JP2007282537A - Method for producing roasted coffee bean reduced in acrylamide and increased in chlorogenic acids, and food and beverage comprising the roasted coffee bean - Google Patents

Method for producing roasted coffee bean reduced in acrylamide and increased in chlorogenic acids, and food and beverage comprising the roasted coffee bean Download PDF

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JP2007282537A
JP2007282537A JP2006111522A JP2006111522A JP2007282537A JP 2007282537 A JP2007282537 A JP 2007282537A JP 2006111522 A JP2006111522 A JP 2006111522A JP 2006111522 A JP2006111522 A JP 2006111522A JP 2007282537 A JP2007282537 A JP 2007282537A
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coffee beans
roasting
roasted
acrylamide
roasted coffee
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Tadaaki Sakano
忠明 酒野
Motohiko Sugiura
元彦 杉浦
Shigeyoshi Fujii
繁佳 藤井
Kenji Yamamura
健司 山村
Makoto Ikezaka
誠 池阪
Tsutomu Haruyama
務 春山
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Ajinomoto AGF Inc
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Ajinomoto General Foods Inc
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Abstract

<P>PROBLEM TO BE SOLVED: To provide a method for producing roasted coffee beans reduced in acrylamide and increased in chlorogenic acids without using/adding any other materials than coffee beans. <P>SOLUTION: The method for producing roasted coffee beans comprises roasting coffee beans with superheated steam so as to reduce the content of acrylamide and increase the content of chlorogenic acids. Roasted coffee beans have a reduced content of acrylamide and an increased content of chlorogenic acids. The food and drink served as health-appealing coffee is obtained by using roasted coffee beans reduced in acrylamide and increased in chlorogenic acids. <P>COPYRIGHT: (C)2008,JPO&INPIT

Description

本発明は、コーヒー豆以外の原材料を使用・添加することなく、通常焙煎コーヒー豆よりもアクリルアミドの含量を減少させ及びクロロゲン酸類の含量を増加させた、焙煎コーヒー豆の製造方法に関する。 The present invention relates to a method for producing roasted coffee beans in which the content of acrylamide and the content of chlorogenic acids are increased as compared with normal roasted coffee beans without using or adding raw materials other than coffee beans.

コーヒーは世界で最も人気のある飲料のひとつであり、コーヒーは何千年もの間楽しまれてきた。2002年4月、スウェーデン国立食品庁(Swedish National Food Administration)及びストックホルム大学(Stockholm University)の研究者は、発癌性化学物質のおそれのあるアクリルアミドが、加熱処理を受ける食品及び飲料の多くの種類に形成されることを発表した。焙煎したコーヒー豆にもアクリルアミドの存在が指摘されている。アクリルアミドは、動物実験においては食品中の他の発癌性物質と同様の発癌能力を有するが、ヒトに対しての発癌リスクは未知である。アクリルアミドについては、限られたヒトのデータしか得られておらず、これらはアクリルアミド摂取による癌の危険性について何の証拠も提供するものではない。しかしながら、アクリルアミドの低減は、世界的規模で求められている実態がある。日本でも厚生労働省から産業界に対して、アクリルアミド生成を抑制する製造条件等の検討を早急に実施するよう要請されている。   Coffee is one of the most popular beverages in the world and has been enjoyed for thousands of years. In April 2002, researchers at the Swedish National Food Administration and Stockholm University found that acrylamide, a potentially carcinogenic chemical, was added to many types of foods and beverages that were heat-treated. Announced that it will be formed. The presence of acrylamide has also been pointed out in roasted coffee beans. Acrylamide has a carcinogenic potential similar to other carcinogenic substances in food in animal experiments, but the risk of carcinogenesis for humans is unknown. Only limited human data are available for acrylamide, and they do not provide any evidence about the risk of cancer from acrylamide intake. However, there is an actual situation that reduction of acrylamide is required on a global scale. In Japan as well, the Ministry of Health, Labor and Welfare has requested the industry to urgently consider manufacturing conditions that suppress acrylamide production.

一方、クロロゲン酸類は、コーヒー豆中に含まれるポリフェノールの一種であり、生コーヒー豆抽出物由来のクロロゲン酸類を含む食品の摂取による人体への生理学的改善効果として以下の報告がある。約500mg/日の摂取で胃酸分泌抑制による消化性改善効果、400〜1000mg/日の摂取で血糖値上昇抑制効果及び、140〜280mg/日の摂取で血圧上昇抑制効果により有効性が確認されている。   On the other hand, chlorogenic acids are a kind of polyphenols contained in coffee beans, and the following reports have been made on the physiological improvement effect on the human body due to the intake of food containing chlorogenic acids derived from raw coffee bean extract. Efficacy is confirmed by digestive improvement effect by suppressing gastric acid secretion at intake of about 500 mg / day, suppressive effect on increase in blood glucose level by intake at 400 to 1000 mg / day, and suppressive effect on blood pressure by intake at 140 to 280 mg / day Yes.

更に、クロロゲン酸類を必須成分として含有するコーヒーノキ種子抽出物を用いた急性毒性試験でLD50は2000mg/kg以上であると判定されており、安全性においても非常に高いことが確認されている。   Furthermore, LD50 was determined to be 2000 mg / kg or more in an acute toxicity test using a coffee seed extract containing chlorogenic acids as an essential component, and it was confirmed that the safety was very high.

コーヒー生豆には、種々のクロロゲン酸類が含まれるが、クロロゲン酸類としてモノカフェオイルキナ酸、フェルラキナ酸及びジカフェオイルキナ酸の三種を含有する。ここでモノカフェオイルキナ酸としては、3−カフェオイルキナ酸、4−カフェオイルキナ酸及び5−カフェオイルキナ酸の異性体が存在するが、本明細書において「クロロゲン酸類」と云う場合は、上述の化合物の総称として用いるものとする。   The green coffee beans contain various chlorogenic acids, and as the chlorogenic acids, three kinds of monocaffeoylquinic acid, ferlaquinic acid and dicaffeoylquinic acid are contained. Here, as mono-caffeoylquinic acid, there are isomers of 3-caffeoylquinic acid, 4-caffeoylquinic acid, and 5-caffeoylquinic acid. In this specification, the term “chlorogenic acids” is used. And used as a general term for the above-mentioned compounds.

通常焙煎コーヒーにおいてアクリルアミドが含まれることへの懸念を示す人は、凡そ健康や食品に含まれる健康障害に対して疑わしい成分のみならず、栄養機能性成分に対する関心が高く、コーヒー豆中にポリフェノールの一種であるクロロゲン酸類の摂取にも関心を持つことが容易に推測される。このような消費者のニーズにこたえるため、より健康危害へのおそれのない、或いはより機能性のある成分を含む焙煎コーヒー豆を含むコーヒー商品の登場が待ち望まれていた。   Those who are concerned about the inclusion of acrylamide in roasted coffee usually have high interest in nutritional functional ingredients as well as suspicious ingredients for health and health problems in foods, and polyphenols in coffee beans It is easily presumed that they are also interested in the intake of chlorogenic acids, which is a type of the above. In order to meet such consumer needs, there has been a long-awaited appearance of coffee products including roasted coffee beans that contain ingredients that are less likely to be a health hazard or that have more functionality.

コーヒー生豆は、通常250〜400℃の温度範囲の熱風を用いて焙煎される。その焙煎時間や焙煎のスピードが、コーヒーの風味特性のみならずその成分組成においても重大な影響を与える。コーヒー豆中のアクリルアミドは、焙煎の初期段階において顕著に生成され、その後焙煎工程の終了に向かってアクリルアミドの分解が支配的になることが知られている。コーヒー豆の焙煎とアクリルアミド含量の推移の一般的な例を図1に示す。図1より、浅煎りに焙煎したコーヒー豆は、焙煎の進行した豆より多くのアクリルアミドが含まれることになる。しかしながら、アクリルアミドを減少させるための手段として、焙煎をより深煎りにすることは、苦味や焦げ臭の増加といった風味上の変化をもたらす。
一方、クロロゲン酸類は、コーヒー生豆に5〜10%程度ふくまれるが、焙煎と共に著しく減少し、浅煎りに焙煎したコーヒー豆は、深煎りの豆より顕著に多くのクロロゲン酸類が含まれることが知られている。また、同じ焙煎度合いであっても焙煎時間が長いと分解反応により減少する。焙煎コーヒー豆中のクロロゲン酸類を増加させる手段として、より焙煎を浅煎りにし短時間の焙煎を行うことは、不快な酸味や生豆臭の増加といった風味上必ずしも好ましくない作用をもたらす。
Green coffee beans are usually roasted using hot air in the temperature range of 250 to 400 ° C. The roasting time and roasting speed have a significant influence not only on the flavor characteristics of coffee but also on the composition of the ingredients. It is known that acrylamide in coffee beans is prominently produced in the initial stage of roasting, and then the degradation of acrylamide becomes dominant toward the end of the roasting process. A typical example of coffee beans roasting and the transition of acrylamide content is shown in FIG. From FIG. 1, coffee beans roasted shallowly contain more acrylamide than beans that have been roasted. However, deeper roasting as a means for reducing acrylamide results in flavor changes such as increased bitterness and burnt odor.
On the other hand, although chlorogenic acids are included in green coffee beans by about 5 to 10%, it decreases significantly with roasting, and coffee beans roasted in shallow roast contain significantly more chlorogenic acids than deep roasted beans. It is known. Moreover, even if the roasting degree is the same, if the roasting time is long, it decreases due to the decomposition reaction. As a means for increasing chlorogenic acids in roasted coffee beans, performing roasting for a short time by further roasting brings about an unfavorable effect on flavor such as an unpleasant acidity and an increase in raw bean odor.

焙煎したコーヒー豆のアクリルアミドの量を減らす方法としては、コーヒー生豆をアスパラキナーゼを含むアスパラギン還元酵素で処理する工程を実施し、その後加熱調理或いはコーヒー豆を焙煎する方法も開示されている。しかしながら、これらの方法は、酵素といった原材料をコーヒー豆に添加・処理する工程が必要であり、コーヒー豆以外の原材料がたとえ僅かであれ添加され、原材料コーヒー豆100%でないことに懸念を示す人に受け入れられないことへの問題が残る。   As a method for reducing the amount of acrylamide in roasted coffee beans, a method of treating green coffee beans with an asparagine reductase containing asparakinase and then cooking or roasting coffee beans is also disclosed. . However, these methods require a process of adding and processing raw materials such as enzymes to coffee beans, and those who are concerned that raw materials other than coffee beans are added, even if only a small amount is not 100% raw coffee beans. The problem of being unacceptable remains.

また、過熱水蒸気を用いてコーヒー豆を焙煎する方法において、以下の先行文献があるが、これらにおいてアクリルアミドの低減がなされる記述は見当たらない。また、クロロゲン酸類を強化する方法に関しても見当たらない。
特表昭63−502319 特開2003−346362 特開平8−92−57 特開2004−283062号 特開2006−503592号 特開平1−256347号 特開平5−168410号 特開平6−046755号 特開平6−030754号 特開平10−234345号 食品中のアクリルアミドの健康への影響についての国連食糧農業機関/世界保健機関合同専門家会合報告書(FAO/WHO Consultation on the Health Implications of Acrylamide in Food: Summary Report)、スイスのジュネーブ、2002年6月25〜27日。 斎藤郁夫ら、医学と薬学、47(1):67-74,2002、生コーヒー豆抽出物配合飲料のヒト血圧に及ぼす影響 吉田 充、外6名、“日本で市販されている加工食品中のアクリルアミドの分析”、日本食品科学工学会誌、2002年12月、第49巻、第12号、p.822−825 H. Guenther, "Status of research on acryl amide formation during theroasting of coffee", Acryl amide status report, December 2004, CIAA, pp.38-43 中林敏郎ら、「コーヒーの焙煎の化学と技術」、弘学出版、p.52−54
Moreover, in the method of roasting coffee beans using superheated steam, there are the following prior literatures, but there is no description of reduction of acrylamide in these. There is also no method for strengthening chlorogenic acids.
Special Table Sho 63-502319 JP 2003-346362 A JP-A-8-92-57 JP 2004-283062 A JP 2006-503592 A JP-A-1-256347 JP-A-5-168410 JP-A-6-046755 JP-A-6-030754 JP-A-10-234345 FAO / WHO Consultation on the Health Implications of Acrylamide in Food: Summary Report on Health Effects of Acrylamide in Food, Geneva, Switzerland, June 2002 Month 25-27. Ikuo Saito et al., Medicine and pharmacy, 47 (1): 67-74,2002, Effects of beverages containing fresh coffee bean extract on human blood pressure Mitsuru Yoshida and 6 others, “Analysis of acrylamide in processed foods marketed in Japan”, Journal of Japanese Society for Food Science and Technology, December 2002, Vol. 49, No. 12, p. 822-825 H. Guenther, "Status of research on acryl amide formation during theroasting of coffee", Acryl amide status report, December 2004, CIAA, pp.38-43 Toshiro Nakabayashi et al., “Chemistry and Technology of Coffee Roasting”, Kogaku Publishing, p. 52-54

焙煎したコーヒー製品中に一般的に見出される含量でのアクリルアミドをヒトが消費した結果、どんな健康への影響をもたらすことがあるのかを評価するには慎重かつ十分な研究が必要であるが、アクリルアミドを低減するために、酵素のようなコーヒー豆以外の原材料を添加するという事実に対し消費者が安全性に懸念を表明するが故に、コーヒー豆以外の原材料を使用・添加することなく、通常焙煎コーヒー豆よりもアクリルアミドの含量が減少した焙煎コーヒー豆を提供することが、本発明の目的である。また同時に、焙煎により著しく減少しうるクロロゲン酸類を低減させることなくコーヒー豆を焙煎する方法を提供することもまた、本発明の目的である。   Careful and thorough research is required to assess what human health consequences may result from human consumption of acrylamide in a content commonly found in roasted coffee products, Without the use or addition of ingredients other than coffee beans, because consumers express safety concerns over the fact that ingredients other than coffee beans such as enzymes are added to reduce acrylamide. It is an object of the present invention to provide roasted coffee beans that have a reduced acrylamide content than roasted coffee beans. At the same time, it is also an object of the present invention to provide a method for roasting coffee beans without reducing chlorogenic acids that can be significantly reduced by roasting.

本発明者は、コーヒー豆以外の原材料を使用・添加することなく、通常焙煎法よりも焙煎コーヒー豆のアクリルアミド含量の生成を抑制すべく種々検討したところ、過熱水蒸気を用いて加圧下で焙煎し、加水分解反応を早めることで、アクリルアミドの前駆物質に変化する生成反応を抑制し、水蒸気以外の熱源、例えば一般的な熱風式や直火加熱により得られる同じ焙煎時間・焙煎色に調製した焙煎コーヒー豆と比べ、焙煎コーヒー豆中のアクリルアミドの生成が低減されるということを見出した。更には、驚くべきことに、過熱水蒸気での焙煎を行なうことでクロロゲン酸類の分解反応の抑制にも効果的であることを見出し、本発明を完成させた。   The present inventor has made various studies to suppress the production of acrylamide content of roasted coffee beans rather than the usual roasting method without using / adding raw materials other than coffee beans, and under pressure using superheated steam. By roasting and speeding up the hydrolysis reaction, it suppresses the formation reaction that changes to the precursor of acrylamide, and the same roasting time and roasting obtained by heat sources other than water vapor, for example, general hot air type or direct heating We have found that the production of acrylamide in roasted coffee beans is reduced compared to roasted coffee beans prepared in color. Furthermore, surprisingly, it has been found that roasting with superheated steam is effective in suppressing the decomposition reaction of chlorogenic acids, and the present invention has been completed.

過熱水蒸気を用いる利点は多い。これらの利点には:(a)それが全く毒性のない物質であること;(b)それの持つ熱量でもって、一般に望ましくない副反応を生ずることなくアクリルアミドの含量が低減された焙煎したコーヒー豆が得られること、である。   There are many advantages to using superheated steam. These advantages include: (a) it is a completely non-toxic substance; (b) roasted coffee with a reduced amount of acrylamide with its calorific value, generally without causing undesirable side reactions. The beans are obtained.

本明細書で引用されるすべての文献は、その関連部分において本明細書に参考として組み込まれており、いかなる文献の引用も、それが本発明に関連する先行技術であるとの容認として解釈すべきでない。また、本明細書で使用するとき、指示がない限り、パーセンテージ(%)はすべて重量によるものである。   All references cited herein are incorporated herein by reference in their relevant parts, and any citation of any reference shall be construed as an admission that it is prior art relevant to the present invention. Should not. Also, as used herein, all percentages (%) are by weight unless otherwise indicated.

本発明の様態は次の通りである。
1.コーヒー豆を、過熱水蒸気を用いた加圧下で焙煎することを特徴とする、通常焙煎コーヒー豆よりもアクリルアミドの含量が少なく、かつクロロゲン酸の含量の多い焙煎コーヒー豆を製造する方法。
2.過熱水蒸気で焙煎する際の圧力が1.0barG〜20barGであることを特徴とする、上記1に記載の製造方法。
3.前記焙煎コーヒー豆中のアクリルアミドの含量が通常焙煎コーヒー豆を基準として10%〜100%減少しており、かつクロロゲン酸の含量が10%〜100%増加していることを特徴とする、上記1又は2のいずれか一項に記載の製造方法。
4.焙煎色5Lu以下で、焙煎コーヒー豆中のアクリルアミド含量が0〜180μg/kgかつクロロゲン酸類含量が7〜29g/kgである、請求項1〜3のいずれか一項に記載の方法で製造した焙煎コーヒー豆。
5.焙煎色5〜10Luで、アクリルアミド含量が0〜220μg/kgかつクロロゲン酸類含量が13〜43g/kgである、上記1〜3のいずれか一項に記載の方法で製造した焙煎コーヒー豆。
6.焙煎色10〜25Luで、焙煎コーヒー豆中のアクリルアミド含量が0〜280μg/kgかつクロロゲン酸類含量が18〜60g/kgである、請求項1〜3のいずれか一項に記載の方法で製造した焙煎コーヒー豆。上記1〜3のいずれか一項に記載した製造方法により製造した焙煎コーヒー豆。
7.上記1〜6に記載の焙煎コーヒー豆を含む飲食物。
The mode of the present invention is as follows.
1. A method for producing roasted coffee beans having a lower content of acrylamide and a higher content of chlorogenic acid than normal roasted coffee beans, characterized by roasting coffee beans under pressure using superheated steam.
2. 2. The production method according to 1 above, wherein the pressure when roasting with superheated steam is 1.0 barG to 20 barG.
3. The acrylamide content in the roasted coffee beans is usually reduced by 10% to 100% based on the roasted coffee beans, and the chlorogenic acid content is increased by 10% to 100%, The manufacturing method as described in any one of said 1 or 2.
4). Manufactured by the method according to any one of claims 1 to 3, wherein the roasted color is 5Lu or less, the acrylamide content in the roasted coffee beans is 0 to 180 µg / kg, and the chlorogenic acid content is 7 to 29 g / kg. Roasted coffee beans.
5). Roasted coffee beans produced by the method according to any one of the above 1 to 3, having a roasting color of 5 to 10 Lu, an acrylamide content of 0 to 220 μg / kg and a chlorogenic acid content of 13 to 43 g / kg.
6). The method according to claim 1, wherein the roasted color is 10 to 25 Lu, the acrylamide content in the roasted coffee beans is 0 to 280 μg / kg, and the chlorogenic acid content is 18 to 60 g / kg. Produced roasted coffee beans. Roasted coffee beans produced by the production method described in any one of 1 to 3 above.
7). Food and drink containing the roasted coffee beans according to 1 to 6 above.

以下に発明の詳細を説明する。
本発明に使用するコーヒー生豆の種類は、特に制限されるものではなく、アラビカ種、ロブスタ種、リベリカ種等のものが挙げられる。複数の種類をブレンドした豆を用いてもよい。
本発明において「通常焙煎コーヒー豆」とは、従来製法である熱風又は直火加熱方式により、本発明の製造方法と同じ焙煎時間焙煎を行うことにより得た、同じ焙煎色の焙煎コーヒー豆のことを指すものとする。
本発明において、過熱水蒸気で焙煎する際の圧力とは、焙煎すべきコーヒー豆を入れた焙煎室の圧力のことであり、1.0barG〜20barGとすることが好ましい。
本発明におけるコーヒー豆の焙煎色については、後に詳細に述べる。
Details of the invention will be described below.
The kind of green coffee beans used in the present invention is not particularly limited, and examples include arabica, Robusta, and Riberica. You may use the bean which blended several kinds.
In the present invention, “normally roasted coffee beans” means roasting with the same roasting color obtained by performing roasting for the same roasting time as in the production method of the present invention by hot air or a direct heating method that is a conventional manufacturing method It refers to the green coffee beans.
In the present invention, the pressure when roasting with superheated steam is the pressure of the roasting chamber containing the coffee beans to be roasted, and is preferably 1.0 barG to 20 barG.
The roasted color of coffee beans in the present invention will be described in detail later.

本発明によれば、コーヒー豆以外の原材料使用・添加することなく、焙煎したコーヒー豆中のアクリルアミドの減少した含量を有する及び又はクロロゲン酸類の増加した含量を有する焙煎したコーヒー豆を消費者に供することができる。   According to the present invention, roasted coffee beans having a reduced content of acrylamide and / or an increased content of chlorogenic acids in roasted coffee beans without the use or addition of ingredients other than coffee beans Can be used.

以下、本発明の実施の形態について説明する。
コーヒー豆は密閉された圧力容器の中に取り付けられた回転する焙煎室に投入され流動する。過熱水蒸気は焙煎室内に挿入されたノズルにより流動するコーヒー豆に吹き付けられコーヒー豆を加圧下で焙煎する。コーヒー豆の流動化の方法は、特に制限されるものではないが、均一に焙煎反応が行われるように過熱水蒸気の供給・循環によりコーヒー豆を流動化させても良い。
Embodiments of the present invention will be described below.
The coffee beans flow into a rotating roasting chamber mounted in a sealed pressure vessel. The superheated steam is sprayed on the flowing coffee beans by a nozzle inserted in the roasting chamber, and the coffee beans are roasted under pressure. The method of fluidizing the coffee beans is not particularly limited, but the coffee beans may be fluidized by supplying and circulating superheated steam so that the roasting reaction is uniformly performed.

焙煎室内のコーヒー豆の温度が所定の温度に達したら過熱水蒸気の供給を止め、圧力容器内の蒸気を常圧付近まで拭き取り焙煎を終了させる。大気圧下の容器内に排出後、直ちに冷却水を添加し同時に室温以下の空気を送り込み、流動させながら焙煎したコーヒー豆の温度を急激に50℃以下に低下させる。   When the temperature of the coffee beans in the roasting chamber reaches a predetermined temperature, the supply of superheated steam is stopped, and the steam in the pressure vessel is wiped to near normal pressure to finish roasting. Immediately after discharging into a container under atmospheric pressure, cooling water is added and air below room temperature is sent at the same time, and the temperature of roasted coffee beans is rapidly lowered to 50 ° C. or less while flowing.

過熱水蒸気を用いた6.5〜20barGの加圧下でコーヒー豆を予備焙煎した後に過熱水蒸気を用い1.0barGの加圧のもとで最終焙煎を行なう2段階で実施しても良い。   Alternatively, the coffee beans may be pre-roasted under pressure of 6.5 to 20 barG using superheated steam, and then the final roasting may be performed under pressure of 1.0 barG using superheated steam.

前記加熱温度は、200〜400℃であるが、過熱水蒸気を焙煎に適する温度にするという観点から、好ましくは250〜320℃、より好ましくは260〜300℃である。焙煎圧力は、加水分解を促進する上で1.0barG以上であることが必要であるが、焙煎コーヒー豆の風味の観点から焙煎圧力は20barG以下が好ましい。焙煎時間は、焙煎度合いによっても変わるが3〜15分の間で行なうことが出来る。   Although the said heating temperature is 200-400 degreeC, from a viewpoint of making superheated steam the temperature suitable for roasting, Preferably it is 250-320 degreeC, More preferably, it is 260-300 degreeC. The roasting pressure needs to be 1.0 barG or more in order to promote hydrolysis, but the roasting pressure is preferably 20 barG or less from the viewpoint of the flavor of the roasted coffee beans. The roasting time can be 3 to 15 minutes although it varies depending on the roasting degree.

本発明において、焙煎したコーヒー豆中のアクリルアミドの含量、クロロゲン酸類の含量に関して、低減、増加した割合を言う場合、それぞれ、同じオリジンのコーヒー生豆を熱風又は直火加熱による通常焙煎によって、本発明の方法と同じ焙煎時間焙煎し、同じ焙煎色に調製した焙煎コーヒー豆中のアクリルアミドの含量、クロロゲン酸類の含量を対照とする。   In the present invention, when the ratio of acrylamide and chlorogenic acids in roasted coffee beans is reduced or increased, the ratio of the same origin of green coffee beans by normal roasting with hot air or direct heating is used. The content of acrylamide and the content of chlorogenic acids in roasted coffee beans roasted at the same roasting time as in the method of the present invention and prepared in the same roast color are used as controls.

ここでいう「焙煎度」とは、内部640nmフィルターを有するDr.LangeのColor Reflectance Meter ModelLK−100(Dr.LangeGmbH,ドイツ、デュッセルドルフ)を用いた、焙煎コーヒー豆の粉砕サンプルの可視光線反射率を用いて、間接的に算出される焙煎色のことである。焙煎色は“Lu”単位で表記され、Luの値が小さいほど焙煎色が暗色であることを表す。   As used herein, “roasting degree” refers to Dr. Roast color calculated indirectly using the visible light reflectance of a ground sample of roasted coffee beans using Lang's Color Reflectance Meter Model LK-100 (Dr. LangeGmbH, Dusseldorf, Germany). . The roasting color is expressed in “Lu” units, and the smaller the value of Lu, the darker the roasting color.

コーヒー豆は、粉砕度700〜800μを得るように、ベンチトップ・コーヒーグラインダー(Modern Process Equipment Co.,イリノイ州、シカゴ)によって粉砕する。次に、粉砕コーヒー・サンプルをDr.Langeの反射率計を備えた、表面を均一にならすためのペトリ皿に緩く注入する。次に、ナイフなどを用いて、サンプル上に平面を得る。次に、ペトリ皿を反射率計の下部に配置される引き出し部に入れ、この機器の測定モードにて、反射率測定値を表示させる。反射率値が低ければ低いほど、焙煎色は暗色になる。
(分析方法)
1.食品中のアクリルアミドを測定する方法
[アクリルアミド測定方法]
前出、非特許文献3記載の実験方法に準じて行った。詳細を以下に記す。
1)内標準物質の合成
RaneyR Copper(Aldrich社製)5gにアクリロニトリル−d3(99.5%,C/D/NIsotope Inc.)水溶液(1g/30ml)を加え、窒素雰囲気下、80℃で3時間攪拌した。反応液を吸引ろ過し、凍結乾燥し、アクリルアミド−d3を無色固体として得た。この一部を昇華精製した純度99%以上の純品を内標準物質として用いた。
2)抽出操作
フードプロセッサーで粉砕した試験試料約50gを容量500mlの共栓三角フラスコに精密に量り採り、アクリルアミド−d3水溶液500μlを添加し、5分間振り混ぜた。水300〜400mlを加え、ポリトロン・ホモジナイザー(PT2100Model DA2120/2;KINEMATICアクリルアミドG)で内容物が均一になるまで1〜3分間破砕した後、粉砕物の一部を容量50mlの遠心管に取り、48000×gで20分間遠心分離した。
The coffee beans are ground by a bench top coffee grinder (Moden Process Equipment Co., Chicago, Ill.) To obtain a grinding degree of 700-800μ. Next, the ground coffee sample is dr. Loosely pour into a Petri dish with a Lange reflectometer to homogenize the surface. Next, a plane is obtained on the sample using a knife or the like. Next, the Petri dish is placed in a drawer arranged at the lower part of the reflectometer, and the measured reflectance value is displayed in the measurement mode of the instrument. The lower the reflectance value, the darker the roast color.
(Analysis method)
1. Method for measuring acrylamide in foods [Method for measuring acrylamide]
The experiment was performed according to the experimental method described in Non-Patent Document 3 above. Details are described below.
1) Synthesis of internal standard substance Acrylonitrile-d3 (99.5%, C / D / NIsotope Inc.) aqueous solution (1 g / 30 ml) was added to 5 g of RaneyR Copper (manufactured by Aldrich), and 3% at 80 ° C. under a nitrogen atmosphere. Stir for hours. The reaction solution was suction filtered and freeze-dried to obtain acrylamide-d3 as a colorless solid. A pure product with a purity of 99% or more obtained by sublimation purification was used as an internal standard substance.
2) Extraction operation About 50 g of the test sample pulverized by a food processor was accurately weighed into a 500 ml stoppered Erlenmeyer flask, and 500 μl of an acrylamide-d3 aqueous solution was added and shaken for 5 minutes. After adding 300-400 ml of water and crushing with a Polytron homogenizer (PT2100 Model DA2120 / 2; KINEMATIC Acrylamide G) for 1 to 3 minutes, a part of the pulverized product is taken into a 50 ml centrifuge tube. Centrifugation at 48000 xg for 20 minutes.

上澄み液2mlをプラスチックチューブ1本に分注し、−30℃に凍結後、解凍、再遠心(21700×g、10分間)した。その遠心上澄み液全量をメタノール1ml、水2mlでコンディショニングした固相抽出カートリッジ(ISOLUTEMultimodeTM,500mg,International Sorbent Technology Ltd.)に負荷し、水で溶出を行った。試料負荷後、最初の1mlを捨て、3mlをガスクロマト質量分析(GC−MS)用試料溶液として採取した。
3)GC−MSによる測定
分析用試料溶液3mlを氷浴中で冷却し、臭素化試薬(臭化カリウム 15.2g、臭化水素水0.8ml、臭素水5ml、水60ml)を臭素の色が残るまで加え、氷浴上1時間放置した。1.0mol/Lチオ硫酸ナトリウム水溶液を添加し、過剰の臭素を還元、消失させ、酢酸エチル4.0mlで抽出した。抽出液を硫酸ナトリウム(無水)で脱水し、遠心エバポレーターを用いて30℃で大部分の溶媒を減圧留去した。完全に乾固する前にGC−MS分析用ミクロ試料管へ移し替え、さらに遠心エバポレーターで約5分間減圧遠心して乾固させた。この試料管を4℃に保管し、分析直前に25μlの酢酸エチルで溶解した。
2 ml of the supernatant was dispensed into one plastic tube, frozen at −30 ° C., thawed and recentrifuged (21700 × g, 10 minutes). The total amount of the centrifugal supernatant was loaded onto a solid-phase extraction cartridge (ISOLUTEMultimode ™, 500 mg, International Sorbology Technology Ltd.) conditioned with 1 ml of methanol and 2 ml of water, and elution was performed with water. After loading the sample, the first 1 ml was discarded, and 3 ml was taken as a sample solution for gas chromatography mass spectrometry (GC-MS).
3) 3 ml of sample solution for measurement and analysis by GC-MS was cooled in an ice bath, and bromine reagent (15.2 g of potassium bromide, 0.8 ml of hydrogen bromide water, 5 ml of bromine water, 60 ml of water) was added to the color of bromine. Was added until it remained and left on an ice bath for 1 hour. A 1.0 mol / L aqueous sodium thiosulfate solution was added to reduce and eliminate excess bromine, and the mixture was extracted with 4.0 ml of ethyl acetate. The extract was dehydrated with sodium sulfate (anhydrous), and most of the solvent was distilled off under reduced pressure at 30 ° C. using a centrifugal evaporator. Before complete drying, the sample was transferred to a micro sample tube for GC-MS analysis, and further dried under reduced pressure by a centrifugal evaporator for about 5 minutes. The sample tube was stored at 4 ° C. and dissolved in 25 μl of ethyl acetate just prior to analysis.

GC−MS分析にはGCMS−QP2010(島津製作所製)を用い、カラムはCP−Sil24CB Lowbleed/MS(0.25mm×30m、Varian)を使用した。試料溶液1μlをスプリットレスモードで注入し、85℃で1分間保持、25℃/分で175℃まで昇温、6分間保持、40℃/分で250℃まで昇温、250℃で7.52分保持という昇温プログラムでGCを行った。キャリアーガスはHe、カラムヘッド圧は100kPa、試料導入部温度は120℃とした。   For GC-MS analysis, GCMS-QP2010 (manufactured by Shimadzu Corporation) was used, and CP-Sil24CB Lowbleed / MS (0.25 mm × 30 m, Varian) was used as the column. 1 μl of sample solution is injected in splitless mode, held at 85 ° C. for 1 minute, heated to 175 ° C. at 25 ° C./minute, held for 6 minutes, heated to 250 ° C. at 40 ° C./minute, 7.52 at 250 ° C. GC was performed with a temperature rising program of minute retention. The carrier gas was He, the column head pressure was 100 kPa, and the sample introduction part temperature was 120 ° C.

保持時間8.2分の2,3−ジブロモプロピオンアミドの脱臭素フラグメントイオンピーク(m/z 150,152)を選択的イオン検出法(SIM)で検出し、内標準由来の保持時間8.1分のピーク(m/z 153,155)との面積比から試料中のアクリルアミド含量を算出した。
2.(アクリルアミドの減少%)
アクリルアミドの%減少=[(対照焙煎コーヒー豆中のアクリルアミド含量−過熱水蒸気焙煎コーヒー豆中のアクリルアミド含量)/対照焙煎コーヒー豆中のアクリルアミド含量]×100
3.クロロゲン酸類分析法
焙煎コーヒー豆中のクロロゲン酸類含量を、HPLC(高速液体クロマトグラフィー)を用いた以下の分析方法で測定した。
1)焙煎豆からクロロゲン酸類の抽出操作
a)メスシリンダーで70%(v/v)メタノール水溶液を必要量調製(100ml以上/検体)する。
b)ドラフト内に冷却管をスタンドなどでウオーターバス上に固定し、水道水を冷却部に流す。
c)三角フラスコに300〜500μm粒度に粉砕した分析試料約1gを精密天秤で測りとり、三角フラスコに全量移す。
d)70%メタノール溶液を約30ml測りとり三角フラスコに移し沸騰石を4〜5粒加える。
e)三角フラスコを凝縮器に取り付け、フラスコの液面が水面より下にくるようウオーターバス内におく。このとき、凝縮器とフラスコを固定クリップで固定する。
f)メタノール溶液が沸騰を始めてから15分間抽出を行い、時間がきたら三角フラスコをウオーターバス内から引き上げ、凝縮液が落下し終わるまで数分静置する。
g)三角フラスコを凝縮器から取り外し液中の微粉試料を底に沈殿させるため数分間静置させる。
h)三角フラスコ内の溶液をピペッターなどで、100mlメスフラスコに移す。この際、特に最初のバッチでは分析試料粒子を移さない様に注意する。
i)e〜hの操作を合計三回繰り返す。但し、メタノール溶液を新しく加えた後に沸騰石を一粒加える。
j)最後の抽出操作後、三角フラスコ内の液はパスツールピペットを用いて出来る限り100mlメスフラスコに移しとる。この際、分析試料の微粉が多少移ってもかまわない。
k)70%メタノール溶液を少量(20〜30ml)用いて、三角フラスコ内の分析試料を二度にわけてリンスし、リンスした液をパスツールピペットで採取し室温下で100mlにメスアップする。
2)HPLC法
ODS−2逆相カラムを用い、溶離液A(0.05M酢酸 3vol%アセトニトリル水溶液)と溶離液B(0.05M酢酸 100vol%アセトニトリル溶液)にてグラジエントをかけて溶出した。標準品とリテンションタイムを比較し同定した。ここで得られたエリア%に対して、クロロゲン酸類について5位のカフェオイルキナ酸を標準物質として、粉砕焙煎コーヒー豆1g当りのクロロゲン酸類量(mg)で表示する。
4.クロロゲン酸類の増加%
クロロゲン酸類の増加%=[(対照焙煎コーヒー豆中のクロロゲン酸類含量−過熱水蒸気焙煎コーヒー豆中のクロロゲン酸類含量)/対照焙煎コーヒー豆中のクロロゲン酸類含量]×100
本発明の方法により焙煎したコーヒー豆をそのままの形態で各種飲料又は食品に添加することができる。また本発明の方法により焙煎したコーヒー豆を一般的な粉砕機、ロールミルなどを用いて粉砕して、焙煎粉砕コーヒー(粗挽き、中粗挽き、中挽き、中細挽き、細挽きなどの種々の形状のものを含む)を得ることができ、焙煎粉砕コーヒーの形で各種飲料または食品に添加することも可能である。焙煎粉砕コーヒーを水、アルコール類などの抽出液を用いて抽出することにより、アクリルアミドの含有量の少ない、かつクロロゲン酸類の含有量の多い、所望の含量の液体コーヒーを得ることができる。次いで得られた液体コーヒーをそのままの状態で、液体コーヒーを濃縮した液体コーヒー濃縮物の状態で、あるいは液体コーヒーを噴霧乾燥、凍結乾燥等の手段により乾燥させて得た粉末コーヒーの状態で、各種飲料や食品に添加することができる。このように本発明の方法により得られるコーヒー豆及びその抽出液を、飲料や食品の風味付け等のために用いることができる。
The debrominated fragment ion peak (m / z 150,152) of 2,3-dibromopropionamide having a retention time of 8.2 minutes was detected by selective ion detection (SIM), and the retention time derived from the internal standard was 8.1. The acrylamide content in the sample was calculated from the area ratio with the peak of minutes (m / z 153, 155).
2. (% Decrease in acrylamide)
% Reduction of acrylamide = [(acrylamide content in control roasted coffee beans−acrylamide content in superheated steam roasted coffee beans) / acrylamide content in control roasted coffee beans] × 100
3. Chlorogenic acid analysis method The chlorogenic acid content in roasted coffee beans was measured by the following analysis method using HPLC (high performance liquid chromatography).
1) Extraction operation of chlorogenic acids from roasted beans
a) Prepare a required amount of 70% (v / v) aqueous methanol solution (100 ml or more / sample) with a graduated cylinder.
b) Fix the cooling pipe in the draft on the water bath with a stand, etc., and let the tap water flow to the cooling section.
c) About 1 g of an analytical sample pulverized to a particle size of 300 to 500 μm in an Erlenmeyer flask is measured with a precision balance and transferred to the Erlenmeyer flask.
d) About 30 ml of 70% methanol solution is weighed and transferred to an Erlenmeyer flask, and 4 to 5 boiling stones are added.
e) Attach the Erlenmeyer flask to the condenser and place it in a water bath so that the liquid level of the flask is below the water level. At this time, the condenser and the flask are fixed with a fixing clip.
f) Extraction is performed for 15 minutes after the methanol solution starts to boil, and when the time is up, the Erlenmeyer flask is lifted out of the water bath and allowed to stand for several minutes until the condensate finishes dropping.
g) Remove the Erlenmeyer flask from the condenser and let it stand for a few minutes to allow the fine powder sample in the liquid to settle to the bottom.
h) Transfer the solution in the Erlenmeyer flask to a 100 ml volumetric flask with a pipetter or the like. Care should be taken not to transfer the analytical sample particles, especially in the first batch.
i) Repeat steps e through h three times in total. However, after a new methanol solution is added, one boiling stone is added.
j) After the final extraction operation, transfer the liquid in the Erlenmeyer flask to a 100 ml volumetric flask as much as possible using a Pasteur pipette. At this time, the fine powder of the analysis sample may be slightly transferred.
k) Using a small amount (20-30 ml) of a 70% methanol solution, rinse the analytical sample in the Erlenmeyer flask in two portions, collect the rinsed solution with a Pasteur pipette, and make up to 100 ml at room temperature.
2) HPLC method Using an ODS-2 reverse phase column, elution was performed with a gradient of eluent A (0.05 M acetic acid 3 vol% acetonitrile aqueous solution) and eluent B (0.05 M acetic acid 100 vol% acetonitrile solution). The standard product and the retention time were compared and identified. With respect to the area% obtained here, the chlorogenic acid amount (mg) per 1 g of the pulverized roasted coffee beans is expressed using caffeoylquinic acid at the fifth position for chlorogenic acids as a standard substance.
4). Increase in chlorogenic acids
% Increase in chlorogenic acids = [(chlorogenic acids content in control roasted coffee beans−chlorogenic acids content in superheated steam roasted coffee beans) / chlorogenic acids content in control roasted coffee beans] × 100
The coffee beans roasted by the method of the present invention can be added to various beverages or foods as they are. Further, the coffee beans roasted by the method of the present invention are pulverized by using a general pulverizer, a roll mill, etc. Including various shapes) and can be added to various beverages or foods in the form of roast and ground coffee. By extracting the roast and ground coffee using an extract such as water or alcohol, liquid coffee having a desired content with a low acrylamide content and a high chlorogenic acid content can be obtained. Next, in the state of the obtained liquid coffee as it is, in the state of a liquid coffee concentrate obtained by concentrating the liquid coffee, or in the state of powdered coffee obtained by drying the liquid coffee by means of spray drying, freeze drying, etc. Can be added to beverages and foods. Thus, the coffee beans obtained by the method of the present invention and the extract thereof can be used for flavoring beverages and foods.

以下、本発明を実施例により具体的に説明するが、本発明はこれら実施例に限定されるものではない。
対照焙煎コーヒー豆は、当該技術分野において既知のような従来の熱風加熱・直火加熱方式で調製される。対照焙煎コーヒー豆及び過熱水蒸気焙煎コーヒー豆の両方は、ほぼ同じ焙煎時間で、ほぼ同じ焙煎度に焙煎した。
実施例1:インドネシアEK−1豆(ロバスタ種)を用い、図2に示す焙煎装置で一段圧力焙煎を行った。コーヒー豆投入弁(1)を開きインドネシアEK−1豆1Kgを投入ホッパー(2)から焙煎室(3)に投入した後、圧力6.0barG、温度270℃の過熱水蒸気で6.5分間焙煎を行い0.85Kgの焙煎豆を得た。このときの焙煎色は9.0Luであった。
実施例2:実施例1と同様にして、圧力6.0barG、温度270℃の過熱水蒸気で5.5分間焙煎を行い0.85Kgの焙煎豆を得た。このときの焙煎色は12.0Luであった。
実施例3:実施例1と同様にして、圧力6.0barG、温度270℃の過熱水蒸気で4.5分間焙煎を行い0.86Kgの焙煎豆を得た。このときの焙煎色は18.0Luであった。
実施例4:コロンビアエクセルソ豆(アラビカ種)を用い図2に示す焙煎装置で二段圧力焙煎を行った。コーヒー豆投入弁を開きコロンビアエクセルソ豆1Kgを投入ホッパー(2)から焙煎室(3)に投入した後、圧力8.0barG、温度280℃の過熱水蒸気で2.0分間予備焙煎した後、過熱水蒸気供給弁(4)で過熱水蒸気の供給を止め、圧力放出弁(5)により焙煎室内の圧力を抜き取ったあと、過熱水蒸気供給弁(4)を再び開き、圧力1.0barG、温度250℃の過熱水蒸気で5.0分間最終焙煎を行い0.84Kgの焙煎豆を得た。このときの焙煎度は4.5Luであった。
実施例5:実施例4と同様にして、圧力8.0barG、温度280℃の過熱水蒸気で2.0分間予備焙煎した後、過熱水蒸気供給弁(4)で過熱水蒸気の供給を止め、圧力放出弁(5)により焙煎室内の圧力を抜き取ったあと、過熱水蒸気供給弁(4)を再び開き、圧力1.0barG、温度250℃の過熱水蒸気で4.0分間最終焙煎を行い0.85Kgの焙煎豆を得た。このときの焙煎度は9.5Luであった。
実施例6:実施例4と同様にして、圧力8.0barG、温度280℃の過熱水蒸気で2.0分間予備焙煎した後、過熱水蒸気供給弁(4)で過熱水蒸気の供給を止め、圧力放出弁(5)により焙煎室内の圧力を抜き取ったあと、過熱水蒸気供給弁(4)を再び開き、圧力1.0barG、温度250℃の過熱水蒸気で3.0分間最終焙煎を行い0.85Kgの焙煎豆を得た。このときの焙煎度は12.0Luであった。
EXAMPLES The present invention will be specifically described below with reference to examples, but the present invention is not limited to these examples.
Control roasted coffee beans are prepared by conventional hot air heating / direct fire heating systems as known in the art. Both the control roasted coffee beans and the superheated steam roasted coffee beans were roasted to approximately the same roasting degree with approximately the same roasting time.
Example 1: One-stage pressure roasting was performed using a roasting apparatus shown in FIG. 2 using Indonesia EK-1 beans (Robusta seed). Open the coffee bean charging valve (1) and add 1 kg of Indonesian EK-1 beans to the roasting chamber (3) from the charging hopper (2), then roast for 6.5 minutes with superheated steam at a pressure of 6.0 barG and a temperature of 270 ° C. Roasting was performed to obtain 0.85 kg roasted beans. The roast color at this time was 9.0 Lu.
Example 2 In the same manner as in Example 1, roasting was performed for 5.5 minutes with superheated steam at a pressure of 6.0 barG and a temperature of 270 ° C. to obtain 0.85 kg of roasted beans. The roast color at this time was 12.0 Lu.
Example 3 In the same manner as in Example 1, roasting beans of 0.86 kg were obtained by roasting with superheated steam at a pressure of 6.0 barG and a temperature of 270 ° C. for 4.5 minutes. The roast color at this time was 18.0 Lu.
Example 4: Two-stage pressure roasting was performed using a roasting apparatus shown in Fig. 2 using Colombian Excelso beans (Arabica variety). After opening the coffee bean charging valve and charging 1 kg of Columbia Excelso beans into the roasting chamber (3) from the charging hopper (2), pre-roasting with superheated steam at a pressure of 8.0 barG and a temperature of 280 ° C. for 2.0 minutes After the superheated steam supply valve (4) stops supplying superheated steam and the pressure release valve (5) extracts the pressure in the roasting chamber, the superheated steam supply valve (4) is opened again, and the pressure is 1.0 barG, temperature Final roasting was performed with superheated steam at 250 ° C. for 5.0 minutes to obtain 0.84 kg of roasted beans. The roasting degree at this time was 4.5 Lu.
Example 5: In the same manner as in Example 4, after pre-roasting with superheated steam at a pressure of 8.0 barG and a temperature of 280 ° C. for 2.0 minutes, the superheated steam supply valve (4) was used to stop the supply of superheated steam, After extracting the pressure in the roasting chamber with the discharge valve (5), the superheated steam supply valve (4) is opened again, and final roasting is performed with superheated steam at a pressure of 1.0 barG and a temperature of 250 ° C. for 4.0 minutes. 85 kg roasted beans were obtained. The roasting degree at this time was 9.5 Lu.
Example 6: In the same manner as in Example 4, after pre-roasting with superheated steam at a pressure of 8.0 barG and a temperature of 280 ° C. for 2.0 minutes, the superheated steam supply valve (4) was used to stop the supply of superheated steam. After extracting the pressure in the roasting chamber with the discharge valve (5), the superheated steam supply valve (4) is opened again, and final roasting is performed with superheated steam at a pressure of 1.0 barG and a temperature of 250 ° C. for 3.0 minutes. 85 kg roasted beans were obtained. The roasting degree at this time was 12.0 Lu.

<比較例;通常焙煎>
比較例1:
インドネシアEK−1豆(ロバスタ種)を用い、フジロイヤル製のコーヒーロースター(TYPE R−101)を使用し焙煎を行った。
インドネシアEK−1豆1Kgを投入しプロパンの燃焼ガスで6.5分間焙煎を行い焙煎色9.0Luの0.85Kgの焙煎豆を得た。
比較例2:比較例1と同様にして、5.5分間焙煎を行い焙煎色12.0Luの0.85Kgの焙煎豆を得た。
比較例3:比較例1と同様にして、4.5分間焙煎を行い焙煎色18.0Luの0.86Kgの焙煎豆を得た。
比較例4:コロンビアエクセルソ豆(アラビカ種)を用い、フジロイヤル製のコーヒーロースター(TYPE R−101)を使用し焙煎を行った。
コロンビアエクセルソ豆1Kgを投入しプロパンの燃焼ガスで7.0分間焙煎を行い焙煎色4.5Luの0.83Kgの焙煎豆を得た。
比較例5:比較例4と同様にして6.0分間焙煎を行い焙煎色9.5Luの0.85Kgの焙煎豆を得た。
比較例6:比較例4と同様にして5.0分間焙煎を行い焙煎色12.0Luの0.86Kgの焙煎豆を得た。
<比較例;常圧過熱水蒸気焙煎>
比較例7:インドネシアEK−1豆(ロバスタ種)を用い、図2に示す焙煎装置で過熱水蒸気焙煎を行った。
コーヒー豆投入弁(1)を開きインドネシアEK−1豆1Kgを投入ホッパー(2)から焙煎室(3)に投入した後、圧力放出弁(5)を開けまま過熱水蒸気供給弁(4)から温度270℃の過熱水蒸気を供給し5.5分間焙煎した後、過熱水蒸気の供給を止めた。これにより焙煎色9.0Luの0.85Kgの焙煎豆を得た。
比較例8:コロンビアエクセルソ豆(アラビカ種)を用い図2に示す焙煎装置で過熱水蒸気焙煎を行った。コーヒー豆投入弁(1)を開きコロンビアエクセルソ豆1Kgを投入ホッパー(2)から焙煎室(3)に投入した後、圧力放出弁(5)を開けたまま過熱水蒸気供給弁(4)から温度270℃の過熱水蒸気を供給し6.0分間焙煎した後、過熱水蒸気の供給を止めた。これにより焙煎色9.5Luの0.84Kgの焙煎豆を得た。
<Comparative example: Normal roasting>
Comparative Example 1:
Using Indonesian EK-1 beans (Robusta), roasting was performed using Fuji Royal coffee roaster (TYPE R-101).
Indonesia EK-1 beans 1Kg was charged and roasted with propane combustion gas for 6.5 minutes to obtain roasted color 9.0Lu 0.85Kg roasted beans.
Comparative Example 2: In the same manner as in Comparative Example 1, roasting was performed for 5.5 minutes to obtain 0.85 kg roasted beans having a roasting color of 12.0 Lu.
Comparative Example 3: In the same manner as in Comparative Example 1, roasting was performed for 4.5 minutes to obtain 0.86 kg roasted beans having a roasted color of 18.0 Lu.
Comparative Example 4: Using Colombian Excelso beans (Arabica), roasting was performed using Fuji Royal coffee roaster (TYPE R-101).
Colombian Excelso beans 1Kg was added and roasted with propane combustion gas for 7.0 minutes to obtain 0.83Kg roasted beans of roasted color 4.5Lu.
Comparative Example 5: In the same manner as in Comparative Example 4, roasting was performed for 6.0 minutes to obtain a roasted color of 9.5 Lu and 0.85 kg roasted beans.
Comparative Example 6: Roasting was performed for 5.0 minutes in the same manner as in Comparative Example 4 to obtain 0.86 kg roasted beans having a roasted color of 12.0 Lu.
<Comparative example: normal pressure superheated steam roasting>
Comparative Example 7: Superheated steam roasting was performed using a roasting apparatus shown in FIG. 2 using Indonesia EK-1 beans (Robusta seed).
After opening the coffee bean charging valve (1) and charging 1Kg of Indonesian EK-1 beans into the roasting chamber (3) from the hopper (2), the superheated steam supply valve (4) is opened with the pressure release valve (5) open. After supplying superheated steam at a temperature of 270 ° C. and roasting for 5.5 minutes, the supply of superheated steam was stopped. This obtained roasted beans of 0.85 kg of roasted color 9.0 Lu.
Comparative Example 8: Superheated steam roasting was performed using a roasting apparatus shown in FIG. 2 using Colombian Excelso beans (Arabica variety). After opening the coffee bean charging valve (1) and charging 1 kg of Colombian Excelso beans into the roasting chamber (3) from the charging hopper (2), the superheated steam supply valve (4) is opened with the pressure release valve (5) open. After supplying superheated steam at a temperature of 270 ° C. and roasting for 6.0 minutes, the supply of superheated steam was stopped. As a result, a roasted color of 9.5 Lu and 0.84 kg roasted beans were obtained.

Figure 2007282537
Figure 2007282537

コーヒー豆の焙煎度とアクリルアミド含量との関係の例を表すグラフである。It is a graph showing the example of the relationship between the roasting degree of coffee beans, and acrylamide content. 過熱水蒸気を用いる焙煎装置の模式図である。It is a schematic diagram of the roasting apparatus using superheated steam.

Claims (7)

コーヒー豆を、過熱水蒸気を用いた加圧下で焙煎することを特徴とする、通常焙煎コーヒー豆よりもアクリルアミドの含量が少なく、かつクロロゲン酸類の含量の多い焙煎コーヒー豆を製造する方法。 A method for producing roasted coffee beans having a lower content of acrylamide and a higher content of chlorogenic acids than normal roasted coffee beans, wherein the coffee beans are roasted under pressure using superheated steam. 過熱水蒸気で焙煎する際の圧力が1.0barG〜20barGであることを特徴とする、請求項1に記載の製造方法。 The production method according to claim 1, wherein the pressure when roasting with superheated steam is 1.0 barG to 20 barG. 前記焙煎コーヒー豆中のアクリルアミドの含量が通常焙煎コーヒー豆を基準として10%〜100%減少しており、かつクロロゲン酸類の含量が10%〜100%増加していることを特徴とする、請求項1又は2のいずれか一項に記載の製造方法。 The acrylamide content in the roasted coffee beans is usually reduced by 10% to 100% based on the roasted coffee beans, and the content of chlorogenic acids is increased by 10% to 100%, The manufacturing method as described in any one of Claim 1 or 2. 焙煎色5Lu以下で、焙煎コーヒー豆中のアクリルアミド含量が0〜180μg/kgかつクロロゲン酸類含量が7〜29g/kgである、請求項1〜3のいずれか一項に記載の方法で製造した焙煎コーヒー豆。 Manufactured by the method according to any one of claims 1 to 3, wherein the roasted color is 5Lu or less, the acrylamide content in the roasted coffee beans is 0 to 180 µg / kg, and the chlorogenic acid content is 7 to 29 g / kg. Roasted coffee beans. 焙煎色5〜10Luで、アクリルアミド含量が0〜220μg/kgかつクロロゲン酸類含量が13〜43g/kgである、請求項1〜3のいずれか一項に記載の方法で製造した焙煎コーヒー豆。 Roasted coffee beans produced by the method according to any one of claims 1 to 3, having a roasting color of 5 to 10 Lu, an acrylamide content of 0 to 220 µg / kg and a chlorogenic acid content of 13 to 43 g / kg. . 焙煎色10〜25Luで、焙煎コーヒー豆中のアクリルアミド含量が0〜280μg/kgかつクロロゲン酸類含量が18〜60g/kgである、請求項1〜3のいずれか一項に記載の方法で製造した焙煎コーヒー豆。 The method according to claim 1, wherein the roasted color is 10 to 25 Lu, the acrylamide content in the roasted coffee beans is 0 to 280 μg / kg, and the chlorogenic acid content is 18 to 60 g / kg. Produced roasted coffee beans. 請求項1〜6に記載の焙煎コーヒー豆を含む飲食物。 A food or drink comprising the roasted coffee beans according to claim 1.
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Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2011016432A1 (en) * 2009-08-06 2011-02-10 国立大学法人北海道大学 Immune balance-regulating agent
JP2013514065A (en) * 2009-12-18 2013-04-25 ネステク ソシエテ アノニム Method for producing raw coffee extract
WO2014037837A1 (en) 2012-09-05 2014-03-13 Gokmen Vural Instant coffee or coffee substitute with reduced acrylamide and hydroxymethyl furfural content and production method thereof
WO2014147189A1 (en) * 2013-03-21 2014-09-25 Novozymes A/S Method for producing roasted coffee beans
JP2014195445A (en) * 2013-03-29 2014-10-16 花王株式会社 Packed coffee drink
JP2018093741A (en) * 2016-12-08 2018-06-21 花王株式会社 Method for producing chlorogenic acid-containing composition
CN108366573A (en) * 2015-12-11 2018-08-03 雀巢产品技术援助有限公司 Method for roast coffee beans
JP2019103496A (en) * 2017-12-14 2019-06-27 ビューラー バルト ゲゼルシャフト ミット ベシュレンクテル ハフツングBuehler Barth GmbH Heat treatment of bulk food product
JP2023507191A (en) * 2019-12-20 2023-02-21 コーニンクレイケ ダウ エグバーツ ビー.ヴイ. Process for preparing liquid coffee concentrate with reduced acrylamide content by treatment with a selectively permeable membrane

Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0630754A (en) * 1992-07-16 1994-02-08 Kikkoman Corp Method for roasting coffee bean
JPH0646755A (en) * 1994-01-28 1994-02-22 Ajinomoto General Foods Inc Method for roasting coffee bean using superheated steam
JP2000300180A (en) * 1999-03-22 2000-10-31 Kraft Foods Inc Roasted coffee and coffee roasting method
JP2002330699A (en) * 2001-05-02 2002-11-19 Tamao Ashida Control of catabolic reaction of protein by method for roasting coffee bean without crushing and method for preventing the same from oxidizing
JP2003144050A (en) * 2001-11-15 2003-05-20 Ucc Ueshima Coffee Co Ltd Method for producing roasted coffee bean
JP2004121138A (en) * 2002-10-04 2004-04-22 Ucc Ueshima Coffee Co Ltd Method for producing coffee extract or water-soluble coffee
JP2005137269A (en) * 2003-11-06 2005-06-02 Pokka Corp Volatile component, method for producing the same, and food and drink
JP2006503592A (en) * 2002-10-25 2006-02-02 ザ プロクター アンド ギャンブル カンパニー Method for reducing acrylamide in roasted coffee beans, roasted coffee beans having reduced concentration of acrylamide, and goods
WO2006080333A1 (en) * 2005-01-28 2006-08-03 Suntory Limited Method of processing chlorogenic acid-rich coffee beans

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0630754A (en) * 1992-07-16 1994-02-08 Kikkoman Corp Method for roasting coffee bean
JPH0646755A (en) * 1994-01-28 1994-02-22 Ajinomoto General Foods Inc Method for roasting coffee bean using superheated steam
JP2000300180A (en) * 1999-03-22 2000-10-31 Kraft Foods Inc Roasted coffee and coffee roasting method
JP2002330699A (en) * 2001-05-02 2002-11-19 Tamao Ashida Control of catabolic reaction of protein by method for roasting coffee bean without crushing and method for preventing the same from oxidizing
JP2003144050A (en) * 2001-11-15 2003-05-20 Ucc Ueshima Coffee Co Ltd Method for producing roasted coffee bean
JP2004121138A (en) * 2002-10-04 2004-04-22 Ucc Ueshima Coffee Co Ltd Method for producing coffee extract or water-soluble coffee
JP2006503592A (en) * 2002-10-25 2006-02-02 ザ プロクター アンド ギャンブル カンパニー Method for reducing acrylamide in roasted coffee beans, roasted coffee beans having reduced concentration of acrylamide, and goods
JP2005137269A (en) * 2003-11-06 2005-06-02 Pokka Corp Volatile component, method for producing the same, and food and drink
WO2006080333A1 (en) * 2005-01-28 2006-08-03 Suntory Limited Method of processing chlorogenic acid-rich coffee beans

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2011016432A1 (en) * 2009-08-06 2011-02-10 国立大学法人北海道大学 Immune balance-regulating agent
JP2013514065A (en) * 2009-12-18 2013-04-25 ネステク ソシエテ アノニム Method for producing raw coffee extract
WO2014037837A1 (en) 2012-09-05 2014-03-13 Gokmen Vural Instant coffee or coffee substitute with reduced acrylamide and hydroxymethyl furfural content and production method thereof
WO2014147189A1 (en) * 2013-03-21 2014-09-25 Novozymes A/S Method for producing roasted coffee beans
CN105072919A (en) * 2013-03-21 2015-11-18 诺维信公司 Method for producing roasted coffee beans
JP2014195445A (en) * 2013-03-29 2014-10-16 花王株式会社 Packed coffee drink
CN108366573A (en) * 2015-12-11 2018-08-03 雀巢产品技术援助有限公司 Method for roast coffee beans
JP2018536408A (en) * 2015-12-11 2018-12-13 ネステク ソシエテ アノニム How to roast coffee beans
JP2018093741A (en) * 2016-12-08 2018-06-21 花王株式会社 Method for producing chlorogenic acid-containing composition
JP2019103496A (en) * 2017-12-14 2019-06-27 ビューラー バルト ゲゼルシャフト ミット ベシュレンクテル ハフツングBuehler Barth GmbH Heat treatment of bulk food product
JP2023507191A (en) * 2019-12-20 2023-02-21 コーニンクレイケ ダウ エグバーツ ビー.ヴイ. Process for preparing liquid coffee concentrate with reduced acrylamide content by treatment with a selectively permeable membrane
JP7361927B2 (en) 2019-12-20 2023-10-16 コーニンクレイケ ダウ エグバーツ ビー.ヴイ. Process for preparing liquid coffee concentrate with reduced acrylamide content by treatment with a selectively permeable membrane

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