JP2008235089A - Organic el display panel and its manufacturing method - Google Patents

Organic el display panel and its manufacturing method Download PDF

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JP2008235089A
JP2008235089A JP2007075093A JP2007075093A JP2008235089A JP 2008235089 A JP2008235089 A JP 2008235089A JP 2007075093 A JP2007075093 A JP 2007075093A JP 2007075093 A JP2007075093 A JP 2007075093A JP 2008235089 A JP2008235089 A JP 2008235089A
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organic
color filter
filter element
display panel
light emitting
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Hideyo Nakamura
秀世 仲村
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Fuji Electric Co Ltd
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Fuji Electric Holdings Ltd
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    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10KORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K59/00Integrated devices, or assemblies of multiple devices, comprising at least one organic light-emitting element covered by group H10K50/00
    • H10K59/80Constructional details
    • H10K59/87Passivation; Containers; Encapsulations
    • H10K59/871Self-supporting sealing arrangements
    • H10K59/8722Peripheral sealing arrangements, e.g. adhesives, sealants
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10KORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K59/00Integrated devices, or assemblies of multiple devices, comprising at least one organic light-emitting element covered by group H10K50/00
    • H10K59/80Constructional details
    • H10K59/87Passivation; Containers; Encapsulations
    • H10K59/871Self-supporting sealing arrangements
    • H10K59/8723Vertical spacers, e.g. arranged between the sealing arrangement and the OLED

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Abstract

<P>PROBLEM TO BE SOLVED: To provide an organic EL display panel of the top emission structure having a structure completely sealing with a resin based filler a laminated structural part of an organic EL light-emitting element, and also to provide its manufacturing method. <P>SOLUTION: In the organic EL display panel of the top emission structure, a rib structure is installed between a screen display region of a color filter element and the outer peripheral sealing material, and the space between the organic EL light-emitting element and the color filter element is filled with the resin based filler. <P>COPYRIGHT: (C)2009,JPO&INPIT

Description

本発明は、有機エレクトロルミネッセンス(以下「有機EL」と称す)ディスプレイパネルに関し、さらに詳しくは、有機EL発光素子の出光面とカラーフィルタ素子の入光面とを一定の間隔を保持して対向させて有機EL発光素子およびカラーフィルタ素子の外周を外周封止材により封止してなるトップエミッション構造の有機ELディスプレイパネルおよびその製造方法に関する。   The present invention relates to an organic electroluminescence (hereinafter referred to as “organic EL”) display panel. More specifically, the light emission surface of an organic EL light emitting element and the light incident surface of a color filter element are opposed to each other while maintaining a certain distance. In particular, the present invention relates to an organic EL display panel having a top emission structure in which outer peripheries of an organic EL light emitting element and a color filter element are sealed with a peripheral sealing material, and a manufacturing method thereof.

有機ELディスプレイのパネルユニットには、トップエミッション構造とボトムエミッション構造とが知られており、カラーフィルタ素子上に、有機EL発光素子を積層することにより製造されるボトムエミッション構造のパネルユニットに対して、トップエミッション構造のパネルユニットでは、個別に製造された有機EL発光素子とカラーフィルタ素子とを位置合わせして最終的に貼り合わせることにより製造される。   A panel unit of an organic EL display is known to have a top emission structure and a bottom emission structure. For a panel unit having a bottom emission structure manufactured by stacking an organic EL light emitting element on a color filter element. A panel unit having a top emission structure is manufactured by aligning and finally bonding individually manufactured organic EL light emitting elements and color filter elements.

図12はトップエミッション構造のパネルユニットの要部を模式的に示す断面図である。図12に示すように、有機EL発光素子1とカラーフィルタ素子2とが、有機EL発光素子1およびカラーフィルタ素子2の積層構造部の外気との接触を防止するための両素子の積層構造部の外周に設けられた外周封止材3によって貼り合わされ、通常、外周封止材3の高さの調整と、必要に応じて画素ごとに設けられたスペーサ6によって、有機EL発光素子の出光面とカラーフィルタ素子の入光面との間隔が一定の間隔に保持されている。   FIG. 12 is a cross-sectional view schematically showing the main part of a panel unit having a top emission structure. As shown in FIG. 12, the organic EL light-emitting element 1 and the color filter element 2 are laminated structures of both elements for preventing the organic EL light-emitting element 1 and the color filter element 2 from coming into contact with the outside air. The outer surface sealing material 3 provided on the outer periphery of the organic EL light-emitting element is usually bonded to the light emitting surface of the organic EL light-emitting element by adjusting the height of the outer peripheral sealing material 3 and, if necessary, the spacer 6 provided for each pixel. And the light incident surface of the color filter element are kept at a constant distance.

有機EL発光素子およびカラーフィルタ素子の積層構造部の封止をより完全なものとする手段として、封止領域の酸素濃度および水分濃度を調整する方法(特許文献1、2)、封止領域に窒素ガス等の不活性ガスを封入する方法(特許文献3)、液晶等の不活性な液体を封入する方法(特許文献2)、より高粘度の樹脂系接着剤等の樹脂系充填剤を充填する方法(特許文献4、5、6、7)などが知られている。   As a means for more complete sealing of the laminated structure portion of the organic EL light emitting element and the color filter element, a method of adjusting the oxygen concentration and moisture concentration of the sealing region (Patent Documents 1 and 2), Filling with an inert gas such as nitrogen gas (Patent Document 3), enclosing an inert liquid such as liquid crystal (Patent Document 2), and a resin filler such as a higher viscosity resin adhesive (Patent Documents 4, 5, 6, and 7) are known.

有機EL発光素子の出光面を構成する透明電極層の屈折率は2.0前後、一方、カラーフィルタ素子の入光面の屈折率は1.5前後であるのに対して、窒素などの気体の屈折率は1.0前後、不活性な液体の屈折率は1.3前後が限界であるので、これらの境界面における界面反射により有機EL発光素子からの光の取り出し効率が低くなる。一方、エポキシ系接着剤などは硬化後に1.5以上の高い屈折率を有しており、これらを充填剤として用いることにより、有機EL発光素子からの光の取り出し効率を高めることが期待できるばかりでなく、機械的強度の面でも有利となる。   While the refractive index of the transparent electrode layer constituting the light emitting surface of the organic EL light emitting element is around 2.0, the refractive index of the light incident surface of the color filter element is around 1.5, whereas a gas such as nitrogen is used. The refractive index of the liquid crystal is limited to about 1.0, and the refractive index of the inert liquid is limited to about 1.3. Therefore, the light extraction efficiency from the organic EL light emitting element is lowered due to the interface reflection at these boundary surfaces. On the other hand, epoxy adhesives and the like have a high refractive index of 1.5 or more after curing, and by using these as fillers, it can be expected that the efficiency of extracting light from the organic EL light emitting device will be improved. In addition, it is advantageous in terms of mechanical strength.

一般的に、これらの樹脂系接着剤は、粘度が約1〜100Pa・sと液晶等の液体充填剤に比較して高く、有機EL発光素子とカラーフィルタ素子との貼り合わせの際の広がりが悪く、図10および11に示すような単純な樹脂系充填剤の滴下貼り合わせでは、外周封止材の内側の隅々まで広がらず、2〜3インチ程度のパネルであっても、画面領域の一部が充填剤で埋まらない充填不良が発生する可能性が多々ある。   Generally, these resin-based adhesives have a viscosity of about 1 to 100 Pa · s, which is higher than that of liquid fillers such as liquid crystals, and spread when an organic EL light emitting element and a color filter element are bonded. Unfortunately, a simple resin-based filler dripping and bonding as shown in FIGS. 10 and 11 does not spread to every corner inside the outer peripheral sealing material, and even in the case of a panel of about 2 to 3 inches, There is often the possibility of poor filling that is not partially filled with filler.

また、樹脂系充填剤は、スクリューバルブやジェットディスペンサなどを用いた高精度定量吐出装置から滴下させると、機械的な稼動部によって気泡を巻き込みやすい。また、素子表面の凹凸を高速で覆う際にも気泡を作りやすく、素子表面に気泡が付着してしまう。特に画素内にスペーサ6を設けると、発生した気泡が外側へ流れにくくなる。生成した気泡は、真空下で貼り合わせを行う場合であっても、高粘度のために容易には取り除けず、画面領域に残った気泡は輝度ムラを生起する。   In addition, when the resin filler is dropped from a high-precision quantitative discharge device using a screw valve, a jet dispenser, or the like, bubbles are easily caught by a mechanical operation unit. Further, bubbles are easily formed even when the irregularities on the element surface are covered at high speed, and the bubbles adhere to the element surface. In particular, when the spacer 6 is provided in the pixel, it is difficult for the generated bubbles to flow outward. The generated bubbles are not easily removed due to the high viscosity even when they are bonded together under vacuum, and the bubbles remaining in the screen region cause uneven brightness.

樹脂系充填剤を封止領域全体に完全充填する手段として、ギャップ材を含む不連続な外周封止材に沿って樹脂を広がらせ、余剰の樹脂充填剤を外周封止材に設けた開口部からはみ出させる方法(特許文献4)、外周封止材を越えてはみ出した樹脂充填剤による電極領域の汚染を防止するために、外周封止材と電極領域との間に防護壁を設ける方法(特許文献5)、樹脂接着剤を中央領域に配した第一基板と、凸面上に反らせた第2基板とを貼り合わせる方法(特許文献6)などが提案されている。
特開平11−045778号公報 特開2001−093664号公報 特開2000−068049号公報 特開2004−207234号公報 特開2003−178866号公報 特開平11−283739号公報 特開2004−103534号公報
As a means to completely fill the entire sealing region with the resin-based filler, the resin is spread along the discontinuous outer peripheral sealing material including the gap material, and an opening provided with an excess resin filler in the outer peripheral sealing material A method of protruding from the outer peripheral sealing material (Patent Document 4), and a method of providing a protective wall between the outer peripheral sealing material and the electrode region in order to prevent contamination of the electrode region by the resin filler protruding beyond the outer peripheral sealing material ( Patent Document 5), a method (Patent Document 6) and the like in which a first substrate in which a resin adhesive is disposed in a central region and a second substrate warped on a convex surface are bonded to each other have been proposed.
JP 11-045778 A JP 2001-093664 A JP 2000-068049 A JP 2004-207234 A JP 2003-178866 A Japanese Patent Laid-Open No. 11-283737 JP 2004-103534 A

前記充填剤を外周封止材に設けた開口部からはみ出させる方法(特許文献4)は、簡便に画面全体を充填できるが、その一方で、はみ出した充填剤の処理が難しい。たとえば、複数パネル取り基板の場合には、隣のパネルとの間隔を十分に空けておかなければならず、1基板当たりのパネルの取り数が制限を受ける。また、充填剤として熱硬化型樹脂を採用することが要求され、充填剤の一部が外周封止材からはみ出した状態で熱硬化させたとき、硬化前に充填剤が膨張・流動して端子部を汚染し、導通不良を生起する。   Although the method of making the said filler protrude from the opening part provided in the outer periphery sealing material (patent document 4) can fill the whole screen easily, on the other hand, the process of the protruded filler is difficult. For example, in the case of a multi-panel substrate, a sufficient interval between adjacent panels must be provided, and the number of panels per substrate is limited. In addition, it is required to use a thermosetting resin as the filler, and when the thermosetting is carried out with a part of the filler protruding from the outer peripheral sealing material, the filler expands and flows before curing. Contaminating parts and causing poor conduction.

外周封止材と電極部との間に防護壁を設ける方法(特許文献5)では、上記外周封止材からはみ出した充填剤による電極部の汚染を防止できても、充填剤が高粘度接着剤の場合には、外周封止材内部に樹脂が均一に広がらない状態や気泡の巻き込みの課題を解決できない。さらに、基板を凸面状に反らせて貼り合わせる方法(特許文献6)では、基板を凸面上にそらせても破損しないような強度が基板に要求されることから、トップエミッション構造の有機ELディスプレイパネルには採用し難い。   In the method of providing a protective wall between the outer peripheral sealing material and the electrode part (Patent Document 5), even if the electrode part can be prevented from being contaminated by the filler protruding from the outer peripheral sealing material, the filler is bonded with high viscosity. In the case of the agent, the problem that the resin does not spread uniformly inside the outer peripheral sealing material and the problem of entrainment of bubbles cannot be solved. Furthermore, in the method in which the substrates are warped and bonded together (Patent Document 6), the substrate is required to have strength that does not break even if the substrate is warped on the convex surface. Is difficult to adopt.

本発明は、有機EL発光素子とカラーフィルタ素子との間隙に樹脂系充填剤を、気泡を巻き込むことなく完全充填することを可能とする構造を有するトップエミッション構造の有機ELディスプレイパネル、およびその製造方法を提供することを目的とする。   The present invention relates to an organic EL display panel having a top emission structure having a structure that allows a resin filler to be completely filled in a gap between an organic EL light emitting element and a color filter element without entraining air bubbles, and manufacturing the same. It aims to provide a method.

本発明者等は、前記目的を達成すべく鋭意研究した結果、有機EL発光素子の画素領域と外周封止材との間に、樹脂系充填剤の流れを案内するリブ構造体を設けることにより、少なくとも画面表示領域の全体に樹脂系充填剤を完全充填できることを見出し、本発明を完成した。   As a result of diligent research to achieve the above object, the present inventors have provided a rib structure that guides the flow of the resin filler between the pixel region of the organic EL light emitting element and the outer peripheral sealing material. The inventors have found that at least the entire screen display area can be completely filled with the resin-based filler, thereby completing the present invention.

本発明の有機ELディスプレイパネルは、有機EL発光素子の出光面とカラーフィルタ素子の入光面とを一定の間隔を保持して対向させて有機EL発光素子およびカラーフィルタ素子の外周を封止材により封止してなるトップエミッション構造の有機ELディスプレイパネルであって、前記カラーフィルタ素子の画面表示領域と外周封止材との間にリブ構造体が設けられ、前記有機EL発光素子とカラーフィルタ素子との間に樹脂系充填剤が充填されていることを特徴とする。   The organic EL display panel of the present invention has a light emitting surface of an organic EL light emitting element and a light incident surface of a color filter element facing each other while maintaining a certain distance, and the outer periphery of the organic EL light emitting element and the color filter element is sealed. An organic EL display panel having a top emission structure sealed with a rib structure provided between a screen display region of the color filter element and an outer peripheral sealing material, and the organic EL light emitting element and the color filter A resin filler is filled between the elements.

前記リブ構造体は、連続した構造体であってもよく、4隅が不連続な構造体であってもよく、さらに、前記カラーフィルタ素子の画面表示領域と外周封止剤との間に、複数列設けられていてもよい。   The rib structure may be a continuous structure or a structure with four discontinuous corners, and further, between the screen display region of the color filter element and the outer periphery sealing agent, Multiple rows may be provided.

本発明の有機ELディスプレイパネルの製造方法は、有機EL発光素子の出光面とカラーフィルタ素子の入光面とを一定の間隔を保持して対向させて有機EL発光素子およびカラーフィルタ素子の外周を封止材により封止してなるトップエミッション構造の有機ELディスプレイパネルの製造方法であって、前記カラーフィルタ素子の画面表示領域の外周に沿って連続または不連続なリブ構造体を形成する工程、前記リブ構造体の外周に沿って連続した外周封止材層を形成する工程、前記カラーフィルタ素子上に樹脂系充填剤を配する工程、前記カラーフィルタ素子と前記有機EL発光素子とを位置合わせして真空下に貼り合せた後、大気圧に戻してカラーフィルタ層と有機EL発光素子とを圧着する工程、前記外周封止材層に紫外線を照射し、外周封止材層を仮硬化させる工程、およびパネルを加熱し、前記樹脂系充填剤および外周封止材を完全硬化させる工程、を含むことを特徴とする。   The method for producing an organic EL display panel of the present invention is such that the light emitting surface of the organic EL light emitting element and the light incident surface of the color filter element are opposed to each other while maintaining a certain distance so that the outer periphery of the organic EL light emitting element and the color filter element is A method of manufacturing an organic EL display panel having a top emission structure formed by sealing with a sealing material, the step of forming a continuous or discontinuous rib structure along the outer periphery of the screen display region of the color filter element, A step of forming a continuous outer peripheral sealing material layer along an outer periphery of the rib structure, a step of arranging a resin filler on the color filter element, and aligning the color filter element and the organic EL light emitting element Then, after bonding under vacuum, returning to atmospheric pressure, pressure bonding the color filter layer and the organic EL light emitting element, irradiating the outer peripheral sealing material layer with ultraviolet rays And heating step of temporarily curing the outer peripheral sealing material layer, and the panel, characterized in that it comprises a step, to completely cure the resin filler and the outer peripheral sealing material.

前記方法は、外周封止材層の仮硬化後、個々のパネルに分断する工程をさらに含むことができる。   The method may further include a step of dividing the peripheral sealing material layer into individual panels after temporary curing.

前記方法において、カラーフィルタ素子上への樹脂系充填剤を配する工程は、樹脂系充填剤を定量滴下する工程であってもよく、定量塗布する工程であってもよい。   In the above method, the step of arranging the resin filler on the color filter element may be a step of quantitatively dropping the resin filler or a step of applying a constant amount.

本発明において、カラーフィルタ素子の画面表示領域の外周で、かつ外周封止材の内側にスペーサとしてのリブ構造体が設けられていることにより、有機EL発光素子とカラーフィルタ素子との貼り合わせに際して、カラーフィルタ素子上に配された樹脂系充填剤は、画素内で遮られることなく延展される結果、画面表示領域内に気泡が残りにくくなる。   In the present invention, a rib structure as a spacer is provided on the outer periphery of the screen display area of the color filter element and inside the outer peripheral sealing material, so that the organic EL light emitting element and the color filter element are bonded together. The resin-based filler disposed on the color filter element is spread without being blocked in the pixel, so that bubbles are less likely to remain in the screen display area.

さらに、複数のリブ構造体を設けた場合には、樹脂充填剤の流動がリブ構造体に沿って長手方向に制御される結果、画面表示領域が完全充填される確率が向上し、画面表示領域端部に残りやすい空間を画面表示領域外に押し出すことができる。   Further, when a plurality of rib structures are provided, the flow rate of the resin filler is controlled in the longitudinal direction along the rib structures, so that the probability that the screen display area is completely filled is improved. A space that tends to remain at the end can be pushed out of the screen display area.

また、その製造に際して、リブ構造体を設けたことにより、充填剤の滴下または塗布量は、リブ構造体の内側を充填するのに十分な量であればよく、外周封止材の内側を完全充填することは要求されないので、精度の高くない充填剤吐出装置を利用することが可能となる。これは、例えば空気圧制御+シリンジのディスペンサなど、気泡が入りにくい充填剤吐出装置の選択を可能とし、結果的に画面表示領域内の気泡を無くすことにつながる。
さらに、外周封止材を仮硬化させた後、個々のパネルに分断し、樹脂系充填剤と外周封止材を加熱硬化させることにより、充填剤が漏れ出すシール不良が発生しても、不良のないパネルへの影響を小さくできる。
In addition, since the rib structure is provided during the production, the amount of the filler dropped or applied may be sufficient to fill the inside of the rib structure, and the inside of the outer peripheral sealing material is completely filled. Since filling is not required, it is possible to use a filler discharging apparatus that is not highly accurate. This makes it possible to select a filler discharge device that is difficult for air bubbles to enter, such as air pressure control + syringe dispenser, and as a result, eliminates air bubbles in the screen display area.
Furthermore, after preliminarily curing the outer peripheral sealing material, it is divided into individual panels, and the resin-based filler and the outer peripheral sealing material are heat-cured, so that even if a seal failure occurs where the filler leaks, The influence on the panel without a mark can be reduced.

本発明を、本発明の実施態様を示す図1〜9に基づいて説明する。   The present invention will be described based on FIGS. 1 to 9 showing an embodiment of the present invention.

図1は、有機ELディスプレイパネルの断面構造、図2は有機EL発光素子の平面構造、図3はカラーフィルタ素子の平面構造、図4は有機ELディスプレイパネル端部の詳細構造をそれぞれ表す模式図である。   1 is a cross-sectional structure of an organic EL display panel, FIG. 2 is a plan view of an organic EL light emitting element, FIG. 3 is a plan view of a color filter element, and FIG. 4 is a schematic diagram showing a detailed structure of an end portion of the organic EL display panel. It is.

図5〜7は、それぞれカラーフィルタ素子に設けられるリブ構造体のパターンおよびカラーフィルタ素子上に樹脂充填剤を配する態様を表す樹脂充填剤の配置図であり、図8は、樹脂充填剤を配したカラーフィルタ素子に有機EL発光素子を貼り合わせた時の樹脂充填剤の延展状態を示す模式図、図9は、有機ELディスプレイパネルの多面取りの形態を表す模式図である。   FIGS. 5 to 7 are arrangement diagrams of resin fillers representing patterns of rib structures provided in the color filter elements and modes of arranging resin fillers on the color filter elements, respectively. FIG. 9 is a schematic diagram showing a multi-planar configuration of the organic EL display panel, and FIG. 9 is a schematic view showing the extended state of the resin filler when the organic EL light emitting element is bonded to the arranged color filter element.

図10および11は、従来方法により樹脂充填剤を配したカラーフィルタ素子に有機EL発光素子を貼り合わせた時の樹脂充填剤の延展状態を示す模式図、図12は、従来の有機ELディスプレイパネルの断面構造を表す模式図である。   FIGS. 10 and 11 are schematic views showing an extended state of the resin filler when the organic EL light emitting element is bonded to the color filter element in which the resin filler is arranged by a conventional method, and FIG. 12 is a conventional organic EL display panel. It is a schematic diagram showing the cross-sectional structure.

本発明のトップエミッション構造を有する有機ELパネルユニットは、図2に示す有機EL発光素子1と図3に示すカラーフィルタ素子2とを備える。そして、図1に示すように有機EL発光素子1の画素領域Aに対応した出光面とカラーフィルタ素子2の画面表示領域Bに対応した入光面とを対向させ、リブ構造体4を介して一定の間隔を保持し、有機EL発光素子1およびカラーフィルタ素子2の外周を外周封止材3により封止した基本構造を有する。リブ構造体4はカラーフィルタ素子2の画面表示領域Bと外周封止材3との間に設けられ、有機EL発光素子1、カラーフィルタ素子2および外周封止材3で画定される空間部に樹脂系充填剤5が充填されている。なお、有機EL発光素子1とカラーフィルタ素子2との間隔を保持するために、さらに必要な場合には、スペーサを設けてもよい。   The organic EL panel unit having the top emission structure of the present invention includes the organic EL light emitting element 1 shown in FIG. 2 and the color filter element 2 shown in FIG. Then, as shown in FIG. 1, the light exit surface corresponding to the pixel region A of the organic EL light emitting element 1 and the light incident surface corresponding to the screen display region B of the color filter element 2 are opposed to each other through the rib structure 4. It has a basic structure in which the outer periphery of the organic EL light emitting element 1 and the color filter element 2 is sealed with the outer peripheral sealing material 3 while maintaining a constant interval. The rib structure 4 is provided between the screen display region B of the color filter element 2 and the outer periphery sealing material 3, and in a space defined by the organic EL light emitting element 1, the color filter element 2 and the outer periphery sealing material 3. A resin filler 5 is filled. In addition, in order to maintain the space | interval of the organic EL light emitting element 1 and the color filter element 2, you may provide a spacer as needed.

上記有機ELパネルユニットは、以下の方法により製造することができる。   The organic EL panel unit can be manufactured by the following method.

図3に示すように、有機EL発光素子1の積層構造部を取り囲み、カラーフィルタ素子2の画面表示領域Bの外周に沿って、連続した、または不連続のリブ構造体4、およびリブ構造体4の外周に沿って外周封止材3層を形成する。   As shown in FIG. 3, a rib structure 4 that is continuous or discontinuous along the outer periphery of the screen display region B of the color filter element 2 and surrounds the stacked structure portion of the organic EL light emitting element 1, and the rib structure 4 layers of the outer peripheral sealing material are formed along the outer periphery of 4.

次いで、図5〜7に示すようにカラーフィルタ素子2の上面に樹脂系充填剤5を滴下法または塗布法を採用して配し、カラーフィルタ素子2の画面表示領域Bと有機EL発光素子1の画素領域Aとを、要すればスペーサを介して位置合わせして真空下に貼り合わせた後、大気圧に戻して有機EL発光素子1とカラーフィルタ素子2とを圧着し、樹脂充填剤5を図8に示すように有機EL発光素子1、カラーフィルタ素子2およびリブ構造体4によって画定される空間部内に延展させて充満させる。   Next, as shown in FIGS. 5 to 7, the resin filler 5 is disposed on the upper surface of the color filter element 2 by employing a dropping method or a coating method, and the screen display region B of the color filter element 2 and the organic EL light emitting element 1 are arranged. If necessary, the pixel region A is aligned through a spacer and bonded under vacuum, and then returned to atmospheric pressure, the organic EL light-emitting element 1 and the color filter element 2 are pressure-bonded, and the resin filler 5 As shown in FIG. 8, it is extended and filled in the space defined by the organic EL light emitting element 1, the color filter element 2, and the rib structure 4.

次いで、外周封止材3層に紫外線を照射して仮硬化させ、図9に示すような複数パネル取りの場合には、それぞれのパネルに分断した後、個々のパネルを加熱して樹脂充填剤5および外周封止材3を完全硬化させる。   Next, the outer peripheral sealing material 3 layers are irradiated with ultraviolet rays to be temporarily cured, and in the case of taking a plurality of panels as shown in FIG. 9, after dividing into each panel, each panel is heated to form a resin filler. 5 and the outer peripheral sealing material 3 are completely cured.

本発明において、リブ構造体4は、有機EL発光素子1の積層構造部を取り囲む、カラーフィルタ素子2の画面表示領域Bの外周に沿って配置されるリブ幅が10〜20μmの構造体である。   In the present invention, the rib structure 4 is a structure having a rib width of 10 to 20 μm that is disposed along the outer periphery of the screen display region B of the color filter element 2 that surrounds the stacked structure portion of the organic EL light emitting element 1. .

リブ構造体4は、図5に示すように連続していてもよく、また、図3、6〜8に示すように不連続であってもよい。また、図3〜8では、3列のリブ構造体が並列して設けられているが、1〜2列でもよく、さらに多数の列となっていてもよい。少なくとも4隅が不連続となっている、3〜5列の並列するリブ構造体が好ましい。   The rib structure 4 may be continuous as shown in FIG. 5 or may be discontinuous as shown in FIGS. In addition, in FIGS. 3 to 8, three rows of rib structures are provided in parallel, but one or two rows may be provided, and more rows may be provided. 3-5 rows of parallel rib structures with at least four corners being discontinuous are preferred.

図3、6および7に示したように、少なくとも4隅が不連続なリブ構造体4とすることにより、樹脂系充填剤5の延展時に、図8に示したように樹脂系充填剤5のリブ構造体4の4隅への流れが助長され、図10に示したような画面表示領域Bの4隅部の未充填部Cの生成を防止することができる。   As shown in FIGS. 3, 6, and 7, by forming the rib structure 4 having at least four corners that are discontinuous, when the resin filler 5 is extended, as shown in FIG. The flow to the four corners of the rib structure 4 is promoted, and generation of unfilled portions C at the four corners of the screen display region B as shown in FIG. 10 can be prevented.

また、リブ構造体4を複数列設けることにより、樹脂系充填剤5の延展時に、図8に示したように樹脂系充填剤5の複数列のリブ構造体4のそれぞれに沿った流れが助長され、図11に示したような有機EL発光素子1の積層構造部と封止材3との間の未充填部Cの生成を防止することができる。リブ構造体4を多重に設ける場合のリブ構造4の間隔は、通常、100〜300μmの範囲である。   Further, by providing a plurality of rows of rib structures 4, the flow along each of the plurality of rows of rib structures 4 of the resin filler 5 is promoted as shown in FIG. 8 when the resin filler 5 is extended. Thus, the generation of the unfilled portion C between the stacked structure portion of the organic EL light emitting element 1 and the sealing material 3 as shown in FIG. 11 can be prevented. When the rib structures 4 are provided in multiple layers, the interval between the rib structures 4 is usually in the range of 100 to 300 μm.

リブ構造体4および外周封止材3には、通常、感光性樹脂が用いられ、それぞれフォトリソグラフ法等、公知の方法により形成される。   Photosensitive resin is usually used for the rib structure 4 and the outer peripheral sealing material 3, and each is formed by a known method such as a photolithography method.

本発明において、樹脂系充填剤5には、カラーフィルタ素子2への有機EL発光素子1の貼り合わせによって、カラーフィルタ素子2上に配した樹脂系充填剤5がそれぞれの表面に密着して延展されるような熱硬化性樹脂が用いられる。熱硬化性樹脂の未硬化時の粘度は0.1Pa・s〜100Pa・sであるが、未硬化時の粘度が、好ましくは0.2Pa・s〜10Pa・s、さらに好ましくは1Pa・s〜10Pa・sの熱硬化性樹脂を用いる。   In the present invention, the resin filler 5 disposed on the color filter element 2 is adhered to and spreads on the surface of the resin filler 5 by bonding the organic EL light emitting element 1 to the color filter element 2. Such a thermosetting resin is used. The uncured viscosity of the thermosetting resin is 0.1 Pa · s to 100 Pa · s, but the uncured viscosity is preferably 0.2 Pa · s to 10 Pa · s, more preferably 1 Pa · s to A 10 Pa · s thermosetting resin is used.

樹脂系充填剤5の未硬化時の粘度が0.2Pa・s未満では、未充填部の生成を比較的容易に解消できるが、硬化樹脂の水分遮断性が不足するものがあり、封止が不十分となる可能性がある。一方、未硬化時の粘度が10Pa・sを越えると、本発明の構成によっても未充填部の生成や気泡の残留などの充填不良が発生し易くなる。   When the uncured viscosity of the resin-based filler 5 is less than 0.2 Pa · s, the formation of the unfilled portion can be eliminated relatively easily, but there are cases where the moisture barrier property of the cured resin is insufficient, and sealing is performed. It may be insufficient. On the other hand, when the viscosity at the time of uncuring exceeds 10 Pa · s, filling failure such as generation of unfilled portions and residual bubbles is likely to occur even with the configuration of the present invention.

さらに、樹脂系充填剤5は、硬化後に1.3〜2の屈折率、および波長400〜800nmにおいて50%以上の光透過率を有することが好ましい。このような樹脂系充填剤5として、エポキシ樹脂系、シリコン系、フッ素樹脂系等の各種樹脂系接着剤を挙げることができる。   Further, the resin filler 5 preferably has a refractive index of 1.3 to 2 after curing and a light transmittance of 50% or more at a wavelength of 400 to 800 nm. Examples of such resin filler 5 include various resin adhesives such as epoxy resin, silicon, and fluororesin.

カラーフィルタ素子2上に配される樹脂充填剤5の量は、有機EL発光素子1、カラーフィルタ素子2およびリブ構造体4により画定される空間容積を越え、有機EL発光素子1、カラーフィルタ素子2および外周封止材3により画定される空間容積未満である。有機EL発光素子1、カラーフィルタ素子2およびリブ構造体4により画定される空間内が、樹脂系充填剤5により充満されることにより、有機EL発光素子1の積層構造部分の樹脂系充填剤5による完全な封止が達成される。   The amount of the resin filler 5 disposed on the color filter element 2 exceeds the space volume defined by the organic EL light emitting element 1, the color filter element 2, and the rib structure 4, and the organic EL light emitting element 1, the color filter element 2 and the space volume defined by the outer peripheral sealing material 3. The space defined by the organic EL light-emitting element 1, the color filter element 2 and the rib structure 4 is filled with the resin-based filler 5, whereby the resin-based filler 5 in the laminated structure portion of the organic EL light-emitting element 1. A complete seal is achieved.

樹脂系充填剤5をカラーフィルタ素子2上に配する方法は、図5に示すような中央滴下法、図6に示すような多点分散滴下法、図7に示すような線状塗布法のいずれをも採用することができる。これらは画面サイズや形状により適宜選択されるが、樹脂系充填剤5がリブ構造体4の内壁に沿って広がる傾向があることから、樹脂系充填剤5の滴下位置や塗布位置には特別の制限はない。2〜3インチ程度の画面サイズの場合、中心1点滴下で十分である。   The resin filler 5 is disposed on the color filter element 2 by a central dropping method as shown in FIG. 5, a multi-point dispersion dropping method as shown in FIG. 6, or a linear coating method as shown in FIG. Either can be adopted. These are appropriately selected depending on the screen size and shape, but since the resin filler 5 tends to spread along the inner wall of the rib structure 4, there is a special drop position or application position of the resin filler 5. There is no limit. In the case of a screen size of about 2 to 3 inches, one point drop at the center is sufficient.

樹脂系充填剤5の滴下法や塗布法には、前記したように従来に比較して充填剤の定量精度に余裕があることから、高精度定量吐出装置のみならず、吐出精度が10%程度であるが、気泡の巻き込みのない空気圧制御のディスペンサでシリンジから吐出させる方法を採用することができる。   As described above, the dropping method and the coating method of the resin-based filler 5 have a margin in the quantitative accuracy of the filler as compared with the conventional method, so that not only the high-precision quantitative discharge device but also the discharge accuracy is about 10%. However, it is possible to employ a method of discharging from a syringe with a pneumatically controlled dispenser that does not involve bubbles.

カラーフィルタ素子2上に樹脂系充填剤5を配した後、カラーフィルタ素子2と有機EL発光素子1との貼り合わせを、通常、50Pa以下の真空下で行い、次いで、大気圧に戻すことによって、カラーフィルタ素子2と有機EL発光素子1とを圧着させる。   After arranging the resin filler 5 on the color filter element 2, the color filter element 2 and the organic EL light emitting element 1 are usually bonded together under a vacuum of 50 Pa or less, and then returned to atmospheric pressure. The color filter element 2 and the organic EL light emitting element 1 are pressure-bonded.

カラーフィルタ素子2と有機EL発光素子1との、貼り合わせおよび圧着により、カラーフィルタ素子2上に配された樹脂系充填剤5の一部は、図8に示すようにリブ構造体4の内壁に沿って、残りはリブ構造体4を越えて延展され、外周封止材3の内側に充満する。   A part of the resin filler 5 disposed on the color filter element 2 by bonding and pressure bonding between the color filter element 2 and the organic EL light emitting element 1 is the inner wall of the rib structure 4 as shown in FIG. The remaining portion extends beyond the rib structure 4 and fills the inside of the outer peripheral sealing material 3.

カラーフィルタ素子2と有機EL発光素子1との真空下における貼り合わせにより、有機EL発光素子1、カラーフィルタ素子2およびリブ構造体4により画定される空間内から気泡が空間外へ効率的に排出される。特に、気泡の停滞しやすい4隅が不連続なリブ構造体4とすることにより、気泡のリブ構造体4の外部への排出が助長され、有機EL発光素子1の積層構造部の樹脂系充填剤5による完全被覆が達成される。   By bonding the color filter element 2 and the organic EL light emitting element 1 under vacuum, air bubbles are efficiently discharged out of the space defined by the organic EL light emitting element 1, the color filter element 2, and the rib structure 4. Is done. In particular, by making the rib structure 4 in which the four corners where bubbles tend to stagnate are discontinuous, the discharge of the bubbles to the outside of the rib structure 4 is promoted, and the resin-based filling of the laminated structure portion of the organic EL light emitting element 1 is facilitated. Complete coverage with agent 5 is achieved.

系を大気圧に戻すことにより、有機EL発光素子1をカラーフィルタ素子2に圧着させた後、外周封止材3層に紫外線を照射して、外周封止材3を仮硬化させ、図9に示すようにパネルユニットの多面取りの場合には、それぞれのパネルユニットに分断する。   By returning the system to atmospheric pressure, the organic EL light emitting element 1 is pressure-bonded to the color filter element 2, and then the outer peripheral sealing material 3 layer is irradiated with ultraviolet rays to temporarily cure the outer peripheral sealing material 3, FIG. As shown in FIG. 2, when the panel unit is multi-chamfered, it is divided into each panel unit.

この段階で、各パネルユニットの樹脂系充填剤5の充填不良をチェックし、充填不良のないパネルユニットを加熱処理し、樹脂系充填剤5および外周封止材3を完全硬化させる。   At this stage, the filling failure of the resin filler 5 of each panel unit is checked, the panel unit without filling failure is heat-treated, and the resin filler 5 and the outer peripheral sealing material 3 are completely cured.

本発明において、トップエミッション構造のパネルユニットを構成する有機EL発光素子1は、アクティブマトリックス方式またはパッシブマトリックス方式のいずれであってもよく、アクティブマトリックス方式のパネルユニットは、図4に示すように、基板10、該基板10上に形成されたTFT構造およびそれを覆う平坦化樹脂層を含む下地層11、該下地層11上にパターン化された絶縁膜12および反射電極13、該絶縁膜および反射電極13上の有機発光層を含む複数の有機層の積層体からなる有機EL発光層14、有機EL発光層14上にパターン化された透明電極15、透明電極15と制御端子とを接続する配線および画素部全面を覆うバリア層16で、通常、構成されている。   In the present invention, the organic EL light-emitting element 1 constituting the panel unit of the top emission structure may be either an active matrix type or a passive matrix type, and the active matrix type panel unit is as shown in FIG. Substrate 10, base layer 11 including a TFT structure formed on substrate 10 and a planarizing resin layer covering it, insulating film 12 and reflective electrode 13 patterned on base layer 11, insulating film and reflection Organic EL light-emitting layer 14 composed of a stack of a plurality of organic layers including an organic light-emitting layer on electrode 13, transparent electrode 15 patterned on organic EL light-emitting layer 14, wiring for connecting transparent electrode 15 and the control terminal The barrier layer 16 that covers the entire surface of the pixel portion is usually configured.

トップエミッション構造のパネルユニットの一方を構成するカラーフィルタ素子2は、図4に示すように、ガラス基板などの透明基板20、および該透明基板20上にパターン化されているブラックマトリックス層21およびカラーフィルタ層22で構成され、マルチカラー方式およびフルカラー方式の場合には、前記カラーフィルタ層22上に色変換層23、前記ブラックマトリックス層21および色変換層23を有する。さらに樹脂充填剤の流動性やアウトガスを考慮して、色変換層23上に高分子平坦化層および該高分子平坦化層を覆うパッシベーション層が設けられていてもよい。   As shown in FIG. 4, the color filter element 2 constituting one of the panel units having the top emission structure includes a transparent substrate 20 such as a glass substrate, and a black matrix layer 21 and a color patterned on the transparent substrate 20. In the case of the multi-color system and the full-color system, the color conversion layer 23, the black matrix layer 21, and the color conversion layer 23 are provided on the color filter layer 22. Further, in consideration of the fluidity and outgas of the resin filler, a polymer flattening layer and a passivation layer covering the polymer flattening layer may be provided on the color conversion layer 23.

本発明を実施例によりさらに詳細に説明する。   The invention is explained in more detail by means of examples.

[有機EL発光素子1]
200mm×200mm×0.7mm厚さの無アルカリガラス基板10上に、図4に示したように複数のTFT、それを覆う平坦化樹脂上に厚さ300nmのSiOパッシベーション膜を形成し、その上に厚さ50nmのIZO膜をRF−プレーナマグネトロンを用いArガス雰囲気下にスパッタ成膜し、さらにレジスト剤(OFRP−800、商品名、東京応化(株)製)を塗布し、露光・現像し、ウェットエッチングによって、サブピクセルごとに島状に分離した下地パターン11を形成した。この下地パターンは、平坦化層とパッシベーション層に設けられたコンタクトホールによって、TFTと接続された。
[Organic EL light emitting device 1]
On the alkali-free glass substrate 10 having a thickness of 200 mm × 200 mm × 0.7 mm, a plurality of TFTs as shown in FIG. 4 and a SiO 2 passivation film having a thickness of 300 nm are formed on a planarizing resin covering the TFTs. An IZO film with a thickness of 50 nm is sputter-deposited in an Ar gas atmosphere using an RF-planar magnetron, and a resist agent (OFRP-800, trade name, manufactured by Tokyo Ohka Kogyo Co., Ltd.) is applied, and exposure and development are performed. Then, the base pattern 11 separated into islands for each subpixel was formed by wet etching. This base pattern was connected to the TFT by contact holes provided in the planarization layer and the passivation layer.

次に、前記下地パターン11上にAg膜を200nm厚さにスパッタ成膜し、下地パターン11からはみ出ないように、同様の方法で島状にパターン化し反射電極13を形成した。   Next, an Ag film having a thickness of 200 nm was formed on the base pattern 11 by sputtering, and the reflective electrode 13 was formed by patterning into an island shape by the same method so as not to protrude from the base pattern 11.

反射電極13上に1μmのノボラック系樹脂(JEM−700R2:商品名、JSR社製)をスピンコート法により塗布し、フォトリソグラフ法によって発光させる部位(画素)に窓を開けるように有機絶縁膜12を形成した。   A 1 μm novolak resin (JEM-700R2: trade name, manufactured by JSR) is applied on the reflective electrode 13 by a spin coating method, and the organic insulating film 12 is opened so as to open a window at a portion (pixel) that emits light by a photolithographic method. Formed.

次いで、上記基板を抵抗加熱装置内に装着し、反射電極13上に厚さ1.5nmのLiを堆積させ、陰極バッファ層を形成し、さらに、真空層内圧を1×10−4Paに減圧し、それを維持したまま電子輸送層、有機EL発光層、正孔輸送層および正孔注入層を順次積層し、有機EL層14を形成した。それぞれの層は、0.1nm/secの蒸着速度で積層された。 Next, the substrate is mounted in a resistance heating device, Li having a thickness of 1.5 nm is deposited on the reflective electrode 13, a cathode buffer layer is formed, and the internal pressure of the vacuum layer is reduced to 1 × 10 −4 Pa. While maintaining this, an electron transport layer, an organic EL light emitting layer, a hole transport layer, and a hole injection layer were sequentially laminated to form an organic EL layer 14. Each layer was laminated at a deposition rate of 0.1 nm / sec.

電子輸送層として膜厚20nmのトリス(8−ヒドロキキノリナト)アルミニウム(Alq)、有機EL発光層として膜厚30nmの4,4´−ビス(2,2´−ジフェニルビニル)ビフェニル(DPVBi)、正孔輸送層として膜厚10nmの4,4´−[N−(1−ナフチル)−N−フェニルアミノ]ビフェニル(α−NPD)、および正孔注入層として膜厚100nmの銅フタロシアニン(CuPc)が積層された。 Tris (8-hydroquinolinato) aluminum (Alq 3 ) with a thickness of 20 nm as an electron transport layer, and 4,4′-bis (2,2′-diphenylvinyl) biphenyl (DPVBi) with a thickness of 30 nm as an organic EL light emitting layer 4,4 ′-[N- (1-naphthyl) -N-phenylamino] biphenyl (α-NPD) having a thickness of 10 nm as a hole transport layer, and copper phthalocyanine (CuPc) having a thickness of 100 nm as a hole injection layer ) Was laminated.

次いで、有機EL層14上に透明電極15をスパッタ成膜する際のダメージ緩和層としてMgAg50nmを蒸着し、対向スパッタ装置に真空を破らずに移動させ、透明電極15としてIZOを100nm成膜した。MgAgおよびIZOの成膜には、複数のユニットの表示部に対応する位置に四角窓が空いたメタルマスクを使用した。さらに、真空を破らずにCVD装置に移動させ、バリア層16としてSiNを2μmの厚さに全面被覆し、有機EL発光素子1を得た。   Next, MgAg 50 nm was vapor-deposited as a damage mitigating layer when the transparent electrode 15 was formed on the organic EL layer 14 by sputtering, and moved to the counter sputtering apparatus without breaking the vacuum, and IZO was formed as the transparent electrode 15 with a thickness of 100 nm. For the film formation of MgAg and IZO, a metal mask having a square window opened at a position corresponding to the display portion of a plurality of units was used. Furthermore, it was moved to a CVD apparatus without breaking the vacuum, and SiN as a barrier layer 16 was entirely coated to a thickness of 2 μm to obtain the organic EL light emitting device 1.

[カラーフィルタ素子2]
200mm×200mm×0.7mm厚さの無アルカリガラス(1737:コーニング社製)に、図9に示すように複数のユニットに対応したブラックマトリックス(CK−7001、富士フィルムARCH製)21をフォトリソグラフ法により形成した。
[Color filter element 2]
Photolithograph of black matrix (CK-7001, manufactured by Fuji Film ARCH) 21 corresponding to a plurality of units as shown in FIG. 9 on non-alkali glass (1737: manufactured by Corning) having a thickness of 200 mm × 200 mm × 0.7 mm. Formed by the method.

次いで、ブラックマトリックス21のパターン間に、赤色(CR−7001、富士フィルムARCH製)、緑色(CG−7001、富士フィルムARCH製)および青色(CB−7001、富士フィルムARCH製)の厚さ約2μmの短冊状のカラーフィルタ22をフォトリソグラフ法により形成した。   Next, between the patterns of the black matrix 21, the thickness of red (CR-7001, manufactured by Fuji Film ARCH), green (CG-7001, manufactured by Fuji Film ARCH) and blue (CB-7001, manufactured by Fuji Film ARCH) is about 2 μm. The strip-shaped color filter 22 was formed by a photolithographic method.

次いで、カラーフィルタと同じフォトマスクを用いて、厚さ約10μmの色変換層23を形成した。塗布液として、フォトレジスト(V259PAP5:新日鐵化学(株)製)25gに対して、緑色変換層にはクマリン6を0.05g、赤色変換層にはローダミンBを0.04gおよびクマリン6を0.05g添加して用いた。なお、青色変換層には、有機EL発光素子1の発光スペクトルが青色〜青緑色(400nm〜550nm)であることから、透明なアクリル系樹脂を用いた。   Next, a color conversion layer 23 having a thickness of about 10 μm was formed using the same photomask as the color filter. As a coating solution, 25 g of photoresist (V259PAP5: manufactured by Nippon Steel Chemical Co., Ltd.), 0.05 g of coumarin 6 for the green conversion layer, 0.04 g of rhodamine B and coumarin 6 for the red conversion layer 0.05 g was added and used. In addition, since the emission spectrum of the organic EL light-emitting element 1 is blue to blue-green (400 nm to 550 nm), a transparent acrylic resin was used for the blue conversion layer.

次いで、図4に示したように、カラーフィルタパターンの外周のブラックマトリックス21上に、フォトリソグラフ法により、4隅が不連続となっている、幅12μmのリブ構造体(CR−600:日立化成工業(株)製)3を、間隔180μmで3重に形成し、カラーフィルタ素子2を得た。   Next, as shown in FIG. 4, on the black matrix 21 on the outer periphery of the color filter pattern, a rib structure (CR-600: Hitachi Chemical Co., Ltd.) having a discontinuous four corners and having four corners discontinuous by photolithography. Kogyo Co., Ltd.) 3 was formed in triplicate at intervals of 180 μm to obtain a color filter element 2.

リブ構造体4の形成位置は、図4に示したように、有機EL発光素子1の透明電極(陽極)15の取り出し部17より外側で、パッシベーション層16に接触する位置としたが、より内側の画面領域に近い方に設けてもよい。   As shown in FIG. 4, the rib structure 4 is formed at a position outside the take-out portion 17 of the transparent electrode (anode) 15 of the organic EL light emitting device 1 and in contact with the passivation layer 16. It may be provided closer to the screen area.

[有機ELディスプレイパネル]
上記で得られたカラーフィルタ素子2を、酸素濃度5ppm以下、かつ水分濃度5ppm以下に制御された、貼り合わせ装置に移動し、カラーフィルタ素子2の入光面を上に向けてセットし、複数画面のそれぞれの外周にディスペンサを用いてエポキシ系紫外線硬化型接着剤(粘度:約130Pa・s、XNR5516:ナガセケムテックス社製)を塗布し外周封止材3層を形成し、さらに画面表示領域の中央付近に樹脂系充填剤5として、前記外周封止材層3よりも低粘度の熱硬化型エポキシ接着剤(粘度:約2Pa・s)を、空気圧制御+シリンジのディスペンサシステムを用いて滴下した(図9)。上記エポキシ系紫外線硬化型接着剤および熱硬化型エポキシ接着剤の粘度は回転式粘度計を用い、25℃、1atmの環境で測定した値である。
[Organic EL display panel]
The color filter element 2 obtained above is moved to a bonding apparatus in which the oxygen concentration is controlled to 5 ppm or less and the water concentration is 5 ppm or less, and the color filter element 2 is set with the light incident surface facing upward. Epoxy UV curable adhesive (viscosity: about 130 Pa · s, XNR5516: manufactured by Nagase ChemteX Corporation) is applied to each outer periphery of the screen using a dispenser to form three layers of outer peripheral sealing material, and screen display area A thermosetting epoxy adhesive (viscosity: about 2 Pa · s) having a viscosity lower than that of the outer peripheral sealing material layer 3 is dropped as a resin filler 5 in the vicinity of the center using an air pressure control + syringe dispenser system. (FIG. 9). The viscosity of the epoxy ultraviolet curable adhesive and the thermosetting epoxy adhesive is a value measured using a rotary viscometer in an environment of 25 ° C. and 1 atm.

次に、前記で得られた有機EL発光素子1の出光面を下向きにして、カラーフィルタ素子2の入光面と対向させてセットし、装置内を約10Paまで減圧して両素子間の間隔を約20μmまで接近させ、アラインメント機構で両素子の画素位置の位置合わせを行った後、装置内を大気圧に戻しつつ両素子間に僅かの荷重を付加して圧着させ、リブ構造体4の上端が有機EL発光素子1に接触する位置で荷重の付加を停止した。このとき、外周封止材3層の上端が有機EL発光素子1のガラス基板10に密着していた。   Next, the light emitting surface of the organic EL light-emitting device 1 obtained as described above is set face down and opposed to the light incident surface of the color filter device 2, and the inside of the apparatus is reduced to about 10 Pa to reduce the distance between the two devices. Is adjusted to approximately 20 μm, and the pixel positions of both elements are aligned by an alignment mechanism, and then the pressure inside the apparatus is returned to atmospheric pressure by applying a slight load between the two elements and crimping. The load application was stopped at a position where the upper end was in contact with the organic EL light emitting device 1. At this time, the upper ends of the three layers of the outer peripheral sealing material were in close contact with the glass substrate 10 of the organic EL light emitting device 1.

両素子間の圧着時に、カラーフィルタ素子2上に滴下した樹脂系充填剤5は、図8に示したようにリブ構造体4の内壁に沿って外周封止材3の内側に至るまでパネルの全面に広がり、リブ構造体4より内側に完全に充満された。     The resin filler 5 dripped onto the color filter element 2 during the pressure bonding between the two elements, along the inner wall of the rib structure 4 as shown in FIG. It spreads over the entire surface and was completely filled inside the rib structure 4.

次に、カラーフィルタ素子2のガラス基板20側から外周封止剤3層部に紫外線を照射して、外周封止材3層を仮硬化させ、一般環境に取り出し、自動ガラススクライバーとブレイク装置を用いて、個々のパネルユニットに分割した。分割した個々のパネルユニットの樹脂充填剤5の気泡の巻き込み、充填不足、過剰充填などによる充填不良は0であった。   Next, the outer peripheral sealing agent 3 layer part is irradiated with ultraviolet rays from the glass substrate 20 side of the color filter element 2 to temporarily cure the outer peripheral sealing material 3 layer, taken out to the general environment, and an automatic glass scriber and breaker are installed. Used and divided into individual panel units. Filling failure due to entrainment of bubbles of the resin filler 5 of each divided panel unit, insufficient filling, excessive filling, etc. was zero.

分割した個々のパネルユニットを、十分な間隔を置いて加熱炉に入れ、80℃で1時間加熱し、炉内で30分間自然放冷して取り出した。   The divided individual panel units were placed in a heating furnace at a sufficient interval, heated at 80 ° C. for 1 hour, and naturally cooled in the furnace for 30 minutes and taken out.

次いで、個々のパネルユニットをドライエッチング装置に入れ、配線部18、端子部19およびIC接続用パッドを覆うバリア層を除去し、フレキシブルプリント基板などとの接続が可能なように端子部を露出させ、本発明の有機ELディスプレイパネルを得た。   Next, each panel unit is put into a dry etching apparatus, the barrier layer covering the wiring part 18, the terminal part 19 and the IC connection pad is removed, and the terminal part is exposed so that it can be connected to a flexible printed circuit board or the like. The organic EL display panel of the present invention was obtained.

本発明の有機ELディスプレイパネルの断面構造を示す模式図。The schematic diagram which shows the cross-section of the organic electroluminescence display panel of this invention. 本発明の有機ELディスプレイパネルを構成する有機EL発光素子の平面構造を示す模式図。The schematic diagram which shows the planar structure of the organic electroluminescent light emitting element which comprises the organic electroluminescent display panel of this invention. 本発明の有機ELディスプレイパネルを構成するカラーフィルタ素子の平面構造を示す模式図。The schematic diagram which shows the planar structure of the color filter element which comprises the organic electroluminescent display panel of this invention. 有機ELディスプレイパネルの断面端部構造を示す模式図。The schematic diagram which shows the cross-section edge part structure of an organic electroluminescence display panel. リブ構造体のパターンおよび樹脂充填剤の中央滴下の態様図。The aspect figure of the pattern of a rib structure, and the center dripping of the resin filler. 樹脂充填剤の分散滴下の態様図。FIG. 3 is a diagram illustrating an embodiment of dispersion dropping of a resin filler. 樹脂充填剤の線状塗布の態様図。The aspect diagram of linear application | coating of a resin filler. 両素子の貼り合せ、圧着による樹脂充填剤の延展状態を示す模式図。The schematic diagram which shows the extended state of the resin filler by bonding of both elements and pressure bonding. 複数パネルの多面取りの説明図。Explanatory drawing of multiple chamfering of a plurality of panels. 従来技術による、両素子の貼り合せ、圧着による樹脂充填剤の延展状態を示す模式図。The schematic diagram which shows the spreading | diffusion state of the resin filler by bonding of both elements by conventional technology, and crimping | compression-bonding. 従来技術による、両素子の貼り合せ、圧着による樹脂充填剤の延展状態を示す模式図。The schematic diagram which shows the spreading | diffusion state of the resin filler by bonding of both elements by conventional technology, and crimping | compression-bonding. 従来の有機ELディスプレイパネルの断面構造を示す模式図。The schematic diagram which shows the cross-section of the conventional organic EL display panel.

符号の説明Explanation of symbols

1 有機EL発光素子
10 有機EL発光素子の基板
11 TFT構造を含む下地層
12 絶縁層
13 反射電極(陰極)
14 有機EL層
15 透明電極(陽極)
16 パッシベーション層
17 陽極取り出し部
18 配線
19 端子
2 カラーフィルタ素子
20 カラーフィルタ素子の基板
21 ブラックマトリックス
22 カラーフィルタ
23 色変換層
3 外周封止材
4 リブ構造体
5 樹脂系充填剤
6 スペーサ
7 真空状態に維持された空間部
A 有機EL発光素子の画素領域
B カラーフィルタ素子の画面表示領域
C 充填剤が充填されていない空間部
DESCRIPTION OF SYMBOLS 1 Organic EL light emitting element 10 Substrate of organic EL light emitting element 11 Underlayer including TFT structure 12 Insulating layer 13 Reflective electrode (cathode)
14 Organic EL layer 15 Transparent electrode (anode)
DESCRIPTION OF SYMBOLS 16 Passivation layer 17 Anode extraction part 18 Wiring 19 Terminal 2 Color filter element 20 Color filter element substrate 21 Black matrix 22 Color filter 23 Color conversion layer 3 Peripheral sealing material 4 Rib structure 5 Resin filler 6 Spacer 7 Vacuum state A space area maintained in A A pixel area of an organic EL light emitting element B Screen display area of a color filter element C Space area not filled with a filler

Claims (13)

有機EL発光素子の出光面とカラーフィルタ素子の入光面とを一定の間隔を保持して対向させて有機EL発光素子およびカラーフィルタ素子の外周を封止材により封止してなるトップエミッション構造の有機ELディスプレイパネルであって、
前記カラーフィルタ素子の画面表示領域と外周封止材との間にリブ構造体が設けられ、前記有機EL発光素子とカラーフィルタ素子との間に樹脂系充填剤が充填されていることを特徴とする有機ELディスプレイパネル。
A top emission structure in which the light emission surface of the organic EL light emitting element and the light incident surface of the color filter element are opposed to each other while maintaining a certain distance, and the outer periphery of the organic EL light emitting element and the color filter element is sealed with a sealing material An organic EL display panel
A rib structure is provided between the screen display region of the color filter element and the outer peripheral sealing material, and a resin filler is filled between the organic EL light emitting element and the color filter element. Organic EL display panel.
前記リブ構造体が、連続したリブ構造体である請求項1に記載の有機ELディスプレイパネル。   The organic EL display panel according to claim 1, wherein the rib structure is a continuous rib structure. 前記リブ構造体が、少なくとも4隅が不連続なリブ構造体である請求項1に記載の有機ELディスプレイパネル。   The organic EL display panel according to claim 1, wherein the rib structure is a rib structure having at least four corners that are discontinuous. 前記リブ構造体が、複数列設けられていることを特徴とする請求項1ないし3のいずれか一項に記載の有機ELディスプレイパネル。   The organic EL display panel according to claim 1, wherein the rib structures are provided in a plurality of rows. 前記リブ構造体が、幅10〜20μmを有することを特徴とする請求項1ないし4のいずれか一項に記載の有機ELディスプレイパネル。   The organic EL display panel according to claim 1, wherein the rib structure has a width of 10 to 20 μm. 前記複数列のリブ構造体の間隔が、100〜300μmであることを特徴とする請求項4に記載の有機ELディスプレイパネル。   The organic EL display panel according to claim 4, wherein an interval between the plurality of rows of rib structures is 100 to 300 μm. 前記樹脂系充填剤が、透明な熱硬化型接着剤である請求項1に記載の有機ELディスプレイパネル。   The organic EL display panel according to claim 1, wherein the resin filler is a transparent thermosetting adhesive. 前記樹脂系充填剤が、0.2Pa・s〜10Pa・sの粘度を有することを特徴とする請求項1または7に記載の有機ELディスプレイパネル。   The organic EL display panel according to claim 1, wherein the resin filler has a viscosity of 0.2 Pa · s to 10 Pa · s. 有機EL発光素子の出光面とカラーフィルタ素子の入光面とを一定の間隔を保持して対向させて有機EL発光素子およびカラーフィルタ素子の外周を封止材により封止してなるトップエミッション構造の有機ELディスプレイパネルの製造方法であって、
前記カラーフィルタ素子の画面表示領域の外周に沿って連続または不連続なリブ構造体を形成する工程、
前記リブ構造体の外周に沿って連続した外周封止材層を形成する工程、
前記カラーフィルタ素子上に樹脂系充填剤を配する工程、
前記カラーフィルタ素子と前記有機EL発光素子とを位置合わせして真空下に貼り合せた後、大気圧に戻してカラーフィルタ層と有機EL発光素子とを圧着する工程、
前記外周封止材層に紫外線を照射し、外周封止材層を仮硬化させる工程、および
パネルを加熱し、前記樹脂系充填剤および外周封止材を完全硬化させる工程、
を含むことを特徴とする有機ELディスプレイパネルの製造方法。
A top emission structure in which the light emitting surface of the organic EL light emitting element and the light incident surface of the color filter element are opposed to each other while maintaining a certain distance, and the outer periphery of the organic EL light emitting element and the color filter element is sealed with a sealing material. An organic EL display panel manufacturing method,
Forming a continuous or discontinuous rib structure along the outer periphery of the screen display area of the color filter element;
Forming a continuous outer peripheral sealing material layer along the outer periphery of the rib structure;
Arranging a resin filler on the color filter element;
A step of aligning the color filter element and the organic EL light emitting element and bonding them together under vacuum, and then pressure bonding the color filter layer and the organic EL light emitting element by returning to atmospheric pressure;
Irradiating the outer peripheral sealing material layer with ultraviolet rays, preliminarily curing the outer peripheral sealing material layer, and heating the panel to completely cure the resin filler and the outer peripheral sealing material;
A method for producing an organic EL display panel, comprising:
外周封止材層の仮硬化後、個々のパネルに分断する工程をさらに含むことを特徴とする請求項9に記載の有機ELディスプレイパネルの製造方法。   The method for manufacturing an organic EL display panel according to claim 9, further comprising a step of dividing the peripheral sealing material layer into individual panels after temporary curing. カラーフィルタ素子上への樹脂系充填剤を配する工程が、樹脂系充填剤を定量滴下する工程であることを特徴とする請求項9または10に記載の有機ELディスプレイパネルの製造方法。   The method for producing an organic EL display panel according to claim 9 or 10, wherein the step of arranging the resin filler on the color filter element is a step of dropping a resin filler in a fixed amount. カラーフィルタ素子上への樹脂系充填剤を配する工程が、樹脂系充填剤を定量塗布する工程であることを特徴とする請求項9または10に記載の有機ELディスプレイパネルの製造方法。   The method for producing an organic EL display panel according to claim 9 or 10, wherein the step of arranging the resin filler on the color filter element is a step of applying the resin filler quantitatively. 前記樹脂系充填剤の充填量が、カラーフィルタ素子と有機EL発光素子とを対向させて貼り合せた際に、リブ構造体の内側に形成される容積以上で、かつ外周封止材の内側に形成される容積以下であることを特徴とする請求項9ないし12のいずれか一項に記載の有機ELディスプレイパネルの製造方法。   When the color filter element and the organic EL light emitting element are bonded to each other so that the filling amount of the resin filler is equal to or larger than the volume formed inside the rib structure, and inside the outer peripheral sealing material It is below the volume formed, The manufacturing method of the organic electroluminescent display panel as described in any one of Claim 9 thru | or 12 characterized by the above-mentioned.
JP2007075093A 2007-03-22 2007-03-22 Organic el display panel and its manufacturing method Withdrawn JP2008235089A (en)

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