えられている。   In this raw material floating tank 37, long steel material insertion holes 41a and 41b are opened so that the steel stranded wire 3 can be continuously passed through the wall surfaces facing each other at the intermediate height position. In addition, a hopper 37 a for supplying the coating raw material 36 is provided in the upper part of the raw material floating tank 37.

そして、原料浮遊槽37内にエチレン酢酸ビニル共重合体(EVA)、エチレン酢酸ビニル共重合体ケン化物(EVOH)、エチレン−メタクリル酸共重合体(EMAA)、アイオノマー樹脂、エチレンエチルアクリルレート等の極性基を有する熱可塑性の樹脂又はフッソ樹脂からなる粉末合成樹脂からなる塗装原料36を収容し、底板38の噴気孔から空気を噴出させることにより、塗装原料36が浮き上がる。この状態で、長尺鋼材挿通孔41a,41bに、前述した熱処理によって加熱された鋼撚線3を通過させる。これによって浮遊している塗装原料36が鋼撚線3に接触し、該鋼撚線3の熱によって溶融されて表面に被着させる。   In the raw material floating tank 37, ethylene vinyl acetate copolymer (EVA), ethylene vinyl acetate copolymer saponified product (EVOH), ethylene-methacrylic acid copolymer (EMAA), ionomer resin, ethylene ethyl acrylate, etc. A coating raw material 36 made of a powdered synthetic resin made of a thermoplastic resin or a fluorine resin having a polar group is accommodated, and the coating raw material 36 is lifted by ejecting air from the air holes of the bottom plate 38. In this state, the steel stranded wire 3 heated by the heat treatment described above is passed through the long steel material insertion holes 41a and 41b. As a result, the floating coating raw material 36 comes into contact with the steel stranded wire 3 and is melted by the heat of the steel stranded wire 3 to adhere to the surface.

このようにして鋼撚線3の外周を外部被覆防錆材6で覆った後、冷却機42に通し、冷風によって全体を冷却し、防錆材5,6を固化させて防錆被覆鋼撚線となし、巻き取りリール43巻き取る。   After the outer periphery of the steel stranded wire 3 is thus covered with the externally coated anticorrosive material 6, it is passed through a cooler 42, the whole is cooled with cold air, and the anticorrosive materials 5 and 6 are solidified to prevent rustproof coated steel Take up the winding reel 43.

上述の実施例では、図6に示すように心線1の外周に一層の側線2を撚り合せた鋼撚線3からなる防錆被覆鋼撚線の製造について説明したが、例えば図8に示す如き、心線50の外側に中層線51を撚り合せ、その外周に外層線52を撚り合せ多層鋼撚線となし、各線材撚り加工毎に内部空隙を埋めるように内部充填防錆材5を充填し、その外周を図9に示すように外部被覆防錆材6で被覆した防錆被覆鋼撚線7を製造することができ、その製造に際しては、図4に示すように、中層線51、外層線52をそれぞれ撚り合せるための鋼線撚り加工機60,61に順次通して各層ごとに撚り合せと内部空隙への防錆材の充填とを前述と同様にして行うことにより多層鋼撚線からなる防錆被覆鋼撚線が成型できる。尚、各実施例を示す図において、同じ又は同等の部分には同一符号を付して重複説明を省略する。   In the above-described embodiment, the manufacture of the rust-proof coated steel stranded wire made of the steel stranded wire 3 in which one side wire 2 is twisted around the outer periphery of the core wire 1 as shown in FIG. 6 has been described. In this way, the middle layer wire 51 is twisted on the outer side of the core wire 50 and the outer layer wire 52 is twisted on the outer periphery thereof to form a multilayer steel twisted wire. As shown in FIG. 9, a rust-proof coated steel stranded wire 7 that is filled and coated with an outer-coated rust-proofing material 6 can be manufactured. As shown in FIG. The multi-layer steel twisting is performed by sequentially passing through the steel wire twisting machines 60 and 61 for twisting the outer layer wires 52, respectively, and twisting each layer and filling the internal voids in the same manner as described above. A rust-proof coated steel stranded wire made of wire can be molded. In the drawings showing the embodiments, the same or equivalent parts are denoted by the same reference numerals, and redundant description is omitted.

この他、図には示してないが、心線50と外層線52の中層線51が複数層に分けてより合せた多層鋼撚線についても、各層ごとの撚り加工時に同様にして内部空隙を内部充填防錆材で埋めるようにすることにより多層の防錆被覆鋼撚線が製造できる。   In addition to this, although not shown in the drawing, for the multilayer steel stranded wire in which the core wire 50 and the middle layer wire 51 of the outer layer wire 52 are divided into a plurality of layers, the internal voids are similarly formed during the twisting process for each layer. A multi-layer rust-proof coated steel stranded wire can be manufactured by filling with an internally filled rust-proof material.

この場合、鋼線撚り加工機60は前述した図2と同じ構造のものであり、鋼線撚り加工機61は、図5に示すように、撚り加工された鋼撚線3の外周に中層線51及び/又は外層線52を撚り合せるものである他、その構造は撚り加工機60と同様である。尚、撚り加工機61は、単素線である心線50の外周に中層線50を撚り合せた鋼撚線3を中心線とし、その外周に外層線52をより合わせるものであり、その撚り合せ位置直前の加熱器17は、心線と中層線からなる鋼撚線3を予備加熱するものである。   In this case, the steel wire twisting machine 60 has the same structure as that of FIG. 2 described above, and the steel wire twisting machine 61 has an intermediate layer wire on the outer periphery of the twisted steel twisted wire 3 as shown in FIG. 51 and / or the outer layer wire 52 are twisted together, and the structure is the same as that of the twisting machine 60. The twisting machine 61 uses a steel stranded wire 3 in which the middle layer wire 50 is twisted around the outer periphery of the core wire 50, which is a single strand, as the center line, and more closely matches the outer layer wire 52 around the outer periphery. The heater 17 immediately before the alignment position preheats the steel stranded wire 3 composed of the core wire and the middle layer wire.

次に、本発明を異型鋼棒などの単鋼棒及び単鋼線(撚線ではないもの)などの長尺鋼材に実施する場合について説明する。この場合においては、図10に示すように長尺鋼材ヒートストレッチング装置31に通した後、ディスケール装置34に通し、しかる後、前述した原料浮遊槽37に通し、冷却機42に通す。各装置は前述と同様であるため重複説明を省略する。   Next, a case where the present invention is applied to a long steel material such as a single steel bar such as a modified steel bar and a single steel wire (not a stranded wire) will be described. In this case, as shown in FIG. 10, after passing through the long steel material heat stretching device 31, it passes through the descaling device 34, and then passes through the raw material floating tank 37 and passes through the cooler 42. Since each device is the same as described above, a duplicate description is omitted.

尚、長尺鋼材が容易に曲がらない鋼棒である場合は、所定長さに切断したものを使用し、リールによる巻取りが可能な鋼線の場合は、リールに巻いた状態(図示せず)のものを順次伸ばして供給し、被覆冷却後にリールに巻きとる。   If the long steel material is a steel bar that does not easily bend, use a steel bar that has been cut to a predetermined length. If the steel wire can be wound by a reel, it is wound on a reel (not shown) ) Are sequentially stretched and supplied, and after the coating is cooled, it is wound on a reel.

上述した各実施例においては、熱処理であるブルーイング処理の後、同じく熱処理であるヒートストレッチング処理を施す場合を示したが、ヒートストレッチング処理を施す必要がない場合には、ブルーイング処理におけるブルーイング炉による加熱を利用し、該加熱後、鋼線に対する樹脂被着に必要な温度まで温度が降下した時点で外部被覆防錆材による被覆処理を行う。また、熱処理としては、上述のほか、一様伸び率を改善するための熱処理等、鋼線の加工及び所望の品質を発現させるための各種の熱処理を含む。   In each of the above-described embodiments, the case where the heat stretching process, which is also a heat treatment, is performed after the blueing process, which is a heat treatment, is shown. Heating by a bluing furnace is used, and after the heating, when the temperature drops to a temperature required for resin deposition on the steel wire, coating with an external coating rust preventive material is performed. In addition to the above, the heat treatment includes various heat treatments for processing the steel wire and developing desired quality such as heat treatment for improving the uniform elongation.

更に、上記ディスケール装置34による錆落しは、必要な際に行うものであり、必ずしも必要ではない。このディスケール装置は上記の他、サンドブラストやショットピーニング加工によっても良い。   Further, the rust removal by the descaler 34 is performed when necessary and is not always necessary. In addition to the above, this descaling device may be sandblasting or shot peening.

また、上述した実施例では、前記粉末合成樹脂塗装原料の長尺鋼材に対する接触を、空気によって粉末状の塗装原料を浮遊させた粉末塗装原料浮遊槽内に、前記長尺鋼材を連続して通過させる所謂流動浸漬法による場合を示しているがが、この他、長尺鋼材をアースさせておき、これに静電気を帯電させた粉末状の塗装原料を吹き付けることにより静電引力により付着させる所謂静電吸着法によってもよい。   In the above-described embodiment, the long steel material is continuously passed through the powder coating raw material floating tank in which the powdered coating raw material is suspended by air in contact with the long steel material of the powder synthetic resin coating raw material. In addition to this, the so-called fluidized dipping method is used, but in addition to this, a long steel material is grounded, and a powdery coating material charged with static electricity is sprayed on the long steel material, so that it is attached by electrostatic attraction. An electroadsorption method may be used.

本発明の第一実施例の加工工程図である。It is a processing-process figure of the 1st Example of this invention. 図1の加工工程における撚り加工機部分を示す断面図である。It is sectional drawing which shows the twist processing machine part in the process of FIG. 同、外周面の防錆被覆装置の一例を示す断面図である。It is sectional drawing which shows an example of the same antirust coating apparatus of an outer peripheral surface. 本発明の第二実施例の加工工程図である。It is a processing-process figure of the 2nd Example of this invention. 同上の中層線又は外層線の撚り加工装置の一例を示す断面図である。It is sectional drawing which shows an example of the twist processing apparatus of an intermediate | middle layer wire or an outer layer wire same as the above. 図1に示す例における内部空隙を防錆材で埋めた状態の鋼撚線を示す切断端面図である。It is a cut end view which shows the steel twisted wire of the state which filled the internal space | gap in the example shown in FIG. 1 with the antirust material. 同上の外周面防錆被覆工程後の防錆被覆鋼撚線の一例を示す切断端面図である。It is a cut end view showing an example of a rust-proof coated steel stranded wire after the same outer peripheral surface rust-proof coating step. 本発明の第二実施例における中層線及び外層線を撚り合せ加工した状態の鋼撚線の切断端面図である。It is a cut end view of the steel twisted wire of the state which twisted the middle layer wire and the outer layer wire in the second example of the present invention. 同上の外周面防錆被覆工程後の防錆被覆鋼撚線の一例を示す切断端面図である。It is a cut end view showing an example of a rust-proof coated steel stranded wire after the same outer peripheral surface rust-proof coating step. 本発明の第三実施例を示す加工工程図である。It is a processing-process figure which shows the 3rd Example of this invention.

符号の説明Explanation of symbols

1 心線
2 側線
3 鋼撚線
5 内部充填防錆材
6 外部被覆防錆材
7 防錆被覆鋼撚線
10 鋼線撚り加工機
11 機台
12 水平支軸
13 回転盤
14 撚り線用リール
15 心線用リール
17 加熱器
20 容器
21 内周面
22 防錆材供給口
23 樹脂加熱溶融押し出し機
24 蓋体
25.26 導入口
27 撚線通過孔
28 ダイス
29 電熱器
30 ブルーイング炉
31 ヒートストレッチング装置
32 加熱炉
33a,33b 送り機構
34 ディスケール装置
35 粉体塗装装置
36 粉末合成樹脂塗装原料
37 原料浮遊槽
38 底板
39 エア導入室
40 ブロワー
41a,41b 長尺鋼材挿通孔
42 冷却機
43 巻取りリール
50 心線
51 中層線
52 外層線
60,61 鋼線撚り加工機
DESCRIPTION OF SYMBOLS 1 Core wire 2 Side wire 3 Steel twisted wire 5 Internal filling antirust material 6 Outer covering antirust material 7 Anticorrosion coated steel twisted wire 10 Steel wire twisting machine 11 Machine stand 12 Horizontal support shaft 13 Turntable 14 Reel 15 for twisted wire Core wire reel 17 Heater 20 Container 21 Inner peripheral surface 22 Anticorrosive material supply port 23 Resin heating melt extruder 24 Lid 25.26 Inlet 27 Twisted wire passage hole 28 Die 29 Electric heater 30 Brewing furnace 31 Heat stretch Heating furnace 33a, 33b Feeding mechanism 34 Descale device 35 Powder coating device 36 Powder synthetic resin coating raw material 37 Raw material floating tank 38 Bottom plate 39 Air introduction chamber 40 Blower 41a, 41b Long steel material insertion hole 42 Cooler 43 winding Reel 50 Core wire 51 Middle layer wire 52 Outer layer wire 60, 61 Steel wire twisting machine

Claims (6)

鋼線、鋼棒等の長尺鋼材にブルーイング処理及び/又はヒートストレッチング処理等の熱処理を施した後、該熱処理によって加熱状態にある該長尺鋼材にエチレン酢酸ビニル共重合体(EVA)、エチレン酢酸ビニル共重合体ケン化物(EVOH)、エチレン−メタクリル酸共重合体(EMAA)、アイオノマー樹脂、エチレンエチルアクリルレート等の極性基を有する熱可塑性の樹脂又はフッソ樹脂からなる粉末合成樹脂塗装原料を接触させることにより、該塗装原料を長尺鋼材の前記熱処理の際の熱によって溶融させて外周面に被着させ、然る後冷却することにより前記長尺鋼材に溶融被着したに塗装原料を固化させることを特徴としてなる長尺鋼材に対する防錆加工方法。   After subjecting long steel materials such as steel wires and steel bars to heat treatment such as bluing treatment and / or heat stretching treatment, ethylene vinyl acetate copolymer (EVA) is applied to the long steel materials heated by the heat treatment. , Saponified ethylene vinyl acetate copolymer (EVOH), ethylene-methacrylic acid copolymer (EMAA), ionomer resin, powdered synthetic resin coating made of thermoplastic resin or fluorine resin having polar group such as ethylene ethyl acrylate When the raw material is brought into contact, the coating raw material is melted by the heat during the heat treatment of the long steel material, and is applied to the outer peripheral surface, and then is cooled and applied to the long steel material by being cooled. A rust-proofing method for a long steel material characterized by solidifying a raw material. 前記長尺鋼材が、PC鋼材である請求項1に記載の長尺鋼材に対する防錆加工方法。   The rust-proofing method for a long steel material according to claim 1, wherein the long steel material is a PC steel material. 前記長尺鋼材が、異型鋼棒である請求項1に記載の長尺鋼材に対する防錆加工方法。   The rust-proofing method for a long steel material according to claim 1, wherein the long steel material is a modified steel bar. 前記粉末合成樹脂塗装原料の長尺鋼材に対する接触は、空気によって粉末状の塗装原料を浮遊させた粉末塗装原料浮遊槽内に、前記長尺鋼材を連続して通過させることによって行わせる請求項1〜3のいずれか1に記載の長尺鋼材に対する防錆加工方法。   The contact of the powdered synthetic resin coating raw material with the long steel material is performed by continuously passing the long steel material through a powder coating raw material floating tank in which the powdery coating raw material is floated by air. The antirust processing method with respect to the long steel materials of any one of -3. 前記粉末合成樹脂塗装原料の長尺鋼材に対する接触は、長尺鋼材をアースさせておき、これに静電気を帯電させた粉末状の塗装原料を吹き付けることにより静電引力により付着させることによって行わせる請求項1〜3のいずれか1に記載の長尺鋼材に対する防錆加工方法。   The contact of the powdered synthetic resin coating raw material with the long steel material is performed by allowing the long steel material to be grounded, and by adhering the powdered coating raw material charged with static electricity to the steel material by electrostatic attraction. The rust prevention processing method with respect to the long steel material of any one of claim | item 1-3. 心線の外周に側線を、又は心線の外周に1層又は複数層状に撚り合せ中層線の外側に外層線を拠り合せて鋼撚線となす撚り加工をなし、該鋼撚線に対してブルーイング処理及び/又はヒートストレッチング処理等の熱処理を施すとともに、前記鋼撚線を構成している各単素線間の空隙を防錆材で埋め、かつ前記鋼撚線の外周を防錆材で被覆する長尺鋼材に対する防錆加工方法において、
前記該撚り加工時における撚り合せ位置に加熱溶融させた熱可塑性合成樹脂からなる防錆材を供給して該防錆材により前記鋼撚線の各単素線間の空隙を埋め、然る後該鋼撚線に対して前記熱処理を施した後、該熱処理によって加熱状態にある該鋼撚線にエチレン酢酸ビニル共重合体(EVA)、エチレン酢酸ビニル共重合体ケン化物(EVOH)、エチレン−メタクリル酸共重合体(EMAA)、アイオノマー樹脂、エチレンエチルアクリルレート等の極性基を有する熱可塑性の樹脂又はフッソ樹脂からなる粉末合成樹脂塗装原料を接触させることにより、該塗装原料を長尺鋼材の熱によって溶融させて外周面に被着させ、然る後冷却することにより前記長尺鋼材に溶融被着したに塗装原料を固化させることを特徴としてなる長尺鋼材に対する防錆加工方法。
Twist processing to make a steel stranded wire by laying one side or multiple layers on the outer periphery of the core wire or twisting the outer layer wire on the outer side of the middle layer wire to the outer periphery of the core wire, While performing heat treatment such as blueing treatment and / or heat stretching treatment, the space between each single strand constituting the steel stranded wire is filled with a rust-proofing material, and the outer periphery of the steel stranded wire is rust-proof In the rust prevention processing method for long steel materials covered with the material,
Supplying a rust preventive material composed of a thermoplastic synthetic resin heated and melted at the twisting position at the time of the twist processing to fill the gaps between the single strands of the steel stranded wire with the rust preventive material, and then The steel stranded wire is subjected to the heat treatment, and then the steel stranded wire heated by the heat treatment is subjected to ethylene vinyl acetate copolymer (EVA), ethylene vinyl acetate copolymer saponified product (EVOH), ethylene- By contacting a powdered synthetic resin coating raw material made of a thermoplastic resin having a polar group such as a methacrylic acid copolymer (EMAA), an ionomer resin, ethylene ethyl acrylate, or a fluorine resin, the coating raw material is made of a long steel material. For a long steel material characterized in that it is melted by heat and deposited on the outer peripheral surface, and then cooled, and then the coating raw material is solidified when melted and deposited on the long steel material. Rust processing method.
JP2007136447A 2007-05-23 2007-05-23 Rustproof working method for long steel material Pending JP2008289972A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101929219A (en) * 2010-08-20 2010-12-29 常州大学 Preparation method of thermoplastic resin cladding reinforcing steel bar structural material
JP2021159903A (en) * 2020-04-04 2021-10-11 株式会社川熱 Apparatus and method for manufacturing paint-coated steel material

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101929219A (en) * 2010-08-20 2010-12-29 常州大学 Preparation method of thermoplastic resin cladding reinforcing steel bar structural material
JP2021159903A (en) * 2020-04-04 2021-10-11 株式会社川熱 Apparatus and method for manufacturing paint-coated steel material

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