JP2008134091A - Diagnosis method of concrete - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To provide a diagnosis method of concrete capable of removing an influence of the first deteriorated component, and detecting accurately the second deteriorated component. <P>SOLUTION: This concrete diagnosis method for detecting a deteriorated component by performing spectroscopic analysis of reflected light of a near infrared ray irradiated to a concrete surface, is characterized by having: the first process for collecting a plurality of absorption spectrums; the second process for removing the influence of the first deteriorated component from the absorption spectrums collected in the first process; and the third process for detecting the second deteriorated component by applying a statistical procedure to the absorption spectrums from which the influence of the factor is removed. <P>COPYRIGHT: (C)2008,JPO&INPIT

Description

  The present invention relates to a concrete diagnostic method for diagnosing the soundness of a concrete building.

Causes of deterioration of concrete structures such as tunnels and bridges include neutralization, salt damage, and alkali aggregate reaction in addition to poor construction.
Neutralization occurs when concrete reacts with carbon dioxide (carbon dioxide) in the atmosphere and changes to calcium carbonate. When this neutralization proceeds to the reinforcing bar part, the protective coating on the surface of the reinforcing bar is lost and corrosion of the reinforcing bar occurs.
Corrosion of rebars due to salt damage includes a large amount of chloride in the concrete, such as the penetration of chloride from the surface of the concrete by seawater, etc., and the protective coating of the rebar is destroyed by the action of chloride ions, resulting in rebar corrosion. End up.
Alkali-aggregate reaction is a reaction in which certain reactive components in the aggregate react with the alkali contained in the cement and the product absorbs and expands with moisture in the concrete, causing cracks in the concrete. It is.

  As a method for diagnosing such concrete, after conducting a visual inspection for cracks, cut the specimen from the concrete and test the specimen for compressive strength, bruise the concrete surface, measure the degree of rebound, There is a method such as estimating. However, the specimen is cut from the concrete or the concrete is directly damaged, and the structure is damaged.

Therefore, the concrete surface to be measured is irradiated with light including the wavelength band that the degradation factor absorbs, and the reflected light (scattered light) on the concrete surface is received. Proposed a non-destructive and non-contact method to detect the concentration distribution of degradation factors in concrete structures using a spectroscopic analysis method that utilizes the phenomenon of attenuation in a specific wavelength range depending on the concentration of the material. . In other words, neutralization factors such as calcium carbonate have an absorption peak at 1.42 μm and chloride has an absorption peak at 2.26 μm. By analyzing this wavelength peak using a difference spectrum, the degree of deterioration is diagnosed from the difference in absorbance. To do.
JP 2005-218881 A

The deterioration of concrete is not caused by neutralization or salt damage, but is caused by a plurality of deterioration factors such as neutralization and salt damage. These degradation factors may be affected by other degradation factors.
For example, if salt damage and neutralization occur at the same time, it is highly possible that the conventional method of detecting deterioration factors by irradiating concrete with near-infrared rays cannot accurately detect chloride. The inventors have discovered. That is, as neutralization progresses, the absorption peak of chloride is affected and the absorption peak of salt damage becomes small even if the chloride concentration is the same. There is a problem that quantitative evaluation of deterioration factors is difficult.

  The present invention has been made in view of the above-described circumstances, and eliminates the influence of the first deterioration component in the concrete diagnosis method for detecting the deterioration component by spectroscopically analyzing the reflected light of the near infrared ray irradiated on the concrete surface. An object of the present invention is to propose a concrete diagnosis method capable of accurately detecting the second deterioration component.

In the concrete diagnosis method according to the present invention, the following means are employed in order to solve the above problems.
The present invention relates to a concrete diagnostic method for detecting degradation components by spectroscopically analyzing near-infrared reflected light irradiated on a concrete surface, a first step of collecting a plurality of absorption spectra, and an absorption spectrum collected in the first step. A second step of eliminating the influence of the first deterioration component from the third step, and a third step of detecting the second deterioration component by applying a statistical method to the absorption spectrum excluding the influence of the factor. To do.

The first deterioration component is calcium hydroxide.
The second deterioration component is a chloride ion.

The second step includes a step of eliminating the influence of the first deterioration component and the third component related to the second deterioration component.
The third component is a hydroxide ion.

The second step includes a relativization step of relativizing each absorption spectrum collected in the first step with reference to the absorption peak of the third component.
The relativization step includes a step of extracting an absorption spectrum of a predetermined range including the absorption peak of the third component for each absorption spectrum collected in the first step, and a maximum value and a minimum value of the extracted absorption spectrum, respectively. The method includes a step of obtaining a correction value to be matched with a predetermined value, and a step of correcting with the correction value for each absorption spectrum collected in the first step.

  The statistical method is a multivariate analysis method.

According to the present invention, the following effects can be obtained.
In an evaluation method that detects the degradation component by spectroscopically analyzing the reflected light collected by irradiating the concrete surface with light, the second degradation component is detected by eliminating the influence of the first degradation component from the collected absorption spectrum. It becomes possible.
In addition, since the collected absorption spectrum is simply relativized based on the absorption peak of the third component, accurate analysis can be performed easily and reliably without any special equipment or cost increase.

Hereinafter, an embodiment of a concrete diagnosis method according to the present invention will be described with reference to the drawings.
The concrete diagnostic method using the spectroscopic analysis method is a method of optically detecting deterioration of the concrete surface by irradiating the concrete surface C of the structure to be measured with light L and measuring the reflected light.
In the concrete diagnosis method of the present embodiment, there are, for example, a salt damage factor, a neutralization factor, a sulfate factor, and the like as components (deterioration factors) that cause deterioration of the concrete. Since it has an absorption peak in the infrared to mid-infrared), a spectroscopic analysis method for obtaining the concentration of the degradation factor from the absorbance of the absorption peak is used.

FIG. 1 is a schematic diagram showing a schematic configuration of a spectroscopic analyzer 10 used in a concrete diagnostic method according to an embodiment of the present invention.
As shown in FIG. 1A, the spectroscopic analyzer 10 irradiates a concrete surface C to be measured with light L, and measures a two-dimensional distribution of deterioration factors and the like on the concrete surface C from the reflected light L1. And includes a light source 11, a scanning device 12, a multi-channel spectrometer (hereinafter, “spectrometer”) 14, and a calculation means 15.

  The light source 11 is a member that irradiates the concrete surface C with light L. As the light (light emitted from the light source) L emitted from the light source 11, in order to detect deterioration factors such as a salt damage factor, a neutralization factor, and a sulfate factor, these deterioration factors have infrared rays (in particular, near infrared rays) having absorption peaks. It is sufficient that the light includes (mid infrared).

The scanning device 12 is optically connected to the spectroscope 14 via the optical fiber 13, and one point (measurement point p) among a plurality of points arranged in the concrete surface C among the light L reflected from the concrete surface C. The reflected light L <b> 1 is sequentially taken into the spectroscope 14.
Specifically, as shown in FIG. 1B, the scanning device 12 includes a polygon mirror 16 and a galvanometer mirror 17. The polygon mirror 16 is a deflector composed of a rotating polyhedron having a series of plane mirrors around a rotation axis, and the galvano mirror 17 has a single mirror attached to the axis, and the rotation angle of the mirror is adjusted according to an electric signal. It is a deflector that can be changed.
In the spectroscopic analyzer 10, the polygon mirror 16 rotates about an axis perpendicular to the paper surface in FIG. 1B as a rotation axis, and scans the concrete surface C in the lateral direction (i direction in FIG. 1A). The mirror 17 is configured to rotate about an axis parallel to the sheet surface in FIG. 1B as a rotation axis, and to scan the concrete surface C in the longitudinal direction (j direction in FIG. 1A).

  The computing means 15 is electrically connected to the spectroscope 14 and computes data output from the spectroscope 14.

FIG. 2 is a schematic diagram showing a schematic configuration of the spectrometer 14.
The spectroscope 14 is optically connected to the other end side of the optical fiber 13, and from the upstream side in the light propagation direction, the diffraction grating 31, the light reflection deflecting means 32, the aperture 33, the light collecting means 34, and the light detector 35. It is provided in order.

  The diffraction grating 31 is irradiated with the light L1 emitted through the optical fiber 13, reflected, and dispersed for each predetermined wavelength. Here, the light L <b> 1 is emitted from the light source 11 to the concrete surface C, reflected (or scattered) by the concrete surface C, and guided from the scanning device 12.

  The light reflection deflecting means 32 is irradiated with the light L1 split by the diffraction grating 31, and is reflected and deflected. The light reflection deflecting unit 32 has a MEMS actuator that sweeps and modulates the dispersed light L1 for each predetermined wavelength.

  The aperture 33 is a light-shielding stop that passes / blocks the deflected light L1. When the deflected light L1 is applied to the blocking body 33a, the propagation is blocked. Further, when the deflected light L1 is irradiated toward the opening between the adjacent blocking bodies 33a, the light L1 passes. The shape of the blocking body 33a is not particularly limited, and may be circular instead of rectangular. The opening may be a groove (slit) provided in the blocking body 33a itself.

  The condensing means 34 is a member that condenses the light expanded in the spectroscope 14 onto the photodetector 35, and uses a conventional condensing lens.

  The light detector 35 detects the light L1 collected by the light collecting means 34 and outputs the light intensity of the light L1. The light detector 35 is electrically connected to a calculation means (for example, a data calculation device) 15 via an AC amplifier or the like, and the calculation means 15 stores the output value of the light detector 35 and the output value Based on the above, a two-dimensional distribution of the concrete surface C is calculated.

Next, the concrete diagnosis method of this embodiment will be described. First, how to determine the absorbance based on the deterioration factor will be described.
When the concrete surface C is irradiated with the light L having the light intensity I0 and reflected, a part of the wavelength band of the light L is absorbed by the deterioration factor in the concrete surface C and emitted as the reflected light L1 having the light intensity I1.

At this time, between the light source outgoing light L and the reflected light L1,
L1 (λ) = L (λ) × T (λ)
Here, T (λ) has a reflectance relationship.
As the reflectance T (λ) is smaller, the light intensity of the reflected light L1 (λ) is attenuated, and the type of the deterioration factor can be determined from the wavelength band where the light intensity is attenuated, and the concentration of the deterioration factor can be determined from the absorbance. .
Here, the absorbance is defined as a logarithmic ratio of the light intensity of the light source outgoing light L and the light intensity of the reflected light L1.

When diagnosing deterioration due to neutralization of a concrete structure, the absorbance of the reflected light L1 in the wavelength band near 1420 nm, 2390 nm, or 3980 nm is measured. This is because a neutralizing factor such as CaCO ₃ has an absorption peak near a wavelength of 1420 nm, 2390 nm, or 3980 nm.

  When diagnosing salt damage of a concrete structure (deterioration due to penetration of chloride ions), the absorbance of the reflected light L1 in the wavelength band near 2260 nm is measured. This is because the salt damage factor (chloride ion) has an absorption peak near the wavelength of 2260 nm.

  When diagnosing deterioration of the concrete structure due to sulfate, the absorbance of the reflected light L1 in the wavelength band near 1410 nm or 1750 nm is measured. This is because the sulfate factor has an absorption peak near the wavelength of 1410 nm or 1750 nm.

  Therefore, conventionally, from the collected absorption spectrum, the concentration of the neutralizing factor is measured from the absorbance of the absorption peak existing at a wavelength of 1420 nm, 2390 nm, or 3980 nm, and the concentration of the salt damage factor is an absorption peak existing at a wavelength of 2260 nm. The concentration was measured from the absorbance.

FIG. 3 is a cross-sectional view of concrete in which neutralization and salt damage occur simultaneously.
However, when salt damage and neutralization occur at the same time, the absorption peak that should exist near the wavelength of 2260 nm almost disappears, making it difficult to detect salt damage.
As shown in FIG. 3, there is a phenomenon in which the concrete in which chloride penetrates due to salt damage is then neutralized from the concrete surface, and the chloride existing on the surface side is reduced. It is.

The following reactions are known to occur when concrete is neutralized.
Ca (OH) ₂ + CO ₂ → CaCO ₃ + H ₂ O (1)
Thus, as neutralization proceeds, calcium hydroxide decreases and calcium carbonate increases.
Therefore, as the neutralization proceeds, the absorbance at 1420 nm indicating the characteristics of calcium hydroxide decreases, and 3980 nm indicating the characteristics of calcium carbonate increases.

On the other hand, the absorption peak due to salt damage (chloride ions) is considered to depend on C ₃ A (tricalcium aluminate) in the cement. For this reason, it is considered that C ₃ A hydrate fixes chloride ions and a peak appears at 2260 nm. Also, if there are chloride ions in the concrete, it is fixed and exists as Friedel's salt (3CaO · Al ₂ O ₃ · CaCl ₂ · 10H ₂ O).

However, the following chemical reaction occurs by intervening with carbon dioxide.
3CaO ・ Al ₂ O ₃・ CaCl ₂・ 10H ₂ O + 3CO ₂ → 3CaCO ₃ + 2Al (OH) ₃ + CaCl ₂ + 7H ₂ O ・ ・ ・ (2)
This reaction indicates that Friedel's salt near the concrete surface reacts with carbon dioxide and dissolves by neutralization. And as concrete ages, the Friedel's salt does not exist near the surface.

In this way, even when chloride is present inside the concrete, since the chloride near the surface decreases due to the progress of neutralization, the spectroscopic analysis that detects deterioration factors by irradiating the concrete surface with light Then, the detection of chloride becomes difficult. That is, there is a high possibility that an appropriate absorption peak does not appear in the vicinity of 2260 nm.
Accordingly, regarding salt damage to concrete, accurate information cannot be obtained simply by observing the absorption peak near 2260 nm, so it is necessary to make a comprehensive judgment by observing other absorption peak fluctuations.

By the way, as shown in Formula (1), neutralization is a reaction in which the hydroxide ions (OH ⁻ ) in calcium hydroxide are lost. Similarly, salt damage is a reaction mediated by hydroxide ions (OH ⁻ ). The hydroxide ions (OH ^-) and increase or decrease of relevance to the increase or decrease of chloride is observed.
Therefore, hydroxide ions (OH ^-), i.e., focusing on the absorption peak of water, relative to the absorption peak of the reducing (water influence of the absorption peak of water from the data collected absorption spectra, collected data on the absorption spectrum By relativizing (standardizing), the influence of neutralization is eliminated and the salt damage of concrete is judged.

Hereinafter, a concrete diagnostic method according to an embodiment of the present invention will be described.
FIG. 4 is a flowchart showing the concrete diagnosis method according to the embodiment of the present invention. 5-10 shows the data obtained in the concrete diagnostic method (step S1-step S7) based on this embodiment.

First, in step S1, the light L is irradiated to the concrete surface C of the concrete structure to be measured, and the reflected light L1 is acquired.
Specifically, the light L is irradiated from the light source 11 of the spectroscopic analyzer 10 onto the concrete surface C. The light L is reflected by the concrete surface C and emitted as reflected light L1.
At that time, the scanning device 12 adjusts the angles of the polygon mirror 16 and the galvanometer mirror 17 to capture the reflected light L1 from the measurement point p (1, 1) in the concrete surface C. Specifically, the optical axis is adjusted so that the optical axis of the reflected light L1 coincides with the polygon mirror 16 and the galvano mirror 17 so that the reflected light L1 enters the optical fiber 13.

  The reflected light L <b> 1 whose optical axis is adjusted by the scanning device 12 is incident on the spectroscope 14 via the optical fiber 13. The light L1 that has entered the spectroscope 14 is split into light for each predetermined wavelength by the diffraction grating 31 and travels toward the light reflection deflecting means 32.

The reflected reflected light L1 is reflected and deflected by the light reflection deflecting means 32. The light reflection deflecting unit 32 is, for example, a MEMS programmable diffraction grating, and the MEMS programmable diffraction grating includes a MEMS actuator.
The light L1 that has reached the MEMS actuator is reflected and deflected at a high speed within a predetermined angle range and travels toward the aperture 33. Due to this reflection and deflection, the light intensity is adjusted for each of the light beams having the dispersed wavelengths in the reflected light L1.

The light L1 that has passed through the aperture 33 enters the light collecting means 34. The light L1 incident on the condensing means 34 is condensed, and light for each predetermined wavelength band is received by the photodetector 35. The received light L1 is output to the computing means 15 as an electrical signal.
Then, the computing means 15 processes the collected electrical signal to obtain the waveform data of the absorption spectrum as shown in FIG.

Next, in step S2, only the range including the water absorption peak and the chloride absorption peak is extracted (extracted and filtered) from each waveform data of the collected absorption spectrum.
Specifically, as shown in FIG. 6, only data in the range of 1850 nm to 2400 nm is extracted.

Furthermore, in step S3, as shown in FIG. 6, baseline correction is performed for each waveform data of the extracted absorption spectrum in the range of 1850 nm to 2400 nm.
Baseline correction is a process for correcting the inclination and waviness of the baseline that occurs in the waveform of the absorption spectrum due to the influence of light scattering on the concrete surface C and the like. Here, the baseline correction is a correction so that a line connecting both ends of a selected wavelength range (usually a straight line, which is called a baseline) becomes zero.

In step S4, only the range including the water absorption peak is extracted (extracted and filtered) from the extracted waveform data of the absorption spectrum in the range of 1850 nm to 2400 nm.
Specifically, as shown in FIG. 7, only data in the range of 1850 nm to 2150 nm is extracted.

Next, in step S5, baseline correction is performed on each extracted waveform data of the absorption spectrum in the range of 1850 nm to 2150 nm. Further, as shown in FIG. 8, each waveform data is relativized (normalized) so that the maximum value becomes 1.0. That is, for each waveform data of the absorption spectrum,
Relativization coefficient Q = 1.0 / (maximum value of the waveform data)
Multiply
The relativization coefficient Q value for each waveform data is stored.

  On the other hand, in step S6, the base alignment is performed so that the minimum value is 0 as shown in FIG. 9 for each waveform data of the absorption spectrum in the range of 1850 nm to 2400 nm after the baseline correction collected in step S3. (Negative) is performed. This is because the subsequent calculation is facilitated by non-negative data.

In step S7, each waveform data of the absorption spectrum collected in step S6 is multiplied by the relativization coefficient Q collected in step S5.
Thereby, as shown in FIG. 10, each waveform data of the absorption spectrum after relativization is obtained. The waveform data of the absorption spectrum is waveform data that is relativized (normalized) with reference to the absorption peak of water.
That is, the waveform data of each absorption spectrum has a maximum value (water absorption peak) and a minimum value that are substantially the same. That is, in each of the relativized absorption spectra, the influence of the water absorption peak is substantially the same.

Finally, in step S8, chemometric analysis is performed on each waveform data of the absorption spectrum collected in step S7.
Chemometric analysis applies mathematical and statistical methods to multivariate data such as spectra, and is an effective method for spectral analysis. Especially, the information behind multivariate data is analyzed. Direct reading is very effective in analyzing difficult data. Typical methods include PCR (Principal Component Regression) and PLSR (Partial Least Squares Regression).
Furthermore, PCA (Principal Component Analysis), LDA (Linear Discriminant Analysis), ANNs (Artificial Neural Networks), SVM (Support Vector Machine), K-means, SOM (Self-Organizing Map), Self Modeling Curve Resolution (SMCR), etc. There is.

  By performing the above processing, the neutralization effect is eliminated from each waveform data of the collected absorption spectrum (relative to the water absorption peak (standardization)), and the salt damage of concrete is accurately determined. It becomes possible.

Hereinafter, the analysis result using the concrete diagnostic method of this embodiment is demonstrated.
A spectroscope manufactured by PCX (Polychromix) was used as the spectroscopic analyzer 10, and the concrete surface C was measured for the degree of deterioration of the test specimen simulating neutralization and salt damage of ground and unground cement paste, mortar and concrete. .
A halogen lamp was applied to the concrete surface C, and the reflected light was scanned with a MEMS actuator.
In order to mainly detect the absorption peak (2260 nm) of chloride ions, spectral analysis of 1700 nm to 2500 nm was performed as a wavelength region.

[Outline of specimen]
a) Specimens for neutralization and salt damage measurement Specimen type: Cement paste, mortar, concrete Water-cement ratio: 48.5%
Shape: 4 × 4 × 16 cm (cement paste, mortar), 10 × 10 × 40 cm (concrete), used in pulverized and unground respectively Chloride ion concentration: 0, 1, ³ , 5, 10, 20 kg / m ³
Neutralization promotion period: 0, 1, 3 months (carbon dioxide concentration: 7%, temperature 40 ° C, humidity 50%)

b) Actual structure test specimen Blending strength: 30 N / mm ²
Slump: 10cm
Air volume: 3.9%
Shape: 0.5 × 0.5 × 0.1m 4 bodies, 1 × 1 × 0.1m 1 body Chloride ion concentration: 0, 1, 5, 10 kg / m ³
(Shape: mixed in 0.5 × 0.5 × 0.1m)

〔Experimental result〕
FIG. 11 is a diagram illustrating a result of performing the diagnostic method according to the present embodiment on the hanging surface of the concrete test body. The horizontal axis represents the chloride concentration of the test specimen, and the vertical axis represents the determined salinity concentration. FIG. 11B shows the result of the conventional method.
As shown in FIG. 11A, when the concrete diagnostic method of the present embodiment is used, there is a correlation between the chloride concentration of the concrete specimen and the obtained salinity concentration.
On the other hand, as shown in FIG. 11B, such correlation is not recognized in the conventional method.
That is, according to the concrete diagnostic method of this embodiment, it is clear that the influence of neutralization can be eliminated and the salt damage of concrete can be accurately determined.

FIG. 12 shows analysis results obtained by the diagnostic method according to the present embodiment. FIG. 12A is a regression vector diagram, and FIG. 12B is a correlation spectrum diagram.
According to the concrete diagnosis method according to the present embodiment, since the influence of neutralization is eliminated, it is possible to accurately determine other deterioration factors other than salt damage from the regression vector diagram and the correlation spectrum diagram. is there. Based on this, the result of FIG. 11A is derived.

FIG. 13 is a diagram illustrating a result of performing the diagnostic method according to the present embodiment on concrete paste and mortar.
Also in the concrete paste (FIG. 13 (a)) and mortar (FIG. 13 (b)), there is a correlation between the chloride concentration of the test specimen and the determined salt concentration.

FIG. 14 is a diagram illustrating a result when the range extracted from each waveform data of the absorption spectrum is set to 1350 nm to 2500 nm in step S <b> 2 described above.
When the range extracted from each waveform data of the absorption spectrum is changed, there is a correlation between the chloride concentration of each specimen (concrete, concrete paste and mortar) and the obtained salinity concentration.

15 and 16 show the analysis results of the chloride concentration in the actual structural specimen.
15A shows the waveform data of the absorption spectrum, FIG. 15B shows the result of analyzing the absorption peak at a wavelength of 2600 nm using the difference spectrum method, and FIG. 15C shows the result of the analysis using the analysis method of this embodiment. It is the result of having determined the object concentration.
When the difference spectrum method is used, it can be seen that the absorption peak at a wavelength of 2600 nm varies for each specimen.
It can be seen that even in the actual structure test specimen, by using the analysis method of the present embodiment, variation in chloride concentration for each test specimen is reduced, and accurate measurement is performed.

As described above, according to the analysis method of the present embodiment, in the evaluation method in which the reflected light collected by irradiating the concrete surface with light is spectrally analyzed to detect the degradation component, the waveform data of the collected absorption spectrum By eliminating the effect of neutralization, it is possible to accurately determine the salt damage of concrete.
In addition, since the waveform data of the collected absorption spectrum is simply relativized (normalized) based on the water absorption peak, it is easy, reliable and accurate without any special equipment or cost increase. Analysis is possible.

  Note that the operation procedures and the like shown in the above-described embodiments are examples, and can be variously changed based on measurement conditions and the like without departing from the gist of the present invention.

  In the above-described embodiment, the salt damage of concrete has been mainly described, but the present invention is not limited to this. As shown in FIG. 12, according to the concrete diagnosis method of the present embodiment, it is possible to accurately determine other deterioration factors from the regression vector diagram and the correlation spectrum diagram by eliminating the influence of neutralization. That's why.

  Here, in step S3, extraction was performed in the range of 1850 nm to 2400 nm. However, since 1410 nm is also an absorption band of water (OH group), normalization of water can be performed here instead of 1900 nm. In step S8, a wavelength of 1400 nm to 2400 nm can be extracted.

It is a mimetic diagram showing a schematic structure of spectroscopic analysis device 10 used for a concrete diagnostic method concerning an embodiment of the present invention. 2 is a schematic diagram showing a schematic configuration of a spectroscope 14. FIG. It is sectional drawing of the concrete which neutralization and salt damage generate | occur | produced simultaneously. It is a flowchart figure which shows the concrete diagnostic method which concerns on embodiment of this invention. Waveform data of the collected absorption spectrum is shown. The waveform data of the absorption spectrum in step S3 is shown. The waveform data of the absorption spectrum in step S4 is shown. The waveform data of the absorption spectrum in step S5 is shown. The waveform data of the absorption spectrum in step S6 is shown. The waveform data of the absorption spectrum after relativization is shown. It is the figure (a) which shows the result of the concrete diagnostic method which concerns on embodiment of this invention, and the figure (b) which shows a prior art example. It is a figure which shows the result of the concrete diagnostic method which concerns on embodiment of this invention. It is a figure which shows the result of having performed the diagnostic method which concerns on embodiment of this invention with respect to concrete paste and mortar. It is a figure which shows the result at the time of changing the process of step S2. The analysis result of the light absorbency by the difference spectrum method in a real structure test body and the chloride concentration in embodiment of this invention is shown.

Explanation of symbols

10 ... Spectroscopic analyzer L ... Emission light L1 ... Reflected light C ... Concrete surface

Claims (8)

In the concrete diagnostic method that detects the degradation component by spectroscopic analysis of the reflected light of near infrared rays irradiated on the concrete surface,
A first step of collecting a plurality of absorption spectra;
A second step of eliminating the influence of the first deterioration component from the absorption spectrum collected in the first step;
A third step of detecting a second degradation component by applying a statistical method to the absorption spectrum excluding the influence of the factor;
A method for diagnosing concrete, comprising:   The method for diagnosing concrete according to claim 1, wherein the first deterioration component is calcium hydroxide.   The diagnostic method for concrete according to claim 1, wherein the second deterioration component is chloride ion.   4. The method according to claim 1, wherein the second step includes a step of eliminating an influence of the first deterioration component and a third component related to the second deterioration component. 5. The method for diagnosing concrete as described.   The method for diagnosing concrete according to claim 4, wherein the third component is a hydroxide ion.   The said 2nd process includes the relativization process relativized on the basis of the absorption peak of said 3rd component for every absorption spectrum extract | collected at said 1st process, The Claim 4 or Claim 5 characterized by the above-mentioned. Diagnostic method for concrete. The relativization step includes
Extracting an absorption spectrum of a predetermined range including an absorption peak of the third component for each absorption spectrum collected in the first step;
Obtaining each correction value for matching the maximum and minimum values of the extracted absorption spectrum with a predetermined value, and
Correcting with the correction value for each absorption spectrum collected in the first step;
The method for diagnosing concrete according to any one of claims 4 to 6, characterized by comprising:   The method for diagnosing concrete according to any one of claims 1 to 7, wherein the statistical method is a multivariate analysis method.

Images