JP2007324243A - Solid electrolytic capacitor - Google Patents

Solid electrolytic capacitor Download PDF

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JP2007324243A
JP2007324243A JP2006150583A JP2006150583A JP2007324243A JP 2007324243 A JP2007324243 A JP 2007324243A JP 2006150583 A JP2006150583 A JP 2006150583A JP 2006150583 A JP2006150583 A JP 2006150583A JP 2007324243 A JP2007324243 A JP 2007324243A
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lead frame
cathode
capacitor element
layer
solid electrolytic
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Yuichi Igawa
祐一 井川
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Nichicon Corp
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Abstract

<P>PROBLEM TO BE SOLVED: To provide a solid electrolytic capacitor which improves the volume efficiency at a low production cost without manufacturing a new die, even at the change of the thickness of a lead frame used for a general-purposed structure. <P>SOLUTION: An anode lead wire is planted on one end face of a capacitor element composed of an oxide film layer, a solid electrolyte layer, and a cathode leading layer in this order on the surface of an anode made of a valve action metal. The anode lead wire is resistance-welded to an anode lead frame, and thereafter the cathode leading layer is connected to a cathode lead frame with conductive adhesives. The cathode lead frame has at least a thinner part facing the capacitor element than portions not covered with the armor resin. <P>COPYRIGHT: (C)2008,JPO&INPIT

Description

本発明は、チップ形固体電解コンデンサに関し、特に、陰極リードフレームの形状を改良したチップ形固体電解コンデンサに関するものである。   The present invention relates to a chip-type solid electrolytic capacitor, and more particularly to a chip-type solid electrolytic capacitor having an improved cathode lead frame shape.

従来から、電子回路においては、チップ形コンデンサが幅広く利用されている。コンデンサの中でも固体電解コンデンサは、比較的小形で大容量であることから、携帯電子機器等に用いられている。   Conventionally, chip-type capacitors have been widely used in electronic circuits. Among capacitors, solid electrolytic capacitors are used in portable electronic devices and the like because they are relatively small and have a large capacity.

従来の固体電解コンデンサとしては、たとえば図2に示すような構成のものがある。この固体電解コンデンサでは、タンタル、ニオブ等の弁作用金属粉末を所望の形状にプレス成形し、その圧縮成形体を焼結して焼結体1を形成する。
該焼結体は、陽極導出線2が埋設、または溶接されて一体化され、焼結体表面を陽極酸化にて誘電体となる酸化皮膜層3を形成し、二酸化マンガン、導電性高分子等の固体電解質層4、陰極引出層となるカーボン層5および陰極銀層6が順次積層され、コンデンサ素子7が形成される。
As a conventional solid electrolytic capacitor, there exists a thing of a structure as shown, for example in FIG. In this solid electrolytic capacitor, a valve action metal powder such as tantalum or niobium is press-molded into a desired shape, and the compression-molded body is sintered to form a sintered body 1.
The sintered body is integrated by burying or welding the anode lead-out wire 2, and the surface of the sintered body is anodized to form an oxide film layer 3 serving as a dielectric, such as manganese dioxide, conductive polymer, etc. The solid electrolyte layer 4, the carbon layer 5 serving as the cathode lead layer, and the cathode silver layer 6 are sequentially laminated to form the capacitor element 7.

さらに、このコンデンサ素子を、実装部品とするために外部電極引出し用の陽極リードフレーム8に陽極導出線2を溶接し、陰極リードフレーム9と陰極銀層6とを導電性接着剤10で接続する。
その後、一般的には成形金型を用いて、上記コンデンサ素子にエポキシ系の外装樹脂11をトランスファーモールドする(例えば、特許文献1参照)。
特開2001−126959号公報
Further, in order to use this capacitor element as a mounting component, the anode lead wire 2 is welded to the anode lead frame 8 for leading out the external electrode, and the cathode lead frame 9 and the cathode silver layer 6 are connected by the conductive adhesive 10. .
Thereafter, generally, an epoxy-type exterior resin 11 is transfer-molded to the capacitor element using a molding die (see, for example, Patent Document 1).
JP 2001-126959 A

しかしながら、上記特許文献1の方法で製造された固体電解コンデンサは、電極を導出するためのリードフレームの外装樹脂内に占める体積が大きくなり、結果として、外装樹脂内のコンデンサ素子の体積を制限するため、体積効率の低いコンデンサとなる問題がある。   However, the solid electrolytic capacitor manufactured by the method of Patent Document 1 has a large volume in the exterior resin of the lead frame for leading the electrode, and as a result, the volume of the capacitor element in the exterior resin is limited. Therefore, there is a problem that the capacitor is low in volume efficiency.

本発明は、上記課題を解決するもので、
弁作用金属からなる陽極体表面に、酸化皮膜層、固体電解質層、陰極引出層を順次積層したコンデンサ素子を、その一端面に植立された陽極導出線と陽極リードフレームとを抵抗溶接で接続し、陰極引出層と陰極リードフレームとを導電性接着剤で接着後、外装樹脂にて被覆する固体電解コンデンサにおいて、
上記陰極リードフレームの厚さが、少なくともコンデンサ素子と対向する部分の厚さを、外装樹脂で被覆されていない部分より薄くしたことを特徴とするチップ型固体電解コンデンサである。
The present invention solves the above problems,
Capacitor element in which oxide film layer, solid electrolyte layer and cathode lead layer are sequentially laminated on the anode body surface made of valve action metal, and the anode lead wire and anode lead frame planted on one end face are connected by resistance welding In the solid electrolytic capacitor in which the cathode lead layer and the cathode lead frame are bonded with a conductive adhesive and then covered with an exterior resin,
The chip-type solid electrolytic capacitor is characterized in that the cathode lead frame has a thickness at least a portion facing the capacitor element thinner than a portion not covered with the exterior resin.

本発明によると、少なくともコンデンサ素子と対向する部分の陰極リードフレームを薄くすることで、外装樹脂内で確保できるコンデンサ素子の空間が増加するため、コンデンサ素子の体積拡大が可能になる。   According to the present invention, since the space of the capacitor element that can be secured in the exterior resin is increased by thinning the cathode lead frame at least in the portion facing the capacitor element, the volume of the capacitor element can be increased.

さらに、コンデンサ素子と対向する部分の陰極リードフレームを薄くすることで、コンデンサ素子の形状に合わせて曲げ加工する際、その曲げ角度をより90°近くにすることが可能で、また、曲げ半径をより小さくできることから、外装樹脂の外部寄りの、より陰極リードフレームに近い位置までコンデンサ素子の体積を大きくすることができる。   Furthermore, by thinning the cathode lead frame at the portion facing the capacitor element, the bending angle can be made closer to 90 ° when bending according to the shape of the capacitor element, and the bending radius can be reduced. Since it can be made smaller, the volume of the capacitor element can be increased to a position closer to the cathode lead frame and closer to the outside of the exterior resin.

通常、リードフレームの厚さを薄くすると、トランスファーモールドする際に、厚さを薄くした部分とモールド金型の隙間により外装樹脂を封止できなくなるため、リードフレームの厚さに合わせた金型を新規に作製する必要があり、コストアップにつながってしまうが、本発明によると、リードフレームを薄くする部分は、外装樹脂内部に位置する部分のみであるため、金型を新規に作製することなく、既存のモールド金型で製造可能となり、コストアップすることなく、コンデンサ素子の体積拡大が可能になる。
また、外部電極を形成する部分が薄くなると電極の強度が弱くなるが、本発明により、リードフレームの外部電極を形成する部分の厚さは変わらないため、リードフレームの外部電極となる部分の機械的強度が低下することもない。
Normally, if the thickness of the lead frame is reduced, when performing transfer molding, the exterior resin cannot be sealed due to the gap between the reduced thickness portion and the mold die, so a die that matches the thickness of the lead frame must be used. However, according to the present invention, the thinned portion of the lead frame is only the portion located inside the exterior resin, so that no new mold is produced. It is possible to manufacture with an existing mold, and it is possible to expand the volume of the capacitor element without increasing the cost.
Further, when the portion where the external electrode is formed becomes thin, the strength of the electrode becomes weak. However, according to the present invention, the thickness of the portion where the external electrode of the lead frame is formed does not change. The mechanical strength is not reduced.

[実施例1]
本発明の実施例を、図1を参照しながら説明する。
弁作用金属粉末であるタンタル粉末に陽極導出線2を埋設させて、所望の形状に加圧成形し、その圧縮成形体を焼結して焼結体1を形成した。その後、表面を陽極酸化により誘電体となる酸化皮膜層3を形成させ、固体電解質層4、カーボン層5、陰極銀層6の陰極引出層を順次積層し、コンデンサ素子7を作製した。
[Example 1]
An embodiment of the present invention will be described with reference to FIG.
The anode lead wire 2 was embedded in a tantalum powder that is a valve action metal powder, pressure-formed into a desired shape, and the compression-molded body was sintered to form a sintered body 1. Thereafter, an oxide film layer 3 serving as a dielectric was formed by anodic oxidation on the surface, and a solid electrolyte layer 4, a carbon layer 5, and a cathode lead layer of a cathode silver layer 6 were sequentially laminated to produce a capacitor element 7.

このコンデンサ素子を、厚さが0.10mmである外部電極引出し用の陽極リードフレーム8と陽極導出線2とを抵抗溶接により接合し、外装樹脂内部に位置する部分の厚さt1が0.07mm、外部リードフレーム厚さt2が0.10mmである陰極リードフレーム9と陰極銀層6とを導電性接着剤10で接続した。
その後、既存の成形金型を用いてエポキシ系の外装樹脂11をトランスファーモールドにより形成した。
This capacitor element is joined to the anode lead frame 8 for leading out the external electrode having a thickness of 0.10 mm and the anode lead wire 2 by resistance welding, and the thickness t1 of the portion located inside the exterior resin is 0.07 mm. The cathode lead frame 9 having the external lead frame thickness t2 of 0.10 mm and the cathode silver layer 6 were connected by the conductive adhesive 10.
Then, the epoxy-type exterior resin 11 was formed by transfer molding using the existing molding die.

[実施例2]
外装樹脂内部に位置する部分の厚さt1が0.05mm、外部リードフレーム厚さt2が0.10mmである外部電極引出し用の陰極リードフレーム8を用いた以外は、実施例1と同様の方法で固体電解コンデンサを作製した。
[Example 2]
A method similar to that of Example 1 except that the cathode lead frame 8 for leading out the external electrode in which the thickness t1 of the portion located inside the exterior resin is 0.05 mm and the external lead frame thickness t2 is 0.10 mm is used. A solid electrolytic capacitor was produced.

(従来例)
図2に示すように、全ての厚さが0.10mmである従来のリードフレームを用いた以外は、実施例1と同様の方法で固体電解コンデンサを作製した。
(Conventional example)
As shown in FIG. 2, a solid electrolytic capacitor was produced in the same manner as in Example 1 except that a conventional lead frame having a total thickness of 0.10 mm was used.

次に、本発明の実施例と従来例について、外装樹脂内のコンデンサ素子の体積を測定した。その測定結果を表1に示す。なお、実施例と従来例の陰極リードフレームとコンデンサ素子との最短距離は、同じとなるようにした。   Next, the volume of the capacitor element in the exterior resin was measured for the examples of the present invention and the conventional example. The measurement results are shown in Table 1. The shortest distance between the cathode lead frame of the example and the conventional example and the capacitor element was made the same.

Figure 2007324243
Figure 2007324243

表1より明らかなように、本発明による実施例1、2とも、従来例と比較し、コンデンサ素子の体積を大きくすることができ、体積比率を向上させることができた。
これは、外装樹脂内の陰極側リードフレームを薄くしたことにより、外装樹脂内のコンデンサ素子を収納する空間を確保できたためである。
また、リードフレーム厚さを薄くしたことで、コンデンサ素子の形状に合わせた曲げ加工が容易になったことから、曲げ角度を90°近くにでき、さらに、曲げ半径をより小さくできるので、外装樹脂外部近くの、より陰極フレームに近い位置までコンデンサ素子を拡大することができる。
As is clear from Table 1, in both Examples 1 and 2 according to the present invention, the volume of the capacitor element can be increased and the volume ratio can be improved as compared with the conventional example.
This is because a space for housing the capacitor element in the exterior resin can be secured by thinning the cathode side lead frame in the exterior resin.
In addition, since the lead frame thickness has been reduced, it has become easy to perform bending processing in accordance with the shape of the capacitor element, so that the bending angle can be close to 90 ° and the bending radius can be further reduced. The capacitor element can be expanded to a position near the outside and closer to the cathode frame.

なお、本発明の陰極リードフレームの厚さを外装樹脂内部0.05mmまたは0.07mm、外装樹脂外部0.10mmとしたが、厚さはこれに限るものではない。
また、陰極リードフレームの曲げ形状は、今回用いたものに限るものではない。
The thickness of the cathode lead frame of the present invention is 0.05 mm or 0.07 mm inside the exterior resin and 0.10 mm outside the exterior resin, but the thickness is not limited to this.
Further, the bent shape of the cathode lead frame is not limited to that used this time.

本発明の実施例の固体電解コンデンサの断面図である。It is sectional drawing of the solid electrolytic capacitor of the Example of this invention. 従来例の固体電解コンデンサの断面図である。It is sectional drawing of the solid electrolytic capacitor of a prior art example.

符号の説明Explanation of symbols

1 焼結体
2 陽極導出線
3 酸化皮膜層
4 固体電解質層
5 カーボン層
6 陰極銀層
7 コンデンサ素子
8 陽極リードフレーム
9 陰極リードフレーム
10 導電性接着剤
11 外装樹脂
t1 外装樹脂内部の陰極リードフレーム厚さ
t2 外部電極部分の陰極リードフレーム厚さ
DESCRIPTION OF SYMBOLS 1 Sintered body 2 Anode lead-out line 3 Oxide film layer 4 Solid electrolyte layer 5 Carbon layer 6 Cathode silver layer 7 Capacitor element 8 Anode lead frame 9 Cathode lead frame 10 Conductive adhesive 11 Exterior resin t1 Cathode lead frame inside exterior resin Thickness t2 Cathode lead frame thickness of external electrode part

Claims (1)

弁作用金属からなる陽極体表面に、酸化皮膜層、固体電解質層、陰極引出層を順次形成したコンデンサ素子の一端面に植立された陽極リード線と陽極リードフレームとを抵抗溶接で接続し、陰極引出層と陰極リードフレームとを導電性接着剤で接続後、外装樹脂にて被覆する固体電解コンデンサにおいて、
上記陰極リードフレームの厚さが、少なくともコンデンサ素子と対向する部分の厚さを、外装樹脂で被覆されていない部分より薄くしたことを特徴とするチップ型固体電解コンデンサ。
An anode lead wire and an anode lead frame planted on one end face of a capacitor element in which an oxide film layer, a solid electrolyte layer, and a cathode lead layer are sequentially formed on the anode body surface made of a valve metal are connected by resistance welding. In a solid electrolytic capacitor in which a cathode lead layer and a cathode lead frame are connected with a conductive adhesive and then covered with an exterior resin.
A chip-type solid electrolytic capacitor characterized in that the cathode lead frame has a thickness that is at least a portion facing the capacitor element thinner than a portion not covered with an exterior resin.
JP2006150583A 2006-05-30 2006-05-30 Solid electrolytic capacitor Pending JP2007324243A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2019067923A (en) * 2017-09-29 2019-04-25 パナソニックIpマネジメント株式会社 Solid electrolytic capacitor and method for manufacturing the same

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5386552A (en) * 1977-01-10 1978-07-31 Citizen Watch Co Ltd Piezoelectric oscillator
JPH0247028A (en) * 1988-08-09 1990-02-16 Sekisui Chem Co Ltd Manufacture of composite tube

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5386552A (en) * 1977-01-10 1978-07-31 Citizen Watch Co Ltd Piezoelectric oscillator
JPH0247028A (en) * 1988-08-09 1990-02-16 Sekisui Chem Co Ltd Manufacture of composite tube

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2019067923A (en) * 2017-09-29 2019-04-25 パナソニックIpマネジメント株式会社 Solid electrolytic capacitor and method for manufacturing the same
JP7012260B2 (en) 2017-09-29 2022-01-28 パナソニックIpマネジメント株式会社 Solid electrolytic capacitors and their manufacturing methods

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