JP2007314496A - Method for producing gel, and gel - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To provide gel having activities in addition to water supplying/moisture-keeping of skin, oil supply, circulation promotion, cleansing/make up removal, etc., such as compatibility with the skin based on a living body reaction theory, eliminating activity of free radicals such as active oxygen attached to the skin, and improving the bioactivity and cleansing activity of the skin. <P>SOLUTION: This method for producing the gel is provided by adding and dissolving 4cc carboxyvinyl polymer and 2cc methylcellulose to 840cc hydrogen-added water having 1.31 ppm dissolved hydrogen, -615 mV oxidation reduction potential, and pH7.35, then preparing a water phase by adding 80cc polyethylene glycol 1,500, a discoloration-preventing agent, a coloring matter and a chelating agent by each of suitable amounts, and in a separate process, dissolving 10cc polyoxyethylene oleyl alcohol ether to 70cc dipropylene glycol by heating at approximately 55°C, preparing an oil phase by adding a preservative and aromatizing agent, then adding the water phase gradually into the oil phase while agitating, then neutralizing by adding 1cc potassium hydroxide as an alkali, agitating, degassing and filtering. <P>COPYRIGHT: (C)2008,JPO&INPIT

Description

  The present invention relates to a method of producing a gel and a gel, and more particularly, the basic component constituting the aqueous gel and the aqueous component of the oily gel comprises 0.5 ppm to 1.5 ppm of hydrogen and a redox potential of -400 mV The present invention relates to a gel characterized by the following hydrogenated water and a method for producing the same.

  Gels are roughly divided into aqueous gels and oily gels. Explain each gel purpose and effect.

  The aqueous gel mainly uses the gelling property of the water-soluble polymer. For example, using a carboxyvinyl polymer or a methylcellulose gel, a moisturizer, a surfactant, a preservative, various drugs, colors are contained in this gel. It is a transparent gel with additives, flavors, etc. added. The aqueous gel is fresh, has a refreshing feeling, and has a refreshing feeling of use. Some aqueous gels do not contain oil and some contain a small amount of oil, both of which are for the purpose of supplying water and moisturizing.

  As the oil-based gel, an emulsion type in which the gelling property and the crystal structure of the surfactant are utilized or the refractive index of the inner and outer phases is combined to make it transparent is the mainstream. Since it is an oily type, it has a feeling of weight like oily cream, and aims at moisturizing retention and oil supply.

  In addition, there are an aqueous gel for the purpose of promoting circulation, an aqueous gel and an oily gel for the purpose of cleansing (make-up removal), and the like, and the present invention includes all these gels.

  In addition to purified water, the components of the gel for hydration and moisturizing purposes include moisturizers, water-soluble polymers, surfactants, alkalis, preservatives, anti-fading agents, coloring agents, chelating agents, and perfumes. Etc. Among these, purified water contains 80 to 90% or more. Moreover, the component of the gel for washing | cleaning and base (make) removal contains an oil, a moisturizer, surfactant, a perfume, etc. other than a purified water. Among these, purified water is about 8 to 10%.

  In any case, although water is a basic component of gel, it is considered that water should be purified water listed in the Japanese Pharmacopoeia, and researches focusing on its redox potential. It was not done.

  By the way, various redox reaction systems exist in the living body, and many of them are mutually coupled to be involved in the in vivo redox reaction. The redox potential of the in vivo redox system is directly related to the free energy change of the reaction and the equilibrium constant, and serves to predict the direction of these reactions.

  The skin on the outermost surface of the human body performs various functions. For example, water retention function to prevent the water contained in the skin escapes, barrier function to prevent allergens and harmful substances, irritants from entering the body, UV protection function, antioxidant function, immune function, It has various functions and functions such as moisturizing control function, sensory function, female hormone, male hormone, steroid hormone such as adrenocortical hormone, fat-soluble substance such as vitamin A, D, E, K etc.

  Naturally, the various functions and actions of the skin are also due to the in vivo redox reaction. Therefore, the inventor focused on the relationship between water, which is a basic component of the gel applied to the skin, and the bioredox reaction of the skin.

  The redox reaction of the in vivo reaction has a low potential, usually in the range of -100 mV to -400 mV, and its pH is in the range of 3-7. It is said that when the redox potential of body fluid is high, active oxygen tends to be retained, resulting in organ damage.

For example, in vivo, the redox potential of (acetic acid + CO ₂ + 2 H ⁺ / α-ketoglutaric acid reaction) is -673 mV, the redox potential of (acetic acid + CO ₂ / pyruvic acid reaction) is -699 mV, (acetic acid + 2 H ⁺ / acetaldehyde The redox potential of the reaction) is -581 mV, the redox potential of ferredoxin is -413 mV, the redox potential of (xanthine + H ⁺ / hypoxanthine + H ₂ O) is-371 mV, (uric acid + H ⁺ / xanthine + H ₂ O) oxidation The reduction potential is -360 mV, and the redox potential of (acetoacetic acid + 2 H ⁺ / β-hydroxybutyric acid reaction) is -346 mV (cystine + 2 H ⁺ / 2 cysteine reaction)-340 mV.

  Thus, reactions of enzymes, coenzymes, and metabolic substances in vivo are in an environment where the redox potential is low. In addition, water or food with low redox potential has the function of separating and eliminating active oxygen that oxidizes the body, molecules or atoms having one or more unpaired electrons, that is, free radicals. It is said to promote the reaction of a reactive oxygen scavenging enzyme called SOD (superoxide dismutase).

  By the way, the redox potential of normal tap water (13.0 ° C) in Japan is +400 to +800 mV, the pH is 7.0 to 7.5, the amount of dissolved hydrogen is 2.3 to 2.6 ppb, and the amount of dissolved oxygen is about It is in the range of 10.0 ppm. That is, since tap water has a large amount of dissolved oxygen, it easily generates active oxygen to the living body, and since the redox potential is positive, there is no reducing power even if it has oxidizing power, and the redox potential is -400 mV. It is believed to be out of balance with human skin in the range of -700 mV.

  Furthermore, the present inventors examined providing the gel with a function of eliminating free radicals such as active oxygen attached to the skin. The dissolved hydrogen content of the purified water, which is the basic component of the conventional gel, is extremely small at 2.3 ppb to 2.6 ppb, and is insufficient to continuously eliminate free radicals such as active oxygen generated in vivo. Furthermore, the redox potential is as large as +400 mV to +800 mV, and the reducing power in vivo is weak.

  By the way, one of the inventors of the present invention has filed and filed a patent application for a related technique for blowing hydrogen into purified water in a mixed state of an oxidant and a reductant to maintain the redox potential of the purified water at -400 mV or less.

  Patent Document 1 describes: “Hydrogen has a gas pressure of 0.1 MPa to 0.95 MPa while contacting purified water in a mixed state of an oxidant and a reductant with a reduction catalyst having a silica-based quartz rock supporting a metal; By bubbling for 10 seconds to 10 minutes to reduce the redox potential of purified water to -400 mV to -600 mV, and then filling this water in a container with a perfect barrier function against light, oxygen, hydrogen and water vapor Method of maintaining the redox potential between -400 mV and -600 mV.

  Patent Document 2 states that “hydrogen is introduced at a gas pressure of 0.1 MPa to 0.95 MPa while contacting purified water in a mixed state of an oxidant and a reductant with a reduction catalyst having a silica-based quartz rock supporting a metal. Method of maintaining the redox potential at -400 mV or less by increasing the activity of the reductant by more than the activity of the oxidant in a method of lowering the redox potential of purified water by blowing in for 10 seconds to 10 minutes Is disclosed.

  Patent Document 3 describes that “water having an oxidation reduction potential of −400 mV to −600 mV prepared by a predetermined method is filled in a variable volume container having a perfect barrier function against oxygen, hydrogen and water vapor at 85 ° C. to 100 ° C.) Discloses a method of sterilizing water having a redox potential of -400 mV to -600 mV, which comprises heating at 30 ° C. for 30 minutes to 45 minutes.

  Patent Document 4 discloses that “a reaction tank having a purified water storage capacity is divided into an upper chamber and a lower chamber by a partition plate having a through hole and a reduction catalyst mounted thereon, and a purified water supply system pipe connected to household water supply , Sealingly join a reduced pressure system pipe, a hydrogen supply system pipe connected to a hydrogen bomb, and a product water extraction system pipe, and boil 29 liters of hydrogen for 3 minutes to produce up to 30 liters of hydrogen water per hour Apparatus is disclosed.

  Furthermore, the present inventor examined that water, which is a basic component of the gel, has the function of enhancing the biological activity of the skin and the cleansing action of the skin.

  When hydrogen peroxide water having a dissolved hydrogen content of 0.5 ppm to 1.5 ppm or less as disclosed in Patent Documents 1 to 4 is used as a basic component of the gel, the redox potential is in the range of -400 mV to -700 mV It is a well-balanced gel with human skin. However, since hydrogen dissolved in hydrogenated water disclosed in Patent Documents 1 to 4 has a particle size as large as several mm, is not uniform, and is not uniformly dispersed, the function of enhancing the biological activity of the skin and the skin It does not have the effect of eliminating free radicals such as active oxygen attached to the skin.

Therefore, if the particle size of hydrogen contained in water, which is the basic component of the gel, can be made as small as possible, made uniform, and made uniform, the absorption efficiency into the liquid is high, and the skin's bioactivity and cleansing action Can be enhanced.
JP 2005-901A JP 2005-21875 A JP, 2005-66584, A JP 2005-177724 A

  The first problem to be solved by the invention is the basic performance of the gel: moisturization and softness of the skin, blood circulation promotion and softness of the skin, washing and makeup removal of the skin, protection of living ultraviolet rays, cosmetic base, and softness of keratin It is to provide a gel which not only has an effect such as conversion, but is also in harmony with the skin from the biological reaction theory.

  A second problem to be solved by the invention is, in addition to the first problem, to provide a gel having an action of eliminating free radicals such as active oxygen attached to the skin.

The third problem to be solved by the invention is, in addition to the above first and second problems, a gel having a function of enhancing the bioactivity of the skin and the cleansing action of the skin in water itself which is a basic component of the gel. It is to provide.
Further problems and advantages to be solved by the invention will be clarified sequentially below.

  The first problem is solved by using hydrogenated water of −400 mV or less and having a dissolved hydrogen content of 0.5 ppm to 1.5 ppm as a basic component of the gel.

  In the present invention, the reason why the maximum value of the redox potential is −400 mV is that the redox reaction of human skin is usually in the range of −400 mV to −700 mV. Therefore, in the present invention, the minimum value of the redox potential is preferably -700 mV.

Next, means for solving the second problem will be described. The present inventors have made theoretical considerations as to the generation of free radicals, their action and elimination as follows. The causes of generation of free radicals such as active oxygen in the living body have not been completely elucidated. However, as one of them, for example, when ultraviolet light is irradiated to the skin, it acts on water molecules existing inside and outside the cells constituting the skin to generate positive and negative water molecular ions. These ions are further decomposed to form free radicals of OH · and H · in addition to stable ions of H ⁺ and OH ⁻ . If reactant is not, between these free _{radicals, OH · + H · → H} 2 O ( water), H · + H · → H 2 ( hydrogen), OH · + OH · → H 2 O 2 ( peroxide A reaction like hydrogen occurs. By the way, since OH ·, H ·, etc. free radicals have unpaired electrons in the outermost shell orbit, the spins of the electrons remain without being canceled. That is, the spin angular motion is not zero and exhibits various magnetic properties. For example, a molecule in which all electrons are paired exhibits diamagnetism, but one having unpaired electrons exhibits paramagnetism. Usually, free radicals are highly reactive in order to form an electron pair with one having another unpaired electron and to bind and stabilize. Therefore, as in the living body, when there are reactive substances in the surroundings, OH ·, H ·, H ₂ O ₂ react with them, resulting in various abnormal phenomena in the living body. For example, when it acts on DNA, it causes deamination, dehydrogenation, splitting of a base bond, cleavage of a base, oxidation of sugar, release of inorganic phosphorus and the like, leading to various diseases.

Next, theoretical considerations were made regarding the elimination of free radicals. The living body is no exception to the law of thermodynamics, and changes in free energy (Gibbs free energy) as a measure of energy to do work, that is, ΔG = ΔH−TΔS (ΔH is the enthalpy change, T is the absolute temperature, ΔS Is a change (entropy change) represented by (entropy change) as the starting point of bioenergy. The free energy production in the living body is mostly due to the free energy released due to the difference in the redox potential of the reactant in the redox reaction, rather than the concentration change in the natural world. Here, oxidation is a reaction that loses an electron, and reduction is a reaction that obtains an electron. For _example, reaction of ^{_{1 / 2H 2 + Fe 3+ ⇔H}} + + Fe 2+ ^{_{is, 1 / 2H 2 -e → H}} + ( ^{_{or, 1 / 2H 2 → H +}} + e) an oxidation reaction of, that ^{Fe 3+} + e → ^{Fe 2+} It can be divided into reduction reactions. In this case, 1⁄2H _{2 which} is oxidized, ie, loses an electron and given to the other, acts as a reducing agent, and is reduced, ie, Fe ³⁺ which receives an electron, acts as an oxidizing agent. Further, in general, the redox reaction by the transfer of hydrogen AH + B⇔A + BH can also be considered as being decomposed into an oxidation reaction AH → A + H ⁺ + e and a reduction reaction B + H ⁺ + e → BH. Transfer of hydrogen can be regarded as transfer of electrons H ⁺ + e. In this way, the movement of electrons and the movement of hydrogen can be regarded as equivalent.

In this way, in order to eliminate free radicals such as active oxygen, it is sufficient to reduce and stabilize it with atomic hydrogen (H⇔H ⁺ + e).

  By the way, “Chemical Hydrogen Dictionary 2” issued by Kyoritsu Publishing Co., Ltd. is “active hydrogen”, it is easy to cause a chemical reaction because “stable hydrogen bond of hydrogen molecule is broken by discharge, high heat, ultraviolet light and atomic hydrogen is generated. Also, so-called nascent hydrogen and hydrogen on reduction catalysts such as palladium and nickel are considered to be in atomic state or near atomic state, and are rich in reactivity, and these are also active hydrogen in a broad sense. It is defined as “inclusive,” and described as showing strong reducing action.

The present invention is mainly based on blowing and dissolving as much hydrogen as possible into water as a basic component of the gel, but hydrogen blown into purified water is molecular hydrogen (H ₂ ) and atomic hydrogen (H ₂ ) Since it is not H), it has no ability to reduce free radicals such as active oxygen as it is. Therefore, in the present invention, it is decided to reduce hydrogen radicals such as active oxygen by converting hydrogen water produced by hydrogen bubble injection into active hydrogen by bringing it into contact with a platinum group element in site.

  The platinum group element used in the present invention will be described. Among the elements belonging to periodic table group VIII, platinum group elements are six elements of ruthenium (Ru), rhodium (Rh), palladium (Pd), osmium (Os), iridium (Ir) and platinum (Pt). It is a generic term. These platinum group elements are active in various reactions of hydrogenation, dehydrogenation and oxidation. It has a function as a so-called reduction catalyst. Therefore, when molecular hydrogen comes in contact with a platinum group element, the molecular hydrogen becomes atomic or close to it. Therefore, in the present specification, the action of a platinum group element to bring molecular hydrogen into an atomic state or close state is referred to as “catalysis action”.

  The platinum group element particularly preferably used in the present invention is platinum. Also, its shape is preferably colloidal since it is added to the gel.

  The platinum colloid particularly preferably used in the present invention is protected, for example, by (1) reducing the external surface of an aqueous solution of hexachloroplatinum (IV) acid by applying a Bunsen burner flame, and (2) protecting the aqueous solution of hexachloroplatinum (IV) Sodium ascorbate, gum arabic or gelatin etc. is added as a colloid and reduced with a reducing agent such as hydrazine. (3) Put pure water in an evaporation dish and put it between two platinum wires immersed in this while cooling. The arc is produced by a method such as the Bledch method. The platinum colloids prepared by the Breedich method are unstable, but the catalytic ability is strong because the colloidal particles are not coated with the protective colloid. On the other hand, those containing protective colloids are stable although their catalytic ability is lower than that of platinum colloids produced by the Bredich method.

  In the present invention, the addition amount of platinum colloid is 0.1 ppm to 1.0 ppm, preferably 0.4 ppm to 1.0 ppm.

  Next, the third subject, which is the basic component of the gel, providing the gel having the function of enhancing the biological activity of the skin and the cleansing action of the skin to water itself will be described.

  In recent years, research on so-called microbubbles and their application development have been actively conducted. Microbubbles are defined as fine bubbles of 10 μm to several 10 μm in diameter. Usually, the diameter of the bubbles generated or formed in water is about several millimeters, but the application utilizing the characteristic that the microbubbles are 1/100 or less thereof has been researched and developed. That is, the microbubbles are applied to the cleaning action of the living body, etc., which have high absorption efficiency in the liquid, are excellent in uniformity and dispersibility, enhance biological activity of the living body, and the like.

  The present inventor does not adversely affect the bioreaction of the skin, but it is a water which has the same or very similar nature as the bioreaction of the skin, and which is dissolved in water with a redox potential of -400 mV or less. The formation of a bubble was examined, and as a result of repeating the experiment, it was found that fine bubbles in the range of 2 μm (0.002 mm) to 120 μm (0.12 mm) in diameter can be produced. Therefore, based on this finding, the third problem can be solved by using hydrogen water containing a large amount of hydrogen as mixed fine bubbles of 2 μm (0.002 mm) to 120 μm (0.12 mm) in diameter. It is a solution.

  The term “hydrogenated water containing a large amount of hydrogen as mixed fine bubbles with a diameter of 2 μm (0.002 mm) to 120 μm (0.12 mm)” used in the present invention refers to the hydrogen water of the present invention. Hydrogen may be contained as mixed fine bubbles of 2 μm (0.002 mm) to 120 μm (0.12 mm) in diameter, and usually, bubbles of about several millimeters in diameter generated or formed in water are simultaneously Do not exclude inclusion.

  If the diameter of hydrogen bubbles is 2 μm or less, it is not preferable because the cost required for generation is high, and if it is 120 μm or more, it is not preferable because the desired bioactivity as a microbubble and the skin cleansing effect can not be obtained. .

  In the present invention, hydrogenated water containing a large amount of hydrogen as mixed fine bubbles having a diameter of 2 μm (0.002 mm) to 120 μm (0.12 mm) is purified water, i. Tube and b. A purified water supply system, which is formed at one end of the tube and supplies purified water at high pressure, and c. And a hydrogen supply system for supplying hydrogen substantially at right angles to the water formed in the tubular body and supplied from the purified water supply system. It is formed in the longitudinal direction of the pipe downstream of the hydrogen supply system in the pipe and mixes and diffuses the water supplied from the purified water supply system to the pipe and the hydrogen supplied from the hydrogen supply system to the pipe. Because of the diffusion room, ho. A porous element having a predetermined pore size filled in the diffusion chamber; It is manufactured by passing through the mixed micro-bubbles containing hydrogen water production device provided with the outlet which is formed in the other end of a tube, and discharges the manufactured target hydrogen water.

  An opening serving as an injection port for purified water of water is formed at one end of the tubular body, and a purified water supply system for supplying purified water at high pressure is watertightly coupled. The purified water supply system is connected to a water supply facility with a water pressure of 0.1 to 1.0 MPa, usually tap water, and a pump is connected between them. The amount of water supplied is preferably 8 to 20 liters / minute.

  The inside of the water jet nozzle formed at one end of the pipe is the inside of the nozzle, and the water jetted at high pressure is jetted at a higher pressure. Usually, since the purified water is jetted in an incompressible state, the shape of the nozzle may be a so-called tapered nozzle such that the flow passage area is properly reduced. However, in the case of injecting purified water in a compressible state, a combination of a tapered nozzle and a diverging nozzle is preferable.

  The pipe body is provided with a hydrogen supply system for supplying hydrogen substantially perpendicularly to the water supplied from the purified water supply system in watertight connection. The hydrogen supply system is preferably provided with a check valve to prevent water supplied from the purified water supply system from flowing back to the hydrogen supply system. A hydrogen cylinder, a gas pressure regulator, piping, etc. are incorporated in the hydrogen supply system, and hydrogen whose pressure is adjusted is jetted.

  The injection amount of hydrogen is preferably 0.05 to 1 liter / min, and the injection pressure is preferably equal to or higher than the water pressure. As one example, in the case of a water pressure of 0.1 MPa, the injection pressure of hydrogen is preferably 0.5 MPa.

  A diffusion chamber is formed in the tubular body in the longitudinal direction of the tubular body downstream of the hydrogen supply system, in the form of a so-called double tube. The diffusion chamber is for diffusing a mixed fluid of water supplied from the purified water supply system to the pipe and hydrogen supplied from the hydrogen supply system to the pipe.

  The diffusion chamber has a diameter reducing structure, that is, a throttling structure from the both ends toward the center, and a negative pressure is formed at the throttling portion. Since the diffusion chamber has a squeezed structure so that a negative pressure is formed, the water supplied from the purified water supply system to the pipe and the hydrogen supplied from the hydrogen supply system to the pipe The suction effect of the mixed fluid is enhanced.

  The diffusion chamber is filled with a porous element having a predetermined pore size. The porous element disposed in the diffusion chamber is a type of filter. It is for forming the mixed fluid which consists of water and hydrogen introduced into a diffusion chamber as a bubble of the same diameter as the diameter of the hole currently formed by the porous by injecting through a porous element.

  The material is not particularly limited as long as the porous element has a pore size of 2 μm to 120 μm. Gunmetals, bronzes, nickels, stainless steels, sintered bodies such as ceramics, wire netting, etc. can be used. In the case of using abrasion resistance and produced water for drinking, a sintered body of stainless steel is preferable.

  The shape of the porous element may be in a variety of shapes such as a disc, a cylinder, a cylinder bottom, a cap and the like, but a cylinder is preferred for insertion into a tube.

  The thickness of the porous element is 5 mm to 20 mm, preferably 5 mm to 10 mm, and is appropriately selected depending on conditions such as water pressure and water amount.

  Commercially available porous bodies include sintered metal elements with pore sizes in the range of 2 μm to 120 μm. In order to form finer cells, sintered metal elements with a pore diameter as small as possible will be used, but the pressure loss of the amount of hydraulic water will be large, and the production efficiency will be reduced. Therefore, it is important to select appropriately depending on the amount of dissolved hydrogen and the amount of water to be obtained.

  When producing hydrogenated water in the present invention, the injection pressure of hydrogen gas is, for example, in the range of 0.1 MPa to 1.0 MPa. If the injection pressure of hydrogen gas is in this range, a redox potential of -550 mV can be secured.

  In the case of producing hydrogenated water in the present invention, the injection time of hydrogen gas is, for example, 10 seconds to 10 minutes, preferably 2 minutes to 5 minutes. If the hydrogen gas injection time is in this range, a redox potential of -550 mV can be secured. If the injection time of hydrogen gas is too short, the potential is unstable, and on the contrary, if it is too long, the potential lowering effect is not significantly affected, which raises the cost.

  The gel for hydration and moisturizing which is a typical gel of the present invention is first oxidized, for example, by blowing hydrogen into (1) purified water at a gas pressure of 0.25 MPa and a gas flow rate of 0.1 to 1 liter / minute. Hydrogenated water production process for producing hydrogenated water having a reduction potential of −400 mV or less and a dissolved hydrogen content of 0.5 ppm to 1.5 ppm, and (2) uniformly dissolving a water-soluble polymer in the hydrogenated water. Water phase manufacturing step of manufacturing an aqueous phase to which a part of the moisturizing agent, antifading agent, coloring agent and chelating agent are added, and (3) an interface to another moisturizing agent separately from the aqueous phase manufacturing step. Adding an activator, heating at a predetermined temperature, adding a preservative, a fragrance and the like to this to produce a surfactant solution, and (4) gradually stirring the aqueous phase into the surfactant solution And (5) adding an alkaline aqueous solution and neutralizing it. No.

  Alternatively, according to the present invention, a representative gel for hydration and moisturizing gel may be, for example, (1) a portion of the moisturizing agent after uniformly dissolving the water-soluble polymer in (1) purified water; The aqueous phase manufacturing process which manufactures the aqueous phase which added the preventive agent, the coloring agent, and the chelating agent, (2) separately from the above aqueous phase manufacturing process, a surfactant is added to another moisturizer and heated at a predetermined temperature And adding a preservative, a perfume and the like thereto to produce a surfactant solution, (3) gradually adding the aqueous phase to the surfactant solution while stirring, and (4) an alkaline aqueous solution (5) Next, bubbling hydrogen at a gas pressure of 0.25 MPa and a gas flow rate of 0.1 to 1 l / min to make the purified water have an oxidation reduction potential of -400 mV or less, and an amount of dissolved hydrogen Conversion process to 0.5 ppm to 1.5 ppm hydrogen water No.

  Therefore, according to this manufacturing method, it is possible to use, as a starting material, a commercially available gel in which the components of the gel are blended in advance.

  Further, according to the present invention, the gel for water supply for moisturizing finely mixed and moisturizing is first mixed with (1) purified water by blowing hydrogen at a gas pressure of 0.25 MPa and a gas flow rate of 0.1 to 1 liter / min. A large amount of hydrogen produced by being jetted from a porous element having a pore diameter of 2 μm to 120 μm as a mixed microbubble of 2 μm to 120 μm in diameter, an oxidation reduction potential of −400 mV or less, and a dissolved hydrogen amount of 0.5 ppm to 1. Hydrogenated water production process for producing 5 ppm hydrogenated water, (2) A part of a moisturizing agent, an antifading agent, a coloring agent, a chelating agent after uniformly dissolving a water-soluble polymer in the hydrogenated water Separately from the aqueous phase production step of producing an aqueous phase to which the above is added, and (3) the aqueous phase production step, a surfactant is added to another moisturizing agent, heated at a predetermined temperature, Etc. to produce a surfactant solution And a step, (4) a step of gradually adding with stirring the surfactant solution aqueous phase, and (5) a step of adding an alkali aqueous solution neutralization.

  Further, according to the present invention, the fine mixed bubbled hydration and moisturizing gel is prepared by first dissolving the water-soluble polymer uniformly in (1) purified water, and then part of the moisturizing agent, antifading agent, color Separate from the aqueous phase production step of producing the aqueous phase to which the agent and the chelating agent have been added, and (2) the aqueous phase production step, a surfactant is added to another humectant, and heated at a predetermined temperature, The step of blending a preservative, a fragrance and the like to produce a surfactant solution, (3) the step of gradually adding the aqueous phase to the surfactant solution while stirring, and (4) the addition of an alkaline aqueous solution And hydrogen were blown into the purified water at a gas pressure of 0.25 MPa and a gas flow rate of 0.1 to 1 l / min and mixed, and the hydrogen was injected from a porous element having a pore size of 2 μm to 120 μm. Contain hydrogen in large quantities as mixed fine bubbles with a diameter of 2 μm to 120 μm Includes the step of oxidation-reduction potential is -400mV or less, the dissolved hydrogen content is converted to hydrogenolysis water 0.5Ppm～1.5Ppm.

  Therefore, according to this manufacturing method, it is possible to use, as a starting material, a commercially available gel in which the components of the gel are blended in advance.

  The oil-based gel which is a typical gel of the present invention is, for example, first, (1) bubbling hydrogen into purified water at a gas pressure of 0.25 MPa and a gas flow rate of 0.1 to 1 liter / minute to Hydrogenated water production process for producing hydrogenated water with 400mV or less and dissolved hydrogen content of 0.5ppm to 1.5ppm, (2) Add a moisturizer and surfactant to the above hydrogenated water, and obtain a predetermined temperature Water phase manufacturing process to adjust to (3) oil phase manufacturing process of adding another surfactant and flavor to oil and adjusting to a predetermined temperature, (4) gradually adding to oil phase and water phase The process includes (5) emulsifying with an emulsifying device, and a degassing / filtering / cooling process is further added.

  Alternatively, according to the present invention, an oil gel, which is a typical gel, may be prepared, for example, by first adding (1) a moisturizer and a surfactant to purified water to adjust to a predetermined temperature; ) An oil phase production step of adjusting the temperature to a predetermined temperature by adding another surfactant and flavor to the oil, (3) gradually adding it to the oil phase and the water phase, and (4) emulsifying with an emulsifying device (5) Bubbling hydrogen at a gas pressure of 0.25 MPa and a gas flow rate of 0.1 to 1 l / min to produce purified water, and an oxidation reduction potential of -400 mV or less, and a dissolved hydrogen amount of 0.5 ppm to 1.5 ppm The process of converting into hydrogenated water and the process of degassing / filtering / cooling are added.

  Therefore, according to this manufacturing method, it is possible to use, as a starting material, a commercially available gel in which the components of the gel are blended in advance.

  Further, according to the present invention, for example, firstly, (1) hydrogen is injected into (1) purified water at a gas pressure of 0.25 MPa and a gas flow rate of 0.1 to 1 liter / minute, and mixed. Contains a large amount of hydrogen produced by spraying from a porous element with a diameter of 2 μm to 120 μm as mixed fine cells with a diameter of 2 μm to 120 μm, an oxidation reduction potential of -400 mV or less, and a dissolved hydrogen content of 0.5 ppm to 1.5 ppm Hydrogenated water production process for producing hydrogenated water, (2) Water phase production process for adding a moisturizer and surfactant to the above-mentioned hydrogenated water to adjust the temperature to a predetermined temperature, (3) Separately into oil components And (4) a step of gradually adding to an oil phase and an aqueous phase, and (5) a step of emulsifying with an emulsifying device, In addition degassing, filtration and cooling processes are added It is.

  Further, according to the present invention, the finely mixed mixed bubbled oil gel is prepared, for example, by first adding (1) a moisturizer and a surfactant to purified water to adjust the temperature to a predetermined temperature, and (2) Oil phase production process of adjusting the temperature to a predetermined temperature by adding another surfactant and perfume to the oil, (3) gradually adding to the oil phase and water phase, and (4) emulsifying with an emulsifying device And (5) Hydrogen is blown into and mixed with purified water at a gas pressure of 0.25 MPa and a gas flow rate of 0.1 to 1 l / min, and hydrogen is produced by spouting from a porous element having a pore size of 2 μm to 120 μm. Degassing, filtration, and the like including a step of converting into a hydrogenated water containing a large amount of mixed fine bubbles having a diameter of 2 μm to 120 μm, an oxidation reduction potential of -400 mV or less, and a dissolved hydrogen amount of 0.5 ppm to 1.5 ppm. A cooling step is added.

  Therefore, according to this manufacturing method, it is possible to use, as a starting material, a commercially available gel in which the components of the gel are blended in advance.

  In the method of the present invention described above, it is preferable to add the colloidal platinum group element at any step before introducing hydrogen.

  The platinum group element used in the present invention will be described. Among the elements belonging to periodic table group VIII, platinum group elements are six elements of ruthenium (Ru), rhodium (Rh), palladium (Pd), osmium (Os), iridium (Ir) and platinum (Pt). It is a generic term. These platinum group elements are active in various reactions of hydrogenation, dehydrogenation and oxidation. It has a function as a so-called reduction catalyst. Therefore, when molecular hydrogen comes in contact with a platinum group element, the molecular hydrogen becomes atomic or close to it. Therefore, in the present specification, the action of a platinum group element to bring molecular hydrogen into an atomic state or close state is referred to as “catalysis action”.

  The platinum group element particularly preferably used in the present invention is platinum. Also, its shape is preferably colloidal since it is added to the emulsion.

  The platinum colloid particularly preferably used in the present invention is protected, for example, by (1) reducing the external surface of an aqueous solution of hexachloroplatinum (IV) acid by applying a Bunsen burner flame, and (2) protecting the aqueous solution of hexachloroplatinum (IV) Sodium ascorbate, gum arabic or gelatin etc. is added as a colloid and reduced with a reducing agent such as hydrazine. (3) Put pure water in an evaporation dish and put it between two platinum wires immersed in this while cooling. The arc is produced by a method such as the Bledch method. The platinum colloids prepared by the Breedich method are unstable, but the catalytic ability is strong because the colloidal particles are not coated with the protective colloid. On the other hand, those containing protective colloids are stable although their catalytic ability is lower than that of platinum colloids produced by the Bredich method.

In the present invention, the addition amount of platinum colloid is 0.1 ppm to 1.0 ppm, preferably 0.4 ppm to 1.0 ppm.
Any of the methods can be carried out either batchwise or continuously.

  Next, the aqueous component, the emulsifier (surfactant), the oily component, various components and drugs used to produce the gel of the present invention will be described.

  The purified water, which is the basic component of the aqueous component of the gel of the present invention, is the purified water listed in the Japanese Pharmacopoeia, and ordinary tap water, that is, water purified by passing ordinary water through a predetermined water purifier. Include. As a water purification apparatus, fibrous activated carbon made of ordinary activated carbon, polymeric fiber, acrylic fiber, special phenolic resin fiber, etc., tube fiber, helical fiber, double tube fiber, fish bone fiber, charcoal, various filter media, or these are used. Use a combination. However, it is not limited to these, and it is sufficient if it has a function of removing dirt, mold, odor, chlorine, impurities and the like of tap water.

  In the gel of the present invention, the amount of hydrogenated water having an oxidation reduction potential of -400 mV or less and a dissolved hydrogen amount of 0.5 ppm to 1.5 ppm is preferably in the range of 50 to 80% by mass. When the amount of the hydrogenated water is 50% by mass or less, the function and effect inherent to the hydrogenated water are not sufficiently expressed, which is not preferable. However, when it manufactures using a commercially available gel, it becomes the quantity of the purified water contained in the gel.

  The oil phase component used in the gel of the present invention is squalane, liquid paraffin, petrolatum, solid paraffin, microcrystalline wax, ceresin, squalane hydrocarbon, olive oil, camellia oil, macadamia nut oil, castor oil, almond oil, cocoa oil , Avocado oil, hydrogenated palm oil, castor oil, sunflower oil, evening primrose oil etc., carnauba wax, candelilla wax, jojoba oil, beeswax, lanolin etc. waxes, lauric acid, myristic acid, palmitic acid, stearic acid, isostearic acid Fatty acids, cetyl alcohol, stearyl alcohol, isostearyl alcohol, higher alcohols such as 2-octyldodecanol, isopropyl myristate, 2-octyldodecyl myristate, cetyl 2-ethylhexanoate, diisostearyl malate Etc. esters, methyl polysiloxane, methylphenyl polysiloxane and silicone oil and the like.

  In the present invention, the amount and type of the oily component are determined in consideration of various conditions such as usability and stability of the gel.

  The gel of the present invention may contain, as an aqueous component, up to 20% by mass of a moisturizing agent which functions to moisturize the stratum corneum, improve the feeling in use, and function as a solvent for other components. Examples of the humectant include glycerin, sorbitol, propylene glycol, dipropylene glycol, 1,3-butylene glycol, polyethylene glycol, hyaluronic acid, polysaccharides such as maltitol, and amino acids such as pyrrolidone carboxylic acid.

  For example, when using glycerin as a moisturizing agent in the gel of the present invention, it is preferable to add the grade listed in the Japanese Pharmacopoeia in the range of 10 to 20 grams per liter of ordinary water. .

  In the gel of the present invention, a softener (emollient agent) may be added as an aqueous component in an appropriate amount for the purpose of improving the emollient of the skin, the feeling of use, and moisturizing. Examples of softeners (emollients) include ester oils, vegetable oils such as olive oil, and the like.

  The gel of the present invention may contain, as an aqueous component, at most 1% by mass of a solubilizing agent for the purpose of solubilizing the raw material component. Examples of solubilizers are surfactants having a high HLB (hydrophilic-lipophilic balance), such as polyoxyethylene and oleyl ether.

  The gel of the present invention may contain, as an aqueous component, an alkali such as potassium hydroxide or potassium carbonate as a stratum corneum softener in the range of 1 to 2 g per liter of water.

  To the gel of the present invention, appropriate amounts of various natural or artificial flavors such as geraniol and linalool may be added as an aqueous component in order to impart a flavor.

  In the gel of the present invention, as an aqueous component, methyl paraben, phenoxyethanol or the like may be added as a preservative.

  An optional dye may be added to the gel of the present invention as an aqueous component.

  In the gel of the present invention, as an aqueous component, if desired, a metal ion element blocking agent, an ultraviolet light absorber, etc. may be added as an antifading agent.

  The gel of the present invention may contain, as an aqueous component, an astringent agent such as zinc paraphenol sulfonate, a bactericidal agent such as benzalkonium hydrochloride, and a nutrient such as vitamins and amino acid derivatives.

  In addition, in the gel of the present invention, as an aqueous component, an astringent agent for tightening the skin such as zinc sulfocalate or sodium sulfocalate, a bactericidal agent for disinfecting the skin such as benzalkonium hydrochloride, a vitamin, an amino acid derivative, an animal plant extract Activators for activating the skin, etc., glycyrrhizin derivatives, anti-inflammatory agents having anti-inflammatory activity such as allantoin, whitening agents such as arubutin, kojic acid, vitamin C, etc. which inhibit the formation of melanin may be blended.

  As the anionic surfactant used as an emulsifier in the present invention, higher fatty acid soap, alkyl sulfate ester salt, polyoxyethylene alkyl ether sulfate, acyl N-methyl taurine salt, alkyl ether phosphate ester salt, N-acyl Amino acid salts and the like are exemplified.

  Examples of the nonionic surfactant used as an emulsifying agent in the present invention include glycerin monoesteria phosphate, polyethylene sorbitan ester, sorbitan fatty acid ester, polyhydric alcohol ester type, ethylene oxide / propylene oxide block copolymer, etc. .

  Emulsifiers particularly preferably used in the present invention are highly stable nonionic and anionic surfactants, in particular, higher fatty acid soaps, higher fatty acid soaps and nonionic surfactants, water-soluble polymers, protein interfaces Activators and the like are preferred.

  In addition, the gel of the present invention includes alkalis such as potassium hydroxide, sodium hydroxide and triethanolamine, various flavors, coloring materials, chelating agents such as EDTA, parabens, preservatives such as sorbic acid and isopropylmethylphenol, dibutyl hydride Various agents such as antioxidants such as kerosene toluene and vitamin E, buffering agents such as citric acid, sodium citrate, lactic acid and sodium lactate, vitamins, ultraviolet light absorbers, amino acids and whitening agents may be added if desired.

  As an emulsifying machine that can be used in the present invention, for example, the stirrer has a stator with several holes, and a rotating blade with a rotational speed of 500 rpm to 10,000 rpm, and the liquid is rotated by the rotating blade. It is preferred to be of the type which allows the blade to be sheared by passing through and sucking up from above.

  Recently, cosmetic users have become widespread and diverse, regardless of gender, from elementary school students to the elderly. As a result, cosmetic containers and their materials, functions, forms and designs are becoming more diverse. However, the basic performance required for cosmetic containers is from the user's side, the quality retention performance of the content, the functionality that is easy to use, and the economy, and from the manufacturer's side, the economy and the promotion effect It is. In the case of a conventional gel, a plastic or glass bottle may be used, but in the case of the present invention, a hydrogenated water having an oxidation reduction potential of -400 mV or less and a dissolved hydrogen content of 0.5 ppm to 1.5 ppm is used Therefore, containers made of materials that do not reduce the redox potential and the amount of dissolved hydrogen over time are preferred. Therefore, it is preferable to fill the gel of the present invention in an aluminum pouch, an aluminum can, or a glass bottle so that dissolved hydrogen does not escape.

Therefore, the above problem is solved by any means described in the following sections.
1. (1) Hydrogen with a gas pressure of 0.25 MPa and a gas flow rate of 0.1 to 1 liter / minute is injected into purified water to produce hydrogen with an oxidation reduction potential of -400 mV or less and a dissolved hydrogen content of 0.5 ppm to 1.5 ppm After the water-soluble polymer is uniformly dissolved in (2) the hydrogenated water, a part of the moisturizing agent, the antifading agent, the coloring agent and the chelating agent are added. Apart from the aqueous phase production process for producing the aqueous phase and (3) the aqueous phase production process, a surfactant is added to another moisturizing agent, heated at a predetermined temperature, and a preservative, a fragrance and the like are added thereto A gel including the steps of: preparing a surfactant solution; (4) gradually adding the aqueous phase to the surfactant solution while stirring; and (5) neutralizing the aqueous alkali solution. How to manufacture.

2. (1) an aqueous phase production step of producing an aqueous phase in which a part of a moisturizer, an antifading agent, a coloring agent, and a chelating agent are added after uniformly dissolving a water-soluble polymer in purified water; ) Separately from the aqueous phase production step, adding a surfactant to another moisturizing agent, heating at a predetermined temperature, adding an antiseptic agent, a perfume, etc. thereto to produce a surfactant solution; 3) A step of gradually adding the aqueous phase to the surfactant solution while stirring, a step of (4) a step of adding an alkaline aqueous solution for neutralization, and (5) a gas pressure of 0.25 MPa, a gas flow rate of 0. A method for producing a gel comprising a step of blowing in hydrogen at 1 to 1 liter / min to convert purified water into hydrogenated water having an oxidation reduction potential of -400 mV or less and a dissolved hydrogen content of 0.5 ppm to 1.5 ppm.

3. (1) Hydrogen is blown into and mixed with purified water at a gas pressure of 0.25 MPa and a gas flow rate of 0.1 to 1 liter / minute, and the diameter of the hydrogen produced by injecting from a porous element with a pore diameter of 2 μm to 120 μm is Hydrogenated water production process for producing hydrogenated water containing a large amount of mixed fine bubbles of 2 μm to 120 μm, an oxidation reduction potential of -400 mV or less, and a dissolved hydrogen content of 0.5 ppm to 1.5 ppm, (2) An aqueous phase manufacturing step of manufacturing an aqueous phase to which a part of a moisturizer, an antifading agent, a coloring agent and a chelating agent are added after uniformly dissolving a water-soluble polymer in hydrogen water; (3) the aqueous phase Separately from the production process, adding a surfactant to another moisturizing agent, heating at a predetermined temperature, adding an antiseptic agent, a fragrance, etc. thereto to produce a surfactant solution, and (4) surfactant Gradually adding the aqueous phase to the agent solution while stirring the (5) A method for producing a gel which comprises the step of adding an alkali aqueous solution neutralization.

4. (1) an aqueous phase production step of producing an aqueous phase in which a part of a moisturizer, an antifading agent, a coloring agent, and a chelating agent are added after uniformly dissolving a water-soluble polymer in purified water; ) Separately from the aqueous phase production step, adding a surfactant to another moisturizing agent, heating at a predetermined temperature, adding an antiseptic agent, a perfume, etc. thereto to produce a surfactant solution; 3) a step of gradually adding the aqueous phase to the surfactant solution while stirring, a step of (4) a step of adding an alkaline aqueous solution for neutralization, and (5) a purified water with a gas pressure of 0.25 MPa, a gas flow rate Hydrogen containing at a rate of 0.1 to 1 l / min. Hydrogen is mixed and blown out from a porous element with a pore size of 2 μm to 120 μm in a large amount as mixed microbubbles of 2 μm to 120 μm in diameter, and the redox potential is -400mV or less, 0.5 ppm to 1.5 ppm of dissolved hydrogen Method of making a gel comprising the step of converting the pressurized hydrogen water.

5. (1) Hydrogen with a gas pressure of 0.25 MPa and a gas flow rate of 0.1 to 1 liter / minute is injected into purified water to produce hydrogen with an oxidation reduction potential of -400 mV or less and a dissolved hydrogen content of 0.5 ppm to 1.5 ppm Hydrogenated water production process for producing water, (2) Water phase production process for adjusting the temperature to a predetermined temperature by adding a moisturizer and a surfactant to the above-mentioned hydrogenated water, (3) Another interface for oil components An oil phase production process of adding an activator and a flavor to adjust to a predetermined temperature, (4) a process of gradually adding an oil phase to an aqueous phase, (5) a process of emulsifying with an emulsifying device, (6) A method of producing a gel comprising degassing, filtration and cooling steps.

6. (1) An aqueous phase production step of adjusting the temperature to a predetermined temperature by adding a moisturizer and a surfactant to purified water, and (2) adjusting the temperature to a predetermined temperature by adding another surfactant and fragrance to the oil component Oil phase production step, (3) Step of gradually adding oil phase to water phase, (4) Step of emulsifying with emulsification device, (5) Gas pressure 0.25 MPa, gas flow rate 0.1 to 1 liter Hydrogen is blown at a rate of 1 / min to convert purified water into hydrogenated water having an oxidation reduction potential of -400 mV or less and a dissolved hydrogen content of 0.5 ppm to 1.5 ppm, (6) Degassing, filtration, and cooling steps How to make a gel containing.

7. (1) Hydrogen is blown into and mixed with purified water at a gas pressure of 0.25 MPa and a gas flow rate of 0.1 to 1 liter / minute, and the diameter of the hydrogen produced by injecting from a porous element with a pore diameter of 2 μm to 120 μm is Hydrogenated water production process for producing hydrogenated water containing a large amount of mixed fine bubbles of 2 μm to 120 μm, an oxidation reduction potential of -400 mV or less, and a dissolved hydrogen content of 0.5 ppm to 1.5 ppm, (2) Water phase manufacturing step of adjusting the temperature to a predetermined temperature by adding a moisturizer and surfactant to hydrogen water, (3) Oil phase adjusting to a predetermined temperature by adding another surfactant and fragrance to the oil A method of producing a gel comprising a production step, (4) a step of gradually adding to an oil phase and an aqueous phase, (5) a step of emulsifying with an emulsifying device, and (6) a degassing / filtering / cooling step.

8. (1) Water phase manufacturing process of adjusting the temperature to a predetermined temperature by adding a moisturizer and a surfactant to purified water, and (2) adding another surfactant and perfume to the oil to adjust the temperature to a predetermined temperature Oil phase production step, (3) step of gradually adding to oil phase and water phase, (4) step of emulsifying with an emulsifying device, (5) purified water, gas pressure 0.25 MPa, gas flow rate 0 1 to 1 liter / min. Hydrogen is blown in and mixed, and the hydrogen is produced by injecting from a porous element with a pore diameter of 2 μm to 120 μm in a large amount as mixed micro bubbles of 2 μm to 120 μm in diameter, and the redox potential is -A method for producing a gel including the steps of: converting into hydrogenated water having a dissolved hydrogen content of 0.5 ppm to 1.5 ppm or less and (6) degassing, filtration, and cooling steps.

9. 9. A method for producing a gel according to any one of the above 1 to 8, further comprising the addition of adding a colloidal platinum group element prior to the step of blowing hydrogen.

10. The gel manufactured by the method of any one of 1 to 9 above.

  According to the invention of claim 1, as water which is a basic component of the aqueous component of the gel, the redox potential very close to the redox reaction of the living body of the skin is -400 mV or less, and the amount of dissolved hydrogen is 0.5 ppm to 1.5 ppm It is possible to produce a hydration and moisturizing gel containing a large amount of hydrogen water.

  According to the invention of claim 2, it is possible to produce the same gel for hydration / moisturizing as that produced by the method described in claim 1 using as a starting material a commercially available gel into which components of the gel have been previously incorporated.

  According to the invention of claim 3, in addition to the effects according to claim 1, the water itself, which is a basic component of the aqueous component of the gel, has a function of enhancing the bioactivity of the skin and a cleansing action of the skin, A moisturizing gel can be produced.

  According to the invention of claim 4, the same fine mixed aeration and hydration gel as that produced by the method according to claim 3 is produced using as a starting material a commercially available gel into which components of the gel have been previously incorporated. Can.

  According to the invention of claim 5, as water which is a basic component of the aqueous component of the gel, the redox potential very close to the redox reaction of the living body of the skin is -400 mV or less, and the amount of dissolved hydrogen is 0.5 ppm to 1.5 ppm For example, it is possible to produce an oil gel etc. for washing and base (make-up removal) containing a large amount of hydrogen water.

  According to the invention of claim 6, the same gel as that produced by the method described in claim 5 using as a starting material a commercially available gel in which components of the gel are blended in advance is the same, for example, an oil gel etc. It can be manufactured.

  According to the invention of claim 7, in addition to the effect according to claim 5, the water itself which is the basic component of the aqueous component of the gel has a function of enhancing the bioactivity of the skin and the cleansing action of the skin. It is possible to produce an oily gel for foundation (make-up removal) and the like.

  According to the invention of claim 8, a commercially available gel in which the components of the gel are mixed in advance is used as a starting material, and the same fine mixed air-bubbled wash / base (make-up removal) oil gel is manufactured by the method described in claim 3. Etc. can be manufactured.

  According to the invention of claim 9, in addition to the effects of the invention of claims 1 to 8, the ability to eliminate free radicals such as active oxygen adhering to the skin can be provided.

  According to the invention of claim 10, the gel manufactured according to the invention of claims 1 to 9 can be targeted for commerce.

Hereinafter, the best mode for carrying out the invention will be described by way of examples.
[Measurement equipment used]
1. Oxidation reduction potential: Portable ORP meter "RM-20P" (registered trademark) (made by Toa D.K. industrial)
2. pH: Portable pH meter "HM-20P" (registered trademark) (made by Toa DK Corporation)
3. Dissolved hydrogen: "DHD1-1 type dissolved hydrogen meter" (registered trademark) (made by Toa DK Corporation)
4. Viscosity: "Viscotester VT-04F" (registered trademark) manufactured by Rion Corporation

[Production of Hydrogenated Water]
It is listed in the Japanese Pharmacopoeia using a tubular hydrogen water production system equipped with a raw water jet nozzle, a hydrogen gas jet nozzle, and an outlet for discharging the manufactured hydrogen water. Purified water (oxidation reduction potential = 357 mV, pH = 7.25 dissolved hydrogen amount = 3 ppb, water temperature = 13.2 ° C) Flow rate 10 liters / min, gas pressure at 0.25 MPa, flow rate 0 with gas pressure regulator Hydrogenated water was produced by injecting 100% hydrogen gas adjusted to 5 liters / minute. The amount of dissolved hydrogen in this hydrogenated water was 1.31 ppm, the redox potential was -615 mV, and the pH was 7.35.

[Manufacture of hydration and moisturizing gel]
First, 4 cc of a carboxyvinyl polymer as a water-soluble polymer and 2 cc of methyl cellulose are added to 840 cc of hydrogen water and dissolved, and then 80 cc of polyethylene glycol 1500 as a moisturizer, an appropriate amount of each of an antifading agent, a coloring agent and a chelating agent The aqueous phase was prepared by addition. Separately, 10 cc of polyoxyethylene and oleyl alcohol ether as surfactant are added to 70 cc of dipropylene glycol as moisturizer, and dissolved by heating at about 55 ° C. to dissolve, and preservative and perfume are added to this and oil phase Manufactured. The aqueous phase was gradually added to the oil phase while stirring, and then 1 cc of potassium hydroxide was added as an alkali to neutralize and stir. After degassing, filtering and filling into non-translucent glass bottles (100 cc / bottle), eight bottles were manufactured.

  The amount of dissolved hydrogen and the redox potential of eight gels produced were measured every 10 days for two months, and their changes over time were examined. As a result, all of them maintained the values at the time of production.

[Manufacture of mixed fine bubble-containing hydration and moisturizing gel]
A double tube having a diameter reducing structure, that is, a squeezing structure from the both ends toward the center inside the hydrogenated water producing apparatus used in Example 1, so that a negative pressure is formed at the throttling portion. A diffusion chamber having a structure was provided, and a porous element which was a sintered body of stainless steel with a thickness of 10 mm and a pore size of 2 μm was attached to the diffusion chamber.

  The purified water (oxidation-reduction potential = 357 mV, pH = 7. 25, dissolved hydrogen amount = 3 ppb, water temperature = 13.2 ° C) listed in the Japanese Pharmacopoeia The hydrogen gas is jetted from the hydrogen gas jet nozzle by adjusting the gas pressure to 0.25 MPa and the flow rate to 0.5 liter / minute with the gas pressure regulator while jetting the water pressure at 0.25 MPa and the water volume at 20 liters / minute. A mixed fluid of raw material water and hydrogen gas was formed, and was diffused into the diffusion chamber through the porous element, and the hydrogen water was taken out from the outlet.

  The produced hydrogen water had a water temperature of 13.5 ° C, an amount of dissolved hydrogen of 1.31 ppm, an oxidation reduction potential of -660 mV, a pH of 7.85, and contained a large amount of micro bubbles centered on 2 μm. .

  The experiment was conducted according to the same procedure as in Example 1 except that this hydrogen hydride water was used, to produce eight gels for mixed fine bubbled water supply and moisturizing gel.

  The amount of dissolved hydrogen and the redox potential of eight gels produced were measured every 10 days for two months, and their changes over time were examined. As a result, all of them maintained the values at the time of production.

[Manufacture of active oxygen erasable hydration and moisturizing gel containing platinum colloid]
[Production of Reactive Oxygen Scavenging Hydrogenated Water]
Platinum (Pt) -PVP (polyvinylpyrrolidone) colloid (4.0 wt%) was diluted 100 times with ultrapure water, and purified water listed in the Japanese Pharmacopoeia (oxidation-reduction potential = 357 mV, pH = 7.25 A platinum colloid solution was prepared by adding 1000 ppm of dissolved hydrogen amount = 3 ppb, water temperature = 13.2 ° C.) so that the concentration of platinum colloid is 0.4 ppm. Then, adjust the gas pressure to 0.25 MPa and the flow rate to 0.5 l / min with a gas pressure regulator and inject 100% hydrogen gas into the platinum colloid solution at a flow rate of 10 l / min for the platinum colloid solution Hydrogenated water was produced. The redox potential of this platinum colloid-containing hydrogenated water was -615 mV, and the pH was 7.35.

  The experiment was carried out in the same procedure as in Example 1 except that hydrogen colloid water containing platinum colloid was used, to produce eight active oxygen scavenging O / W burnishing gels containing platinum colloid.

  The amount of dissolved hydrogen and the redox potential of eight gels produced were measured every 10 days for two months, and their changes over time were examined. As a result, all of them maintained the values at the time of production.

[Measurement of free radical scavenging ability]
1. Measuring instrument used: Hitachi spectrophotometer 2. Reagents Used 2-1: Source of Free Radicals 1,1-Diphenyl-2-picrylhydrazyl (DPPH) was used as a free radical model. Although DPPH is a relatively stable free radical, it easily binds to other free radicals, and is therefore used to confirm the presence of free radicals generated by heat, radiation and the like, and to determine the concentration and the like. In the present invention, the free radical scavenging functional water of the present invention was used as a measure of the free radical scavenging ability by measuring the ability of DPPH to scavenge free radicals generated.

2-2: Preparation of DPPH solution 2-2-1: 100 μM-DPPH (50% ethyl alcohol solution)
0.0010 g of DPPH was precisely weighed and placed in a 50 ml measuring flask protected from light by aluminum foil. Then, about 25 ml of 99% ethanol was added and dissolved. After complete dissolution, the total volume was made up to 50 ml with ultrapure water. During the dissolution operation, the volumetric flask was completely shielded from light.
2-2-2: 25 μM-DPPH (50% ethyl alcohol solution)
3 ml of a 100 μM DPPH solution (50% ethyl alcohol solution) was taken and added to 9 ml of 50% ethanol.

[Measuring method]
2 ml of a 25 μM DPPH solution and 2 ml of the gel containing platinum colloid prepared in Example 8 were mixed in a test tube using a vortex mixer, stirred, and the absorbance was measured at a wavelength of 520 nm.

[Measurement result]
The absorbance at 520 nm of platinum colloid-containing hydrogenated water was 0.037, and that of ultrapure water as a control example was 0.123.
In the case of hydrogenated water containing Pt-PVP colloid solution, purple which is the color of DPPH radical faded and turned to yellow of diphenyl picryl hydrazine. On the other hand, in the case of ultrapure water, it did not fade immediately after addition of the Pt-PVP colloid solution, and faded after about 5 to 6 minutes. As a result of several experiments, it was confirmed that radicals of 2 ml of 25 μM-DPPH solution can be completely eliminated by 2 ml of hydrogen water and 10 μl of Pt-PVP colloid solution.

[Manufacture of oily gel for cleaning and base (make) removal]
First, 10 cc of sorbitol as a humectant and 5 cc of polyethylene glycol as a humectant and 5 cc of acylmethyltaurine as a surfactant were added to 8 cc of hydrogen water, and dissolved by heating to about 70 ° C. to produce an aqueous phase. In a separate step, add 12 cc of liquid paraffin as oil and 50 cc of glycerol tri-2-ethyl hexane ester, add 10 cc of polyoxyethylene octyldodecyl alcohol ether as surfactant and an appropriate amount of perfume and heat to about 70 ° C. The phase was manufactured. The oil phase was gradually added to the aqueous phase, emulsified with a homomixer, degassed, filtered and cooled, and a translucent oily gel was filled in a non-translucent glass container to prepare 10 pieces.

  The amount of dissolved hydrogen and the oxidation-reduction potential of 10 gels produced were measured every 10 days for 2 months, and their changes over time were examined. As a result, the total amount retained the value at the time of production.

[Manufacture of oil gel for washing with mixed fine bubbles and removing foundation (make)]
A double tube having a diameter reducing structure, that is, a squeezing structure from the both ends toward the center inside the hydrogenated water producing apparatus used in Example 1, so that a negative pressure is formed at the throttling portion. A diffusion chamber having a structure was provided, and a porous element which was a sintered body of stainless steel with a thickness of 10 mm and a pore size of 2 μm was attached to the diffusion chamber.

  The purified water (oxidation-reduction potential = 357 mV, pH = 7. 25, dissolved hydrogen amount = 3 ppb, water temperature = 13.2 ° C) listed in the Japanese Pharmacopoeia The hydrogen gas is jetted from the hydrogen gas jet nozzle by adjusting the gas pressure to 0.25 MPa and the flow rate to 0.5 liter / minute with the gas pressure regulator while jetting the water pressure at 0.25 MPa and the water volume at 20 liters / minute. A mixed fluid of raw material water and hydrogen gas was formed, and was diffused into the diffusion chamber through the porous element, and the hydrogen water was taken out from the outlet.

  The produced hydrogen water had a water temperature of 13.5 ° C, an amount of dissolved hydrogen of 1.31 ppm, an oxidation reduction potential of -660 mV, a pH of 7.85, and contained a large amount of micro bubbles centered on 2 μm. .

  An experiment was conducted in the same procedure as in Example 4 except that this hydrogen hydride water was used, to produce eight mixed fine bubble-containing water replenishment and moisturizing gels.

  The amount of dissolved hydrogen and the redox potential of eight gels produced were measured every 10 days for two months, and their changes over time were examined. As a result, all of them maintained the values at the time of production.

  In the gel of the present invention, water, which is a basic component of the aqueous component of the gel, is made into hydrogenated water having an oxidation reduction potential of -400 mV or less close to that of the human body, and a dissolved hydrogen content of 0.5 ppm to 1.5 ppm. Furthermore, molecular hydrogen can be converted to atomic hydrogen by containing a colloidal white metal element, and hydrogen can be contained as mixed fine bubbles with a diameter of 2 μm to 120 μm, so the basic performance of the gel (A) to supply moisture and moisturizing ingredients to the horny layer of the skin, to maintain a fresh, smooth and moist skin, and (b) to have an astringent action to temporarily tighten the skin and a function to suppress excessive sebum, Not only does it have an effect on cosmetic makeup with a refreshing feeling of use, (C) as light make-up and as dirt removal on bare skin, it is also in harmony with the skin from biological reaction theory, It has an action of eliminating free radicals such as active oxygen attached to the skin, water itself is excellent in uniformity and dispersibility, and has biological activity and cleansing action on the skin. Therefore, expansion of the application as a new gel is expected.

  In the gel of the present invention, hydrogen gas is blown into purified water at a gas pressure of 0.25 MPa and a gas flow rate of 0.1 to 1 liter / minute, so that the redox potential is -400 mV or less, and the amount of dissolved hydrogen is 0.5 ppm to 1. A new composition and performance can be obtained by using one previously prepared as 5 ppm hydrogenated water as water as the basic component of the gel and the other components, ie, the oil component and the surfactant, as desired. The gel market can be easily created.

  The gel of the present invention is a basic component of the aqueous component by blowing hydrogen gas at a gas pressure of 0.25 MPa and a gas flow rate of 0.1 to 1 liter / minute to the gel containing the aqueous component, the oil component and the surfactant. It can also be produced by converting purified water, which has a redox potential of -400 mV or less, into hydrogenated water with a dissolved hydrogen content of 0.5 ppm to 1.5 ppm, so starting from commercially available gels is also possible. Because it can, it is possible to easily create a gel market of new composition and performance.

Claims (10)

(1) Hydrogen with a gas pressure of 0.25 MPa and a gas flow rate of 0.1 to 1 liter / minute is injected into purified water to produce hydrogen with an oxidation reduction potential of -400 mV or less and a dissolved hydrogen content of 0.5 ppm to 1.5 ppm After the water-soluble polymer is uniformly dissolved in (2) the hydrogenated water, a part of the moisturizing agent, the antifading agent, the coloring agent and the chelating agent are added. Apart from the aqueous phase production process for producing the aqueous phase and (3) the aqueous phase production process, a surfactant is added to another moisturizing agent, heated at a predetermined temperature, and a preservative, a fragrance and the like are added thereto A gel including the steps of: preparing a surfactant solution; (4) gradually adding the aqueous phase to the surfactant solution while stirring; and (5) neutralizing the aqueous alkali solution. How to manufacture. (1) an aqueous phase production step of producing an aqueous phase in which a part of a moisturizer, an antifading agent, a coloring agent, and a chelating agent are added after uniformly dissolving a water-soluble polymer in purified water; ) Separately from the aqueous phase production step, adding a surfactant to another moisturizing agent, heating at a predetermined temperature, adding an antiseptic agent, a perfume, etc. thereto to produce a surfactant solution; 3) A step of gradually adding the aqueous phase to the surfactant solution while stirring, a step of (4) a step of adding an alkaline aqueous solution for neutralization, and (5) a gas pressure of 0.25 MPa, a gas flow rate of 0. A method for producing a gel comprising a step of blowing in hydrogen at 1 to 1 liter / min to convert purified water into hydrogenated water having an oxidation reduction potential of -400 mV or less and a dissolved hydrogen content of 0.5 ppm to 1.5 ppm. (1) Hydrogen is blown into and mixed with purified water at a gas pressure of 0.25 MPa and a gas flow rate of 0.1 to 1 liter / minute, and the diameter of the hydrogen produced by injecting from a porous element with a pore diameter of 2 μm to 120 μm is Hydrogenated water production process for producing hydrogenated water containing a large amount of mixed fine bubbles of 2 μm to 120 μm, an oxidation reduction potential of -400 mV or less, and a dissolved hydrogen content of 0.5 ppm to 1.5 ppm, (2) An aqueous phase manufacturing step of manufacturing an aqueous phase to which a part of a moisturizer, an antifading agent, a coloring agent and a chelating agent are added after uniformly dissolving a water-soluble polymer in hydrogen water; (3) the aqueous phase Separately from the production process, adding a surfactant to another moisturizing agent, heating at a predetermined temperature, adding an antiseptic agent, a fragrance, etc. thereto to produce a surfactant solution, and (4) surfactant Gradually adding the aqueous phase to the agent solution while stirring the (5) A method for producing a gel which comprises the step of adding an alkali aqueous solution neutralization. (1) an aqueous phase production step of producing an aqueous phase in which a part of a moisturizer, an antifading agent, a coloring agent, and a chelating agent are added after uniformly dissolving a water-soluble polymer in purified water; ) Separately from the aqueous phase production step, adding a surfactant to another moisturizing agent, heating at a predetermined temperature, adding an antiseptic agent, a perfume, etc. thereto to produce a surfactant solution; 3) a step of gradually adding the aqueous phase to the surfactant solution while stirring, a step of (4) a step of adding an alkaline aqueous solution for neutralization, and (5) a purified water with a gas pressure of 0.25 MPa, a gas flow rate Hydrogen containing at a rate of 0.1 to 1 l / min. Hydrogen is mixed and blown out from a porous element with a pore size of 2 μm to 120 μm in a large amount as mixed microbubbles of 2 μm to 120 μm in diameter, and the redox potential is -400mV or less, 0.5 ppm to 1.5 ppm of dissolved hydrogen Method of making a gel comprising the step of converting the pressurized hydrogen water. (1) Hydrogen with a gas pressure of 0.25 MPa and a gas flow rate of 0.1 to 1 liter / minute is injected into purified water to produce hydrogen with an oxidation reduction potential of -400 mV or less and a dissolved hydrogen content of 0.5 ppm to 1.5 ppm Hydrogenated water production process for producing water, (2) Water phase production process for adjusting the temperature to a predetermined temperature by adding a moisturizer and a surfactant to the above-mentioned hydrogenated water, (3) Another interface for oil components An oil phase production process of adding an activator and a flavor to adjust to a predetermined temperature, (4) a process of gradually adding an oil phase to an aqueous phase, (5) a process of emulsifying with an emulsifying device, (6) A method of producing a gel comprising degassing, filtration and cooling steps. (1) An aqueous phase production step of adjusting the temperature to a predetermined temperature by adding a moisturizer and a surfactant to purified water, and (2) adjusting the temperature to a predetermined temperature by adding another surfactant and fragrance to the oil component Oil phase production step, (3) Step of gradually adding oil phase to water phase, (4) Step of emulsifying with emulsification device, (5) Gas pressure 0.25 MPa, gas flow rate 0.1 to 1 liter Hydrogen is blown at a rate of 1 / min to convert purified water into hydrogenated water having an oxidation reduction potential of -400 mV or less and a dissolved hydrogen content of 0.5 ppm to 1.5 ppm, (6) Degassing, filtration, and cooling steps How to make a gel containing. (1) Hydrogen is blown into and mixed with purified water at a gas pressure of 0.25 MPa and a gas flow rate of 0.1 to 1 liter / minute, and the diameter of the hydrogen produced by injecting from a porous element with a pore diameter of 2 μm to 120 μm is Hydrogenated water production process for producing hydrogenated water containing a large amount of mixed fine bubbles of 2 μm to 120 μm, an oxidation reduction potential of -400 mV or less, and a dissolved hydrogen content of 0.5 ppm to 1.5 ppm, (2) Water phase manufacturing step of adjusting the temperature to a predetermined temperature by adding a moisturizer and surfactant to hydrogen water, (3) Oil phase adjusting to a predetermined temperature by adding another surfactant and fragrance to the oil A method of producing a gel including a production step, (4) a step of gradually adding to an oil phase and an aqueous phase, (5) a step of emulsifying with an emulsifying device, and (5) a degassing / filtering / cooling step. (1) Water phase manufacturing process of adjusting the temperature to a predetermined temperature by adding a moisturizer and a surfactant to purified water, and (2) adding another surfactant and perfume to the oil to adjust the temperature to a predetermined temperature Oil phase production step, (3) step of gradually adding to oil phase and water phase, (4) step of emulsifying with an emulsifying device, (5) purified water, gas pressure 0.25 MPa, gas flow rate 0 1 to 1 liter / min. Hydrogen is blown in and mixed, and the hydrogen is produced by injecting from a porous element with a pore diameter of 2 μm to 120 μm in a large amount as mixed micro bubbles of 2 μm to 120 μm in diameter, and the redox potential is -A method for producing a gel including the steps of: converting into hydrogenated water having a dissolved hydrogen content of 0.5 ppm to 1.5 ppm or less and (6) degassing, filtration, and cooling steps. A method of making a gel according to any of the preceding claims, further comprising the addition of adding a colloidal platinum group element prior to the step of blowing hydrogen. The gel manufactured by the method of any one of Claims 1-9.