JP2007316377A - Optical film with adhesive - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To provide an optical film highly anti-static and having a high durability adhesive layer on its surface. <P>SOLUTION: This is an optical film having an adhesive layer at least on its one surface. This adhesive layer contains (A) acrylic resin containing structural units derived from (meta-)acrylic ester as shown in expression 1 (I) as a main component, structural units derived from unsaturated carboxylic acid, and a first acrylic resin having an average molecular weight of 800,000-2,000,000, wherein the content of the structural unit derived from unsaturated carboxylic acid is 0.5-10 pts.wt. to the whole resin of 100 pts.wt., (B) an ion compound containing cation of expression 1 (II), and (C) a composition containing a cross-linking agent. In expression 1 (I), R<SB>1</SB>represents hydrogen or methyl, and R<SB>2</SB>represents alkyl or aralkyl group of C<SB>1-14</SB>. In expression 1 (II), R<SB>3</SB>represents alkyl of C<SB>1-12</SB>, and R<SB>4</SB>, R<SB>5</SB>R<SB>6</SB>represents alkyl of C<SB>6-12</SB>. <P>COPYRIGHT: (C)2008,JPO&INPIT

Description

  The present invention relates to an optical film with an adhesive. As an optical film made into object by this invention, a polarizing film and retardation film can be mentioned, for example. The present invention also relates to an optical laminate for liquid crystal display using the optical film with an adhesive.

  A polarizing film is mounted on a liquid crystal display device and is widely used. A transparent protective film is laminated on both sides of a polarizer, and an adhesive layer is formed on the surface of at least one protective film. It is distributed in the state where the release film is stuck to. Moreover, a retardation film is laminated | stacked on the polarizing film of the state in which the protective film was bonded on both surfaces of the polarizer, and it is set as an elliptically polarizing film, and an adhesive layer / peeling film may be stuck on the retardation film side. is there. Furthermore, an adhesive layer / release film may be stuck on the surface of the retardation film. Prior to bonding to the liquid crystal cell, the release film is peeled off from these polarizing film, elliptical polarizing film, retardation film, etc., and bonded to the liquid crystal cell via the exposed adhesive layer. Such a polarizing film, an elliptically polarizing film, or a retardation film generates static electricity when the release film is peeled off and bonded to a liquid crystal cell.

  As one of the countermeasures, in Japanese Patent No. 3012860 (Patent Document 1), in a polarizing film in which a protective film is laminated on the surface of a polarizer film and an adhesive layer is provided on the surface of the protective film, It has been proposed to use an ion conductive composition composed of an electrolyte salt and an organopolysiloxane and a composition containing an acrylic copolymer. By using such a pressure-sensitive adhesive, antistatic properties are exhibited, but the performance is not necessarily sufficient, and the adhesion durability is not sufficient.

  On the other hand, JP 2004-536940 A (Patent Document 2) discloses that an organic salt-based antistatic agent is blended with a pressure-sensitive adhesive (adhesive) to impart antistatic properties to the adhesive. It is disclosed. Furthermore, JP 2004-114665 A (Patent Document 3) discloses that an adhesive or the like contains a salt composed of a quaternary ammonium cation having 4 to 20 carbon atoms in total and a fluorine atom-containing anion. Is described.

  Now, the optical film with an adhesive as described above is bonded to a liquid crystal cell on the adhesive layer side to form a liquid crystal display device. In this state, the optical film is placed under high temperature or high temperature and high humidity conditions, or heated. When cooling is repeated, foaming occurs in the pressure-sensitive adhesive layer with the dimensional change of the optical film, or floats or peels between the optical film and the pressure-sensitive adhesive layer, or between the pressure-sensitive adhesive layer and the liquid crystal cell glass. Therefore, it is also required to have excellent durability without causing such problems. In addition, when exposed to high temperatures, the distribution of residual stress acting on the optical film becomes non-uniform and stress concentration occurs on the outer periphery of the optical film, resulting in a phenomenon called whitening that causes the outer periphery to become whitish when displaying black. In some cases, color unevenness may occur, and suppression of such white spots and color unevenness is also required. Furthermore, when there is a deficiency when the optical film with the pressure-sensitive adhesive is bonded to the liquid crystal cell, the optical film is peeled off once and then re-attached. So-called reworkability is also required that is peeled off along with the optical film, does not leave an adhesive on the cell glass, and does not cause fogging or the like.

Japanese Patent No. 3012860 (= Japanese Patent Laid-Open No. 6-313807) Japanese translation of PCT publication No. 2004-536940 (= WO 2003/011958) JP 2004-114665 A

  The subject of this invention is providing the optical film with an adhesive which provided the adhesive layer which the antistatic property was improved and was excellent also in durability on the surface of the optical film. As a result of intensive studies to solve such problems, the present inventors have formulated a specific ionic compound with respect to a pressure-sensitive adhesive containing a specific acrylic resin, and applied this composition to the surface of the optical film. By providing as an adhesive layer, it discovered that the optical film with an adhesive excellent in antistatic property and durability was obtained, and reached | attained this invention.

  That is, according to the present invention, an adhesive layer is formed on at least one surface of the optical film, and the adhesive layer is formed from a composition containing the following components (A), (B) and (C). An optical film with an adhesive is provided.

（式中、Ｒ₁は水素原子又はメチル基を表し、Ｒ₂は、それぞれ炭素数１〜１０のアルコキシ基で置換されていてもよい炭素数１〜１４のアルキル基又はアラルキル基を表す）
で示される（メタ）アクリル酸エステルに由来する構造単位を主成分とし、さらに、分子内に１個のオレフィン性二重結合と少なくとも１個のカルボキシル基を有する不飽和カルボン酸に由来する構造単位を含み、重量平均分子量が 800,000〜2,000,000 である第一のアクリル樹脂を含有し、前記不飽和カルボン酸に由来する構造単位の含有量が、樹脂全体１００重量部に対して ０.５〜１０重量部であるアクリル樹脂、
（Ｂ）下式（II）

（式中、Ｒ₃は炭素数１〜１２のアルキル基を表し、Ｒ₄、Ｒ₅及びＲ₆はそれぞれ独立に炭素数６〜１２のアルキル基を表す）
で示されるカチオンを含むイオン性化合物、及び
（Ｃ）架橋剤。 (A) The following formula (I)

(In the formula, R ₁ represents a hydrogen atom or a methyl group, and R ₂ represents a C 1-14 alkyl group or an aralkyl group, each of which may be substituted with a C 1-10 alkoxy group)
A structural unit derived from an unsaturated carboxylic acid having a structural unit derived from a (meth) acrylic acid ester represented by formula (1) as a main component and further having one olefinic double bond and at least one carboxyl group in the molecule The first acrylic resin having a weight average molecular weight of 800,000 to 2,000,000 is contained, and the content of structural units derived from the unsaturated carboxylic acid is 0.5 to 10 weights per 100 weight parts of the whole resin Part acrylic resin,
(B) The following formula (II)

(Wherein R ₃ represents an alkyl group having 1 to 12 carbon atoms, and R ₄ , R ₅ and R ₆ each independently represents an alkyl group having 6 to 12 carbon atoms)
And an ionic compound containing a cation represented by (C), and (C) a crosslinking agent.

  Said acrylic resin (A) can also be comprised only with the 1st acrylic resin prescribed | regulated above, and in addition to the 1st acrylic resin, it is different acrylic resin (it is set as 2nd acrylic resin) It can also be composed of a mixture of Examples of the second acrylic resin include those having a structural unit derived from the (meth) acrylic acid ester represented by the formula (I) as a main component and having a weight average molecular weight of 50,000 to 500,000.

  Moreover, according to this invention, the optical laminated body by which this optical film with an adhesive is laminated | stacked on the glass substrate by the adhesive layer side is also provided.

  The optical film with a pressure-sensitive adhesive of the present invention can effectively suppress charging of the optical member. For example, this optical film with an adhesive is laminated on a glass substrate of a liquid crystal cell to give an optical laminate for liquid crystal display. In this optical laminate, the pressure-sensitive adhesive layer absorbs and relaxes stress caused by dimensional changes of the optical film and the glass substrate under wet heat conditions, so that local stress concentration is reduced and the pressure-sensitive adhesive layer floats on the glass substrate. And peeling are suppressed. In addition, since optical defects due to non-uniform stress distribution are prevented, white spots are suppressed. In addition, if there is any inconvenience after laminating the optical film with adhesive once on the glass substrate, even if the optical film is peeled off from the glass substrate together with the adhesive, adhesive residue or Clouding is less likely to occur, and it can be used again as a glass substrate, resulting in excellent reworkability.

  Hereinafter, the present invention will be described in detail. In the present invention, the acrylic resin (A) serving as a resin component constituting the pressure-sensitive adhesive has a structural unit derived from the (meth) acrylic acid ester represented by the formula (I) as a main component, and further includes 1 in the molecule. It contains a first acrylic resin containing structural units derived from an unsaturated carboxylic acid having one olefinic double bond and at least one carboxyl group, and having a weight average molecular weight of 800,000 to 2,000,000. The acrylic resin (A) can be composed only of the first acrylic resin specified here, and includes an acrylic resin different from the first acrylic resin (referred to as a second acrylic resin). It can also be composed of a mixture. The structural unit derived from the unsaturated carboxylic acid is contained in the first acrylic resin at a ratio of 0.5 to 10 parts by weight based on 100 parts by weight of the entire acrylic resin (A). In addition, (meth) acrylic acid means that either acrylic acid or methacrylic acid may be used, and “(meth)” when referred to as (meth) acrylate or the like has the same meaning.

In the formula (I), which is the main structural unit of the first acrylic resin, R ₁ is a hydrogen atom or a methyl group, and R ₂ is an alkyl group or aralkyl group having 1 to 14 carbon atoms, preferably an alkyl group. is there. In the alkyl group or aralkyl group represented by R ₂ , a hydrogen atom in each group may be substituted with an alkoxy group having 1 to 10 carbon atoms.

  Specific examples of the (meth) acrylic acid ester represented by the formula (I) include methyl acrylate, ethyl acrylate, propyl acrylate, n-butyl acrylate, n-octyl acrylate, and lauryl acrylate, Linear alkyl acrylate ester; branched alkyl acrylate ester such as isobutyl acrylate, 2-ethylhexyl acrylate, isooctyl acrylate; methyl methacrylate, ethyl methacrylate, propyl methacrylate, n-butyl methacrylate, Examples thereof include linear alkyl methacrylates such as n-octyl methacrylate and lauryl methacrylate; branched alkyl alkyl esters such as isobutyl methacrylate, 2-ethylhexyl methacrylate and isooctyl methacrylate.

When R ₂ is an alkyl group substituted with an alkoxy group, that is, when R ₂ is an alkoxyalkyl group, the (meth) acrylic acid ester represented by the formula (I) is specifically acrylic acid. Examples include 2-methoxyethyl, ethoxymethyl acrylate, 2-methoxyethyl methacrylate, ethoxymethyl methacrylate, and the like. Specific examples of the (meth) acrylic acid ester represented by the formula (I) when R ₂ is an aralkyl group include benzyl acrylate and benzyl methacrylate.

  In the production of the first acrylic resin, as the (meth) acrylic acid ester represented by the formula (I), one kind of compound may be used, or two or more kinds of compounds may be used. Among them, it is preferable to use butyl acrylate as at least one monomer. Therefore, it is a preferable embodiment that the structural unit derived from the (meth) acrylic acid ester constituting the first acrylic resin contains a unit derived from butyl acrylate.

  The unsaturated carboxylic acid, which is another structural unit of the first acrylic resin, is a compound having one olefinic double bond and at least one carboxyl group in the molecule. Examples include acid, methacrylic acid, maleic acid, and itaconic acid. Among these, acrylic acid or methacrylic acid is preferable.

  The first acrylic resin may contain a structural unit derived from a monomer having a polar functional group other than a carboxyl group. Examples of the polar functional group other than the carboxyl group include a hydroxyl group, an amide group, an epoxy group, an oxetanyl group, an amino group, an isocyanato group, and an aldehyde group.

  Examples of the monomer whose polar functional group is a hydroxyl group include 2-hydroxyethyl (meth) acrylate, 2-hydroxypropyl (meth) acrylate, 4-hydroxybutyl (meth) acrylate, and the like. Examples of the monomer whose polar functional group is an amide group include acrylamide, methacrylamide, N, N-dimethylaminopropylacrylamide, N, N-dimethylacrylamide, N, N-diethylacrylamide, and N-methylolacrylamide. Can be mentioned. Examples of the monomer whose polar functional group is an epoxy group include glycidyl acrylate, glycidyl methacrylate, 3,4-epoxycyclohexylmethyl acrylate, 3,4-epoxycyclohexylmethyl methacrylate, and the like. Examples of the monomer whose polar functional group is an oxetanyl group include, for example, oxetanyl (meth) acrylate, 3-oxetanylmethyl (meth) acrylate, (3-methyl-3-oxetanyl) methyl (meth) acrylate, (3-ethyl- 3-oxetanyl) methyl (meth) acrylate and the like. Examples of the monomer whose polar functional group is an amino group include N, N-dimethylaminoethyl acrylate and allylamine. Examples of the monomer whose polar functional group is an isocyanato group include 2-methacryloyloxyethyl isocyanate. Examples of the monomer whose polar functional group is an aldehyde group include acrylic aldehyde.

  In the first acrylic resin, the structural unit derived from the (meth) acrylic acid ester represented by the formula (I) is usually 60 to 99.5% by weight, preferably 80, based on the weight of the entire nonvolatile content. It is contained in 99.5% by weight. The structural unit derived from the unsaturated carboxylic acid is usually contained in an amount of about 0.5 to 10% by weight, preferably 1 to 6% by weight. The structural unit derived from the unsaturated carboxylic acid is based on 100 parts by weight of the entire acrylic resin (A), that is, 100 parts by weight when the acrylic resin (A) is composed of only the first acrylic resin. Moreover, when comprised with a 1st acrylic resin and a 2nd acrylic resin different from it, it is made to contain in the ratio of 0.5-10 weight part with respect to those total 100 weight part. The ratio of the structural unit derived from unsaturated carboxylic acid to 100 parts by weight of the entire acrylic resin (A) is preferably 0.5 to 6 parts by weight. When the amount of the structural unit derived from the unsaturated carboxylic acid is 0.5% by weight or more with respect to 100 parts by weight of the acrylic resin (A), when the pressure-sensitive adhesive layer containing the structural unit is bonded to a glass substrate, glass This is preferable because floating and peeling between the substrate and the pressure-sensitive adhesive layer tend to be suppressed. Further, if the amount is 10 parts by weight or less, even if the dimension of the optical film changes due to a temperature change or the like, the adhesive layer fluctuates following the change in dimension, so This is preferable because there is no difference between the brightness of the central portion and white spots and color unevenness tend to be suppressed. Furthermore, if the amount of the structural unit derived from the unsaturated carboxylic acid is in the range of 0.5 to 10 parts by weight with respect to 100 parts by weight of the acrylic resin (A), the phase with the ionic compound (B) described later It is also preferable from the viewpoint of solubility.

  The first acrylic resin may contain a structural unit derived from a monomer other than the (meth) acrylic acid ester represented by the formula (I) and the unsaturated carboxylic acid described above. Examples of such a monomer that can be optionally used include a heterocyclic monomer having one olefinic double bond and at least one heterocyclic group having at least one 5-membered ring in the molecule. be able to. Here, the 5- or more-membered heterocyclic group is an alicyclic hydrocarbon group having 5 or more carbon atoms, preferably 5 to 7 carbon atoms, in which at least one methylene group is a nitrogen atom, an oxygen atom, A group substituted with a heteroatom such as a sulfur atom.

  Specific examples of the heterocyclic monomer include acryloylmorpholine, vinylcaprolactam, N-vinyl-2-pyrrolidone, tetrahydrofurfuryl acrylate, tetrahydrofurfuryl methacrylate, caprolactone-modified tetrahydrofurfuryl acrylate, and the like. . In addition, monomers such as 3,4-epoxycyclohexylmethyl acrylate, 3,4-epoxycyclohexylmethyl methacrylate and the like in which a hetero atom constitutes a 3-membered ring and a 7-membered ring are 7-membered heterocyclic groups. Therefore, it can be treated as a heterocyclic monomer. Furthermore, an olefinic double bond may be contained in the heterocyclic group such as 2,5-dihydrofuran. Two or more different monomers may be used as the heterocyclic monomer. Among the heterocyclic monomers, N-vinylpyrrolidone, vinylcaprolactam, acryloylmorpholine, or a mixture thereof is particularly preferable.

  When the first acrylic resin contains a structural unit derived from a heterocyclic monomer, the amount is usually up to about 30% by weight, preferably 20% by weight or less, based on the first acrylic resin. is there. When the structural unit derived from the heterocyclic monomer is contained in the first acrylic resin in an amount of 0.1% by weight or more, the pressure-sensitive adhesive layer follows the dimensional change even if the optical film size changes. Therefore, there is no difference between the brightness at the peripheral edge of the liquid crystal cell and the brightness at the center, and there is a tendency for white spots and color unevenness to be suppressed.

  Moreover, as another monomer which can be used arbitrarily, the alicyclic monomer which has one olefinic double bond and at least 1 alicyclic structure in a molecule | numerator can be mentioned. The alicyclic structure is usually a cycloparaffin structure or a cycloolefin structure having 5 or more carbon atoms, preferably about 5 to 7 carbon atoms, and the cycloolefin structure has an olefinic double bond in the alicyclic structure. . Specifically, as an acrylate ester having an alicyclic structure, isobornyl acrylate, cyclohexyl acrylate, dicyclopentanyl acrylate, cyclododecyl acrylate, methyl cyclohexyl acrylate, trimethyl cyclohexyl acrylate, tert-acrylate acrylate Examples include butylcyclohexyl, α-ethoxyacrylate cyclohexyl, cyclohexylphenyl acrylate, etc., and methacrylic acid ester having an alicyclic structure, such as isobornyl methacrylate, cyclohexyl methacrylate, dicyclopentanyl methacrylate, cyclododecyl methacrylate, Examples include methyl cyclohexyl methacrylate, trimethyl cyclohexyl methacrylate, tert-butyl cyclohexyl methacrylate, cyclohexyl phenyl methacrylate, etc. It is done. Examples of the acrylate having a plurality of alicyclic structures in the molecule include biscyclohexylmethyl itaconate, dicyclooctyl itaconate, and dicyclododecylmethyl succinate. Furthermore, vinyl cyclohexyl acetate having a vinyl group can also be an alicyclic monomer. Among them, isobornyl acrylate, cyclohexyl acrylate, isobornyl methacrylate, cyclohexyl methacrylate, and dicyclopentanyl acrylate are preferable because they are easily available. As the alicyclic monomer, two or more different compounds may be used in combination.

  When the first acrylic resin contains a structural unit derived from an alicyclic monomer, the amount is usually up to about 30% by weight, preferably 15% by weight or less, based on the first acrylic resin. is there. In addition, when the structural unit derived from the alicyclic monomer is contained in the first acrylic resin in an amount of 0.1% by weight or more, and further 1% by weight or more, the floating or peeling between the glass substrate and the pressure-sensitive adhesive layer. Tend to be suppressed.

  As another monomer, a vinyl monomer different from any of the (meth) acrylic acid ester represented by the formula (I), the heterocyclic monomer, and the alicyclic monomer may be used. Examples of such vinyl monomers include fatty acid vinyl esters, vinyl halides, vinylidene halides, (meth) acrylonitrile, conjugated diene compounds, and aromatic vinyls.

  Here, examples of the fatty acid vinyl ester include vinyl acetate, vinyl propionate, vinyl butyrate, vinyl 2-ethylhexanoate, vinyl laurate, and the like. Examples of the vinyl halide include vinyl chloride and vinyl bromide, examples of the vinylidene halide include vinylidene chloride, and examples of the (meth) acrylonitrile include acrylonitrile and methacrylonitrile. The conjugated diene compound is an olefin having a conjugated double bond in the molecule, and specific examples include isoprene, butadiene and chloroprene. Aromatic vinyl is a compound having an aromatic ring and a vinyl group. Specific examples include styrene, methylstyrene, dimethylstyrene, trimethylstyrene, ethylstyrene, diethylstyrene, triethylstyrene, propylstyrene, butylstyrene, hexyl. Styrene monomers such as styrene, heptylstyrene, octylstyrene, fluorostyrene, chlorostyrene, bromostyrene, dibromostyrene, iodostyrene, nitrostyrene, acetylstyrene, methoxystyrene, and nitrogen-containing aromatics such as vinylpyridine and vinylcarbazole Vinyl etc. are mentioned. These vinyl monomers may be used in combination of two or more different compounds.

  When the first acrylic resin contains a structural unit derived from the vinyl monomer as described above, the amount is usually 5% by weight or less, preferably 0.05% by weight based on the first acrylic resin. However, it is more preferable that these are not substantially contained.

  Even when a plurality of structural units derived from a heterocyclic monomer, structural units derived from an alicyclic monomer, and structural units derived from a vinyl monomer are introduced, their total amount Is preferably 30% by weight or less, more preferably 20% by weight or less, based on the first acrylic resin.

  Examples of the method for producing the first acrylic resin described above include a solution polymerization method, an emulsion polymerization method, a bulk polymerization method, a suspension polymerization method, and the like. Among these, the solution polymerization method is preferable. As a specific example of the solution polymerization method, a desired monomer and an organic solvent are mixed to adjust the concentration of the monomer to 50% by weight or more, preferably 50 to 60% by weight, and then nitrogen. Under an atmosphere, about 0.001 to 5 parts by weight of a polymerization initiator is added per 100 parts by weight of the monomer, and is about 40 to 90 ° C., preferably about 50 to 70 ° C., preferably 8 hours or more, preferably Examples include a method of stirring for about 8 to 12 hours.

  As the polymerization initiator, a thermal polymerization initiator, a photopolymerization initiator, or the like is used. Examples of the photopolymerization initiator include 4- (2-hydroxyethoxy) phenyl (2-hydroxy-2-propyl) ketone. Examples of the thermal polymerization initiator include 2,2′-azobisisobutyronitrile, 2,2′-azobis (2-methylbutyronitrile), 1,1′-azobis (cyclohexane-1-carbonitrile). 2,2'-azobis (2,4-dimethylvaleronitrile), 2,2'-azobis (2,4-dimethyl-4-methoxyvaleronitrile), dimethyl-2,2'-azobis (2-methylpro) Pionate), azo compounds such as 2,2'-azobis (2-hydroxymethylpropionitrile); lauryl peroxide, tert-butyl hydroperoxide, benzoyl peroxide, tert-butyl peroxybenzoate, cumene hydroper Oxide, diisopropyl peroxydicarbonate, di-n-propyl peroxydicarbonate, tert-butyl -Organic peroxides such as oxyneodecanoate, tert-butyl peroxypivalate, (3,5,5-trimethylhexanoyl) peroxide; inorganic peroxides such as potassium persulfate, ammonium persulfate, hydrogen peroxide Etc. A redox initiator using a peroxide and a reducing agent in combination can also be used as the polymerization initiator.

  Examples of the organic solvent used in the polymerization reaction include aromatic hydrocarbons such as toluene and xylene; esters such as ethyl acetate and butyl acetate; aliphatic alcohols such as n-propyl alcohol and isopropyl alcohol; acetone, methyl ethyl ketone, And ketones such as methyl isobutyl ketone.

  The molecular weight of the first acrylic resin is in the range of 800,000 to 2,000,000 in terms of weight average molecular weight (Mw) in terms of standard polystyrene by gel permeation chromatography (GPC). When the weight average molecular weight is 800,000 or more, the adhesiveness under high temperature and high humidity is improved, and there is a tendency that the possibility of floating or peeling between the glass substrate and the pressure-sensitive adhesive layer tends to be reduced. It is preferable because the property tends to be improved. Also, if the weight average molecular weight is 2,000,000 or less, even if the dimensions of the optical film bonded to the pressure-sensitive adhesive layer change due to a temperature change, the pressure-sensitive adhesive layer fluctuates following the dimensional change. The difference between the brightness of the peripheral edge of the liquid crystal cell and the brightness of the central portion is eliminated, and this is preferable because white spots and color unevenness tend to be suppressed. The molecular weight distribution represented by the ratio (Mw / Mn) of the weight average molecular weight (Mw) to the number average molecular weight (Mn) is usually in the range of about 2 to 10.

  The pressure-sensitive adhesive used in the present invention may contain a second acrylic resin different from the first acrylic resin as the acrylic resin (A). Examples of the second acrylic resin that can be separately contained include, for example, a structural unit derived from the (meth) acrylic acid ester represented by the formula (I) as a main component, and a weight average molecular weight (Mw) in terms of standard polystyrene by GPC. May have a low molecular weight in the range of about 50,000 to 500,000.

  When the second acrylic resin having a low molecular weight is used, the amount is usually about 10 to 50 parts by weight, preferably about 20 to 40 parts by weight with respect to 100 parts by weight of the total nonvolatile content of the acrylic resin (A). If the amount of the second acrylic resin relative to 100 parts by weight of the total acrylic resin is 10 parts by weight or more, even if the dimension of the optical film changes, the adhesive layer follows the dimensional change and fluctuates. This is preferable because there is no difference between the brightness of the peripheral edge of the liquid crystal cell and the brightness of the central portion, and white spots and color unevenness tend to be suppressed, and the amount of the second acrylic resin is 50 parts by weight or less. Because the adhesiveness at high temperature and high humidity is improved, the possibility of floating or peeling between the glass substrate and the adhesive layer tends to be low, and the reworkability tends to be improved. preferable.

  The acrylic resin (A) used for the adhesive is only the acrylic resin (if only the first acrylic resin is used, the acrylic resin, or if the first acrylic resin and the second acrylic resin are used in combination, these It is preferable that a solution prepared by dissolving a mixture of the above compound in ethyl acetate to have a non-volatile content of 20% by weight exhibits a viscosity of 10 Pa · s or less, more preferably 0.1 to 7 Pa · s at a temperature of 25 ° C. When the viscosity is 10 Pa · s or less, the adhesiveness under high temperature and high humidity is improved, and there is a tendency that the possibility of floating or peeling between the glass substrate and the adhesive layer tends to be reduced. It is preferable because the property tends to be improved. Viscosity can be measured with a Brookfield viscometer.

In the present invention, an ionic compound (B) is used in addition to the acrylic resin (A) as described above. This ionic compound (B) contains a cation represented by the above formula (II). In this formula (II), R ₃ represents an alkyl group having 1 to 12 carbon atoms, and R ₄ , R ₅ And R ₆ each independently represents an alkyl group having 6 to 12 carbon atoms. Therefore, the cation represented by the formula (II) is a tetraalkylammonium cation. This ionic compound (B) is advantageously liquid at room temperature (around 23 ° C.). The tetraalkylammonium cation represented by the formula (II) preferably has a total carbon number of 15 or more, more preferably 20 or more, and especially 22 or more from the viewpoint of compatibility with the acrylic resin (A). Further, the total number of carbon atoms is preferably 36 or less, more preferably 30 or less.

  Specific examples of the tetraalkylammonium cation represented by the formula (II) include the following.

Tetrahexyl ammonium cation,
Tetraoctyl ammonium cation,
Trihexylmethylammonium cation,
Trioctylmethylammonium cation,
Tridecylmethylammonium cation,
Trihexylethylammonium cation,
Trioctylethylammonium cation, etc.

  On the other hand, it is preferable that the anionic component constituting the ionic compound (B) satisfies the fact that it becomes an ionic liquid, and the others are not particularly limited, but examples thereof include the following. it can.

Chloride anion [Cl ⁻ ],
Bromide anion [Br ⁻ ],
Iodide anion [I ⁻ ],
Tetrachloroaluminate anion [AlCl ₄ ⁻ ],
Heptachlorodialuminate anion [Al ₂ Cl ₇ ⁻ ],
Tetrafluoroborate anion [BF ₄ ⁻ ],
Hexafluorophosphate anion [PF ₆ ⁻ ],
Perchlorate anion [ClO ₄ ⁻ ],
Nitrate anion [NO ₃ ⁻ ],
Acetate anion [CH ₃ COO ⁻ ],
Trifluoroacetate anion [CF ₃ COO ⁻ ],
Methanesulfonate anion [CH ₃ SO ₃ ⁻ ],
Trifluoromethanesulfonate anion [CF ₃ SO ₃ ⁻ ],
Bis (trifluoromethanesulfonyl) imide anion [(CF ₃ SO ₂ ) ₂ N ⁻ ],
Tris (trifluoromethanesulfonyl) methanide anion [(CF ₃ SO ₂ ) ₃ C ⁻ ],
Hexafluoroarsenate anion [AsF ₆ ⁻ ],
Hexafluoroantimonate anion [SbF ₆ ⁻ ],
Hexafluoroniobate anion [NbF ₆ ⁻ ],
Hexafluorotantalate anion [TaF ₆ ⁻ ],
(Poly) hydrofluorofluoride anion [F (HF) _n ⁻ ] (n is about 1 to 3),
Dicyanamide anion [(CN) ₂ N ⁻ ],
Perfluorobutanesulfonate anion [C ₄ F ₉ SO ₃ ⁻ ],
Bis (pentafluoroethanesulfonyl) imide anion [(C ₂ F ₅ SO ₂ ) ₂ N ⁻ ],
Perfluorobutanoate anion [C ₃ F ₇ COO ⁻ ],
(Trifluoromethanesulfonyl) (trifluoromethanecarbonyl) imide anion [(CF ₃ SO ₂ ) (CF ₃ CO) N ⁻ ] and the like.

  Among these, an anion component containing a fluorine atom is particularly preferably used since an ionic compound having a low melting point is obtained, and a bis (trifluoromethanesulfonyl) imide anion is particularly preferable.

  Specific examples of the ionic compound used in the present invention can be appropriately selected from the combination of the cation component and the anion component. Specific examples of the compound that is a combination of a cation component and an anion component include the following.

Tetrahexylammonium bis (trifluoromethanesulfonyl) imide,
Trihexylmethylammonium bis (trifluoromethanesulfonyl) imide,
Trioctylmethylammonium bis (trifluoromethanesulfonyl) imide,
Tetrahexylammonium hexafluorophosphate,
Trihexylmethylammonium hexafluorophosphate,
Trioctylmethylammonium hexafluorophosphate,
Tetrahexylammonium perchlorate,
Trihexylmethylammonium perchlorate,
Trioctylmethylammonium perchlorate.

  The ionic compound (B) is preferably contained at a ratio of about 0.5 to 10 parts by weight with respect to 100 parts by weight of the nonvolatile content of the acrylic resin (A), and more preferably 1 to 6 parts by weight. It is more preferable to make it contain in the ratio. When the ionic compound (B) is contained in an amount of 0.5 part by weight or more with respect to 100 parts by weight of the non-volatile content of the acrylic resin (A), the antistatic performance is preferably improved. The compound (B) is preferred because it is difficult to bleed out.

  A crosslinking agent (C) is further blended into the acrylic resin (A) and the ionic compound (B) as described above to obtain a pressure-sensitive adhesive composition. The crosslinking agent (C) is a compound having in the molecule at least two functional groups capable of crosslinking with the structural unit derived from the unsaturated carboxylic acid in the acrylic resin (A), particularly in the first acrylic resin. Specifically, an isocyanate compound, an epoxy compound, a metal chelate compound, an aziridine compound and the like are exemplified.

  Isocyanate compounds are compounds having at least two isocyanato groups (-NCO) in the molecule, such as tolylene diisocyanate, hexamethylene diisocyanate, isophorone diisocyanate, xylylene diisocyanate, hydrogenated xylylene diisocyanate, diphenylmethane diisocyanate, Examples thereof include hydrogenated diphenylmethane diisocyanate, naphthalene diisocyanate, and triphenylmethane triisocyanate. In addition, adducts obtained by reacting these isocyanate compounds with polyols such as glycerol and trimethylolpropane, and those obtained by converting isocyanate compounds into dimers, trimers, and the like can also be used as crosslinking agents for pressure-sensitive adhesives. Two or more isocyanate compounds can be mixed and used.

  The epoxy compound is a compound having at least two epoxy groups in the molecule, for example, bisphenol A type epoxy resin, ethylene glycol diglycidyl ether, polyethylene glycol diglycidyl ether, glycerin diglycidyl ether, glycerin triglycidyl ether. 1,6-hexanediol diglycidyl ether, trimethylolpropane triglycidyl ether, N, N-diglycidylaniline, N, N, N ′, N′-tetraglycidyl-m-xylenediamine, 1,3-bis ( N, N'-diglycidylaminomethyl) cyclohexane and the like. Two or more types of epoxy compounds can be mixed and used.

  Examples of the metal chelate compound include compounds in which acetylacetone or ethyl acetoacetate is coordinated to a polyvalent metal such as aluminum, iron, copper, zinc, tin, titanium, nickel, antimony, magnesium, vanadium, chromium, and zirconium. Can be mentioned.

  An aziridine-based compound is a compound having at least two skeletons of a three-membered ring composed of one nitrogen atom and two carbon atoms, also called ethyleneimine, for example, diphenylmethane-4,4′-bis ( 1-aziridinecarboxamide), toluene-2,4-bis (1-aziridinecarboxamide), triethylenemelamine, isophthaloylbis-1- (2-methylaziridine), tris-1-aziridinylphosphine oxide, hexamethylene Examples include -1,6-bis (1-aziridinecarboxamide), trimethylolpropane-tri-β-aziridinylpropionate, tetramethylolmethane-tri-β-aziridinylpropionate, and the like.

  Among these crosslinking agents, isocyanate compounds, particularly xylylene diisocyanate or tolylene diisocyanate, or adducts obtained by reacting polyols such as glycerol and trimethylolpropane with these isocyanate compounds, dimers of isocyanate compounds, A mixture of trimers and the like, a mixture of these isocyanate compounds, and the like are preferably used. Suitable isocyanate compounds include tolylene diisocyanate, adducts obtained by reacting tolylene diisocyanate with a polyol, tolylene diisocyanate dimers, and tolylene diisocyanate trimers.

  A crosslinking agent (C) is normally mix | blended in the ratio of about 0.01-10 weight part with respect to 100 weight part of acrylic resins (A), Preferably about 0.1-7 weight part. The amount of the crosslinking agent (C) relative to 100 parts by weight of the acrylic resin (A) is preferably 0.01 parts by weight or more because the durability of the pressure-sensitive adhesive layer tends to be improved, and is preferably 10 parts by weight or less. And, when the optical film with a pressure-sensitive adhesive is applied to a liquid crystal display device, white spots are not noticeable.

  In order to improve the adhesiveness between the pressure-sensitive adhesive layer and the glass substrate, the pressure-sensitive adhesive for forming the pressure-sensitive adhesive layer in the present invention preferably contains a silane-based compound, especially before the crosslinking agent is blended. It is preferable to contain a silane compound in the acrylic resin.

  Examples of the silane compound include vinyltrimethoxysilane, vinyltriethoxysilane, vinyltris (2-methoxyethoxy) silane, N- (2-aminoethyl) -3-aminopropylmethyldimethoxysilane, and N- (2-aminoethyl). ) -3-Aminopropyltrimethoxysilane, 3-aminopropyltriethoxysilane, 3-glycidoxypropyltrimethoxysilane, 3-glycidoxypropylmethyldimethoxysilane, 2- (3,4-epoxycyclohexyl) ethyltri Methoxysilane, 3-chloropropylmethyldimethoxysilane, 3-chloropropyltrimethoxysilane, 3-methacryloxypropyltrimethoxysilane, 3-mercaptopropyltrimethoxysilane, 3-glycidoxypropyltrimethoxysilane, 3 Glycidoxypropyl triethoxysilane, 3-glycidoxypropyl dimethoxymethyl silane, such as 3-glycidoxypropyl ethoxy dimethyl silane. Two or more silane compounds may be used.

  The silane compound may be of a silicone oligomer type. When the silicone oligomer is shown in the form of (monomer) oligomer, for example, the following can be mentioned.

3-mercaptopropyltrimethoxysilane-tetramethoxysilane copolymer,
3-mercaptopropyltrimethoxysilane-tetraethoxysilane copolymer,
3-mercaptopropyltriethoxysilane-tetramethoxysilane copolymer,
A copolymer containing mercaptopropyl groups, such as a 3-mercaptopropyltriethoxysilane-tetraethoxysilane copolymer;

Mercaptomethyltrimethoxysilane-tetramethoxysilane copolymer,
Mercaptomethyltrimethoxysilane-tetraethoxysilane copolymer,
Mercaptomethyltriethoxysilane-tetramethoxysilane copolymer,
A copolymer containing a mercaptomethyl group, such as a mercaptomethyltriethoxysilane-tetraethoxysilane copolymer;

3-methacryloyloxypropyltrimethoxysilane-tetramethoxysilane copolymer,
3-methacryloyloxypropyltrimethoxysilane-tetraethoxysilane copolymer,
3-methacryloyloxypropyltriethoxysilane-tetramethoxysilane copolymer,
3-methacryloyloxypropyltriethoxysilane-tetraethoxysilane copolymer,
3-methacryloyloxypropylmethyldimethoxysilane-tetramethoxysilane copolymer,
3-methacryloyloxypropylmethyldimethoxysilane-tetraethoxysilane copolymer,
3-methacryloyloxypropylmethyldiethoxysilane-tetramethoxysilane copolymer,
Copolymers containing methacryloyloxypropyl groups, such as 3-methacryloxyyl propylmethyldiethoxysilane-tetraethoxysilane copolymer;

3-acryloyloxypropyltrimethoxysilane-tetramethoxysilane copolymer,
3-acryloyloxypropyltrimethoxysilane-tetraethoxysilane copolymer,
3-acryloyloxypropyltriethoxysilane-tetramethoxysilane copolymer,
3-acryloyloxypropyltriethoxysilane-tetraethoxysilane copolymer,
3-acryloyloxypropylmethyldimethoxysilane-tetramethoxysilane copolymer,
3-acryloyloxypropylmethyldimethoxysilane-tetraethoxysilane copolymer,
3-acryloyloxypropylmethyldiethoxysilane-tetramethoxysilane copolymer,
A copolymer containing acryloyloxypropyl groups, such as 3-acryloyloxypropylmethyldiethoxysilane-tetraethoxysilane copolymer;

Vinyltrimethoxysilane-tetramethoxysilane copolymer,
Vinyltrimethoxysilane-tetraethoxysilane copolymer,
Vinyltriethoxysilane-tetramethoxysilane copolymer,
Vinyltriethoxysilane-tetraethoxysilane copolymer,
Vinylmethyldimethoxysilane-tetramethoxysilane copolymer,
Vinylmethyldimethoxysilane-tetraethoxysilane copolymer,
Vinylmethyldiethoxysilane-tetramethoxysilane copolymer,
A vinyl group-containing copolymer, such as vinylmethyldiethoxysilane-tetraethoxysilane copolymer;

3-aminopropyltrimethoxysilane-tetramethoxysilane copolymer,
3-aminopropyltrimethoxysilane-tetraethoxysilane copolymer,
3-aminopropyltriethoxysilane-tetramethoxysilane copolymer,
3-aminopropyltriethoxysilane-tetraethoxysilane copolymer,
3-aminopropylmethyldimethoxysilane-tetramethoxysilane copolymer,
3-aminopropylmethyldimethoxysilane-tetraethoxysilane copolymer,
3-aminopropylmethyldiethoxysilane-tetramethoxysilane copolymer,
Amino group-containing copolymers such as 3-aminopropylmethyldiethoxysilane-tetraethoxysilane copolymer.

  These silane-based compounds are often liquids. The compounding amount of the silane compound in the pressure-sensitive adhesive is usually about 0.0001 to 10 parts by weight with respect to 100 parts by weight of the nonvolatile content of the acrylic resin (A) (the total weight when two or more types are used), preferably Is used in a proportion of 0.01 to 5 parts by weight. It is preferable that the amount of the silane compound with respect to 100 parts by weight of the acrylic resin is 0.0001 part by weight or more because adhesion between the pressure-sensitive adhesive layer and the glass substrate is improved. Moreover, it is preferable for the amount to be 10 parts by weight or less because the silane compound tends to be suppressed from bleeding out from the pressure-sensitive adhesive layer.

  The pressure-sensitive adhesive described above may further contain a crosslinking catalyst, a weather stabilizer, a tackifier, a plasticizer, a softener, a dye, a pigment, an inorganic filler, and the like. Among them, when a crosslinking catalyst is blended with a crosslinking agent in the pressure-sensitive adhesive, the pressure-sensitive adhesive layer can be prepared by aging in a short time, and the resulting optical optical film with pressure-sensitive adhesive floats between the optical film and the pressure-sensitive adhesive layer. Occurrence of peeling or peeling or foaming in the pressure-sensitive adhesive layer can be suppressed, and reworkability can be further improved. Examples of the crosslinking catalyst include amine compounds such as hexamethylenediamine, ethylenediamine, polyethyleneimine, hexamethylenetetramine, diethylenetriamine, triethylenetetramine, isophoronediamine, trimethylenediamine, polyamino resin, and melamine resin. When an amine compound is added to the adhesive as a crosslinking catalyst, an isocyanate compound is suitable as the crosslinking agent.

  The optical film used for the optical film with a pressure-sensitive adhesive of the present invention is a film having optical characteristics, and examples thereof include a polarizing film and a retardation film.

  A polarizing film is an optical film having a function of emitting polarized light with respect to incident light such as natural light. The polarizing film absorbs linearly polarized light having a vibration surface in a certain direction and reflects linearly polarized film having a property of transmitting linearly polarized light having a vibration surface orthogonal to the vibration surface, and reflects linearly polarized light having a vibration surface in a certain direction, There are a polarizing separation film having a property of transmitting linearly polarized light having a vibration plane orthogonal to the polarizing film, an elliptically polarizing film in which a polarizing film and a retardation film described later are laminated. As a suitable specific example of a polarizing film, particularly a linear polarizing film (sometimes called a polarizer or a polarizer film), a dichroic dye such as iodine or a dichroic dye is added to a uniaxially stretched polyvinyl alcohol resin film. Are adsorbed and oriented.

  The retardation film is an optical film exhibiting optical anisotropy, for example, polyvinyl alcohol, polycarbonate, polyester, polyarylate, polyimide, polyolefin, cyclic polyolefin, polystyrene, polysulfone, polyethersulfone, polyvinylidene fluoride. / Stretched film obtained by stretching polymer film made of polymethyl methacrylate, liquid crystal polyester, acetyl cellulose, saponified ethylene-vinyl acetate copolymer, polyvinyl chloride, etc. by about 1.0 to 6 times It is done. Among them, a polymer film obtained by uniaxially or biaxially stretching a polycarbonate film or a cyclic polyolefin film is preferable. Although there exist what is called a uniaxial phase difference film, a wide viewing angle phase difference film, a low photoelasticity phase difference film, etc., it is applicable to all.

  Moreover, the film which expressed optical anisotropy by application | coating and orientation of a liquid crystalline compound, and the film which expressed optical anisotropy by application | coating of an inorganic layered compound can also be used as retardation film. Such retardation films include what are called temperature-compensated retardation films, and films with a twisted orientation of rod-like liquid crystals sold under the trade name “LC film” by Nippon Oil Corporation. Also, a film with a tilted orientation of a rod-shaped liquid crystal sold under the trade name “NH film” from Shin Nippon Oil Co., Ltd., and a disc shape sold under the trade name “WV film” from Fuji Photo Film Co., Ltd. Film with tilted orientation of liquid crystal, fully biaxially oriented film sold under the trade name “VAC film” by Sumitomo Chemical Co., Ltd. Also sold under the trade name “new VAC film” from Sumitomo Chemical Co., Ltd. Biaxially oriented film.

  Furthermore, those in which a protective film is attached to these optical films can also be used as the optical film. As the protective film, a transparent resin film is used, and as the transparent resin, for example, an acetyl cellulose resin typified by triacetyl cellulose or diacetyl cellulose, a methacrylic resin typified by polymethyl methacrylate, a polyester resin, or a polyolefin Resin, polycarbonate resin, polyether ether ketone resin, polysulfone resin and the like. The resin constituting the protective film may contain an ultraviolet absorber such as a salicylic acid ester compound, a benzophenone compound, a benzotriazole compound, a triazine compound, a cyanoacrylate compound, or a nickel complex compound. As the protective film, an acetyl cellulose resin film such as a triacetyl cellulose film is preferably used.

  Among the optical films described above, the linearly polarizing film is used in a state where a protective film is attached to one or both sides of a polarizer constituting the polarizer, for example, a polarizer film made of a polyvinyl alcohol-based resin. There are many. Moreover, although the above-mentioned elliptically polarizing film is a laminate of a linearly polarizing film and a retardation film, the polarizing film may also be in a state where a protective film is attached to one or both sides of the polarizer film. Many. When the pressure-sensitive adhesive layer according to the present invention is formed on such an elliptically polarizing film, the pressure-sensitive adhesive layer is usually formed on the retardation film side.

  The optical film with pressure-sensitive adhesive of the present invention can be laminated on a glass substrate with the pressure-sensitive adhesive layer to form an optical laminate. Here, as a glass substrate, the glass substrate of a liquid crystal cell, the glass for glare-proof, the glass for sunglasses etc. can be mentioned, for example. Above all, an optical film with adhesive (upper polarizing film) is laminated on the glass substrate on the front side (viewing side) of the liquid crystal cell, and another optical film with adhesive (lower polarizing film) on the glass substrate on the rear side of the liquid crystal cell. The optical laminate formed by laminating is preferable because it can be used as a liquid crystal display device. Examples of the material for the glass substrate include soda lime glass, low alkali glass, and non-alkali glass.

  An optical film with an adhesive is, for example, a method of laminating an adhesive on a release film, further laminating an optical film on the obtained adhesive layer, laminating an adhesive on an optical film, and the adhesive surface The film can be manufactured by, for example, a method in which a release film is bonded and protected to form an optical film with an adhesive. Here, as the release film, for example, a film made of various resins such as polyethylene terephthalate, polybutylene terephthalate, polycarbonate, polyarylate and the like is used as a base material, and the bonding surface with the adhesive layer of the base material is treated with silicone. Examples include those subjected to mold release treatment. In order to laminate an optical film with an adhesive on a glass substrate to form an optical laminate, for example, the release film is peeled off from the optical film with an adhesive obtained as described above, and the exposed adhesive layer is removed from the surface of the glass substrate. You just have to stick together.

  The optical film with the pressure-sensitive adhesive of the present invention is attached to a glass substrate to form an optical laminate, and when there is some inconvenience and the optical film is peeled from the glass substrate, the pressure-sensitive adhesive layer is accompanied by the optical film. Since the surface of the glass substrate that has been peeled off and is in contact with the pressure-sensitive adhesive layer hardly causes fogging or adhesive residue, it is easy to re-attach the optical film with the pressure-sensitive adhesive again to the glass substrate after peeling. That is, it is excellent in so-called reworkability.

  The liquid crystal display device formed from the optical laminate of the present invention includes, for example, a liquid crystal display for personal computers including a notebook type, a desktop type, a PDA (Personal Digital Assistance), a television, an in-vehicle display, an electronic dictionary, a digital It can be used for cameras, digital video cameras, electronic desk calculators, watches, etc.

  EXAMPLES Hereinafter, although an Example is given and this invention is demonstrated further more concretely, this invention is not limited by these examples. In the examples, “parts” and “%” representing the amount used or content are based on weight unless otherwise specified.

The nonvolatile content is a value measured by a method according to JIS K 5407. Specifically, the adhesive solution was taken in a petri dish at an arbitrary weight, and the residual non-volatile content after drying for 2 hours at 115 ° C. in an explosion-proof oven was expressed as a percentage of the weight of the solution first measured. It is. Measurement of weight-average molecular weight, the GPC device, manufactured by Tosoh Co., Ltd. manufactured "TSK gel G6000H _XL" 2 present a "TSK gel G5000H _XL" 2 present arranged sequentially connecting in series as columns, and tetrahydrofuran as an eluent The sample was converted into standard polystyrene under the conditions of a sample concentration of 5 mg / ml, a sample introduction amount of 100 μl, a temperature of 40 ° C., and a flow rate of 1 ml / min.

  First, the example which manufactured the high molecular weight 1st acrylic resin prescribed | regulated by this invention is shown.

[Polymerization Example 1]
In a reactor equipped with a cooling tube, a nitrogen introduction tube, a thermometer and a stirrer, a mixed solution of 81.8 parts of ethyl acetate, 77.0 parts of butyl acrylate, 20.0 parts of methyl acrylate and 3.0 parts of acrylic acid The internal temperature was raised to 55 ° C. while substituting the air in the apparatus with nitrogen gas so as not to contain oxygen. Thereafter, a total amount of a solution prepared by dissolving 0.14 parts of azobisisobutyronitrile (polymerization initiator) in 10 parts of ethyl acetate was added. One hour after the addition of the initiator, an internal temperature of 54 to 56 was added while continuously adding ethyl acetate to the reactor at an addition rate of 17.3 parts / hr so that the concentration of the acrylic resin excluding the monomer was 35%. The mixture was kept at 12 ° C. for 12 hours, and finally ethyl acetate was added to adjust the concentration of the acrylic resin to 20%. The resulting acrylic resin had a polystyrene equivalent weight average molecular weight Mw of 1,560,000 and Mw / Mn of 4.7 by GPC. This is designated as acrylic resin A1.

[Polymerization Example 2]
An acrylic resin solution was obtained in the same manner as in Polymerization Example 1 except that the monomer composition was changed to 98.9 parts of butyl acrylate and 1.1 parts of acrylic acid. The resulting acrylic resin had a polystyrene equivalent weight average molecular weight Mw of 1,200,000 and Mw / Mn of 3.9 by GPC. This is designated as acrylic resin A2.

  Next, an example in which a low molecular weight second acrylic resin was produced will be shown.

[Polymerization Example 3]
In the same reactor used in Polymerization Example 1, 222 parts of ethyl acetate, 35 parts of butyl acrylate, 44 parts of butyl methacrylate, 20 parts of methyl acrylate and 1 part of 2-hydroxyethyl acrylate were charged with nitrogen gas. After replacing the air in the reactor, the internal temperature was raised to 75 ° C. After adding a total amount of 0.55 parts of azobisisobutyronitrile (polymerization initiator) dissolved in 12.5 parts of ethyl acetate, the temperature was kept at 69-71 ° C. for 8 hours to complete the reaction. did. The obtained acrylic resin had a polystyrene-equivalent weight average molecular weight Mw by GPC of 90,000. This is designated as acrylic resin A3.

  Next, the Example and comparative example which manufactured the adhesive using the acrylic resin manufactured above and applied to the optical film are shown. In the following examples, the following were used as ionic compounds. The symbols for each compound are given for later reference. Compound 1, Compound 4, Compound 5, and Compound 6 having bis (trifluoromethanesulfonyl) imide as an anion were liquid at room temperature.

Compound 1: Trioctylmethylammonium bis (trifluoromethanesulfonyl) imide (having the structure of the following formula)

Compound 2: Trioctylmethylammonium perchlorate (having the structure of the following formula)

Compound 3: N-hexyl-4-methylpyridinium perchlorate (having the structure of the following formula)

Compound 4: N-hexyl-4-methylpyridinium bis (trifluoromethanesulfonyl) imide (having the structure of the following formula)

Compound 5: Hexyltrimethylammonium bis (trifluoromethanesulfonyl) imide (having the structure of the following formula)

Compound 6: N-butyl-N-methylpyrrolidinium bis (trifluoromethanesulfonyl) imide (having the structure of the following formula)

  Moreover, the following were each used as a crosslinking agent and a silane compound (all are brand names).

Cross-linking agent Coronate L: Trimethylolpropane adduct of tolylene diisocyanate in ethyl acetate solution (solid content concentration 75%), obtained from Nippon Polyurethane Industry Co., Ltd.

Silane compounds
X-41-1805: Silane oligomer having a mercapto group (liquid), obtained from Shin-Etsu Chemical Co., Ltd.

[Examples 1 to 4, Comparative Examples 1 to 8]
(A) Production of pressure-sensitive adhesive Acrylic resin A1 obtained in Polymerization Example 1 alone, or acrylic resin A2 obtained in Polymerization Example 2 and acrylic resin A3 obtained in Polymerization Example 3 were mixed at a weight ratio shown in Table 1. Thus, an ethyl acetate solution was obtained. The proportions of the ionic compounds 1 to 6 shown above, the cross-linking agent “Coronate L”, and the silane compound “X-41-1805” shown in Table 1 with respect to 100 parts of the non-volatile content of the obtained solution, respectively. To prepare an adhesive composition. However, in Table 1, the blending amount (part) of the crosslinking agent “Coronate L” is the amount of solids. In the example using the acrylic resin A1 alone, the amount of the structural unit derived from the unsaturated carboxylic acid in the acrylic resin A1 is 3 parts with respect to 100 parts of the acrylic resin, and the acrylic resin A2 and the acrylic resin A3 are 70 parts. In the example mixed at a weight ratio of / 30, the amount of the structural unit derived from the unsaturated carboxylic acid therein is 0.77 parts with respect to 100 parts of the acrylic resin.

(B) Production of optical film with pressure-sensitive adhesive Each of the above-mentioned pressure-sensitive adhesive compositions was subjected to mold release treatment of a polyethylene terephthalate film (trade name “PET 3811”, obtained from Lintec Co., Ltd .; called a separator) subjected to a release process It applied to the surface using an applicator so that the thickness after drying would be 25 μm, and dried at 90 ° C. for 1 minute to obtain a sheet-like pressure-sensitive adhesive. Next, on one side of a polarizing film having a three-layer structure in which both sides of a polyvinyl alcohol polarizer to which iodine is adsorbed and oriented are sandwiched between protective films made of triacetyl cellulose, the surface opposite to the separator of the sheet-like adhesive obtained above ( The pressure-sensitive adhesive surface) was pasted with a laminator and then aged for 10 days under conditions of a temperature of 23 ° C. and a relative humidity of 65% to obtain a polarizing film with a pressure-sensitive adhesive.

(C) Evaluation of antistatic property of optical film with pressure-sensitive adhesive When the separator of the obtained polarizing film with pressure-sensitive adhesive was peeled off, the surface resistance value of the pressure-sensitive adhesive was measured using a surface resistivity measuring device ["Mitsubishi Chemical Co., Ltd." Measured with Hirest-up MCP-HT450 "(trade name)] to evaluate antistatic properties. If the surface resistance value is 10 ¹² Ω / □ or less, a corresponding antistatic property is obtained, and if it is 10 ¹¹ Ω / □ or less, it is more preferable.

(D) Production and evaluation of optical laminate so that the polarizing film with adhesive produced in (b) above is crossed Nicol on both surfaces of a glass substrate for liquid crystal cells [“1737” (trade name) manufactured by Corning Inc.] The optical laminate was prepared by sticking. When this optical laminate was stored for 96 hours under a dry condition at a temperature of 80 ° C. (heat resistance test), the appearance of white spots was visually observed. In addition, when the above heat resistance test is performed, when stored at a temperature of 60 ° C. and a relative humidity of 90% for 96 hours (moisture heat resistance test), the temperature is decreased to −20 ° C. from the state heated to 60 ° C., then 60 The process of raising the temperature to 1 ° C. was defined as one cycle (one hour), and the optical laminate after the test was visually observed for each of the cases where this was repeated 100 cycles (heat shock resistance test). The results were classified according to the following criteria and summarized in Table 2.

<Expression of white spots>
The appearance of white spots when light was incident from one polarizing film side was evaluated in the following four stages.

A: No white spots are observed.
○: White spots are hardly noticeable.
Δ: White spots are slightly noticeable.
X: White spots are noticeable.

<Heat resistance, moist heat resistance and heat shock resistance (referred to as “HS resistance” in Table 2)>
These evaluations were performed in the following four stages.

A: No change in appearance such as floating, peeling or foaming is observed.
○: Almost no change in appearance such as floating, peeling or foaming.
Δ: Appearance changes such as floating, peeling and foaming are slightly noticeable.
X: Remarkable changes in appearance such as floating, peeling, foaming, etc.

(E) Reworkability evaluation of optical film with adhesive The reworkability was evaluated as follows. First, the polarizing film with an adhesive was cut into a test piece having a size of 25 mm × 150 mm. Next, the test piece was attached to the glass substrate for a liquid crystal cell on the pressure-sensitive adhesive side using a sticking device ["Lamipacker" (trade name) manufactured by Fuji Plastics Machine Co., Ltd.], 50 ° C., 5 kg / cm ² (490.3 kPa) was autoclaved for 20 minutes. Next, after heat-treating at 70 ° C. for 2 hours and subsequently storing in an oven at 50 ° C. for 48 hours, a polarizing film was removed from the adhesion test piece at 300 mm / mm in an atmosphere at a temperature of 23 ° C. and a relative humidity of 50%. The film was peeled in the direction of 180 ° at a speed of minutes, and the state of the glass plate surface was observed and classified according to the following criteria. The results are also shown in Table 2.

A: No fogging or the like is observed on the glass plate surface.
A: Almost no fogging or the like is observed on the glass plate surface.
(Triangle | delta): Cloudiness etc. are recognized by the glass plate surface.
X: The remainder of an adhesive is recognized by the glass plate surface.

  As can be seen from Tables 1 and 2, Examples 1 to 4 blended with the ionic compound defined in the present invention have a low surface resistance, so that they have excellent antistatic properties and are less likely to cause white spots. In addition, almost satisfactory results were obtained in any of heat resistance, moist heat resistance, heat shock resistance and reworkability. On the other hand, Comparative Examples 1 and 3 in which no ionic compound is blended have a high surface resistance value, so that antistatic properties cannot be expected. On the other hand, compounds that are ionic but do not satisfy the provisions of the present invention. In Comparative Example 2 in which 3 was blended, the decrease in the surface resistance value was small. Comparative Examples 4 to 8 containing Compound 4, Compound 5 or Compound 6 that are ionic but do not satisfy the provisions of the present invention have antistatic effects, but have heat resistance, moist heat resistance, heat shock resistance and In any of the reworkability, sufficient results were not obtained.

  The optical film with a pressure-sensitive adhesive of the present invention is suitably used for a liquid crystal display device because it has high antistatic properties, is less likely to cause white spots even when enlarged, and has excellent durability. For example, it is suitable for a TN liquid crystal cell or the like, and can suppress white spots and enhance durability while imparting antistatic properties. Moreover, when this optical film with an adhesive is used for an STN liquid crystal cell, the occurrence of color unevenness can be suppressed.

Claims (11)

An optical film with an adhesive in which an adhesive layer is formed on at least one surface of the optical film, the adhesive layer comprising:
(A) The following formula (I)

(In the formula, R ₁ represents a hydrogen atom or a methyl group, and R ₂ represents a C 1-14 alkyl group or an aralkyl group, each of which may be substituted with a C 1-10 alkoxy group)
A structural unit derived from an unsaturated carboxylic acid having a structural unit derived from a (meth) acrylic acid ester represented by formula (1) as a main component and further having one olefinic double bond and at least one carboxyl group in the molecule The first acrylic resin having a weight average molecular weight of 800,000 to 2,000,000 is contained, and the content of structural units derived from the unsaturated carboxylic acid is 0.5 to 10 weights per 100 weight parts of the whole resin Part acrylic resin,
(B) The following formula (II)

(Wherein R ₃ represents an alkyl group having 1 to 12 carbon atoms, and R ₄ , R ₅ and R ₆ each independently represents an alkyl group having 6 to 12 carbon atoms)
An optical film with an adhesive, which is formed from a composition containing an ionic compound containing a cation represented by formula (C) and a crosslinking agent (C).   The optical unit with an adhesive according to claim 1, wherein the structural unit derived from the (meth) acrylic acid ester constituting the first acrylic resin includes a unit derived from butyl acrylate. The acrylic resin (A) has, in addition to the first acrylic resin, a structural unit derived from the (meth) acrylic acid ester represented by the formula (I) as a main component, and a weight average molecular weight of 50,000 to 500,000. The optical film with an adhesive according to claim 1 or 2, comprising a second acrylic resin.   The optical film with an adhesive according to any one of claims 1 to 3, wherein the ionic compound (B) has an anion containing a fluorine atom.   The optical film with an adhesive according to claim 4, wherein the anion is bis (trifluoromethanesulfonyl) imide.   The optical film with an adhesive according to any one of claims 1 to 5, wherein the ionic compound (B) is present in an amount of 0.5 to 10 parts by weight with respect to 100 parts by weight of the acrylic resin (A).   Crosslinking agent (C) is an isocyanate type compound, The optical film with an adhesive in any one of Claims 1-6.   The cross-linking agent (C) is selected from the group consisting of tolylene diisocyanate, an adduct obtained by reacting a polyol with tolylene diisocyanate, a dimer of tolylene diisocyanate, and a trimer of tolylene diisocyanate. Optical film with adhesive.   The optical film with an adhesive according to any one of claims 1 to 8, wherein the composition forming the adhesive layer further contains a silane compound.   The optical film with an adhesive according to any one of claims 1 to 9, wherein the optical film is selected from a polarizing film and a retardation film.   The optical laminated body by which the optical film with an adhesive in any one of Claims 1-10 is laminated | stacked on the glass substrate by the adhesive layer side.