JP2008238078A - Methane fermentation processing method and apparatus - Google Patents

Methane fermentation processing method and apparatus Download PDF

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JP2008238078A
JP2008238078A JP2007083746A JP2007083746A JP2008238078A JP 2008238078 A JP2008238078 A JP 2008238078A JP 2007083746 A JP2007083746 A JP 2007083746A JP 2007083746 A JP2007083746 A JP 2007083746A JP 2008238078 A JP2008238078 A JP 2008238078A
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fermenter
methane fermentation
methane
liquid
stirrer
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Masakazu Kusakabe
正和 日下部
Hiroyuki Miyamoto
博幸 宮本
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Panasonic Holdings Corp
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Matsushita Electric Industrial Co Ltd
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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Abstract

<P>PROBLEM TO BE SOLVED: To provide a methane fermentation processing method capable of increasing fungus concentration inside a methane fermentation tank, thereby accelerating a processing speed without using a concentrating apparatus or a carrier. <P>SOLUTION: In the methane fermentation processing method, the precipitation time for solid-liquid separation is provided by stopping an agitation apparatus 8 and an agitation apparatus 12 when mixing and agitating organic waste 4 and acid producing bacteria inside a first fermentation tank 1 and lower fatty acid and methane fermentation bacteria inside a second fermentation tank 2. By the means, the fungus concentration inside the first fermentation tank 1 and the second fermentation tank 2 is increased to improve the throughput. <P>COPYRIGHT: (C)2009,JPO&INPIT

Description

本発明は、有機性廃棄物の処理装置に係り、特に固形分の多い厨芥類を中心としたメタン発酵処理方法に関するものである。   The present invention relates to an organic waste treatment apparatus, and more particularly to a methane fermentation treatment method centering on moss having a high solid content.

現在、廃水処理として主流である好気性処理はその過程で生成される余剰汚泥が多量なことに加え、有害な揮発性有機汚染物質などの難分解性物質を分解することができないなどの問題を抱えている。   At present, aerobic treatment, which is the mainstream wastewater treatment, has problems such as being unable to decompose difficult-to-decompose substances such as harmful volatile organic pollutants in addition to a large amount of excess sludge produced in the process. I have it.

一方、嫌気性処理は産業廃水中の一般的な有機汚泥物質は言うに及ばず、毒性物質も分解する能力が備わっていることから産業廃水を再生する手段として使用価値が高まっている。さらに発酵により発生したメタンガスを電気、熱として利用する一方で、メタン発酵をさせた後の消化汚泥は廃棄される過程でコンポスト化して肥料としたり、あるいは固形燃料、乾燥汚泥などとして再利用可能であり、経済的である。   On the other hand, the anaerobic treatment is not only a general organic sludge substance in industrial wastewater, but also has a capability of decomposing toxic substances, so that the use value is increasing as a means for regenerating industrial wastewater. Furthermore, while the methane gas generated by fermentation is used as electricity and heat, the digested sludge after methane fermentation can be composted into fertilizer in the process of being discarded, or reused as solid fuel, dry sludge, etc. Yes and economical.

メタン発酵は、大きく分けると加水分解菌、酸生成菌による可溶化過程と、メタン発酵菌によるメタン発酵過程の二段階の生化学反応から成っている。タンパク質、炭水化物、脂肪等の高分子有機化合物は、まず加水分解菌などによって低分子化されて高級脂肪酸、アミノ酸、糖類となる。次に酸生成菌等によってH2、CO2、低級脂肪酸(酢酸、酪酸、プロピオン酸、ピルビン酸、ギ酸、乳酸、コハク酸等)に分解され、最後にメタン発酵過程でメタン発酵菌によってメタンが生成する。 Methane fermentation is roughly divided into a two-stage biochemical reaction, a solubilization process by hydrolyzing bacteria and acid-producing bacteria, and a methane fermentation process by methane fermentation bacteria. High molecular organic compounds such as proteins, carbohydrates, and fats are first reduced in molecular weight by hydrolyzing bacteria to become higher fatty acids, amino acids, and saccharides. Next, it is decomposed into H 2 , CO 2 , and lower fatty acids (acetic acid, butyric acid, propionic acid, pyruvic acid, formic acid, lactic acid, succinic acid, etc.) by acid producing bacteria, etc. Generate.

このように可溶化過程とメタン発酵過程では、活躍する微生物の種類が全く異なり、最適pH値も可溶化過程は5.5〜6.5、メタン生成過程は7〜8と異なることから、最近は可溶化槽とメタン発酵槽を分離して発酵効率を高める二相式と呼ばれる方法が採用される場合が多い(例えば、特許文献1参照)。   Thus, the solubilization process and the methane fermentation process have completely different types of active microorganisms, and the optimum pH value is different from 5.5 to 6.5 for the solubilization process and 7 to 8 for the methane production process. In many cases, a so-called solubilization tank and a methane fermentation tank are separated from each other and a method called a two-phase system is employed to increase fermentation efficiency (see, for example, Patent Document 1).

この特許文献1では、メタン発酵菌の活性低下を防ぐため、pHに着目し、処理水の返送工程を設けている。すなわち、菌数ではなく、菌の質(活性)を改善し、可溶化を十分に行うアイデアである。   In this patent document 1, in order to prevent the activity fall of methane fermentation bacteria, paying attention to pH, the process water return process is provided. In other words, it is an idea of improving the quality (activity) of bacteria, not the number of bacteria, and sufficiently solubilizing.

このように、可溶化を十分に行わないまま第一発酵槽内発酵液を第二発酵槽へ移送すると、メタン発酵菌では分解できない物質が第二発酵槽へ蓄積し、メタン発酵装置が破綻する恐れがある。   In this way, if the fermentation liquid in the first fermentor is transferred to the second fermenter without sufficiently solubilizing, substances that cannot be decomposed by the methane fermentation bacteria accumulate in the second fermentor, and the methane fermentation apparatus fails. There is a fear.

なお、本明細書において「可溶化」とは、微生物の働きによる有機物の低分子化、低級脂肪酸への変換のみでなく、各種の物理化学的方法により、固形物粒子を細かくすることをも含んでいる。   In the present specification, “solubilization” includes not only the reduction of molecular weight of organic substances by the action of microorganisms and the conversion to lower fatty acids, but also the refinement of solid particles by various physicochemical methods. It is out.

他に、メタン発酵における処理効率を向上させる各種の方法が検討されている。   In addition, various methods for improving the processing efficiency in methane fermentation have been studied.

図3は発酵効率を高めるため、メタン発酵菌を含む汚泥を濃縮する例である。   FIG. 3 shows an example in which sludge containing methane fermentation bacteria is concentrated in order to increase fermentation efficiency.

厨芥類を中心とした有機性廃棄物102は破砕機101で破砕された後、ポンプ105、流入管103により第一発酵槽104に投入され、主に廃棄物中に存在する不特定の微生物の働きと撹拌程度の比較的穏やかな条件により可溶化され、メタン発酵の原料となる低級脂肪酸や低分子有機物を生成する。   Organic waste 102, mainly moss, is crushed by a crusher 101, and then introduced into a first fermenter 104 by a pump 105 and an inflow pipe 103, and mainly unspecified microorganisms present in the waste. It is solubilized under relatively mild conditions such as working and stirring, and produces lower fatty acids and low-molecular organic substances that are raw materials for methane fermentation.

スラリ状となった可溶化物はポンプ110、流出入管109により第二発酵槽111へ送られ、メタン発酵菌の働きにより、メタン50〜65%、二酸化炭素約35〜50%のバイオガスが生成される。   The slurry solubilized product is sent to the second fermenter 111 by the pump 110 and the inflow / outflow pipe 109, and biogas of 50 to 65% methane and about 35 to 50% carbon dioxide is produced by the action of the methane fermentation bacteria. Is done.

第二発酵槽111には、メタン発酵菌以外にも可溶化作用を行う菌が各種共存しているため、低級脂肪酸以外の有機物も分解されて低級脂肪酸に変換され、メタン発酵の原料となる。   In the second fermenter 111, various bacteria that solubilize in addition to methane fermentation bacteria coexist, so that organic substances other than lower fatty acids are also decomposed and converted into lower fatty acids to become raw materials for methane fermentation.

生成したバイオガスはガス流出管112を経由してガスホルダー113に貯留された後、主に燃料として利用される。第二発酵槽111では、低級脂肪酸を多く含んだ可溶化液の流入量に応じてポンプ116、流出管114により汚泥を抜き出し、槽内液レベルを一定に保っている。   The generated biogas is stored in the gas holder 113 via the gas outflow pipe 112 and then used mainly as fuel. In the second fermentation tank 111, sludge is extracted by the pump 116 and the outflow pipe 114 in accordance with the inflow amount of the solubilizing liquid containing a large amount of lower fatty acids, and the liquid level in the tank is kept constant.

抜き出された汚泥は汚泥濃縮装置117に送られ、通常は凝集剤118を添加して濃縮汚泥(主に菌体)と脱離水に分けられる。脱離水は脱離水管119から排水処理装置115へ送られ、好気活性汚泥法などにより最終処理された後放流される。   The extracted sludge is sent to a sludge concentrator 117, and usually a flocculant 118 is added to separate the sludge into concentrated sludge (mainly bacterial cells) and desorbed water. The desorbed water is sent from the desorbed water pipe 119 to the waste water treatment device 115 and discharged after being subjected to final treatment by an aerobic activated sludge method or the like.

一方、濃縮汚泥はポンプ120、切替弁121を介して、一部は濃縮汚泥返送管123を経由して第二発酵槽111へ返送し、槽内の菌体濃度を高めるのに使用する。残りの濃縮汚泥は汚泥排出管124から余剰汚泥として排出される。余剰汚泥は、第一発酵槽104へ返送して再発酵したり、コンポスト化あるいは焼却処理される場合が多い。   On the other hand, the concentrated sludge is returned to the second fermenter 111 via the pump 120 and the switching valve 121, and partly via the concentrated sludge return pipe 123, and used to increase the bacterial cell concentration in the tank. The remaining concentrated sludge is discharged from the sludge discharge pipe 124 as excess sludge. The surplus sludge is often returned to the first fermenter 104 and re-fermented, or composted or incinerated.

図4は発酵効率を高めるため、メタン発酵槽として担体を使用した例である。   FIG. 4 shows an example in which a carrier is used as a methane fermentation tank in order to increase fermentation efficiency.

固定床型メタン発酵槽130は、内部に菌を保持する担体充填層131が設置されており、これに可溶化液を流通させて分解し、バイオガスを発生させる。すなわち、固定床型メタン発酵槽130では、濃縮汚泥の返送を行わなくても菌濃度維持が可能であるため、凝集剤や濃縮装置が不要で、運転も容易である。   The fixed bed type methane fermentation tank 130 is provided with a carrier packed layer 131 for holding bacteria therein, and a solubilized liquid is circulated and decomposed to generate biogas. That is, in the fixed bed type methane fermenter 130, since the concentration of bacteria can be maintained without returning the concentrated sludge, a flocculant and a concentrating device are unnecessary, and the operation is easy.

通常、ポンプ133によって液を循環させており、固定床型メタン発酵槽130内で上向流を形成しており、処理水134がオーバーフローとして処理水管135から流出する。処理水134は、担体充填層131のフィルタ作用により固形分濃度が低くなっているため、濃縮分離せずに排水処理装置115で処理することが可能である。   Usually, the liquid is circulated by the pump 133, and an upward flow is formed in the fixed bed methane fermentation tank 130, and the treated water 134 flows out from the treated water pipe 135 as an overflow. Since the solid content of the treated water 134 is low due to the filter action of the carrier packed bed 131, the treated water 134 can be treated by the wastewater treatment device 115 without being concentrated and separated.

逆に担体充填層131よりも下の固定床底部136には濃厚な汚泥(菌体と未分解の微粒有機物)が蓄積しており、これは必要に応じて弁137、汚泥排出管138により余剰汚泥として排出する。   On the contrary, a thick sludge (bacteria and undecomposed fine organic matter) is accumulated in the fixed bed bottom 136 below the carrier packed bed 131. This is surplus by a valve 137 and a sludge discharge pipe 138 as necessary. Discharge as sludge.

このように固定床型メタン発酵槽130は、担体により菌体を高濃度に保持することができるため、処理速度が速く、発酵槽をコンパクト化できる。   Thus, since the fixed bed type | mold methane fermenter 130 can hold | maintain a microbial cell with a high density | concentration with a support | carrier, a process speed is quick and can make a fermenter compact.

しかし、汚泥や廃水と比較して固形分の比較的多い厨芥等の有機性廃棄物を対象とする場合、粗粒子による固定床の閉塞が問題となるため、可溶化を高度に行うか、可溶化後に固液分離を行って粗大な固形物粒子を除去しておくか、または閉塞を抑制する構成にする必要がある。可溶化促進の手段としては、酵素添加、アルカリ添加、機械的微破砕、オゾン、超音波処理、高温高圧処理などの手段が用いられる。   However, when organic waste such as soot with a relatively high solid content compared to sludge and wastewater is targeted, clogging of the fixed bed with coarse particles becomes a problem. It is necessary to perform solid-liquid separation after solubilization to remove coarse solid particles or to prevent clogging. As means for promoting solubilization, means such as enzyme addition, alkali addition, mechanical pulverization, ozone, ultrasonic treatment, high temperature and high pressure treatment are used.

また、メタン発酵槽内に、メタン発酵菌などの微生物の流出を防止するための分離膜を設けることも知られている(例えば、特許文献2参照)。
特開2000−167587号公報 特開2001−170631号公報
It is also known to provide a separation membrane for preventing the outflow of microorganisms such as methane fermentation bacteria in the methane fermentation tank (see, for example, Patent Document 2).
JP 2000-167487 A JP 2001-170631 A

メタン発酵の処理効率を向上させる場合、特許文献1のようにメタン発酵菌の活性低下の防止と、図3、図4及び特許文献2のように菌数の確保という、大きく分けて2種類の方法がある。   When improving the processing efficiency of methane fermentation, there are roughly two types of prevention, such as prevention of activity reduction of methane fermentation bacteria as in Patent Document 1 and securing of the number of bacteria as in FIG. 3, FIG. 4 and Patent Document 2. There is a way.

しかし、いずれの場合も、メタン発酵槽を大型化するか、返送や濃縮(膜も含む)のために新たな装置が必要である上、濃縮作業は非常に煩雑であるという問題があり、装置と作業を簡略化することが要求されている。   However, in either case, there is a problem that the methane fermenter is enlarged or a new apparatus is required for returning or concentrating (including a membrane), and the concentration work is very complicated. It is required to simplify the work.

また、図4に示したような従来のメタン発酵処理方法及び装置において、担体を用いて菌体濃度を上げる場合、発酵槽の閉塞防止のため高度な可溶化が必要となり、可溶化工程が複雑化するという課題があり、担体を用いず菌体濃度を上げることが要求されている。   Further, in the conventional methane fermentation treatment method and apparatus as shown in FIG. 4, when the cell concentration is increased using a carrier, high solubilization is necessary to prevent clogging of the fermenter, and the solubilization process is complicated. There is a problem of increasing the cell concentration without using a carrier.

本発明は、このような従来の課題を解決するものであり、新たな装置を設けず、各槽からの菌の流出を防ぎ、工程を複雑化せずに効率的にメタン発酵槽内の菌体濃度と、メタン発酵菌と低級脂肪酸の接触機会を上げ、発酵処理速度を上昇させることができるメタン発酵処理方法及び装置を提供することを目的としている。   The present invention solves such a conventional problem, does not provide a new device, prevents outflow of bacteria from each tank, and efficiently eliminates bacteria in the methane fermentation tank without complicating the process. An object of the present invention is to provide a methane fermentation treatment method and apparatus capable of increasing the body concentration, the contact opportunity between methane fermentation bacteria and lower fatty acids, and increasing the fermentation treatment rate.

本発明のメタン発酵処理方法及び装置は上記目的を達成するために、メタン発酵槽内の低級脂肪酸とメタン発酵菌を混合撹拌する際に、撹拌装置を停止して固液分離する沈殿時間を設けることとしたものである。   In order to achieve the above object, the methane fermentation treatment method and apparatus of the present invention provide a precipitation time for stopping the agitation device and performing solid-liquid separation when mixing and stirring the lower fatty acid and methane fermentation bacteria in the methane fermentation tank. That's what it meant.

この手段により濃縮装置を使用せず、メタン発酵槽内の菌体濃度を上げて処理速度を上げることができるメタン発酵処理方法及び装置が得られる。   By this means, a methane fermentation treatment method and apparatus capable of increasing the cell concentration in the methane fermentation tank and increasing the treatment speed without using a concentrator can be obtained.

本発明によれば濃縮装置や担体を用いず、メタン発酵槽内の菌体濃度を上げて処理速度を上げることができるという効果のあるメタン発酵処理方法及び装置を提供できる。   ADVANTAGE OF THE INVENTION According to this invention, the methane fermentation processing method and apparatus which have the effect that the process speed can be raised by raising the fungal | concentration density | concentration in a methane fermentation tank, without using a concentration apparatus and a support | carrier can be provided.

また、工程を複雑化せずにメタン発酵菌と低級脂肪酸の接触機会を維持することができるという効果のあるメタン発酵処理方法及び装置を提供できる。   Moreover, the methane fermentation processing method and apparatus which can maintain the contact opportunity of a methane fermentation microbe and a lower fatty acid without complicating a process can be provided.

本発明は、有機性廃棄物を酸生成菌により低級脂肪酸に分解する第一発酵槽と低級脂肪酸をさらにメタン発酵菌によりメタンと炭酸ガスに分解する第二発酵槽と、第一発酵槽及び第二発酵槽に撹拌装置を設け、第一発酵槽内で有機性廃棄物と酸生成菌、及び第二発酵槽内で低級脂肪酸とメタン発酵菌を混合撹拌するメタン発酵処理方法において、撹拌装置を停止して固液分離した沈殿部内の菌体濃度を上げるための沈殿時間を設けるものであり、濃縮装置を用いず、メタン発酵槽内の菌体濃度を上げて処理速度を上げることができるという作用を有する。   The present invention includes a first fermenter that decomposes organic waste into lower fatty acids by acid-producing bacteria, a second fermenter that further decomposes lower fatty acids into methane and carbon dioxide gas by methane-fermenting bacteria, In the methane fermentation treatment method in which the two fermenters are equipped with a stirrer, and organic waste and acid-producing bacteria are mixed in the first fermentor, and the lower fatty acid and methane fermenter are mixed and stirred in the second fermenter. It is intended to provide a sedimentation time to increase the bacterial cell concentration in the sedimentation section that has been stopped and solid-liquid separated, and the processing speed can be increased by increasing the bacterial cell concentration in the methane fermentation tank without using a concentrator. Has an effect.

また、撹拌装置は撹拌翼を有し、固液分離した沈殿部内に撹拌翼を固定することにより、有機性廃棄物と酸生成菌、及び低級脂肪酸とメタン発酵菌を沈殿部内で混合撹拌するとしたものであり、有機性廃棄物と酸生成菌及び、低級脂肪酸とメタン発酵菌を沈殿部内で混合撹拌することができる。   In addition, the stirrer has a stirring blade, and by fixing the stirring blade in the solid-liquid separated precipitation part, organic waste, acid-producing bacteria, and lower fatty acid and methane fermentation bacteria are mixed and stirred in the precipitation part. It is possible to mix and stir organic waste and acid-producing bacteria, and lower fatty acids and methane-fermenting bacteria in the precipitation part.

また、有機性廃棄物の流入管を有する第一発酵槽と、スカムや上澄み液を流出するための流出口を有する第二発酵槽と、第一発酵槽内で生成した低級脂肪酸を第二発酵槽へ移流する流出入管と、第一発酵槽及び第二発酵槽内を撹拌するための撹拌装置と、第一発酵槽及び第二発酵槽内で発生したバイオガスを捕集するためのガス流出管とガスホルダーを備え、第二発酵槽内の攪拌装置は、攪拌翼とこれを駆動させるモーターからなり、第二発酵槽内の撹拌翼は固液分離した沈殿部内に固定し、回転により下向流を発生させるとともに、流出入管の出口は、第二発酵槽の前記撹拌翼より下部に配するとしたものであり、低級脂肪酸とメタン発酵菌を沈殿部内で効率的に混合撹拌することができ、槽全体での攪拌に比べ短時間で沈殿させることができるという作用を有する。   In addition, a first fermentor having an inflow pipe for organic waste, a second fermenter having an outlet for discharging scum and supernatant, and a lower fatty acid produced in the first fermenter are subjected to second fermentation. An outflow / inflow pipe that is transferred to the tank, a stirrer for stirring the first and second fermenters, and a gas outflow for collecting biogas generated in the first and second fermenters The stirrer in the second fermentor is equipped with a pipe and a gas holder, and consists of a stirrer blade and a motor that drives the stirrer blade. The counterflow is generated and the outlet of the inflow / outflow pipe is arranged below the stirring blade of the second fermenter, so that the lower fatty acid and the methane fermentation bacteria can be mixed and stirred efficiently in the precipitation part. It can be precipitated in a short time compared to stirring in the entire tank It has the effect of kill.

また、撹拌装置を停止して固液分離した沈殿部内の菌体濃度を上げるための沈殿時間を設けるものであり、濃縮装置を用いず、メタン発酵槽内の菌体濃度を上げて処理速度を上げることができるという作用を有する。   Moreover, the stirring device is stopped to provide a sedimentation time for increasing the bacterial cell concentration in the sedimentation part separated by solid-liquid separation, and the processing speed is increased by increasing the bacterial cell concentration in the methane fermentation tank without using a concentrator. It has the effect that it can be raised.

また、第一発酵槽内の攪拌装置は、攪拌翼とこれを駆動させるモーターからなり、第一発酵槽内の撹拌翼は固液分離した沈殿部内に固定し、回転により下向流を発生させるとともに、流入管の出口は、第一発酵槽の前記撹拌翼より下部に配したものであり、有機性廃棄物と酸生成菌を沈殿部内で効率的に混合撹拌することができ、槽全体での攪拌に比べ短時間で沈殿させることができるという作用を有する。   The stirring device in the first fermenter is composed of a stirring blade and a motor for driving the stirring blade, and the stirring blade in the first fermenter is fixed in the precipitation portion separated into solid and liquid and generates a downward flow by rotation. In addition, the outlet of the inflow pipe is disposed below the stirring blade of the first fermenter, and organic waste and acid-producing bacteria can be efficiently mixed and stirred in the precipitation part. It has the effect | action that it can be made to precipitate in a short time compared with stirring.

また、第二発酵槽の流出口を第二発酵槽の液位に配するとしたものであり、第二発酵槽内の発酵液位を一定に保つという作用を有する。   Moreover, it is supposed that the outlet of the second fermenter is arranged at the liquid level of the second fermenter, and has an effect of keeping the fermentation liquid level in the second fermenter constant.

また、第一発酵槽内の前記流出入管の流出口を第一発酵槽の液位に配するとしたものであり、第一発酵槽内の発酵液位を一定に保つという作用を有する。   Further, the outlet of the inflow / outflow pipe in the first fermenter is arranged at the liquid level of the first fermentor, and has an effect of keeping the fermentation liquid level in the first fermenter constant.

以下、本発明の実施の形態について図面を参照しながら説明する。   Hereinafter, embodiments of the present invention will be described with reference to the drawings.

(実施の形態1)
図1は、本発明の第1実施形態に係るメタン発酵装置の構成図である。
(Embodiment 1)
FIG. 1 is a configuration diagram of a methane fermentation apparatus according to the first embodiment of the present invention.

図1に示すように、本メタン発酵処理装置は第一発酵槽1と第二発酵槽2が同じ槽に設けられており、その間を仕切り板3で分割するといった構成になっている。   As shown in FIG. 1, the present methane fermentation treatment apparatus is configured such that the first fermenter 1 and the second fermenter 2 are provided in the same tank, and a partition plate 3 divides the first fermenter 1 and the second fermenter 2.

第一発酵槽1は破砕機により破砕された有機性廃棄物4を流入するための流入管5と、第一発酵槽内発酵液を撹拌するための撹拌翼6とこれを駆動させるモーター7からなる撹拌装置8で構成される。   The first fermenter 1 includes an inflow pipe 5 for inflowing the organic waste 4 crushed by the crusher, a stirring blade 6 for agitating the fermented liquid in the first fermenter, and a motor 7 for driving this. The stirring device 8 is configured.

第一発酵槽1に備えられた撹拌翼6は第一発酵槽内発酵液を固液分離した状態の沈殿部内に固定し、回転時に撹拌翼6から下向流を発生させる構造となっている。また、流入管5の出口は、第一発酵槽1の撹拌翼6より下部に固定する。   The stirring blade 6 provided in the first fermenter 1 is fixed in a precipitation portion in a state where the fermentation liquid in the first fermenter is solid-liquid separated, and a downward flow is generated from the stirring blade 6 during rotation. . The outlet of the inflow pipe 5 is fixed below the stirring blade 6 of the first fermenter 1.

第一発酵槽1は流出入管9により第二発酵槽2と接続されており、第一発酵槽1に配されている流出入管9の入口は保持したい第一発酵槽内発酵液の液位に固定する。   The first fermenter 1 is connected to the second fermenter 2 by an inflow / outflow pipe 9, and the inlet of the outflow / inflow pipe 9 arranged in the first fermenter 1 is at the level of the fermented liquid in the first fermenter. Fix it.

第二発酵槽2は第二発酵槽内発酵液を撹拌するための撹拌翼10とこれを起動させるモーター11からなる撹拌装置12と、第二発酵槽の上澄み液である廃液13を流出するための流出管14で構成されている。   The second fermenter 2 flows out the agitator blade 10 for agitating the fermented liquid in the second fermenter and the stirrer 12 composed of a motor 11 for starting it, and the waste liquid 13 which is the supernatant of the second fermenter. The outflow pipe 14 is constituted.

第二発酵槽2に備えられた撹拌翼10は第二発酵槽内発酵液を固液分離した状態の沈殿部内に固定し、回転時に撹拌翼10から下向流を発生させる構造となっている。また、流出入管9の出口は、第二発酵槽2の撹拌翼10より下部に固定し、流出管の入口は保持したい第二発酵槽内発酵液の液位に固定する。   The agitating blade 10 provided in the second fermenter 2 is fixed in a precipitation portion in a state where the fermentation liquid in the second fermenter is solid-liquid separated, and has a structure for generating a downward flow from the agitating blade 10 during rotation. . Moreover, the outlet of the outflow / inflow pipe 9 is fixed below the stirring blade 10 of the second fermenter 2, and the inlet of the outflow pipe is fixed at the liquid level of the fermentation liquid in the second fermenter to be retained.

また、第一発酵槽1及び第二発酵槽2には各槽内で発生したバイオガス15をガスホルダー(図示なし)へ移流するためのガス流出管16を備えている。   Moreover, the first fermenter 1 and the second fermenter 2 are provided with a gas outflow pipe 16 for transferring biogas 15 generated in each tank to a gas holder (not shown).

上記の構成におけるメタン発酵の処理を詳細に説明する。   The process of methane fermentation in the above configuration will be described in detail.

厨芥を中心とした有機性廃棄物4を破砕機により20mm以下程度に破砕し、流入管5により、第一発酵槽1の沈殿部内の撹拌翼6より下の位置へ流入する。このとき、第一発酵槽1の上澄み液に有機性廃棄物4が混合して、酸生成菌による低級脂肪酸への分解が完了する前に第二発酵槽2へ流出することをできるだけ防ぐために、流入管5の出口は第一発酵槽1の底面により近い方が好ましい。   The organic waste 4 centering on the straw is crushed to about 20 mm or less by a crusher, and flows into a position below the stirring blade 6 in the settling portion of the first fermenter 1 through the inflow pipe 5. At this time, in order to prevent the organic waste 4 from being mixed with the supernatant of the first fermenter 1 and flowing out into the second fermenter 2 as much as possible before the decomposition into lower fatty acids by the acid-producing bacteria is completed, The outlet of the inflow pipe 5 is preferably closer to the bottom surface of the first fermenter 1.

粉砕された有機性廃棄物4が第一発酵槽1へ流入を完了したら、第一発酵槽1に設置している適正な撹拌翼6とモーター7からなる撹拌装置8を低回転で起動させ、第一発酵槽内発酵液の上澄み液を取り込まずに沈殿部のみを混合撹拌する。   When the pulverized organic waste 4 completes the flow into the first fermenter 1, the stirrer 8 composed of an appropriate stirrer blade 6 and a motor 7 installed in the first fermenter 1 is started at a low speed, Only the precipitation part is mixed and stirred without taking in the supernatant of the fermentation liquid in the first fermentor.

沈殿部内の撹拌翼6より下の位置へ流入された、粉砕された有機性廃棄物4は沈殿部内で滞留するため、上澄み液を含めた全体攪拌に比べ、酸生成菌を主とした不特定の微生物との接触機会は増大し、固液分離のための沈殿時間も短くなる。   Since the pulverized organic waste 4 that has flowed into the position below the stirring blade 6 in the settling part stays in the settling part, it is unspecified mainly with acid-producing bacteria compared to the entire stirring including the supernatant. The opportunity for contact with microorganisms increases and the precipitation time for solid-liquid separation also decreases.

図2に適正な撹拌翼6の一例を示す。図2(a)は、撹拌翼6を上から見た構成図、(b)は撹拌翼6を横から見た構成図であり、撹拌翼6が4枚の羽根板17で構成された例である。   FIG. 2 shows an example of a proper stirring blade 6. FIG. 2A is a configuration diagram of the stirring blade 6 viewed from above, and FIG. 2B is a configuration diagram of the stirring blade 6 viewed from the side, in which the stirring blade 6 is configured by four blade plates 17. It is.

発酵槽を円筒形とした場合、翼径Dが直径の40%、羽根板17の幅Wが発酵槽直径の10%および羽根板17の傾斜角度θが25°の撹拌翼であり、これを有する撹拌装置8を50rpmで沈殿部内において撹拌翼6から下向流を発生させるように回転させた場合、上澄み液を取り込まない効率的な沈殿部の撹拌を約5分維持することができたことを確認した。   When the fermenter is cylindrical, the blade diameter D is 40% of the diameter, the width W of the blade plate 17 is 10% of the fermenter diameter, and the blade 17 has an inclination angle θ of 25 °. When the stirring device 8 having the rotating device was rotated at 50 rpm so as to generate a downward flow from the stirring blade 6 in the settling portion, it was possible to maintain efficient stirring of the settling portion without taking in the supernatant liquid for about 5 minutes. It was confirmed.

上記攪拌翼の数値は、組合せの一例であり、各数値の増減により、適正な攪拌強度となる組合せは多数ある。   The numerical values of the stirring blades are examples of combinations, and there are many combinations that provide appropriate stirring strength by increasing or decreasing each numerical value.

実際の攪拌においては、撹拌装置8の起動から約1分経過したら撹拌装置8を停止し、次の有機性廃棄物4が流入されるまで約5分間、発酵液を沈殿させて処理を行った。   In actual stirring, the stirring device 8 was stopped after about 1 minute from the start of the stirring device 8, and the fermented liquid was allowed to settle for about 5 minutes until the next organic waste 4 was introduced. .

発酵液全体を撹拌した場合、固液分離に時間がかかるが、以上のような適正な撹拌翼6を有する撹拌装置8を低回転で運転した場合は沈殿部内のみの撹拌となるため、上澄み液を取り込まずに沈殿部と有機性廃棄物が効率的に短時間で撹拌することができ、さらに固液分離の効率を上げることができる。   When the entire fermentation broth is stirred, it takes time to separate the solid and liquid. However, when the stirring device 8 having the proper stirring blade 6 as described above is operated at a low rotation, stirring is performed only in the precipitation portion, so that the supernatant liquid is obtained. Thus, the precipitation part and the organic waste can be efficiently stirred in a short time without taking in water, and the efficiency of solid-liquid separation can be further increased.

第一発酵槽1へ流入された有機性廃棄物4は主に廃棄物中に存在する不特定の微生物の働きと撹拌程度の比較的穏やかな条件により可溶化され、メタン発酵の原料となる低級脂肪酸や低分子有機物を生成する。   The organic waste 4 that has flowed into the first fermenter 1 is solubilized mainly under the relatively mild conditions such as the action of unspecified microorganisms present in the waste and the degree of stirring. Produces fatty acids and low molecular weight organic substances.

第一発酵槽1へ流入した有機廃棄物4の量に比例した第一発酵槽内発酵液における液位の上昇により、第一発酵槽内発酵液は第二発酵槽2へ越流するが、上記のように沈殿部内のみの攪拌のため、沈殿時間が短くても第一発酵槽内発酵液の固液分離は促進され、越流するものは第一発酵槽内発酵液の上澄み液が主となる。   Although the fermentation liquid in the first fermentation tank overflows to the second fermentation tank 2 due to the rise in the liquid level in the fermentation liquid in the first fermentation tank proportional to the amount of the organic waste 4 that has flowed into the first fermentation tank 1, As described above, because only the inside of the precipitation part is stirred, the solid-liquid separation of the fermentation liquid in the first fermenter is promoted even if the precipitation time is short, and the supernatant of the fermentation liquid in the first fermenter is mainly used for the overflow. It becomes.

第一発酵槽内発酵液の上澄み液には低級脂肪酸に分解されていない有機性廃棄物は少なく、また酸生成菌も少ないので、第二発酵槽2に与える負荷を抑制することができ、第一発酵槽の酸生成菌が第二発酵槽へ流出することを防ぎ、酸生成菌の菌体濃度を上げることができる。すなわち、酸生成が促進され、同一処理量に対しては、処理時間の短縮あるいは処理槽の小型化が実現できる。   In the supernatant of the fermentation liquid in the first fermenter, there are few organic wastes that are not decomposed into lower fatty acids, and there are also fewer acid-producing bacteria, so the load on the second fermenter 2 can be suppressed, It is possible to prevent the acid-producing bacteria in one fermenter from flowing out to the second fermenter and increase the cell concentration of the acid-producing bacteria. That is, acid generation is promoted, and for the same processing amount, the processing time can be shortened or the processing tank can be downsized.

次に、低級脂肪酸を多く含む可溶化液を流出入管9により、第二発酵槽2の沈殿部内の撹拌翼10より下の位置へ流入する。このとき、第一発酵槽の場合と同様、第二発酵槽2の上澄み液に低級脂肪酸が混合して、メタン発酵菌によるバイオガス15への分解が完了する前に流出することをできるだけ防ぐために、流出入管9の出口は第二発酵槽2の底面により近い方が好ましい。   Next, the solubilized liquid containing a large amount of lower fatty acids flows into the position below the stirring blade 10 in the precipitation part of the second fermenter 2 through the inflow / outflow pipe 9. At this time, as in the case of the first fermenter, in order to prevent the lower fatty acid from mixing with the supernatant of the second fermenter 2 and flowing out before the decomposition to the biogas 15 by the methane fermentation bacteria is completed as much as possible. The outlet of the inflow / outflow pipe 9 is preferably closer to the bottom surface of the second fermenter 2.

低級脂肪酸を多く含む可溶化液の第二発酵槽2への流入を完了したら、第二発酵槽2に設置している適正な撹拌翼10とモーター11からなる撹拌装置12を低回転で起動させ、第二発酵槽内発酵液の上澄み液を取り込まずに沈殿部のみを混合撹拌し、低級脂肪酸を多く含む可溶化液とメタン発酵菌を主とした不特定の微生物の接触機会を増大させる。   When the inflow of the solubilized liquid containing a large amount of lower fatty acids into the second fermenter 2 is completed, the stirring device 12 including the appropriate stirring blade 10 and the motor 11 installed in the second fermenter 2 is started at a low speed. Then, only the precipitation part is mixed and stirred without taking in the supernatant of the fermentation liquid in the second fermenter, and the solubilized liquid containing a large amount of lower fatty acids and the chance of contact with unspecified microorganisms mainly composed of methane fermentation bacteria are increased.

沈殿部内の撹拌翼10より下の位置へ流入された、低級脂肪酸を多く含む可溶化液は、攪拌により、沈殿部内の下部から上部へ移動する間に、沈殿部内のメタン発酵菌を主とした不特定の微生物と接触する。   The solubilized liquid containing a large amount of lower fatty acid, which was flowed to a position below the stirring blade 10 in the precipitation part, moved mainly from the lower part in the precipitation part to the upper part by stirring. Contact with unspecified microorganisms.

また、接触できないまま沈殿部内を上澄み液側まで上昇した場合でも、上澄み液より低級脂肪酸の方が比重が重いため、沈殿部と上澄み液の境界に滞留し、メタン発酵菌を主とした不特定の微生物との接触機会があり、全体攪拌に比べ、接触機会は増大する。   In addition, even when the inside of the precipitation part rises to the supernatant liquid side without contact, the lower fatty acid has a higher specific gravity than the supernatant liquid, so it stays at the boundary between the precipitation part and the supernatant liquid and is unspecified mainly consisting of methane fermentation There is an opportunity for contact with other microorganisms, and the contact opportunity increases compared to the whole agitation.

さらに、第二発酵槽2へ流入した可溶化液の量に比例した第二発酵槽内発酵液における液位の上昇により、第二発酵槽内発酵液は流出管14より装置外へ越流するが、上記のように沈殿部内のみの攪拌のため、沈殿時間が短くても第二発酵槽内発酵液の固液分離は促進され、越流するものは第二発酵槽内発酵液の上澄み液が主となる。   Furthermore, the fermentation liquid in the second fermenter overflows out of the apparatus from the outflow pipe 14 due to the rise in the liquid level in the fermentation liquid in the second fermentor proportional to the amount of the solubilized liquid flowing into the second fermenter 2. However, as described above, because of stirring only in the precipitation part, solid-liquid separation of the fermentation liquid in the second fermenter is promoted even if the precipitation time is short, and what overflows is the supernatant of the fermentation liquid in the second fermenter Is the main.

第二発酵槽内発酵液の上澄み液にはメタン発酵菌に分解されていない低級脂肪酸は少なく、またメタン発酵菌も少ないので、第二発酵槽のメタン発酵菌が装置外へ流出することを防ぎ、メタン発酵菌の菌体濃度を上げることができる。   The supernatant of the fermented liquid in the second fermenter contains few lower fatty acids that have not been decomposed into methane-fermenting bacteria, and there are also few methane-fermenting bacteria. The cell concentration of methane fermentation bacteria can be increased.

すなわち、菌体濃度を上げるとともに、メタン発酵菌と低級脂肪酸との接触機会が増大することにより、メタン発酵が促進され、同一処理量に対しては、処理時間の短縮あるいは処理槽の小型化が実現できる。   In other words, methane fermentation is promoted by increasing the cell concentration and increasing the chance of contact between methane-fermenting bacteria and lower fatty acids. For the same amount of processing, the processing time is shortened or the processing tank is downsized. realizable.

撹拌装置12の起動から約1分経過したら撹拌装置12を停止し、次の可溶化液が流入されるまで約5分間、発酵液を沈殿させる。ここで、適正な撹拌翼10の条件は、前記第一発酵槽の撹拌翼6と同じである。   When about 1 minute has elapsed since the start of the stirring device 12, the stirring device 12 is stopped, and the fermentation solution is allowed to settle for about 5 minutes until the next solubilizing solution is introduced. Here, the conditions of the suitable stirring blade 10 are the same as the stirring blade 6 of the said 1st fermenter.

第二発酵槽2へ流入した可溶化液はメタン発酵菌の働きにより、メタン50〜65%、二酸化炭素約35〜50%のバイオガス15に分解される。   The solubilized liquid flowing into the second fermenter 2 is decomposed into biogas 15 containing 50 to 65% methane and about 35 to 50% carbon dioxide by the action of methane fermentation bacteria.

生成したバイオガス15はガス流出管16を経由してガスホルダー(図示なし)に貯留された後、主に燃料として利用される。   The generated biogas 15 is stored in a gas holder (not shown) via the gas outflow pipe 16 and then used mainly as fuel.

流出管より越流した第二発酵槽2の上澄み液は廃液13として濃縮分離せずに排水処理装置で処理する。   The supernatant liquid of the second fermenter 2 that has overflowed from the outflow pipe is processed as a waste liquid 13 by a wastewater treatment device without being concentrated and separated.

ここで、第二発酵槽2は内部に固定床などの構造体を持たない単なる容器上のものであるため、粗粒子による閉塞は問題とならない。   Here, since the 2nd fermenter 2 is on the mere container which does not have structures, such as a fixed bed, the obstruction | occlusion by a coarse particle does not become a problem.

このように本実施形態の装置構成と運転方法により、酸生成菌の菌体濃度をあげることにより可溶化を促進するので、担体を用いたメタン発酵方法のように、可溶化を促進させるためのアルカリなどの薬剤投入や超音波やオゾンなどの特別な装置の設置などが不必要で可溶化工程がシンプルとなり、装置と薬剤のコスト低減、運転の省力化が可能となる。   As described above, the apparatus configuration and operation method of this embodiment promotes solubilization by increasing the cell concentration of acid-producing bacteria, so that the solubilization is promoted as in the methane fermentation method using a carrier. It is not necessary to add chemicals such as alkali or to install special devices such as ultrasonic waves and ozone, so that the solubilization process is simplified, and the cost of the device and the chemicals can be reduced and the labor can be saved.

また、酸生成菌およびメタン発酵菌の流出防止により可溶化促進とともにメタン発酵も促進され、特別な装置および汚泥濃縮返送の不要な高速処理システムとなり、従来のメタン発酵装置と比較した処理量が同じであれば、各発酵槽を小型化することができる。   Moreover, solubilization and methane fermentation are promoted by preventing outflow of acid-producing bacteria and methane-fermenting bacteria, resulting in a high-speed processing system that does not require special equipment and sludge concentration and return, with the same amount of processing compared to conventional methane fermentation equipment. If it is, each fermenter can be reduced in size.

さらに、可溶化残渣及びメタン発酵汚泥の排出量を低減でき、コンポスト化、焼却処理するべき最終処理物の量が減り、その分、バイオガスの発生量を増加させることができる。   Furthermore, the discharge amount of solubilization residue and methane fermentation sludge can be reduced, the amount of final processed products to be composted and incinerated can be reduced, and the amount of biogas generated can be increased accordingly.

なお、上記実施の形態では、仕切り板3による槽の分割を例としたが、別槽で水位差を利用できない場合は、ポンプを利用しても、同様の効果が得られる。   In addition, in the said embodiment, although division | segmentation of the tank by the partition plate 3 was made into the example, when a water level difference cannot be utilized with another tank, even if it uses a pump, the same effect is acquired.

本発明によるメタン発酵処理方法及び処理装置は、固形分の多い厨芥類を中心とした有機性廃棄物の処理に適用できる。   The methane fermentation treatment method and treatment apparatus according to the present invention can be applied to the treatment of organic waste centering on moss having a high solid content.

本発明の第1実施形態に係るメタン発酵システムの構成図The block diagram of the methane fermentation system which concerns on 1st Embodiment of this invention. 本発明の第1実施形態に係る撹拌翼の構成図((a)同撹拌翼を上から見た構成図、(b)同攪拌翼を横から見た構成図)The block diagram of the stirring blade which concerns on 1st Embodiment of this invention ((a) The block diagram which looked at the stirring blade from the top, (b) The block diagram which looked at the stirring blade from the side) 従来のメタン発酵システムの系統図System diagram of conventional methane fermentation system 従来のメタン発酵システムの系統図System diagram of conventional methane fermentation system

符号の説明Explanation of symbols

1 第一発酵槽
2 第二発酵槽
3 仕切り板
4 有機性廃棄物
5 流入管
6、10 撹拌翼
7、11 モーター
8、12 撹拌装置
9 流出入管
13 廃液
14 流出管
15 バイオガス
16 ガス流出管
17 羽根板
DESCRIPTION OF SYMBOLS 1 1st fermenter 2 2nd fermenter 3 Partition plate 4 Organic waste 5 Inflow pipe 6, 10 Stirring blade 7, 11 Motor 8, 12 Stirrer 9 Outflow inflow pipe 13 Waste liquid 14 Outflow pipe 15 Biogas 16 Gas outflow pipe 17 slats

Claims (7)

有機性廃棄物を酸生成菌により低級脂肪酸に分解する第一発酵槽と、前記低級脂肪酸をさらにメタン発酵菌によりメタンと炭酸ガスに分解する第二発酵槽と、前記第一発酵槽及び前記第二発酵槽に撹拌装置を設け、前記第一発酵槽内で前記有機性廃棄物と酸生成菌、及び前記第二発酵槽内で前記低級脂肪酸とメタン発酵菌を混合撹拌するメタン発酵処理方法において、前記撹拌装置を停止して固液分離した沈殿部内の菌体濃度を上げるための沈殿時間を設けることを特徴とするメタン発酵処理方法。 A first fermenter that decomposes organic waste into lower fatty acids by acid-producing bacteria, a second fermenter that further decomposes the lower fatty acids into methane and carbon dioxide by methane-fermenting bacteria, the first fermenter, and the first In a methane fermentation treatment method in which a stirrer is provided in a two-fermentor, and the organic waste and acid-producing bacteria are mixed and stirred in the first fermentor, and the lower fatty acid and methane-fermenting bacteria are mixed in the second fermenter. A methane fermentation treatment method characterized by providing a sedimentation time for stopping the agitator and increasing the cell concentration in the sedimentation part separated by solid-liquid separation. 前記撹拌装置は撹拌翼を有し、固液分離した沈殿部内に前記撹拌翼を固定することにより、前記有機性廃棄物と酸生成菌、及び前記低級脂肪酸とメタン発酵菌を沈殿部内で混合撹拌することを特徴とする請求項1記載のメタン発酵処理方法。 The stirrer has a stirring blade, and the agitation blade is fixed in a solid-liquid separated precipitation part, whereby the organic waste, acid-producing bacteria, and the lower fatty acid and methane fermentation bacteria are mixed and stirred in the precipitation part. The methane fermentation treatment method according to claim 1, wherein: 有機性廃棄物の流入管を有する第一発酵槽と、スカムや上澄み液を流出するための流出口を有する第二発酵槽と、前記第一発酵槽内で生成した低級脂肪酸を前記第二発酵槽へ移流する流出入管と、前記第一発酵槽及び前記第二発酵槽内を撹拌するための撹拌装置と、前記第一発酵槽及び前記第二発酵槽内で発生したバイオガスを捕集するためのガス流出管とガスホルダーを備え、前記第二発酵槽内の攪拌装置は、攪拌翼とこれを駆動させるモーターからなり、前記第二発酵槽内の撹拌翼は固液分離した沈殿部内に固定し、回転により下向流を発生させるとともに、前記流出入管の出口は、前記第二発酵槽の前記撹拌翼より下部に配することを特徴とするメタン発酵処理装置。 A first fermenter having an inflow pipe for organic waste, a second fermenter having an outlet for discharging scum and supernatant liquid, and lower fatty acids produced in the first fermenter by the second fermentation An inflow / outflow pipe that flows into the tank, a stirring device for stirring the inside of the first fermenter and the second fermenter, and biogas generated in the first fermenter and the second fermenter are collected. The stirrer in the second fermenter comprises a stirrer blade and a motor that drives the stirrer, and the stirrer blade in the second fermenter is placed in a solid-liquid separated precipitation section. The methane fermentation treatment apparatus is characterized in that it is fixed and generates a downward flow by rotation, and an outlet of the inflow / outflow pipe is disposed below the stirring blade of the second fermentation tank. 前記撹拌装置を停止して固液分離した沈殿部内の菌体濃度を上げるための沈殿時間を設けることを特徴とする請求項3記載のメタン発酵処理装置。 The methane fermentation treatment apparatus according to claim 3, wherein a precipitation time is provided for increasing the bacterial cell concentration in the precipitation portion where the stirring device is stopped and solid-liquid separated. 前記第一発酵槽内の攪拌装置は、攪拌翼とこれを駆動させるモーターからなり、前記第一発酵槽内の撹拌翼は固液分離した沈殿部内に固定し、回転により下向流を発生させるとともに、前記流入管の出口は、前記第一発酵槽の前記撹拌翼より下部に配することを特徴とする請求項3または4記載のメタン発酵処理装置。 The stirrer in the first fermenter comprises a stirrer blade and a motor for driving the stirrer blade. The stirrer blade in the first fermenter is fixed in a precipitation portion separated into solid and liquid and generates a downward flow by rotation. The methane fermentation treatment apparatus according to claim 3, wherein the outlet of the inflow pipe is disposed below the stirring blade of the first fermentation tank. 前記第二発酵槽の流出口を前記第二発酵槽の液位に配することを特徴とする請求項3〜5いずれか1項に記載のメタン発酵処理装置。 The methane fermentation treatment apparatus according to any one of claims 3 to 5, wherein an outlet of the second fermenter is disposed at a liquid level of the second fermenter. 前記第一発酵槽内の前記流出入管の流出口を前記第一発酵槽の液位に配することを特徴とする請求項3〜6いずれか1項に記載のメタン発酵処理装置。 The methane fermentation treatment apparatus according to any one of claims 3 to 6, wherein an outlet / outlet of the inflow / outflow pipe in the first fermenter is disposed at a liquid level of the first fermenter.
JP2007083746A 2007-03-28 2007-03-28 Methane fermentation processing method and apparatus Pending JP2008238078A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101048516B1 (en) 2011-03-30 2011-07-12 (주)거성테크 Apparatus for anaerobic fermentation and equipment for making liquid fertilizer and purifying wastewater of livestock having the same
CN109626775A (en) * 2018-12-24 2019-04-16 农业部沼气科学研究所 A kind of continous way biogas fermentation device and method for nearly dry fermentation
CN112450124A (en) * 2020-12-21 2021-03-09 河北尚粮农业科技有限公司 Laying hen chicken room capable of naturally regulating microclimate environment and breeding method

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101048516B1 (en) 2011-03-30 2011-07-12 (주)거성테크 Apparatus for anaerobic fermentation and equipment for making liquid fertilizer and purifying wastewater of livestock having the same
CN109626775A (en) * 2018-12-24 2019-04-16 农业部沼气科学研究所 A kind of continous way biogas fermentation device and method for nearly dry fermentation
CN112450124A (en) * 2020-12-21 2021-03-09 河北尚粮农业科技有限公司 Laying hen chicken room capable of naturally regulating microclimate environment and breeding method
CN112450124B (en) * 2020-12-21 2023-10-03 河北尚粮农业科技有限公司 Laying hen house capable of naturally regulating microclimate environment and breeding method

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