JP2008142583A - Hollow fiber membrane module - Google Patents

Hollow fiber membrane module Download PDF

Info

Publication number
JP2008142583A
JP2008142583A JP2006329104A JP2006329104A JP2008142583A JP 2008142583 A JP2008142583 A JP 2008142583A JP 2006329104 A JP2006329104 A JP 2006329104A JP 2006329104 A JP2006329104 A JP 2006329104A JP 2008142583 A JP2008142583 A JP 2008142583A
Authority
JP
Japan
Prior art keywords
housing
hollow fiber
fiber membrane
membrane module
reinforcing member
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP2006329104A
Other languages
Japanese (ja)
Other versions
JP4913571B2 (en
Inventor
Tetsuya Torii
哲也 取違
Sadahito Nakahara
禎仁 中原
Satoshi Suzuki
敏 鈴木
Atsuyasu Ueno
敦靖 上野
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Rayon Engineering Co Ltd
Original Assignee
Mitsubishi Rayon Engineering Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Rayon Engineering Co Ltd filed Critical Mitsubishi Rayon Engineering Co Ltd
Priority to JP2006329104A priority Critical patent/JP4913571B2/en
Publication of JP2008142583A publication Critical patent/JP2008142583A/en
Application granted granted Critical
Publication of JP4913571B2 publication Critical patent/JP4913571B2/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Landscapes

  • Separation Using Semi-Permeable Membranes (AREA)

Abstract

<P>PROBLEM TO BE SOLVED: To provide a flat type hollow fiber membrane module which is capable of enhancing the resistance to pressure even if the bending stiffness of the housing itself is not enhanced. <P>SOLUTION: The hollow fiber membrane module is provided with a bundled body 2 being a bundle of a plurality of hollow fiber membranes 1, a long and slender housing 3 having a long and slender opening 30 through which the end portion of the bundled body 2, is inserted and a resin part 4 for fixation to fix each end portion of the hollow fiber membrane 1 of the bundled body 2 inserted into the opening 30 of the housing 3 in a state being opened to the inner space 32 through which the treatment liquid in the housing 3 passes and to seal the gap between the bundled body 2 and the inner wall of the housing 3. A reinforcing member 5 which is extended along the longitudinal direction of the housing 3 is installed at the resin part 4 for fixation. <P>COPYRIGHT: (C)2008,JPO&INPIT

Description

本発明は、平型の中空糸膜モジュールに関し、特に、ハウジングの曲げ剛性の高い平型の中空糸膜モジュールに関する。   The present invention relates to a flat hollow fiber membrane module, and more particularly to a flat hollow fiber membrane module having a housing with high bending rigidity.

中空糸膜モジュールは、一般に、中空糸膜を多数本束ねた集束体の端部をハウジングに挿入し、端部を開口させた状態で、中空糸膜とハウジングとの間を樹脂で封止した構造を有する。そして、中空糸膜モジュールは、従来から、無菌水、飲料水、高度純水の製造や、空気の浄化等の多くの用途に使用されている。   The hollow fiber membrane module is generally sealed with a resin between the hollow fiber membrane and the housing with the end of the bundling body in which a number of hollow fiber membranes are bundled inserted into the housing and the end opened. It has a structure. And the hollow fiber membrane module is conventionally used for many uses, such as manufacture of aseptic water, drinking water, highly purified water, and air purification.

これらの用途に加えて、近年、中空糸膜モジュールは、下水処理場における2次処理、3次処理や、浄化槽における固液分離、産業廃水中のSS(懸濁物質)の固液分離など処理のための高汚濁性水濾過にも用いられている。高汚濁性水濾過においては、中空糸膜端部の開口部分に、繰り返し加圧や吸引を行うことにより、所定の処理水を得たり、中空糸膜の膜表面を洗浄したりする。このため、高汚濁性水濾過用の中空糸膜モジュールには、特に高い耐圧性が要求される。   In addition to these applications, in recent years, hollow fiber membrane modules have undergone secondary treatment and tertiary treatment in sewage treatment plants, solid-liquid separation in septic tanks, solid-liquid separation of SS (suspended material) in industrial wastewater, etc. It is also used for highly polluting water filtration. In highly polluting water filtration, predetermined treatment water is obtained or the membrane surface of the hollow fiber membrane is washed by repeatedly applying pressure and suction to the opening at the end of the hollow fiber membrane. For this reason, especially high pressure resistance is requested | required of the hollow fiber membrane module for highly polluting water filtration.

そのような耐圧性を高めた中空糸膜モジュールの一例が、下記の特許文献1に開示されている。この特許文献1に開示の技術によれば、中空糸膜の集束体の少なくとも一方の端部における中空糸膜相互間を封止する封止樹脂として、硬度測定における10秒後のショアD硬度が60以上であるポリウレタン系樹脂を使用することにより、封止樹脂の耐圧性能を向上させている。また、下記の特許文献2には、固定用樹脂部とハウジングの内壁との接合面がハウジングの内部空間に露出した継ぎ目の上に、10秒後のショアA硬度で10〜60度の範囲の接着用樹脂を設けることにより、固定用樹脂とハウジングとの剥離の発生を抑制して耐圧性能を高めた中空糸膜モジュール及びその製造方法が開示されている。   An example of such a hollow fiber membrane module with improved pressure resistance is disclosed in Patent Document 1 below. According to the technology disclosed in Patent Document 1, the Shore D hardness after 10 seconds in hardness measurement is used as a sealing resin for sealing between the hollow fiber membranes at at least one end of the bundle of hollow fiber membranes. By using a polyurethane-based resin that is 60 or more, the pressure resistance performance of the sealing resin is improved. Further, in Patent Document 2 below, the joint surface between the fixing resin portion and the inner wall of the housing is on the seam exposed in the inner space of the housing, and the Shore A hardness after 10 seconds is in the range of 10 to 60 degrees. Disclosed is a hollow fiber membrane module in which pressure resistance is improved by providing an adhesive resin to suppress the occurrence of peeling between the fixing resin and the housing, and a method for manufacturing the same.

特開2003−103146号公報JP 2003-103146 A 特開2006−61816号公報JP 2006-61816 A

中空糸モジュールは、一般に、集束体の横断面の輪郭形状が円形の円筒型の中空糸モジュールと、集束体の横断面の輪郭形状が細長い平型の中空糸膜モジュールとに分けられる。平型の中空糸膜モジュールは、収束体の横断面の輪郭形状に合わせて細長いハウジングを有する。平型の中空糸膜モジュールは、通常、ハウジングの長手方向の両端が支持された状態で使用される。   The hollow fiber module is generally divided into a cylindrical hollow fiber module having a circular cross-sectional contour shape of the focusing body and a flat hollow fiber membrane module having a narrow cross-sectional contour shape of the focusing body. The flat hollow fiber membrane module has an elongated housing in accordance with the contour shape of the cross section of the converging body. The flat hollow fiber membrane module is usually used in a state where both ends in the longitudinal direction of the housing are supported.

ところで、ハウジングは、通常、汎用の安価なプラスチック材料で形成されている。このため、ハウジングに中空糸膜モジュールの自重や外力が加わると、ハウジングが撓んでしまうことがある。具体的には、ハウジングの長手方向の中央付近が、支持された両端よりも下方へ変形する。その撓み量は、ハウジングの長手方向の長さとハウジングへ加わる荷重に比例する傾向がある。   Incidentally, the housing is usually made of a general-purpose inexpensive plastic material. For this reason, when the weight or external force of the hollow fiber membrane module is applied to the housing, the housing may be bent. Specifically, the vicinity of the center in the longitudinal direction of the housing is deformed downward from both supported ends. The amount of deflection tends to be proportional to the length in the longitudinal direction of the housing and the load applied to the housing.

その結果、上記の特許文献1にあるように封止樹脂の種類や量を適当に用いることによって封止樹脂自体の耐圧性を高めた場合であっても、ハウジングの撓みが大きくなると、その変形に耐えられずに封止樹脂が割れたり、封止樹脂とハウジングとの剥離が発生したりすることがある。同様に、上記の特許文献2にあるように10秒後のショアA硬度で10〜60度の範囲の接着用樹脂で固定用樹脂をハウジングへ接着することによって固定用樹脂とハウジングとの剥離を抑制した場合であっても、ハウジングの撓みが大きくなると、その変形に耐えられずに接着用樹脂が裂けたり、剥がれたりすることがある。   As a result, even when the pressure resistance of the sealing resin itself is increased by appropriately using the type and amount of the sealing resin as described in Patent Document 1, the deformation of the housing increases when the deflection of the housing increases. In some cases, the sealing resin may be broken without being able to withstand, or the sealing resin may be peeled off from the housing. Similarly, as described in Patent Document 2, the fixing resin and the housing are peeled off by bonding the fixing resin to the housing with an adhesive resin having a Shore A hardness of 10 seconds after 10 seconds. Even if it is suppressed, if the deflection of the housing increases, the adhesive resin may tear or peel off without being able to withstand the deformation.

そこで、ハウジングの曲げ剛性を高めて中空糸モジュールの耐圧性を高めるために、ハウジング自体を、例えば、金属、エンジニアリングプラスチック、又は繊維強化プラスチック(FRP:fiber reinforced plastics)といった高強度材料で形成することが考えられる。しかし、これらの材料は汎用で安価なプラスチックに比べて高価である。このため、ハウジングをこれらの材料で形成すると、中空糸膜モジュールのコストが上昇してしまう。   Therefore, in order to increase the bending rigidity of the housing and increase the pressure resistance of the hollow fiber module, the housing itself is formed of a high-strength material such as metal, engineering plastic, or fiber reinforced plastics (FRP). Can be considered. However, these materials are more expensive than general-purpose and inexpensive plastics. For this reason, if the housing is formed of these materials, the cost of the hollow fiber membrane module increases.

また、安価なプラスチック材料で形成したハウジングの曲げ剛性を高めるために、ハウジング自体の肉厚を厚くしたり、ハウジングにリブを設けたりすることが考えられる。しかし、ハウジングの肉厚を厚くすると、ハウジングに反りやヒケといった成形上の欠陥が発生しやすくなる。また、ハウジングにリブを設けると、リブの付け根に応力が集中し、荷重が繰り返しかかることにより亀裂が発生しやすくなる。さらに、リブの部分は肉厚が厚いため、ヒケが発生しやすい。そのため、リブを設けると、ハウジングの外観が悪くなるおそれがある。   Further, in order to increase the bending rigidity of the housing formed of an inexpensive plastic material, it is conceivable to increase the thickness of the housing itself or to provide a rib on the housing. However, when the thickness of the housing is increased, molding defects such as warping and sinking tend to occur in the housing. Further, when the rib is provided on the housing, stress concentrates on the base of the rib, and cracks are likely to occur due to repeated load. Furthermore, since the rib portion is thick, sink marks are likely to occur. Therefore, when the rib is provided, the appearance of the housing may be deteriorated.

そこで、本発明の目的は、ハウジング自体の曲げ剛性を高めなくとも、耐圧性を高めることができる平型の中空糸膜モジュールを提供することにある。   Accordingly, an object of the present invention is to provide a flat hollow fiber membrane module capable of improving pressure resistance without increasing the bending rigidity of the housing itself.

上記の目的を達成するため、本発明の中空糸モジュールは、複数の中空糸膜を束ねた集束体と、収束体の端部が挿入される細長い開口を有する細長いハウジングと、ハウジングの開口に挿入された収束体の前記中空糸膜の各々の端部を、ハウジング内部の処理液の通過する内部空間に開口させた状態で固定するとともに、収束体と前記ハウジングの内壁との間を封止した固定用樹脂部とを備え、固定用樹脂部に、ハウジングの長手方向に沿って延在する補強部材を設けたことを特徴としている。   In order to achieve the above object, a hollow fiber module of the present invention includes a converging body in which a plurality of hollow fiber membranes are bundled, an elongated housing having an elongated opening into which an end of the converging body is inserted, and an insertion in the opening of the housing. Each end of the hollow fiber membrane of the convergent body is fixed in an open state in the internal space through which the processing liquid passes inside the housing, and the gap between the convergent body and the inner wall of the housing is sealed. A fixing resin portion, and the reinforcing resin portion is provided with a reinforcing member extending along the longitudinal direction of the housing.

このように構成された本発明の中空糸膜モジュールによれば、固定用樹脂部に補強部材を設けたことにより、ハウジング自体の剛性を高めなくとも、ハウジングの曲がりに対する強度、即ち、曲げ剛性が高くなる。これにより、ハウジングの撓みによる固定用樹脂部の剥離等の発生が抑制されて、中空糸膜モジュールの耐圧性の向上を図ることができる。   According to the hollow fiber membrane module of the present invention configured as described above, the reinforcing member is provided in the fixing resin portion, so that the strength against bending of the housing, that is, the bending rigidity is improved without increasing the rigidity of the housing itself. Get higher. Thereby, generation | occurrence | production of peeling of the resin part for fixation by bending of a housing, etc. are suppressed, and the pressure | voltage resistance of a hollow fiber membrane module can be aimed at.

なお、ハウジングの曲げ剛性を高めるために、固定用樹脂部に補強部材を設けるのではなく、固定用樹脂部全体の硬度を高くすることも考えられる。しかし、固定用樹脂部全体の硬度を高くすると、固定用樹脂部が割れやすくなる。このため、固定用樹脂部全体の硬度を高くすることは、中空糸膜モジュールの耐圧性を高める観点からは好ましくない。   In order to increase the bending rigidity of the housing, it is conceivable to increase the hardness of the entire fixing resin portion instead of providing a reinforcing member in the fixing resin portion. However, when the hardness of the entire fixing resin portion is increased, the fixing resin portion is easily broken. For this reason, it is not preferable to increase the hardness of the entire fixing resin part from the viewpoint of increasing the pressure resistance of the hollow fiber membrane module.

また、本発明において好ましくは、補強部材は、ハウジングを構成する材料のヤング率以上のヤング率を有する材料から構成される。
このように、ハウジング自体のヤング率よりも高いヤング率の補強部材の使用により、ハウジングの曲げ剛性が効果的に高められる。
In the present invention, preferably, the reinforcing member is made of a material having a Young's modulus equal to or higher than that of the material constituting the housing.
Thus, the use of a reinforcing member having a Young's modulus higher than the Young's modulus of the housing itself effectively increases the bending rigidity of the housing.

また、本発明において好ましくは、補強部材は、集束体とハウジングの長手方向の内壁との間に、当該内壁に面して帯状に配置される。
このように、帯状の形状の補強部材がハウジングの長手方向に沿って配置されることにより、ハウジングの曲げ剛性が効果的に高められる。
In the present invention, preferably, the reinforcing member is disposed in a band shape between the converging body and the inner wall in the longitudinal direction of the housing so as to face the inner wall.
As described above, the band-shaped reinforcing member is arranged along the longitudinal direction of the housing, so that the bending rigidity of the housing is effectively enhanced.

また、本発明において好ましくは、補強部材は、集束体に当接する突起部を有する。
このように、補強部材に突起部が設けられることにより、集束体に対する補強部材の位置決めを容易に行うことができる。
In the present invention, it is preferable that the reinforcing member has a protruding portion that comes into contact with the converging body.
As described above, the protrusions are provided on the reinforcing member, whereby the reinforcing member can be easily positioned with respect to the focusing body.

このように、本発明の平型の中空糸膜モジュールによれば、ハウジング自体の曲げ剛性を高めなくとも、耐圧性を高めることができる。   Thus, according to the flat hollow fiber membrane module of the present invention, the pressure resistance can be increased without increasing the bending rigidity of the housing itself.

以下、添付の図面を参照して、本発明の中空糸膜モジュールの実施形態を説明する。
まず、図1を参照して、実施形態の中空糸膜モジュールの構成について説明する。図1は、実施形態の中空糸膜モジュールの概略斜視図である。
Hereinafter, embodiments of the hollow fiber membrane module of the present invention will be described with reference to the accompanying drawings.
First, with reference to FIG. 1, the structure of the hollow fiber membrane module of embodiment is demonstrated. FIG. 1 is a schematic perspective view of the hollow fiber membrane module of the embodiment.

図1に示すように、本実施形態の中空糸膜モジュールは、複数の中空糸膜1を束ねた集束体2と、収束体2の端部が挿入される細長い開口30を有する細長いハウジング3と、ハウジング3の開口30に挿入された収束体2の前記中空糸膜1の各々の端部を固定するとともに、収束体2と前記ハウジング3の開口30の内壁との間を封止する固定用樹脂部4とを備え、固定用樹脂部4に、ハウジング3の長手方向に沿って延在する補強部材5を設けている。
なお、図1には示さていないが、各中空糸膜1の各々の端部は、ハウジング3内部の処理液の通過する内部空間32に開口した状態で、固定用樹脂部4により固定されている。
以下、中空糸膜モジュールの構成要素について説明する。
As shown in FIG. 1, the hollow fiber membrane module of the present embodiment includes a converging body 2 in which a plurality of hollow fiber membranes 1 are bundled, and an elongated housing 3 having an elongated opening 30 into which an end of the converging body 2 is inserted. , For fixing each end of the hollow fiber membrane 1 of the converging body 2 inserted into the opening 30 of the housing 3 and sealing between the converging body 2 and the inner wall of the opening 30 of the housing 3 The fixing resin portion 4 is provided with a reinforcing member 5 extending along the longitudinal direction of the housing 3.
Although not shown in FIG. 1, each end portion of each hollow fiber membrane 1 is fixed by the fixing resin portion 4 in an open state in the internal space 32 through which the processing liquid passes inside the housing 3. Yes.
Hereinafter, the components of the hollow fiber membrane module will be described.

中空糸膜1は、濾過膜として使用可能なものであれば、その孔径、空孔率、膜厚、外径等は、特に限定されない。好ましくは、中空糸膜の外径は20〜3000μm、孔径は0.001〜5μm、空孔率は20〜90%、膜厚は5〜300μmの範囲がよい。   As long as the hollow fiber membrane 1 can be used as a filtration membrane, its pore diameter, porosity, film thickness, outer diameter, etc. are not particularly limited. Preferably, the hollow fiber membrane has an outer diameter of 20 to 3000 μm, a pore diameter of 0.001 to 5 μm, a porosity of 20 to 90%, and a film thickness of 5 to 300 μm.

また、中空糸膜1の材質は、特に限定されるものではない。好ましくは、ポリスルホン系樹脂、ポリアクリロニトリル、セルロース誘導体、ポリエチレンやポリプロピレンなどのポリオレフィン、ポリフッ化ビニリデンやポリテトラフルオロエチレンなどのフッ素系樹脂、ポリアミド、ポリエステル、ポリメタクリレート、ポリアクリレートなどが挙げられる。また、これらの樹脂の共重合体や一部に置換基を導入したものであってもよい。さらに、2種以上の樹脂を混合したものであってもよい。   Moreover, the material of the hollow fiber membrane 1 is not specifically limited. Preferable examples include polysulfone resins, polyacrylonitrile, cellulose derivatives, polyolefins such as polyethylene and polypropylene, fluorine resins such as polyvinylidene fluoride and polytetrafluoroethylene, polyamides, polyesters, polymethacrylates, and polyacrylates. In addition, copolymers of these resins or those having a substituent introduced into a part thereof may be used. Furthermore, what mixed 2 or more types of resin may be used.

本発明の中空糸モジュールは平型の中空糸モジュールであるので、集束体2の横断面は細長い輪郭形状を有する。また、集束体2における中空糸膜1の配列方向は、特に限定されない。好ましくは、中空糸膜1が、被処理液の流れ方向に対し、概ね平行に配列される。このように配列すれば、中空糸膜1が被処理液の流れの障害とならない。その結果、夾雑物を含む高汚濁液を処理する場合に、夾雑物の中空糸膜1への堆積や絞絡が軽減される。   Since the hollow fiber module of the present invention is a flat hollow fiber module, the cross section of the focusing body 2 has an elongated contour shape. Further, the arrangement direction of the hollow fiber membranes 1 in the converging body 2 is not particularly limited. Preferably, the hollow fiber membrane 1 is arranged substantially parallel to the flow direction of the liquid to be treated. If arranged in this way, the hollow fiber membrane 1 does not become an obstacle to the flow of the liquid to be treated. As a result, when a highly contaminated liquid containing contaminants is processed, accumulation of the contaminants on the hollow fiber membrane 1 and constriction are reduced.

さらに、中空糸膜1の配列方向は、中空糸膜1の長さ方向が縦方向、即ち上下方向であることが好ましい。このように配列すれば、夾雑物を洗浄するエアバブリング洗浄時に発生する被処理液の上昇流方向と中空糸膜1の延在方向とが概ね平行となる。その結果、夾雑物の堆積が防止される。   Furthermore, the arrangement direction of the hollow fiber membranes 1 is preferably such that the length direction of the hollow fiber membranes 1 is the vertical direction, that is, the vertical direction. If arranged in this way, the upward flow direction of the liquid to be treated generated during air bubbling cleaning for cleaning contaminants and the extending direction of the hollow fiber membrane 1 are substantially parallel. As a result, accumulation of impurities is prevented.

ハウジング3は、図1に示すように、細長い外形を有する。そして、ハウジング3は、横断面の輪郭形状が細長い集束体2の端部を挿入するため、細長い開口30を有する。   The housing 3 has an elongated external shape as shown in FIG. And the housing 3 has the elongate opening 30 in order to insert the edge part of the condensing body 2 with the cross-sectional outline shape elongate.

さらに、図2及び図3を参照して、ハウジング3について説明する。図2及び図3は、図1のA−A線及びB−B線に沿ったハウジング3の断面図である。   Furthermore, the housing 3 will be described with reference to FIGS. 2 and 3. 2 and 3 are cross-sectional views of the housing 3 taken along lines AA and BB in FIG.

図2及び図3に示すように、ハウジング3の内側には段差部31が形成されている。集束体2及び固定用樹脂部4は、ハウジング3の開口30からこの段差部31まで挿入される。その結果、ハウジング3内に、固定用樹脂部4とハウジング3の内壁とによって囲まれた内部空間32が形成される。この内部空間32には、中空糸膜1の端部が開口している。また、この内部空間32は、通路33により外部と連通している。そして、中空糸膜1の端部の開口から、この通路33及び内部空間32を処理液が通過する。   As shown in FIGS. 2 and 3, a step portion 31 is formed inside the housing 3. The focusing body 2 and the fixing resin portion 4 are inserted from the opening 30 of the housing 3 to the step portion 31. As a result, an internal space 32 surrounded by the fixing resin portion 4 and the inner wall of the housing 3 is formed in the housing 3. In the internal space 32, the end of the hollow fiber membrane 1 is open. The internal space 32 communicates with the outside through a passage 33. Then, the processing liquid passes through the passage 33 and the internal space 32 from the opening at the end of the hollow fiber membrane 1.

本実施形態におけるハウジング3の各部の寸法は、例えば、図2に示すように、幅Aが30mm、高さBが75mm、段差から上の高さCが45mm、段差から下の高さDが30mm、内側段差Eが3mmである。また、図3に示す、外側長さFが1250mm、内側長さGが1150mm、そして内側段差Hが3mmである。   The dimensions of each part of the housing 3 in this embodiment are, for example, as shown in FIG. 2, the width A is 30 mm, the height B is 75 mm, the height C above the step is 45 mm, and the height D below the step. 30 mm, inner step E is 3 mm. Also, the outer length F shown in FIG. 3 is 1250 mm, the inner length G is 1150 mm, and the inner step H is 3 mm.

また、ハウジング3の材質は、中空糸膜モジュールの製造コスト低減の観点から汎用の安価なプラスチックが好ましい。例えば、ポリカーボネート、ポリスルホン、ポリオレフィン、PVC(ポリ塩化ビニル)、アクリル樹脂、ABS樹脂、変成PPE(ポリフェニレンエーテル)が挙げられる。また、使用後に焼却処理が必要な場合には、燃焼により有毒ガスを出さずに、完全燃焼させることのできるポリオレフィン等の炭化水素系の樹脂が好ましい。また、機械的強度及び耐久性を有する材質であることが更に好ましい。   The material of the housing 3 is preferably a general-purpose inexpensive plastic from the viewpoint of reducing the manufacturing cost of the hollow fiber membrane module. Examples thereof include polycarbonate, polysulfone, polyolefin, PVC (polyvinyl chloride), acrylic resin, ABS resin, and modified PPE (polyphenylene ether). Further, when an incineration treatment is necessary after use, a hydrocarbon-based resin such as polyolefin that can be completely burned without emitting a toxic gas by combustion is preferable. Further, a material having mechanical strength and durability is more preferable.

また、固定用樹脂部4を構成する樹脂としては、集束体2の中空糸膜1の端部を固定する固定用樹脂として、エポキシ樹脂、不飽和ポリエステル樹脂、ポリウレタン樹脂、シリコーン系充填材、各種ホットメルト樹脂等を用いることができ、適宜選定することが可能である。   Moreover, as resin which comprises the resin part 4 for fixation, as resin for fixation which fixes the edge part of the hollow fiber membrane 1 of the bundling body 2, an epoxy resin, unsaturated polyester resin, a polyurethane resin, a silicone type filler, various A hot melt resin or the like can be used and can be appropriately selected.

また、固定用樹脂部4は、中空糸膜1の集束体2を担持し、かつ、固定用樹脂を嵌め込んだハウジング3の剛性を確保して、使用時の耐圧性を発揮する。このため、固定用樹脂部4は、所定の範囲の硬度を有することが好ましい。すなわち、固定用樹脂部4の硬度が、10秒後のショアA硬度で80度を下回ると、耐圧性を維持するために、多くの樹脂量が必要となり、中空糸膜モジュールのコストを高騰させる要因となる。また、固定用樹脂部4の硬度が、10秒後のショアA硬度で99度を上回る場合は、固定用樹脂部4自体が割れ易くなる。したがって、固定用樹脂部4の硬度は、10秒後のショアA硬度で80〜99度であることは好ましい。   Further, the fixing resin portion 4 carries the bundling body 2 of the hollow fiber membrane 1 and secures the rigidity of the housing 3 into which the fixing resin is fitted, thereby exhibiting pressure resistance during use. For this reason, it is preferable that the fixing resin portion 4 has a predetermined range of hardness. That is, when the hardness of the fixing resin portion 4 is less than 80 degrees in Shore A hardness after 10 seconds, a large amount of resin is required to maintain pressure resistance, and the cost of the hollow fiber membrane module is increased. It becomes a factor. Further, when the hardness of the fixing resin portion 4 exceeds 99 degrees in Shore A hardness after 10 seconds, the fixing resin portion 4 itself is easily cracked. Therefore, it is preferable that the hardness of the fixing resin portion 4 is 80 to 99 degrees in Shore A hardness after 10 seconds.

次に、図4、図5(a)及び図5(b)を参照して、本実施形態の中空糸膜モジュールの補強部材5について説明する。図4は、図1のA−A線に沿った部分断面図である。また、図5(a)は、図4のC−Cに沿った横断面図である。図5(b)は、ハウジング3の側面図である。   Next, the reinforcing member 5 of the hollow fiber membrane module of the present embodiment will be described with reference to FIGS. 4, 5 (a), and 5 (b). FIG. 4 is a partial cross-sectional view taken along line AA in FIG. FIG. 5A is a cross-sectional view taken along the line CC in FIG. FIG. 5B is a side view of the housing 3.

図4及び図5に示すように、補強部材5は、集束体2とハウジング3の長手方向の内壁との間の固定用樹脂部4内に、当該内壁に面して帯状に配置されている。さらに、図5に示すように、補強部材5は、ハウジング3の開口30の長手方向の実質的に全長に亘って連続して延在している。   As shown in FIGS. 4 and 5, the reinforcing member 5 is disposed in a band shape facing the inner wall in the fixing resin portion 4 between the focusing body 2 and the inner wall in the longitudinal direction of the housing 3. . Furthermore, as shown in FIG. 5, the reinforcing member 5 extends continuously over substantially the entire length in the longitudinal direction of the opening 30 of the housing 3.

このように補強部材5を設けたことにより、ハウジング3に対する応力集中が、補強部材5にも分散される。その結果、ハウジング3の撓みを減らして固定用樹脂部4とハウジング3との間の剥離の発生が大幅に低減される。これにより、固定用樹脂部4とハウジング3との接着界面での剥離の進行、ハウジング3の部分的な破壊、更にはリークの発生が抑制される。   By providing the reinforcing member 5 in this way, the stress concentration on the housing 3 is also distributed to the reinforcing member 5. As a result, the bending of the housing 3 is reduced, and the occurrence of peeling between the fixing resin portion 4 and the housing 3 is greatly reduced. Thereby, the progress of peeling at the bonding interface between the fixing resin portion 4 and the housing 3, the partial destruction of the housing 3, and the occurrence of leakage are suppressed.

これにより、ハウジング3を厚肉化したり、補強リブを設けたりしなくとも、ハウジング3の撓みが抑制される。また、固定用樹脂部4に使用する樹脂の量も減らせるため、中空糸膜モジュールのコストアップを抑えて、耐圧性の向上を図ることができる。   Thereby, even if it does not thicken the housing 3 or provide a reinforcement rib, the bending of the housing 3 is suppressed. In addition, since the amount of resin used for the fixing resin portion 4 can be reduced, the cost of the hollow fiber membrane module can be suppressed and the pressure resistance can be improved.

また、帯状の補強部材5の配置形状は、ハウジング3の底面と対向する横長の配置よりも、図4に示すように、ハウジング3の内壁と対向する縦長の配置であるのがよい。横長の配置に比べて、縦長の配置の方が、ハウジング3の中央部が下方に撓む場合の断面2次モーメントを大きくできるので、撓みを効果的に抑制することができる。さらに、縦長の配置とすれば、集束体2とハウジング3内壁との隙間が狭い場合であっても、ハウジング3の長手方向に垂直な幅を広げることなく、補強部材5を配置することができる。   Further, the arrangement shape of the strip-shaped reinforcing member 5 is preferably a vertically long arrangement facing the inner wall of the housing 3 as shown in FIG. 4 rather than a horizontally long arrangement facing the bottom surface of the housing 3. Compared to the horizontally long arrangement, the vertically long arrangement can increase the cross-sectional secondary moment when the central portion of the housing 3 bends downward, so that the bending can be effectively suppressed. Further, if the vertically long arrangement is adopted, the reinforcing member 5 can be arranged without increasing the width perpendicular to the longitudinal direction of the housing 3 even when the gap between the focusing body 2 and the inner wall of the housing 3 is narrow. .

補強部材5の材質の曲げ弾性率については、特に限定はされないが、中空糸膜モジュールに十分な曲げ剛性を与えるため、補強部材のヤング率は、2000MPa以上、より好ましくは2500MPa以上であるのが好ましい。   The bending elastic modulus of the material of the reinforcing member 5 is not particularly limited, but in order to give the hollow fiber membrane module sufficient bending rigidity, the Young's modulus of the reinforcing member is 2000 MPa or more, more preferably 2500 MPa or more. preferable.

また、補強部材5は、ハウジング3を構成する材料のヤング率以上のヤング率を有する材料から構成されるのがよい。ハウジング3の材質のヤング率は、通常、補強部材5を除く固定用樹脂部4の材質のヤング率よりも高い。したがって、補強部材5の材質のヤング率は、補強部材5を除く固定用樹脂部4の材質のヤング率よりも大きく、且つハウジングと同等以上のヤング率を有するのがよい。   The reinforcing member 5 is preferably made of a material having a Young's modulus equal to or higher than that of the material constituting the housing 3. The Young's modulus of the material of the housing 3 is usually higher than the Young's modulus of the material of the fixing resin portion 4 excluding the reinforcing member 5. Therefore, the Young's modulus of the material of the reinforcing member 5 is preferably larger than the Young's modulus of the material of the fixing resin portion 4 excluding the reinforcing member 5 and equal to or higher than that of the housing.

また、補強部材5の材質は、機械的強度及び耐久性を有し、更に接着性のよいものであるのがよい。例えば、ポリカーボネート、ポリスルホン、PVC(ポリ塩化ビニル)、アクリル樹脂、ABS樹脂、変成PPE(ポリフェニレンエーテル)等が挙げられる。さらに、補強部材5に、金属、エンジニアリングプラスチック、FRP等の他の材料を用いてもよい。しかし、中空糸膜モジュールの製造コスト低減の観点からは、廉価のプラスチック材料を用いることが好ましい。   Moreover, the material of the reinforcing member 5 should have mechanical strength and durability, and further have good adhesiveness. Examples thereof include polycarbonate, polysulfone, PVC (polyvinyl chloride), acrylic resin, ABS resin, and modified PPE (polyphenylene ether). Furthermore, other materials such as metal, engineering plastics, FRP may be used for the reinforcing member 5. However, from the viewpoint of reducing the manufacturing cost of the hollow fiber membrane module, it is preferable to use an inexpensive plastic material.

次に、図6を参照して、中空糸膜モジュールの他の一例について説明する。図6は、ハウジング3の長手方向に垂直な切り口に沿った、中櫛空糸膜モジュールの部分断面図である。図6に示す例では、補強部材5の側面に、集束体に当接する位置決め用の突起部51が設けられている。このように、補強部材5の側面に突起部51を設けることにより、集束体2の位置を常にハウジング3の中央に固定できる。このため、形態の整った中空糸膜モジュールを効率よく製造することが可能となる。   Next, another example of the hollow fiber membrane module will be described with reference to FIG. FIG. 6 is a partial cross-sectional view of the medium comb hollow fiber membrane module along a cut surface perpendicular to the longitudinal direction of the housing 3. In the example shown in FIG. 6, a positioning projection 51 is provided on the side surface of the reinforcing member 5 so as to come into contact with the converging body. Thus, by providing the protrusion 51 on the side surface of the reinforcing member 5, the position of the focusing body 2 can always be fixed at the center of the housing 3. For this reason, it becomes possible to manufacture efficiently the hollow fiber membrane module with the form.

なお、突起部51の位置と個数について特に限定はされないが、例えば、補強部材5の上下に各1箇所あれば集束体2が傾かなくてすむので、最低でも2箇所以上が好ましい。また、突起部51の形状と大きさについても特に限定はされないが、ハウジング3内壁と集束体2で挟まれた空間の広さに応じて適宜決定されることが好ましい。   The position and the number of the protrusions 51 are not particularly limited. For example, if there is one each above and below the reinforcing member 5, the converging body 2 does not need to be tilted. Further, the shape and size of the protrusion 51 are not particularly limited, but are preferably determined as appropriate according to the size of the space between the inner wall of the housing 3 and the focusing body 2.

以下、本発明の実施例について説明する。
実施例1では、図6に示す断面構造を有する中空糸膜モジュール、即ち、突起部51を有する補強部材5を、ハウジング3と集束体2との間に左右2箇所に設けた中空糸膜モジュールを以下のようにして製造した。
Examples of the present invention will be described below.
In Example 1, the hollow fiber membrane module having the cross-sectional structure shown in FIG. 6, that is, the hollow fiber membrane module in which the reinforcing member 5 having the protrusion 51 is provided between the housing 3 and the converging body 2 at two places on the left and right. Was produced as follows.

先ず、2000mmの長さに切り揃えたポリフッ化ビニリデン製中空糸膜(外径2800μm)を1500本用意した。次いで、固定用樹脂としてのポリウレタン樹脂(日本ポリウレタン製、ニッポラン4224/4403、硬化時硬度:10秒後ショアA硬度97度)を、混合状態で、長さ1150mm、幅23mm、深さ55mm、厚さ2mmのABS製の容器に入れ、更にその容器に、中空糸膜1の集束体2を浸漬し、樹脂を硬化させ、ABS容器と一体となった固定用樹脂部4を形成した。   First, 1500 hollow fiber membranes (outer diameter: 2800 μm) made of polyvinylidene fluoride cut to a length of 2000 mm were prepared. Next, polyurethane resin as a fixing resin (Nippon Polyurethane, Nippon Run 4224/4403, hardness at curing: Shore A hardness 97 degrees after 10 seconds), in a mixed state, length 1150 mm, width 23 mm, depth 55 mm, thickness This was placed in a 2 mm ABS container, and the converging body 2 of the hollow fiber membrane 1 was immersed in the container to cure the resin, thereby forming a fixing resin portion 4 integrated with the ABS container.

また、中空糸膜の他端についても同様の作業を行い、ABS容器と一体となった固定用樹脂部を有する中空糸膜の集束体2を作成した。ここでABS製の容器は、底面から30mmと55mmの高さへ長手方向に連続する2mm角の突起を左右に設けて、集束体2を突起部51で挟み込む構造とした。   Moreover, the same operation | work was performed also about the other end of the hollow fiber membrane, and the convergence body 2 of the hollow fiber membrane which has the fixing resin part integrated with the ABS container was created. Here, the ABS container has a structure in which 2 mm square protrusions extending in the longitudinal direction from the bottom to the heights of 30 mm and 55 mm are provided on the left and right sides, and the converging body 2 is sandwiched between the protrusions 51.

次に、両端の固定用樹脂部を、端部から25mmの長さで切断した。この際に、固定用樹脂部3と一体となっていたABS容器の底部も切断される。その結果、ABS容器の残存部分が補強部材5となる。これにより、補強部材5が接着され、かつ、各中空糸膜の端面が開口された樹脂固定部を有する中空糸膜1の集束体2を得た。   Next, the fixing resin portions at both ends were cut to a length of 25 mm from the end portions. At this time, the bottom portion of the ABS container integrated with the fixing resin portion 3 is also cut. As a result, the remaining part of the ABS container becomes the reinforcing member 5. As a result, the bundle 2 of the hollow fiber membrane 1 having the resin fixing portion to which the reinforcing member 5 was bonded and the end face of each hollow fiber membrane was opened was obtained.

次に、この固定用樹脂部を、ダイヤラックEX18Z(UMG ABS(株)社製)のハウジング3に配置するに先立ち、ハウジング3の開口30の段差部31に接着樹脂(バンティコ製22B、硬化時硬度:10秒後ショアA硬度40度)を、シリンジを用いて垂れ下がらない程度に定量塗布し、約5分間増粘させた。そして、先の固定用樹脂部4を段差部31に配置し、約12時間放置した。その後、ウレタン樹脂(日本ポリウレタン製、ニッポラン4224/4403)を、ハウジング3内、及び中空糸膜1間を満たすように注入し、硬化させた。さらに、もう一方の端面についても、同様の作業を行い、固定用樹脂部及び接着樹脂から構成される樹脂部4内に補強部材5を設けた中空糸膜モジュールを得た。   Next, prior to disposing the fixing resin portion on the housing 3 of Diarac EX18Z (manufactured by UMG ABS Co., Ltd.), an adhesive resin (22B made by Bantico, when cured) is formed on the step portion 31 of the opening 30 of the housing 3. (Hardness: Shore A hardness 40 degrees after 10 seconds) was applied quantitatively using a syringe so as not to sag, and was thickened for about 5 minutes. The previous fixing resin portion 4 was placed on the step portion 31 and left for about 12 hours. Thereafter, urethane resin (Nippon Polyurethane, Nippon Run 4224/4403) was injected so as to fill the housing 3 and between the hollow fiber membranes 1 and cured. Further, the same operation was performed on the other end face to obtain a hollow fiber membrane module in which the reinforcing member 5 was provided in the resin part 4 composed of the fixing resin part and the adhesive resin.

なお、本実施例における固定用樹脂部4のヤング率は500MPaであり、補強部材5を構成するABS樹脂のヤング率は2400MPaであり、ハウジング3のヤング率は、2250MPaである。   In this embodiment, the Young's modulus of the fixing resin portion 4 is 500 MPa, the Young's modulus of the ABS resin constituting the reinforcing member 5 is 2400 MPa, and the Young's modulus of the housing 3 is 2250 MPa.

このようにして製造した中空糸膜モジュールのハウジングの両端を支持して、両端を結ぶ線を基準として、ハウジング中央部の下方への撓み量を測定した。その結果、ハウジングの撓み量は、5mmだけであり、ハウジングと固定用樹脂部に割れや剥離は発生していなかった。   The both ends of the housing of the hollow fiber membrane module manufactured in this way were supported, and the amount of bending downward of the central portion of the housing was measured with reference to the line connecting the ends. As a result, the amount of bending of the housing was only 5 mm, and no cracking or peeling occurred in the housing and the fixing resin portion.

次に、耐圧性の試験のために、製作した中空糸膜モジュールの中空糸膜を、長さ20mmを残して切断し、切断した中空糸膜の膜面、及び端面を、ウレタン樹脂(日本ポリウレタン製、ニッポラン4224/4403)で全て封止した中空糸膜モジュール試験体を作成した。この中空糸膜モジュール試験体では、ハウジング3の内部空間32が、通路33を除いて密閉されている。   Next, for the pressure resistance test, the hollow fiber membrane of the manufactured hollow fiber membrane module was cut leaving a length of 20 mm, and the membrane surface and end surface of the cut hollow fiber membrane were made of urethane resin (Nippon Polyurethane). A hollow fiber membrane module test body was produced that was completely sealed with NIPPORAN 4224/4403). In this hollow fiber membrane module test body, the internal space 32 of the housing 3 is sealed except for the passage 33.

耐圧性の試験を行うにあたり、ハウジング3の内部空間32にシリンジで水を充填し、テストポンプ((株)キョーワ製T−100)に接続されたホースを通路33に接続した。そして、テストポンプにより、ハウジング3の内部空間32に水圧をかけたところ、水圧が1.2MPaとなったときに、ハウジング3と固定用樹脂部4との間に剥離が生じ破壊した。   In performing the pressure resistance test, the internal space 32 of the housing 3 was filled with water with a syringe, and a hose connected to a test pump (T-100 manufactured by Kyowa Corporation) was connected to the passage 33. Then, when water pressure was applied to the internal space 32 of the housing 3 by the test pump, peeling occurred between the housing 3 and the fixing resin portion 4 when the water pressure reached 1.2 MPa.

(比較例)
比較例の中空糸膜モジュールは、ハウジングと集束体で挟まれた空間の樹脂部4内に補強部材を設けない点を除いて、実施例1で製造した中空糸膜モジュールと同じ構造を有する。
上記実施例と同様にして、比較例の中空糸膜モジュールのハウジングの撓み量を測定したところ、撓み量は、10mmであった。また、ハウジングの中央部分へ変形による白化がみられた。さらに、ハウジングと固定用樹脂部との剥離がみられた。
そして、上記の実施例1と同様にして、ハウジングの内部空間に水圧をかけたところ、水圧が0.9MPaとなったときに、ハウジング3と固定用樹脂部4との間に剥離が生じ破壊した。
(Comparative example)
The hollow fiber membrane module of the comparative example has the same structure as the hollow fiber membrane module manufactured in Example 1 except that no reinforcing member is provided in the resin part 4 in the space sandwiched between the housing and the focusing body.
When the amount of bending of the housing of the hollow fiber membrane module of the comparative example was measured in the same manner as in the above example, the amount of bending was 10 mm. In addition, whitening due to deformation was observed in the central portion of the housing. Further, peeling between the housing and the fixing resin portion was observed.
Then, when water pressure is applied to the internal space of the housing in the same manner as in the first embodiment, when the water pressure becomes 0.9 MPa, peeling occurs between the housing 3 and the fixing resin portion 4 and breaks. did.

したがって、上記の実施例1と比較例との比較から、樹脂部に補強部材を設けたことにより、ハウジングの高強度化を特に行わずに、ハウジングに従来の汎用材料を用いて、ハウジングの撓みを抑制することができたことが分かる。そして、補強部材を設けたことにより、撓みによるハウジングと固定用樹脂の剥離を抑制ならびに封止樹脂自体の破損を防止して、耐圧性能を大幅に向上させることができたことが分かる。   Therefore, from the comparison between the first embodiment and the comparative example, by providing a reinforcing member in the resin portion, the housing is bent without using any conventional general-purpose material without increasing the strength of the housing. It turns out that it was able to be suppressed. Further, it can be seen that by providing the reinforcing member, it was possible to suppress the peeling of the housing and the fixing resin due to bending and to prevent the sealing resin itself from being damaged, and to significantly improve the pressure resistance performance.

上述した各実施形態においては、本発明を特定の条件で構成した例について説明したが、本発明は種々の変更及び組み合わせを行うことができ、これに限定されるものではない。例えば、上述した実施例では、固定用樹脂部を形成するために用いるABS容器を補強部材として用いて製造した中空糸膜モジュールについて説明したが、本発明の中空糸膜モジュールはその製造方法によっては限定されない。本発明は、例えば、固定用樹脂部と補強部材を予め接着することなく、ハウジングへ固定用樹脂と補強部材を別々に入れてから封止用樹脂を流し込んで樹脂部とした中空糸膜モジュールにも適用される。   In each embodiment mentioned above, although the example which constituted the present invention on specific conditions was explained, the present invention can perform various change and combination, and is not limited to this. For example, in the above-described embodiment, the hollow fiber membrane module manufactured using the ABS container used for forming the fixing resin portion as the reinforcing member has been described. However, the hollow fiber membrane module of the present invention depends on the manufacturing method. It is not limited. The present invention provides, for example, a hollow fiber membrane module in which a fixing resin and a reinforcing member are separately put into a housing and then a sealing resin is poured into the housing to form a resin portion without bonding the fixing resin portion and the reinforcing member in advance. Also applies.

また、上述した実施形態では、中空糸膜の集束体の両端にそれぞれハウジングを設けた例について説明したが、本発明は、集束体の一方の端部にのみハウジングを設けた中空糸モジュールにも適用される。   In the above-described embodiment, the example in which the housing is provided at both ends of the converging body of the hollow fiber membrane has been described. However, the present invention also applies to the hollow fiber module in which the housing is provided only at one end of the converging body. Applied.

また、上述した実施形態では、補強部材を、集束体の両側でそれぞれ、ハウジングの長手方向の実質的全長に沿って設けた例について説明したが、本発明では、補強部材の配置はこれに限定されない。例えば、集束体の両側にそれぞれ設けた補強部材とどうしをハウジングの端部付近で連結し、ハウジングの開口の全周に沿って集束体を囲むように補強部材を配置してもよい。   Further, in the above-described embodiment, the example in which the reinforcing members are provided along the substantially entire length in the longitudinal direction of the housing on both sides of the focusing body has been described. However, in the present invention, the arrangement of the reinforcing members is limited to this. Not. For example, the reinforcing members provided on both sides of the converging body may be connected to each other in the vicinity of the end of the housing, and the reinforcing member may be disposed so as to surround the converging body along the entire circumference of the opening of the housing.

本発明の中空糸膜モジュールは、繰り返し加圧、吸引を行う濾過に用いられ、高い耐圧性の要求される用途に好適であり、例えば、無菌水、飲料水、高純度純水の製造、空気の浄化等の用途に加えて、下水処理場における2次処理、3次処理や、浄化槽における固液分離、産業排水中のSS(懸濁物質)の固液分離等の高汚濁水の処理用途に用いて好適である。   The hollow fiber membrane module of the present invention is used for filtration that repeatedly pressurizes and sucks, and is suitable for applications requiring high pressure resistance. For example, aseptic water, drinking water, production of high-purity pure water, air In addition to applications such as purification of wastewater, secondary and tertiary treatment in sewage treatment plants, solid-liquid separation in septic tanks, and solid-liquid separation of SS (suspended substances) in industrial wastewater, etc. It is suitable for use.

本発明の実施形態の中空糸膜モジュールの概略斜視図である。It is a schematic perspective view of the hollow fiber membrane module of embodiment of this invention. 本発明の実施形態の中空糸膜モジュールを構成するハウジングの断面図である。It is sectional drawing of the housing which comprises the hollow fiber membrane module of embodiment of this invention. 本発明の実施形態の中空糸膜モジュールを構成するハウジングの断面図である。It is sectional drawing of the housing which comprises the hollow fiber membrane module of embodiment of this invention. 本発明の実施形態の中空糸膜モジュールの一例であり、図1のA−A線に沿った部分断面図である。It is an example of the hollow fiber membrane module of embodiment of this invention, and is a fragmentary sectional view along the AA line of FIG. (a)は、本発明の実施形態の中空糸膜モジュールの一例であり、図4のC−Cに沿った横断面図であり、(b)は、ハウジングの側面図である。(A) is an example of the hollow fiber membrane module of embodiment of this invention, is a cross-sectional view along CC of FIG. 4, (b) is a side view of a housing. 本発明の実施形態の中空糸膜モジュールの他の一例であり、ハウジングの長手方向に垂直な切り口に沿った部分断面図である。It is another example of the hollow fiber membrane module of embodiment of this invention, and is a fragmentary sectional view along the cut surface perpendicular | vertical to the longitudinal direction of a housing.

符号の説明Explanation of symbols

1 中空糸膜
2 集束体
3 ハウジング
4 固定用樹脂部
5 補強部材
30 開口
31 段差部
32 内部空間
33 通路
51 突起部
DESCRIPTION OF SYMBOLS 1 Hollow fiber membrane 2 Condensing body 3 Housing 4 Fixing resin part 5 Reinforcing member 30 Opening 31 Step part 32 Internal space 33 Passage 51 Projection part

Claims (4)

複数の中空糸膜を束ねた集束体と、
前記収束体の端部が挿入される細長い開口を有する細長いハウジングと、
前記ハウジングの開口に挿入された前記収束体の前記中空糸膜の各々の端部を前記ハウジング内部の処理液の通過する内部空間に開口させた状態で固定するとともに、前記収束体と前記ハウジングの内壁との間を封止する固定用樹脂部とを備え、
前記固定用樹脂部に、前記ハウジングの長手方向に沿って延在する補強部材を設けた
ことを特徴とする中空糸膜モジュール。
A converging body in which a plurality of hollow fiber membranes are bundled;
An elongated housing having an elongated opening into which the end of the converging body is inserted;
The end of each of the hollow fiber membranes of the converging body inserted into the opening of the housing is fixed in an open state in an internal space through which the processing liquid passes inside the housing, and the converging body and the housing A fixing resin portion for sealing between the inner wall and
A hollow fiber membrane module, wherein a reinforcing member extending along a longitudinal direction of the housing is provided on the fixing resin portion.
前記補強部材は、前記ハウジングを構成する材料のヤング率以上のヤング率を有する材料から構成される
ことを特徴とする請求項1記載の中空糸膜モジュール。
2. The hollow fiber membrane module according to claim 1, wherein the reinforcing member is made of a material having a Young's modulus equal to or higher than that of the material constituting the housing.
前記補強部材は、前記集束体と前記ハウジングの長手方向の内壁との間に、当該内壁に面して帯状に配置される
ことを特徴とする請求項1又は2記載の中空糸膜モジュール。
The hollow fiber membrane module according to claim 1, wherein the reinforcing member is disposed in a band shape facing the inner wall between the converging body and the inner wall in the longitudinal direction of the housing.
前記補強部材は、前記集束体に当接する突起部を有する
ことを特徴とする請求項3記載の中空糸膜モジュール。
The hollow fiber membrane module according to claim 3, wherein the reinforcing member has a protrusion that contacts the converging body.
JP2006329104A 2006-12-06 2006-12-06 Hollow fiber membrane module Active JP4913571B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2006329104A JP4913571B2 (en) 2006-12-06 2006-12-06 Hollow fiber membrane module

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2006329104A JP4913571B2 (en) 2006-12-06 2006-12-06 Hollow fiber membrane module

Publications (2)

Publication Number Publication Date
JP2008142583A true JP2008142583A (en) 2008-06-26
JP4913571B2 JP4913571B2 (en) 2012-04-11

Family

ID=39603356

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2006329104A Active JP4913571B2 (en) 2006-12-06 2006-12-06 Hollow fiber membrane module

Country Status (1)

Country Link
JP (1) JP4913571B2 (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2012147926A1 (en) * 2011-04-28 2012-11-01 三菱レイヨン株式会社 Method for producing hollow fiber membrane modules
WO2013151051A1 (en) 2012-04-02 2013-10-10 三菱レイヨン株式会社 Hollow-fiber membrane module, process for producing hollow-fiber membrane module, and hollow-fiber membrane unit equipped with hollow-fiber membrane module
JP2014503357A (en) * 2011-12-27 2014-02-13 コーロン インダストリーズ インク Filtration membrane header and filtration membrane module including the same
US9283727B2 (en) 2010-09-16 2016-03-15 Mitsubishi Rayon Co., Ltd. Method for producing hollow fiber membrane sheet-like object, method for producing hollow fiber membrane module, and device for producing hollow fiber membrane sheet-like object

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS63158103A (en) * 1986-06-25 1988-07-01 Daicel Chem Ind Ltd Production of hollow yarn type module
JP2000288358A (en) * 1999-04-01 2000-10-17 Mitsubishi Rayon Co Ltd Filtration screen equipped with end part reinforcing member, method for manufacturing hollow-fiber membrane module, and injection mold for molding fixing member
JP2006061816A (en) * 2004-08-26 2006-03-09 Mitsubishi Rayon Eng Co Ltd Hollow fiber membrane module and its manufacturing method

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS63158103A (en) * 1986-06-25 1988-07-01 Daicel Chem Ind Ltd Production of hollow yarn type module
JP2000288358A (en) * 1999-04-01 2000-10-17 Mitsubishi Rayon Co Ltd Filtration screen equipped with end part reinforcing member, method for manufacturing hollow-fiber membrane module, and injection mold for molding fixing member
JP2006061816A (en) * 2004-08-26 2006-03-09 Mitsubishi Rayon Eng Co Ltd Hollow fiber membrane module and its manufacturing method

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9283727B2 (en) 2010-09-16 2016-03-15 Mitsubishi Rayon Co., Ltd. Method for producing hollow fiber membrane sheet-like object, method for producing hollow fiber membrane module, and device for producing hollow fiber membrane sheet-like object
WO2012147926A1 (en) * 2011-04-28 2012-11-01 三菱レイヨン株式会社 Method for producing hollow fiber membrane modules
JP5369236B2 (en) * 2011-04-28 2013-12-18 三菱レイヨン株式会社 Method for producing hollow fiber membrane module
JP2014503357A (en) * 2011-12-27 2014-02-13 コーロン インダストリーズ インク Filtration membrane header and filtration membrane module including the same
US20140048472A1 (en) * 2011-12-27 2014-02-20 Kolon Industries, Inc. Header for filtration membrane and filtration membrane module comprising the same
US9987595B2 (en) 2011-12-27 2018-06-05 Kolon Industries, Inc. Header for filtration membrane and filtration membrane module comprising the same
WO2013151051A1 (en) 2012-04-02 2013-10-10 三菱レイヨン株式会社 Hollow-fiber membrane module, process for producing hollow-fiber membrane module, and hollow-fiber membrane unit equipped with hollow-fiber membrane module
KR20140138808A (en) 2012-04-02 2014-12-04 미쯔비시 레이온 가부시끼가이샤 Hollow-fiber membrane module, process for producing hollow-fiber membrane module, and hollow-fiber membrane unit equipped with hollow-fiber membrane module
EP2835174A4 (en) * 2012-04-02 2016-08-03 Mitsubishi Rayon Co Hollow-fiber membrane module, process for producing hollow-fiber membrane module, and hollow-fiber membrane unit equipped with hollow-fiber membrane module

Also Published As

Publication number Publication date
JP4913571B2 (en) 2012-04-11

Similar Documents

Publication Publication Date Title
JP3431166B2 (en) Hollow membrane module
JP5075669B2 (en) Hollow fiber membrane module
JP6283973B2 (en) Method for producing hollow fiber membrane module
JP4913571B2 (en) Hollow fiber membrane module
AU2014371714B2 (en) Hollow-fiber membrane module
US11565216B2 (en) Hollow fiber membrane module
JP2006061816A (en) Hollow fiber membrane module and its manufacturing method
JP2009018283A (en) Hollow fiber membrane module and manufacturing method thereof
JPWO2020111175A1 (en) Hollow fiber membrane element and its manufacturing method
JP2013066870A (en) Method for repairing hollow fiber membrane module, and hollow fiber membrane module
JP6319463B2 (en) Membrane filtration unit and water treatment method
JP5291530B2 (en) Hollow fiber membrane module and manufacturing method thereof
US5599600A (en) Nozzle repair shield
JP6827789B2 (en) Membrane element
JP2011031174A (en) Separating membrane module and filter equipped with separating membrane module
JP2009202108A (en) Separation membrane element, separation membrane module, and manufacturing method of separation membrane element
JP4509690B2 (en) Method for manufacturing separation membrane module
JP4629884B2 (en) Hollow fiber membrane module
JP2022052722A (en) Hollow fiber membrane element, hollow fiber membrane module, water treatment device and water treatment method
JP2017203491A (en) Joint for hose, hose with joint, hollow fiber membrane module unit, and method of manufacturing hose with joint
KR20020065207A (en) Coating to prevent breakage of hollow fiber membrane
JP6834532B2 (en) Hollow fiber membrane module repair method and hollow fiber membrane module
JP2005052736A (en) Hollow fiber membrane module
JP2009195899A (en) Cylindrical module case and hollow fiber membrane module
TW202112435A (en) Hollow fiber membrane module

Legal Events

Date Code Title Description
A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20091126

A711 Notification of change in applicant

Free format text: JAPANESE INTERMEDIATE CODE: A711

Effective date: 20100803

A977 Report on retrieval

Free format text: JAPANESE INTERMEDIATE CODE: A971007

Effective date: 20110304

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20110414

A521 Written amendment

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20110603

A521 Written amendment

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20110614

RD03 Notification of appointment of power of attorney

Free format text: JAPANESE INTERMEDIATE CODE: A7423

Effective date: 20110614

TRDD Decision of grant or rejection written
A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

Effective date: 20120110

A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

A61 First payment of annual fees (during grant procedure)

Free format text: JAPANESE INTERMEDIATE CODE: A61

Effective date: 20120119

R151 Written notification of patent or utility model registration

Ref document number: 4913571

Country of ref document: JP

Free format text: JAPANESE INTERMEDIATE CODE: R151

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20150127

Year of fee payment: 3

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20150127

Year of fee payment: 3

S531 Written request for registration of change of domicile

Free format text: JAPANESE INTERMEDIATE CODE: R313531

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20150127

Year of fee payment: 3

R350 Written notification of registration of transfer

Free format text: JAPANESE INTERMEDIATE CODE: R350

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20150127

Year of fee payment: 3

S531 Written request for registration of change of domicile

Free format text: JAPANESE INTERMEDIATE CODE: R313531

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20150127

Year of fee payment: 3

R371 Transfer withdrawn

Free format text: JAPANESE INTERMEDIATE CODE: R371

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

S533 Written request for registration of change of name

Free format text: JAPANESE INTERMEDIATE CODE: R313533

R350 Written notification of registration of transfer

Free format text: JAPANESE INTERMEDIATE CODE: R350

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250