JP2008119600A - Method for mixing powder and powder mixer - Google Patents

Method for mixing powder and powder mixer Download PDF

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JP2008119600A
JP2008119600A JP2006306435A JP2006306435A JP2008119600A JP 2008119600 A JP2008119600 A JP 2008119600A JP 2006306435 A JP2006306435 A JP 2006306435A JP 2006306435 A JP2006306435 A JP 2006306435A JP 2008119600 A JP2008119600 A JP 2008119600A
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wall
powder
water
activated carbon
water stream
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JP4889452B2 (en
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Kenichi Kawamoto
健一 川本
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Suido Kiko Kaisha Ltd
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Suido Kiko Kaisha Ltd
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Abstract

<P>PROBLEM TO BE SOLVED: To provide a method for mixing powders and a powder mixer suppressing powdery activated carbon from floating on water and enabling suitably mixing the powdery activated carbon in water. <P>SOLUTION: A first water stream (W1) is made to fall along the upper part of the inner wall (1a) of a mixing container (1) while circulating, the powdery activated carbon (P) is made to fall over the circulating first water stream (W1), a second water stream (W2) is made to join so as to cover the first water stream (W1) transferring the powdery activated carbon (P) while circulating along the upper inner wall (1a) and the joined water stream is made to fall and mix while circulating along the lower inner wall (1b) of the mixing container (1). The powdery activated carbon is held between the first and the second water streams to prevent the powdery activated carbon from floating on water. Since the first water stream, the activated carbon and the second water stream are mixed by circulating, the powdery activated carbon is suitably mixed with water. <P>COPYRIGHT: (C)2008,JPO&INPIT

Description

本発明は、粉末混合方法および粉末混合器に関し、さらに詳しくは、粉末が水上に浮いてしまうことを抑制し、好適に粉末を水に混合することが出来る粉末混合方法および粉末混合器に関する。   The present invention relates to a powder mixing method and a powder mixer, and more particularly to a powder mixing method and a powder mixer capable of suppressing powder from floating on water and suitably mixing the powder with water.

従来、流水上に粉末活性炭を落下させながら、落下する粉末活性炭に向けて斜め上から下向きに水を噴射して、粉末活性炭と水とを混合する混合器が知られている(例えば、特許文献1参照。)。
特開平9−155334号公報(図4)
Conventionally, a mixer is known that mixes powdered activated carbon and water by spraying water downward from the top toward the falling powdered activated carbon while dropping the powdered activated carbon on flowing water (for example, Patent Documents). 1).
JP-A-9-155334 (FIG. 4)

上記従来の混合器では、水上に粉末活性炭を落下させただけでは粉末活性炭が水上に浮いてしまうため、落下する粉末活性炭に向けて水を噴射することにより噴射水で粉末活性炭を押さえ込んでいる。
しかし、粉末活性炭が上から連続して落下してくるため、噴射水で粉末活性炭を完全に押さえ込むことが出来ず、一部の粉末活性炭が水上に浮いてしまう問題点があった。
そこで、本発明の目的は、粉末が水上に浮いてしまうことを抑制し、好適に粉末を水に混合することが出来る粉末混合方法および粉末混合器を提供することにある。
In the conventional mixer, since the powdered activated carbon floats on the water simply by dropping the powdered activated carbon on the water, the powdered activated carbon is pressed down with the spray water by spraying water toward the powdered activated carbon.
However, since the powdered activated carbon falls continuously from above, the powdered activated carbon cannot be completely pressed down with the jet water, and there is a problem that some powdered activated carbon floats on the water.
Therefore, an object of the present invention is to provide a powder mixing method and a powder mixer capable of suppressing powder from floating on water and suitably mixing the powder with water.

第1の観点では、本発明は、第1の水流を混合容器の上部内壁に沿って旋回しながら落下させる第1のステップと、前記旋回する第1の水流に対して上方から粉末を落下させる第2のステップと、前記上部内壁に沿って旋回しながら前記粉末を搬送する前記第1の水流に対して上方から第2の水流を被せるように合流させる第3のステップと、前記合流した水流を前記混合容器の下部内壁に沿って旋回させながら落下させる第4のステップとを有することを特徴とする粉末混合方法を提供する。
上記第1の観点による粉末混合方法では、第1の水流上に粉末(粉末活性炭や消石灰など)を落下させた後、その上に第2の水流を被せ、第1の水流と第2の水流の間に粉末が挟まれるため、粉末が水上に浮いてしまうことを抑制できる。そして、第1の水流と粉末と第2の水流とが旋回することにより混合されるから、好適に粉末を水に混合することが出来る。
In the first aspect, the present invention provides a first step of dropping the first water stream while swirling along the upper inner wall of the mixing container, and dropping the powder from above with respect to the swirling first water stream. A second step, a third step for joining the first water flow for conveying the powder while swirling along the upper inner wall so as to cover the second water flow from above, and the combined water flow And a fourth step of dropping while swirling along the lower inner wall of the mixing container.
In the powder mixing method according to the first aspect, after a powder (powdered activated carbon, slaked lime, etc.) is dropped on the first water stream, the second water stream is put on the powder, and the first water stream and the second water stream are covered. Since the powder is sandwiched between them, it can be suppressed that the powder floats on the water. Since the first water stream, the powder, and the second water stream are mixed by swirling, the powder can be suitably mixed with water.

第2の観点では、本発明は、水平断面円形の内壁を有する混合容器と、前記混合容器の上部内壁に沿って旋回しながら落下するように前記上部内壁に向けて第1の水流を噴射する第1の給水ノズルと、前記旋回する第1の水流に対して上方から粉末を落下させる粉末注入管と、前記上部内壁に沿って旋回しながら前記粉末を搬送する前記第1の水流に対して上方から第2の水流を被せるように合流させる第2の給水ノズルと、前記合流した水流が旋回しながら落下する前記混合容器の下部内壁とを具備したことを特徴とする粉末混合器を提供する。
上記第2の観点による粉末混合器では、前記第1の観点による粉末混合方法を好適に実施できる。
In a second aspect, the present invention injects a first water flow toward the upper inner wall so as to fall while swirling along the upper inner wall of the mixing container, and a mixing container having a circular inner wall with a horizontal section. For a first water supply nozzle, a powder injection tube for dropping powder from above with respect to the swirling first water flow, and for the first water flow for conveying the powder while swirling along the upper inner wall Provided is a powder mixer comprising a second water supply nozzle for joining so as to cover a second water flow from above, and a lower inner wall of the mixing container in which the joined water flow falls while swirling. .
In the powder mixer according to the second aspect, the powder mixing method according to the first aspect can be suitably implemented.

第3の観点では、本発明は、前記第2の観点による粉末混合器において、前記上部内壁が円筒状であり、前記下部内壁は前記上部内壁よりも内径が小さい円筒状であり、それらの中間部は漏斗状になっていることを特徴とする粉末混合器を提供する。
上記第3の観点による粉末混合器では、混合容器の上部で第1の水流と粉末と第2の水流の旋回流を作り、その旋回流を混合容器の下部へ向けて半径を絞り込むことで周速度を高速化し、全体を好適に混合することが出来る。また、構造的に製造し易い。
In a third aspect, the present invention provides the powder mixer according to the second aspect, wherein the upper inner wall is cylindrical, and the lower inner wall is cylindrical with an inner diameter smaller than that of the upper inner wall. The powder mixer is characterized in that the part has a funnel shape.
In the powder mixer according to the third aspect, a swirl flow of the first water flow, the powder, and the second water flow is created in the upper part of the mixing container, and the swirl flow is directed toward the lower part of the mixing container to reduce the radius. The speed can be increased and the whole can be suitably mixed. Moreover, it is easy to manufacture structurally.

第4の観点では、本発明は、前記第2の観点による粉末混合器において、前記上部内壁から前記下部内壁まで内径が徐々に小さくなる漏斗状であることを特徴とする粉末混合器を提供する。
上記第4の観点による粉末混合器では、混合容器の上部で第1の水流と粉末と第2の水流の旋回流を作り、その旋回流を混合容器の下部へ向けて半径を絞り込むことで周速度を高速化し、全体を好適に混合することが出来る。また、内壁に粉末が付着・堆積し難い。
In a fourth aspect, the present invention provides the powder mixer according to the second aspect, wherein the powder mixer has a funnel shape in which the inner diameter gradually decreases from the upper inner wall to the lower inner wall. .
In the powder mixer according to the fourth aspect, a swirl flow of the first water flow, the powder, and the second water flow is formed at the upper part of the mixing container, and the swirl flow is directed toward the lower part of the mixing container to reduce the radius. The speed can be increased and the whole can be suitably mixed. In addition, it is difficult for powder to adhere to and accumulate on the inner wall.

第5の観点では、本発明は、前記第2の観点による粉末混合器において、前記上部内壁が下方へ向けて内径が徐々に小さくなる漏斗状であり且つ前記下部内壁は円筒状であることを特徴とする粉末混合器を提供する。
上記第5の観点による粉末混合器では、混合容器の上部で第1の水流と粉末と第2の水流の旋回流を作り、その旋回流を混合容器の下部へ向けて半径を絞り込むことで周速度を高速化し、全体を好適に混合することが出来る。また、構造的に製造しやすい。
In a fifth aspect, the present invention provides the powder mixer according to the second aspect, wherein the upper inner wall has a funnel shape in which an inner diameter gradually decreases downward, and the lower inner wall has a cylindrical shape. A powder mixer is provided.
In the powder mixer according to the fifth aspect, a swirl flow of the first water flow, the powder, and the second water flow is created at the upper part of the mixing container, and the swirl flow is directed toward the lower part of the mixing container to reduce the radius. The speed can be increased and the whole can be suitably mixed. Moreover, it is easy to manufacture structurally.

本発明の粉末混合器によれば、粉末が水上に浮いてしまうことを抑制し、好適に粉末を水に混合することが出来る。   According to the powder mixer of the present invention, the powder can be prevented from floating on the water, and the powder can be suitably mixed with water.

以下、図に示す実施の形態により本発明をさらに詳細に説明する。なお、これにより本発明が限定されるものではない。   Hereinafter, the present invention will be described in more detail with reference to embodiments shown in the drawings. Note that the present invention is not limited thereby.

図1は、実施例1に係る粉末活性炭混合器100の縦断面図である。また、図2は、同上面図である。
この粉末活性炭混合器100は、上部内壁1aが円筒状であり且つ下部内壁1bは上部内壁1aよりも内径が小さい円筒状であり且つそれらの中間部1cは漏斗状になっている混合容器1と、混合容器1の上部内壁1aに沿って旋回しながら落下するように上部内壁1aに向けて第1の水流(図3のW1)を噴射する第1の給水ノズル2と、旋回する第1の水流(図3のW1)に対して上方から粉末活性炭(図3のP)を落下させる粉末活性炭注入管3と、上部内壁1aに沿って旋回しながら粉末活性炭Pを搬送する第1の水流(図3のW1)に対して上方から第2の水流(図3のW2)を合流させる第2の給水ノズル4とを具備している。
FIG. 1 is a longitudinal sectional view of a powdered activated carbon mixer 100 according to the first embodiment. FIG. 2 is a top view of the same.
This powder activated carbon mixer 100 includes a mixing container 1 in which an upper inner wall 1a has a cylindrical shape, a lower inner wall 1b has a cylindrical shape whose inner diameter is smaller than that of the upper inner wall 1a, and an intermediate portion 1c thereof has a funnel shape. The first water supply nozzle 2 that injects the first water flow (W1 in FIG. 3) toward the upper inner wall 1a so as to fall while swirling along the upper inner wall 1a of the mixing container 1, and the first swirling first A powdered activated carbon injection pipe 3 for dropping powdered activated carbon (P in FIG. 3) from above with respect to the water flow (W1 in FIG. 3), and a first water stream (PW) that conveys the powdered activated carbon P while turning along the upper inner wall 1a ( 3 is provided with a second water supply nozzle 4 that joins a second water flow (W2 in FIG. 3) from above with respect to W1) in FIG.

図3および図4に示すように、第1の給水ノズル2から上部内壁1aに向けて第1の水流W1を噴射すると、第1の水流W1は上部内壁1aに沿って旋回しながら落下する。その旋回しながら落下する第1の水流W1上に粉末活性炭注入管3から粉末活性炭Pを落下させると、第1の水流W1が粉末活性炭Pを乗せて上部内壁1aに沿って旋回しながら落下する。
図5に示すように、第2の給水ノズル4から上部内壁1aに向けて第2の水流W2を噴射すると、粉末活性炭Pを乗せて旋回しながら落下する第1の水流W1上の粉末活性炭Pの上に第2の水流W2が被さり(そうなるように配置してある)、第1の水流W1と第2の水流W2の間に粉末活性炭Pが挟まれる。
そして、第1の水流W1と粉末活性炭Pと第2の水流W2とが中間部1cや下部内壁1bに沿って高速周速度で旋回することにより、好適に粉末活性炭Pを水に混合することが出来る。
As shown in FIGS. 3 and 4, when the first water flow W1 is injected from the first water supply nozzle 2 toward the upper inner wall 1a, the first water flow W1 falls while turning along the upper inner wall 1a. When the powdered activated carbon P is dropped from the powdered activated carbon injection pipe 3 onto the first water flow W1 falling while turning, the first water flow W1 falls while turning along the upper inner wall 1a with the powdered activated carbon P placed thereon. .
As shown in FIG. 5, when the second water flow W2 is sprayed from the second water supply nozzle 4 toward the upper inner wall 1a, the powdered activated carbon P on the first water flow W1 falling while swirling with the powdered activated carbon P is placed. A second water flow W2 is covered on (arranged so as to be), and the powdered activated carbon P is sandwiched between the first water flow W1 and the second water flow W2.
The first activated water stream W1, the powdered activated carbon P, and the second activated water stream W2 are swirled at a high speed peripheral speed along the intermediate portion 1c and the lower inner wall 1b, so that the powdered activated carbon P can be suitably mixed with water. I can do it.

なお、粉末活性炭混合器100は浄水施設における着水井の上方に設置されており、粉末活性炭Pと水の混合流は着水井の注入点に放出される。   The powdered activated carbon mixer 100 is installed above the landing well in the water purification facility, and the mixed flow of the powdered activated carbon P and water is discharged to the injection point of the landing well.

実施例1の粉末活性炭混合器100によれば、粉末活性炭Pが水上に浮いてしまうことを抑制し、好適に粉末活性炭Pを水に混合することが出来る。また、製造し易い構造の混合容器1になっている。   According to the powdered activated carbon mixer 100 of Example 1, it can suppress that the powdered activated carbon P floats on water, and can mix the powdered activated carbon P with water suitably. Moreover, it is the mixing container 1 of the structure which is easy to manufacture.

図6は、実施例2に係る粉末活性炭混合器200の縦断面図である。また、図7は、同上面図である。
この粉末活性炭混合器200では、上部内壁1aから下部内壁1bまで内径が徐々に小さくなる漏斗状の混合容器1を用いている。他の構成は実施例1と同様である。
FIG. 6 is a longitudinal sectional view of the powdered activated carbon mixer 200 according to the second embodiment. FIG. 7 is a top view of the same.
The powdered activated carbon mixer 200 uses a funnel-shaped mixing container 1 whose inner diameter gradually decreases from the upper inner wall 1a to the lower inner wall 1b. Other configurations are the same as those of the first embodiment.

実施例2の粉末活性炭混合器200によれば、粉末活性炭Pが水上に浮いてしまうことを抑制し、好適に粉末活性炭Pを水に混合することが出来る。また、粉末活性炭Pが付着・堆積し難い構造の混合容器1になっている。   According to the powdered activated carbon mixer 200 of Example 2, it can suppress that the powdered activated carbon P floats on water, and can mix the powdered activated carbon P with water suitably. Moreover, it is the mixing container 1 of the structure where powdered activated carbon P does not adhere and deposit easily.

図8は、実施例3に係る粉末活性炭混合器300の縦断面図である。また、図9は、同上面図である。
この粉末活性炭混合器300では、上部内壁1aは下方へ向けて内径が徐々に小さくなる漏斗状になっており且つ下部内壁1bは円筒状になっている混合容器1を用いている。他の構成は実施例1と同様である。
FIG. 8 is a longitudinal sectional view of the powdered activated carbon mixer 300 according to the third embodiment. FIG. 9 is a top view of the same.
In the powdered activated carbon mixer 300, the upper inner wall 1a has a funnel shape in which the inner diameter gradually decreases downward, and the lower inner wall 1b has a cylindrical mixing container 1. Other configurations are the same as those of the first embodiment.

実施例3の粉末活性炭混合器300によれば、粉末活性炭Pが水上に浮いてしまうことを抑制し、好適に粉末活性炭Pを水に混合することが出来る。また、構造的に製造しやすい。   According to the powdered activated carbon mixer 300 of Example 3, it can suppress that the powdered activated carbon P floats on water, and can mix the powdered activated carbon P with water suitably. Moreover, it is easy to manufacture structurally.

第2の水流を被せた旋回流にさらに第3の水流を被せる第3の給水ノズルを設けてもよい。
同様に、さらに水流を被せる第4の給水ノズル等を設けてもよい。
You may provide the 3rd water supply nozzle which covers a swirl flow which covered the 2nd water flow further, and covers a 3rd water flow.
Similarly, you may provide the 4th water supply nozzle etc. which cover a water flow further.

本発明の粉末混合器は、例えば浄水施設で粉末活性炭や消石灰を水に混合するのに利用できる。   The powder mixer of the present invention can be used, for example, to mix powdered activated carbon or slaked lime with water in a water purification facility.

実施例1に係る粉末活性炭混合器を示す縦断面図である。1 is a longitudinal sectional view showing a powdered activated carbon mixer according to Example 1. FIG. 実施例1に係る粉末活性炭混合器を示す上面図である。1 is a top view showing a powdered activated carbon mixer according to Example 1. FIG. 実施例1に係る第1の水流と粉末活性炭と第2の水流とを示す説明図である。It is explanatory drawing which shows the 1st water flow which concerns on Example 1, a powdered activated carbon, and a 2nd water flow. 実施例1に係る第1の水流と粉末活性炭とを示す説明図である。It is explanatory drawing which shows the 1st water flow and powdered activated carbon which concern on Example 1. FIG. 実施例1に係る第1の水流と粉末活性炭と第2の水流とを示す説明図である。It is explanatory drawing which shows the 1st water flow which concerns on Example 1, a powdered activated carbon, and a 2nd water flow. 実施例2に係る粉末活性炭混合器を示す縦断面図である。3 is a longitudinal sectional view showing a powdered activated carbon mixer according to Example 2. FIG. 実施例2に係る粉末活性炭混合器を示す上面図である。6 is a top view showing a powdered activated carbon mixer according to Example 2. FIG. 実施例3に係る粉末活性炭混合器を示す縦断面図である。It is a longitudinal cross-sectional view which shows the powdered activated carbon mixer which concerns on Example 3. FIG. 実施例3に係る粉末活性炭混合器を示す上面図である。6 is a top view showing a powdered activated carbon mixer according to Example 3. FIG.

符号の説明Explanation of symbols

1 混合容器
1a 上部内壁
1b 下部内壁
1c 中間部
2 第1の給水ノズル
3 粉末活性炭注入管
4 第2の給水ノズル
100,200 粉末活性炭混合器
P 粉末活性炭
W1 第1の水流
W2 第2の水流
DESCRIPTION OF SYMBOLS 1 Mixing container 1a Upper inner wall 1b Lower inner wall 1c Middle part 2 1st water supply nozzle 3 Powdered activated carbon injection pipe 4 2nd water supply nozzle 100,200 Powdered activated carbon mixer P Powdered activated carbon W1 1st water flow W2 2nd water flow

Claims (5)

第1の水流を混合容器の上部内壁に沿って旋回しながら落下させる第1のステップと、前記旋回する第1の水流に対して上方から粉末を落下させる第2のステップと、前記上部内壁に沿って旋回しながら前記粉末を搬送する前記第1の水流に対して上方から第2の水流を被せるように合流させる第3のステップと、前記合流した水流を前記混合容器の下部内壁に沿って旋回させながら落下させる第4のステップとを有することを特徴とする粉末混合方法。 A first step of dropping the first water stream while swirling along the upper inner wall of the mixing container; a second step of dropping powder from above with respect to the swirling first water stream; A third step of joining the first water stream carrying the powder while swirling along the second water stream from above, and the joined water stream along the lower inner wall of the mixing vessel A powder mixing method comprising: a fourth step of dropping while swirling. 水平断面円形の内壁を有する混合容器と、前記混合容器の上部内壁に沿って旋回しながら落下するように前記上部内壁に向けて第1の水流を噴射する第1の給水ノズルと、前記旋回する第1の水流に対して上方から粉末を落下させる粉末注入管と、前記上部内壁に沿って旋回しながら前記粉末を搬送する前記第1の水流に対して上方から第2の水流を被せるように合流させる第2の給水ノズルと、前記合流した水流が旋回しながら落下する前記混合容器の下部内壁とを具備したことを特徴とする粉末混合器。 A mixing container having a circular inner wall with a horizontal cross section; a first water supply nozzle that injects a first water stream toward the upper inner wall so as to fall while swirling along the upper inner wall of the mixing container; A powder injection tube for dropping powder from above with respect to the first water flow, and a second water flow from above to cover the first water flow for conveying the powder while turning along the upper inner wall. A powder mixer, comprising: a second water supply nozzle to be joined; and a lower inner wall of the mixing container in which the joined water flow falls while swirling. 請求項2に記載の粉末混合器において、前記上部内壁が円筒状であり、前記下部内壁は前記上部内壁よりも内径が小さい円筒状であり、それらの中間部は漏斗状になっていることを特徴とする粉末混合器。 The powder mixer according to claim 2, wherein the upper inner wall is cylindrical, the lower inner wall is cylindrical with an inner diameter smaller than the upper inner wall, and an intermediate portion thereof is funnel-shaped. Characteristic powder mixer. 請求項2に記載の粉末混合器において、前記上部内壁から前記下部内壁まで内径が徐々に小さくなる漏斗状であることを特徴とする粉末混合器。 The powder mixer according to claim 2, wherein the powder mixer has a funnel shape in which an inner diameter gradually decreases from the upper inner wall to the lower inner wall. 請求項2に記載の粉末混合器において、前記上部内壁が下方へ向けて内径が徐々に小さくなる漏斗状であり且つ前記下部内壁は円筒状であることを特徴とする粉末混合器。 3. The powder mixer according to claim 2, wherein the upper inner wall has a funnel shape in which an inner diameter gradually decreases downward and the lower inner wall has a cylindrical shape. 4.
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Publication number Priority date Publication date Assignee Title
CN101934159A (en) * 2009-06-30 2011-01-05 江苏瀚深水业科技发展有限公司 Powdery active carbon (PAC) tiptronic wet-type feeding device and dust absorption device thereof
CN101935084A (en) * 2009-06-30 2011-01-05 江苏瀚深水业科技发展有限公司 Dust absorbing device for storage hopper in wet powdered activated carbon dosing equipment
CN101935083A (en) * 2009-06-30 2011-01-05 江苏瀚深水业科技发展有限公司 Dust absorbing device of mixing barrel in automatic wet powdery activated carbon adding equipment
CN101935082A (en) * 2009-06-30 2011-01-05 江苏瀚深水业科技发展有限公司 Dust absorption device for mixing drum in powder activated carbon manual wet-type feeding device
JP2012082110A (en) * 2010-10-13 2012-04-26 Bio Coke Lab Co Ltd Hydrogen generation apparatus
JP2013193033A (en) * 2012-03-21 2013-09-30 Kureha Ecology Management Co Ltd Method for producing activated carbon slurry
JP2016218048A (en) * 2015-05-21 2016-12-22 株式会社堀場製作所 Sample introduction device

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CN101934159A (en) * 2009-06-30 2011-01-05 江苏瀚深水业科技发展有限公司 Powdery active carbon (PAC) tiptronic wet-type feeding device and dust absorption device thereof
CN101935084A (en) * 2009-06-30 2011-01-05 江苏瀚深水业科技发展有限公司 Dust absorbing device for storage hopper in wet powdered activated carbon dosing equipment
CN101935083A (en) * 2009-06-30 2011-01-05 江苏瀚深水业科技发展有限公司 Dust absorbing device of mixing barrel in automatic wet powdery activated carbon adding equipment
CN101935082A (en) * 2009-06-30 2011-01-05 江苏瀚深水业科技发展有限公司 Dust absorption device for mixing drum in powder activated carbon manual wet-type feeding device
CN101934159B (en) * 2009-06-30 2013-02-13 江苏瀚深水业科技发展有限公司 Powdery active carbon (PAC) tiptronic wet-type feeding device and dust absorption device thereof
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JP2012082110A (en) * 2010-10-13 2012-04-26 Bio Coke Lab Co Ltd Hydrogen generation apparatus
JP2013193033A (en) * 2012-03-21 2013-09-30 Kureha Ecology Management Co Ltd Method for producing activated carbon slurry
JP2016218048A (en) * 2015-05-21 2016-12-22 株式会社堀場製作所 Sample introduction device

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