JP2008280220A - Granular nitrogen fertilizer - Google Patents

Granular nitrogen fertilizer Download PDF

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JP2008280220A
JP2008280220A JP2007127117A JP2007127117A JP2008280220A JP 2008280220 A JP2008280220 A JP 2008280220A JP 2007127117 A JP2007127117 A JP 2007127117A JP 2007127117 A JP2007127117 A JP 2007127117A JP 2008280220 A JP2008280220 A JP 2008280220A
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urea
nitrogen
granular
lime
nitrolime
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Takuji Oyama
卓爾 大山
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Niigata University NUC
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P60/00Technologies relating to agriculture, livestock or agroalimentary industries
    • Y02P60/20Reduction of greenhouse gas [GHG] emissions in agriculture, e.g. CO2
    • Y02P60/21Dinitrogen oxide [N2O], e.g. using aquaponics, hydroponics or efficiency measures

Abstract

<P>PROBLEM TO BE SOLVED: To provide a slow acting granular nitrogen fertilizer which is inexpensive, and can be easily manufactured. <P>SOLUTION: The granular nitrogen fertilizer containing nitrolime and urea is prepared by mixing nitrolime and urea by a ratio of a nitrogen amount of nitrolime to that of urea of 1:1-3 and granulating while spraying water. The granular nitrogen fertilizer having a homogeneous constituent and an average particle size of 2-6 mm prepared by granulating using a powdery nitrolime and a powdery urea, the granular nitrogen fertilizer composed of urea covered with nitrolime by granulating using the powdery nitrolime and the granular urea, and the granular nitrogen fertilizer composed of nitrolime covered with urea by granulating using the powdery urea and the granular nitrolime are provided. <P>COPYRIGHT: (C)2009,JPO&INPIT

Description

本発明は、緩効性の粒状窒素肥料に関する。   The present invention relates to a slow-acting granular nitrogen fertilizer.

緩孔性の窒素肥料は、速効性肥料の欠点を補うために開発されたものであり、これまで緩効性肥料としては、土壌中で分解されにくい化学形態の肥料である尿素‐アセトアルデヒド縮合物(CDU)、尿素‐イソブチルアルデヒド縮合物(IB)が使われてきた。   The slow-pouring nitrogen fertilizer was developed to compensate for the shortcomings of the fast-acting fertilizer. To date, the slow-acting fertilizer is a urea-acetaldehyde condensate that is a fertilizer with a chemical form that is difficult to decompose in soil. (CDU), urea-isobutyraldehyde condensate (IB) has been used.

また、近年、尿素を膜で被覆した被覆尿素が開発され、溶出時間が比較的厳密に制御できること、多量に与えても高濃度の肥料成分による障害を起こさないことから、作物栽培、園芸等に利用が広がっている。   In recent years, urea coated with urea has been developed as a membrane, and the elution time can be controlled relatively closely, and even if given in large amounts, it does not cause damage due to high-concentration fertilizer components. Use is spreading.

一方、石灰窒素は、20世紀初頭に開発された肥料であるが、硝酸化成の抑制効果を持つことから、石灰窒素の分解により生じた窒素がアンモニアのままとどまり、流亡や脱窒がおこりにくく長期間にわたり植物に利用される。   On the other hand, lime nitrogen is a fertilizer developed at the beginning of the 20th century, but because it has the effect of suppressing nitrification, the nitrogen produced by the decomposition of lime nitrogen remains ammonia, and it is difficult to run away and denitrify. Used for plants over a period of time.

しかしながら、上記の被覆尿素や石灰窒素は、尿素や硫安に比べて値段が数倍高いため、農家にとっては大きな経済的負担であった。   However, since the above-mentioned coated urea and lime nitrogen are several times more expensive than urea and ammonium sulfate, it was a great economic burden for farmers.

また、特許文献1には、尿素を用いて石灰窒素等を粒状化する方法が開示されている。
特開平7−157385号公報
Patent Document 1 discloses a method of granulating lime nitrogen or the like using urea.
JP-A-7-157385

しかし、この方法は、尿素を溶融状態として石灰窒素等と結合させた後に粒状化するものであって、原料混合物の摩擦熱を利用するために加圧と成形を同時に行うことができる成形機を用いることが必要とされ、また、尿素を溶融状態とするために成形機の温度管理等が必要となり、決して効率のよいものではなかった。   However, this method granulates urea after being combined with lime nitrogen or the like in a molten state, and a molding machine capable of simultaneously performing pressurization and molding in order to utilize the frictional heat of the raw material mixture. It was necessary to use it, and temperature control of the molding machine was required to make urea into a molten state, which was not efficient at all.

そこで、本発明は、安価で、かつ、簡単に製造することのできる、緩効性の粒状窒素肥料を提供することを目的とする。   Accordingly, an object of the present invention is to provide a slow-acting granular nitrogen fertilizer that is inexpensive and can be easily manufactured.

上記課題を解決するために鋭意検討した結果、石灰窒素と尿素の混合物に水を噴霧することによって、簡単に粒状窒素肥料が得られることを見出し、本発明に想到した。   As a result of intensive studies to solve the above problems, it was found that a granular nitrogen fertilizer can be easily obtained by spraying water on a mixture of lime nitrogen and urea, and the present invention has been conceived.

すなわち、本発明の粒状窒素肥料は、石灰窒素と尿素を含有した粒状窒素肥料であって、石灰窒素の窒素量と尿素の窒素量の比が1:1〜3となるように石灰窒素と尿素を混合し、水を噴霧しながら造粒されたものである。   That is, the granular nitrogen fertilizer of the present invention is a granular nitrogen fertilizer containing lime nitrogen and urea, and lime nitrogen and urea so that the ratio of the nitrogen amount of lime nitrogen and the nitrogen amount of urea is 1: 1-3. And granulated while spraying water.

本発明によれば、安価で、かつ、簡単に製造することのできる、緩効性の粒状窒素肥料を提供することができる。   According to the present invention, it is possible to provide a slow-acting granular nitrogen fertilizer that is inexpensive and can be easily manufactured.

本発明の粒状窒素肥料は、石灰窒素と尿素を含有した粒状窒素肥料であって、石灰窒素の窒素量と尿素の窒素量の比が1:1〜3となるように石灰窒素と尿素を混合し、水を噴霧しながら造粒されたものである。   The granular nitrogen fertilizer of the present invention is a granular nitrogen fertilizer containing lime nitrogen and urea, and lime nitrogen and urea are mixed so that the ratio of the nitrogen amount of lime nitrogen and the nitrogen amount of urea is 1: 1 to 3 And granulated while spraying water.

本発明の粒状窒素肥料は、石灰窒素と尿素を含有したものであり、石灰窒素のもつ硝化抑制作用によって、尿素や尿素の分解により生成したアンモニアの硝化が抑制される。したがって、流亡や脱窒がおこりにくく長期間にわたり植物に利用される。なお、本発明の粒状窒素肥料が含有する成分は石灰窒素と尿素に限定されず、例えば硫安などを含有していてもよい。   The granular nitrogen fertilizer of the present invention contains lime nitrogen and urea, and nitrification of ammonia produced by decomposition of urea and urea is suppressed by the nitrification inhibiting action of lime nitrogen. Therefore, runoff and denitrification hardly occur, and it is used for plants for a long time. In addition, the component which the granular nitrogen fertilizer of this invention contains is not limited to lime nitrogen and urea, For example, you may contain ammonium sulfate etc.

また、本発明の粒状窒素肥料は、石灰窒素の窒素量と尿素の窒素量の比が1:1〜3となるように石灰窒素と尿素を混合してなるものであり、高価な石灰窒素の使用量が抑えられるので、原料価格が安価である。   Moreover, the granular nitrogen fertilizer of the present invention is formed by mixing lime nitrogen and urea so that the ratio of the nitrogen amount of lime nitrogen and the nitrogen amount of urea is 1: 1 to 3, and is an expensive lime nitrogen. Since the amount used is reduced, the raw material price is low.

なお、石灰窒素の窒素量に対して尿素の窒素量が3倍を超える混合比とした場合には、石灰窒素のもつ硝化抑制作用が低くなる。また、石灰窒素の窒素量に対して尿素の窒素量が1倍未満となる混合比とした場合には、1:1で混合した場合と硝化抑制作用にほとんど差が見られない。したがって、石灰窒素の窒素量と尿素の窒素量の比が1:1〜3となるように石灰窒素と尿素を混合するのが好ましい。   In addition, when the nitrogen ratio of urea exceeds 3 times the nitrogen amount of lime nitrogen, the nitrification inhibiting action of lime nitrogen is reduced. In addition, when the mixing ratio is such that the nitrogen amount of urea is less than 1 times the nitrogen amount of lime nitrogen, there is almost no difference in the nitrification inhibitory effect from the case of mixing at 1: 1. Therefore, it is preferable to mix lime nitrogen and urea so that the ratio of the nitrogen amount of lime nitrogen and the nitrogen amount of urea is 1: 1 to 3.

また、本発明の粒状窒素肥料は、水を噴霧しながら造粒されたものであり、特別な結合剤を用いる必要がなく、既存のパン型造粒装置などを用いて簡単に造粒できるので、製造コストが抑えられる。   Further, the granular nitrogen fertilizer of the present invention is granulated while spraying water, and it is not necessary to use a special binder, and can be easily granulated using an existing bread type granulator. , Manufacturing costs can be reduced.

また、本発明の粒状窒素肥料は、尿素が石灰窒素で被覆されてなる。石灰窒素で被覆されることで尿素の溶出が抑制され、その結果、より長期間にわたって施肥効果が持続する。   The granular nitrogen fertilizer of the present invention is formed by coating urea with lime nitrogen. By covering with lime nitrogen, elution of urea is suppressed, and as a result, the fertilization effect is sustained over a longer period.

さらに、本発明の粒状窒素肥料は、石灰窒素が尿素で被覆されてなる。石灰窒素は毒性を有するが、これが無害な尿素で被覆されることで施肥作業者が石灰窒素に接触することが防止される。   Furthermore, the granular nitrogen fertilizer of the present invention is formed by coating lime nitrogen with urea. Lime nitrogen is toxic, but it is coated with harmless urea to prevent fertilizer workers from coming into contact with lime nitrogen.

つぎに、本発明の粒状窒素肥料の製造方法について説明する。   Below, the manufacturing method of the granular nitrogen fertilizer of this invention is demonstrated.

一実施形態において、粉末状の石灰窒素と粉末状の尿素が用いられる。図1に示すように、粉末石灰窒素1と粉末尿素2を石灰窒素の窒素量と尿素の窒素量の比が1:1〜3となるように混合して、粉末石灰窒素と粉末尿素の混合物3とし、これに水を噴霧しながら造粒することによって、粉末石灰窒素と粉末尿素から造粒した粒状肥料4が得られる。この実施形態によれば、機械や人力で施肥するのに適した、平均粒径2〜6mmの均一な成分を有する粒状窒素肥料が得られる。   In one embodiment, powdered lime nitrogen and powdered urea are used. As shown in FIG. 1, powdered lime nitrogen 1 and powdered urea 2 are mixed so that the ratio of nitrogen content of lime nitrogen and nitrogen content of urea is 1: 1 to 3, and a mixture of powdered lime nitrogen and powdered urea. The granulated fertilizer 4 granulated from powdered lime nitrogen and powdered urea is obtained by granulating while spraying water onto this. According to this embodiment, the granular nitrogen fertilizer which has a uniform component with an average particle diameter of 2-6 mm suitable for fertilizing with a machine or human power is obtained.

別の実施形態においては、粉末状の石灰窒素と粒状の尿素が用いられる。図2に示すように、粉末石灰窒素1と粒状尿素5を混合し、これに水を噴霧しながら造粒することによって、粒状尿素に粉末石灰窒素を被覆した粒状肥料6が得られる。この実施形態によれば、均一な粒径の粒状の尿素を用いることによって、均一な粒径を有する粒状窒素肥料が得られる。また、この実施形態において、粉末石灰窒素と粒状尿素の代わりに粒状石灰窒素と粉末尿素を用いれば、粒状石灰窒素に粉末尿素を被覆した粒状肥料が得られる。   In another embodiment, powdered lime nitrogen and granular urea are used. As shown in FIG. 2, granular fertilizer 6 in which granular urea is coated with powdered lime nitrogen is obtained by mixing powdered lime nitrogen 1 and granular urea 5 and granulating the mixture while spraying water. According to this embodiment, a granular nitrogen fertilizer having a uniform particle diameter can be obtained by using granular urea having a uniform particle diameter. Moreover, in this embodiment, if granular lime nitrogen and powdered urea are used instead of powdered lime nitrogen and granular urea, the granular fertilizer which coat | covered granular lime nitrogen with powdered urea will be obtained.

以下、具体的な実施例に基づいて、本発明について詳細に説明する。なお、本発明は、以下の実施例によって制限されるものではない。   Hereinafter, the present invention will be described in detail based on specific examples. In addition, this invention is not restrict | limited by a following example.

石灰窒素の窒素量と尿素の窒素量の比が1:1になるように、粉末石灰窒素と粉末尿素を重量にして46:20の割合で混合した。パン型造粒装置を用いて、回転する容器の中で水を噴霧しながら造粒した。粒径2〜6mm程度の均一な成分を有する粒状窒素肥料が得られた。   Powdered lime nitrogen and powdered urea were mixed in a weight ratio of 46:20 so that the ratio of the amount of nitrogen in lime nitrogen and the amount of nitrogen in urea was 1: 1. Using a pan-type granulator, granulation was performed while spraying water in a rotating container. A granular nitrogen fertilizer having a uniform component with a particle size of about 2 to 6 mm was obtained.

直径2mm程度の粒状尿素に粉末石灰窒素を加えて、パン型造粒装置を用いて、回転する容器の中で水を噴霧した。尿素が石灰窒素に被覆され、外径3mm程度の均一な粒径を有する粒状窒素肥料が得られた。   Powdered lime nitrogen was added to granular urea having a diameter of about 2 mm, and water was sprayed in a rotating container using a pan-type granulator. Urea was covered with lime nitrogen, and a granular nitrogen fertilizer having a uniform particle diameter of about 3 mm in outer diameter was obtained.

水田転換畑にて、石灰窒素と尿素の混合比率を変化させて施肥する試験を行った。   In the paddy field conversion field, the test which fertilizes by changing the mixing ratio of lime nitrogen and urea was conducted.

施肥を行わない「無施用区」、尿素のみの「尿素区」、窒素として石灰窒素1/4、尿素3/4を混合した「1/4石灰窒素区」、窒素として石灰窒素1/2、尿素1/2を混合した「1/2石灰窒素区」、石灰窒素のみの「石灰窒素区」を設け、それぞれ100kgN/haを地表下20cmに深層施肥した。   "No application section" without fertilization, "urea section" of urea only, 1/4 lime nitrogen as nitrogen, "1/4 lime nitrogen section" mixed with urea 3/4, lime nitrogen 1/2 as nitrogen, A “1/2 lime nitrogen section” mixed with urea 1/2 and a “lime nitrogen section” containing only lime nitrogen were provided, and 100 kg N / ha was applied deeply 20 cm below the surface.

無施用区の大豆の株あたり種子重量が31.1g、尿素区では35.6gであったのに対し、1/4石灰窒素区では37.8g、1/2石灰窒素区では37.5gであった。石灰窒素区では38.5gであったので、1/4石灰窒素区、1/2石灰窒素区で石灰窒素区に近い増収効果が得られた。   The seed weight per soybean strain in the non-application area was 31.1 g, the urea area was 35.6 g, whereas the 1/4 lime nitrogen area was 37.8 g, and the 1/2 lime nitrogen area was 37.5 g. there were. Since it was 38.5 g in the lime nitrogen section, a yield increasing effect close to the lime nitrogen section was obtained in the 1/4 lime nitrogen section and the 1/2 lime nitrogen section.

石灰窒素の窒素量と尿素の窒素量の比が1:1〜3となるように石灰窒素と尿素を混合したときに、際立った増収効果が得られることが確認された。   It was confirmed that when lime nitrogen and urea were mixed so that the ratio between the nitrogen amount of lime nitrogen and the nitrogen amount of urea was 1: 1 to 3, a remarkable effect of increasing the yield was obtained.

本発明の粒状窒素肥料の製造方法を示す模式図である。It is a schematic diagram which shows the manufacturing method of the granular nitrogen fertilizer of this invention. 同上別の製造方法を示す模式図である。It is a schematic diagram which shows another manufacturing method same as the above.

Claims (4)

石灰窒素と尿素を含有した粒状窒素肥料であって、石灰窒素の窒素量と尿素の窒素量の比が1:1〜3となるように石灰窒素と尿素を混合し、水を噴霧しながら造粒されたものであることを特徴とする粒状窒素肥料。 A granular nitrogen fertilizer containing lime nitrogen and urea, mixed with lime nitrogen and urea so that the ratio of the nitrogen amount of lime nitrogen to the nitrogen amount of urea is 1: 1 to 3, and produced while spraying water. Granular nitrogen fertilizer characterized by being granulated. 尿素が石灰窒素で被覆されてなることを特徴とする請求項1記載の粒状窒素肥料。 The granular nitrogen fertilizer according to claim 1, wherein urea is coated with lime nitrogen. 石灰窒素が尿素で被覆されてなることを特徴とする請求項1記載の粒状窒素肥料。 The granular nitrogen fertilizer according to claim 1, wherein lime nitrogen is coated with urea. 平均粒径が2〜6mmであることを特徴とする請求項1〜3のいずれか1項記載の粒状窒素肥料。 The granular nitrogen fertilizer according to any one of claims 1 to 3, wherein an average particle diameter is 2 to 6 mm.
JP2007127117A 2007-05-11 2007-05-11 Granular nitrogen fertilizer Pending JP2008280220A (en)

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Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS52150280A (en) * 1976-06-04 1977-12-13 Fukuei Hiriyou Kk Process for producing compound fertilizer

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS52150280A (en) * 1976-06-04 1977-12-13 Fukuei Hiriyou Kk Process for producing compound fertilizer

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