JP5398929B1 - Coffee beverage, method for producing the same, method for suppressing acidity of coffee beverage, and method for improving roasted feeling - Google Patents

Abstract

[Problem] To provide a coffee beverage capable of suppressing the sourness caused by organic acids contained in a large amount of lightly roasted beans and the like, and feeling the savory roasted feeling of coffee in spite of the high content of chlorogenic acids. The present invention provides a method, a method for reducing the sourness of a coffee beverage, and a method for improving the roast feeling.
A coffee beverage containing chlorogenic acids in a predetermined amount or more, wherein the chlorogenic acid content [CQ] (mg / 100 g) in the beverage is 140 or more, and citric acid and quinic acid in the beverage. The total content [A] (ppm) is 1000 to 2200, and the ratio [A] to the chlorogenic acid content [CQ] (mg / 100 g) in the beverage is [A] / [CQ]. 5.5 or more.
[Selection figure] None

Description

The present invention relates to a coffee beverage, particularly a coffee beverage containing a chlorogenic acid, which is a physiologically active ingredient, in a predetermined amount or more, a method for producing the same, and a sourness control method and roast for a coffee beverage containing a chlorogenic acid in a predetermined amount or more. It relates to a feeling improvement method.

Coffee is a typical palatability food that has been widely used not only as a beverage but also as a flavor additive using its unique aroma since ancient times.
In particular, coffee drinks are drinks loved by many people as well as tea, and there are a wide variety of products available on the market.
As a sales form of coffee-related products, for example, green beans before roasting, roasted coffee beans, or a pulverized product of roasted coffee beans, the pulverized coffee bean is used as an extraction bag such as cloth, non-woven fabric, or paper. There are a form of an enclosed extraction bag, a concentrated form of a roasted coffee bean extract, or a form of so-called instant coffee that is solidified by means such as freeze-drying so that the extract can be easily dissolved in hot water.
In addition, RTD (Ready To Drink) type packed coffee beverages in which the extracted coffee is sealed in containers such as cans and PET bottles can be enjoyed at any time in the soft drink market. However, it has the largest market size, and consumer needs for products are diversifying. In response to this diversified consumer needs, there are many different types of products on the market, including black coffee (unsweetened and sugared) and coffee with milk. It is various.

In addition, caffeine, which is a component contained in coffee, has long been known as a component having a physiologically active function such as an arousal action. If caffeine is ingested in an appropriate amount, it can be expected to have various effects such as vasodilation and gastrointestinal secretion promotion in addition to the arousal effect. In recent years, there are many products in which the caffeine content is selectively controlled because of the possibility of adverse effects.

In recent years, with the growing interest in bioactive functions of foods, analytical research on bioactive functional ingredients other than caffeine has also progressed, and it has become clear that coffee contains multiple bioactive functional ingredients. The role as a functional drink has been attracting attention from a simple taste drink.

One of the physiologically active ingredients of coffee that has been attracting attention in recent years is chlorogenic acid.
Chlorogenic acid is a kind of so-called polyphenol and is also called 5-caffeoylquinic acid.
It is one of the plant components having a structure in which a carboxyl group of caffeic acid and a hydroxyl group of quinic acid are dehydrated and have an antioxidant power.
In addition to the above chlorogenic acid, two isomers (3-caffeoylquinic acid, 4-caffeoylquinic acid) having different hydroxyl positions of quinic acid to which caffeic acid binds, dicaffee in which two caffeic acids are bonded. Including oil quinic acid and ferulacic acid to which ferulic acid is bonded instead of caffeic acid, they are collectively referred to as chlorogenic acids, all of which have an antioxidant power similar to chlorogenic acid.

As physiologically active functions of chlorogenic acids, blood pressure lowering action, fat burning action and the like are already known, and in order to exert these physiologically active functions, coffee containing a predetermined amount or more of chlorogenic acid and / or chlorogenic acids Beverages, fat combustion promoters, and the like have been proposed (Patent Document 1 and Patent Document 2).
In addition, a coffee beverage has been proposed in which the bitterness that is strengthened by the high content of chlorogenic acids is masked by the addition of amino acids (Patent Document 3).
Furthermore, a method for producing a savory purified chlorogenic acid composition with reduced caffeine and capable of recovering chlorogenic acid from a chlorogenic acid-containing composition with high purity and efficiency has been proposed. It is disclosed that the content ratio of citric acid and chlorogenic acid in the composition is desirably 0.5 or more (Patent Document 4).

The content of chlorogenic acids in coffee beans is high in green beans and gradually decreases with roasting.
Therefore, in order to increase the content of chlorogenic acids in the coffee beverage, the use rate of so-called shallow roast beans with a low roasting degree is increased, or an extract (extract) derived from raw beans or shallow roast beans is separately added. A method such as adding to a coffee extract can be considered.
However, although it is possible to increase the content of chlorogenic acids by the above method, when the amount of lightly roasted beans is increased, together with the chlorogenic acids, organic acids, particularly citric acid, contained in lightly roasted beans The acidity caused by quinic acid is also extracted.
As a result, the aromatic flavor peculiar to coffee, the so-called roasted feeling, is impaired, and the entire flavor balance is adversely affected.

Chlorogenic acids have a bitter taste per se, but since the bitter taste of coffee involves a plurality of components such as caffeine and tannin in addition to the chlorogenic acids, the coffee beverage according to the invention of Patent Document 3 Thus, even if only the bitterness caused by chlorogenic acids is simply masked, it is insufficient in terms of reducing the acidity and ensuring a good flavor as a coffee beverage, so-called roasted feeling, It is considered that the amino acid to be added adversely affects the taste of the beverage.

In the invention according to Patent Document 4, the object of the invention is different from that of the present application, the content ratio of citric acid and chlorogenic acids, and the content ratio of quinic acid and chlorogenic acids in the purified chlorogenic acid composition (paragraph 0071). , 0072, 0089 (Table 4), etc.), however, there is no disclosure of the optimum content ratio of chlorogenic acids, citric acid and quinic acid as a coffee beverage.

The invention described in the above-mentioned prior art documents shows certain results in terms of improving the overall flavor and taste of coffee beverages with a high content of chlorogenic acids and obtaining a purified chlorogenic acid composition.
However, as described above, the technique of simply masking a specific taste with a separate additive may eventually cause a loss of flavor balance as a coffee beverage.
Therefore, in order to provide a coffee beverage that contains chlorogenic acids in a predetermined amount or more, suppresses the acidity caused by the organic acid contained in the light roasted beans, and can maintain the fragrant roasted feeling of coffee. It is desirable not to add components other than coffee-derived components separately, but to adjust the flavor and taste and evaluate them using the components contained in the coffee extract.
However, up to now, no optimum evaluation index has been provided for performing the adjustment, and the adjustment work has been extremely difficult requiring excessive trial and error.

WO2005 / 072533 JP 2010-148453 A JP2012-062275A JP2013-027388A

The object of the present invention is to suppress the sourness caused by organic acids contained in a large amount of shallow roasted beans and the like, despite the fact that it contains a large amount of chlorogenic acids, and it is possible to feel the fragrant roasted feeling of coffee. It is to provide a coffee beverage having both taste and taste, a method for producing the same, a method for reducing the sourness of the coffee beverage, and a method for improving the roasted feeling.

As a result of diligent research, the present inventors, among organic acids in the coffee extract, in particular, the total content [A] (ppm) of citric acid and quinic acid and the content [CQ] of chlorogenic acids (mg / We focused on the relationship of 100 g).

That is, in a coffee beverage containing a predetermined amount or more of chlorogenic acids, the total content [A] of citric acid and quinic acid is adjusted to a predetermined amount or more, and the total content of citric acid and quinic acid [A] is adjusted. In order to increase the content of chlorogenic acids by adjusting the ratio of chlorogenic acids [CQ] and the value of [A] / [CQ] to a predetermined numerical range, Even when a large amount of extract is used, the sourness of the extract is suppressed, and the roasted beans' roasted feeling is prevented from being impaired. It has been found that a suitable coffee beverage can be obtained.

That is, the present invention will be described in detail as follows.

(1)
A coffee beverage containing chlorogenic acids in a predetermined amount or more, wherein the chlorogenic acid content [CQ] (mg / 100 g) in the beverage is 140 or more, and the total content of citric acid and quinic acid in the beverage [A] (ppm) is 1000 to 2200, the above [A] and the chlorogenic acid content [CQ] (mg / 100 g) ratio in the beverage liquid, [A] / [CQ] is 5.5 or more A coffee drink (Invention 1),
(2)
1 coffee drink (invention 2), wherein the chlorogenic acid content [CQ] (mg / 100 g) in the beverage is 140-300.
(3)
1 or 2 coffee drinks (invention 3), wherein the chlorogenic acid content [CQ] (mg / 100 g) in the beverage is 140 to 250.
(4)
The total content [A] (ppm) of citric acid and quinic acid in the beverage is 1000 to 2000, or any one of 1 to 3 coffee beverages (Invention 4).
(5)
The ratio of the citric acid content (ppm) [CA] and the quinic acid content (ppm) [QA] in the beverage, wherein [QA] / [CA] is 1.0 or more, 1 to 4. Any one of 4 coffee drinks (Invention 5).
(6)
The coffee drink according to any one of 1 to 5, which is black coffee (Invention 6).
(7)
The coffee drink according to any one of 1 to 6, which is a packaged drink (Invention 7).
(8)
A method for producing a coffee beverage containing chlorogenic acids in a predetermined amount or more, wherein the chlorogenic acid content [CQ] (mg / 100 g) in the beverage is 140 or more, and citric acid and quinic acid in the beverage are The total content [A] (ppm) is adjusted to 1000 to 2200, and the above [A] and chlorogenic acid content [CQ] (mg / 100 g) ratio in the beverage liquid, [A] / [CQ] Is adjusted to 5.5 or more, a method for producing a coffee beverage (Invention 8).
(9)
A method for suppressing acidity of a coffee beverage containing a chlorogenic acid in a predetermined amount or more, wherein the chlorogenic acid content [CQ] (mg / 100 g) in the beverage is 140 or more, and citric acid and quinic acid in the beverage The total content [A] (ppm) is adjusted to 1000 to 2200, and the above [A] and chlorogenic acid content [CQ] (mg / 100 g) ratio in the beverage liquid, [A] / [CQ ] Is adjusted to 5.5 or more, sourness suppression method for coffee beverage (Invention 9).
(10)
A method for improving the roast feeling of a coffee beverage containing chlorogenic acids in a predetermined amount or more, wherein the chlorogenic acid content [CQ] (mg / 100 g) in the beverage is 140 or more, and citric acid and quina in the beverage The total acid content [A] (ppm) is adjusted to 1000 to 2200, and the above [A] and chlorogenic acid content [CQ] (mg / 100 g) ratio in the beverage liquid, [A] / [ CQ] is adjusted to 5.5 or more. A method for improving a roasted feeling of a coffee beverage (Invention 10).

ADVANTAGE OF THE INVENTION According to this invention, although there is much content of chlorogenic acids, the coffee drink which can suppress the acidity resulting from the organic acid contained abundantly in shallow roast beans etc. and can feel the fragrant roast feeling of coffee And a method for producing the same, a method for reducing the sourness of a coffee beverage, and a method for improving a roasted feeling.

Although embodiments of the present invention will be described in detail below, known techniques other than the embodiments described below can be selected as appropriate without departing from the technical scope of the present invention.

1. Coffee Beverage In this embodiment, a coffee beverage with a high content of chlorogenic acids is subjected to an extraction process in which the coffee beans that are the raw material are roasted for a predetermined time and then crushed and extracted with hot water, as with a normal coffee beverage. The obtained coffee extract is obtained by mixing a single substance or a plurality of kinds.
Since the content of chlorogenic acids varies depending on the bean type and roasting degree, the coffee bean varieties to be used can be used alone and / or a mixture of two or more bean types, and the mixing ratio is also desired. It is possible to appropriately change the value.
In the extraction step, any known method can be selected, but a method using filtration extraction with a paper or cloth filter is desirable.

In addition, as a method of increasing the content of chlorogenic acids in the extract, in addition to increasing the usage ratio of shallow roast beans, if necessary, a method such as adding an extract of shallow roast beans or green beans should be selected as appropriate. Can do.

When manufacturing a coffee drink, in addition to the extraction process described above, an extract obtained through a process such as concentration can also be used.
Furthermore, in addition to the extraction process, a clarification process such as a filtration process and a centrifugation process, a sterilization process, a container filling process, and the like can be performed.

In addition, the coffee beverage according to the present embodiment includes sugars such as sucrose, glucose, fructose, xylose, fructose glucose solution, sugar alcohol, antioxidants, pH, and the like without departing from the technical scope of the present invention. Additives such as regulators, emulsifiers, fragrances, and milk components such as raw milk, milk, whole milk powder, skimmed milk powder, fresh cream, concentrated milk, skimmed milk, partially skimmed milk, and milk can be added. In order to enjoy a suitable roasted feeling which is also a remarkable effect of the invention, it is desirable that the coffee be black coffee to which at least a milk component is not added.

Examples of the antioxidant include ascorbic acid or a salt thereof, erythorbic acid or a salt thereof, etc. Among them, ascorbic acid or a salt thereof is particularly desirable.

As the emulsifier, sucrose fatty acid ester, glycerin fatty acid ester, lecithin, sorbitan fatty acid ester, polyglycerin fatty acid ester and the like can be selected.

2. Examples of raw beans and coffee beans used for extraction include, but are not limited to, Brazil, Colombia, Tanzania, Ethiopia and the like. Examples of coffee bean varieties include Arabica and Robusta. One kind of coffee beans may be used, or two or more kinds may be blended and used. Coffee beans are roasted using a known method, and the roasting degree (L value) can be adjusted as appropriate in order to obtain an extract necessary for adjusting each component. By increasing the use ratio of roasted beans, the content of chlorogenic acids in the extract can be increased.

3. Containers Coffee beverage containers according to the present embodiment include PET bottles, cans (aluminum, steel), paper, plastics, retort pouches, bottles (glass), and the like. When it is necessary to consider warm sales, it is desirable to use a can (aluminum, steel) or a reinforced plastic container having a reinforced layer or an oxygen absorbing layer.

The sterilization treatment of the coffee beverage according to the present embodiment is performed under the sterilization conditions stipulated in the Food Sanitation Law when the container can be sterilized by heating after filling into a container such as a metal can. Examples of the sterilization method include retort sterilization.

Hereinafter, the components contained in the coffee extract in this embodiment will be described in detail.

4). Chlorogenic acids In the present embodiment, chlorogenic acids are a general term for monocaffeoylquinic acid, dicaffeoylquinic acid, and ferlaquinic acid as described above, and the content (mg / 100 g) of chlorogenic acids is shown in Table 1 below. The total content of each component.
The following shows the structure of monocaffeoylquinic acid 5-caffeoylquinic acid.

In the coffee beverage of this embodiment, the total content of each component shown in Table 1, that is, the content of chlorogenic acids (mg / 100 g) is the ratio of the total content of citric acid and quinic acid described later. Assuming that it is within the scope of the present application, 140 to 300 is desirable, 140 to 280 is more desirable, and 140 to 250 is most desirable.
By being in the said range, the balance of a bitterness and sourness is favorable, and a roast feeling improves more.

5. Quinic acid quinic acid is a cyclic hydroxy acid having a structure in which an ester bond of quinic acid lactone is hydrolyzed. The above-mentioned chlorogenic acid is produced when quinic acid and caffeic acid are ester-bonded.
Specifically, it has a structure represented by the following chemical formula 2.
In this embodiment, the quinic acid content (ppm) is preferably 500 to 1700, more preferably 600 to 1600, and more preferably 700 to 1500 on the assumption that the total content of quinic acid and citric acid described later is satisfied. More desirable.
In quinic acid and citric acid described later, the amount of citric acid is likely to contribute to the strength of sourness, so that the sourness is not excessively emphasized when the quinic acid content is within the above range.

6). Citric acid is an organic acid having three carboxyl groups, and is known to be contained in citrus fruits and plums and in coffee.
It has a strong lemon-like acidity and has been used as a food additive.
In addition to quinic acid and citric acid, the coffee extract contains multiple types of organic acids, but the content of citric acid and quinic acid is higher than other organic acids, It accounts for about 60 to 70%.
The citric acid content is preferably 300 to 800, more preferably 350 to 700, and more preferably 400 to 700, on the premise that the total amount (ppm) of the citric acid content and the quinic acid content is satisfied. 650 is even more desirable.
Moreover, the total content (ppm) of citric acid and quinic acid is 1000 to 2200, more preferably 1000 to 2000, and still more preferably 1000 to 1900.
The quinic acid and citric acid can be quantified by, for example, the following method, and other known methods can be selected.

Organic acids such as quinic acid and citric acid can be quantified by the following method.
(Quantification method of organic acid)
The sample to be measured is diluted with pure water at an arbitrary ratio, filtered through a membrane filter, and subjected to analysis.
= Device configuration =
UV-VIS detector: L-7420 (Hitachi High-Tech Co., Ltd.)
・ Pump: 1525Binary HPLC Pump (Nippon Waters Co., Ltd.)
・ Autosampler: 717Plus (Nippon Waters Co., Ltd.)
Column: RSpak KC-LG (8.0 mm ID × 50 mm) + DE-613 (6.0 mm ID × 150 mm) + KC-811 (8.0 mm ID × 300 mm) × 2 (Showa Denko)
= Analysis conditions =
Sample injection volume: 30 μL
・ Flow rate: 1.0 mL / min
・ Detection wavelength: 430 nm
-Column oven set temperature: 50 ° C
-Mobile phase: 2.5 mM perchloric acid-Reaction reagent: ST3-R (Showa Denko KK)
-Reaction reagent flow rate: 1.0 mL / min
In addition to the above method, any known method can be selected.

7). Roasted coffee polyphenol oligomer (RCPO: Roasted Coffee Polyphenol Oligomer)
The roasted coffee polyphenol oligomer is an assembly of components defined as follows.
That is, roasted coffee polyphenol oligomer (RCPO) does not indicate a specific single component, and its quantitative value is a precursor in a chromatograph obtained by high performance liquid chromatography (HPLC) analysis under the following conditions. It is quantified using the obtained calibration curve using 5-caffeoylquinic acid (5-CQA) as an indicator substance (unit: ppm).
In the present embodiment, the content (ppm) of roasted coffee polyphenol oligomer (RCPO) is not particularly limited, but it is preferably 350 to 550 in order to prevent an excessive taste. 400-530 is still desirable and 450-520 is more desirable.

The roasted coffee polyphenol oligomer (RCPO) is quantified by the following method.
(Quantification method of roasted coffee polyphenol oligomer (RCPO))
= HPLC conditions =
Column: Cadenza CD-C18
(4.6mmΦx150mm, Intact Corporation)
・ Mobile phase:
A: 0.05M acetic acid aqueous solution
B: Acetonitrile ・ Flow rate: 0.8 ml / min
-Column temperature: 40 ° C
・ Gradient conditions:
From 5 minutes after the start of analysis, solution B is 7%
B liquid 20% from 5 to 11 minutes
B liquid 20% retention from 11 minutes to 17 minutes 90 minutes B liquid from 17 minutes to 18 minutes
90% retention from 18 minutes to 23 minutes 7% retention from 23 minutes to 24 minutes Return to liquid B 7% retention / detection: 280 nm from 24 minutes to 30 minutes
(Data collection time is 30 minutes), quantified by peak area and injection volume: 10 μL
Standard substance: 5-caffeoylquinic acid (abbreviation: 5-CQA)

Under the measurement conditions, roasted coffee polyphenol oligomer (RCPO) is a peak obtained with a retention time of 18 to 23 minutes.
The content of the roasted coffee polyphenol oligomer (RCPO) is calculated based on a calibration curve of 5-caffeoylquinic acid (5-CQA) (unit: ppm).
The roasted coffee polyphenol oligomer (RCPO) contains a plurality of other products generated in the roasting process of coffee beans in addition to the heated product of 5-caffeoylquinic acid. Although it is difficult to quantify individually, it has been confirmed that the L value, which is an index of roasting degree, tends to decrease, that is, increases as deep roasting occurs. It is considered to be a causative substance of bitterness and miscellaneous taste.
It is possible to prepare a coffee beverage that meets the desired requirements by appropriately blending the extract.

8). Quinic acid lactone Quinic acid lactone, also called quinolactone or quinide, has a structure in which a carboxyl group and a hydroxyl group of quinic acid are dehydrated, and is known to be produced in the roasting process of coffee beans. It has a structure (example of 1,5 quinolactone).
In this embodiment, the quinic acid lactone content (ppm) is preferably 3.0 to 15.0, more preferably 3.0 to 13.0, and still more preferably 4.0 to 10.5.
By being in the said range, it can suppress that a sour taste increases excessively at the time of storage.

キナ酸ラクトンは、抽出液中において、次第に加水分解され再びキナ酸となり、本反応は、液温が高いほど顕著に進行することから、抽出液に加えられる熱履歴の指標ともなり得る。

Quinic acid lactone is gradually hydrolyzed into quinic acid again in the extract, and this reaction proceeds more remarkably as the liquid temperature is higher, so it can also be an indicator of the heat history added to the extract.

Quinic acid lactone can be quantified, for example, under the following conditions. (Example of quantification method of quinic acid lactone) An ultra-high performance liquid chromatography (UPLC) and a triple quadrupole mass spectrometer (TQD) are used to perform an absolute calibration curve method using a quinic acid lactone standard product. Detailed conditions are shown below.
= UPLC condition =
Column: ACQUITY UPLC BEH C18 (2.1 mmΦx100 mm, Waters Corporation)
・ Mobile phase:
A: MilliQ water
B: Acetonitrile ・ Flow rate: 0.2 ml / min
-Column temperature: 40 ° C
・ Gradient conditions:
From the start of analysis up to 2 minutes, B solution 5%
Switch from 2.1 minutes to 60% B solution, hold up to 4.5 minutes Switch from 4.6 minutes to 5% solution B, hold 5% up to 8 minutes ・ Injection volume: 2 μL
= TQD condition =
・ Analysis mode: ESI negative V mode ・ Source temperature: 120 ℃
Desolvation temperature: 400 ° C
・ Capillary voltage: 2.5 kV
・ Sampling cone voltage: 35V
Desolvation gas: 600L / Hr
Scan time: 0.2 second collision voltage: 10V
・ Channel: m / z 173> m / z 93
Reference material: quinic acid lactone (abbreviation: QAL)
In addition to this method, any known method can be selected.

9. It is an organic compound having a caffeine purine ring and has been conventionally known to have a cardiotonic / exciting action and awakening action.
In addition to coffee, it is also contained in tea, chocolate, etc., exhibits bitterness, and is one of the bitter components in coffee, but it has the same bitterness in so-called decaffeinated coffee, excluding caffeine, It is considered that the bitter taste of coffee itself is formed by a plurality of components involved in a complicated manner in addition to caffeine.
In the present embodiment, the content of caffeine (mg / 100 ml) is preferably 20 to 150, more preferably 30 to 130, still more preferably 50 to 120, Most preferably, it is 70-115.
This makes it possible to obtain a coffee beverage that is further excellent in taste and flavor.

10. Other Components In the present embodiment, the components contained in the coffee beverage may contain various compounds such as pyrazines involved in aroma, nicotinic acid and the like in addition to the above.
Even if the content of each of the above-described components varies by mixing the coffee beverage, the effect of the present invention can be enjoyed as long as the requirements of the present invention are satisfied.

In the present embodiment, the contents other than the components described above are as follows.

(Tannin)
In this embodiment, the tannin content (mg / 100 g) is desirably 90 to 400, more preferably 100 to 350, and even more preferably 200 to 330.

(PH)
The pH of the coffee drink and / or coffee drink in this embodiment is preferably 5.0 to 6.9, which is a neutral to weak acid region, and more preferably 5.4 to 6.5. More preferably, it is 0-6.4.

(Other additives)
In the present embodiment, a pH adjuster such as sodium bicarbonate (NaHCO 3) can be added within a range that does not adversely affect the taste.
In the case of sodium hydrogen carbonate, those obtained by a known method can be used, and commercially available products can also be used.

Hereinafter, the present invention will be described in more detail by way of examples using a packaged coffee beverage as an example, but the present invention is not limited to the examples.

1. Production of Coffee Beverage In this example, a plurality of coffee extract liquids (extract liquid 1 to extract liquid 7) were prepared under the conditions shown in Table 1 below, and these were mixed as appropriate so that the samples of Examples and Comparative Examples Was prepared.
As described above, the content of chlorogenic acids and organic acids (citric acid and quinic acid) in the coffee extract varies depending on the bean type, roasting conditions, and the like. A coffee beverage having a desired component configuration can be prepared by preparing an extract, measuring the components of each extract, and mixing and preparing them using known means.
In addition, although there is no restriction | limiting in particular about the measuring method of each component, In a present Example, content of chlorogenic acids was measured with the following method.

(Quantitative determination method of chlorogenic acids)
In this example, the content of chlorogenic acids was quantitatively analyzed by the following method.
A sample to be measured was diluted in a suitable amount with mobile phase A, filtered through a membrane filter, and subjected to analysis.
= Device configuration =
・ UV detector: 2487 Dual λ UV / VIS detector (Nihon Waters Co., Ltd.)
・ HPLC: Alliance 2695 Separation Module (Nippon Waters)
Column: Cadenza CD-C18 inner diameter 4.6 mm × length 150 mm, particle diameter 3 μm (Intact Corporation)
= Analysis conditions =
Sample injection volume: 10 μL
・ Flow rate: 1.0 mL / min
・ Detection wavelength: 325nm
-Column oven set temperature: 35 ° C
Eluent A: 0.05 M acetic acid, 10 mM sodium acetate, 5 (V / V)% acetonitrile solution Eluent B: acetonitrile = concentration gradient condition =
・ Gradient method from 100% A to 90% B = Quantitative method =
-The concentration was calculated from the area values of 9 types of chlorogenic acids including monocaffeoylquinic acid, ferulacic acid, and dicaffeoylquinic acid, using 5-caffeoylquinic acid as a standard substance.

In this example, a coffee extract extracted under the following conditions was prepared.

(Preparation of Example Sample and Comparative Sample)
Example coffee samples 1 to 5 and Comparative sample samples 1 to 4 in Table 3 below are prepared by mixing the coffee extract in a predetermined ratio by a known method, and immediately sealed in an aseptic condition. A comparative sample was prepared.
In preparation, if necessary, the coffee extract diluted with water may be used, or it may be concentrated to a predetermined concentration.

2. Sensory evaluation For Examples 1 to 5 and Comparative Examples 1 to 4 adjusted as shown in Table 2 above, a sensory evaluation test was performed according to the following evaluation items.
The sensory evaluation test was conducted by entrusting 7 panelists to evaluate each item according to the following criteria. Here, the numerical values in the table are the average values of the evaluations of the seven panelists (rounded to the nearest decimal place).
<Sour taste>
1 point: very sour 2 points: strong sour 3 points: slightly sour
4 points: Moderate sourness <Rating from sourness>
1 point: almost not felt
2 points: somewhat felt 3 points: felt to some extent
4 points: enough to feel 5 points: very much <roasted coffee>
1 point: Not much felt 2 points: Slightly felt 3 points: Sufficiently felt 4 points: Feels strongly 5 points: Feels very strong <flavor balance>
1 point: poorly balanced 2 points: slightly unbalanced 3 points: normal 4 points: good 5 points: very good <overall evaluation>
The suitability as a product was evaluated by comprehensively considering each evaluation item.
×: Inferior as a product (less than 11 points or 1 point evaluation item)
Δ: Appropriateness as a product is standard (12 to 11 points)
○: Excellent suitability as a product (14 to 13 points)
◎: Excellent suitability as a product (15 points or more)
Table 4 shows the results of evaluating the examples and comparative examples for each of the evaluation items.

(Discussion)
As a result of sensory evaluation, by adjusting the ratio of the organic acid (total of citric acid and quinic acid) content, the organic acid content, and the chlorogenic acid content to a predetermined range shown in the present application, Even if it contains a large amount of chlorogenic acids and can be expected to have a physiologically active function due to chlorogenic acids, and suitably suppress the increase in acidity due to the influence of organic acids that increase with it, and increase the ratio of shallow roast beans It was also confirmed that a coffee beverage and a container-packed coffee beverage that can taste the roasted feeling of roasted coffee can be obtained.

INDUSTRIAL APPLICABILITY The present invention is a coffee beverage, and in particular, can be used for a coffee beverage containing a predetermined amount or more of chlorogenic acids, which is one of physiologically active ingredients, a method for producing the same, a method for reducing the sourness of a coffee beverage, and a method for improving a roasted feeling It is.

Claims (8)

It is a packaged black coffee drink containing chlorogenic acids above a predetermined level,
The chlorogenic acid content [CQ] (mg / 100 g) in the beverage is 140 to 300, and the total content [A] (ppm) of citric acid and quinic acid in the beverage is 1000 to 2200. The above-mentioned [A] and the chlorogenic acid content [CQ] (mg / 100 g) ratio in the beverage liquid, [A] / [CQ] being 5.5 or more, a packaged black coffee beverage characterized by the above. The container-packed black coffee beverage according to claim 1, wherein the chlorogenic acid content [CQ] (mg / 100 g) in the beverage is 140 to 250. The container-filled black coffee beverage according to claim 1 or 2, wherein the total content [A] (ppm) of citric acid and quinic acid in the beverage is 1000 to 2000. Citric acid content (ppm) [CA] and quinic acid content (ppm) [QA]
] [QA] / [CA] ratio is 1.0 or more, The container-packed black coffee drink of any one of Claims 1-3 characterized by the above-mentioned. It is a container-packed drink, The container-packed black coffee drink of any one of Claims 1-4 characterized by the above-mentioned. A method for producing a containerized black coffee beverage containing chlorogenic acids in a predetermined amount or more,
The chlorogenic acid content [CQ] (mg / 100 g) in the beverage is adjusted to 140-300, and the total content [A] (ppm) of citric acid and quinic acid in the beverage is adjusted to 1000-2200. with the container to the [a], chlorogenic acids content in drinking fluid [CQ] (mg / 100g) ratio, characterized in that it is adjusted to 5.5 or more [a] / [CQ] Method for producing a stuffed black coffee beverage. A method for suppressing acidity of black coffee beverages containing chlorogenic acids in a predetermined amount or more,
The chlorogenic acid content [CQ] (mg / 100 g) in the beverage is adjusted to 140-300, and the total content [A] (ppm) of citric acid and quinic acid in the beverage is adjusted to 1000-2200. with the container to the [a], chlorogenic acids content in drinking fluid [CQ] (mg / 100g) ratio, characterized in that it is adjusted to 5.5 or more [a] / [CQ] Method for suppressing acidity of stuffed black coffee beverage. A method for improving the roast feeling of a black coffee beverage containing chlorogenic acids in a predetermined amount or more, wherein the chlorogenic acid content [CQ] (mg / 100 g) in the beverage is adjusted to 140 to 300, and the quencher in the beverage The total content [A] (ppm) of the acid and quinic acid is adjusted to 1000 to 2200, and the above [A] and the chlorogenic acid content [CQ] (mg / 100 g) ratio in the beverage liquid, [A ] / [CQ] is adjusted to 5.5 or more, The roasted feeling improvement method of the container-packed black coffee drink characterized by the above-mentioned.