JP2007519508A - サーモプレートを使用して反応器中の流体反応混合物の反応を監視、制御および/または調節する方法 - Google Patents
サーモプレートを使用して反応器中の流体反応混合物の反応を監視、制御および/または調節する方法 Download PDFInfo
- Publication number
- JP2007519508A JP2007519508A JP2006546034A JP2006546034A JP2007519508A JP 2007519508 A JP2007519508 A JP 2007519508A JP 2006546034 A JP2006546034 A JP 2006546034A JP 2006546034 A JP2006546034 A JP 2006546034A JP 2007519508 A JP2007519508 A JP 2007519508A
- Authority
- JP
- Japan
- Prior art keywords
- sleeve
- gap
- reactor
- reaction mixture
- thermoplate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000011541 reaction mixture Substances 0.000 title claims abstract description 45
- 239000012530 fluid Substances 0.000 title claims abstract description 40
- 238000006243 chemical reaction Methods 0.000 title claims abstract description 38
- 238000000034 method Methods 0.000 title claims abstract description 23
- 238000012544 monitoring process Methods 0.000 title claims abstract description 12
- 239000003054 catalyst Substances 0.000 claims abstract description 42
- 238000005259 measurement Methods 0.000 claims abstract description 14
- 230000001276 controlling effect Effects 0.000 claims abstract description 6
- 230000001105 regulatory effect Effects 0.000 claims abstract description 6
- 238000005070 sampling Methods 0.000 claims description 46
- 229910052751 metal Inorganic materials 0.000 claims description 12
- 239000002184 metal Substances 0.000 claims description 12
- 239000000203 mixture Substances 0.000 claims description 8
- 238000009413 insulation Methods 0.000 claims description 3
- 238000000926 separation method Methods 0.000 claims description 3
- 230000009977 dual effect Effects 0.000 claims 1
- 238000010438 heat treatment Methods 0.000 claims 1
- 238000012546 transfer Methods 0.000 description 17
- 238000003466 welding Methods 0.000 description 11
- 239000000463 material Substances 0.000 description 8
- 238000009826 distribution Methods 0.000 description 5
- 239000002608 ionic liquid Substances 0.000 description 5
- 238000007254 oxidation reaction Methods 0.000 description 5
- 239000002826 coolant Substances 0.000 description 4
- -1 ie gaseous Substances 0.000 description 4
- 239000012429 reaction media Substances 0.000 description 4
- 229910000831 Steel Inorganic materials 0.000 description 3
- 238000009529 body temperature measurement Methods 0.000 description 3
- 238000010586 diagram Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000000376 reactant Substances 0.000 description 3
- 125000006850 spacer group Chemical group 0.000 description 3
- 239000010959 steel Substances 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 2
- 150000001768 cations Chemical class 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 230000009849 deactivation Effects 0.000 description 2
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Chemical compound C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 description 1
- PGNKBEARDDELNB-UHFFFAOYSA-N Diethylcarbamazine citrate Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O.CCN(CC)C(=O)N1CCN(C)CC1 PGNKBEARDDELNB-UHFFFAOYSA-N 0.000 description 1
- RAXXELZNTBOGNW-UHFFFAOYSA-O Imidazolium Chemical compound C1=C[NH+]=CN1 RAXXELZNTBOGNW-UHFFFAOYSA-O 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 230000006978 adaptation Effects 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 229910001413 alkali metal ion Inorganic materials 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 235000010290 biphenyl Nutrition 0.000 description 1
- 239000004305 biphenyl Substances 0.000 description 1
- 125000006267 biphenyl group Chemical group 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 238000012993 chemical processing Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000002452 interceptive effect Effects 0.000 description 1
- 238000005304 joining Methods 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- JUJWROOIHBZHMG-UHFFFAOYSA-O pyridinium Chemical compound C1=CC=[NH+]C=C1 JUJWROOIHBZHMG-UHFFFAOYSA-O 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/24—Stationary reactors without moving elements inside
- B01J19/248—Reactors comprising multiple separated flow channels
- B01J19/249—Plate-type reactors
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/0006—Controlling or regulating processes
- B01J19/0013—Controlling the temperature of the process
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/24—Stationary reactors without moving elements inside
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/001—Controlling catalytic processes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/0285—Heating or cooling the reactor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00008—Controlling the process
- B01J2208/00017—Controlling the temperature
- B01J2208/00026—Controlling or regulating the heat exchange system
- B01J2208/00035—Controlling or regulating the heat exchange system involving measured parameters
- B01J2208/00044—Temperature measurement
- B01J2208/00061—Temperature measurement of the reactants
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00008—Controlling the process
- B01J2208/00017—Controlling the temperature
- B01J2208/00106—Controlling the temperature by indirect heat exchange
- B01J2208/00115—Controlling the temperature by indirect heat exchange with heat exchange elements inside the bed of solid particles
- B01J2208/0015—Plates; Cylinders
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00008—Controlling the process
- B01J2208/00628—Controlling the composition of the reactive mixture
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00796—Details of the reactor or of the particulate material
- B01J2208/00946—Features relating to the reactants or products
- B01J2208/00955—Sampling of the particulate material, the reactants or the products
- B01J2208/00964—Reactants
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00796—Details of the reactor or of the particulate material
- B01J2208/00946—Features relating to the reactants or products
- B01J2208/00955—Sampling of the particulate material, the reactants or the products
- B01J2208/00973—Products
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00051—Controlling the temperature
- B01J2219/00054—Controlling or regulating the heat exchange system
- B01J2219/00056—Controlling or regulating the heat exchange system involving measured parameters
- B01J2219/00058—Temperature measurement
- B01J2219/00063—Temperature measurement of the reactants
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00191—Control algorithm
- B01J2219/00193—Sensing a parameter
- B01J2219/00195—Sensing a parameter of the reaction system
- B01J2219/002—Sensing a parameter of the reaction system inside the reactor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/24—Stationary reactors without moving elements inside
- B01J2219/2401—Reactors comprising multiple separate flow channels
- B01J2219/245—Plate-type reactors
- B01J2219/2451—Geometry of the reactor
- B01J2219/2453—Plates arranged in parallel
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/24—Stationary reactors without moving elements inside
- B01J2219/2401—Reactors comprising multiple separate flow channels
- B01J2219/245—Plate-type reactors
- B01J2219/2451—Geometry of the reactor
- B01J2219/2456—Geometry of the plates
- B01J2219/2459—Corrugated plates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/24—Stationary reactors without moving elements inside
- B01J2219/2401—Reactors comprising multiple separate flow channels
- B01J2219/245—Plate-type reactors
- B01J2219/2461—Heat exchange aspects
- B01J2219/2462—Heat exchange aspects the reactants being in indirect heat exchange with a non reacting heat exchange medium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/24—Stationary reactors without moving elements inside
- B01J2219/2401—Reactors comprising multiple separate flow channels
- B01J2219/245—Plate-type reactors
- B01J2219/2461—Heat exchange aspects
- B01J2219/2462—Heat exchange aspects the reactants being in indirect heat exchange with a non reacting heat exchange medium
- B01J2219/2464—Independent temperature control in various sections of the reactor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/24—Stationary reactors without moving elements inside
- B01J2219/2401—Reactors comprising multiple separate flow channels
- B01J2219/245—Plate-type reactors
- B01J2219/2476—Construction materials
- B01J2219/2477—Construction materials of the catalysts
- B01J2219/2481—Catalysts in granular from between plates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/24—Stationary reactors without moving elements inside
- B01J2219/2401—Reactors comprising multiple separate flow channels
- B01J2219/245—Plate-type reactors
- B01J2219/2476—Construction materials
- B01J2219/2483—Construction materials of the plates
- B01J2219/2485—Metals or alloys
- B01J2219/2486—Steel
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/24—Stationary reactors without moving elements inside
- B01J2219/2401—Reactors comprising multiple separate flow channels
- B01J2219/245—Plate-type reactors
- B01J2219/2491—Other constructional details
- B01J2219/2497—Size aspects, i.e. concrete sizes are being mentioned in the classified document
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
- Monitoring And Testing Of Nuclear Reactors (AREA)
Abstract
Description
1個以上の立方形サーモプレート装置を有し、前記装置はそれぞれ互いに平行にそれぞれ1つの間隙を解放して配置された、2個以上の長方形のサーモプレートから形成され、間隙に不均一粒子状触媒を充填することができ、間隙に流体反応混合物が貫流し、反応熱が熱媒体により吸収され、熱媒体はサーモプレートを貫流し、少なくとも部分的に蒸発し、更に
実質的にシリンダー状シェルを有し、前記シェルはサーモプレート装置で圧力を解放し、サーモプレート装置を完全に包囲し、シリンダージャケットおよびフードを有し、前記フードは両方の端部でジャケットを閉鎖し、ジャケットの縦軸がサーモプレートの平面に平行に配列し、更に
1個以上の閉鎖部品を有し、前記部品は、流体反応混合物が、フードにより境界付けられる反応器内部空間を貫流することを除いて、間隙のみを貫流するように配置される。
サーモプレート装置は圧力を解放する、主にシリンダー状シェルにより完全に包囲され、シリンダージャケットおよびフードを有し、フードは両方の端部で閉鎖され、縦軸がサーモプレートの平面に対して平行に配列され、
流体反応混合物がフードにより結合した反応器内部を貫流することを除いて、間隙のみを貫流するように、1個以上の閉鎖部品が配置され、
1個以上の互いに独立した温度測定インサートを有するそれぞれのサーモプレート装置に有利に2個または3個の、より有利に3個の温度測定インサートが備えられている。
図2は図2Aに横断面で示される、横方向に配置されたスリーブを有する他の構成の縦断面図であり、
図3は図3Aに横断面で示され、図3Bに詳しく示される、間隙に水平に配置されるスリーブを有する他の構成の縦断面図であり。
図4は図4Aに横断面で示される穿孔を有するスリーブおよび試料採取管の他の構成の断面図であり、
図5はサーモプレート装置中の本発明のスリーブを説明する図であり、
図6はサーモプレート表面の有利な溶接点分布の図である。
Claims (29)
- 不均一粒子状触媒の存在で、垂直にかつ互いに平行に、それぞれ1つの間隙(2)を解放して配置される2個以上のサーモプレート(1)を有し、間隙(2)に不均一粒子状触媒が設置され、流体反応混合物が間隙(2)を貫流する反応器中で、流体反応混合物の反応を監視、制御および/または調節する方法において、監視、制御および/または調節パラメーターとして、1個以上の間隙(2)で、それぞれの間隙(2)の高さにより分配されて配置される1個以上の測定点で測定される1個以上の温度値を選択することを特徴とする、流体反応混合物の反応を監視、制御および/または調節する方法。
- 他の監視、制御および/または調節パラメーターとして、1個以上の間隙(2)中の流体反応混合物の組成を選択し、前記組成をそれぞれの間隙(2)の高さにより分配されて配置される1個以上の測定点で測定する請求項1記載の方法。
- 間隙(2)に配置され、反応器の外部に開口し、それぞれ1個以上の測定点を有する1つの温度測定インサート(4)を包囲するスリーブ(3)を有することを特徴とする請求項1の方法を実施する装置。
- スリーブが間隙(2)中に長手方向に配置されている請求項3記載の装置。
- サーモプレート(1)が1個以上の立方形サーモプレート装置(10)に配置され、サーモプレート装置はそれぞれ2個以上の長方形の、互いに平行に、それぞれ1つの間隙(2)を解放して配置されるサーモプレート(1)から形成され、
サーモプレート装置(10)は圧力を解放する、主にシリンダー状シェル(11、12、13)により完全に包囲され、シリンダージャケット(11)および両方の端部で閉鎖された同じフード(13)を有し、フードの縦軸がサーモプレート(1)の平面に対して平行に配列され、
流体反応混合物がフード(12、13)により境界付けられた反応器内部空間を貫流することを除いて、間隙(2)のみを貫流するように、1個以上の閉鎖部品(14、15)が配置され、
1個以上の互いに独立した温度測定インサート(4)を有するそれぞれのサーモプレート装置(10)に、有利に2個または3個の、より有利に3個の温度測定インサート(4)が備えられている、請求項3または4記載の装置。 - 温度測定インサート(4)が複式測定インサート、有利にマルチサーモエレメントである請求項3から5までのいずれか1項記載の装置。
- スリーブが有利に金属管、特に4〜15mm、有利に6〜10mm、より有利に6〜8mmの範囲の外径および更に有利に0.8〜1.5mm、有利に1mmの壁厚を有する金属管である請求項3から5までのいずれか1項記載の装置。
- スリーブ(3)が反応器内部空間内に1個以上の分離点を有する請求項3から7までのいずれか1項記載の装置。
- 温度測定インサート(4)の測定点が期待される温度極大値および/または特に大きい温度勾配を有する反応器部分では、互いにかなり小さい間隔で配置され、残りの反応器部分では互いにかなり大きい間隔で配置されている請求項3から8までのいずれか1項記載の装置。
- 温度測定インサート(4)を包囲するスリーブ(3)が反応器の上と下の両方に開口し、温度特性の妨害されない測定のために、有利に等間隔の測定点が備えられる温度測定インサート(4)を連続的にスリーブ(3)に移動できる請求項3から9までのいずれか1項記載の装置。
- 温度測定インサート(4)が5〜60個、有利に10〜50個、より有利に15〜40個、更に有利に20〜30個の測定点を有する請求項3から10までのいずれか1項記載の装置。
- 温度測定インサート(4)が20個の測定点および約3.8mmの外径を有し、スリーブ(3)が6mmまたは1/4インチの外径および4mmまたは5/32インチの内径を有する請求項11記載の装置。
- 温度測定インサート(4)が40個の測定点および約2.5mmの外径を有し、スリーブ(3)が5mmまたは3/16インチの外径および3mmまたは1/8インチの内径を有する請求項11記載の装置。
- スリーブ(3)が間隙(2)の中心に長手方向に配置される請求項4から13までのいずれか1項記載の装置。
- スリーブ(3)が間隙(2)の横方向の境界(6)に配置される請求項4から13までのいずれか1項記載の装置。
- 間隙(2)の横方向の境界(6)とスリーブ(3)の間に断熱部品が用意され、スリーブ(3)が有利に間隙(2)に固定して設置され、スリーブ(3)がより有利に正方形または半円形横断面を有する請求項15記載の装置。
- 間隙(2)にスリーブ(3)が水平に配置される請求項3または5から13までのいずれか1項記載の装置。
- 請求項3から16までのいずれか1項記載の装置のほかに、1個以上の間隙(2)にそれぞれ1つのスリーブ(3)が用意され、前記スリーブは穿孔(7)およびスリーブ(3)に導入する少なくとも1個の試料採取管(8)を有し、前記管がスリーブ(3)に、流体反応混合物がスリーブ(3)内の穿孔(7)をとおり試料採取管(8)に流れるように配置され、反応器の外部に試料採取管(8)から取り出され、分析される請求項2記載の方法を実施する装置。
- 試料採取管(8)がスリーブ(3)に、試料採取管(8)の開口がスリーブ(3)の穿孔(7)に直接配置されるように固定して接続されている請求項18記載の装置。
- 試料採取管(8)が穿孔されたスリーブ(3)に回転可能に配置され、流体反応混合物が常に1つのみの開口により試料採取管(8)に流れるように、ジャケット表面上にずれて配置された2個以上の開口を有する請求項18記載の装置。
- 試料採取管(8)の開口がその長手方向にスロットとして形成される請求項20記載の装置。
- それぞれの試料採取管(8)が2個以上、有利に2〜4個の、互いに分離した部屋を有し、それぞれの部屋は開口を有し、前記開口に流体反応混合物がスリーブ(3)内の穿孔(7)により流れ、流体反応混合物がそれぞれの部屋から別々に取り出され、分析される請求項18から21までのいずれか1項記載の装置。
- 部屋が互いに隣接してまたは同心状に配置される請求項22記載の装置。
- 多数の部屋を有する試料採取管(8)がその縦軸の周りに回転可能に形成される請求項21または22記載の装置。
- 2個以上の試料採取管(8)が用意され、それぞれスリーブ(3)に、それぞれの試料採取管(8)の開口が直接スリーブ(3)の穿孔(7)に配置され、個々の試料採取管(8)が間隙(2)にそれぞれ異なる高さで開口するように、固定して接続される請求項18から24までのいずれか1項記載の装置。
- スリーブ(3)がそれ自体試料採取管(8)として形成される請求項18記載の装置。
- 反応器に、請求項3から17までおよび/または請求項18から26までのいずれか1項記載の装置を取り付ける方法において、前記装置が、反応器の、流体反応混合物の供給と同じ側から設置されることを特徴とする、反応器に装置を取り付ける方法。
- 装置を設置し、流体反応混合物を反応器にそれぞれ上から供給し、スリーブ(3)が間隙(2)の上側部分にのみ、特にほぼ間隙(2)の中点まで穿孔(7)を有する請求項27記載の方法。
- 装置を設置し、流体反応混合物を反応器にそれぞれ下から供給し、熱媒体が有利にサーモプレート(1)を通過し、反応条件下で部分的にまたは完全に蒸発する請求項27記載の方法。
Applications Claiming Priority (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US53167803P | 2003-12-23 | 2003-12-23 | |
DE10361515.6 | 2003-12-23 | ||
DE2003161515 DE10361515A1 (de) | 2003-12-23 | 2003-12-23 | Verfahren zur Überwachung, Steuerung und/oder Regelung von Reaktionen eines fluiden Reaktionsgemisches in einem Reaktor mit Thermoblechplatten |
US60/531,678 | 2003-12-23 | ||
PCT/EP2004/014532 WO2005063374A1 (de) | 2003-12-23 | 2004-12-21 | Verfahren zur überwachung, steuerung und/oder regelung von reaktionen eines fluiden reaktionsgemisches in einem reaktor mit thermoblechplatten |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2007519508A true JP2007519508A (ja) | 2007-07-19 |
JP4970953B2 JP4970953B2 (ja) | 2012-07-11 |
Family
ID=34740518
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2006546034A Expired - Fee Related JP4970953B2 (ja) | 2003-12-23 | 2004-12-21 | サーモプレートを使用して反応器中の流体反応混合物の反応を監視、制御および/または調節する方法 |
Country Status (11)
Country | Link |
---|---|
US (1) | US20050158217A1 (ja) |
EP (1) | EP1699550B1 (ja) |
JP (1) | JP4970953B2 (ja) |
KR (1) | KR101196082B1 (ja) |
CN (1) | CN100548461C (ja) |
BR (1) | BRPI0417856B1 (ja) |
CA (1) | CA2548360C (ja) |
RU (1) | RU2356617C2 (ja) |
SG (1) | SG149877A1 (ja) |
WO (1) | WO2005063374A1 (ja) |
ZA (1) | ZA200605103B (ja) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8695912B2 (en) | 2011-04-19 | 2014-04-15 | Great Stuff, Inc. | Reel systems and methods for monitoring and controlling linear material slack |
US9067759B2 (en) | 2012-04-17 | 2015-06-30 | Great Stuff, Inc. | Automatic reel devices and method of operating the same |
WO2018105588A1 (ja) | 2016-12-08 | 2018-06-14 | 株式会社Ihi | 反応装置 |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102007028332A1 (de) * | 2007-06-15 | 2008-12-18 | Basf Se | Verfahren zum Beschicken eines Reaktors mit einem Katalysatorfestbett, das wenigstens ringförmige Katalysatorformkörper K umfasst |
DE102007061477A1 (de) | 2007-12-20 | 2009-07-02 | Man Dwe Gmbh | Rohrbündelreaktor |
DE102009031765B4 (de) | 2009-06-25 | 2012-10-11 | Chemieanlagenbau Chemnitz Gmbh | Konverter zur Durchführung exothermer katalytischer Reaktionen |
FR2975922B1 (fr) | 2011-06-06 | 2013-05-31 | Arkema France | Reacteur a plaques avec injection in situ |
PL2594328T3 (pl) * | 2011-11-21 | 2014-12-31 | Its Reaktortechnik Gmbh | Proces do usuwania siarkowodoru ze strumienia gazu |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE19754185C1 (de) * | 1997-12-06 | 1999-02-04 | Deg Engineering Gmbh | Reaktor für die katalytische Umsetzung von Reaktionsmedien, insbesondere von gasförmigen Reaktionsmedien |
DE10110847A1 (de) * | 2001-03-07 | 2002-09-12 | Gerhard Olbert | Meßverfahren und -einrichtung zur Überwachung und Steuerung von Reaktionen in Kontaktrohrbündelreaktoren |
JP2004202430A (ja) * | 2002-12-26 | 2004-07-22 | Mitsubishi Chemical Engineering Corp | プレート型触媒反応器 |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2156463A (en) * | 1984-03-22 | 1985-10-09 | Nat Nuclear Corp Ltd | Pipe junction-internal insulation |
DE10000584A1 (de) * | 2000-01-10 | 2001-07-12 | Basf Ag | Verfahren zur katalytischen Gasphasenoxidation zu Maleinsäureanhydrid |
KR101196047B1 (ko) * | 2003-12-23 | 2012-11-02 | 바스프 에스이 | C3 및/또는 c4 전구체 화합물의 불균질하게 촉매되는부분 산화에 의한 (메트)아크롤레인 및/또는(메트)아크릴산의 생산 방법 |
-
2004
- 2004-12-21 CA CA2548360A patent/CA2548360C/en not_active Expired - Fee Related
- 2004-12-21 EP EP04804130A patent/EP1699550B1/de not_active Not-in-force
- 2004-12-21 RU RU2006126514/12A patent/RU2356617C2/ru not_active IP Right Cessation
- 2004-12-21 CN CNB2004800389279A patent/CN100548461C/zh not_active Expired - Fee Related
- 2004-12-21 SG SG200900496-1A patent/SG149877A1/en unknown
- 2004-12-21 BR BRPI0417856-4A patent/BRPI0417856B1/pt not_active IP Right Cessation
- 2004-12-21 JP JP2006546034A patent/JP4970953B2/ja not_active Expired - Fee Related
- 2004-12-21 WO PCT/EP2004/014532 patent/WO2005063374A1/de active Application Filing
- 2004-12-21 KR KR1020067012443A patent/KR101196082B1/ko not_active IP Right Cessation
- 2004-12-23 US US11/019,193 patent/US20050158217A1/en not_active Abandoned
-
2006
- 2006-06-21 ZA ZA2006/05103A patent/ZA200605103B/en unknown
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE19754185C1 (de) * | 1997-12-06 | 1999-02-04 | Deg Engineering Gmbh | Reaktor für die katalytische Umsetzung von Reaktionsmedien, insbesondere von gasförmigen Reaktionsmedien |
DE10110847A1 (de) * | 2001-03-07 | 2002-09-12 | Gerhard Olbert | Meßverfahren und -einrichtung zur Überwachung und Steuerung von Reaktionen in Kontaktrohrbündelreaktoren |
JP2004202430A (ja) * | 2002-12-26 | 2004-07-22 | Mitsubishi Chemical Engineering Corp | プレート型触媒反応器 |
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8695912B2 (en) | 2011-04-19 | 2014-04-15 | Great Stuff, Inc. | Reel systems and methods for monitoring and controlling linear material slack |
US8746605B2 (en) | 2011-04-19 | 2014-06-10 | Great Stuff, Inc. | Systems and methods for spooling and unspooling linear material |
US9663322B2 (en) | 2011-04-19 | 2017-05-30 | Great Stuff, Inc. | Systems and methods for spooling and unspooling linear material |
US10556772B2 (en) | 2011-04-19 | 2020-02-11 | Great Stuff, Inc. | Systems and methods for spooling and unspooling linear material |
US11697570B2 (en) | 2011-04-19 | 2023-07-11 | Great Stuff, Inc. | Systems and methods for spooling and unspooling linear material |
US9067759B2 (en) | 2012-04-17 | 2015-06-30 | Great Stuff, Inc. | Automatic reel devices and method of operating the same |
US9771239B2 (en) | 2012-07-20 | 2017-09-26 | Great Stuff, Inc. | Automatic reel devices and method of operating the same |
US10370218B2 (en) | 2012-07-20 | 2019-08-06 | Great Stuff, Inc. | Reel with manually actuated retraction system |
WO2018105588A1 (ja) | 2016-12-08 | 2018-06-14 | 株式会社Ihi | 反応装置 |
US10583413B2 (en) | 2016-12-08 | 2020-03-10 | Ihi Corporation | Reactor |
Also Published As
Publication number | Publication date |
---|---|
ZA200605103B (en) | 2008-01-08 |
SG149877A1 (en) | 2009-02-27 |
EP1699550A1 (de) | 2006-09-13 |
RU2006126514A (ru) | 2008-01-27 |
BRPI0417856A (pt) | 2007-04-27 |
RU2356617C2 (ru) | 2009-05-27 |
KR20060115754A (ko) | 2006-11-09 |
WO2005063374A1 (de) | 2005-07-14 |
US20050158217A1 (en) | 2005-07-21 |
CN1898014A (zh) | 2007-01-17 |
CN100548461C (zh) | 2009-10-14 |
BRPI0417856B1 (pt) | 2015-03-17 |
EP1699550B1 (de) | 2013-02-20 |
JP4970953B2 (ja) | 2012-07-11 |
CA2548360C (en) | 2015-07-07 |
CA2548360A1 (en) | 2005-07-14 |
KR101196082B1 (ko) | 2012-11-01 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US8524156B2 (en) | Tube bundle reactor | |
JP4970953B2 (ja) | サーモプレートを使用して反応器中の流体反応混合物の反応を監視、制御および/または調節する方法 | |
JP2008540992A (ja) | 可変プレート熱交換器 | |
KR101317097B1 (ko) | C3 및/또는 c4 전구체 화합물의 불균질하게 촉매되는 부분 산화에 의한 (메트)아크롤레인 및/또는 (메트)아크릴산의 생산 방법 | |
EP1279640A1 (en) | System for controlling and eliminating hydrogen | |
Dixon et al. | The influence of the tube and particle diameters at constant ratio on heat transfer in packed beds | |
US7214821B2 (en) | Preparation of (meth)acrolein and/or (meth)acrylic acid by heterogeneously catalyzed partial oxidation of C3 and/or C4 precursor compounds | |
JP4386719B2 (ja) | 触媒系の試験のための反応器 | |
TWI376267B (en) | Monitoring, control and/or regulation of reactions of a fluid reaction mixture in a reactor having thermoplates | |
MXPA06005767A (en) | Method for monitoring, controlling and/or regulating the reactions of a fluidic reaction mixture in a reactor using thermal sheet metal plates | |
WO2004020084A1 (en) | Combinatorial catalytic reactor | |
Koning et al. | Modeling of Heat and Mass Transport in Wall-Cooled Tubular Reactors |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20090904 |
|
A601 | Written request for extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A601 Effective date: 20091201 |
|
A602 | Written permission of extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A602 Effective date: 20091208 |
|
A601 | Written request for extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A601 Effective date: 20091228 |
|
A602 | Written permission of extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A602 Effective date: 20100108 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20100119 |
|
A02 | Decision of refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A02 Effective date: 20100526 |
|
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 |
|
A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20120405 |
|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20150413 Year of fee payment: 3 |
|
R150 | Certificate of patent or registration of utility model |
Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
LAPS | Cancellation because of no payment of annual fees |